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WO2005060547A3 - Magnesium-based hydrogen storage material and production thereof - Google Patents

Magnesium-based hydrogen storage material and production thereof Download PDF

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Publication number
WO2005060547A3
WO2005060547A3 PCT/US2004/040227 US2004040227W WO2005060547A3 WO 2005060547 A3 WO2005060547 A3 WO 2005060547A3 US 2004040227 W US2004040227 W US 2004040227W WO 2005060547 A3 WO2005060547 A3 WO 2005060547A3
Authority
WO
WIPO (PCT)
Prior art keywords
magnesium
hydrogen storage
based hydrogen
storage alloy
production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2004/040227
Other languages
French (fr)
Other versions
WO2005060547A2 (en
Inventor
Michael A Fetcenko
Kwo Young
Cheng Tung
Stanford R Ovshinsky
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ovonic Hydrogen Systems LLC
Original Assignee
Texaco Ovonic Hydrogen Systems LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Texaco Ovonic Hydrogen Systems LLC filed Critical Texaco Ovonic Hydrogen Systems LLC
Priority to CA002548093A priority Critical patent/CA2548093A1/en
Priority to JP2006543883A priority patent/JP2007522917A/en
Priority to EP04812679A priority patent/EP1691775A2/en
Priority to MXPA06006678A priority patent/MXPA06006678A/en
Publication of WO2005060547A2 publication Critical patent/WO2005060547A2/en
Anticipated expiration legal-status Critical
Priority to NO20063136A priority patent/NO20063136L/en
Publication of WO2005060547A3 publication Critical patent/WO2005060547A3/en
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0026—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof of one single metal or a rare earth metal; Treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C23/00—Alloys based on magnesium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0078—Composite solid storage mediums, i.e. coherent or loose mixtures of different solid constituents, chemically or structurally heterogeneous solid masses, coated solids or solids having a chemically modified surface region
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/04—Making non-ferrous alloys by powder metallurgy
    • C22C1/0408—Light metal alloys
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0244—Coatings comprising several layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
    • B22F2998/10—Processes characterised by the sequence of their steps
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C2202/00—Physical properties
    • C22C2202/04—Hydrogen absorbing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Powder Metallurgy (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)

Abstract

A magnesium-based hydrogen storage material including magnesium or a magnesium-based hydrogen storage alloy and a hydrogen desorption catalyst which is insoluble in said magnesium-based hydrogen storage alloy and is in the form of: 1) discrete dispersed regions of catalytic material in the bulk of said magnesium or magnesium-based hydrogen storage alloy; 2) discrete dispersed regions on the surface of particles of said magnesium or magnesium-based hydrogen storage alloy; 3) a continuous or semi-continuous layer of catalytic material on the surface of said magnesium or magnesium-based hydrogen storage alloy which is in bulk or particulate form; or 4) combinations thereof. Methods of producing the material are also disclosed.
PCT/US2004/040227 2003-12-11 2004-12-02 Magnesium-based hydrogen storage material and production thereof Ceased WO2005060547A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CA002548093A CA2548093A1 (en) 2003-12-11 2004-12-02 Catalyzed hydrogen desorption in mg-based hydrogen storage material and methods for production thereof
JP2006543883A JP2007522917A (en) 2003-12-11 2004-12-02 Catalytic hydrogen desorption in a Mg-based hydrogen storage material and method for producing the material
EP04812679A EP1691775A2 (en) 2003-12-11 2004-12-02 Catalyzed hydrogen desorption in mg-based hydrogen storage material and methods for production thereof
MXPA06006678A MXPA06006678A (en) 2003-12-11 2004-12-02 Catalyzed hydrogen desorption in mg-based hydrogen storage material and methods for production thereof.
NO20063136A NO20063136L (en) 2003-12-11 2006-07-06 Catalyzed hydrogen sorption in Mg-based hydrogen storage material and processes for preparation thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/735,240 US20050126663A1 (en) 2003-12-11 2003-12-11 Catalyzed hydrogen desorption in Mg-based hydrogen storage material and methods for production thereof
US10/735,240 2003-12-11

Publications (2)

Publication Number Publication Date
WO2005060547A2 WO2005060547A2 (en) 2005-07-07
WO2005060547A3 true WO2005060547A3 (en) 2007-05-10

