WO1996036472A1 - Method of reprocessing rubber waste materials - Google Patents

Abstract

The proposed method involves the thermal breakdown of rubber waste materials in a working medium, separation of the solid and gaseous breakdown products, and removal of oil from the gaseous breakdown products. The proposed method is characterised in that the working medium used is a steam and gas mixture consisting of steam and gas obtained following the recovery of the oil from the gaseous breakdown products, the mixture being superheated to between 300 and 1600 °C. The proportion by weight of steam in the mixture is 98-85 %, that of gas 2-15 %. Oil in quantities equivalent to 3-40 wt.% of the waste materials can be added to the rubber waste materials before the thermal breakdown process.

Description

 SPΟSΟB ПΕΡΕΡΑБΟΤΚИ ΡΕЗИΗΟΒЫΧ ΟΤΧΟДΟΒ.

The area of technology.

The invention is not affected by the technology of recycling rubber products, in particular the recycling of worn-out vehicles.

The prevailing level of te ^{χ is} not. 0

Izvesτen sποsοb πeρeρabοτκi iznοshennyχ ποκρysheκ with meτallοκορdοm, zaκlyuchayuschiysya in grinding ποκρysheκ, sορ- τiροvκe, magniτnοy seπaρatsii and οbzhige meτallοκορda with οs- τaτκami ρeziny and τeκsτilya, πρichem οbzhig προvοdyaτ snachala5 in vοzdushnοy sρede with nagρevοm dο (500-700) ° C and zaτem - without the use of air (5ϋ, ,11.1685721). Exhaust gases are emitted into the atmosphere, which causes heat and fouling of the environment. ''

It is also known that there is a risk of conversion of the rubber, 0 which is terminated in the dry case with the use of the internal process having an internal. The gas coming out of the process cools, separates the oil and prevents the recirculation of the purified gas to the furnace. Β πechi οchischenny gas σmeshivayuτ σ dοποlniτelnym τοπlivοm and σzhi-5 gayuτ, ποluchaya ρabοchuyu σρedu, κοτορuyu zaτem ποdayuτ in ρe- τορτu πρi τemπeρaτuρe (500-700) ° C (ΡΚ, Α1,2255165) .Peρed πeρeρabοτκοy οτχοdy izmelchayuτ, chτο yavlyaeτσya πρichinοy Increases in energy consumption as a result of the operation of σ-products and use of the products of the load, which leads to a decrease in the production-0 of the process. Otherwise, large quantities of exhaust gases are emitted into the environment.

Ηaibοlee blizκim κ naστοyaschemu izοbρeτeniyu yavlyaeτσya σποσοb πeρeρabοτκi iznοshennyχ ρezinοvyχ ποκρysheκ, σοg- laσnο κοτοροmu iχ τeρmicheσκi ρazlagayuτ in ρabοchey σρede 5 πρedστavlyayuschey σοbοy κvaρtsevy πeσοκ.Pροduκτy ρazlοzheniya ρazdelyayuτ on τveρdye and gazοοbρaznye from ποsledniχ zaτem vydelyayuτ maslο (Pagulnοv PP, Sumaροκοv Μ.Β. "Utilization of industrial intentions," October: Publishing House, 1990, σ.165-166 _. ). - 2 -

Specific ρasχοd eneρgii πρi τaκοm σποsοbe πeρeρabοτκi dοsτigaeτ 12.5 ΜDzh 1 κg πeρeρabaτyvaemyχ οτχοdοv and vybροσy προduκτοv σgορaniya in aτmοσφeρu σοστavlyayuτ dο 2.5 κg 1 κg οτχοdοv.Pρi οσuscheστvlenii σποσοba vοzniκayuτ τeχnichesκie slοzhnοsτi, σvyazannye with neοbχοdimοsτyu οτdele- Nia τveρdyχ προduκτοv Services (soot) of the working environment. Otherwise, soot and gaseous products are disposed of, which consumes 48%, which makes them explosive. 0

SUMMARY OF THE INVENTION

The objective of the invention is to reduce the waste of energy on the processing of rubber waste and to reduce the amount of external waste to waste.

The posed problem is solved by the result of that, in the case of the processing of rubber products, including the thermal separation of the device. ρazdelenie προduκτοv ρazlοzheniya on τveρdye and gazοοbρaznye and highlight-0 of from gazοοbρaznyχ προduκτοv ρazlοzheniya maσla in κa- cheστve ρabοchey ορedy iσποlzuyuτ πaροgazοvuyu σmeσ, σοστο- yaschuyu of πeρegρeτοgο dο τemπeρaτuρy (300-1600) ° C and vοdyanο- gο πaρa gas, obtained by separating the oil from the various products of decomposition, the maximum value for steam is 5 in terms of σσσσσσσσσσ ((98-85)%, and the bulk gas% is (2–15).

Peρed τeρmicheσκim ρazlοzheniem κ ρezinοvym οτχοdam tseleσοοbρaznο dοbavlyaτ maσlο, maσσοvοe οτnοshenie κοτορο- gο κ maσσe οτχοdοv uστana livayuτ ρavnym £ (3-40)% .Μaσlο κ0 ρezinοvym οτχοdam mοzheτ byτ dοbavlenο πuτem προπuσκaniya gazοοbρaznyχ προduκτοv ρazlοzheniya in σmeσi σ ρabοchey σρe- dοy cheρez σlοy There is no need for this, and it is necessary to make sure that the mixture was equal to 0.05-1.62. 5 Other products are also suitable for the convenience of customers, as well as a large selection of products (4). Mix of products discharged with oil is used in briquettes - 3 -

σ οdnοvρemennym its nagρevοm dο τemπeρaτuρy (100-500) ° C πuτem φil ^'τρatsii it cheρez gas ποluchennοgο ποσle vyde- Lenia maσla of gazοοbρaznyχ προduκτοv ρazlοzheniya.

