WO2003035020A1 - Material with drawing ability, cosmetic composition with drawing ability, make-up composition and make-up method - Google Patents

Abstract

The invention concerns a material with drawing ability comprising, at room temperature, at least a mesomorphous fluid lamellar or direct hexagonal type phase, and at least a crystalline or amorphous solid phase, and/or a mesomorphous cubic or gel lamellar type phase. Said material has, at 25 DEG C in oscillation mode in its linear viscoelastic domain, a G* complex modulus ranging between 102 and 106 Pa and a loss angle ranging between 0 and 45 DEG . The invention also concerns a cosmetic composition with drawing ability containing said material, and a make-up composition as well as a make-up method.

Description

 SPINNABLE MATERIAL, SPINNABLE COSMETIC COMPOSITION, MAKE-UP COMPOSITION AND METHOD OF MAKING

MAKEUP

The present invention relates to a spinnable material, to a cosmetic composition comprising this spinnable material, and to a process for making up keratin materials using the cosmetic composition. In cosmetics, in particular for making up keratin materials such as the skin, hair, nails, eyelashes and eyebrows, lips and any other area of the body and face, and in decoration, it is advantageous to have a sufficiently consistent, moldable material with a stringy character which. can be spread and then stretched by hand or using commonly used instruments, such as a brush, comb, spatula or knife.

We seek to obtain threads which, after stretching, are sufficiently consistent, that is to say that they must retain their shape, not shrink, or sag under the action of their own weight, for example in the case of stage make-up, hair or eyelashes.

A rapid increase in the consistency of the material after its application can be obtained by a transition from the liquid state to the solid state by cooling, but the implementation is difficult in the field of cosmetics.

Indeed, this change of state requires the heating of the material at the time of its use and a melting temperature higher than the ambient temperature while remaining sufficiently low to avoid any risk of burning or burning sensation during its application.

To increase the consistency, it is also possible to use one or more chemical bodies that are solid at room temperature, dispersed, solubilized or swollen by volatile solvents. These solvents then evaporate, increasing the concentration of solid chemicals. We can then obtain a sufficient increase in consistency. This use of organic solvents has a drawback in that it is necessary to have recourse to harmless solvents, and in cosmetics the preferred solvent is water, but it is very little volatile at room temperature.

Furthermore, the materials which may have a known stringing character are solutions of more or less gelled surfactants, molten polymers, gels, sol-gels and derivatives of petroleum products such as carbon fibers, but they have drawbacks. such as lack of consistency and breakage of the strands, need for a high deformation speed, a high temperature, a thermal shock to spin and then freeze the strands obtained or a fiber stabilization treatment.

The Applicant has surprisingly found that certain materials comprising a certain organization of phases were consistent and moldable at room temperature, and made it possible to form threads by simple stretching by hand or using an instrument such as a brush. , a comb, a spatula or a knife. These spinnable materials comprise, at ambient temperature, 1) at least one mesomorphic phase of direct hexagonal or fluid lamellar type, and 2) at least one crystalline or amorphous solid phase, and / or a mesomorphic phase of cubic or lamellar gel type.

By "room temperature" is meant a temperature of about 25 ° C.

The consistency of these spinnable materials is evaluated by measuring the rheological properties in oscillation mode in their linear viscoelastic range. They then have a complex module G * of between 10 ² and 10 ⁶ Pa, preferably between 10 ³ and

10 ⁵ Pa, and a loss angle δ of between 0 ° and 45 °, preferably between 10 ° and 40 °, at 25 ° C and for frequencies ranging from 10 ^'2 Hz to 1 Hz.

In addition, in cosmetics, after application to the hair, eyelashes or eyebrows, the spinnable material has the advantage of not adhering either to itself or to other surfaces and it can be easily removed by washing with water or by using a makeup-removing product such as a lotion based on a solution of surfactants.

