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WO1995004804A1 - Detergent sans phosphate ni chlore - Google Patents

Detergent sans phosphate ni chlore Download PDF

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Publication number
WO1995004804A1
WO1995004804A1 PCT/CH1994/000159 CH9400159W WO9504804A1 WO 1995004804 A1 WO1995004804 A1 WO 1995004804A1 CH 9400159 W CH9400159 W CH 9400159W WO 9504804 A1 WO9504804 A1 WO 9504804A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
detergent
citric acid
sodium
active substances
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CH1994/000159
Other languages
German (de)
English (en)
Inventor
Erna Eichenberger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to EP94922815A priority Critical patent/EP0663944A1/fr
Priority to AU72622/94A priority patent/AU7262294A/en
Publication of WO1995004804A1 publication Critical patent/WO1995004804A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds

Definitions

  • a further object of the invention was to obtain a phosphate- and chlorine-free detergent for dishwashers, which also meets all the requirements of water protection and has the necessary washing activity to completely remove all dirt on dishes and cutlery without attacking the wash ware .
  • the phosphate and chlorine-free detergents and dishwashing detergents according to the invention are defined in claim 1.
  • a preferred composition for such a textile detergent contains, in addition to the detergent substances and citric acid, a detergent-enhancing component (activator), alkali carbonates for setting the desired pH, alkali silicates, sequestering agents, optical brighteners, enzymes and optionally dyes and perfume.
  • a combination of amphoteric and non-ionic and / or anionic surface-active substances are preferably suitable as detergent substances for textile detergents.
  • preparations based on sodium lauryl sulfates such as the commercial product "Texapon” (Henkel AG) or natural soaps such as basic soap, or mixtures thereof, can be used as anionic surface-active substances.
  • Known products based on ethoxylene can be used as the non-ionic surface-active substance higher fatty alcohols, such as the "Lutensole” from BASF and others, and fatty alcohols are used.
  • Suitable amphoteric surface-active substances are, for example, the products sold under the "Ampholak” brand by Berol Nobel AB.
  • the detergent-active substances are advantageously present in a total amount of 10-50% by weight in the textile detergent according to the invention. Thanks to this combination of active washing substances, the washing power of the product is independent of the washing temperature; all the more so since there is no bleaching agent component which exerts its action only at elevated temperatures, for example above 60 ° C.
  • NTA can be added, especially in the form of its trinate salt as e.g. is available from BASF as "Trilon". In an amount of up to 10% by weight, it replaces the phosphates previously used and also acts as an antioxidant.
  • Citric acid or its salts should also be mentioned as a key component. In an amount of 1-20% by weight it ensures the good solubility of the detergent and at the same time acts as a sequestering agent.
  • the activator component preferably contains borates and / or perborates (commercially available sodium borate and / or perborate), and usually in an amount of 10-20% by weight.
  • Optical brighteners can also be used to support the activator component, usually in an amount of up to 1% by weight can be added.
  • the products available under the "Tinopal” brand from CIBA-GEIGY AG have proven themselves very well for this purpose.
  • proteases in particular a mixture of Savinase and Esperase, or also Alcalase, as well as lipases and aminolytic enzymes such as "Termamyl" have proven to be outstanding.
  • the named enzymes which are generally used in a total amount of 0.5-8% by weight, are available from Novo Nordisk Industrie, Copenhagen.
  • This agent which keeps the loosened dirt particles in suspension and, if the detergent is in the form of tablets, also contributes to their rapid disintegration in water, can be added in an amount of usually up to 8% by weight.
  • Zeolites generally in an amount of 5-40 wt% to increase the complexing effect for alkaline earth and Metal ions in the water. Suitable products are commercially available from Degussa.
  • Sodium carbonate and / or bicarbonate can be added in a total amount of 3-20% by weight in order to set the desired pH of about 10-12, preferably 10-11.
  • Fiber and corrosion protection agents As such, sodium metasilicate and disilicate are preferably used in an amount of 5-15% by weight.
  • the most important advantage of the detergents according to the invention is the complete absence of phosphates and chlorine and of fillers.
  • Textile washing agents are produced in a simple manner from the above-mentioned components.
  • the ingredients are mixed very well without the addition of solvents. of any kind.
  • a mixture A which contains the amphoteric and, if present, the anionic surface-active substances together with stabilizing and washing activity-enhancing agents, such as sodium carbonate and / or sodium bicarbonate, sodium silicate, carboxymethyl cellulose and zeolite.
  • stabilizing and washing activity-enhancing agents such as sodium carbonate and / or sodium bicarbonate, sodium silicate, carboxymethyl cellulose and zeolite.
  • mixture B is prepared from the nonionic surface-active substances using stabilizing agents which increase washing activity, such as sodium carbonate-sodium bicarbonate, carboxymethyl cellulose and zeolite.
  • the two mixtures A and B are then combined and combined with the remaining constituents, namely borate and / or perborate, enzymes, citric acid, optical brighteners and, if appropriate, perfume and dyes.
  • the free-flowing product obtained in this way generally tends to form lumps. It is therefore advisable to process it into tablets which are used in a preferred dosage of 12 g / kg dry laundry for machine and hand washing.
  • the powder mixture can be compressed into tablets without any further additives.
  • This form has several advantages over free-flowing powder mixtures. Their dosage is much simpler, the packaging, for example in the blister packs popular today, is impermeable to air and moisture, space-saving and environmentally friendly and enables the detergent to be used without being touched by the consumer.
  • the components are chosen such that the tablets easily disintegrate in contact with water and immediately dissolve completely in the wash liquor, even at low temperatures.
  • the tablets preferably have a weight of 12 g and a diameter of 30-32 mm, and are advantageously added directly to the laundry in the washing drum.
  • the agents according to the invention not only meet all official requirements with regard to environmental and water protection, they do not contain any harmful substances and have proven to be completely harmless to human and animal health, insofar as the usual ones Precautions and dosages are observed as they generally apply to household chores.
  • the detergents are harmless to all types of fabrics and fibers, protect even the most delicate textiles, do not attack textile colors and result in surprising removal of dirt and stains even in cold water, but much more at temperatures of 40-60 ° C . Comparative experiments with washing processes at 60 ° C and 95 ° C have shown that the laundry was not cleaned better or faster during cooking. Investigations are ongoing into the disinfectant effect of the detergents according to the invention.
  • a recommended composition of detergents is as follows (in percent by weight):
  • wash-active substances (amphoteric) 5-15, preferably 8-12
  • the invention further comprises a new detergent for dishwashers, which is based on the same principles, is completely free of phosphate and chlorine and has an excellent cleaning power with the utmost care for dishes (also with delicate decor), cutlery and glasses and a brilliant shine.
  • a suitable composition comprises, in% by weight:
  • This agent too, can advantageously be pressed without further addition to handy and easily dissolvable tablets of preferably 8 g.
  • One tablet is placed in the powder compartment of the dishwasher.
  • Amphoteric surfactants 10 ("Ampholak")
  • Noniogenic surfactants (“Dobanol”) 6.4
  • Components A and B were individually mixed well and then combined with the remaining components of component C.
  • the free-flowing powder obtained is compressed in the usual way to tablets of 12 g, with a diameter of 30-32 mm.
  • the dosage depends on the hardness of the water, but is generally 1 tablet à 12g / kg dry wash.
  • Amphoteric surfactants (“Ampholak”) 5 kg
  • Non-ionic surface-active agent (“Lutenol”) 3 kg
  • the tablets obtained were packed airtight; when used, they are placed directly in the powder compartment of the machine.
  • the dosage is based on the information provided by the machine manufacturer. Usually 1 tablet is sufficient for a normal wash.
  • the use of an additional Rinse aid can be recommended if the water hardness is high, but is not necessary in most cases.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

