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WO2003028635A2 - Compositions filmogenes a base de pullulane et d'alcool polyvinylique - Google Patents

Compositions filmogenes a base de pullulane et d'alcool polyvinylique Download PDF

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Publication number
WO2003028635A2
WO2003028635A2 PCT/US2002/030547 US0230547W WO03028635A2 WO 2003028635 A2 WO2003028635 A2 WO 2003028635A2 US 0230547 W US0230547 W US 0230547W WO 03028635 A2 WO03028635 A2 WO 03028635A2
Authority
WO
WIPO (PCT)
Prior art keywords
composition
pullulan
polyvinyl alcohol
group
skin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2002/030547
Other languages
English (en)
Other versions
WO2003028635A3 (fr
Inventor
Yelena Zolotarsky
David O'halloran
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lavipharm Laboratories Inc
Original Assignee
Lavipharm Laboratories Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lavipharm Laboratories Inc filed Critical Lavipharm Laboratories Inc
Priority to AU2002340016A priority Critical patent/AU2002340016A1/en
Publication of WO2003028635A2 publication Critical patent/WO2003028635A2/fr
Publication of WO2003028635A3 publication Critical patent/WO2003028635A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0212—Face masks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8129—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers or esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers, e.g. polyvinylmethylether
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/28—Rubbing or scrubbing compositions; Peeling or abrasive compositions; Containing exfoliants