The present invention therefore relates to a spinnable material comprising, at room temperature, at least one mesomorphic phase of direct hexagonal or fluid lamellar type, and at least one crystalline or amorphous solid phase, and / or a mesomorphic phase of cubic or lamellar type. gel, and having in oscillation mode in its linear viscoelastic range, a complex module G * between 10 ² and 10 ⁶ Pa, preferably between 10 ³ and 10 ⁵ Pa, and a loss angle δ between 0 ° and 45 ° , preferably between 10 ° and 40 °, at 25 ° C and for frequencies ranging from 10 ^'2 Hz to 1 Hz.

Another subject of the invention consists of a spinnable cosmetic composition comprising said spinnable material.

The present invention also relates to a makeup composition.

The present invention also relates to a process for making up keratin materials using the spinnable cosmetic composition.

Other objects, characteristics, aspects and advantages of the invention will appear even more clearly on reading the description and the various examples which follow.

The present invention relates to a spinnable material comprising, at ambient temperature,

1) at least one mesomorphic phase of fluid lamellar or direct hexagonal type, and

2) at least one crystalline solid phase, amorphous solid and / or a mesomorphic phase of gel or cubic lamellar type.

By fluid lamellar phase (phase D according to Ek all, Advances in Liquid Crystals, vol. 1, pages 1-143, Acad. Press, 1975, Ed. GH Brown) means a liquid crystal phase with plane symmetry, comprising several bilayers of amphiphilic compounds arranged in parallel and separated by a liquid medium which is generally water. By direct hexagonal phase (phase F according to Ek all, Advances in Liquid Crystals, vol. 1, pages 1-143, Acad. Press, 1975, Ed. GH Brown), is meant a liquid crystal phase with hexagonal arrangement of parallel cylinders formed of an amphiphilic compound and separated by a liquid medium which is generally water. The term “cubic phase” is intended to mean a phase organized bipolarly into distinct hydrophilic and lipophilic domains, in close contact and forming a three-dimensional network with cubic symmetry. Such an organization has been described in particular in "La Recherche", Vol. 23, pages 306-315, March 1992 and in "Lipid Technology", Vol. 2, n ° 2, pages 42-45, April 1990. Depending on the arrangement of the hydrophilic and lipophilic domains, the cubic phase is said to be of normal or reverse type. The term cubic phase used according to the present invention groups together the different types of cubic phase.

By gel lamellar phase or Lβ phase is meant a phase in which the surfactant molecules and / or more generally of amphiphilic compounds are organized in the form of bimolecular layers spaced apart by aqueous sheets. Within the bimolecular layers, the molecules are distributed according to a hexagonal geometry and their hydrocarbon chains are in a crystalline state, they are oriented perpendicular to the plane of the bimolecular layers but have no specific orientation with respect to each other in the plan of these layers (Handbook of lipid research 4, the physical chemistry of lipids from alkanes to phospholipids, DM Small Editor, 1986, Plénum Press, p. 51-56). The lamellar gels phases are for example known in the field of hydrated soaps.

The spinable materials according to the invention are characterized by particular rheological properties in oscillation mode in their linear viscoelastic range. They present a module G * complex between 10 ² and 10 ⁶ Pa, preferably between 10 ³ and 10 ⁵ Pa, a loss angle δ between 0 ° and 45 °, preferably between 10 ° and 40 °, at room temperature and for frequencies ranging from 10 ^"2 Hz to 1 Hz. The term linear viscoelastic domain means the range of stress amplitude (τ ₀ ) defined by 0 <τ ₀ ≤τ ₀ in which the values of G * and δ measured at a fixed frequency, are independent of τ ₀ .

In addition, these materials are characterized by the fact that outside the linear viscoelastic range, for which τ> τ _oc , for a frequency of 1 Hz, the value of the complex modulus decreases at most by a factor of 10 when the amplitude of the stress goes from τ _ow to 10 τ ₀₀ , x _oc being determined at the frequency of 1 Hz.

