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WO1996014824A1 - Preparations regeneratrices des cheveux - Google Patents

Preparations regeneratrices des cheveux Download PDF

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Publication number
WO1996014824A1
WO1996014824A1 PCT/EP1995/004281 EP9504281W WO9614824A1 WO 1996014824 A1 WO1996014824 A1 WO 1996014824A1 EP 9504281 W EP9504281 W EP 9504281W WO 9614824 A1 WO9614824 A1 WO 9614824A1
Authority
WO
WIPO (PCT)
Prior art keywords
hair
preparations according
carbon atoms
preparations
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP1995/004281
Other languages
German (de)
English (en)
Inventor
Detlef Hollenberg
Kurt Seidel
Dieter Goddinger
Christian Priebe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of WO1996014824A1 publication Critical patent/WO1996014824A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring

Definitions

  • the invention relates to hair cosmetic preparations which contain a special hair-regenerating active ingredient combination.
  • the human hair is treated in many different ways with hair cosmetic preparations. This includes, for example, cleaning the hair with shampoos and shower preparations and bleaching, dyeing and shaping hair with waving agents, tinting agents and styling preparations.
  • hair cosmetic preparations for example, cleaning the hair with shampoos and shower preparations and bleaching, dyeing and shaping hair with waving agents, tinting agents and styling preparations.
  • the hair structure can be undesirably impaired.
  • impairments can be seen, among other things. in poor wet and dry combability, an increased electrostatic charge, increased brittleness and, in more serious cases, in split, i.e. split hair. This not only worsens the external appearance of the hairstyle, but in particular the hair split should also be counteracted on account of the health of the hair.
  • a known way to alleviate these abuses is to subject the hair to a post-treatment with appropriate active ingredients, mostly cationic surfactants, which may be combined with other substances.
  • cationic surfactants are only suitable for the treatment of non-greasy hair;
  • their use with rapidly regreasing hair is problematic, since they put additional strain on the hair and strengthen the natural regreasing of the hair.
  • the invention thus relates to preparations for the treatment of keratin fibers, in particular human hair, characterized in that they contain an active ingredient combination consisting of (A) a cationically derivatized panthenol and (B) a carbohydrate selected from monosaccharides, oligosaccharides, On and uronic acids (sugar acids), sugar alcohols, glycosides and quaternized monosaccharides.
  • A a cationically derivatized panthenol
  • B a carbohydrate selected from monosaccharides, oligosaccharides, On and uronic acids (sugar acids), sugar alcohols, glycosides and quaternized monosaccharides.
  • Preferred cationically derivatized panthenols (A) are compounds of the formula (I)
  • R, R and R2 independently of one another for an alkyl group with 1-24 carbon atoms or an alkenyl group with 8-24 carbon atoms, 3 for an alkylene group with 1-18 carbon atoms, Y for an OH group or for hydrogen and X for a monovalent one , organic or inorganic anion.
  • Preferred compounds of the formula (I) are those in which R represents an alkyl or alkenyl group having 8-24 carbon atoms.
  • alkyl or alkenyl groups are, for example, lauryl, myristyl, cetyl, stearyl and oleyl groups.
  • R 1 and R 2 are preferably alkyl groups with 1-4 carbon atoms, especially methyl groups.
  • R3 is preferably a shorter alkylene group with 1-4 carbon atoms, in particular a methylene group.
  • Y due to the production process, preferably represents a hydroxyl group, X represents a halide ion, in particular chloride.
  • panthenol derivatives are found in the mentioned publication WO 92/13829, to which reference is expressly made here.
  • a corresponding product is sold by the Tri-K company under the name PANTHEQUAT R.
  • the cationically derivatized panthenols are preferably present in the preparations according to the invention in an amount of 0.05 to 10% by weight, in particular 0.05 to 5% by weight, based on the preparation as a whole.
  • both monosaccharides and oligosaccharides can be used as carbohydrates (B).
  • the use of monosaccharides is preferred.
  • those compounds are preferred which contain 5 or 6 carbon atoms.
  • Suitable pentoses and hexoses are, for example, ribose, arabinose, xylos, lyxose, allose, old rose, glucose, mannose, gulose, idose, galactose, talose and fructose.
  • Arabinose, glucose, galactose and fructose are preferred carbohydrates; Glucose is especially preferred.
  • sugar acids are gluconic acid, glucuronic acid, sugar acid, mannosugar acid and mucic acid.
  • Preferred sugar alcohols are sorbitol, mannitol and dulcite.
  • Preferred glycosides are the methyl glucosides.