Definitions

  • the present invention relates to compositions for forming peelable, cosmetic films on the skin of a subject. More particularly, the present invention relates to compositions for forming peelable, cosmetic films on the skin of a subject, containing 3 to 30wt% pullulan and 3 to 30wt% polyvinyl alcohol; wherein the combination of pullulan and polyvinyl alcohol constitute 6 to 33wt% of the composition.
  • the present invention also relates to a method for forming a peelable, cosmetic film on the skin of a subject including applying a composition of the present invention to the skin of the subject, wherein the composition contains 3 to 30wt% pullulan and 3 to 30wt% polyvinyl alcohol; wherein the combination of pullulan and polyvinyl alcohol constitute 6 to 33wt% of the composition.
  • Cosmetic films in are conventionally used to produce a variety of favorable results for the user. Two general categories of cosmetic films are: peel-off films and a rinse- away films. Both types of cosmetic films require that a coating be formed over the contours of the skin to which it is applied, typically on the face. The peel-off films are removed by physically peeling the dried film away from the skin and the rinse-away films are removed by thorough rinsing with water.
  • compositions for forming a peelable, cosmetic film on the skin of a subject containing: 3 to 30wt% pullulan and 3 to 30wt% polyvinyl alcohol, wherein the combination of pullulan and polyvinyl alcohol constitutes 6 to 33wt% of the composition.
  • the composition for forming a peelable, cosmetic film is provided as a semi-liquid gel or as a roll-on.
  • compositions for forming a peelable, cosmetic film on the skin of a subject contain pullulan having a molecular weight of
  • compositions for forming a peelable, cosmetic film on the skin of a subject contain polyvinyl alcohol having a single weight portion having an average molecular weight of 5,000 to 200,000 Daltons.
  • compositions for forming a peelable, cosmetic film on the skin of a subject contain polyvinyl alcohol having a plurality of different weight portions, with each weight portion having a different average molecular weight in the range of 5,000 to 200,000 Daltons.
  • compositions for forming a peelable, cosmetic film on the skin of a subject contain 20 to 94wt% solvent.
  • the solvent is selected from the group of water, alcohol, glycol and mixtures thereof.
  • compositions for forming a peelable, cosmetic film on the skin of a subject contain 0.01 to 10wt% active agent.
  • the active agent is selected from the group of alpha- and beta- hydroxy acids and derivatives thereof; vitamins and the salts, esters, alcohols and acid forms thereof; marine products and their derivatives; and topical over the counter active ingredients.
  • compositions for forming a peelable, cosmetic film on the skin of a subject contain 0.5 to 20wt% humectant.
  • the humectant is selected from the group of glycols, sorbitol, sodium polycarboxcylic acid, sodium citrate and mixtures thereof.
  • compositions for forming a peelable, cosmetic film on the skin of the subject contain 0.1 to 10wt% thickener.
  • the thickener is selected from the group of xanthan gum, cellulose, polyvinyl pyrolidone, carbomer and mixtures thereof.
  • the thickener may preferably be selected from the following group of mixtures, namely: a mixture of ammonium polyacrylate, isohexadecane and polyethylene glycol-40 castor oil; a mixture of polyacrylamide, polydecene, and ethoxylated lauryl alcohol; a mixture of polyacrylamide, C 13-14 isoparaffin, and ethoxylated lauryl alcohol; and, polyquarternium 32, and mineral oil.
  • the compositions for forming a peelable, cosmetic film on the skin of the subject contain 0.01 to 10wt% pigment.
  • the pigment is selected from the group of titanium dioxide, zinc oxide, iron oxide,
  • D&C Drug and Cosmetic
  • compositions for forming a peelable, cosmetic film on the skin of the subject contain 0.5 to 10wt% emulsifier.
  • the emulsifier is selected from the group of ethoxylated alcohols, sodium lauryl sulfate, and polyquaternium-31.
  • compositions for forming a peelable, cosmetic film on the skin of the subject contain 0.5 to 10wt% hydrocarbon.
  • the hydrocarbon is selected from the group of iso-paraffin, mineral oil, isododecane, almond oil and other natural oils.
  • compositions for forming a peelable, cosmetic film on the skin of the subject contain 0.1 to 5wt% fragrance.
  • the compositions for forming a peelable, cosmetic film on the skin of the subject contain 0.01 to lwt% chelating agent.
  • the chelating agent is selected from the group of ethylenediaminetetraacetic acid, ethylenediaminetetraacetic acid-disodium salt and ethylenediaminetetraacetic acid-tetrasodium salt.
  • compositions for forming a peelable, cosmetic film on the skin of the subject contain 0.1 to 4wt% UV absorber.
  • the UV absorber is selected from the group of benzophenone-3 and benzophenone-4.
  • compositions for forming a peelable, cosmetic film on the skin of the subject contain 0.05 to 3wt% antioxidant.
  • the antioxidant is selected from the group of tocopherol, tocopherol acetate, propyl gallate, butylated hydroxyanisole, and butylated hydroxytoluene.
  • compositions for forming a peelable, cosmetic film on the skin of the subject contain 0.2 to 3wt% preservative.