Les nouveaux produits sans danger pour l'environnement, à base de substances tensioactives non-iogènes et/ou anioniques à activité détergente contiennent en outre, des agents tensioactifs amphotères et de l'acide citrique ou ses sels, ainsi que d'autres substances auxiliaires. Grâce à leur haute activité détergente, la consommation de tels produits est très faible tant pour le nettoyage des textiles que pour celui de la vaisselle.
PCT/CH1994/000159 1993-08-06 1994-08-05 Detergent sans phosphate ni chlore Ceased WO1995004804A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP94922815A EP0663944A1 (fr) 1993-08-06 1994-08-05 Detergent sans phosphate ni chlore
AU72622/94A AU7262294A (en) 1993-08-06 1994-08-05 Phosphate and chlorine-free detergent

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH2359/93-6 1993-08-06
CH235993A CH686002A5 (de) 1993-08-06 1993-08-06 Phosphatfreies Waschmittel.

Publications (1)

Publication Number Publication Date
WO1995004804A1 true WO1995004804A1 (fr) 1995-02-16

Family

ID=4231961

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CH1994/000159 Ceased WO1995004804A1 (fr) 1993-08-06 1994-08-05 Detergent sans phosphate ni chlore

Country Status (5)

Country Link
EP (1) EP0663944A1 (fr)
AU (1) AU7262294A (fr)
CA (1) CA2145096A1 (fr)
CH (1) CH686002A5 (fr)
WO (1) WO1995004804A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0711827A3 (fr) * 1994-11-14 1996-11-13 Unilever Plc Compositions détergentes sous forme de tablettes
WO1998055582A1 (fr) * 1997-06-06 1998-12-10 Unilever Plc Compositions de nettoyage sous forme de tablette
WO2000023559A1 (fr) * 1998-10-21 2000-04-27 Henkel Kommanditgesellschaft Auf Aktien Combinaison emballage/corps façonnes d'agents de lavage et de nettoyage
EP3656838A1 (fr) * 2018-11-26 2020-05-27 Global Cosmed Group spolka akcyjna Détergent à lessive liquide