Family

ID=34653573

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2004/040227 Ceased WO2005060547A2 (en) 2003-12-11 2004-12-02 Magnesium-based hydrogen storage material and production thereof

Country Status (9)

Country Link
US (1) US20050126663A1 (en)
EP (1) EP1691775A2 (en)
JP (1) JP2007522917A (en)
KR (1) KR20060123300A (en)
CN (1) CN101072889A (en)
CA (1) CA2548093A1 (en)
MX (1) MXPA06006678A (en)
NO (1) NO20063136L (en)
WO (1) WO2005060547A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9234264B2 (en) 2004-12-07 2016-01-12 Hydrexia Pty Limited Magnesium alloys for hydrogen storage

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7211541B2 (en) * 2003-12-11 2007-05-01 Ovonic Hydrogen Systems Llc Mg—Ni hydrogen storage composite having high storage capacity and excellent room temperature kinetics
FR2900401B1 (en) * 2006-04-26 2008-07-18 Centre Nat Rech Scient NANOCRYSTALLINE COMPOSITE FOR THE STORAGE OF HYDROGEN
JP5034567B2 (en) * 2007-03-08 2012-09-26 日産自動車株式会社 Hydrogen generator and fuel cell vehicle equipped with the same
KR100803074B1 (en) * 2007-03-20 2008-02-18 박정태 Hydrogen generating composition and high purity hydrogen generating device using same
CN100482833C (en) * 2007-04-03 2009-04-29 中国科学院上海微系统与信息技术研究所 Surface catalyzed high activity magnesium-base hydrogen storing material and preparing method thereof
US7998454B2 (en) * 2007-05-10 2011-08-16 Bio Coke Lab. Co. Ltd. Method of producing magnesium-based hydrides and apparatus for producing magnesium-based hydrides
CN101570314B (en) * 2008-05-04 2011-07-13 比亚迪股份有限公司 Preparation method of hydrogen storage material
JP5353252B2 (en) * 2009-01-09 2013-11-27 トヨタ自動車株式会社 Hydrogen-containing metal material state determination device and hydrogen generation device
WO2011026214A1 (en) * 2009-09-01 2011-03-10 The Governors Of The University Of Alberta Kinetic stabilization of magnesium hydride
JP5394273B2 (en) * 2010-02-03 2014-01-22 本田技研工業株式会社 Hydrogen storage material and method for producing the same
KR101915624B1 (en) 2010-02-24 2019-01-07 하이드렉시아 피티와이 리미티드 Hydrogen release system
WO2012021996A1 (en) * 2010-08-18 2012-02-23 The Governors Of The University Of Alberta Kinetic stabilization of magnesium hydride
US9045335B2 (en) 2010-08-18 2015-06-02 The Governors Of The University Of Alberta Kinetic stabilization of magnesium hydride
US9061907B2 (en) 2011-09-21 2015-06-23 The United States of America as represented by the Secretary of Commerce The National Institute of Standards and Technology Two-component structures providing fast-low temperature charging of Mg with hydrogen
TWI450764B (en) 2011-12-27 2014-09-01 Ind Tech Res Inst Hydrogen storage composite material and forming method thereof
US9206945B2 (en) * 2012-02-15 2015-12-08 Ford Global Technologies, Llc System and method for hydrogen storage
CN102586660B (en) * 2012-02-27 2013-06-05 燕山大学 Magnesium-based hydrogen storage alloy composite material with added metal sulfide
TWI526396B (en) * 2012-09-12 2016-03-21 財團法人工業技術研究院 Hydrogen storage composite and method of forming the same
US20140277328A1 (en) * 2013-03-14 2014-09-18 St. Jude Medical Systems Ab Composite material and uses thereof
CN103526141B (en) * 2013-09-05 2015-03-11 华南理工大学 Magnesium-based hydrogen storage material and preparation method thereof
US9343735B2 (en) 2014-04-14 2016-05-17 Ovonic Battery Company, Inc. Shared electrode hybrid battery-fuel cell system
US9954222B2 (en) 2014-12-10 2018-04-24 Basf Corporation Metal hydride compositions and lithium ion batteries
ITUB20150914A1 (en) * 2015-05-28 2016-11-28 Enea Agenzia Naz Per Le Nuove Tecnologie Lenergia E Lo Sviluppo Economico Sostenibile 00196 Roma / I PREPARATION OF PADS SUITABLE FOR REPEATED ABSORPTION AND DESORPTION CYCLES OF GAS, IN PARTICULAR FOR THE STORAGE OF HYDROGEN
CN104988344B (en) * 2015-06-23 2017-07-28 辽宁石化职业技术学院 The preparation method of composite hydrogen storage material
CN107848027A (en) 2015-07-23 2018-03-27 海德瑞克斯亚股份有限公司 Mg based alloys for hydrogen storage
CN105132838B (en) * 2015-09-25 2017-03-29 广西大学 A kind of regulation method of Mg17Al12 hydrogenation reaction
CN106614639A (en) * 2016-12-26 2017-05-10 常熟市胜阳干燥剂贸易有限公司 Broad-spectrum high-efficiency safe mildewproof material
CN107154481B (en) * 2017-04-28 2020-05-19 内蒙古科技大学 Hydrogen storage electrode alloy for Ni-MH battery and preparation method thereof
CN108950334B (en) * 2018-08-10 2020-07-14 中南大学 Magnesium-aluminum alloy with continuous eutectic structure and preparation method thereof
CN114164369B (en) * 2021-12-08 2022-08-12 河北科技大学 A kind of Mg/Ni/In hydrogen storage material and preparation method thereof
CN114229797B (en) * 2022-01-17 2024-01-12 重庆大学 Method for producing hydrogen based on hydrolysis of Mg-Ni-Y alloy containing LPSO second phase
CN114411028B (en) * 2022-01-21 2022-09-20 徐州工程学院 Trace nickel composite layered magnesium composite material and preparation method and application thereof
CN115417373B (en) * 2022-08-02 2023-09-15 华南理工大学 Preparation method of amorphous/crystalline composite magnesium-based hydrogen storage material
CN115367700B (en) * 2022-08-31 2024-04-05 理工清科(重庆)先进材料研究院有限公司 MgH catalyzed by zinc-copper bimetallic MOF 2 Hydrogen storage material, preparation method and application thereof
CN116426803B (en) * 2023-03-07 2025-07-08 上海镁源动力科技有限公司 Magnesium-based alloy for cyclic hydrogen storage and release and preparation method thereof
US20250075294A1 (en) * 2023-09-01 2025-03-06 National Taiwan University Of Science And Technology Magnesium-based composite material and method of forming the same

