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WO1994024860A1 - Compositions fongicides coulantes de bicarbonate - Google Patents

Compositions fongicides coulantes de bicarbonate Download PDF

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Publication number
WO1994024860A1
WO1994024860A1 PCT/US1994/001195 US9401195W WO9424860A1 WO 1994024860 A1 WO1994024860 A1 WO 1994024860A1 US 9401195 W US9401195 W US 9401195W WO 9424860 A1 WO9424860 A1 WO 9424860A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
accordance
ingredient
weight percent
bicarbonate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1994/001195
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English (en)
Inventor
Anthony E. Winston
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Church and Dwight Co Inc
Original Assignee
Church and Dwight Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Church and Dwight Co Inc filed Critical Church and Dwight Co Inc
Priority to AU66956/94A priority Critical patent/AU6695694A/en
Publication of WO1994024860A1 publication Critical patent/WO1994024860A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/04—Carbon disulfide; Carbon monoxide; Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants

Definitions

  • fungicide compositions which contain an inorganic bicarbonate or carbonate compound. It is known that bicarbonate and carbonate compounds exhibit fungicidal properties for agricultural purposes.
  • U.S. 1,560,558 discloses the use of salts such as lithium carbonate, sodium carbonate, sodium bicarbonate, potassium bicarbonate, potassium carbonate and ammonium bicarbonate as fungicide ingredients.
  • Japanese patent 53090319 describes the application of potassium bicarbonate as an active biocide for the control of fungal diseases common to tomato and cucumber plants.
  • Japanese patent 53118523 describes the combination of sodium bicarbonate and lecithin as an active agent for the control of agricultural and fruit storage fungus diseases.
  • Japanese patent 56043207 describes a biocidal composition containing sodium bicarbonate and a polyglycerol fatty acid ester. The biocide controls Penicillium di itatu on oranges,
  • Japanese patent 60097909 describes a soil fungicide prepared by admixing slaked lime with sodium bicarbonate, potassium bicarbonate, boric acid and phenolphthalein.
  • German patent DE 2927994 describes a fungicide which consists of sodium bicarbonate incorporated into a food-compatible surfactant such as saccharose laurate.
  • Japanese patent 57062208 describes horticultural fungicides in which the addition of sodium bicarbonate to polyoxin or thiophanatemethyl increases the fungicidal activity of the organic biocide against botrytis cinerea on cucumbers.
  • Japanese patent 58023609 describes an agricultural fungicide composed of a mixture of sodium bicarbonate or potassium bicarbonate with cupric hydroxide, basic copper carbonate or basic copper sulfate. The combination of ingredients exhibits a synergistic fungicidal effect against cucumber early blight, tomato wilt, rice sheath blight, rice blast and citrus canker.
  • It is another object of this invention to provide a dry blend fungicide composition which is a non-caking and free-flowing formulation, and which contains particulate ingredients comprising a bicarbonate salt, and a combination of fatty acid salt and hydrophilic polymer which functions as a spreader-sticker and film-forming medium when the composition is diluted with water and applied to plant foliage.
  • fungicide composition which is a dry blend formulation comprising (1) an ingredient selected from alkali metal and ammonium bicarbonates; (2) an ingredient selected from alkali metal and ammonium salts of C 10 -C 22 fatty acids; (3) a film- forming hydrophilic polymer ingredient; and (4) an anti-caking ingredient.
  • An invention dry blend fungicide composition can contain about 20-85 weight percent of bicarbonate ingredient, about 10-75 weight percent of C 10 -C 22 fatty acid salt ingredient, about 0.5-20 weight percent of hydrophilic polymer ingredient, and about 0.1-8 weight percent of anti-caking ingredient, based on the composition weight.
  • a dry blend fungicide composition can be diluted with water to form aqueous fungicidal solutions with controlled rheological properties.
  • An aqueous fungicidal solution typically contains less than about 5 weight percent of active ingredients, based on the solution weight. For most applications the content of bicarbonate ingredient is maintained at a concentration below about one weight percent, as a means of minimizing phytotoxic effects on treated plants which are sensitive to alkaline pH conditions.
