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WO2002036529A1 - Procede de fabrication de dicyclopentadiene a partir de fractions c5 provenant de la pyrolyse du carbone - Google Patents

Procede de fabrication de dicyclopentadiene a partir de fractions c5 provenant de la pyrolyse du carbone Download PDF

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Publication number
WO2002036529A1
WO2002036529A1 PCT/KR2000/001338 KR0001338W WO0236529A1 WO 2002036529 A1 WO2002036529 A1 WO 2002036529A1 KR 0001338 W KR0001338 W KR 0001338W WO 0236529 A1 WO0236529 A1 WO 0236529A1
Authority
WO
WIPO (PCT)
Prior art keywords
dicyclopentadiene
pure
dcpd
mixture
dimerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2000/001338
Other languages
English (en)
Inventor
Elena-Valentinovna Nurullina
Natalia-Borisovna Solovieva
Yakov-Dmitrievich Samuilov
Alexander-Grigorievi Liakumovich
Valentina-Stepanovna Lekareva
Youn-Seok Park
Ki-Hwa Lee
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hanwha Impact Corp
Original Assignee
Samsung General Chemicals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Samsung General Chemicals Co Ltd filed Critical Samsung General Chemicals Co Ltd
Publication of WO2002036529A1 publication Critical patent/WO2002036529A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/02—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/08—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with a five-membered ring
    • C07C13/15—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with a five-membered ring with a cyclopentadiene ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/54—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings
    • C07C13/605—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings with a bridged ring system
    • C07C13/61—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings with a bridged ring system with a bridged indene ring, e.g. dicyclopentadiene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/50—Diels-Alder conversion
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/22—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by depolymerisation to the original monomer, e.g. dicyclopentadiene to cyclopentadiene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/56—Ring systems containing bridged rings
    • C07C2603/58—Ring systems containing bridged rings containing three rings
    • C07C2603/60—Ring systems containing bridged rings containing three rings containing at least one ring with less than six members
    • C07C2603/66—Ring systems containing bridged rings containing three rings containing at least one ring with less than six members containing five-membered rings
    • C07C2603/68—Dicyclopentadienes; Hydrogenated dicyclopentadienes

Definitions

  • the present invention relates to petrochemistry and more specifically to
  • DCPD dicyclopentadiene
  • DCPD modified ethylene-propylene copolymers
  • German Pat. No. 2,334,633 discloses the production method of a pure
  • DCPD by dimerization of C 5 -fraction containing cyclopentadiene (CPD).
  • the purified DCPD produced by this method can be used in some limited
  • the level of purity can be increased by further dimerization of a pure
  • Russia Pat. No. 2,059,595 discloses the production method of a pure
  • DCPD from a C 5 -fraction produced by hydrocarbon pyrolysis comprises the following steps. Firstly, a pure DCPD is
  • the purpose of the present invention are directed to increasing of the
  • high-boiling solvent preferably heptadecane and polymerization inhibitor
  • a produced CPD is dimerized at 40-150 °C, preferably 50-135 °C, more
  • the purity level of DCPD is
  • compositions is used as feedstock.
  • Pentene-2 (cis- and trans-) 2.8- 4.8
  • DCPD having more than 99.5 % purity was produced with a yield of 77 %.
  • Table 1 shows the results of examplel.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention concerne un procédé de fabrication de dicyclopentadiène très pur pouvant servir à la fabrication de résines et de dérivés norbornène à partir de fractions C5 provenant de la pyrolyse du carbone. Ledit procédé consiste à dimériser le cyclopentadiène contenu dans des fractions C5 par chauffage à une température de 50-110 °C avec un degré de conversion de 95 % de manière à former un mélange dimérisé ; à séparer ledit mélange dimérisé en un dicyclopentadiène pur par fractionnement ; à monomériser ledit dicyclopentadiène pur en présence d'un solvant à point d'ébullition élevé et d'un inhibiteur de polymérisation à une température de 180-210 °C de manière à former un mélange monomérisé ; à séparer ledit mélange monomérisé en un cyclopentadiène pur par fractionnement ; à dimériser ledit cyclopentadiène pur par chauffage à une température de 50-110 °C avec un degré de conversion de 90-99 % de manière à former un effluent enrichi en dicyclopentadiène ; et, à séparer ledit effluent enrichi en dicyclopentadiène en dicyclopentadiène très pur par fractionnement, le dicyclopentadiène très pur ayant une pureté d'au moins 99,5 %.
PCT/KR2000/001338 2000-10-30 2000-11-21 Procede de fabrication de dicyclopentadiene a partir de fractions c5 provenant de la pyrolyse du carbone Ceased WO2002036529A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2000127233 2000-10-30
RU2000127233/04A RU2186051C1 (ru) 2000-10-30 2000-10-30 Способ получения дициклопентадиена из c5-фракции пиролиза углеводородов

Publications (1)