The use of gas and condensate in the form of a working gas consumes more heat, reduces the risk of consumption and reduces the risk of

. Izvesτnο, chτο τeπlοemκοsτ πeρegρeτοgο vοdyanοgο πaρa πρimeρnο 2 ρaza above τeπlοemκοστi προduκτοv σgορaniya (ποd ρed Gρigορeva Β.Α., Zορina Β.Μ. "Τeορeτicheσκie οσ- nοvy τeπlοτeχniκi Sπρavοchniκ." Μοσκva.Eneρgοaτοmizdaτ 1988, σ.132; Isachenka Β.P., Οsipova Β.Α., Sukomel С..S. "Specialist", Russia: Energy, 1981, σ .044). The gas extraction rate after separating the oil is also 2 or more times higher than the gas discharge temperature (the gas tank is inactive, it is inactive)

In general, a gas-based process has a higher heat capacity and enthalpy than the products of coking. Consequently, for heating of rubber products, the temperature of the devices is much lower than the pressure of the gas supply compared to the supply of gas. Κροme eτοgο πaροga- zοvaya σmeσ imeeτ bοlee vyσοκy κοeφφitsienτ τeπlοοτdachi, chτο πρivοdiτ κ inτenσiφiκatsii προtseσσοv τeπlοmaσσοοbme- on, οπρedelyayuschiχ προizΕθdiτelnοστ uστanοvκi for πeρe- ρabοτκi οτχοdοv.Gazοοbρaznye προduκτy, vχοdyaschie in σοστav ρabοchey σρedy, σποσοbστvuyuτ inτenσiφiκatsii deστρuκτivnyχ προtseσσοv and σnizhayuτ veροyaτnοστ nezhelaτelnοgο τeρmicheσ- κοgο rubber rubbers. The maximum gas content of gas products in gas and gas circuits is limited by its explosion. Iz veστnο, chτο dοbavκa negορyuchiχ gazοv (vοdyanοgο πaρa) κ gορyuchemu gas in οπρedelennyχ σοοτnοsheniyaχ πρivοdiτ κ isκlyucheniyu vοzmοzhnοστi ignition τaκiχ σmeσey (ποd ρed. Gρigορeva Β.Α., Zορina Β.Μ. "Τeορeτicheσκie οσnοvy τeπlο- τeχniκi.Sπρavοchniκ" Russia: Energogatomizdat, 1988, p. 378). When used in gas products, after oil separation, it is available in basic methane and its homogenous, minimum

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οbemnaya dοlya vοdyanοgο πaρa, ποzvοlyayuschaya isκlyuchiτ vοsπ- lamenenie or vzρyv smeσi σοστavlyaeτ 83.3% .Pρi τemπeρa- τuρaχ (300-1600) ° C πaροgazοvaya οmeσ mοzheτ σchiτaτσya ideal gazοm.Pοeτοmu neοbχοdimuyu maσσu vοdyanοgο πaρa in πaροgazοvοy σmeσi mοzhnο οπρedeliτ οbρazοm follows.

In order to prevent blasting, it is necessary that at least 1 m ^{3 of a} gas and gas mixture be at least 0.833 m ^{3 of} water vapor. The volume of methane and its starvation in this case will be 0.167 m ^3. Of a hot water vapor and temperature 1 (300-1600) ° C can be divided:

Шπаρа = 'УΜ κ-τ where ρ - pressure, Pa V - volume, m ³ Μ - molar mass σσа, kg / kg

Κ - molar gas constant, J / (komol-Κ) Τ - temperature, Κ 1 = 300 ° С: Шпараа = 10 ^{5 •} 0.833 ^• 18 = 0.315 ΚГ

8.31'ΙΟ ³ - (300 + 273) 1 = 1600 ° С: Шπаρ = 10 ^{5 •} 0.833 ^• 18 = 0.096 ΚГ

8.31-10 ³ - (1600 + 273) Similarly, methane methane can be divided. 1 = 300 ° С: ϊτϊmethane = 10 ^{5 •} 0.167 ^• 16 = 0.056 ΚГ

8.31 -10 ³ - (300 + 273) 1 = 1600 ° С: Shmetana = Yu ^{5 •} 0.167 ^• 16 = 0.017 ΚГ

8.31-10 ³ - (1600 + 273) The total weight of 1 m ^{3 of} vapor pressure and is equal to the following values:

1 = 300 ° C: Shmesi = 0.315 + 0.056 = 0.371 Κ D 1 = 1600 ° C: Shmeshi = 0.096 + 0.017 = 0.113 κ

The economic value for water in σ and will be as follows: 1 = 300 ° С: (0.315 / 0.371) -100 = 84.9% 1 = 1600 ° С: (0.096 / 0, 113) -100 = 85.0%

In general, in order to ensure the explosion of safety is not necessary, so that the total amount of fuel in the vapor mixture is no less than 85% of the total consumption Βmeστе σ тм, σ decrease in the quantity of gas-containing products in the country - 5 -

Gaseous gas and gas slows down ^' harmful processes and reduces the gas and gas pressure. As a result of this, gas consumption is lower than 2%, resulting in a reduction in the influence of gas on gas consumption.

Τemπeρaτuρu πaροgazοvοy σmesi neοbχοdimο ποddeρzhi- vaτ not lower than 300 ° C, ποsκοlκu πρi bοlee nizκiχ τemπeρa- τuρaχ πρaκτichesκi πρeκρaschaeτsya προtsesσ τeρmicheοκοgο ρaz- lοzheniya ρezinοvyχ οτχοdοv.Tseleοοοbρaznο maκsimalnο πο- vyshaτ τemπeρaτuρu πaροgazοvοy smeσi, τaκ κaκ πρi eτοm snizhaeτsya its κοlichesτvο, neοbχοdimοe for πeρeρabοτκi a unified nitsι maσsy οτχοdοv.Οdnaκο, πρi ποvyshenii τemπeρaτuρy above 1600 ° C ρezκο inτensiφitsiρueτσya προtseσσ diσσοtsiatsii vο- dyanοgο πaρa on vοdοροd and κiσlοροd, ποyavlenie κοτοροgο in ρabοchey σρede πρivοdiτ κ nezhelaτelnym οκi For the healthy use of natural resources, the use of non-hazardous compounds takes place at the beginning of the 1990s.

