[go: up one dir, main page]

WO1994001078A1 - Preparations capillaires cosmetiques - Google Patents

Preparations capillaires cosmetiques Download PDF

Info

Publication number
WO1994001078A1
WO1994001078A1 PCT/EP1993/001627 EP9301627W WO9401078A1 WO 1994001078 A1 WO1994001078 A1 WO 1994001078A1 EP 9301627 W EP9301627 W EP 9301627W WO 9401078 A1 WO9401078 A1 WO 9401078A1
Authority
WO
WIPO (PCT)
Prior art keywords
hair
preparations
carbon atoms
preparations according
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP1993/001627
Other languages
German (de)
English (en)
Inventor
Horst Höffkes
Kurt Seidel
Reinhard Müller
Christian Priebe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of WO1994001078A1 publication Critical patent/WO1994001078A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5428—Polymers characterized by specific structures/properties characterized by the charge amphoteric or zwitterionic

Definitions

  • the invention relates to hair cosmetic preparations for cleaning and / or grooming hair which contain a special binary combination of active ingredients.
  • quaternary ammonium compounds commonly used as cationic surfactants are only insufficiently biodegradable, so that their use should be reduced as much as possible for ecological reasons.
  • the invention therefore relates to hair cosmetic preparations based on conventional constituents for cleaning and / or grooming hair, comprising an active ingredient combination of (A) an amphopolymer and (B) a fatty acid ester of formula R1-C00R2, wherein
  • R 1 is a saturated or unsaturated, linear or branched alkyl radical having 8 to 22 carbon atoms and
  • R is a saturated or unsaturated, linear or branched alkyl radical having 1 to 12 carbon atoms or a group (CHR 3 -C00) n M, where R is a saturated or unsaturated, linear or branched alkyl radical having 1 to 4 C atoms, n is an integer from 1 to 5 and M is hydrogen, an alkali metal, an alkaline earth metal, aluminum or an alkyl or alkylolam onium group with 1 to 4 C atoms in each alkyl or alkylol group.
  • the preparations according to the invention bring about good wet combability of hair while at the same time increasing dry combability. This requires both a significant improvement in hair styling when wet, as well as an increase in hairstyle hold when dry.
  • the preparations according to the invention improve the curl retention and the bounce of wavy hair. Last but not least, when applied to colored hair, pronounced color protection is achieved with good leveling. In addition, the color gloss is increased. The observed effects are surprisingly greater in the mixtures according to the invention than in preparations which contain only one of the components.
  • An amphopolymer (A) is understood to mean polymers which contain both free amino groups and free -C00H or SO3H groups in the molecule and are capable of forming internal salts, zwitterionic polymers which group quaternary ammonium groups in the molecule and -C00 "or -S ⁇ 3" groups, and such polymers containing -C00H or SC ⁇ H groups and quaternary ammonium groups.
  • amphopolymer that can be used according to the invention is the acrylic resin available under the name Amphomer ⁇ , which is a copolymer of tert-butylaminoethyl methacrylate, N- (1,1,3,3-tetramethylbutyl) acrylate and two or more monomers represents from the group acrylic acid, methacrylic acid and their simple esters.
  • Amphomer ⁇ is a copolymer of tert-butylaminoethyl methacrylate, N- (1,1,3,3-tetramethylbutyl) acrylate and two or more monomers represents from the group acrylic acid, methacrylic acid and their simple esters.
  • Ampho-polymers used with particular preference are those polymers which essentially consist of one another
  • R -CH CR5-C0-X- (C n H2n) -N ( + ) R 6 R 7 R 8 ⁇ ( " ) (i)
  • R 4 and R - independently of one another stand for hydrogen or a methyl group and R-, R7 and R 8 independently of one another for alkyl groups with 1 to 4 carbon atoms, X an NH group or an oxygen atom, n an integer from 2 to 5 and ⁇ (") is the anion of an organic or inorganic acid
  • R9-CH CR10_C00H (ii) in which R9 and R ⁇ ⁇ are independently hydrogen or methyl groups.
  • monomer (b) for the mentioned polymers acrylic acid is preferably used.
  • the active ingredients (A) are contained in an amount of 0.05 to 5% by weight, based on the entire preparation. Concentrations of 0.1 to 3% by weight are preferred.
  • those compounds are used as fatty acid esters (B) in which the radical R 2 is (CHR 3 -C00) n M; R and M have the meaning given above, n stands for an integer from 1 to 3.
  • the active ingredients (B) are present in an amount of 0.1 to 10% by weight, based on the entire preparation. Concentrations of 0.5 to 5% by weight are preferred.
  • mixtures according to the invention additionally contain a cationic surfactant (C).
  • C cationic surfactant
  • (C) are quaternary ammonium compounds.
