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WO1994002676A1 - Produit auxiliaire pour le passage au tumbler - Google Patents

Produit auxiliaire pour le passage au tumbler Download PDF

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Publication number
WO1994002676A1
WO1994002676A1 PCT/EP1993/001824 EP9301824W WO9402676A1 WO 1994002676 A1 WO1994002676 A1 WO 1994002676A1 EP 9301824 W EP9301824 W EP 9301824W WO 9402676 A1 WO9402676 A1 WO 9402676A1
Authority
WO
WIPO (PCT)
Prior art keywords
tumble
aid according
auxiliary
acid
auxiliaries
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP1993/001824
Other languages
German (de)
English (en)
Inventor
Rolf Puchta
Peter Sandkühler
Jutta Schreiber
Theodor Völkel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of WO1994002676A1 publication Critical patent/WO1994002676A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/047—Arrangements specially adapted for dry cleaning or laundry dryer related applications
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/65—Mixtures of anionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/405—Acylated polyalkylene polyamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/667—Neutral esters, e.g. sorbitan esters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Definitions

  • the present invention relates to a fabric softening agent for treating textiles in a tumble dryer with a rotating drum.
  • Fabric softening agents for use in automatic household laundry dryers with a rotating drum have become known around the end of the 1960s. Such fabric softening agents often consist of a more or less absorbent substrate impregnated with textile softeners and, if appropriate, with auxiliaries and additives, which is generally present as a sheet. Such fabric softening agents are described, for example, in DE-A-1965470 and DE-A-3003249. DE-A-3818013 also describes fabric softening agents for use in the tumble dryer.
  • the impregnated fabrics together with the still moist, freshly washed laundry, are placed in the drum of the tumble dryer, where they are under the conditions of laundry drying, ie with constantly renewed contact with the textiles and in contact with Give heated air a more or less large proportion of its softening active ingredients and auxiliary substances and transfer them to the washed textiles.
  • a class of textile plasticizers which is advantageous in this respect are quaternary ammonium compounds which contain groups which are easily cleavable, in particular ester groups, in their long residues.
  • the object of the present invention was therefore to provide a tumbling aid comprising a cationic fabric softener which is derived from alkanolamines which may be substituted by short-chain alkyl chains and which contain one, two or three acyloxyalkyl groups and which, together with auxiliaries, are flexible sheet-like substrate are applied in such a way that a desirable high production output is ensured by an early start of crystallization during production.
  • a tumbling aid comprising a cationic fabric softener which is derived from alkanolamines which may be substituted by short-chain alkyl chains and which contain one, two or three acyloxyalkyl groups and which, together with auxiliaries, are flexible sheet-like substrate are applied in such a way that a desirable high production output is ensured by an early start of crystallization during production.
  • a tumble aid comprising a flexible sheet-like substrate coated with cationic fabric softeners and auxiliary substances, characterized in that quaternary ammonium compounds derived from alkanolamines and containing one, two or three acyloxyalkyl groups and as auxiliary substances
  • Fat derivatives selected from the group consisting of fatty acid, fatty alcohol and fatty acid esters with glycerol or fatty alcohol are used, with the proviso that the mixture containing textile softening agents and auxiliary substances has an onset of crystallization, measured with a differential scanning calorimeter (DSC) at a cooling rate of 10 ° C per minute, of more than 45 ° C, preferably more than 55 ° C.
  • DSC differential scanning calorimeter