  • An invention dry blend fungicide composition in finely divided form also can be utilized as a dusting powder, which optionally can include a solid diluent such as bentonite, gypsum, diatomaceous earth, and the like.
  • Plant foliage can be treated with a dusting powder, and ambient weather cycles and atmospheric conditions provide sufficient moisture to convert the applied dusting powder to an adherent coating on the plant foliage.
  • a dusting powder preferably has an average particle size diameter between about 1-100 microns, and has a content of submicron particles.
  • the inorganic salt ingredient of an invention fungicide composition is selected from compounds which include sodium bicarbonate, potassium bicarbonate and ammonium bicarbonate.
  • the inorganic salt ingredient can include an additional compound selected from sodium carbonate, potassium carbonate, lithium carbonate and ammonium carbonate, in a quantity of about 1-30 weight percent based on the weight of bicarbonate ingredient.
  • Illustrative of inorganic salt ingredients in a formulation are sodium, potassium or ammonium bicarbonate; or mixtures such as sodium bicarbonate and potassium bicarbonate; sodium bicarbonate and ammonium bicarbonate; potassium bicarbonate and ammonium bicarbonate; sodium bicarbonate, potassium bicarbonate and ammonium bicarbonate; sodium bicarbonate and potassium carbonate; potassium bicarbonate and potassium carbonate; and the like.
  • Multiple inorganic salt compounds can be utilized in a broad range of molar quantities relative to each other.
  • the molar quantity of a carbonate salt ingredient normally is determined by pH control considerations when dry blend formulations are being water-diluted.
  • the content of a carbonate salt compound can be varied to control the pH at a desired level in the range of 7.5-12. Water-diluted fungicidal formulations of the present invention tend to have a higher fungicidal activity at higher pH values.
  • the C 10 -C 22 fatty acid salt ingredient is selected from alkali metal and ammonium salts of natural straight chain and synthetic branched chain fatty acids, which have a saturated or unsaturated structure.
  • the C 10 -C 22 fatty acid salt ingredient can be incorporated in a quantity between about 10-75 weight percent, based on the weight of active ingredients in a composition.
  • Illustrative of natural fatty acids are capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, linoleic acid, arachidic acid, behenic acid, cetoleic acid, and the like.
  • the C 10 -C 22 fatty acid salt ingredient can consist of two or more saturated or unsaturated carboxylic acids such as those derived from beef and mutton tallow, lard, cottonseed oil, palm oil, and the like.
  • Palm fatty acid distillate is a commercial product produced by distilling the fatty acids present in natural palm oil.
  • a distillate product typically has the following weight percent content:
  • the iodine value is less than 54 and the melting point is about 45°C.
  • the content of peroxides is below 10 milliequivalents of oxygen per kilogram.
  • the fatty acids in the free fatty acids and the triglycerides consist of the following weight percent:
  • Beef tallow acids are available commercially as a byproduct obtained by alkaline extraction of waste beef fat and subsequent acidification, and normally contain the following weight percent of fatty constituents: Free fatty acids 60-90
  • the iodine value is less than 50 and the melting point is 40°-45°C.
  • the content of peroxides is less than 10 milliequivalents of oxygen per kilogram.
  • the fatty acids in the free fatty acids and in the triglycerides have the following weight percent content:
  • C 10 -C 22 fatty acids and glycerides are susceptible to atmospheric oxidation, it is advantageous to incorporate an antioxidant, and/or a chelating agent to bind any ferric, copper, zinc or other metal capable of catalyzing atmospheric oxidation.
  • Suitable quantities for inclusion in the fatty acid bulk are about 0.01-0.4% or higher of antioxidant as permitted by regulation, and/or about 0.05-0.3% of chelating agent, based on the weight of fatty acid.
  • an antioxidant and/or chelating agent can be added to a dry blend or aqueous fungicide composition as additional ingredients during the formulation stage.
  • Illustrative of preferred additives are butylated hydroxytoluene, butylated hydroxyanisole and tertiary-butylhydroquinone antioxidant, and citric acid and ethylenediamine tetraacetate chelating agents.
  • the chelating agent and antioxidant can be added per se, or in a solvent such as propylene glycol to facilitate incorporation into the fatty acid or formulated ingredients.
  • the hydrophilic polymer of an invention fungicide composition is selected from organic polymers which exhibit film-forming properties when an aqueous formulation is applied to plant foliage.