  • Suitable quaternary ammonium compounds are, for example, alkyltrimethylammonium salts with 12-22 carbon atoms in the optionally substituted alkyl chain, such as e.g. Hexadecyltrimethylammoniumsalze and Ricinolklaropylamidotrimethylam oniumsalze, and Dialkyldimethylammoniumsalze with 2-22 C atoms in the optionally substituted alkyl chain such as e.g.
  • polyoxyethylstearylammonium salts penta (oxyethylene) octadecylammonium salts, bis-tallowacylaminoethyl-2-hydroxyethyl-methyl-a monium salts, di- (tallow carboxyethyl) -hydroxyethyl-methylammonium-methosulfate, cocospentaethoxy-methylethyl-3-ammonium acylamino-salts, linium salts, tallow alkylamidoethyl-methyl-2-tallowalkylimidazolinium salts, bis-oleylamidoethyl-2-oleylimidazolinium salts and alkylamidoethyl-methyl-alkylimidazolinium salts.
  • Trialkylmethylammonium chloride e.g. B. Tricetylmethylammonium chloride, also Glucquat 100 (CTFA-Na- e: lauryl-methyl gluceth-10-hydroxypropyl-dimonium-chloride).
  • Compounds of the alkyl pyridiniu salt type such as lauryl pyridinium salts, are also suitable.
  • the alkyl and acyl groups contained in the compounds mentioned usually have about 12 to 22 carbon atoms.
  • halide ions in particular chloride and bromide ions, lactate ions, methosulfate ions, ethosulfate ions, phosphate ions, hydrogen and dihydrogen phosphate ions, saccharinate ions and acetate ions can act as counterions in these salts.
  • the cationic surfactants (C) are preferably present in the preparations according to the invention in an amount of 0.05 to 5, in particular 0.1 to 3% by weight, based on the preparation as a whole.
  • Celquat R Quaternized cellulose derivatives, as are commercially available under the names Celquat R and Polymer JR R.
  • the compounds Celquat H 100, Celquat L 200 and polymer JR R 400 are preferred quaternized cellulose derivatives.
  • the cationic polymers (D) are preferably present in the preparations according to the invention in an amount of 0.05 to 5, in particular 0.1 to 3,% by weight, based on the preparation as a whole.
  • aqueous emulsions can be influenced in a targeted manner by adding so-called thickeners. It may therefore be desirable for the emulsions according to the invention to contain 0.1 to 10% by weight, preferably 0.5 to 5% by weight, of a thickener in order to set a viscosity suitable for the particular application. It is again preferred to use thickeners of natural origin. Such are e.g. Polysaccharides, in particular xanthan gum, guar gum, agar agar, alginates and tyloses, locust bean gum and pectins.
  • carboxymethyl cellulose methyl hydroxypropyl cellulose and hydroxyethyl cellulose, higher molecular weight polyethylene glycol mono- and diesters of fatty acids, polyacrylates, polyvinyl alcohol and polyvinyl pyrrolidone are suitable as thickeners.
  • inorganic electrolyte salts can also be used as thickeners.
  • the chlorides or sulfates of an alkali metal, ammonium or magne- siu s used; sodium chloride and magnesium chloride are particularly preferred.
  • the amount of the electrolyte salt is preferably 0.1 to 10% by weight, in particular 0.2 to 5% by weight.
  • the skin-protecting properties of the agents according to the invention come into their own when they are formulated in such a way that they have a pH close to the neutral point of the skin. Agents with pH values in the range from 2.5 to 7.5, in particular from 3.5 to 5.8, are therefore preferred.
  • the preferred acidic setting of the agents according to the invention already has a positive effect on their durability.
  • additional preservatives can be used. Suitable for this purpose are, for example, formic acid, propionic acid, salicylic acid, benzoic acid, sorbic acid, cinnamic acid and their esters and salts, furthermore menthol, thymol, eugenol and lemon grass extract as well as the substances listed in the annex to the Cosmetics Regulation.
  • the preservatives are usually used in the hair treatment emulsions in amounts of 0.1 to 2% by weight.
  • the use of benzoic acid as a preservative is particularly preferred.
  • the preparations according to the invention can be used both in those hair treatment processes in which the preparations are rinsed out of the hair after use, and in those hair treatment processes in which the preparation remains in the hair.
  • Preparations, after which the hair is usually rinsed are, for example, shampoos, hair rinses, waving agents and colorants.
  • Products that usually remain in the hair are, for example, hair setting agents, hair treatments and hair dryer preparations.
  • all auxiliaries and additives customary for the respective application can be included.
  • these are usually anionic, nonionic and zwitterionic surfactants, pearlescent agents, perfumes, agents for adjusting the pH, dyes, preservatives, optionally alkoxylated fatty acids and fatty alcohols and components for adjusting the viscosity in addition to the base of water.
  • Hair rinses which are also usually based on water, generally contain quaternary ammonium compounds, lower alcohols, solubilizers, active ingredients such as. B. panthenol, nonionic polymers, viscosity adjusting agents and perfume oils.