G * and δ are the viscoelastic parameters used to measure the physical properties of viscoelastic fluids. They were measured using a Haake RS 150 rheometer at 25 ° C with bodies of cone-plane geometry (cone diameter and plane dimension of 35 mm, cone angle of 2 °, and air gap between the cone and the plane of 0, 1 mm). The spinnable material according to the invention preferably comprises at least water, at least one water-soluble surfactant and at least one water-insoluble surfactant, the surfactants being chosen from anionic, amphoteric or zwitterionic, cationic, nonionic surfactants , and mixtures thereof. The term “water-soluble surfactant” means a surfactant which, at a concentration of 20 g / l in permuted water at a temperature of 25 ° C., gives a transparent, isotropic solution which is fluid and does not contain particles detectable by optical microscopy.

The water-soluble surfactants constitute all or part of the mesomorphic phase or phases of the fluid lamellar and / or direct hexagonal type of the material.

The water-soluble surfactants suitable in the present invention are those well known in the art and are chosen among anionic, amphoteric or zwitterionic, cationic, nonionic surfactants, and mixtures thereof.

As water-soluble anionic surfactants, it is possible to use the carboxylic acid salts with a linear or branched, saturated or unsaturated alkyl chain, containing from 6 to 14 carbon atoms, preferably from 10 to 14 carbon atoms, such as the acid salts lauric and myristic acid; and their mixtures. The salts are, for example, the alkali or alkaline earth metal salts, the ammonia, amino alcohol, or amino acid salts, such as the sodium, potassium, magnesium, triethanolamine, N salts. - methylglucamine, lysine or arginine.

As the carboxylic acid salt which can be used in the present invention, mention may in particular be made of the N-methylglucamine salt of lauric acid and the N-methylglucamine salt of myristic acid. As other water-soluble anionic surfactants suitable for the present invention, mention may in particular be made of the salts of ethoxylated carboxylic acids; galacturonates, sarcosinates and acylsarcosinates such as sodium laurylsarcosinate; taurates and methyltaurates; isethionates and acylisethionates such as sodium isethionate and sodium cocoylisethionate; sulfosuccinates; alkyl sulphates and alkyl ether sulphates such as sodium or triethanolamine lauryl sulphate, sodium or potassium lauryl ether sulphate; monoalkyl or dialkyl esters of phosphoric acid such as, for example, sodium, potassium or triethanolamine monolauryl- or dilaurylphosphate, sodium, potassium or diethanolamine myristylphosphate; alkane sulfonates; bile salts such as cholates, deoxycholates, taurocholates, taurodeoxycholates; lipoamino acids and their salts such as mono- or disodium acylglutamates; acylalginates, acylaspartates, twin, bipolar surfactants such as those described in Surfactant Science Series, Vol. 74, edited by Krister Homberg. The alkyl and acyl groups of the above compounds have in particular 1 to 14 carbon atoms. As amphoteric or zwitterionic water-soluble surfactants, there may be mentioned, as examples, betaines such as dimethylbetaine; sulfobetaines such as cocoamidopropyl hydroxysultaine; the (C ₁₄ -C.) amphoacetates such as cocoamphodiacetate; and their mixtures.

As water-soluble cationic surfactants, it is possible to use in the present invention, (C 1 -C 4 alkyl) -trimethylammonium salts such as, for example, chlorides, bromides and acetates of decyltrimethylammonium, dodecyltrimethylammonium, tetradecyltrimethylammonium and hexadecyltrimethylammonium.

As water-soluble nonionic surfactants, it is possible to use, for example, polyol ethers such as oxyethylenated sorbitol or glyceryl ethers; polyglycerol ethers and esters; polyoxyethylenated ethers of fatty alcohols comprising at least one chain of fatty alcohols having from 10 to 22 carbon atoms and the solubility of which depends on the number of oxyethylene units and on the length of the fatty chain. For example, for a fatty chain comprising 12 carbon atoms, the number of oxyethylene units must be greater than 7. By way of example, mention may be made of lauryl alcohol ethers comprising more than 7 oxyethylene units; alkylpolyglucosides in which the alkyl group contains from 1 to 14 carbon atoms, such as decylglucoside, laurylglucoside and cocoylglucoside; the (C _14!.) glucopyranoside and (C _1-14) thioglucopyranosides; the (C _{1. 14)} maltosides; the (C _{1- 4} ι) -N-methyl glucamides; polyoxyethylenated sorbitan esters which generally contain from 1 to 100 oxyethylene units and preferably from 2 to 40 oxyethylene units; amino alcohol esters and mixtures thereof.