  • Quaternized carbohydrates can also be used according to the invention as component (B).
  • the commercial product GlucquatR100 (according to the CTFA nomenclature a lauryl methyl gluceth-10 hydroxypropyl dimonium chloride) is a preferred quaternized carbohydrate.
  • the carbohydrates used are usually obtained from natural raw materials such as starch, the carbohydrates generally have the configurations corresponding to these raw materials (e.g. D-glucose, D-fructose and D-galactose).
  • the carbohydrates are preferably present in the preparations according to the invention in an amount of 0.1 to 10% by weight, in particular 0.1 to 5% by weight, based on the total preparation.
  • These polymer classes are nonionic and anionic polymers.
  • Suitable nonionic polymers are, for example: Polyvinylpyrrolidones, such as those sold under the name Luviskol R (BASF). Polyvinylpyrrolidones are preferred nonionic polymers in the context of the invention.
  • Vinyl pyrrolidone / vinyl ester copolymers such as those sold under the trademark Luviskol R (BASF). Lüviskol R VA 64 and Luviskol VA 73, each vinylpyrrolidone / vinyl acetate copolymers, are also preferred nonionic polymers.
  • Cellulose ethers such as hydroxypropyl cellulose, hydroxyethyl cellulose and methyl hydroxypropyl cellulose, as are sold, for example, under the trademark Culminal R and Benecel R (AQUALON).
  • anionic polymers suitable according to the invention are:
  • Compounds of this type are, for example, under the names Carbopol R 934, Carbopol R 934P, Carbopol R 940 (Carbopol EDT 2001), Carbopol 941 (Carbopol R EDT 2050), Carbopol R 950, Carbopol R 980, Carbopol R 981, Carbopol R EDT 2020 and Hostacerin R PN 73 available.
  • Copolymers of acrylic acid and / or methacrylic acid or their esters with C ⁇ o-30-alkyl acrylates such as those sold under the name Pemulen R.
  • Polyoxycarboxylic acids such as polyketo- and polyaldehydocarboxylic acids and their salts, such as, for example, P0C R HS 5060 and P0C R AS5060.
  • Vinyl pyrrolidone / vinyl acrylate copolymers available, for example, under the trademark Luviflex R (BASF).
  • a preferred polymer is the vinyl pyrrolid / acrylate terpolymers available under the name Luviflex R VBM-35 (BASF).
  • Acrylic acid / ethyl acrylate / N-tert-butyl acrylamide terpolymers which are sold, for example, under the name Ultrahold R strong (BASF)
  • methacrylic acid / ethyl acrylate / t-butyl acrylate terpolymer which are sold under the name Luvimer R 100P (BASF) become.
  • nonionic or anionic polymers are preferably used in an amount of 0.01 to 5% by weight, in particular 0.1 to 2% by weight, based on the preparation as a whole.
  • the preparations according to the invention can furthermore contain surfactants, in particular nonionic surfactants.
  • Non-ionic surfactants contain z.
  • Such connections are, for example
  • alkyl polyglycosides of the general formula R0- (Z) x . These connections are characterized by the following parameters.
  • the alkyl radical R contains 6 to 22 carbon atoms and can be either linear or branched. Primary linear and methyl-branched aliphatic radicals in the 2-position are preferred. Such alkyl radicals are, for example, 1-octyl, 1-decyl, 1-lauryl, 1-myristyl, 1-cetyl and 1-stearyl. 1-Octyl, 1-decyl, 1-lauryl, 1-myristyl are particularly preferred. When using so-called "oxo alcohols" as starting materials, compounds with an odd number of carbon atoms in the alkyl chain predominate.
  • alkyl glycosides which can be used according to the invention can contain only one specific alkyl radical R. Usually, however, these compounds are produced from natural fats and oils or mineral oils. In this case, the alkyl radicals R are mixtures corresponding to the starting compounds or corresponding to the respective working up of these compounds.
  • R consists essentially of Cg and CiQ alkyl groups, essentially from C 2 and Ci 4 alkyl groups, essentially from C 6 to C 5 alkyl groups or essentially from C 2 to C j ß Alkyl groups.
  • Any mono- or oligosaccharides can be used as sugar building block Z.
  • Sugar with 5 or 6 carbon atoms and the corresponding oligosaccharides are usually used.
  • sugars are glucose, fructose, galactose, arabinose, ribose, xylose, lyxose, allose, old rose, mannose, gulose, idose, talose and sucrose.
  • Preferred sugar components are glucose, fructose, galactose, arabinose and sucrose; Glucose is particularly preferred.
  • alkyl polyglycosides which can be used according to the invention contain on average
  • Alkyl glycosides with x values from 1.1 to 1.6 are preferred. Alkyl glycosides in which x is 1.1 to 1.4 are very particularly preferred.
  • alkoxylated homologs of the alkyl polyglycosides mentioned can also be used according to the invention. These homologues can be average contain up to 10 ethylene oxide and / or propylene oxide units per alkyl glycoside unit.
