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WO1996036739A1 - Associations de substances actives - Google Patents

Associations de substances actives Download PDF

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Publication number
WO1996036739A1
WO1996036739A1 PCT/EP1996/001845 EP9601845W WO9636739A1 WO 1996036739 A1 WO1996036739 A1 WO 1996036739A1 EP 9601845 W EP9601845 W EP 9601845W WO 9636739 A1 WO9636739 A1 WO 9636739A1
Authority
WO
WIPO (PCT)
Prior art keywords
leather
chlorophenol
use according
mixture
phenylphenol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP1996/001845
Other languages
German (de)
English (en)
Inventor
Heinz-Joachim Rother
Martin Kugler
Hartmut Rehbein
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Priority to EP96915014A priority Critical patent/EP0827553B1/fr
Priority to AU56935/96A priority patent/AU704282B2/en
Priority to US08/952,413 priority patent/US5888415A/en
Priority to DE59609922T priority patent/DE59609922D1/de
Priority to AT96915014T priority patent/ATE228575T1/de
Priority to BR9609081A priority patent/BR9609081A/pt
Publication of WO1996036739A1 publication Critical patent/WO1996036739A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C14—SKINS; HIDES; PELTS; LEATHER
    • C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C9/00—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system

Definitions

  • the present application relates to the use of active ingredient combinations of phenolic active ingredients with azole compounds for the preservation of animal hides and leather.
  • the application therefore relates to the use of a combination of at least one triazole and / or at least one benzimidazole and / or at least one imidazole and / or at least one morpholine derivative with at least one phenolic compound for protecting animal hides and leather during manufacture and storage.
  • phenolic active substances there are preferably phenol derivatives such as tribromophenol, trichlorophenol, tetrachlorophenol, nitrophenol, 3-methyl-4-chlorophenol, 3,5-dimethyl-4-chlorophenol, phenoxyethanol, dichlorophen, o-phenylphenol, m-phenylphenol, p-phenylphenol , 2-benzyl-4-chlorophenol, 2,4-dichloro-3,5-dimethylphenol, 4-chlorothymol, chlorophen, triclosan, fentichlor and their ammonium,
  • phenol derivatives such as tribromophenol, trichlorophenol, tetrachlorophenol, nitrophenol, 3-methyl-4-chlorophenol, 3,5-dimethyl-4-chlorophenol, phenoxyethanol, dichlorophen, o-phenylphenol, m-phenylphenol, p-phenylphenol , 2-benzyl-4-chlorophenol, 2,
  • Alkali and alkaline earth salts and their mixtures in question are Alkali and alkaline earth salts and their mixtures in question.
  • Triazoles such as amitroles, azo-cyclotin, azaconazole, BAS 480F, bitertanols, cyproconazole, difenoconazole, fenbuconazole, fenchlorazole, fenethanil, fluquinconazole, flusilazole, flutriafole, hexaconazole, imozofanazole, myozonazole, imibenconazole, imibenconazole, imibenconazole, imibenconazole, myobenzolone, imibenconazole, myobenzole , Penconazole, propiconazole, cis-l- (4-chlorophenyl) -2- (1H- 1, 2,4-triazol-1 -yl) -cy cloheptanol, tebuconazole, 2- (1-tert.-butyl) - 1 - (2- chlorpheny
  • Preferred imidazoles are compounds such as imazalil, pefurazoate, prochloraz, triflumizole, bifonazole, canesten, fluotimazole, miconazole,
  • Preferred benzimidazoles are compounds such as methyl benzimidazolylcarbamate (BCM), benomyl, fuberidazole, thiabendazole.
  • Compounds such as tridemorph, aldimorph, fenpropimorph, amorolfine and dodemorph are preferably suitable as morpholine derivatives.
  • Combinations of 3,5-dimethyl-4-chlorophenol, 2-benzyl-4-chlorophenol, p-chloro-m-cresol (CMK) and / or o-phenylphenol (OPP) are preferred as phenolic components and azoles such as tebuconazole , Propiconazole, Azaconazole, Cyproconazole, Hexaconazole, Epoxyconazole and / or Imazalil as further
  • Combinations of CMK and / or OPP with tebuconazole and / or propiconazole are particularly preferred.
  • Preferred combinations are further combinations of OPP and / or CMK with BCM.
  • CMK CMK
  • OPP tebuconazole
  • the mixing ratios of the phenolic constituent to the further active substances are generally 5 to 200, preferably 10 to 100, in particular 12 to 50, parts by weight to 1 part by weight.
  • the ratio of the phenolic compounds to one another can be varied widely and is preferably 1: 1 to 1: 5 in the case of a mixture of OPP and CMK.
  • the above-mentioned mixtures of the active ingredients are generally used in the form of formulations.
  • the application concentration is preferably 0.1 to 1% active ingredient mixture, based on the hides or leather to be protected.
  • the agents formed in the formulation preferably contain 10 to 50% of the active ingredient mixture.
  • the agents contain 10 to 30% of alkali and / or alkaline earth metal hydroxides as further constituents; 1 to 20% ionic and / or non-ionic emulsifiers; 5 to 30% organic solvents such as in particular glycols, ketones, glycol ethers, alcohols such as ethanol, methanol, 1,2-propanediol, n-propanol, 2-propanol and 0-0.5% aroma and fragrance.
  • the rest is 100% water.
  • the active substance mixtures and the compositions which can be produced therefrom are used according to the invention in leather production for protecting animal hides against attack and damage by microorganisms. It is of particular interest that representatives of the species Aspergillus niger, Aspergillus repens, Hormoconis resinae, Penicillium glaucum and Trichoderma viride, Penicillium species such as P. citrinum or P. glaucum, Paecilomjces variotii, Cladosporium species such as Mucor species such as Mucor mucedo , Rhizopus species such as Rhizopus orizae, Rhizopus rouxii are completely and permanently suppressed.
  • Agar plates are contaminated with conidia of the species Aspergillus niger, Aspergillus repens, Penicillium glaucum, Trichoderma viride and Hormoconis resinae. Subsequently, moist chrome leather (wet blue) treated with mixture I and mixture II is applied and incubated for 28 days at 95% relative atmospheric humidity and 20 to 30 ° C.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne l'utilisation d'associations de substances actives comprenant des substances actives phénoliques avec des composés azoles pour la conservation de cuirs et peaux d'animaux.
PCT/EP1996/001845 1995-05-16 1996-05-03 Associations de substances actives Ceased WO1996036739A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP96915014A EP0827553B1 (fr) 1995-05-16 1996-05-03 Associations de substances actives
AU56935/96A AU704282B2 (en) 1995-05-16 1996-05-03 Active compound combinations
US08/952,413 US5888415A (en) 1995-05-16 1996-05-03 Method of using a mixture of a phenolic compound and an azole or morpholine compound to protect animal hides and leather against microbes
DE59609922T DE59609922D1 (de) 1995-05-16 1996-05-03 Wirkstoffkombinationen
AT96915014T ATE228575T1 (de) 1995-05-16 1996-05-03 Wirkstoffkombinationen
BR9609081A BR9609081A (pt) 1995-05-16 1996-05-03 Combinações de substáncias ativas