Preferably, the water-soluble C ₆ carboxylic acid salts are used as water-soluble surfactants. ₁₄ .

The spinnable material according to the invention preferably comprises the water-soluble surfactants in an amount of 5 to 75% by weight, better still 10 to 50% by weight relative to the total weight of the spinnable material. By water-insoluble surfactant is meant a surfactant which, at a concentration of 20 g / l in water deionized at room temperature, gives a cloudy solution indicating the non-solubilization of the surfactant in water. Water-insoluble surfactants help provide texture, that is, the consistency of the final material. They constitute all or part of the gel lamellar mesomorphic phase and / or crystalline or amorphous solid phases of the material.

The water-insoluble surfactants suitable for the present invention are those well known in the art and are chosen from anionic, amphoteric or zwitterionic, cationic, nonionic surfactants and their mixtures.

As anionic surfactants insoluble in water, mention may in particular be made of the salts of carboxylic acids comprising a linear or branched, saturated or unsaturated alkyl chain, comprising from 15 to

34 carbon atoms, preferably from 16 to 22 carbon atoms, such as the salts of palmitic or stearic acid; and their mixtures. The carboxylic acid salts comprising a fatty chain preferably contain 15 to 32 carbon atoms, better still from 16 to 22 carbon atoms, while the salts comprising a monounsaturated or polyunsaturated or branched fatty chain preferably contain 16 to 34 carbon atoms, and better still 18 to 24 carbon atoms. The salts are, for example, the alkali or alkaline earth metal salts, the ammonia, amino alcohol, or amino acid salts, such as the sodium, potassium, magnesium, triethanolamine, N salts. -methylglucamine, lysine or arginine.

As salt of carboxylic acid is particularly suitable in the present invention, the sodium salts of fatty acids there may be mentioned C ₁₆ -C _22, potassium salt of fatty acids, C ₁₆ -

C ₂₂ , the N-methylglucamine salts of Cι ₆ -C ₂₂ fatty acids, for example, the N-methylglucamine salt of palmitic acid and the N-methylglucamine salt of stearic acid. As other anionic surfactants which are insoluble in water and which can be used in the present invention, mention may in particular be made of salts comprising C ₁₆ -C ₃₀ alkyl chains such as alkyl sulfates, alkyl ether sulfates, dialkylphosphates, for example, metal salts alkaline or amino alcohol, and in particular the sodium, potassium or N-methylglucamine salts, dicetylphosphate or dimyristylphosphate; alkane sulfonates, lipoamino acids and their salts; the alkali metal and amino alcohol salts of cholesterol sulfate or cholesterol phosphate. As amphoteric or zwitterionic surfactant insoluble in water, Examples betaines and (C _16-30 alkyl) sulphobetaines (alkyl C _{16 30.);} lecithins and sphingomyelins.

As cationic water-insoluble surfactants which can be used in the present invention, mention may in particular be made of (C ₁₇ -C ₃₀ alkyl) trimethylammonium salts such as chlorides, bromides and acetates of octadecyltrimethylammonium, and di ( C ₁₂ -C ₂₂ alkyl) dimethylammonium such as chlorides, bromides and acetates of didodecyldimethylammonium, ditetradecyl dimethylammonium, dihexadecyldimethylammonium and dioctadecyldimethylammonium.