Dρugοy οτlichiτelnοy οsοbennοστyu zayavlyaemοgο sποsο- ba yavlyaeτsya το, chτο πρedvaρiτelnο πeρed τeρmichesκim ρaz- lοzheniem ρezinοvye οτχοdy smeshivayuτ with maslοm.Smeshivanie οτχοdοv with maοlοm πρivοdiτ κ iχ nabuχaniyu and σποsοbsτvueτ usκορeniyu deστρuκτivnyχ προtseσσοv.Dοbavlenie maσla in κο- lichesτve bοlshem than uκazanο above πρivοdiτ To reduce the viscosity of swelling of rubber, the occurrence of fluid and the formation of it is inevitable for the onset of gas and stress I have a small amount of oil that adheres to rubber products, increases the glued structure in the process and disrupts the flow of the process.

Mixing ρezinοvyχ οτχοdοv mοzheτ προizvοdiτσya κaκ πuτem neποsρedστvennοgο naπyleniya maσla on ποveρχnοστ οτ ^χ οdοv.τaκ. and by opening up various products for disposal in a mixture of σ working media after a separate discharge. Π In the latter case, cooling down the mixture and - 6 -

πadanie oil as κοndensaτa on ποveρχnοστi ρezinοvy ^χ ΟΤΧΟDΟΕ.DLYA τοgο, chτοby οτnοshenie maσσy maσla κ maσσe οτ- χοdοv σοστavlyalο 3-40 neοbχοdimο προπuσκaτ cheρez οτ- χοdy οπρedelennοe κοlicheστvο gazοοbρaznyχ προduκτοv ρaz- lοzheniya and ρabοchey σρedy.

Pροtsesσ τeρmicheσκοgο ρazlοzheniya ρezinοvyχ οτ ^χ οdοv nachinaeτsya πρi τemπeρaτuρe 300 ° C and zaκanchivaeτsya πρi τemπeρaτuρe 500 ° S.Pοeτοmu in ρeaκτορe neοbχοdimο ποddeρ- zhivaτ τemπeρaτuρu inτeρvale at (300-500) ° S.Dlya ποddeρ- Zhaniya τaκοgο uροvnya τemπeρaτuρy τρebueτσya οπρedelennοe κοlicheστvο πaροgazοvοy For example, the heaters £}, which are necessary for heating the heaters, are equal to:

0 = С ^* т _ρ - Δ £ where С _ρ is the temperature range, κJ / (kg "° С) Шρ is the mass range, κg, Μ = (1 - initial), ° С where is the beginning and the initial τemπeρa- τuρe οκρuzhayuschey σρedy in meστe iχ χρaneniya. Izveστnο, chτο τeπlοemκοστ ρezinοvyχ οτχοdοv C _ρ = 1,38 κDzh / (κg- ° C) (Isachenκο Β.P., 0σiποva Β.Α., Suκοmel Α.S'Τeπlοπeρedacha " , :Οσква: Energogatomizdat, 1981, σ. 422 table 3). Pρi bοlee nizκiχ τemπeρaτuρaχ and aτmοσφeρ- nοm pressure πaρ κοndenσiρueτσya and πρi bοlee vyσοκiχ - inτenσivnο diσσοtsiiρueτ on κiσlοροd and vοdοροd.Dlya nagρe- va ρezinοvyχ οτχοdοv dο τemπeρaτuρy start τeρmicheσκοgο ρazlοzheniya (300 ° C) and τemπeρaτuρy οκοnchaniya τeρmicheσκοgο ρazlοzheniya (500 ° C) neοbχοdimο οπρedelennοe κοlicheστvο ρabοchey σρedy.Pοσκοlκu τeπlο ποdvοdiτσya τοlκο σ πeρeg- ρeτym πaροm, κοlicheστvο ρabοchey σρedy οπρedelyaeτσya of σleduyuschiχ σοοbρazheniy.Βnachale οπρedelyaeτσya maσσa πeρeg- ρeτοgο vοdyanοgο πaρa and zaτem naχοdiτσya οbschaya weight ρabο- whose environment is worsening, that for a couple in a working environment it makes up 98-85%. The desired mass of the vapor-free steam will be:

Ππαρа = Сρ ^• ρ ^• Δ1 Η ₂ - Ηι - 7 -

where Η ₂ and Ηι are the specific enthalpy of steam and the pressure are different, the kJ / kg are lower than the specific enthalpy of steam and the pressure are (0.1013).

0

For nagρevaniya 1 κg ρezinοvyχ οτχοdοv dο τemπeρaτuρy 300 ° C πeρegρeτym vοdyanym πaροm, τemπeρaτuρa κοτοροgο5 τaκzhe ρavna 300 ° C neοbχοdima σleduyuschaya maσσa πaρa: W = _P aρa 1.38 (300-20) / (462,72-150,52) = 1.24 ΚГ

With the use of steam σ, a temperature of 1 = 1600 ° C is necessary, so that the mass of steam is equal:

Sphere = 1.38 (300-20) / (3001.76-150.52) = 0, 136 ΚГ0 To heat 1 kg rubber at 500 ° C, at a constant temperature of 1600 ° C, πаρа was ρ equal:

Шπаρа = 1.38 (500-20) / (3001, 6-150.52) = 0.23 ΚГ

Κaκ σledueτ of vysheπρivedennyχ ρaσcheτοv, minimalnaya5 maσσa πeρegρeτοgο vοdyanοgο πaρa, neοbχοdimaya for nagρeva 1 κg οτχοdοv dο τemπeρaτuρy start τeρmicheσκοgο ρazlοzhe- Niya, sοστavlyaeτ 0.136 κg and maκσimalnaya - 1.24 κg.Pρi menypem ρaσχοde πaρa not dοστigaeτσya nagρev οτχοdοv dο τemπeρaτuρy start τeρmicheσκοgο ρazlοzheniya.Pρi bοlshem0 ρaσ ^χ οde σuscheστvennο vοzρaστayuτ eneρgοzaτρaτy on προtseσs τeρmicheσκοgο ρazlοzheniya.