Publication Number Publication Date
WO2002036529A1 true WO2002036529A1 (fr) 2002-05-10

Family

ID=20241555

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2000/001338 Ceased WO2002036529A1 (fr) 2000-10-30 2000-11-21 Procede de fabrication de dicyclopentadiene a partir de fractions c5 provenant de la pyrolyse du carbone

Country Status (3)

Country Link
KR (1) KR100494022B1 (fr)
RU (1) RU2186051C1 (fr)
WO (1) WO2002036529A1 (fr)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100494022B1 (ko) * 2000-10-30 2005-06-10 삼성토탈 주식회사 고순도 디시클로펜타디엔의 제조방법
CN102336628A (zh) * 2010-07-22 2012-02-01 中国石油天然气股份有限公司 一种连续解聚精馏制备环戊二烯的方法
CN102399123A (zh) * 2010-09-17 2012-04-04 中国石油化工股份有限公司 一种双环戊二烯及双甲基环戊二烯的制备方法
CN102399122A (zh) * 2010-09-17 2012-04-04 中国石油化工股份有限公司 制备环戊二烯及甲基环戊二烯的方法
JP2013091610A (ja) * 2011-10-25 2013-05-16 Mitsubishi Chemicals Corp ジシクロペンタジエンの分離回収方法
WO2017078904A1 (fr) * 2015-11-04 2017-05-11 Exxonmobil Chemical Patents Inc. Procédé et système de fabrication de cyclopentadiène et/ou de dicyclopentadiène
WO2017078900A1 (fr) * 2015-11-04 2017-05-11 Exxonmobil Chemical Patents Inc. Procédé et système de fabrication de cyclopentadiène et/ou de dicyclopentadiène
WO2017078902A1 (fr) * 2015-11-04 2017-05-11 Exxonmobil Chemical Patents Inc. Procédé et système de fabrication de cyclopentadiène et/ou de dicyclopentadiène
WO2017103736A1 (fr) 2015-12-14 2017-06-22 Sabic Global Technologies B.V. Procédés et systèmes de récupération de dicyclopentadiène à partir d'essence de pyrolyse
US9896396B2 (en) 2015-11-04 2018-02-20 Exxonmobil Chemical Patents Inc. Process and system for making cyclopentadiene and/or dicyclopentadiene
WO2019234524A1 (fr) * 2018-06-04 2019-12-12 Sabic Global Technologies B.V. Dimérisation de cyclopentadiène à l'aide d'un mélange de jets réactifs
CN117567227A (zh) * 2023-11-16 2024-02-20 广东新华粤石化集团股份公司 一种高纯度双环戊二烯及衍生物的制备方法

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2289563C2 (ru) * 2004-12-07 2006-12-20 ЗАО "Стерлитамакский нефтехимический завод" Способ получения дициклопентадиена из c5-углеводородной фракции
RU2289564C2 (ru) * 2004-12-07 2006-12-20 ЗАО "Стерлитамакский нефтехимический завод" Способ получения дициклопентадиена из c5-фракций пиролиза
IT1391108B1 (it) * 2008-08-19 2011-11-18 Fastech S R L Processo per la preparazione di etilidennorbornene.
KR101106938B1 (ko) * 2009-06-17 2012-01-20 정문규 건식좌훈기기
RU2463284C1 (ru) * 2011-05-04 2012-10-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Казанский национальный исследовательский технологический университет" Способ получения дициклопентадиена
AR101431A1 (es) * 2013-06-05 2016-12-21 Gtc Technology Us Llc Proceso y aparatos para separar di-olefinas c₅ de naftas de pirólisis
RU2538954C1 (ru) * 2013-12-25 2015-01-10 Общество с ограниченной ответственностью "Алексинский этилен полимерный комплекс" ООО "АЛЭП" Способ получения дициклопентадиена из с5-фракции пиролиза углеводородов
RU2540329C1 (ru) * 2014-01-29 2015-02-10 Открытое акционерное общество "Нефтяная компания "Роснефть" Способ получения циклопентадиена
RU2540322C1 (ru) * 2014-01-29 2015-02-10 Открытое акционерное общество "Нефтяная компания "Роснефть" Способ получения дициклопентадиена

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3676509A (en) * 1971-01-20 1972-07-11 Dow Chemical Co Recovery of dicyclopentadiene from cracked petroleum
US5321177A (en) * 1991-04-18 1994-06-14 Maruzen Petrochemical Co., Ltd. Process for the vapor-phase thermal cracking of dicyclopentadiene and a process for the manufacture of high purity dicyclopentadiene
US5401891A (en) * 1993-12-17 1995-03-28 Exxon Chemical Patents Inc. Production of polymerization grade dicyclopentadiene

Family Cites Families (6)

