[go: up one dir, main page]

WO2000030597A1 - Dentifrices rayes - Google Patents

Dentifrices rayes Download PDF

Info

Publication number
WO2000030597A1
WO2000030597A1 PCT/EP1999/008753 EP9908753W WO0030597A1 WO 2000030597 A1 WO2000030597 A1 WO 2000030597A1 EP 9908753 W EP9908753 W EP 9908753W WO 0030597 A1 WO0030597 A1 WO 0030597A1
Authority
WO
WIPO (PCT)
Prior art keywords
components
pigments
red
toothpaste composition
composition according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP1999/008753
Other languages
German (de)
English (en)
Inventor
Hans-Theo Leinen
Miracle Pujol Galiano
Maria Rosa Carbo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to AU19658/00A priority Critical patent/AU1965800A/en
Publication of WO2000030597A1 publication Critical patent/WO2000030597A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216—Solid or semisolid forms
    • A61K8/0233—Distinct layers, e.g. core/shell sticks
    • A61K8/0237—Striped compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/347—Phenols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/67—Vitamins
    • A61K8/671—Vitamin A; Derivatives thereof, e.g. ester of vitamin A acid, ester of retinol, retinol, retinal
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes

Definitions

  • the invention relates to a toothpaste composition consisting of at least two separate, plastically flowing components which are filled in a container and can be squeezed out of this together in the form of parallel, concentric or striped strands, at least one of the components being colored, water-insoluble pigments, preferably of contains yellow to red color direction.
  • Striped toothpastes are known.
  • EP 0 331 617 AI describes a striped toothpaste, the strip component of which is a clear gel with organic pigments from the group ⁇ -carotene and chlorophyllin.
  • DE 38 41 775 AI a striped toothpaste was known, the strip component of which has a lower yield point than the carrier component.
  • EP 0 661 041 AI describes a striped toothpaste, the strip component of which has a significantly higher viscosity than the carrier component.
  • a toothpaste composition consisting of at least two separate, plastically flowing components which are filled in a container and can be pressed out of this in the form of parallel, concentric or striped strands, and the polishing agents in an aqueous carrier with a content contain humectants and surfactants, at least one of the components containing colored, water-insoluble iron oxide pigments or organic red pigments from the group Pigment Red 4, 5 and 181 or a mixture thereof in an amount sufficient for coloring.
  • Such toothpastes are particularly attractive to the user, especially since the known devices and containers for dispensing striped toothpastes are very versatile due to the corresponding design of the outlet opening of the containers and the number, size and shape of the openings through which the components emerge from the container enable aesthetic design of the product line.
  • the toothpaste composition according to the invention can be composed of two, three or even four separate, plastically flowing components, of which at least one, but optionally also two, three or all, contain colored pigments. If more than one of the components is pigmented in color, pigments of different color directions are preferably used in the pigmented components.
  • a colorless component can also be colored white with white pigments, for example with titanium dioxide or zinc oxide, and in this way create very appealing contrasts.
  • Another very attractive possibility is to formulate one of the components as a clear gel and to store strips of pigmented paste in this clear gel matrix.
  • the essence of the present invention lies in the selection of suitable pigments, in particular yellow and red pigments, which make it possible to achieve beautiful orange to vermilion colorations which do not pass into the adjacent component even in long storage times.
  • iron oxide pigments are primarily suitable for this.
  • Such pigments are available in a wide range of colors from various manufacturers. They belong to the dyes of Color Index No. 77491 and 77492 and are iron oxide powders with different oxidation levels and hydration.
  • the following commercial products have proven to be particularly suitable:
  • Pigment Red 101 (C.I. 77491):
  • Pigment Yellow 42 (C.I. 77492):
  • Pigment Red 4 (C.I. 12085):
  • Pigment Red 5 (C.I. 12490):
  • Pigment Red 181 (C.I. 73360):
  • the toothpaste according to the invention preferably consists of two components, one of which contains colored iron oxide pigments from the group Pigment Red 101 and Pigment Yellow 42 or organic red pigments from the group Pigment Red 4, 5 or 181 or a mixture thereof and the other colorless or is white pigmented.
  • the colored pigmented component represents the strip paste and the colorless or white pigmented paste serves as a matrix or carrier paste.
  • Orange stripes are particularly preferred, which are achieved by the pigmented component containing a combination of red pigments and a yellow pigment, which together create an orange color.