  • the term "hydrophilic” as employed herein refers to a water-soluble or water-dispersible organic polymer which has a solubility of at least one gram per 100 grams of water at 25°C.
  • CMC Sodium carboxymethyl cellulose
  • DS degree of substitution
  • the anti-caking ingredient of an invention fungicide composition is selected from particulate inorganic and organic compounds which are chemically unreactive with the other ingredients when the composition is in the form of a dry blend formulation.
  • a selected compound preferably has a particulate size distribution less than about 100 microns in diameter.
  • Suitable anti-caking ingredients include silicious compounds, magnesium compounds, C 10 -C 22 fatty acid polyvalent metal salt compounds, and the like.
  • anti-caking ingredients are attapulgite clay, kieselguhr, silica aerogel, silica xerogel, perlite, talc, vermiculite, sodium aluminosilicate, ammonium carbonate, zirconium oxychloride, starch, sodium or potassium phthalate, calcium silicate, calcium phosphate, calcium nitride, aluminum nitride, copper oxide, magnesium carbonate, magnesium silicate, magnesium nitride, magnesium phosphate, magnesium oxide, magnesium nitrate, magnesium sulfate, magnesium chloride, and the like.
  • Preferred anti-caking ingredients include magnesium silicate, and the magnesium, aluminum and calcium salts of C 1Q -C 22 fatty acids such as palmitic acid, stearic acid and oleic acid.
  • the use of magnesium silicate as an anti-caking ingredient has particular advantage for purposes of the present invention.
  • Magnesium silicate contributes excellent anti-caking and free-flowing properties to an invention dry blend formulation. Also, when a dry blend formulation is water-diluted, the alkaline pH and the presence of alkali metal compounds cause the conversion of some magnesium silicate to alkali metal silicate. The resultant alkali metal silicate exhibits strong adhesive activity when the aqueous formulation is applied to plant foliage.
  • the anti-caking ingredient normally is utilized in the least quantity which will effect the desired degree of anti-caking and free-flowing properties.
  • the anti-caking ingredient is incorporated in a dry blend formulation in a quantity between about 0.1-2 weight percent, based on the composition weight.
  • a preferred dry blend fungicide composition of the present invention is one containing sodium or potassium bicarbonate, sodium or potassium oleate, xanthan gum, and magnesium silicate ingredients.
  • the ingredients in an invention fungicide composition can be selected to include nitrogen, phosphorus and potassium elements in a ratio that qualifies the composition to function as a fertilizer in addition to its function as a fungicide, when applied to cultivated crops.
  • this invention provides a fungicidal fertilizer composition which is a dry blend formulation comprising (1) about 20-85 weight percent of an ingredient selected from alkali metal and ammonium bicarbonates; (2) about 10-75 weight percent of an ingredient selected from alkali metal and ammonium salts of C 1Q -C 22 fatty acids; (3) about 0.5-20 weight percent of a hydrophilic polymer ingredient; (4) about 0.1-8 weight percent of an anti-caking ingredient; and (5) about 20-65 weight percent of an ingredient selected from phosphorus-containing compounds; based on the composition weight; wherein the composition ingredients have a formulated ratio of nitrogen, phosphorus and potassium elements.
  • the formulated ratio depends on the intended application. A typical ratio is 10-15-10.
  • an invention fungicidal fertilizer composition can contain trace elements, and other essential elements as exemplified by sulfur as contained in a compound such as sodium bisulfite or thiourea.
  • a present invention fungicide composition can be prepared by dry-blending the particulate ingredients using conventional equipment.
  • the bicarbonate, fatty acid salt and hydrophilic polymer are pre-blended, and subsequently the anti-caking ingredient is added to the pre-blend in a rotating type mixer before any agglomeration of particles occurs.
  • the anti-caking ingredient is pre-blended with the hydrophilic polymer, and the pre-blend then is admixed with the other particulate ingredients.
  • the particulate ingredients of a dry blend fungicide composition tend to agglomerate on standing, and the free-flow character of the composition is diminished.
  • An invention fungicide composition can include one or more other biologically active ingredients, such as those which exhibit herbicidal, insecticidal or plant growth regulating activity.
  • a fungicide composition of the present invention has a novel combination of properties for the practice of pesticide control in agricultural and horticultural applications.