  • the preservative is selected from the group of methylparaben, propylparaben and phenoxyethanol.
  • compositions for forming a peelable, cosmetic film on the skin of a subject containing: 3 to 30wt% pullulan, 3 to 30wt% polyvinyl alcohol, 20 to 94wt% solvent, 0.01 to 10wt% active agent, 0.5-20wt% humectant, 0.1 to 10wt% thickener, 0.01 to 10wt% pigment, 0.5 to 10wt% emulsifier, 0.5 to 10wt% hydrocarbon, 0.1 to 5wt% fragrance, 0.01 to lwt% chelating agent, 0.1 to 4wt% UV absorber, 0.05 to 3wt% antioxidant and 0.2 to 3wt% preservative; wherein the combination of pullulan and polyvinyl alcohol constitute 6 to 33wt% of the composition.
  • the composition for forming a peelable, cosmetic film is provided as a semi-liquid gel or as a roll-on.
  • a method for forming a peelable, cosmetic film on the skin of a subject includes: applying to the skin of the subject a composition containing: 3 to 30wt% pullulan and 3 to 30wt% polyvinyl alcohol; wherein the combination of pullulan and polyvinyl alcohol constitute 6 to 33wt% of the composition.
  • the method for forming a peelable, cosmetic film on the skin of a subject includes: applying to the skin of the subject a composition containing: 3 to 30wt% pullulan, 3 to 30wt% polyvinyl alcohol, 20 to 94wt% solvent, 0.01 to 10wt% active agent, 0.5-20wt% humectant, 0.1 to 10wt% thickener, 0.01 to 10wt% pigment, 0.5 to 10wt% emulsifier, 0.5 to 10wt% hydrocarbon, 0.1 to 5wt% fragrance, 0.01 to lwt% chelating agent, 0.1 to 4wt% UV absorber, 0.05 to 3wt% antioxidant and 0.2 to 3wt% preservative; wherein the combination of pullulan and polyvinyl alcohol constitute 6 to 33wt% of the composition.
  • the present invention provides compositions for forming a comfortable, cosmetically elegant, peelable, film on the skin of a subject.
  • the unique combination of pullulan and polyvinyl alcohol contained in the compositions of the present invention dry to form cosmetically elegant, peelable, films when applied to the skin of a subject.
  • the compositions of the present invention when applied to the skin of a subject form into a visible and distinctive film on the skin as the volatile components of the compositions evaporate.
  • the resultant film is comfortable and can preferably be worn on the skin of the subject for a period of 20 minutes to several hours. After the composition dries into a film, it may be peeled off the skin of the subject. Alternatively, even though the resultant film is peelable, the user may decide to rinse-off the film with water.
  • compositions provided by the present invention for forming a peelable, cosmetic film on the skin of a subject preferably contain 3 to 30wt% pullulan, 3 to 30wt% polyvinyl alcohol and 20 to 94wt% solvent, with the combination of pullulan and polyvinyl alcohol constituting 6 to 33wt% of the composition. It has been found that formulations which contain less than around 6wt% of the combination of pullulan and polyvinyl alcohol fail to produce an acceptable peelable, cosmetic film. Also, it has been found that formulations which contain more than about 33wt% of the combination of pullulan and polyvinyl alcohol do not have sufficient available solvent to acceptably solubilize the combination of pullulan and polyvinyl alcohol contained therein.
  • compositions of the present invention for forming a peelable, cosmetic film on the skin of a subject may optionally contain active ingredients, humectants/plasticizers, thickeners, dyes/pigments, surfactants/emulsifiers, hydrocarbons or other oils, fragrances, chelating agents, UV absorbers, antioxidants, preservatives, and mixtures thereof.
  • Pullulan is a polysaccharide produced from a cultivated fungus of
  • Aureobasidium pullulans (pulluaria pullulans).
  • Pullulan is an alpha-glucan mainly constituted of maltrotriose as repeating units linearly joined through alpha- 1,6-glycosidic linkages, not branched.
  • Pullulan is also amorphous, edible and naturally degradable. It is readily soluble in cold or warm water and forms clear, viscous solutions therewith. Its industrial production has been developed in Japan by Hayashibara Biochemical Laboratories, Inc., from the fermentation of partially hydrolyzed starch.
  • Pullulan may also be produced using sucrose, sugar cane, milk, potato and other sources for the needed carbohydrates.
  • the pullulan used in the compositions of the invention will exhibit a molecular weight of 200,000 to 2,000,000 Daltons.
  • Polyvinyl alcohol suitable for use with the present invention may be composed of a single weight portion having an average molecular weight of 5,000 to 200,000 Daltons. Alternatively, the polyvinyl alcohol may be composed of a plurality of different weight portions, with each weight portion having a different average molecular weight in the range of 5,000 to 200,000 Daltons.
  • An example of polyvinly alcohol suitable for use with the invention is marketed by Air Products and Chemicals under the trademark PVA523S, which polyvinyl alcohol has an average molecular weight in the range of 85,000 to 146,000 Daltons.
  • Solvents suitable for use in the compositions of the present invention include, but are by no means limited to, water, alcohol, glycol and mixtures thereof. Preferably, the compositions of the present invention include water as the solvent.
  • Active ingredients suitable for use in the compositions of the present invention include, but are by no means limited to, oil- or water- soluble synthetic or natural active ingredients conventionally used in cosmetics.