  • Such pigment combinations of pigment red 101 and pigment yellow 42 are also available as commercial products, for example
  • Tan C33-130 Tan C33-107 (Sun Chemical) Orange C33-120 (Sun Chemical) Orange C33-123 (Sun Chemical).
  • a sufficient intensity of the pigmentation is usually already achieved when the colored component contains the pigments in an amount of 0.001-0.1% by weight.
  • the components of the toothpaste composition according to the invention can have different compositions, e.g. the carrier component can be a clear, colorless or colored gel and the strip component can be a conventional opaque but colored pigmented toothpaste.
  • the strip component can also be produced by producing a clear gel and pigmenting it accordingly.
  • the components preferably have largely the same composition except for the pigments or any dyes additionally present.
  • the toothpaste composition according to the invention can in principle contain as polishing agent all of the abrasive components customary for toothpastes, but especially those which do not contain calcium ions.
  • Polishing agent components which are preferably suitable are therefore silicas, aluminum hydroxide, aluminum oxide, sodium aluminum silicates, organic polymers or mixtures of such friction bodies.
  • Calcium-containing polishing components such as chalk, calcium pyrophosphate, dicalcium phosphate dihydrate can, however, be present in amounts of up to 5% by weight.
  • the total content of polishing agents is preferably in the range of 5-50% by weight of the dentifrice.
  • Suitable silicas are e.g. Gel silicas, hydrogel silicas and precipitated silicas.
  • Gel silicas are produced by reacting sodium silicate solutions with strong, aqueous mineral acids to form a hydrosol, aging to the hydrogel, washing and drying. If drying is carried out under gentle conditions to a water content of 15 to 35% by weight, the so-called hydrogel silicas are obtained, such as those e.g. are known from US 4,153,680. Drying to water contents below 15% by weight results in an irreversible shrinkage of the previously loose structure of the hydrogel to form the dense structure of the so-called xerogel.
  • Such xerogel silicas are e.g. in US 3,538,230.
  • a second, preferably suitable group of silicic acid polishing agents are the precipitated silicas. These are obtained by precipitating silica from dilute alkali silicate solutions by adding strong acids under conditions in which the aggregation to the sol and gel cannot occur. Suitable processes for the preparation of precipitated silicas are described, for example, in DE-OS 25 22 486 and in DE-OS 31 14 493.
  • a precipitated silica prepared according to DE-OS 31 14 493 with a BET surface area of 15-110 m 2 / g and a particle size of 0.5-20 ⁇ m is particularly suitable, with at least 80% by weight of the primary particles being below 5 ⁇ m should, and a viscosity in 30% glycerol water (1: 1) dispersion of 30 - 60 Pa.s (20 ° C) in an amount of 10 - 20 wt .-% of the toothpaste.
  • Particularly suitable precipitated silicas of this type have rounded corners and edges and are under the tradename ® Sident 12 DS (DEGUSSA).
  • polishing agent component e.g. Alumina in the form of weakly calcined alumina containing ⁇ - and ⁇ -alumina in an amount of about 1 - 5 wt .-%.
  • Alumina in the form of weakly calcined alumina containing ⁇ - and ⁇ -alumina in an amount of about 1 - 5 wt .-%.
  • Such a suitable aluminum oxide is available under the trade name "Polishing clay P10 finest" (Giulini Chemie).
  • the toothpaste compositions according to the invention can e.g. Contain sodium fluoride, zinc fluoride, tin (II) fluoride, amine fluoride or sodium monofluorophosphate.
  • An amount of 100-1500 ppm fluorine should preferably be contained in the form of the compounds mentioned.
  • Glycerin, sorbitol, xylitol, propylene glycol, polyethylene glycol or mixtures of these substances can be used as humectants.
  • Natural and synthetic water-soluble polymers such as carrageenan, tragacanth, guar, cellulose and their non-ionic derivatives such as hydroxyethyl cellulose or methyl hydroxypropyl cellulose are used as binders and consistency regulators.
  • Agar-agar, xanthan gum, pectins, water-soluble carboxyvinyl polymers (eg Carbopol ® types), polyvinyl alcohol, polyvinylpyrrolidone and higher molecular weight polyethylene glycols (with molecular weights of 10 3 - 10 6 D) are also suitable as binders and thickeners.
  • Preferred toothpaste compositions according to the invention contain 10-30% by weight of silica polishing agent, 30-60% by weight of humectant and 0.1-2% by weight of a binder in both components.
  • the toothpaste compositions according to the invention can contain further auxiliaries and additives known per se.
  • Particularly preferred additional components are non-cationic, bactericidal components, panthenol or salts of pantothenic acid and vitamins, in particular vitamin A (retinol) or its derivatives.