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19517840.8 1995-05-16
DE19517840A DE19517840A1 (de) 1995-05-16 1995-05-16 Wirkstoffkombinationen

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US09/213,584 Division US6083414A (en) 1995-05-16 1998-12-17 Composition of a mixture of a phenolic compound and an azole or morpholine compound to protect animal hides and leather against microbes

Publications (1)

Publication Number Publication Date
WO1996036739A1 true WO1996036739A1 (fr) 1996-11-21

Family

ID=7761982

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1996/001845 Ceased WO1996036739A1 (fr) 1995-05-16 1996-05-03 Associations de substances actives

Country Status (12)

Country Link
US (3) US5888415A (fr)
EP (1) EP0827553B1 (fr)
AR (1) AR001834A1 (fr)
AT (1) ATE228575T1 (fr)
AU (1) AU704282B2 (fr)
BR (1) BR9609081A (fr)
CA (1) CA2220992A1 (fr)
DE (2) DE19517840A1 (fr)
ES (1) ES2183949T3 (fr)
TR (1) TR199701369T1 (fr)
WO (1) WO1996036739A1 (fr)
ZA (1) ZA963849B (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006056266A1 (fr) * 2004-11-22 2006-06-01 Henkel Kommanditgesellschaft Auf Aktien Materiaux de construction resistants a la moisissure
WO2010018156A1 (fr) * 2008-08-12 2010-02-18 Lanxess Deutschland Gmbh Préparations liquides de substances actives phénoliques
EP2570502A1 (fr) 2011-09-13 2013-03-20 LANXESS Deutschland GmbH Préparations de matière active liquide pour la protection fongicide de substrats contenant des fibres collagènes
EP2777396A1 (fr) 2013-03-12 2014-09-17 LANXESS Deutschland GmbH Préparations de matière active pour la protection fongicide de substrats contenant des fibres collagènes

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19517840A1 (de) * 1995-05-16 1996-11-21 Bayer Ag Wirkstoffkombinationen
DE10046265A1 (de) * 2000-09-19 2002-03-28 Bayer Ag Wirkstoffkombination zum Schutz von tierischen Häuten
US20060014810A1 (en) * 2002-07-26 2006-01-19 Microban Products Company Durable antimicrobial leather
GB0330023D0 (en) * 2003-12-24 2004-01-28 Basf Ag Microbicidal compositions
US20060112494A1 (en) * 2004-12-01 2006-06-01 David Oppong Method of protecting an animal skin product from metalloproteinase activity
CN102438457B (zh) * 2009-04-06 2015-01-28 陶氏环球技术有限责任公司 低温稳定的杀生物组合物