  • the bicarbonate ingredient exhibits fungicidal properties, and the efficiency of any additionally included organic pesticide ingredient usually is enhanced by the presence of the bicarbonate ingredient.
  • a lesser quantity of optional pesticide ingredient can be employed to achieve a desired degree of pest control.
  • a present invention fungicide composition can be formulated to exhibit no phytotoxicity, or to minimize the toxic effects of salt stress on plants by the bicarbonate ingredient.
  • a present invention fungicide composition provides particular advantage for the control of infectious phytopathogenic fungi which thrive under acidic soil conditions.
  • All of the fungicide composition ingredients are biocompatible when the composition is applied in an agricultural environment.
  • the bicarbonate, C 10 -C 22 fatty acid salt, hydrophilic polymer and anti-caking ingredients are all harmless to animals and humans.
  • a significant feature of a present invention dry blend fungicide composition is the presence of C 1Q -C 22 fatty acid salt and hydrophilic polymer ingredients, which function as a spreader-sticker medium when the fungicide composition is applied to plant foliage as a water-diluted solution.
  • An applied aqueous solution forms an adherent coating of ingredients on plant foliage or fruit.
  • the fatty acid salt ingredient aids in spreading and sticking the fungicide composition ingredients to the foliage or fruit to which it is applied.
  • the hydrophilic polymer ingredient increases the amount of aqueous fungicide composition which adheres to the plant surfaces because of its static high apparent viscosity.
  • the hydrophilic polymer ingredient contributes a low psuedoplastic viscosity to the spray solution, which facilitates the spraying action.
  • the applied coating resists drifting under wind conditions, and exhibits humectant properties in addition to enhanced fungicidal activity.
  • Another important advantage of a preferred invention fungicide composition derives from the water-solubility of the main ingredients. A coating of an invention fungicide composition on plant foliage or fruit can be removed readily by water-washing.
  • EXAMPLE I This Example illustrates the preparation of a fungicide powder composition in accordance with the present invention.
  • a free-flowing blend of the following ingredients is prepared in a cone mixer:
  • the formulated powder is diluted with water by dispersing 2 parts of the powder blend into 100 parts of water.
  • the resulting solution is sprayed onto plant foliage where it forms an adherent coating on the foliage surfaces.
  • the magnesium silicate is admixed with a pre-blend of the other ingredients to form a non-caking free-flowing powder.
  • the magnesium silicate has an average particle size of about 10 microns.
  • the powder is suspended in water to form an aqueous emulsion with a 0.3 weight percent content of potassium bicarbonate.
  • the diluted formulation is tested as a fungicide medium against plant foliage infected with powdery mildew.
  • the fungicidal medium is 100% effective in mildew eradication, and prevents re-infection.
  • EXAMPLE III This Example illustrates the preparation of a dry blend fungicidal formulation which contains a mixture of bicarbonate compounds and an anti-caking ingredient.
  • the particulate ingredients are dry blended to form a non-caking free-flowing powder.
  • the ingredients are added to the water to form an aqueous solution which has a 0.5 weight percent content of bicarbonate ingredients.
  • the formulation is more effective than a comparative formulation containing a single bicarbonate compound, for controlling a broad range of foliar and soil-born resistant fungi.
  • EXAMPLE IV This Example illustrates the_preparation of a fungicidal fertilizer composition for application to plant foliage and soil. Parts sodium bicarbonate 20 potassium oleate 20 potassium octanoate 10 xanthan gum 4 ammonium nitrate 15 dipotassium orthophosphate 5 magnesium stearate 1
  • the zinc sulfide (0.1-10 micron range) is pre-blended with the particulate ammonium nitrate ingredient, and the pre-blend then is combined with the other ingredients in a rotatory mixer to form a non-caking free-flowing powder.
  • the powder is dispersed in water to form a solution which has a 0.5 weight percent content of potassium bicarbonate.
  • a container of the solution is connected to agricultural sprayer equipment, and sprayed through a hollow cone spray nozzle at a pressure of 250 psi.
  • the spray droplet size is 100-150 microns.
  • a field of ornamental evergreen saplings is sprayed with the solution, and is effective for preventing fungal infection of the trees, and for promoting vigorous growth.