  • Suitable non-cationic, bactericidal components are e.g. Phenols, resorcinols, bisphenols, salicylanilides and their halogenated derivatives, halogenated carbanilides and p-hydroxybenzoic acid esters.
  • Particularly preferred antimicrobial components are halogenated diphenyl ethers, e.g. 2,4-dichloro-2'-hydroxydiphenyl ether, 4,4'-dichloro-2'-hydroxydiphenyl ether, 2,4,4 '-tribromo-2'-hydroxydiphenyl ether and 2,4,4'-trichloro-2'-hydroxydiphenyl ether (Triclosan). They are preferably used in amounts of 0.01-1% by weight in the dentifrices according to the invention. Triclosan is particularly preferably used in an amount of 0.01-0.3% by weight.
  • D-panthenol [D - (+) - 2,4-dihydroxy-N- (3-hydroxypropyl) -3,3-dimethyl-butyramide] shows a biological activity corresponding to pantothenic acid.
  • Pantothenic acid (R - (+) - N - (2,4-dihydroxy-3,3-dimethylbutyryl-ß-alanine) is a precursor in the biosynthesis of coenzyme A and is included in the vitamin B complex (B 3 ) "These substances are known to promote wound healing and have a beneficial effect on the skin. Therefore, they have also been described occasionally in toothpastes.
  • the toothpaste compositions according to the invention preferably contain 0.05-5% by weight panthenol or a.” Salt of pantothenic acid.
  • Retinol (3,7-dimethyl-9- (2,6,6-trimethyl-l-cyclohexenyl) -2,4,6,8-nonatetraen-l-ol is the international free name for vitamin A, instead of retinol one of its derivatives with a similar biological effect, for example an ester or retinoic acid (tretinoin), one of its salts or its esters can also be used .
  • a retinol ester in particular a fatty acid ester of a fatty acid having 12-22 C atoms, is preferably used retinol palmitate is preferably suitable, when using a retinol ester, for example retinol palmitate with an activity of 1.7 10 6 IU per g Amount of 0.001 to 0.1 wt .-% preferred. When using other retinol derivatives, it is recommended to use an amount corresponding to a concentration of 10 3 to 10 6 IU (international units) per 100 g.
  • preferred toothpaste compositions according to the present invention preferably contain in at least one of the components:
  • panthenol or a salt of pantothenic acid 0.05 - 5 wt .-% panthenol or a salt of pantothenic acid
  • a retinol ester preferably retinol palmitate.
  • the toothpaste compositions according to the invention can contain further auxiliaries and additives known per se.
  • An additive that has long been known as a toothpaste component is particularly effective in the dentifrices according to the invention: calcium glycerophosphate, the calcium salt of glycerol-1-phosphoric acid or glycerol-2-phosphoric acid or of the enantiomers of glycerol-1-phosphoric acid Glycerin-3-phosphoric acid - or a mixture of these acids.
  • the compound has a remineralizing effect in dentifrices because it provides both calcium and phosphate ions.
  • Calcium glycerophosphate is preferably used in amounts of 0.01-1% by weight in the dentifrices according to the invention.
  • the tooth cleaning agents according to the invention can contain customary auxiliaries and additives in amounts of up to 10% by weight.
  • the toothpastes according to the invention can be improved in their organoleptic properties, for example, by adding aromatic oils and sweeteners.
  • All the natural and synthetic aromas customary for oral and dental care products can be used as aroma oils.
  • Natural aromas can be contained both in the form of the natural essential oils isolated from drugs and in the individual components isolated therefrom. Suitable flavors are, for example, peppermint oil, spearmint oil, eucalyptus oil, anise oil, fennel oil, caraway oil, menthyl acetate, cinnamaldehyde, anethole, vanillin, thymol and mixtures of these components.
  • Suitable sweeteners are e.g. Saccharin sodium, sodium cyclamate, sucrose, lactose, maltose, fructose.
  • Surface-active substances preferably anionic, zwitterionic, amphoteric, nonionic surfactants or a combination of several different surfactants, solvents and solubilizers, e.g. lower monohydric or polyhydric alcohols or ethers, e.g. Ethanol, 1, 2-propylene glycol, diethylene glycol or butyl glycol glycol dyes
  • - buffer substances e.g. primary, secondary or tertiary alkali phosphates or citric acid / Na citrate
  • wound healing or anti-inflammatory substances e.g. Allantoin, urea, azulene, chamomile active ingredients, acetylsalicylic acid derivatives or rhodanide
  • Two basic toothpastes were produced according to recipes A and B and each 30% by weight of this was colored with pigment dyes (according to recipe AP and BP).
  • Sipernat 320 DS precipitated silica
  • Cekol 500 T carboxy methyl cellulose, sodium salt
  • Soft-Tex Yellow iron oxide, average particle size 0.02 - 0.25 ⁇ m (Sun Chemical) Cosmenyl Rot R: 40% preparation (H 2 O / glycerin) of Pigment Red 4 (CI 12085)
  • Components A and AP or B and BP were filled in a strip dispenser tube according to DE-A 21 41 436. After 4 weeks of storage, the toothpastes could be removed as striped paste strands and a sharp phase boundary (without bleeding).