  • the acyl groups of the quaternary ammonium compounds are derived from saturated or unsaturated carboxylic acids having 10 to 22 carbon atoms, in particular from tallow fatty acid, from oleic acid, from coconut oil fatty acid or from rapeseed oil fatty acid.
  • Typical representatives of this class of compounds are, for example, from DE-A-1699058, DE-A-17 94068 DE-A-1935499 and DE-B-2430 140 known compounds of the type dimethyl di (2-acyloxyalkyl) ammonium methosulfate.
  • the molecule may contain C2- to C4-alkyl or hydroxyalkyl groups, which may also be alkoxylated.
  • the anion can, for example, also be the chloride, bromide or ethyl sulfate anion or be derived from phosphoric acid.
  • the acyl groups are bonded to the nitrogen atom via oxyalkyl groups with 2 to 4 carbon atoms. In the case of oxyalkyl groups with 3 or 4 carbon atoms, the carbon chain can be linear or branched.
  • Quaternary ammonium compounds which are a mixture of quaternary ammonium compounds with one, two and three acyloxyalkyl groups, in which compounds with two acyloxyalkyl groups predominate, are of particular importance as textile softeners.
  • Acyloxyalkyl groups above all include acyloxymethyl, acyloxyethyl, acyloxy-n-propyl and acyloxy-i-propyl groups.
  • Particularly valuable textile softeners have the idealized structure of Formula I.
  • R - C0 - AR Cg / C 2 iAlkyl -
  • the fabric softeners consist of mixtures of compounds of the above formula I.
  • the optionally substituted alkanolamines from which the quaternary ammonium compounds are derived are preferably N-mono- or NN-dimethyl- or -ethyl- or -n-propyl- or -i-propyl-alkanolamines and in particular triethanolamine questionable.
  • the mixture consisting of fabric softener and auxiliary substances (1) additionally contains at least one organic acid which is solid at room temperature, preferably in amounts of 0.5 to 8% by weight, based on that of textile softener and auxiliary substance existing mixture, contains.
  • the weight ratio of textile softener and auxiliaries is greater than 1. It is preferred if the weight ratio is in the range from 2: 1 to 15: 1. Although in many cases it is possible to produce impregnating compositions with a sufficiently high start of crystallization using a textile softener and an auxiliary (1) of the type mentioned, it is often of further advantage if the impregnating composition of the tumble aid according to the invention is used as a further auxiliary (2 ) additionally compounds from the polyethylene glycol, condensation products of natural fats or fatty acids with polyamines or hydroxyalkyl polyamines and fatty acid / pentaerythritol esters comprising the group, preferably in the weight ratio of auxiliary (1) to auxiliary (2) from 5: 1 to 1 : 5 contains. For economic reasons, it is appropriate that the substrate is loaded with as much active ingredient and auxiliary as possible; a weight ratio of substrate to mixture of active ingredients and auxiliaries of 1: 1 to 1: 4 is preferred.
  • the tumble aid according to the invention can additionally contain textile-softening clays of the smectite type as a further, likewise textile-softening active ingredient.
  • Smectite clays are known textile plasticizers of the layered silicate type.
  • the proportion of layered silicas of the type mentioned, based on the mixture consisting of textile plasticizers of the quaternary ammonium compound type and auxiliary substances, is in the range from 0.5 to 15% by weight.
  • the impregnating composition can also contain other auxiliaries or additives, for example dispersants or emulsifiers.
  • Addition products of 4 to 40, preferably 4 to 20 moles of ethylene oxide and / or propylene oxide to one mole of an aliphatic C 1 -C 2 -alcohol or an alkyl phenol in which the alkyl radical 8 to 18 are suitable are primarily suitable for this purpose Has carbon atoms and fatty acids or alkylamines with 10 to 20 carbon atoms.
  • Particularly preferred are the ethoxylation products of the fatty alcohols, in particular the coconut and tallow fatty alcohols as well as the cetyl and oleyl alcohol, and the ethoxylation products of the oxo alcohols and the secondary alcohols of the corresponding chain length.