As non-ionic water-insoluble surfactants which can be used in the present invention, mention may be made of glyceryl ethers; esters of glyceryl and of C ₁₄ -C ₃₀ fatty acids, such as glyceryl stearate; polyoxyethylenated ethers of fatty alcohols comprising in particular less than 10 oxyethylene units; alkylpolyglucosides in which the alkyl group contains from 16 to 30 carbon atoms; the (C _{6 30.)} glucopyranoside and (C ₁₆ _ ₃₀₎ thioglucopyranosides; the (C _{16 30).} maltosides; the (C _{16 30).} methylglucamides; polyoxyethylenated sorbitan esters; amino alcohol esters; optionally oxyethylenated sterols and phytosterols; ceramides; fatty alcohols having from 8 to 30 carbon atoms; ethers and esters of fatty alcohols in Cι ₆ . ₃₀ ; and their mixtures. The spinnable material according to the invention preferably comprises the water-insoluble surfactants in an amount ranging from 5 to 90% by weight, better still from 10 to 60% by weight, relative to the total weight of the spinnable material. The spinnable material according to the invention may further comprise additives in an amount up to 75% by weight, preferably in an amount from 0 to 50% relative to the total weight of the spinnable material.

The additives are intended to constitute all or part of the crystalline or amorphous solid phases possibly present in the material. Any well-known additive can be used in the art such as inorganic or organic fillers such as clays, such as smectites, modified hectorites or not, eg those sold under the trade names Bentone ^® by Rheox, Laponite ^® by SOUTHERN CLAY PRODUCTS,

VEEGUM ^® HS by RT VANDERBILT; pigments, nacres, dyes, silica powders, talc, starch, polyethylene, powders or fibers of rayon, nylon or polyamide. The spinnable material can comprise solvents chosen from lower alcohols containing from 1 to 6 carbon atoms such as ethanol; polyols such as glycerin; glycols such as butylene glycol, isoprene glycol, propylene glycol, polyethylene glycols such as PEG-8; sorbitol; sugars such as glucose, fructose, maltose, lactose or sucrose; and their mixtures.

These solvents are preferably contained in the spinnable material according to the invention in an amount of 0.5 to 90% by weight, preferably from 1% to 30% by weight relative to the total weight of the spinnable material.

To obtain more or less fluid materials, it is also possible to introduce into the material one or more thickening agents in an amount preferably ranging from 0.05 to 5% by weight relative to the total weight of the spinnable material. As thickening agents, mention may in particular be made of polysaccharide biopolymers such as xanthan gum, guar gum, alginates and modified celluloses; synthetic polymers such as acrylic polymers such as CARBOPOL ^® 980 sold by the company Goodrich, acrylate / acrylonitrile such as HYPAN SS201 ^® sold by the company KINGSTON, and mixtures thereof.

The present invention also relates to a spinnable cosmetic composition comprising a spinnable material as described above.

The cosmetic composition may also comprise adjuvants usually used in the cosmetic field, such as hydrocarbon, fluorinated, silicone oils, volatile or not, perfumes, preservatives, sequestrants (for example, the alkali metal salts of the ethylene diamine tetraacetic acid (EDTA)), sun filters, pH stabilizers, preservatives and mixtures.

Those skilled in the art will take care to choose any adjuvants and their quantity so that they do not harm the properties of the compositions of the present invention.

These adjuvants are present in the composition according to the invention in an amount ranging from 0 to 20% by weight relative to the total weight of the composition.

The cosmetic compositions according to the invention can be used as make-up products for keratin materials such as the skin, the hair, the scalp, the nails, the eyelashes and eyebrows, the lips and any other area of the body and of the face, in particular for making up the skin (body or face, including the eyelids), scalp, hair, eyelashes or eyebrows, for example as a mascara.

The present invention also relates to a composition for making up the skin, scalp, hair, eyelashes or eyebrows comprising the spinnable cosmetic composition such as described above. This makeup composition can be, for example, in the form of a mascara.

The present invention also relates to a cosmetic process for making up keratin materials, which consists in applying the spinnable cosmetic composition as defined above, to the keratin materials and in stretching the composition deposited using his fingers or d '' a suitable instrument such as a comb or brush.

The following examples illustrate the present invention and should not be considered in any way as limiting the invention.

EXAMPLES

The quantities indicated in% are in% by weight unless otherwise indicated.