  • the compounds with alkyl groups used as surfactants can each be uniform substances. However, it is generally preferred to start from natural vegetable or animal raw materials in the production of these substances, so that substance mixtures with different alkyl chain lengths depending on the respective raw material are obtained.
  • both products with a "normal” homolog distribution and those with a restricted homolog distribution can be used.
  • “Normal” homolog distribution is understood to mean mixtures of homologs which are obtained as catalysts when fatty alcohol and alkylene oxide are reacted using alkali metals, alkali metal hydroxides or alkali metal alcoholates.
  • narrow homolog distributions are obtained if, for example, hydrotalcites, alkaline earth metal salts of ether carboxylic acids, alkaline earth metal oxides, hydroxides or alcoholates are used as catalysts. The use of products with a narrow homolog distribution can be preferred.
  • the preparations according to the invention preferably contain surfactants in quantities of 0.2 to 20% by weight, based on the respective preparation.
  • the formulations according to the invention include all known types of hair treatment agents, such as Hair shampoos, hair rinses, hair conditioners, hair treatments, hair fixers, hair sprays, blow-dry waves, permanent waving agents and hair colorants. Hair treatments are a preferred form of the agent according to the invention.
  • Preferred hair treatment compositions according to the invention are generally those which remain on the hair after use. Nevertheless, it can be In particular cases, it may also be preferred to formulate the agents according to the invention in the form of rinse-off products.
  • agents according to the invention can be, for example: anionic surfactants, such as, for example, fatty alkyl sulfates and ether sulfates and alkyl ether carboxylic acids, zwitterionic surfactants, such as betaines, ampholytic surfactants, structurants such as maleic acid, hair-conditioning compounds such as phospholipids, for example soy lecithin, egg lecithin and Cephalins, as well as silicone oils, protein hydrolyzates, especially elastin, collagen, keratin, milk protein, soy protein and wheat protein hydrolyzates, their condensation products with fatty acids as well as quaternized protein hydrolyzates, perfume oils, dimethyl isosorbide and cyclodextrins,
  • anionic surfactants such as, for example, fatty alkyl sulfates and ether sulfates and alkyl ether carboxylic acids
  • zwitterionic surfactants such as betaines, ampholytic
  • Solubilizers such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerol and diethylene glycol, dyes,
  • Anti-dandruff agents such as Piroctone Olamine and zinc Omadine, other substances for adjusting the pH value,
  • Active ingredients such as panthenol, allantoin, pyrrolidone carboxylic acids and their salts, plant extracts and vitamins, light stabilizers,
  • Consistency enhancers such as sugar esters, polyol esters or polyol alkyl ethers, fats and waxes such as walrus, beeswax, montan wax, paraffins and fatty alcohols, fatty acid alkanolamides,
  • Swelling and penetration substances such as glycerol, propylene glycol monoethyl ether, carbonates, hydrogen carbonates, guanidines, ureas and also primary, secondary and tertiary phosphates, opacifiers such as latex,
  • Pearlescent agents such as ethylene glycol mono- and distearate, blowing agents such as propane-butane mixtures, N 2 0, dimethyl ether, C0 2 and air and antioxidants, direct dyes, so-called coupler and developer components as oxidation dye precursors,
  • Reducing agents such as Thioglycolic acid and its derivatives, thiolactic acid, cysteamine, thio malic acid and ⁇ -mercaptoethanesulfonic acid,
  • Oxidation agents such as hydrogen peroxide, potassium bromate and sodium bromate.
  • the invention also relates to the use of the compositions according to the invention for the treatment of keratin fibers, in particular hair.
  • the invention also relates to a method for treating hair, in which a preparation according to the invention is applied to the hair and remains there.
  • the invention also relates to a method for treating hair, in which a preparation according to the invention is applied to the hair and rinsed out again after an exposure time (1 to 40 minutes).
  • Panthequat R 1 1.0 - - 1.0 1.0 1.0
  • panthenol derivative 45% active ingredient; CTFA name: panthenyl hydroxypropylsteardimonium chloride (TRI-K Industries)
  • Vinyl imidazolinium methochloride / vinyl pyrrolidone copolymer 50:50 (average molecular weight: approx. 80,000 daltons; 40% active substance; CTFA name: Polyquaternium-16) (BASF) polyvinyl pyrrolidone (95% active substance; CTFA name: PVP) (BASF)
  • Dimethyldiallylammonium chloride-acrylic acid copolymer (approx. 40% active substance in water; CTFA name: Polyquaternium 22) (CHEMVIR0N) 3) shampoo
  • GEODRICH cross-linked polyacrylic acid decamethylcyclopentasiloxane