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne une composition de dentrifices contenant au moins deux composantes séparées et plastiquement fluides qui peuvent être expulsées d'un contenant ensemble sous forme de barres parallèles, concentriques ou rayées et qui contiennent un agent de polissage dans un support aqueux ayant une certaine teneur en conservateurs d'humidité, en tensioactifs et, dans au moins une des composantes, en pigments colorants. Ces composantes sont particulièrement stables en termes de débordement de couleur au niveau de la phase limite si elles contiennent comme pigments, des pigments d'oxyde de fer insolubles dans l'eau choisis dans le groupe pigment rouge 101 et pigment jaune 42 ou des pigments rouges organiques choisis dans le groupe pigment rouge 4,5 ou 181 ou un de leurs mélanges dans une quantité suffisante en termes de coloration. De préférence, une des composantes est incolore ou pigmenté en blanc.
PCT/EP1999/008753 1998-11-24 1999-11-13 Dentifrices rayes Ceased WO2000030597A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU19658/00A AU1965800A (en) 1998-11-24 1999-11-13 Striped toothpastes

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19854086.8 1998-11-24
DE1998154086 DE19854086A1 (de) 1998-11-24 1998-11-24 Gestreifte Zahnpasten

Publications (1)

Publication Number Publication Date
WO2000030597A1 true WO2000030597A1 (fr) 2000-06-02

Family

ID=7888777

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1999/008753 Ceased WO2000030597A1 (fr) 1998-11-24 1999-11-13 Dentifrices rayes

Country Status (3)

Country Link
AU (1) AU1965800A (fr)
DE (1) DE19854086A1 (fr)
WO (1) WO2000030597A1 (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10340348A1 (de) * 2003-09-02 2005-03-24 Beiersdorf Ag Mehrfarbige Kosmetika
US10966916B2 (en) 2014-11-10 2021-04-06 The Procter And Gamble Company Personal care compositions
US10987290B2 (en) 2017-10-20 2021-04-27 The Procter And Gamble Company Aerosol foam skin cleanser
US11207261B2 (en) 2014-11-10 2021-12-28 The Procter And Gamble Company Personal care compositions with two benefit phases
US11207248B2 (en) 2014-11-10 2021-12-28 The Procter And Gamble Company Personal care compositions with two benefit phases
US11365397B2 (en) 2018-11-29 2022-06-21 The Procter & Gamble Company Methods for screening personal care products
US11419805B2 (en) 2017-10-20 2022-08-23 The Procter & Gamble Company Aerosol foam skin cleanser

