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WO2004085710A3 - Verfahren zur anodischen alkoxylierung von organischen substraten - Google Patents

Verfahren zur anodischen alkoxylierung von organischen substraten Download PDF

Info

Publication number
WO2004085710A3
WO2004085710A3 PCT/EP2004/002665 EP2004002665W WO2004085710A3 WO 2004085710 A3 WO2004085710 A3 WO 2004085710A3 EP 2004002665 W EP2004002665 W EP 2004002665W WO 2004085710 A3 WO2004085710 A3 WO 2004085710A3
Authority
WO
WIPO (PCT)
Prior art keywords
organic substrates
alkoxylation
mediator
alkyl
anodic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2004/002665
Other languages
English (en)
French (fr)
Other versions
WO2004085710A2 (de
Inventor
Christian Reufer
Thomas Lehmann
Rainer Sanzenbacher
Christoph Weckbecker
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Degussa GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Degussa GmbH filed Critical Degussa GmbH
Priority to EP04720604A priority Critical patent/EP1606434A2/de
Priority to US10/546,135 priority patent/US20060157353A1/en
Publication of WO2004085710A2 publication Critical patent/WO2004085710A2/de
Publication of WO2004085710A3 publication Critical patent/WO2004085710A3/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/23—Oxidation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

Organische Substrate, wie cyclische Ether, N-substituierte Amide, Ketone, Alkylaromaten und Alkylheteroaromaten, lassen sich in Gegenwart eines Alkohols anodisch alkoxylieren, insbesondere methoxylieren. Bekannt ist die Alkoxylierung in Gegenwart eines Mediators oder in einer geteilten Zelle mit einem Feststoffelektrolyt. Die erfindungsgemäße anodische Alkoxylierung erfolgt in Abwesenheit eines Mediators in einer ungeteilten Elektroysezelle unter Verwendung einer Diamantschichtanode oder Goldanode. Erzielt werden hohe Stoff- und Stromausbeuten.
PCT/EP2004/002665 2003-03-25 2004-03-15 Verfahren zur anodischen alkoxylierung von organischen substraten Ceased WO2004085710A2 (de)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP04720604A EP1606434A2 (de) 2003-03-25 2004-03-15 Verfahren zur anodischen alkoxylierung von organischen substraten
US10/546,135 US20060157353A1 (en) 2003-03-25 2004-03-15 Method for the anodic alkoxylation of organic substances

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10313169A DE10313169A1 (de) 2003-03-25 2003-03-25 Verfahren zur anodischen Alkoxylierung von organischen Substraten
DE10313169.8 2003-03-25

Publications (2)

Publication Number Publication Date
WO2004085710A2 WO2004085710A2 (de) 2004-10-07
WO2004085710A3 true WO2004085710A3 (de) 2005-04-21

Family

ID=32980680

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2004/002665 Ceased WO2004085710A2 (de) 2003-03-25 2004-03-15 Verfahren zur anodischen alkoxylierung von organischen substraten

Country Status (4)

Country Link
US (1) US20060157353A1 (de)
EP (1) EP1606434A2 (de)
DE (1) DE10313169A1 (de)
WO (1) WO2004085710A2 (de)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102009001008A1 (de) * 2009-02-19 2010-08-26 Evonik Degussa Gmbh Reaktivextraktion von freien organischen Säuren aus deren Ammoniumsalzen
CN105198840B (zh) * 2015-09-28 2018-06-26 乐平市康鑫医药化工有限公司 固定床法制备2,5-二甲氧基二氢呋喃的方法
CN113897627B (zh) * 2020-07-06 2023-03-03 万华化学集团股份有限公司 一种电化学制备五元杂环二烷氧基化合物的方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2848397A1 (de) * 1978-11-08 1980-05-22 Basf Ag Elektrochemische herstellung von in 4-stellung substituierten benzaldehyddialkylacetalen
EP0212509A1 (de) * 1985-08-14 1987-03-04 BASF Aktiengesellschaft Verfahren zur Herstellung von Benzoesäureorthoestern sowie Verbindungen dieser Klasse
EP0237769A2 (de) * 1986-02-20 1987-09-23 Bayer Ag Benzaldehyd-dialkylacetale
EP0283807A1 (de) * 1987-03-14 1988-09-28 BASF Aktiengesellschaft Verfahren zur Herstellung von Methoxiacetaldehyddialkylacetalen
DE19911746A1 (de) * 1999-03-16 2000-09-21 Basf Ag Diamantelektroden

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2714579A (en) * 1951-07-18 1955-08-02 Exxon Research Engineering Co Lubricating oil additives
DE3142626A1 (de) * 1981-10-28 1983-05-05 Basf Ag, 6700 Ludwigshafen Elektrochemisches verfahren zur herstellung von 2,5-dialkoxy-2,5-dihydrofuranen
US5074974A (en) * 1990-06-08 1991-12-24 Reilly Industries, Inc. Electrochemical synthesis and simultaneous purification process

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2848397A1 (de) * 1978-11-08 1980-05-22 Basf Ag Elektrochemische herstellung von in 4-stellung substituierten benzaldehyddialkylacetalen
EP0212509A1 (de) * 1985-08-14 1987-03-04 BASF Aktiengesellschaft Verfahren zur Herstellung von Benzoesäureorthoestern sowie Verbindungen dieser Klasse
EP0237769A2 (de) * 1986-02-20 1987-09-23 Bayer Ag Benzaldehyd-dialkylacetale
EP0283807A1 (de) * 1987-03-14 1988-09-28 BASF Aktiengesellschaft Verfahren zur Herstellung von Methoxiacetaldehyddialkylacetalen
DE19911746A1 (de) * 1999-03-16 2000-09-21 Basf Ag Diamantelektroden

Also Published As

Publication number Publication date
WO2004085710A2 (de) 2004-10-07
EP1606434A2 (de) 2005-12-21
US20060157353A1 (en) 2006-07-20
DE10313169A1 (de) 2004-10-14

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