* Cited by examiner, † Cited by third party
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DD207096A3 (de) * 1981-09-22 1984-02-15 Grotewohl Boehlen Veb Verfahren zur gewinnung eines dicyclopentadienkonzentrates
JPH0739354B2 (ja) * 1985-07-08 1995-05-01 日本ゼオン株式会社 高純度ジシクロペンタジエンの製造方法
US5877366A (en) * 1990-08-20 1999-03-02 Boulder Scientific Company Dicyclopentadiene cracking process
RU2059595C1 (ru) * 1994-01-19 1996-05-10 Акционерное общество открытого типа "Всероссийский научно-исследовательский институт органического синтеза" Способ получения дициклопентадиена
JP3766985B2 (ja) * 1995-01-13 2006-04-19 Ｊｓｒ株式会社 高純度ジシクロペンタジエンの製造方法
RU2186051C1 (ru) * 2000-10-30 2002-07-27 Центр по разработке эластомеров Казанского государственного технологического университета Способ получения дициклопентадиена из c5-фракции пиролиза углеводородов

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3676509A (en) * 1971-01-20 1972-07-11 Dow Chemical Co Recovery of dicyclopentadiene from cracked petroleum
US5321177A (en) * 1991-04-18 1994-06-14 Maruzen Petrochemical Co., Ltd. Process for the vapor-phase thermal cracking of dicyclopentadiene and a process for the manufacture of high purity dicyclopentadiene
US5401891A (en) * 1993-12-17 1995-03-28 Exxon Chemical Patents Inc. Production of polymerization grade dicyclopentadiene

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100494022B1 (ko) * 2000-10-30 2005-06-10 삼성토탈 주식회사 고순도 디시클로펜타디엔의 제조방법
CN102336628A (zh) * 2010-07-22 2012-02-01 中国石油天然气股份有限公司 一种连续解聚精馏制备环戊二烯的方法
CN102399123A (zh) * 2010-09-17 2012-04-04 中国石油化工股份有限公司 一种双环戊二烯及双甲基环戊二烯的制备方法
CN102399122A (zh) * 2010-09-17 2012-04-04 中国石油化工股份有限公司 制备环戊二烯及甲基环戊二烯的方法
CN102399122B (zh) * 2010-09-17 2014-04-23 中国石油化工股份有限公司 制备环戊二烯及甲基环戊二烯的方法
JP2013091610A (ja) * 2011-10-25 2013-05-16 Mitsubishi Chemicals Corp ジシクロペンタジエンの分離回収方法
WO2017078902A1 (fr) * 2015-11-04 2017-05-11 Exxonmobil Chemical Patents Inc. Procédé et système de fabrication de cyclopentadiène et/ou de dicyclopentadiène
WO2017078900A1 (fr) * 2015-11-04 2017-05-11 Exxonmobil Chemical Patents Inc. Procédé et système de fabrication de cyclopentadiène et/ou de dicyclopentadiène
WO2017078904A1 (fr) * 2015-11-04 2017-05-11 Exxonmobil Chemical Patents Inc. Procédé et système de fabrication de cyclopentadiène et/ou de dicyclopentadiène
US9896396B2 (en) 2015-11-04 2018-02-20 Exxonmobil Chemical Patents Inc. Process and system for making cyclopentadiene and/or dicyclopentadiene
US9988324B2 (en) 2015-11-04 2018-06-05 Exxonmobil Chemical Patents Inc. Process and system for making cyclopentadiene and/or dicyclopentadiene
JP2018537523A (ja) * 2015-11-04 2018-12-20 エクソンモービル ケミカル パテンツ インコーポレイテッド シクロペンタジエンおよび／またはジシクロペンタジエンを作製する方法およびシステム
WO2017103736A1 (fr) 2015-12-14 2017-06-22 Sabic Global Technologies B.V. Procédés et systèmes de récupération de dicyclopentadiène à partir d'essence de pyrolyse
US20190225560A1 (en) * 2015-12-14 2019-07-25 Sabic Global Technologies B.V. Methods and systems for recovering dicyclopentadiene from pygas
US10611703B2 (en) 2015-12-14 2020-04-07 Sabic Global Technologies B.V. Methods and systems for recovering dicyclopentadiene from pygas
WO2019234524A1 (fr) * 2018-06-04 2019-12-12 Sabic Global Technologies B.V. Dimérisation de cyclopentadiène à l'aide d'un mélange de jets réactifs
CN112272659A (zh) * 2018-06-04 2021-01-26 沙特基础工业全球技术公司 使用反应性射流混合将环戊二烯二聚化
US11203556B2 (en) 2018-06-04 2021-12-21 Sabic Global Technologies B.V. Dimerization of cyclopentadiene using reactive jet mixing
CN117567227A (zh) * 2023-11-16 2024-02-20 广东新华粤石化集团股份公司 一种高纯度双环戊二烯及衍生物的制备方法

Also Published As

Publication number Publication date
KR20020034816A (ko) 2002-05-09
RU2186051C1 (ru) 2002-07-27
KR100494022B1 (ko) 2005-06-10

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