  • the active ingredients may include alpha- and beta-hydroxy acids and their derivatives; botanical extracts, botanical oils and their derivatives; vitamins, for example, vitamin C, vitamin B, vitamin E, vitamin A, their salts, esters, alcohols and acid forms thereof; marine products and their derivatives; and topical over the counter active ingredients.
  • the compositions of the present invention may include an active mixture of bearberry extract, zinc sulfate, sodium salicylate and ethoxydiglycol effective for combating acne.
  • An active mixture of these constituents suitable for use in the compositions of the present invention is available from Gattefosse under the trademark Gatuline Equalizing.
  • the compositions of the present invention may contain 0.01 to 10wt% active ingredients.
  • Humectants/plasticizers suitable for use in the compositions of the present invention include, but are by no means limited to, any water-binding ingredients generally used in cosmetics.
  • the humectants/plasticizers may include glycols, for example glycerin, propylene glycol and 1,3-butylene glycol; sorbitol, sodium polycarboxcylic acid, and sodium citrate.
  • the humectant/plasticizer may include polypropylene glycol-10 methyl glucose ether.
  • a polypropylene glycol-10 methyl glucose ether suitable for use in the compositions of the present invention is available from Amercol under the trademark Glucam P-10.
  • compositions of the present invention may contain 0.5 to 20wt% humectants/plasticizers.
  • Humectants/plasticizers may be added to the compositions of the present invention to modify the properties and wear time of the resultant film produced on the skin of the subject when using the compositions.
  • Thickeners suitable for use in the compositions of the present invention include, but are by no means limited to, any polymer or thickener conventionally used in cosmetics.
  • the thickeners may include xanthan gum; cellulose; polyvinyl pyrolidone; carbomer; mixtures such as (1) ammonium polyacrylate, isohexadecane and polyethylene glycol-40 castor oil (an example of such a mixture suitable for use with the present invention is available from Seppic under the trademark Simulgel A); (2) polyacrylamide, polydecene and ethoxylated lauryl alcohol (an example of such a mixture suitable for use with the present invention is available from C.I.T.
  • compositions of the present invention may contain 0.1 to 10wt% thickeners.
  • Thickeners may be added to the compositions of the present invention to modify the viscosity of the composition, the feel of the composition and the film formed therewith when applied to the skin of a subject, the spreadability of the composition and the strength of the film formed by the composition upon application to the skin of a subject.
  • Dyes/pigments suitable for use in the compositions of the present invention include, but are by no means limited to, any inorganic dyes, organic dyes, pigments and opacifiers conventionally used in cosmetics.
  • the dyes/pigments may include titanium dioxide, zinc oxide, iron oxide, D&C and FD&C dyes.
  • the compositions of the present invention may contain an opacifier.
  • An opacifier suitable for use in the compositions of the present invention may preferably contain a mixture of styrene and polyvinyl pyrolidone copolymer (an example of such a mixture suitable for use with the present invention is available from ISP under the trademark Polectron 430).
  • the compositions of the present invention may contain 0.01 to 10wt% dyes/pigments.
  • Surfactants/emulsifiers suitable for use in the compositions of the present invention include, but are by no means limited to, any anionic, cationic and nonionic surfactants and emulsifiers conventionally used in cosmetics.
  • the surfactants/emulsifiers may include ethoxylated alcohols, sodium lauryl sulfate and polyquatemium-31.
  • the compositions of the present invention may contain 0.5 to 10wt% surfactants/emulsifiers.
  • Surfactants/emulsifiers may be added to the compositions of the present invention to stabilize the composition and/or to improve the spreadability of the composition onto the skin of the subject.
  • Hydrocarbons or other oils suitable for use in the compositions of the present invention include, but are by no means limited to, iso-paraffin, mineral oil, isododecane, almond oil and other natural oils.
  • the compositions of the present invention may contain 0.5 to 10wt% hydrocarbons or other oils.
  • Fragrances suitable for use in the compositions of the present invention include, but are by no means limited to, lime, peppermint and citrus.
  • the compositions of the present invention may contain 0.1 to 5wt% fragrances. Fragrances may be added to the compositions of the present invention to support a marketing concept and/or to mask any unpleasant odors associated with the composition or natural to the cite of application on the subject's skin.
  • Chelating agents suitable for use in the compositions of the present invention include any chelating agents conventionally used in cosmetics.
  • the chelating agents may include ethylenediaminetetraacetic acid, ethylenediaminetetraacetic acid- disodium salt and ethylenediaminetetraacetic acid-tetrasodium salt.