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  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Une composition fongicide contient des ingrédients biocompatibles pour des applications agricoles et inoffensifs pour des animaux et des êtres humains. La composition fongicide décrite sous forme d'un mélange sec ne s'agglutine pas et reste coulante pendant le stockage. Un mode de réalisation de la composition fongicide décrite est une préparation qui contient du bicarbonate de sodium, du bicarbonate de potassium, de l'oléate de potassium et de la gomme xanthane. La combinaison d'oléate de potassium et de gomme xanthane constitue un milieu filmogène et étaleur-adhésif efficace lorsque l'on dilue la composition avec de l'eau pour des applications agricoles. Lorsque le milieu aqueux est de l'eau dure, il se forme de l'oléate de calcium, ce qui améliore les propriétés adhésives de la composition fongicide aqueuse dans des applications agricoles.
PCT/US1994/001195 1993-04-23 1994-02-08 Compositions fongicides coulantes de bicarbonate Ceased WO1994024860A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU66956/94A AU6695694A (en) 1993-04-23 1994-02-08 Free-flowing bicarbonate fungicide compositions

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US5225493A 1993-04-23 1993-04-23
US052,254 1993-04-23

Publications (1)

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WO1994024860A1 true WO1994024860A1 (fr) 1994-11-10

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WO (1) WO1994024860A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1382245A4 (fr) * 2001-04-27 2004-06-09 Ishihara Sangyo Kaisha Procede pour prevenir la consolidation d'un ingredient chimique actif agricole
EP2204095A1 (fr) 2008-12-23 2010-07-07 Basf Se Cristaux mélangés, leur procédé de fabrication et d'utilisation dans la fabrication de produits cuits
AU2005321984B2 (en) * 2004-12-27 2011-06-09 Indorama Ventures Oxides Australia Pty Limited Reduced foam dispersions and formulations therefor
RU2598632C1 (ru) * 2015-03-23 2016-09-27 Виталий Богданович Черногиль Органоминеральное удобрение