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne des préparations contenant un complexe de principes actifs constitué d'un dérivé cationique de panthénol et d'un glucide, ces préparations ayant un effet régénérateur notable sur les cheveux fourchus. Cette action peut être accrue par l'addition de polymères non ioniques ou anioniques.
PCT/EP1995/004281 1994-11-11 1995-11-02 Preparations regeneratrices des cheveux Ceased WO1996014824A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19944440315 DE4440315A1 (de) 1994-11-11 1994-11-11 Haarregenerierende Zubereitungen
DEP4440315.1 1994-11-11

Publications (1)

Publication Number Publication Date
WO1996014824A1 true WO1996014824A1 (fr) 1996-05-23

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ID=6533066

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1995/004281 Ceased WO1996014824A1 (fr) 1994-11-11 1995-11-02 Preparations regeneratrices des cheveux

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DE (1) DE4440315A1 (fr)
WO (1) WO1996014824A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999013821A1 (fr) * 1997-09-13 1999-03-25 Henkel Kommanditgesellschaft Auf Aktien Agents de soins capillaires pour traiter les fourches

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19615145A1 (de) * 1996-04-18 1997-10-23 Henkel Kgaa Verfahren und Mittel zum gleichzeitigen Färben und Pflegen von keratinischen Fasern
DE19720366A1 (de) * 1997-05-15 1998-11-19 Wella Ag Haarreinigungsmittel mit glanzverbessernden Eigenschaften
DE19721411A1 (de) * 1997-05-22 1998-11-26 Beiersdorf Ag Verwendung von Zuckerderivaten gegen die Adhäsion von Protozoen und Parasiten
DE19737604C5 (de) * 1997-08-28 2008-02-07 Kao Corp. Verwendung einer Zusammensetzung als Haarwaschmittel
DE19810598A1 (de) * 1998-03-12 1999-09-23 Braun Gmbh Gerät zum Behandeln von Haaren
US6800302B2 (en) 2001-03-30 2004-10-05 L'oreal S.A. Heat activated durable styling compositions comprising C1 to C22 Substituted C3-C5 monosaccharides and methods for same