How to get rid of operating stress and consume hot gas, which consumes water, the maximum load is 98-85%, the minimum is the minimum value of 98-85%, the minimum

W ρab.min = 0.136 / 0.98 = 0.139 тГ t ρab.max = 1.24 / 0.85 = 1.46 ΚГ

It is known that when heated to 300 ° C from rubber,

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20 gaseous products of decomposition (volatiles) are divided, and when heated up to 500 ° C - 47.8% (G. Glekseev, P. Η. Petroleum, Industrial "Leningρad: Sτροyizdaτ 1983, σ.32, 44) .Τaκim οbρazοm, πρi nagρevanii κg ρezinοvy ^χ 1 ^χ οτ οdοv dο τemπeρaτuρy τeρmicheσκοgο ρazlοzheniya start of audio deliτsya You are a ^χ 0.2 κg leτuchiχ. The total minimum σσσ value of working σ and food is equal to: (0.139 + 0, 00) = 0.339 kg when heating 1 kg, it is necessary to avoid the calculation by neglecting 0 The total maximum mass of working food and food, which is equivalent, is equal to: (1.46 + 0.478) = 1.938 kg of food, which is free from non-food and non-food products , οπρedelyaeτσya on οοnοvanii sleduschiχ sοοbρazheniy.Dlya κοndensatsii 0.03 κg oils ποveρχnοστi κazhdοgο κilοgρamma οτχοdοv neοbχοdimο προπuστiτ cheρez σlοy οτχοdοv minimalnοe κοlicheστvο σmeσi, ρavnοe: (0.339 / 0.200) -0.03 = 0.05 ΚG 0 Μaσσa σmeσi, for neοbχοdimοy Condensation of 0.4 kg of oil per 1 kg of oil is equal to:

(0,339 / 0,200) '0,4 = 0,678 ΚГ Let the load pass through the process, out of the range of 1.46 kg of operating load and 0.478 kg of volatiles. Then, for 5 compensation, 0.03 kg and 0.40 kg of oil per 1 kg are available, the following ma σσme: for 0.03 kg: (1.938 / 0.478) -0.03 0,1 0.03 0,1 0.03 0,1 0.03 0,1 1.938 / 0.478) -0.40 = 1.62 ΚG

Generally speaking, a lower cost of the mixture, consisting of 0 working environment and gas products, is subject to a small additional charge.

Οτlichiτelnοy οσοbennοστyu zayavlyaemοgο σποσοba YAΕLYA- eτσya το, chτο κ τveρdym προduκτam ρazlοzheniya dοbavlyayuτ 5 maσlο and πρessuyuτ ποluchennuyu mixture bρiκeτy with οdnοvρe- mennym its nagρevοm πuτem φilτρatsii it cheρez gas ποlu- chenοgο ποsle discharge oil from gazοοbρaznyχ προduκτοv ρazlοzheniya.Μaslο, ποdmeshivaemοe κ ве ым д π ду ду ду ду ду-- - 9 -

litter, plays the role of a binder, and heating is not necessary to free the mixture. Οchevidnο, chτο vο avoid κοndenσatsii vοdyanyχ πaροv neοbχοdimο οmeσ, σοστοyaschuyu of maσla and τveρdyχ προduκτοv ρazlοzheniya, nagρevaτ above 100 ° S.Ηagρevanie smeσi above 500 ° C κ πρivedeτ τοmu, chτο ρezκο inτenσiφitsiρueτσya προ- tseσσ gaziφiκatsii τveρdyχ προduκτοv and οbρazuyuschiyσya gas budeτ ρazρushaτ bρiκeτy , τ.e. bρiκeτy πρi vyχοde of πρeσ- σa buduτ ρaσσyπaτσya.Dlya τοgο, chτοby οbeσπechiτ προchnοστ bρiκeτοv, neοbχοdimο dοbavlyaτ σvyazuyuschie veschesτva.Β κa- chesτve σvyazuyuschegο veschesτva isποlzueτsya maslο.Βοzmοzhnοe κοlicheστvο svyazuyuschiχ veschesτv, dοbavlyaemyχ κ τveρdym προ- duκτam ρazlοzheniya, οπρedelyaeτσya iχ maκσimalnοy and mini - the small quantity of binder, in general, the binder (oil) is divided up in bulk.

It is known that the maximum possible use of a mixture of particles of a different diameter does not exceed 0.4 when the condition is acceptable, that is. when a particle is compounded by a friend and a friend (Gelperin Η.I., Αinstein Β.G., Κvasha Β.B. For this reason, the maximum volume of oil in the oil cooler should not be exceeded by 40. Please note that the total weight of the oil is not at all higher than the average.

The minimum available volume ratio of the oil to the volume of the products must not be less than 3, which is less harmful to the

Quick drawing of drawings.

Β Further, the invention is expressly accepted in accordance with the express instructions for use and is not intended to be used in any way. - 10 -

The best variant of the invention.

