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WO2005022605A3 - Films polymeres minces tres conducteurs et transparents, formes a partir de couches double ou multiple de poly(3,4-ethylenedioxythiophene) et de derives de celui-ci - Google Patents

Films polymeres minces tres conducteurs et transparents, formes a partir de couches double ou multiple de poly(3,4-ethylenedioxythiophene) et de derives de celui-ci Download PDF

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Publication number
WO2005022605A3
WO2005022605A3 PCT/US2004/005227 US2004005227W WO2005022605A3 WO 2005022605 A3 WO2005022605 A3 WO 2005022605A3 US 2004005227 W US2004005227 W US 2004005227W WO 2005022605 A3 WO2005022605 A3 WO 2005022605A3
Authority
WO
WIPO (PCT)
Prior art keywords
ethylenedioxythiophene
poly
derivatives
multiple layers
thin films
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2004/005227
Other languages
English (en)
Other versions
WO2005022605A2 (fr
Inventor
Brett D Martin
Ranganathan Shashidar
Nikolay Nikolov
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
US Naval Research Laboratory NRL
Original Assignee
US Naval Research Laboratory NRL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by US Naval Research Laboratory NRL filed Critical US Naval Research Laboratory NRL
Publication of WO2005022605A2 publication Critical patent/WO2005022605A2/fr
Publication of WO2005022605A3 publication Critical patent/WO2005022605A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/124—Intrinsically conductive polymers
    • H01B1/127—Intrinsically conductive polymers comprising five-membered aromatic rings in the main chain, e.g. polypyrroles, polythiophenes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
    • Y10T428/264—Up to 3 mils
    • Y10T428/265—1 mil or less
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/269—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension including synthetic resin or polymer layer or component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Non-Insulated Conductors (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

L'invention concerne un film polymère comprenant au moins deux couches possédant individuellement un composé de formule (I), dans laquelle: R1 et R2 désignent de manière indépendante des groupes organiques sélectionnés. L'invention concerne également un procédé de préparation d'un film polymère comprenant les étapes consistant: à utiliser une solution de monomère renfermant au moins un monomère de formule (II), dans laquelle: R1 et R2 représentent de manière indépendante des groupes organiques sélectionnés; à disperser la solution de monomère sur un substrat; à chauffer la solution de monomère sur le substrat, de manière à polymériser celui-ci; et à répéter les étapes consistant à utiliser une solution de monomère, à la disperser et à la chauffer au moins une fois, le revêtement par centrifugation étant effectué sur la couche revêtue par centrifugation antérieure.
PCT/US2004/005227 2003-03-26 2004-03-08 Films polymeres minces tres conducteurs et transparents, formes a partir de couches double ou multiple de poly(3,4-ethylenedioxythiophene) et de derives de celui-ci Ceased WO2005022605A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/396,444 US7026042B2 (en) 2003-03-26 2003-03-26 Highly conducting and transparent thin polymer films formed from double and multiple layers of poly(3,4-ethylenedioxythiopene) and its derivatives
US10/396,444 2003-03-26

Publications (2)

Publication Number Publication Date
WO2005022605A2 WO2005022605A2 (fr) 2005-03-10
WO2005022605A3 true WO2005022605A3 (fr) 2005-07-07

Family

ID=33510276

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2004/005227 Ceased WO2005022605A2 (fr) 2003-03-26 2004-03-08 Films polymeres minces tres conducteurs et transparents, formes a partir de couches double ou multiple de poly(3,4-ethylenedioxythiophene) et de derives de celui-ci

Country Status (2)