  • the compositions of the present invention may contain 0.01 to lwt% chelating agents. Chelating agents may be added to the compositions of the present invention to bind metal ions and to promote the overall stability of the compositions.
  • UV absorbers suitable for use in the compositions of the present invention include any water and/or oil soluble sunscreen conventionally used in cosmetics.
  • the UV absorbers may include benzophenone-3 and benzophenone-4.
  • the compositions of the present invention may contain 0.1 to 4wt% UV absorbers. UV absorbers may be added to the compositions of the present invention to protect the color of the composition from the deleterious effects of exposure to ultra-violet light.
  • Antioxidants suitable for use in the compositions of the present invention include any antioxidants conventionally used in cosmetics.
  • the antioxidants may include tocopherol, tocopherol acetate, propyl gallate, butylated hydroxyanisole and butylated hydroxytoluene.
  • the compositions of the present invention may contain 0.05 to 3wt% antioxidants. Antioxidants may be added to the compositions of the present invention to combat the deleterious effects of oxidation.
  • Preservatives suitable for use in the compositions of the present invention include any preservative or preservative system conventionally used in cosmetics.
  • preservatives suitable for use in the compositions of the present invention may include a mixture of phenoxyethanol, methylparaben, isopropylparaben, isobutyparaben and butylparaben (an example of such a mixture suitable for use with the present invention is available from ISP/Sutton under the trademark LiquaPar Optima).
  • the compositions of the present invention may contain 0.2 to 3wt% preservatives. Preservatives may be added to the compositions of the present invention to combat microbiological contamination.
  • compositions of the present invention for forming a peelable, cosmetic film on the skin of a subject preferably contain: 3 to 30wt% pullulan, 3 to 30wt% polyvinyl alcohol, 20 to 94wt% solvent, 0.01 to 10wt% active agent, 0.5-20wt% humectant, 0.1 to 10wt% thickener, 0.01 to 10wt% pigment, 0.5 to 10wt% emulsifier, 0.5 to 10wt% hydrocarbon, 0.1 to 5wt% fragrance, 0.01 to lwt% chelating agent, 0.1 to 4wt% UV absorber, 0.05 to 3wt% antioxidant and 0.2 to 3wt% preservative; wherein the combination of pullulan and polyvinyl alcohol constitute 6 to 33wt% of the composition.
  • the composition may be provided as a semi-liquid gel or as a roll-on.
  • the method of the present invention for forming a peelable, cosmetic film on the skin of a subject preferably includes: applying to the skin of the subject a composition containing: 3 to 30wt% pullulan and 3 to 30wt% polyvinyl alcohol; wherein the combination of pullulan and polyvinyl alcohol constitute 6 to 33wt% of the composition.
  • the method may include: applying to the skin of the subject a composition containing: 3 to 30wt% pullulan, 3 to 30wt% polyvinyl alcohol, 20 to 94wt% solvent, 0.01 to 10wt% active agent, 0.5-20wt% humectant, 0.1 to 10wt% thickener, 0.01 to 10wt% pigment, 0.5 to 10wt% emulsifier, 0.5 to 10wt% hydrocarbon, 0.1 to 5wt% fragrance, 0.01 to lwt% chelating agent, 0.1 to 3wt% UV absorber, 0.05 to 3wt% antioxidant and 0.2 to 3wt% preservative; wherein the combination of pullulan and polyvinyl alcohol constitute 6 to 33wt% of the composition.
  • the composition may dry to a peelable, film on the skin of the subject in 15 minutes or less following application to the skin, more preferably in 3 to 15 minutes.
  • a composition of the present invention for forming a peelable, cosmetic film on the skin of a subject with the formula presented in Table 1 was prepared.
  • composition identified in Table 1 was prepared as follows:
  • the product composition was a semi-liquid.
  • the product composition was found to form a comfortable and elegant, peelable, film when applied to the skin and allowed to dry.
  • a composition of the present invention for forming a peelable, cosmetic film on the skin of a subject containing an anti-acne active with the formula presented in Table 2 was prepared.
  • composition identified in Table 2 was prepared as follows:
  • the product composition was a semi-liquid.
  • the product composition was found to form a comfortable and elegant, peelable, film when applied to the skin and allowed to dry.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne des compositions destinées à former un film cosmétique pelable sur la peau d'un sujet. Ces compositions contiennent entre 3 et 30% en poids de pullulane et entre 3 et 30% en poids d'alcool polyvinylique, la combinaison de pullulane et d'alcool polyvinylique constituant entre 6 et 33% en poids de la composition. L'invention concerne également un procédé destiné à former un film cosmétique pelable sur la peau d'un sujet et consistant à appliquer une composition sur la peau du sujet, cette composition contenant entre 3 et 30% en poids de pullulane et entre 3 et 30% en poids d'alcool polyvinylique, la combinaison de pullulane et d'alcool polyvinylique constituant entre 6 et 33% en poids de ladite composition.
PCT/US2002/030547 2001-09-27 2002-09-26 Compositions filmogenes a base de pullulane et d'alcool polyvinylique Ceased WO2003028635A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2002340016A AU2002340016A1 (en) 2001-09-27 2002-09-26 Pullulan and polyvinyl alcohol based film forming compositions