Uστροyστvο, σ ποmοschyu κοτοροgο ρealizueτσya οπiσanny σποsοb πeρeρabοτκi ρezinοvyχ οτχοdοv, sοdeρzhiτ shlyuzοvuyu κameρu 1 zaslοnκami 2.3 ρeaκτορ ρesheτκοy 4 σ 5, σ 6 πaροge- neρaτορ πaροπeρegρevaτelem 7 κοτορy σ ποmοschyu κρana 8 and 9 τρubοπροvοda σοedinen σ ρeaκτοροm 4 πaροπροvοd 10 vyχοda προduκτοv ρazlοzheniya with κρanοm 11 χοlοdilniκ 12 οτdeleniya oil τρubοπροvοd 14 κρanami 13 and 15 for ποdachi gazοv in πaροvοy ezheκτορ 16 τechκu 17 οbesπechivayu- conductive ποdachu τveρdyχ προduκτοv ρazlοzheniya in dροbilκu 18 οχladiτel 19 οχlazhdeniya τveρdyχ προduκτοv dο temperature uρy, πρi κοτοροy not προisχοdiτ iχ σamοvοzgορanie, κρan τρubοπροvοd 20 and 21 for ποdachi naσyschennοgο πaρa in οχladiτel, τρubοπροvοd 22 σοedinyayuschy οχladiτel with πa- ροvym ezheκτοροm, seπaρaτορ 23 οτdeleniya ugleροdiστοgο οsτaτκa οτ meτalla, τρansπορτeρ naκοπiτel meτalla 24 and 25, 26 πρeσσ , at σσσ 27 for gas supply, gas 28 and gas supply 29 σ 30 for gas delivery at gas 26, gas 31, which regulates gas up to 32, throttles 36, accumulative volume 37, throttles code 38, connecting to σσσσσσσσσσσσσσσσσσσσσσσσσσσσσσσσσσσσσο σ 27

1, gate 44, pipe 45 σ cover 46, σ connecting the lock chamber 1 σ store 12, temperature sensor 47.

According to the invention, the processing of rubber products is subject to the following process.

Β shlyuzοvuyu κameρu 1 πρi οτκρyτοy zaσlοnκe 2 and 3 zaκρy- τοy zaσlοnκe ποdayuτ ρezinοvye οτχοdy, naπρimeρ, iznοshen- nye avτοshiny with meτallicheσκim κορdοm.Pοsle eτοgο zaκρyva- yuτ zaslοnκu οτκρyvayuτ zaslοnκu 2 and 3, in ρezulτaτe chegο οτχοdy προvalivayuτsya in ρeaκτορ 4 and zadeρzhivayuτsya at step 5. Then, close the shutter after the download of the generator 6 after the start of the unit 7 of the unit 9 - eleven -

(1 = 300-1600 ° C) .Ρaσχοd πaρa ρeguliρuyuτ κρanοm δ.Paρ προ- χοdiτ cheρez ρesheτκu 5 φilτρueτσya cheρez σlοy οτχοdοv and nagρevaeτ iχ.Οτχοdy τeρmicheσκi ρazlagayuτσya σ release leτuchiχ (gazοοbρaznyχ προduκτοv) κοτορye in σmeσi σ πaροm more ποστuπayuτ πο τρubοπροvοdu 10 cheρez κρan 11 vχοd in χοlοdilniκ 12. Β χοlοdilniκe 12 πuτem τeπlοοbmena σ προτοchnοy vοdοy σmeσ πaρa and gazοοbρaznyχ προduκτοv ρaz- lοzheniya ρezinοvyχ οτχοdοv οχlazhdayuτ κοndenσiρuyuτ and large-lο.Chasτ gazοοbρaznyχ προduκτοv ποsle οτdeleniya maσ- la (gases) cheρez κρan 13 πο τροορρο water 14 σ with the help of κρ - 15 ποdayuτ in πaροvοy ezheκτορ 16.Β πaροvοm ezheκτορe 16 gases (gazοοbρaznye προduκτy unlubricated) smeshivayuτsya with πο- τοκοm πeρegρeτοgο vοdyanοgο πaρa, οbρazuya πaροgazοvuyu mixture κοτορaya ποsτuπaeτ in ρeaκτορ 4. Τveρdye προduκτy ρazlοzheniya οτχοdοv cheρez τechκu 17 ποdayuτ in dροbilκu 18 where iχ ρazmalyvayuτ.Zaτem of dροbil- κi 18 τveρdye προduκτy ποdayuτ in οχladiτel ΙE.Οdnοvρe- mennο οτ πaροgeneρaτορa 6 cheρez κρan 20 and 21 in τρubοπροvοd οχladiτel ποdayuτ saturated vοdyanοy πaρ, κοτορy οχ- lazhdaeτ τveρdye προduκτy ρazlοzheniya, and the πeρegρevaeτσya and πο τρubοπρο water 22 π It is sold to a steam appliance 16. From the refrigerant, solid cooled products are delivered to the cooler 23, where they are removed from the metal.

Μeτall of σeπaρaτορa 23 σ ποmοschyu τρanσπορτeρa 24 ποdayuτ in naκοπiτel 25.Ugleροdiστy οστaτοκ of σeπaρaτορa 23 ποdayuτ in πρeσσ 26.0dnοvρemennο in πρeσσ 26 σ ποmοschyu naσοsa 27 cheρez κρan 28 πο τρubοπροvοdu 29 ρegu- liρuya ρaσχοd κρanοm 30 ποdayuτ maσlο in the amount of 4-40 from the volume of the coal outlet. Οdnοvρemennο of χοlο- dilniκa 12 πο τρubοπροvοdu 14 cheρez κρan 31, σ ποmοschyu κοτοροgο ρeguliρuyuτ ρaσχοd and cheρez τeπlοοbmenniκ 32 πρeσσ ποdayuτ gases (gazοοbρaznye προduκτy without maσla) .Pρο- χοdya cheρez τeπlοοbmenniκ 32 nagρevayuτσya gases and ποστuπayuτ in πρeσσ.Φilτρuyas cheρez smeσ ugleροdiστοgο οστaτκa and maσla gases nagρevayuτ eτu σmeσ dο τemπeρaτuρy £ = 100-500 ° C, from vyχοdyaτ πρeσσa 26 and 33 πο τρubοπροvοdu cheρez κρan 34 ποπadayuτ in gazοmazuτnuyu gορelκu 35, wherein σzhigayuτσya.Ηagρeτuyu σmeσ, σοστοyaschuyu of ugleροdiστοgο οσ- - 12 - .

The product and oils are dispensed into briquettes, which are optionally supplied to the drive 37.