Country Link
US (2) US7026042B2 (fr)
WO (1) WO2005022605A2 (fr)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4281442B2 (ja) * 2003-05-29 2009-06-17 セイコーエプソン株式会社 正孔輸送材料
WO2005103109A1 (fr) * 2004-04-20 2005-11-03 Winther-Jensen Bjoern Oxydo-polymerisation de thiophenes et d'anilines au moyen de sels de fer (iii), a inhibition de base
US20070085061A1 (en) * 2005-10-14 2007-04-19 Elder Delwin L Conductivity enhancement of conductive polymers by solvent exposure
US7443566B2 (en) * 2006-03-10 2008-10-28 Sony Ericsson Mobile Communications Ab Low power, configurable display for mobile devices
KR101177188B1 (ko) * 2007-09-26 2012-08-24 다이이치 고교 세이야쿠 가부시키가이샤 도전성 고분자 전극의 제조 방법과 이를 구비한 색소 증감 태양전지
CN101971345B (zh) * 2007-10-29 2014-06-25 三星电子株式会社 纳米结构薄膜lcd设备
FR2924274B1 (fr) * 2007-11-22 2012-11-30 Saint Gobain Substrat porteur d'une electrode, dispositif electroluminescent organique l'incorporant, et sa fabrication
US8705544B2 (en) 2011-03-07 2014-04-22 Broadcom Corporation Method and apparatus for routing in a single tier switched network
US9928964B1 (en) * 2013-08-28 2018-03-27 Kemet Electronics Corporation Preparation of conjugated dimer and products formed therefrom
FR3015116B1 (fr) 2013-12-17 2016-01-01 Saint Gobain Support extracteur de lumiere et dispositif oled l'incorporant.
FR3019941A1 (fr) 2014-04-09 2015-10-16 Saint Gobain Support extracteur de lumiere et dispositif oled l'incorporant
JP6579309B2 (ja) * 2015-05-01 2019-09-25 味の素株式会社 硬化性組成物
FR3069660B1 (fr) 2017-07-31 2019-08-30 Saint-Gobain Glass France Dispositif electrocommandable a diffusion variable par cristaux liquides.
FR3081973B1 (fr) 2018-05-31 2020-05-22 Saint-Gobain Glass France Panneau vitre lumineux a diodes electroluminescentes.
US11152131B2 (en) 2018-06-20 2021-10-19 The Boeing Company Conductive compositions of conductive polymer and metal coated fiber
PL3857301T3 (pl) 2018-09-27 2025-06-09 Saint-Gobain Glass France Elektrycznie sterowane urządzenie o zmiennej dyfuzji przez ciekłe kryształy oraz sposób jego wytwarzania
FR3086771A1 (fr) 2018-09-27 2020-04-03 Saint-Gobain Glass France Dispositif electrocommandable a diffusion variable par cristaux liquides et son procede.
CN113140676B (zh) * 2020-01-20 2022-11-11 复旦大学 基于液滴的有机分子薄膜及其微纳器件阵列的制备方法
FR3108990A1 (fr) 2020-04-01 2021-10-08 Saint-Gobain Glass France Dispositif electrocommandable a diffusion variable par cristaux liquides et son procede

Citations (2)

* Cited by examiner, † Cited by third party
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US5035926A (en) * 1988-04-22 1991-07-30 Bayer Aktiengesellschaft Method of imparting antistatic properties to a substrate by coating the substrate with a novel polythiophene
US6403741B1 (en) * 1998-05-29 2002-06-11 Bayer Aktiengesellschaft UV-stabilized electrochromic assembly based on poly(3,4-ethylenedioxythiophene) derivatives

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DE3814730A1 (de) * 1988-04-30 1989-11-09 Bayer Ag Feststoff-elektrolyte und diese enthaltende elektrolyt-kondensatoren
DE19507413A1 (de) 1994-05-06 1995-11-09 Bayer Ag Leitfähige Beschichtungen
DE19536844C1 (de) 1995-10-02 1997-04-10 Bayer Ag Verfahren zur elektrostatischen Lackierung von nicht leitfähigen Oberflächen
US6001281A (en) * 1998-09-04 1999-12-14 Kemet Electronics Corporation Preparation of conductive polymers from stabilized precursor solutions
KR100442408B1 (ko) 1998-11-05 2004-11-06 제일모직주식회사 고전도성및고투명성을갖는폴리티오펜계전도성고분자용액조성물
KR100390578B1 (ko) 1998-12-17 2003-12-18 제일모직주식회사 고굴절율 전도성 고분자 박막 투명 필름 코팅액 조성물
US6334966B1 (en) * 2000-11-06 2002-01-01 Kemet Electronics Corporation Chemical oxidative preparation of conductive polymers

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5035926A (en) * 1988-04-22 1991-07-30 Bayer Aktiengesellschaft Method of imparting antistatic properties to a substrate by coating the substrate with a novel polythiophene
US6403741B1 (en) * 1998-05-29 2002-06-11 Bayer Aktiengesellschaft UV-stabilized electrochromic assembly based on poly(3,4-ethylenedioxythiophene) derivatives

Also Published As

Publication number Publication date
US20040253439A1 (en) 2004-12-16
US7026042B2 (en) 2006-04-11
US20080213466A1 (en) 2008-09-04
US7691439B2 (en) 2010-04-06
WO2005022605A2 (fr) 2005-03-10

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