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US32549001P 2001-09-27 2001-09-27
US60/325,490 2001-09-27

Publications (2)

Publication Number Publication Date
WO2003028635A2 true WO2003028635A2 (fr) 2003-04-10
WO2003028635A3 WO2003028635A3 (fr) 2003-07-03

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US (1) US20030086954A1 (fr)
AU (1) AU2002340016A1 (fr)
WO (1) WO2003028635A2 (fr)

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ITMI20091647A1 (it) * 2009-09-25 2011-03-26 Skinfit Technologies S R L Composizione cosmetica in forma di maschera e kit per la sua preparazione
EP2979685A1 (fr) * 2014-07-29 2016-02-03 Coty Germany Gmbh Complexe de formation de film, composition cosmétique le comprenant et son utilisation en tant que masque de film retirable
CN114957810A (zh) * 2022-05-05 2022-08-30 中国科学院天津工业生物技术研究所 一种普鲁兰多糖形状记忆材料的制备方法及其4d打印方法及制品

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FR2942407B1 (fr) * 2009-02-23 2011-08-05 Oreal Procede de photomaquillage et composition de photomaquillage
FR2942400B1 (fr) * 2009-02-23 2011-04-22 Oreal Procede de photomaquillage dans lequel un agent optique est utilise pour proteger le resultat obtenu
FR2942403A1 (fr) * 2009-02-23 2010-08-27 Oreal Procede de photomaquillage avec application d'une couche de base et ensemble pour la mise en oeuvre d'un tel procede
KR20130073893A (ko) 2010-04-13 2013-07-03 나지브 바불 1-메틸-2''-6''-피페콜옥실리디드의 피부 약제학적 조성물 및 사용 방법
US9579388B2 (en) 2012-11-29 2017-02-28 Rene Gauthier System and method for alleviating the appearance of scars and/or scar tissue
JP6419417B2 (ja) * 2013-05-24 2018-11-07 ロレアル 自立性美容シート
FR3128880A1 (fr) * 2021-11-10 2023-05-12 Strand Cosmetics Europe Film hydrosoluble pour application topique

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Publication number Priority date Publication date Assignee Title
ITMI20091647A1 (it) * 2009-09-25 2011-03-26 Skinfit Technologies S R L Composizione cosmetica in forma di maschera e kit per la sua preparazione
EP2979685A1 (fr) * 2014-07-29 2016-02-03 Coty Germany Gmbh Complexe de formation de film, composition cosmétique le comprenant et son utilisation en tant que masque de film retirable
WO2016016315A1 (fr) * 2014-07-29 2016-02-04 Coty Germany Gmbh Complexe filmogène, composition cosmétique le comprenant et leur utilisation comme masque de film pelable
CN114957810A (zh) * 2022-05-05 2022-08-30 中国科学院天津工业生物技术研究所 一种普鲁兰多糖形状记忆材料的制备方法及其4d打印方法及制品

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