Example 1

A composition was prepared from the following ingredients:

Lauric acid 3%

Myristic acid 6%

Palmitic acid 10%

Isostearic acid 10%

Glyceryl stearate 5%

N-methylglucamine 14.9%

Disodium cocoamphodiacetate 2%

PEG-8 3%

Glycerin 7%

0.2% tetrasodium EDTA

Preservatives 0.4%

Water qs 100%

First, the preservatives, EDTA, glycerin, PEG-8 and water were mixed, and the mixture was brought to 80 ° C.

In a second step, the mixture containing the fatty acids and the glyceryl stearate was heated, and the mixture was added to the aqueous phase with stirring. Disodium cocoamphodiacetate was then added, followed by N-methylglucamine dissolved in water. Stirring was continued for 10 minutes at 80 ° C and the whole was cooled with stirring.

A homogeneous, opaque, slightly yellowish and consistent composition was obtained.

The nature of the crystalline phases present at 25 ° C. was then determined by observations by light microscopy and by X-ray diffraction analysis. It was then found that the composition of Example 1 had a crystalline phase and a fluid lamellar type mesomorphic phase. Example 2

A composition was prepared from the following ingredients:

Lauric acid 6%

Myristic acid 6%

Palmitic acid 6.5%

Isostearic acid 6.5%

Glyceryl stearate 2.75%

N-methylglucamine 16.3%

Disodium cocoamphodiacetate 4%

PEG-8 4%

Glycerin 4%

0.2% tetrasodium EDTA

Preservatives 0.4%

Water qs 100%

The same procedure was followed as that of Example 1. A homogeneous, opaque, white and consistent composition was obtained. The nature of the crystalline phases present at 25 ° C. was then determined by observations by optical microscopy and by X-ray diffraction analysis. It was then found that the composition of Example 2 exhibits a mesomorphic phase of the type lamellar gel and a mesomorphic phase of fluid lamellar type.

Rheological behavior of the compositions of Examples 1 and 2

Complex modulus and loss angle measurements were made for frequencies of 10 ^"2 Hz and 1 Hz. The measurements were made using a Haake RS 150 rheometer at 25 ° C with cone-plane geometry (diameter of the cone and dimension of the plane 35 mm, cone angle of 2 °, and air gap between the cone and the plane of 0.1 mm). The results are shown in the following table 1:

Table 1

Eyelash makeup test

Hair samples were made up using an eyelash comb. Each hair test piece consists of a segment of

44 hair tied side by side on a cord over a total length of 5 mm. The individual length of each hair is 20 mm and the average diameter is 75 μm.

The eyelash comb is of the type used in plastic mascara packaging articles. It includes 27 teeth distributed over a length of 23 mm, each tooth measuring 2 mm.

The test pieces were made up by 5 successive passes of the comb previously dipped in the compositions of Examples 1 and 2.

The results are collated in Table 2 below.