  • hair setting agents usually contain lower alcohols, tensides, preferably nonionic, stabilizers, cationic and / or anionic polymers, agents for adjusting the pH and, in the case of formulations as foam hair setting agents, blowing agents.
  • Hair dyes usually contain direct dyes and / or precursors for oxidation dyes (coupler, developer components), surfactants, fatty alcohols, reducing agents, perfume oils and agents for adjusting the pH.
  • waving agents In addition to the reducing agent (thioglycolic acid, thiolic acid), waving agents generally contain components for adjusting the pH, surfactants, complexing agents, solubilizers, fatty alcohols and perfume oils.
  • the corresponding fixing solutions contain oxidizing agents such as hydrogen peroxide and potassium bromate instead of the reducing agent.
  • oxidizing agents such as hydrogen peroxide and potassium bromate instead of the reducing agent.
  • Surfactants / emulsifiers e.g. anionic surfactants with carboxylate, sulfonate, sulfate or phosphate groups such as soaps, alkyl and aryl ether sulfates, fatty amines, quaternary ammonium and pyridinium compounds, nonionic emulsifiers such as ethylene oxide adducts with alcohols, carboxylic acids, partial glycerides and sorbitan esters, amphoteric and zwitterionic emulsifiers , Betaines or sulfobetaines and, for example Fatty acid esters and sorbitan fatty acid esters (cf. e.g. W. Umbach [ed.], "Cosmetics - Development, Manufacture and Use of Cosmetics", pp. 86-87, Stuttgart 1988).
  • anionic surfactants with carboxylate, sulfonate, sulfate or phosphate groups such as soap
  • Oil components e.g. Substances such as paraffin oil, vegetable oils, fatty acid esters, squalane and 2-0ctyldodecanol; as fats and waxes, for example, walrus, beeswax, montan wax, paraffin and cetylstearyl alcohol.
  • Solution mediators e.g. low mono- or polyhydric alcohols such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol and diethylene glycol.
  • Thickeners e.g. Polysaccharides, in particular xanthan gum, guar gum, agar agar, alginates and tyloses, and also carboxymethyl cellulose and hydroxyethyl cellulose, as well as higher molecular weight polyethylene glycol mono- and diesters of fatty acids, polyacrylates, polyvinyl alcohol and polyvinyl pyrrolidone.
  • Polysaccharides in particular xanthan gum, guar gum, agar agar, alginates and tyloses, and also carboxymethyl cellulose and hydroxyethyl cellulose, as well as higher molecular weight polyethylene glycol mono- and diesters of fatty acids, polyacrylates, polyvinyl alcohol and polyvinyl pyrrolidone.
  • Superfatting agents e.g. polyethoxylated lanolin derivatives, lecithin derivatives and fatty acid alkanols, the latter also serving as foam stabilizers.
  • Biogenic active ingredients such as plant extracts, protein breakdown products and vitamin complexes.
  • Humectants for example glycerol, polyglycerols, sorbitol, 1,2-propanediol, 1,2,3-butanetriol, polyethylene glycols, mannitol, xylitol, pyrollidone carboxylic acid salts (PCA), amino acids, lactic acid.
  • Antimicrobial substances as preservatives such as benzoic acid, salicylic acid, sorbic acid, and their esters and salts, as well as the substances listed in the annex to the Cosmetics Regulation.
  • Pearlescent agents such as ethylene glycol distearate or fatty acid monoglycol esters.
  • Fragrances for example natural fragrances, which are obtained from plants by distillation, extraction or pressing, and synthetically produced fragrances (see, for example, H.Aebi, E. Baumgartner, HPFiedler, G.Ohloff, "Cosmetics, Fragrances and Food Additives” , Stuttgart 1978).
  • Antioxidants e.g. Tocopherols, lecithin, guaiacol, butyl cresol, 4-methyl-2,6-di-tert-butyl-phenol (BHT), 4-methoxy-2 (3) tert-butylphenol (BHA)
  • Dyes such as e.g. are compiled by the Dye Commission of the German Research Association for Cosmetics ("Colorants for Cosmetics" Notice 3, Wiesbaden 1968).
  • the dyes are usually used in concentrations of 0.001 to 0.1% by weight, based on the mixture as a whole.
  • pH regulators If desired, further components of the agents according to the invention are substances which serve to adjust the pH of the agents.
  • the total amount of auxiliaries is 0-30% by weight, preferably 0-20% by weight.
  • components (A) and (B) or (A) to (C) or (A) to (D) are usually stirred together at 60 to 80 ° C.
  • the mixtures are stirred and then cooled to normal temperature (20 to 40 ° C).
  • the preparations according to the invention are generally distinguished by a double function, since they have a cleaning and nourishing effect at the same time Have an effect.
  • the main focus of the preparations based on the binary combination of active ingredients of (A) and (B) is the nourishing effect.
  • Another object of the invention is therefore the use of the preparations according to the invention for the care of hair.
  • the cleaning action of the preparations can be modified as desired.