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1987003196A1 (fr) * 1985-11-22 1987-06-04 Agave Cosmetics Proprietary Limited Traitement pour les cheveux
EP0287876A1 (fr) * 1987-04-08 1988-10-26 Henkel Kommanditgesellschaft auf Aktien Compositions régénérant les cheveux
WO1992013829A1 (fr) * 1991-02-06 1992-08-20 Smith Ronald J Composes quaternaires de panthenol et utilisation desdits composes
WO1992019217A1 (fr) * 1991-05-04 1992-11-12 The Procter & Gamble Company Compositions cosmetiques
DE4214652A1 (de) * 1992-05-02 1993-11-04 Henkel Kgaa Haarbehandlungsmittel
WO1993024101A1 (fr) * 1992-05-22 1993-12-09 The Procter & Gamble Company Compositions cosmetiques
US5270035A (en) * 1992-05-21 1993-12-14 Lexin International Marketing Corporation Hair conditioner containing disodium cocoamphodiacetate
US5340570A (en) * 1991-11-18 1994-08-23 Shiseido Co., Ltd. Dispensing system for sprayable gel-type hair conditioner
DE9311095U1 (de) * 1993-07-24 1994-11-24 Goldwell Ag, 64297 Darmstadt Haarpflegemittel
US5384118A (en) * 1993-09-13 1995-01-24 Lavalle; Lila S. Gel hairdressing composition
DE4324962A1 (de) * 1993-07-24 1995-01-26 Goldwell Ag Haarpflegemittel

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1987003196A1 (fr) * 1985-11-22 1987-06-04 Agave Cosmetics Proprietary Limited Traitement pour les cheveux
EP0287876A1 (fr) * 1987-04-08 1988-10-26 Henkel Kommanditgesellschaft auf Aktien Compositions régénérant les cheveux
DE3711841A1 (de) * 1987-04-08 1988-10-27 Henkel Kgaa Haarregenerierende zubereitungen
WO1992013829A1 (fr) * 1991-02-06 1992-08-20 Smith Ronald J Composes quaternaires de panthenol et utilisation desdits composes
WO1992019217A1 (fr) * 1991-05-04 1992-11-12 The Procter & Gamble Company Compositions cosmetiques
US5340570A (en) * 1991-11-18 1994-08-23 Shiseido Co., Ltd. Dispensing system for sprayable gel-type hair conditioner
DE4214652A1 (de) * 1992-05-02 1993-11-04 Henkel Kgaa Haarbehandlungsmittel
US5270035A (en) * 1992-05-21 1993-12-14 Lexin International Marketing Corporation Hair conditioner containing disodium cocoamphodiacetate
WO1993024101A1 (fr) * 1992-05-22 1993-12-09 The Procter & Gamble Company Compositions cosmetiques
DE9311095U1 (de) * 1993-07-24 1994-11-24 Goldwell Ag, 64297 Darmstadt Haarpflegemittel
DE4324962A1 (de) * 1993-07-24 1995-01-26 Goldwell Ag Haarpflegemittel
US5384118A (en) * 1993-09-13 1995-01-24 Lavalle; Lila S. Gel hairdressing composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999013821A1 (fr) * 1997-09-13 1999-03-25 Henkel Kommanditgesellschaft Auf Aktien Agents de soins capillaires pour traiter les fourches
US6569414B1 (en) 1997-09-13 2003-05-27 Henkel Kommanditgesellschaft Auf Aktien Hair conditioners for treating split ends

Also Published As

Publication number Publication date
DE4440315A1 (de) 1996-05-15

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