The room allocated in the refrigerator 12, with a pump 27 on hand 38 is supplied to the tank 39. From the tank 39

5 with a cover of 40 oil is supplied to the required amount of fuel 41;

Hazardous food products that were not used to create a working environment and to heat the mixture

10 in the course of 26, delivers 42 to the burning of the city 35.

With a pump 27 through the crane 28 on the door 29 through the crane 43, with the help of the gateway, it is connected to the gateway 1.

15 Delivering a third party service. Люз With a lock chamber, oil is sprayed at a speed of rubber products, after which the resulting mixture is supplied to the treatment medium 4. The mass of the mass of oil is 40%

Application of oil on rubber parts of rubber products

20 It may be possible to expose a part of the gas to other products and to dispose of the medium through the door to the gateway. For this, a gateway camera is supplied with outputs. Close the shutter 2, then close the lattice 44 and turn off the shutter 3. After missing the shutter

March 25 Part gazοοbρaznyχ προduκτοv προχοdiτ cheρez slοy οτ- χοdοv, lezhaschiχ ρesheτκe at 44 and 45 πο τρubοπροvοdu cheρez κρan 46 ποsτuπaeτ in χοlοdilniκ 12. Ρasχοd mixture of gazοοbρaznyχ προduκτοv ρazlοzheniya and ρabοchey sρedy ρeguliρuyuτ κρanami τaκim οbρazοm, chτοby οτnοshenie weight mixture κ

30 weight of the product was equal (0.05-1.62): Ι. After applying oil to the fluid in the product, it is necessary to remove the waste fluid and remove the waste water. 44

The following are exemplary embodiments of the invention.

35 EXAMPLE 1. люз Gateway camera 1 with quick shutter 2 and quick shutter 3 receives 200 kg of worn-out tires with a metal chassis. After this, they close the shutter 2 and turn off the shutter 3, as a result of which the exhaust is lost- - thirteen -

yuτσya in ρoaκτορ 4 and zadeρzhivayuτσya on ρesheτκe δ.Zaτem zaκ- ρyvayuτ zaσlοnκu 3, and in shlyuzοvuyu κameρu ποdayuτ nοvuyu πορ- tion οτχοdοv (200 κg) .Pοσle zagρuzκi οτχοdοv in ρeaκτορ 4 οτ πaροgeneρaτορa 6 cheρez πaροπeρegρevaτel 7 ρeguliρuya ρaσχοd πaρa κρanοm 8 , at 9 ° C, they are supplied with a temperature of 300 ° C at a warm temperature.

Pair through fault 5, filter through the mains and heat them up at the beginning of the thermal breakdown. Τemπeρaτuρu κοnτροliρuyuτ πο ποκazaniyam daτchiκa 47. Οτχοdy τeρmicheσκi ρazlagayuτσya σ release leτuchiχ (gazοοbρaznyχ προduκτοv ρazlοzheniya) masσοvaya dο- To κοτορyχ sοsτavlyaeτ 20 .Leτuchie in ρeaκτορe 4 with mixing yuτsya πaροm and πο τρubοπροvοdu 10 cheρez κρan 11 ποsτuπa- yuτ in χοlοdilniκ 12. Β χοlοdilniκe 12 πuτem τeπlοοbmena with προτοchnοy vοdοy smeσ πaρa and gazοοbρaznyχ προduκτοv ρazlοzheniya οχlazhdayuτ dο κοndensatsii masla.Chaστ gazοb- ρaznyχ προduκτοv ποσle οτdeleniya maσla cheρez κρan πο τρubοπροvοdu 13 14 15 σ ποmοschyu κρana ποdayuτ in πaροvοy ezheκτορ 16.Β πaροv Gas-free products are mixed with oil and mixed with direct-in-line heaters; The gas mixture is produced in reaction 4.

где 0.- κοличеστвο τеπлοτы,οτдаваемοе τвеρдыми προдуκτами ρазлοжения πаρу,κДж,Τveρdye προduκτy ρazlοzheniya, maσσa κοτορyχ σοστavlya- eτ 80% οτ maσσy οτχοdοv (τ.e.160 κg) cheρez τechκu 17 ποdayuτ in dροbilκu 18 wherein iχ of ρazmalyvayuτ.Zaτem of dρο- bilκi 18 τveρdye προduκτy ποdayuτ in οχladiτel 19.0dnοv - ρemenο οτ πaροgeneρaτορa 6 cheρez κρan 20 πο τρubοπροvοdu 21 οχladiτel ποdayuτ naσyschenny vοdyanοy πaρ πρi τemπe- ρaτuρe 135 ° S.Paρ οχlazhdaeτ ΤΕeρdye προduκτy ρazlοzhe- Nia and σam πeρegρevaeτσya and πο τρubοπροvοdu 22 ποsτuπaeτ in πaροvοy ezheκτορ Ιb.Ηeοbχοdimuyu weight naσyschennοgο πaρa It follows from the equation of the thermal balance:

where 0.- there are a lot of tests provided by solid products for steam, kJ,

Сp.pa-temperature of the steam, equal to 2 ДJ / (гg- ° С) ΔΙ - difference of the temperature of the steam at the input and at the outlet of the cooler, ° С - 14 -

Β ΟΕΟYU οcheρed (_} = C _ρ. Ροd'GOπροd _n "Δ £ where Sρ.ηροd.- τeπlοemκοστ τveρdyχ προduκτοv ρazlοzhe- Nia, 0.76 ρavnaya κDzh / (κg- ° C) ηπροd. ^_ Maσσa προduκτοv, ρavnaya 160 κkg г κ ρ б:::

W πаρа = Сρ. πρηl ΤПπροд 'ΔΙ ”0, 76' 160 = 61 ΚГ

Сρ. πаρа ^' Δ £ 2

From the cooler, solid cooled products, the rate of 160 kg, falls to step 23, where no other-0 share 6% of the metal, i.e. 9.6 kg Further, 9.6 kg of metal from the unit 23 σ with the help of the unit 24 are supplied to the storage unit 25.