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR0314573A (pt) 2002-09-20 2005-08-09 Procter & Gamble Composições lìquidas listradas para higiene pessoal contendo uma fase de limpeza e uma fase de benefìcio separada
WO2004050055A1 (fr) 2002-11-04 2004-06-17 The Procter & Gamble Company Compositions pour hygiene personnelle liquides striees contenant une phase de nettoyage et une phase active distincte a stabilite accrue
US20040101492A1 (en) * 2002-11-26 2004-05-27 The Procter & Gamble Company Multicolored striped dentifrice composition
EP1617809B1 (fr) 2003-05-01 2015-07-08 The Procter & Gamble Company Compositions pour hygiene personnelle liquides en couches comprenant une phase nettoyante et une phase active distincte contenant une emulsion a phase interne elevee
CN1784201B (zh) * 2003-05-08 2010-05-26 宝洁公司 包含疏水改性的干涉颜料的个人护理组合物
US20040223991A1 (en) * 2003-05-08 2004-11-11 The Procter & Gamble Company Multi-phase personal care composition
US8951947B2 (en) 2003-12-24 2015-02-10 The Procter & Gamble Company Multi-phase personal cleansing compositions comprising a lathering cleansing phase and a non-lathering structured aqueous phase
EP1796616A1 (fr) * 2004-09-03 2007-06-20 Beiersdorf AG Produits cosmetiques multicolores
US7666825B2 (en) 2004-10-08 2010-02-23 The Procter & Gamble Company Stable, patterned multi-phased personal care composition
CN101111217A (zh) * 2005-02-04 2008-01-23 荷兰联合利华有限公司 牙膏组合物
ATE462404T1 (de) * 2005-02-04 2010-04-15 Unilever Nv Mehrphasige zahnpastenzusammensetzung
US7527077B2 (en) 2005-02-25 2009-05-05 The Procter & Gamble Company Multi-phase personal care compositions, processes for making and providing, and articles of commerce
EP1952801B1 (fr) * 2005-11-25 2018-07-25 "WDS" Company Composition de soins et de prevention pour la cavite buccale
US8104616B2 (en) 2006-02-11 2012-01-31 The Procter & Gamble Company Clamshell package for holding and displaying consumer products
US8153144B2 (en) 2006-02-28 2012-04-10 The Proctor & Gamble Company Stable multiphase composition comprising alkylamphoacetate

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1308483A (en) * 1969-11-07 1973-02-21 Blendax Werke Schneider Co Preparations for the care of the teeth and the mouth
DE2254109A1 (de) * 1971-11-17 1973-05-24 Colgate Palmolive Co Koerniges material, insbesondere zur verwendung in zahnreinigungsmitteln, sowie verfahren zu dessen herstellung
US4007259A (en) * 1973-11-02 1977-02-08 Colgate-Palmolive Company Dental cream
JPS6016912A (ja) * 1983-07-06 1985-01-28 Lion Corp 口腔用組成物
EP0269966A1 (fr) * 1986-11-25 1988-06-08 Kao Corporation Composition granulaire et dentifrice contenant cette composition
EP0353675A2 (fr) * 1988-08-02 1990-02-07 Albert M. Kligman Traitement de la périodontoclasie avec l'acide rétinoique
US5756073A (en) * 1996-11-12 1998-05-26 Colgate Palmolive Company Striped dentifrice stable to color bleeding