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2904392A (en) * 1956-04-19 1959-09-15 Pomerantz Reuben Method of packaging and treating articles
EP0341954A1 (fr) * 1988-05-10 1989-11-15 Kureha Kagaku Kogyo Kabushiki Kaisha Compositions biocides pour matériaux industriels
EP0366071A2 (fr) * 1988-10-28 1990-05-02 Daikin Industries, Limited Composition bactéricide et fongicide
EP0409500A1 (fr) * 1989-07-14 1991-01-23 Buckman Laboratories International, Inc. Compositions contenant 2-(thiocyanométhylthio) benzothiazole et un phénol trihalogéné
JPH0741800A (ja) * 1993-07-26 1995-02-10 Yoshinobu Fujimoto 健康衛生用皮革

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5223524A (en) * 1989-04-19 1993-06-29 Janssen Pharmaceutica N.V. Synergistic compositions containing propiconazole and tebuconazole
DE4202051A1 (de) * 1992-01-25 1993-07-29 Bayer Ag Fliessfaehige mikrobizide mittel
JPH0640821A (ja) * 1992-07-24 1994-02-15 Toshiba Silicone Co Ltd 防カビ性ポリオルガノシロキサン組成物
DE19513990A1 (de) * 1995-04-13 1996-10-17 Bayer Ag Benzimidazol-Derivate
DE19517840A1 (de) * 1995-05-16 1996-11-21 Bayer Ag Wirkstoffkombinationen

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2904392A (en) * 1956-04-19 1959-09-15 Pomerantz Reuben Method of packaging and treating articles
EP0341954A1 (fr) * 1988-05-10 1989-11-15 Kureha Kagaku Kogyo Kabushiki Kaisha Compositions biocides pour matériaux industriels
EP0366071A2 (fr) * 1988-10-28 1990-05-02 Daikin Industries, Limited Composition bactéricide et fongicide
EP0409500A1 (fr) * 1989-07-14 1991-01-23 Buckman Laboratories International, Inc. Compositions contenant 2-(thiocyanométhylthio) benzothiazole et un phénol trihalogéné
JPH0741800A (ja) * 1993-07-26 1995-02-10 Yoshinobu Fujimoto 健康衛生用皮革

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 9516, Derwent World Patents Index; AN 95118959, XP002012461 *

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006056266A1 (fr) * 2004-11-22 2006-06-01 Henkel Kommanditgesellschaft Auf Aktien Materiaux de construction resistants a la moisissure
RU2418412C2 (ru) * 2004-11-22 2011-05-20 Хенкель Аг Унд Ко. Кгаа Устойчивые к плесени строительные материалы
RU2418412C9 (ru) * 2004-11-22 2012-07-10 Хенкель Аг Унд Ко. Кгаа Устойчивые к плесени строительные материалы
US8821908B2 (en) 2004-11-22 2014-09-02 Henkel Ag & Co. Kgaa Mold-resistant construction materials
WO2010018156A1 (fr) * 2008-08-12 2010-02-18 Lanxess Deutschland Gmbh Préparations liquides de substances actives phénoliques
DE102008038709A1 (de) 2008-08-12 2010-02-18 Lanxess Deutschland Gmbh Flüssige Präparationen phenolischer Wirkstoffe
EP2570502A1 (fr) 2011-09-13 2013-03-20 LANXESS Deutschland GmbH Préparations de matière active liquide pour la protection fongicide de substrats contenant des fibres collagènes
WO2013037872A1 (fr) 2011-09-13 2013-03-21 Lanxess Deutschland Gmbh Préparations d'agents actifs liquides pour la protection fongicide contre des substrats contenant des fibres de collagène
EP2777396A1 (fr) 2013-03-12 2014-09-17 LANXESS Deutschland GmbH Préparations de matière active pour la protection fongicide de substrats contenant des fibres collagènes

Also Published As

Publication number Publication date
BR9609081A (pt) 1999-02-02
ATE228575T1 (de) 2002-12-15
ES2183949T3 (es) 2003-04-01
AU5693596A (en) 1996-11-29
CA2220992A1 (fr) 1996-11-21
US5888415A (en) 1999-03-30
AU704282B2 (en) 1999-04-15
DE59609922D1 (de) 2003-01-09
EP0827553B1 (fr) 2002-11-27
EP0827553A1 (fr) 1998-03-11
US6375861B1 (en) 2002-04-23
TR199701369T1 (xx) 1998-02-21
US6083414A (en) 2000-07-04
ZA963849B (en) 1996-11-21
AR001834A1 (es) 1997-12-10
DE19517840A1 (de) 1996-11-21

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