  • the preparations according to the invention are usually applied to the hair and, after an exposure time, rinsed off again with water.
  • those preparations in which the nourishing character is in the foreground are applied to the hair and remain there.
  • Ci6_i8 fatty alcohols (Henkel)
  • the dry combing work was investigated on brown hair (Alkinco # 6634, strand length 12 cm, strand mass 1 g). It was slightly pre-damaged (bleached) hair, as can be expected from the average user.
  • the strands were impregnated with 100 ml of the formulation to be tested. After a contact time of 5 minutes, the strands were rinsed out under running water (1 l / min, 38 ° C.) for 1 minute. The strands were then dried for 12 hours at 30 ° C. and a relative atmospheric humidity of 20% and then measured again and the result result compared to the zero measurement.
  • Table 1 The results of the dry combability tests are summarized in Table 1.
  • the information in the upper block of the table relates to% by weight of active substance.
  • the information in the lower block of the table relates to the experimentally determined value of dry combability TK in comparison to the zero measurement.
  • the example B1 according to the invention has a significantly higher dry combability than VI and V2. Because TK is a measure of. for the hold of the hairstyle, an improvement in hairstyle hold has been proven for Bl. 3. Determination of wet combability
  • the information in the upper block of the table relates to% by weight of active substance.
  • the information in the lower block of the table relates to the experimentally determined value of the wet combability NK in comparison to the zero measurement.
  • the statistical certainty of the TC values was 99.99%.
  • Example B1 according to the invention has a significantly lower value for wet combability than VI and V2. Since lower values of NK mean better combability of wet hair, an improvement in wet combability has been shown for B1.
  • a 15 cm long strand of hair (Alkinco 6634; strand weight: 2 g) was treated with 0.5 g of the substance, left to act for 2 minutes, rinsed and wound on a glass tube with an outer diameter of 2.0 cm, fixed and dried.
  • a measure of the stability of the curl obtained after pulling out the glass rod is the curl retention value.
  • the curl retention value (CR value) is defined as [(ll x ) / (ll 0 )] * 100%, where 1 is the length of the strand of hair (15 cm), 1 0 is the length of the lock of hair immediately after drying and l x is the length of the hair curl after 8 hours storage hanging in a drying cabinet at constant conditions (25 ° C, 60% relative humidity) is.
  • the results of the measurements are summarized in Table 3.
  • the information in the upper block of the table relates to% by weight of active substance.
  • the information in the lower block of the table relates to the experimentally determined CR value.
  • the example B1 according to the invention has a higher CR value than VI and V2. Since higher CR values indicate an improved curl retention capacity, an improvement in the curl retention capacity is shown for B1.
  • An apparatus is used for the objective evaluation of the influence of hair treatment agents on the bounce of hair, in which individual locks of hair are attached to a force measuring device.
  • the curls are treated preparatively on winders with diameters that give exactly one turn.
  • the winding lies in the plane that is perpendicular to the horizontal.
  • the curl with a special bracket which is located within the curl, moves downwards; this movement continues until the end of the curl slides past the bracket and swings upwards.
  • the damped vibration of the curl is a measure of the elastic vibration of the hairstyle.
  • the stretching work, the initial amplitude, the oscillation frequency and the damping constant of the damped oscillation are used to evaluate the means with which the curls were treated.
  • the desired state of resilience of the hair, achieved by the compositions according to the invention, can be clearly understood to lie between the extremes of a fully elastic, undamped oscillation and a "shock-absorber-like" strongly damped oscillation.
  • MP1 the measured value
  • the information in the upper block of the table relates to% by weight of active substance.
  • the data MP 1 to MP 6 in the lower block of the table relate to the experimentally determined measurement parameters (the data in each case represent the differences between treated and untreated strands of hair). They were measured uniformly at a relative air humidity of 60%.
  • the rinses S1 to S4 are notable for good wet combability, increased dry combability and good bounce values and color retention.
  • the formulations are stable for half a year at 40 C. In addition, they are notable for good spreadability, high viscosity and a smooth appearance. When using it, you feel a pleasant feeling on your hand.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