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1560558A (en) * 1925-09-11 1925-11-10 Harry R Fulton Process for prevention of decay of citrous fruits
US3920844A (en) * 1974-06-10 1975-11-18 Nat Patent Dev Corp Chlorinated diaromatic-substituted aminoalkanes as fungicides and insecticides
JPS5396319A (en) * 1977-01-31 1978-08-23 Tokyo Yuuki Kagaku Kougiyou Kk Disease protecting agent for agriculture and horticulture
US4424213A (en) * 1980-11-10 1984-01-03 Sds Biotech Corporation Biologically active heterobicyclic hydroximidates and thiolhydroximidates and carbamate ester derivatives thereof
JPS60153785A (ja) * 1984-01-24 1985-08-13 Nippon Micro-Bu Kagaku Kk 食品等の腐敗防止並びに人体に対する医療効果を有する薬剤
US4556661A (en) * 1981-09-01 1985-12-03 Hoffmann-La Roche Inc. Pyridine derivatives
US4599233A (en) * 1978-07-13 1986-07-08 Rikagaku Kenkyusho Agricultural and horticultural fungicide and fruit storage disease preventing agent and process for production thereof
US4692466A (en) * 1985-02-28 1987-09-08 Mitsui Toatsu Chemicals, Incorporated N-(2-chloro-4-trifluoromethylphenyl)-3-trifluoromethylbenzenesulfonamide derivative and agricultural fungicide containing same
US5030658A (en) * 1988-05-04 1991-07-09 Safer, Inc. Enhanced activity arthropodicidal solution
US5093124A (en) * 1989-11-20 1992-03-03 Safer, Inc. Fatty acid-based pesticide with reduced phytotoxicity

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1560558A (en) * 1925-09-11 1925-11-10 Harry R Fulton Process for prevention of decay of citrous fruits
US3920844A (en) * 1974-06-10 1975-11-18 Nat Patent Dev Corp Chlorinated diaromatic-substituted aminoalkanes as fungicides and insecticides
JPS5396319A (en) * 1977-01-31 1978-08-23 Tokyo Yuuki Kagaku Kougiyou Kk Disease protecting agent for agriculture and horticulture
US4599233A (en) * 1978-07-13 1986-07-08 Rikagaku Kenkyusho Agricultural and horticultural fungicide and fruit storage disease preventing agent and process for production thereof
US4424213A (en) * 1980-11-10 1984-01-03 Sds Biotech Corporation Biologically active heterobicyclic hydroximidates and thiolhydroximidates and carbamate ester derivatives thereof
US4556661A (en) * 1981-09-01 1985-12-03 Hoffmann-La Roche Inc. Pyridine derivatives
JPS60153785A (ja) * 1984-01-24 1985-08-13 Nippon Micro-Bu Kagaku Kk 食品等の腐敗防止並びに人体に対する医療効果を有する薬剤
US4692466A (en) * 1985-02-28 1987-09-08 Mitsui Toatsu Chemicals, Incorporated N-(2-chloro-4-trifluoromethylphenyl)-3-trifluoromethylbenzenesulfonamide derivative and agricultural fungicide containing same
US5030658A (en) * 1988-05-04 1991-07-09 Safer, Inc. Enhanced activity arthropodicidal solution
US5093124A (en) * 1989-11-20 1992-03-03 Safer, Inc. Fatty acid-based pesticide with reduced phytotoxicity

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
FARM CHEMICALS HANDBOOK '87, published 1987, by MEISTER PUBLISHING CO. (OHIO), see Section C: Pesticide Dictionary, pages C228 & C236. *
VAN NOSTRAND REINHOLD ENCYCLOPEDIA OF CHEMISTRY, 4th Ed., published 1984, by VAN NOSTRAND REINHOLD COMPANY, INC. (NY), see page 85. *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1382245A4 (fr) * 2001-04-27 2004-06-09 Ishihara Sangyo Kaisha Procede pour prevenir la consolidation d'un ingredient chimique actif agricole
AU2005321984B2 (en) * 2004-12-27 2011-06-09 Indorama Ventures Oxides Australia Pty Limited Reduced foam dispersions and formulations therefor
EP2204095A1 (fr) 2008-12-23 2010-07-07 Basf Se Cristaux mélangés, leur procédé de fabrication et d'utilisation dans la fabrication de produits cuits
US9894905B2 (en) 2008-12-23 2018-02-20 Basf Se Mixed crystals, method for the production thereof and use thereof in the production of baked goods
US10609931B2 (en) 2008-12-23 2020-04-07 Basf Se Mixed crystals, method for the production thereof and use thereof in the production of baked goods
RU2598632C1 (ru) * 2015-03-23 2016-09-27 Виталий Богданович Черногиль Органоминеральное удобрение

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