  • suitable dispersants or emulsifiers are nonionic, water-soluble, addition products containing 20 to 250 ethylene glycol ether groups and 10 to 100 propylene glycol ether groups of ethylene oxide onto propylene glycol or onto alkylenediamine polypropylene glycol or onto alkyl polypropylene glycol with 1 to 10 carbon atoms, in which the Polypropylene glycol chain acts as a hydrophobic residue.
  • the products can additionally contain 0.5 to 5% by weight of dispersing and softening polyglycol ethers.
  • Suitable polyglycol ethers are derived from ethylene oxide and have a molecular weight in the range from 200 to 8000, preferably in the range from 200 to 1000 and in particular in the range from 400 to 600.
  • Other additives having a dispersing action are addition products of ethylene oxide and / or propylene oxide onto fatty alcohols , Fatty amines, fatty acid or sulfonic acid amides.
  • anti-microbial agents i. H. contain bactericidal and bacteriostatic or fungicidal or fungistatic compounds.
  • Active ingredients for soil-release finishing for textiles may also be present, which improve the ability to remove dirt during washing.
  • These include compounds of the polyacrylic polyphenyl alcohol type, modified fluorocarbons and hydrophilic polymers.
  • Paraffins or also borax are suitable as additives which facilitate the ironing of the laundry, additives such as talc, finely divided zeolites, aerosil or aluminum oxide occasionally improve the shelf life or make the handling of the tumbling aids according to the invention more pleasant.
  • the substrate is a paper or a woven or non-woven Cloth made of natural or synthetic fibers or a foam-like sheet.
  • Suitable fibers for the production of the substrates mentioned are, above all, fibers made of cellulose, polyester, polyolefin, polyacrylonitrile, polyamide, polyurethane or viscose or their mixtures with one another. Natural sponges or synthetic foams, in particular made of polyurethane, are also suitable.
  • the impregnating composition consisting of textile softeners and auxiliaries and optionally additives can be applied to the substrate in any desired manner, for example by spraying or by soaking the nonwoven, the application of a certain amount or improving the uniformity of the application impregnated substrates can then be treated, for example, by squeezing in a roll nip.
  • the non-volatile constituents are melted, applied to the substrate and then optionally volatile constituents, for example fragrances, are added.
  • About 30 to about 200 g of impregnating composition are applied per m 2 of substrate.
  • the impregnating composition solidifies, it being important according to the invention that the mixture containing the textile softener and the auxiliaries starts to crystallize, measured with a differential scanning calorimeter (DSC) at a cooling rate of 10 ° C per minute, of more than 45 ° C, preferably of more than 55 ° C. This requirement ensures a sufficiently high production output.
  • DSC differential scanning calorimeter
  • the table shows that the mixtures of recipes 1 and 2 solidify immediately after application in accordance with their start of crystallization above 45 ° C. during production, and thus no reduction in the Make positioning speed necessary, whereas a mixture without auxiliary requires an unreasonably long drying time corresponding to the start of crystallization below 45 ° C.
  • Another advantage of the formulations 1 and 2 according to the invention is that the active substance release rate, at 92 or 96%, is significantly better than that of the comparison formulation without an auxiliary.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Produit auxiliaire pour le passage au tumbler, comprenant un substrat qui est imprégné d'une matière active d'assouplissement des textiles constituée d'un mélange de composés d'ammonium quaternaire à groupes acyloxyalkyle à chaînes longues, et de produits auxiliaires déterminés, ledit mélange présentant, au refroidissement, un début de cristallisation à plus de 45 °C. Le produit auxiliaire selon l'invention offre des avantages sur le plan de sa fabrication et de son utilisation.
PCT/EP1993/001824 1992-07-21 1993-07-12 Produit auxiliaire pour le passage au tumbler Ceased WO1994002676A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19924224067 DE4224067A1 (de) 1992-07-21 1992-07-21 Tumblerhilfsmittel
DEP4224067.0 1992-07-21