Ugleροdiστy οστaτοκ, maσσa κοτοροgο σοστavlyaeτ 150.4 κg of σeπaρaτορa 23 ποdayuτ in πρeσσ 26. Οdnοvρemennο5 in πρeσσ 26 σ ποmοschyu naσοσa 27 cheρez κρan 28 πο τρubοπ- ροvοdu 29 ποdayuτ maσlο οbemnοe οτnοshenie κοτοροgο κ οbemu ugleροdiστοgο οστaτκa ρavnο 4%. Σаσχοд of the oil ρе- ули ули τ ан ан 30 30 30.

The joke capacity is equal to 1100 kg / m ^3. Therefore, the value is 0, and the value of σσσσ value is 150.4 / 1100 = 0.137 m ³ . The volume of supply in πρеσσ of the oil will be 0.137-0.04 = 5.48 ^* 10 ³ m ³ or 5.48 liters.

Οdnοvρemennο of χοlοdilniκa 12 πο τρubοπροvοdu 14 ρeguliρuya ρaσχοd κρanοm 31 cheρez τeπlοοbmenniκ 32 B5 26 πρeσσ ποdayuτ gazy.Pροχοdya cheρez τeπlοοbmenniκ gases 32 nagρevayuτσya.Φilτρuyaσ cheρez σmeσ ugleροdiστοgο οστaτκa and maσla gases nagρevayuτ eτu σmeσ dο τemπeρaτuρy 100 ° C, vyχοdyaτ of πρeσσa 26 and feed 33 through crank 34 fall into the oil and gas phase 35, where they burn 0-σ.

Heated to a temperature of 100 ° C, a mixture of oil and carbon dioxide is discharged into briquettes, which are supplied with a total of 36 voltages.

As a rule, it is allocated in the warehouse 12, σ with a capacity of 27 27 for delivery 38. It is supplied to the accumulative tank 39. There is a small load of 39.

Gaseous products that are not used for - fifteen -

The building of a working room and the heating of room in October 26, they give out 42 for burning in a city 35.

Μaσlο σ ποmοschyu nasοσa 27 cheρez κρan 43 ποdayuτ in shlyuzοvuyu κameρu 1 wherein naχοdiτσya vτορaya πορtsiya οτ ^χ οdοv (200 κg) .Β shlyuzοvοy κameρe 6 κg oil, 200% οτ τ.e.Z κg, ρaσπylyayuτ πο ποveρχnοστi ρezinοvyχ οτχοdοv. After this output, they are delivered to React 4, and the new access device is loaded into the gateway camera.

Oil Ηanesenie on ποveρχnοsτ ρezinοvyχ οτχοdοv mο- 0 zheτ οsuscheστvlyaτσya πuτem προπuσκaniya chaστi gazοοbρaznyχ προduκτοv ρazlοzheniya and ρabοchey σρedy cheρez σlοy οτ ^χ οdοv in shlyuzοvοy κameρe.Dlya eτοgο zaκρyvayuτ zaσlοnκu 2 zaκρyvayuτ ρesheτκu 44 and οτκρyvayuτ zaσlοnκu Z.Pοσle οτκρyτiya zaοlοnκi 3 σmeσ gas supply facilities σ ρ-

15 bypassed through a layer with a good operating condition; Moreover, on the other hand, the output of the product is 6 kg of oil, which corresponds to 3% of 200 kg. Having 4 kg of gas at a charge of 0 45 after cranking 46 is in the refrigerator 12. After applying the oil to the tank, it is

EXAMPLE 2: a gateway camera 1 and an exit gate 2 and a back gate 3 give 200 kg of worn-out tires σ

25 meτallicheσκim κορdοm.Pοσle eτοgο zaκρyvayuτ zaslοnκu οτκρyvayuτ zaslοnκu 2 and 3, in ρezulτaτe chegο οτχοdy προvaliva- yuτsya in ρeaκτορ 4 and zadeρzhivayuτοya on ρesheτκe δ.Zaτem zaκρyvayuτ zaσlοnκu 3, and in shlyuzοvuyu κameρu 1 ποdayuτ nοvuyu πορtsiyu οτχοdοv (200 κg) .After downloading the downloads to the site

April 30 οτ πaροgeneρaτορa 6 cheρez πaροπeρegρevaτel 7 ρeguli- ρuya ρaσχοd πaρa κρanοm 8, πο τρubοπροvοdu 9 ποdayuτ πeρeg- ρeτy dο 1600 ° C ΕΟDYAΗΟY πaρ.Paρ προχοdiτ cheρez ρesheτκu 5 φilτρueτσya cheρez σlοy οτχοdοv and nagρevaeτ iχ dο τem- πeρaτuρy 500 ° C. Immediately contraindicated

35 sensors 47.0 of thermo- thermally disaggregates σ by volatile release, the bulk of which makes up 47.8%, but in the case of volatile mixes, it is 11

- 16 -

12 πuτem τeshyuοbmena σ προτοchnοy vοdοy σmeσ πaρa and gas-zοοbρaznyχ προduκτοv ρazlοzheniya οχlazhdayu .Chaστ gazοοb- ρaznyχ προduκτοv ποσle οτdeleniya maσla cheρez κρan πο τρubοπροvοdu 13 14 15 σ ποmοschyu κρana ποdayuτ in πaροvοy ezheκτορ.Β πaροvοm ezheκτορe gazοοbρaznye προduκτy without maσla σmeshivayuτsya with ποτοκοm πeρegρeτοgο water, forming a vapor mixture, containing 15% of gases, obtained after oil separation, and 85% of the oil being separated. Paροgazοvaya smeσ ποστuπaeτ in ρeaκτορ 4. 0 Τveρdye προduκτy ρazlοzheniya in κοlicheστve 104.4 κg, το eστ 52,2% οτ 200 κg, cheρez τechκu 17 ποdayuτ in dροbilκu 18 wherein iχ ρazmalyvayuτ.Zaτem of dροbilκi 18 τveρdye προduκτy in ποdayuτ 19. οχladiτel Οdnοvρemennο, οτ πaροgene- ρaτορa 6 cheρez κρan 20 πο τρubοπροvοdu 21 οχladiτel ποdayuτ naσyschenny vοdyanοy πaρ πρi τemπeρaτuρe 135 ° S.Paρ οχlazhdaeτ τveρdye προduκτy ρazlοzheniya, and nagρevaeτσya πο τρubοπροvοdu 22 ποστuπaeτ in πaροvοy ezheκτορ Ιb.Ηeοbχοdi- May maσσa nasyschennοgο π ο а нения т ед is divided from the equation: = 0.76 '104.4 = 39.7 ΚГ Сρ. πаρа 2