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1308483A (en) * 1969-11-07 1973-02-21 Blendax Werke Schneider Co Preparations for the care of the teeth and the mouth
DE2254109A1 (de) * 1971-11-17 1973-05-24 Colgate Palmolive Co Koerniges material, insbesondere zur verwendung in zahnreinigungsmitteln, sowie verfahren zu dessen herstellung
US4007259A (en) * 1973-11-02 1977-02-08 Colgate-Palmolive Company Dental cream
JPS6016912A (ja) * 1983-07-06 1985-01-28 Lion Corp 口腔用組成物
EP0269966A1 (fr) * 1986-11-25 1988-06-08 Kao Corporation Composition granulaire et dentifrice contenant cette composition
EP0353675A2 (fr) * 1988-08-02 1990-02-07 Albert M. Kligman Traitement de la périodontoclasie avec l'acide rétinoique
US5756073A (en) * 1996-11-12 1998-05-26 Colgate Palmolive Company Striped dentifrice stable to color bleeding

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, vol. 102, no. 20, 20 May 1985, Columbus, Ohio, US; abstract no. 172448, LION CORP., JAPAN: "Toothpastes color indicators for timing adequate brushing" XP002133848 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10340348A1 (de) * 2003-09-02 2005-03-24 Beiersdorf Ag Mehrfarbige Kosmetika
US10966916B2 (en) 2014-11-10 2021-04-06 The Procter And Gamble Company Personal care compositions
US11207261B2 (en) 2014-11-10 2021-12-28 The Procter And Gamble Company Personal care compositions with two benefit phases
US11207248B2 (en) 2014-11-10 2021-12-28 The Procter And Gamble Company Personal care compositions with two benefit phases
US10987290B2 (en) 2017-10-20 2021-04-27 The Procter And Gamble Company Aerosol foam skin cleanser
US11419805B2 (en) 2017-10-20 2022-08-23 The Procter & Gamble Company Aerosol foam skin cleanser
US11365397B2 (en) 2018-11-29 2022-06-21 The Procter & Gamble Company Methods for screening personal care products

Also Published As

Publication number Publication date
DE19854086A1 (de) 2000-05-25
AU1965800A (en) 2000-06-13

Similar Documents

Publication Publication Date Title
WO2000030597A1 (fr) Dentifrices rayes
EP1098629B1 (fr) Produits de soins dentaires a effet anti-inflammatoire
DE19845247A1 (de) Flüssiges Zahnreinigungsgel
DE2918134A1 (de) Zahnpflegemittel
EP0447434A1 (fr) Pate dentifrice
EP1272151B1 (fr) Dentifrice liquide anti-plaque
DE19730651A1 (de) Mund- und Zahnpflegemittel für empfindliche Zähne
EP3968940A1 (fr) Dentifrices contenant des biosurfactants
EP1322282B1 (fr) Produits de nettoyage pour les dents
DE60013111T2 (de) Mundpflegezusammensetzung
DE2131942C2 (de) Zahnreinigungsgel mit gesprenkelter Färbung
EP2158894B1 (fr) Produit dentaire
DE102008033105A1 (de) Optisch differenzierte Mund- und Zahnpflege- und -reinigungsmittel
EP1802374A1 (fr) Produits de nettoyage et d'hygiene bucco-dentaire reduisant la mauvaise haleine et assurant le detartrage des dents
EP2813214B1 (fr) Crème dentaire liquide aux fluorure(s) d'amines
EP2727627A2 (fr) Produit de nettoyage et d'entretien de la bouche et des dents contenant de la vitamine E
EP2732850B1 (fr) Crème dentaire finement moussante dotée d'une sensation en bouche améliorée
EP2859879B1 (fr) Produit de nettoyage et de soin de la bouche et des dents contre l'halitose
DE102008062238A1 (de) Remineralisierende Mund- und Zahnpflege- und -reinigungsmittel mit spezieller Wirkstoffkombination
DE10064986A1 (de) Halbflüssige Zahncreme
EP2361603A2 (fr) Produit de nettoyage et d'entretien de la bouche et des dents désensibilisant doté d'éthyllaurolarguinat
DE102006060911A1 (de) Mund- und Zahnpflege- und -reinigungsmittel zur Bekämpfung von Halitosis
DE102006060946A1 (de) Mund- und Zahnpflege- und -reinigungsmittel mit verbesserter Fluoriddeposition
DE102005049980A1 (de) Mund- und Zahnpflege- und -reinigungsmittel mit neuen Wirksubstanzen

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AU BR CA CN CZ HU JP KR MX NO PL SK US

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
122 Ep: pct application non-entry in european phase