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3442812A (en) * 1965-11-26 1969-05-06 Colgate Palmolive Co Detergent bars
GB1379734A (en) * 1971-04-27 1975-01-08 Eldib Eng Research Inc Cleansing and laundering composition
EP0193386A2 (fr) * 1985-02-28 1986-09-03 The Procter & Gamble Company Compositions détergentes douces
JPH02269200A (ja) * 1989-04-07 1990-11-02 Kao Corp 浴室用洗浄剤組成物
EP0448297A1 (fr) * 1990-03-19 1991-09-25 Unilever Plc Compositions détergentes
US5061393A (en) * 1990-09-13 1991-10-29 The Procter & Gamble Company Acidic liquid detergent compositions for bathrooms
EP0462829A2 (fr) * 1990-06-20 1991-12-27 Rohm And Haas Company Composition détergente pour lave-vaisselle automatique
WO1992011346A1 (fr) * 1990-12-21 1992-07-09 Kommentus Ecogreen Aktiebolag Detergent et son procede de fabrication
WO1992018596A1 (fr) * 1991-04-19 1992-10-29 The Procter & Gamble Company Compositions detersives granulaires pour lessive, presentant une solubilite amelioree
WO1993004152A1 (fr) * 1991-08-16 1993-03-04 Kommentus Ecogreen Aktiebolag Detergent en poudre pour machines a laver la vaisselle et sa fabrication
DE4324358A1 (de) * 1992-07-24 1994-01-27 Colgate Palmolive Co Pflegeprodukt für den gesamten Körper mit synthetischem Reinigungsmittel
JPH06116596A (ja) * 1992-10-02 1994-04-26 Sanyo Chem Ind Ltd 洗浄剤組成物

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3442812A (en) * 1965-11-26 1969-05-06 Colgate Palmolive Co Detergent bars
GB1379734A (en) * 1971-04-27 1975-01-08 Eldib Eng Research Inc Cleansing and laundering composition
EP0193386A2 (fr) * 1985-02-28 1986-09-03 The Procter & Gamble Company Compositions détergentes douces
JPH02269200A (ja) * 1989-04-07 1990-11-02 Kao Corp 浴室用洗浄剤組成物
EP0448297A1 (fr) * 1990-03-19 1991-09-25 Unilever Plc Compositions détergentes
EP0462829A2 (fr) * 1990-06-20 1991-12-27 Rohm And Haas Company Composition détergente pour lave-vaisselle automatique
US5061393A (en) * 1990-09-13 1991-10-29 The Procter & Gamble Company Acidic liquid detergent compositions for bathrooms
WO1992011346A1 (fr) * 1990-12-21 1992-07-09 Kommentus Ecogreen Aktiebolag Detergent et son procede de fabrication
WO1992018596A1 (fr) * 1991-04-19 1992-10-29 The Procter & Gamble Company Compositions detersives granulaires pour lessive, presentant une solubilite amelioree
WO1993004152A1 (fr) * 1991-08-16 1993-03-04 Kommentus Ecogreen Aktiebolag Detergent en poudre pour machines a laver la vaisselle et sa fabrication
DE4324358A1 (de) * 1992-07-24 1994-01-27 Colgate Palmolive Co Pflegeprodukt für den gesamten Körper mit synthetischem Reinigungsmittel
JPH06116596A (ja) * 1992-10-02 1994-04-26 Sanyo Chem Ind Ltd 洗浄剤組成物

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch Week 9050, Derwent World Patents Index; Class A97, AN 90-372270 *
DATABASE WPI Section Ch Week 9421, Derwent World Patents Index; Class D21, AN 94-174021 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0711827A3 (fr) * 1994-11-14 1996-11-13 Unilever Plc Compositions détergentes sous forme de tablettes
WO1998055582A1 (fr) * 1997-06-06 1998-12-10 Unilever Plc Compositions de nettoyage sous forme de tablette
US6372707B1 (en) 1997-06-06 2002-04-16 Lever Brothers Company, Division Of Conopco, Inc. Cleaning compositions
WO2000023559A1 (fr) * 1998-10-21 2000-04-27 Henkel Kommanditgesellschaft Auf Aktien Combinaison emballage/corps façonnes d'agents de lavage et de nettoyage
EP3656838A1 (fr) * 2018-11-26 2020-05-27 Global Cosmed Group spolka akcyjna Détergent à lessive liquide
CN111218349A (zh) * 2018-11-26 2020-06-02 环球科诗美集团有限公司 液体衣物洗涤剂
US11365377B2 (en) 2018-11-26 2022-06-21 Global Cosmed Group spolka akcyjna Liquid laundry detergent comprising lauryl ether sulfate and bicarbonate/metasilicate mixture

Also Published As

Publication number Publication date
CH686002A5 (de) 1995-11-30
AU7262294A (en) 1995-02-28
EP0663944A1 (fr) 1995-07-26
CA2145096A1 (fr) 1995-02-16

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