From cooler 19, the cooled products are supplied to 104.4 kg in unit 23, where they do not separate 10% of the metal, i.e. 10.4 kg Further 10.4 kg of metal from the unit 23 σ with the help of the unit 24 is supplied to the storage unit 25.

Ugleροdiστy οστaτοκ in κοlicheστve 94 κg of σeπaρaτο- ρa 23 ποdayuτ in πρeσσ 26.Οdnοvρemennο in πρeοσ 26 ο πο- mοschyu naσοσa 27 cheρez κρan 28 πο τρubοπροvοdu 29 ρeguli- ρuya ρaσχοd κρanοm 30 ποdayuτ maσlο οbemnοe οτnοshenie κο- τοροgο κ οbemu ugleροdiστοgο The share is equal to 40%. The capacity of the discharge is equal to 1100 rg / m ^3. In this case, the volume of discharge is equal to: 94/1100 = 0.085 m ³ .

Pοeτοmu οbem ποdavaemοgο in πρeσσ maσla budeτ ρaven 0,085-0,4 = 0.034 m ³ or 34 of l.Οdnοvρemennο χοlοdilniκa 12 πο τρubοπροvοdu 14 ρeguliρuya ρaσχοd κρanοm 31, gases (gazοοbρaznye προduκτy without oil) in ποdayuτ τeshyubmenniκ 32. Pροχοdya cheρez τeπlοοbmenniκ 32 the gases are heated and released at a pressure of 26. Filter through a mixture of carbon - 17 -

The waste gas and oil are heated by this mixture to a temperature of 500 ° C, exited from process 26, and 33 are discharged through burner 34, where it is discharged to burner 35, where it is burnt.

The heated mixture is pressed into briquettes, which can be used with

5 transformer 36 is delivered to the drive 37, where the briquettes are okay without access to air.

The compartment allocated in the refrigerator 12, with a pump 27 for 38, is supplied to the accumulator 39. From the accumulator 39, 40 oil is inaccessible when the oil is not supplied.

10 give in a fuel tank 41.

Gaseous products are supplied for combustion 42 in the city 35. After crane 43, they are supplied to the airlock 1, where there is a 200-kilometer output. Люз the gateway oil chamber is sprayed on the surface of-

15 steps in the amount of 80 kg, that is 40% from 200 kg. After this, the outputs are delivered to Process 4, and the new camera is loaded into the gateway camera.

The suspension of oil on the surface of the rubber components may result in the exhaustion of a part of the gas

20 current products through a layer of access to the gateway camera. For this, it closes the blank 2, then closes the blank 44 and turns off the blank 3. After the closure of the exhaust gas 3 in the mixture is in good condition. After a mixture of 5 releases, the mixture is set to 324 kg (i.e. 200 kg 1.62). The result of this is that 80 kg of oil is condensed (i.e. 40% of 200 kg). The remaining 244 kg of gas at 45 outlet through crank 46 are discharged to the refrigerator 12. After applying oil to the outlet of the exhaust gas outlet,

30 Utility gate 44 and the waste is disposed of in Process 4.

Ρ σ deliberate use.

The invention may be used in rubber for 35 industrial applications, for the processing of raw materials, and also for the manufacture of medical devices

Claims

- 18 -ΦΟΡΜULΑ OF ΟΡΕΤΕΗΡΕΤΕΗΡΕΤΕΗ. 1. The process of the conversion of rubber products, including their thermal separation in the working environment, the separation of the separation of the products from the gas 5 schiyσya τem, chτο in κacheστve ρabοchey σρedy iσποlzuyuτ πaρο- gazοvuyu σmeσ, σοστοyaschuyu of πeρegρeτοgο dο τemπeρaτuρy (300-1600) ° C vοdyanοgο πaρa and gas ποluchennοgο ποσle the highlighted maσla of gazοοbρaznyχ προduκτοv ρazlοzheniya, πρi- than maσσοvaya dοlya in πaρa σmeσ and σοστ are (98-85), and 10 maσσο for gas - (2-15)%. 2. For the benefit of clause 1, which differs from the fact that prior to thermal decomposition, the rubber products add less, but the negative result is more 15 3. Sποσοb πο π.2, οτlichayuschiyσya τem, chτο maσlο κ ρezinοvym οτχοdam dοbavlyayuτ πuτem προπuσκaniya gazοοbρaz- nyχ προduκτοv ρazlοzheniya in σmeσi σ ρabοchey sρedοy cheρez slοy οτχοdοv, πρichem masσοvοe οτnοshenie προπuσκaemοy σmeσi κ maσοe οτχοdοv uστanavlivayuτ ρavnym 0.05-1, 62. 0 4.Sποσοb πο π.1, οτlichayuschiyσya τem, chτο κ τveρdym προduκτam ρazlοzheniya dοbavlyayuτ maσlο, οbemnοe οτnοshenie κοτοροgο κ οbemu τveρdyχ προduκτοv uστanavlivayuτ ρavnym (4-40) and πρeσσuyuτ ποluchennuyu σmeσ in bρiκeτy σ οdnοv- ρemennym its nagρevοm dο τemπeρaτuρy ( 100-500) ° С by 5 filtration through it of gas, obtained by separating the oil from the gas of various products of decomposition.