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US2228781A (en) * 1938-11-08 1941-01-14 Magnesium Dev Corp Process for the production of magnesium-zirconium alloys
US4613362A (en) * 1981-12-03 1986-09-23 Kernforschungsanlage Julich Method of making magnesium-containing metal granulate for the storage of hydrogen
US4765954A (en) * 1985-09-30 1988-08-23 Allied Corporation Rapidly solidified high strength, corrosion resistant magnesium base metal alloys

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JP3715743B2 (en) * 1997-04-15 2005-11-16 株式会社神戸製鋼所 Manufacturing method of Mg alloy member
US6830725B2 (en) * 2003-04-01 2004-12-14 Texaco Ovonic Battery Systems, Llc Hydrogen storage alloys having a high porosity surface layer

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
US2228781A (en) * 1938-11-08 1941-01-14 Magnesium Dev Corp Process for the production of magnesium-zirconium alloys
US4613362A (en) * 1981-12-03 1986-09-23 Kernforschungsanlage Julich Method of making magnesium-containing metal granulate for the storage of hydrogen
US4765954A (en) * 1985-09-30 1988-08-23 Allied Corporation Rapidly solidified high strength, corrosion resistant magnesium base metal alloys

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
FUJII ET AL.: "Hydrogen Storage Properties in Nano-structured Magnesium and Carbon-related Materials", PHYSICA B CONDENSED MATTER, vol. 328, 30 April 2003 (2003-04-30), pages 77 - 80, XP003012815 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9234264B2 (en) 2004-12-07 2016-01-12 Hydrexia Pty Limited Magnesium alloys for hydrogen storage

Also Published As

Publication number Publication date
NO20063136L (en) 2006-09-07
EP1691775A2 (en) 2006-08-23
WO2005060547A2 (en) 2005-07-07
KR20060123300A (en) 2006-12-01
JP2007522917A (en) 2007-08-16
CN101072889A (en) 2007-11-14
MXPA06006678A (en) 2007-02-02
US20050126663A1 (en) 2005-06-16
CA2548093A1 (en) 2005-07-07

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