Publications (1)

Publication Number Publication Date
WO1994002676A1 true WO1994002676A1 (fr) 1994-02-03

Family

ID=6463771

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1993/001824 Ceased WO1994002676A1 (fr) 1992-07-21 1993-07-12 Produit auxiliaire pour le passage au tumbler

Country Status (2)

Country Link
DE (1) DE4224067A1 (fr)
WO (1) WO1994002676A1 (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994014935A1 (fr) * 1992-12-23 1994-07-07 Henkel Kommanditgesellschaft Auf Aktien Dispersions aqueuses d'adoucissants textiles
WO1995027777A1 (fr) * 1994-04-07 1995-10-19 Unilever Plc Composition assouplissante pour textiles
US5773409A (en) * 1994-04-07 1998-06-30 Lever Brothers Company, Division Of Conopco, Inc. Fabric softening composition
WO1999015612A1 (fr) * 1997-09-25 1999-04-01 The Procter & Gamble Company Composition assouplissante ajoutee dans le seche-linge, comprenant un piegeur de chlore et destinee a respecter les couleurs des textiles et a les doter d'autres qualites
WO1999015611A1 (fr) * 1997-09-25 1999-04-01 The Procter & Gamble Company Utilisation d'une composition assouplissante ajoutee dans le seche-linge et destinee a respecter les couleurs des textiles et a leur donner un bel aspect
WO2000077134A3 (fr) * 1999-06-12 2001-04-05 Henkel Kommandigesellschaft Au Utilisation de polyethylenes partiellement oxydes en tant qu'auxiliaires de repassage dans des assouplissants textiles liquides aqueux
WO2004052971A1 (fr) * 2002-12-11 2004-06-24 Kimberly-Clark Worldwide, Inc. Procede de traitement d'un article elastomere

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0854907A1 (fr) * 1996-01-05 1998-07-29 Stepan Company Articles et procedes pour traiter des tissus en fonction de leurs compositions d'ammonium quaternaire d'acyloxyalkyle
US6906025B2 (en) 1996-01-05 2005-06-14 Stepan Company Articles and methods for treating fabrics based on acyloxyalkyl quaternary ammonium compositions

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1571527A (en) * 1976-01-09 1980-07-16 Procter & Gamble Fabric treatment compositions
DE3608093A1 (de) * 1986-03-12 1987-09-17 Henkel Kgaa Konfektioniertes textilweichmacher-konzentrat
EP0345495A2 (fr) * 1988-05-27 1989-12-13 Henkel Kommanditgesellschaft auf Aktien Agent adoucissant pour tissus
WO1993003132A1 (fr) * 1991-08-03 1993-02-18 Henkel Kommanditgesellschaft Auf Aktien Produit de traitement de linge pour seche-linge

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1571527A (en) * 1976-01-09 1980-07-16 Procter & Gamble Fabric treatment compositions
DE3608093A1 (de) * 1986-03-12 1987-09-17 Henkel Kgaa Konfektioniertes textilweichmacher-konzentrat
EP0345495A2 (fr) * 1988-05-27 1989-12-13 Henkel Kommanditgesellschaft auf Aktien Agent adoucissant pour tissus
WO1993003132A1 (fr) * 1991-08-03 1993-02-18 Henkel Kommanditgesellschaft Auf Aktien Produit de traitement de linge pour seche-linge

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994014935A1 (fr) * 1992-12-23 1994-07-07 Henkel Kommanditgesellschaft Auf Aktien Dispersions aqueuses d'adoucissants textiles
WO1995027777A1 (fr) * 1994-04-07 1995-10-19 Unilever Plc Composition assouplissante pour textiles
AU682952B2 (en) * 1994-04-07 1997-10-23 Unilever Plc Fabric softening composition
US5700387A (en) * 1994-04-07 1997-12-23 Lever Brothers Company, Division Of Conopco, Inc. Fabric softening composition
US5773409A (en) * 1994-04-07 1998-06-30 Lever Brothers Company, Division Of Conopco, Inc. Fabric softening composition
WO1999015612A1 (fr) * 1997-09-25 1999-04-01 The Procter & Gamble Company Composition assouplissante ajoutee dans le seche-linge, comprenant un piegeur de chlore et destinee a respecter les couleurs des textiles et a les doter d'autres qualites
WO1999015611A1 (fr) * 1997-09-25 1999-04-01 The Procter & Gamble Company Utilisation d'une composition assouplissante ajoutee dans le seche-linge et destinee a respecter les couleurs des textiles et a leur donner un bel aspect
WO2000077134A3 (fr) * 1999-06-12 2001-04-05 Henkel Kommandigesellschaft Au Utilisation de polyethylenes partiellement oxydes en tant qu'auxiliaires de repassage dans des assouplissants textiles liquides aqueux
WO2004052971A1 (fr) * 2002-12-11 2004-06-24 Kimberly-Clark Worldwide, Inc. Procede de traitement d'un article elastomere
US6887542B2 (en) 2002-12-11 2005-05-03 Kimberly-Clark Worldwide, Inc. Method for treating an elastomeric article

Also Published As

Publication number Publication date
DE4224067A1 (de) 1994-01-27

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