Table 2

Claims

1. Spinable material characterized in that it comprises, at ambient temperature, 1) at least one mesomorphic phase of fluid lamellar or direct hexagonal type, and 2) at least one crystalline or amorphous solid phase, and / or a mesomorphic phase of cubic or lamellar gel type, and in that it exhibits, at oscillations mode in its linear viscoelastic domain, a complex module G * between 10 ² and 10 ⁶ Pa and a loss angle between 0 and 45 °. 2. Spinable material according to claim 1, characterized in that the complex module G * is between 10 ³ and 10 ⁵ Pa. 3. spinnable material according to claim 1 or 2, characterized in that the loss angle is between 10 and 40 ° 4. Spinable material according to any one of the preceding claims, characterized in that outside the linear viscoelastic range, for which τ> τ ₀₀ , for a frequency of 1 Hz, the value of the complex modulus decreases by more than one factor 10 when the amplitude of the stress goes from τ _oc to 10 τ _oe , τ _oc being determined at the frequency of 1 Hz. 5. Spinable material according to any one of the preceding claims, characterized in that it comprises at least water, at least one water-soluble surfactant and at least one water-insoluble surfactant. 6. Spinable material according to claim 5, characterized in that the surfactants are chosen from anionic, amphoteric or zwitterionic, cationic, nonionic surfactants and their mixtures. 7. Spinable material according to claim 6, characterized in that the anionic surfactants are chosen from the alkali or alkaline earth metal salts, ammonia, amino alcohol or amino acid carboxylic acids with a linear or branched alkyl chain, saturated or unsaturated with C ₆ -C ₃₄ . 8. Spinable material according to claim 6, characterized in that the amphoteric or zwitterionic surfactants are chosen from betaines, sulfobetaines and (C _{1 14} alkyl) amphoacetates. 9. Spinable material according to claim 6, characterized in that the cationic surfactants are chosen from salts of (alkyl in C ₁ -C ₃₀ ) trimethylammonium, and di (C ₁₂ -C ₂₂ alkyl) dimethylammonium. 10. Spinable material according to claim 6, characterized in that the nonionic surfactants are chosen from polyol ethers, polyglycerol ethers and esters, polyoxyethylenated fatty alcohol ethers, (C ₁ alkyl. ₄ ) polyglucosides, (C _{16. 30)} polyglucosides, the alkyl (Cι_ ₁₄₎ glucopyranosides, the (C _{16. 30)} glucopyranosides, the (C Cι_ ₁₄₎ thioglucopyra- nosides, the (C _{16. 30)} thioglucopyranosides, the (C ₁ _ ₁₄₎ maltosides, the (C _{16 30).} maltosides, the (C _1-14) -N- methyl glucamides, the (C _{16 30).} methylglucamides; polyoxyethylenated sorbitan esters; amino alcohol esters; optionally oxyethylenated sterols and phytosterols; ceramides; C ₁₆ fatty alcohol ethers and esters. ₃₀ ; and C _8-30 fatty alcohols. 11. Spinable material according to any one of the preceding claims, characterized in that it comprises the water-soluble surfactants in an amount of 5 to 75% by weight, preferably of 10 to 50% by weight, and the water-insoluble surfactants in an amount ranging from 5 to 90% by weight, preferably from 10 to 60% by weight, relative to the total weight of the spinnable material. 12. Spinable material according to any one of the preceding claims, characterized in that it further comprises additives. an amount of up to 75% by weight relative to the total weight of the spinnable material. 13. Spinable material according to claim 12, characterized in that the additives are chosen from mineral and organic fillers, pigments, nacres, dyes, silica powders, talc, starch, polyethylene, powders or rayon, nylon or polyamide fibers. 14. Spinable material according to any one of the preceding claims, characterized in that it comprises solvents in an amount of 0.5 to 90% by weight relative to the total weight of the spinnable material. 15. Spinable material according to claim 14, characterized in that the organic solvents are chosen from lower alcohols having from 1 to 6 carbon atoms, polyols, glycols, sugars, or mixtures thereof. 16. Spinable material according to any one of the preceding claims, characterized in that it further comprises one or more thickening agents. 17. Spinable material according to claim 16, characterized in that the thickening agents are present in an amount of 0.05 to 5% by weight relative to the total weight of the material. 18. Spinable cosmetic composition, characterized in that it comprises a spinnable material according to any one of the preceding claims. 19. Cosmetic composition according to claim 18, characterized in that it further comprises adjuvants chosen from hydrocarbon-based, fluorinated, silicone oils, volatile or not, perfumes, preservatives, sequestrants, sun filters, agents for stabilization of pH, preservatives and their mixtures. 20. Composition for making up the skin, scalp, hair, eyelashes or eyebrows, characterized in that it comprises the cosmetic composition according to any one of claims 18 and 19. 21. Make-up composition according to claim 20, characterized in that it is in the form of a mascara. 22. Cosmetic process for making up keratin materials, characterized in that the spinnable cosmetic composition according to any one of claims 18 and 19 is applied to the keratin materials and that the composition deposited is stretched using fingers or a suitable instrument.