Des préparations capillaires cosmétiques contenant un amphopolym-ère ainsi que des esters particuliers d'acides gras monovalents se caractérisent en ce qu'elles permettent d'obtenir simultanément une bonne aptitude au coiffage des cheveux humides tout en améliorant l'aptitude au coiffage des cheveux secs, ce qui permet non seulement une meilleure élaboration de la coiffure des cheveux humides, mais également une meuilleure tenue de la coiffure avec des cheveux secs. Les préparations réalisées selon l'invention assurent en outre une meilleure tenue des boucles et un meilleur ressort des ondulations de la coiffure.
PCT/EP1993/001627 1992-07-03 1993-06-24 Preparations capillaires cosmetiques Ceased WO1994001078A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4221914.0 1992-07-03
DE19924221914 DE4221914A1 (de) 1992-07-03 1992-07-03 Haarkosmetische Zubereitungen

Publications (1)

Publication Number Publication Date
WO1994001078A1 true WO1994001078A1 (fr) 1994-01-20

Family

ID=6462431

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1993/001627 Ceased WO1994001078A1 (fr) 1992-07-03 1993-06-24 Preparations capillaires cosmetiques

Country Status (2)

Country Link
DE (1) DE4221914A1 (fr)
WO (1) WO1994001078A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6555100B1 (en) 1997-12-31 2003-04-29 L'ORéAL S.A. Compositions for treating keratinous materials containing a combination of a zwitterion polymer and a water insoluble non-volatile silicon

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2740334B1 (fr) * 1995-10-25 1997-12-05 Oreal Composition cosmetique contenant un monoester d'acide en c4-c10 et d'alcool en c16-c18 et des particules creuses
AT403914B (de) * 1996-09-24 1998-06-25 Krems Chemie Ag Sprühgetrocknete dispersionen, verfahren zu ihrer herstellung und deren anwendung

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3728447A (en) * 1970-03-03 1973-04-17 Patterson Co C Fatty acid lactylates and glycolates for conditioning hair
EP0217274A2 (fr) * 1985-09-30 1987-04-08 Kao Corporation Composition cosmétique pour les cheveux
GB2245585A (en) * 1990-05-31 1992-01-08 Kao Corp Shampoo compositions containing polymers
DE4132776C1 (fr) * 1991-10-02 1992-08-27 Goldwell Ag, 6100 Darmstadt, De

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3728447A (en) * 1970-03-03 1973-04-17 Patterson Co C Fatty acid lactylates and glycolates for conditioning hair
EP0217274A2 (fr) * 1985-09-30 1987-04-08 Kao Corporation Composition cosmétique pour les cheveux
GB2245585A (en) * 1990-05-31 1992-01-08 Kao Corp Shampoo compositions containing polymers
DE4132776C1 (fr) * 1991-10-02 1992-08-27 Goldwell Ag, 6100 Darmstadt, De

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6555100B1 (en) 1997-12-31 2003-04-29 L'ORéAL S.A. Compositions for treating keratinous materials containing a combination of a zwitterion polymer and a water insoluble non-volatile silicon

Also Published As

Publication number Publication date
DE4221914A1 (de) 1994-01-05

Similar Documents

Publication Publication Date Title
DE69223459T3 (de) Ampholitische Terpolymere mit verbesserten Konditionierungseigenschaften in Shampoozusammensetzungen und Haarpflegemitteln
DE69205084T2 (de) Ampholitische Terpolymere mit verbesserten Konditionierungseigenschaften in Shampoozusammensetzungen und Haarpflegemitteln.
DE10101946A1 (de) Haarfärbemittel
EP1110536B2 (fr) Composition de traitement capillaire comprenant une combinaison de polymères
WO1994016679A1 (fr) Melanges tensioactifs contenant un copolymere temporairement cationique
DE10050782A1 (de) Haarpflegemittel
DE69732024T2 (de) Haarbehandlungsmittel
DE69819692T3 (de) Zusammensetzungen für die Behandlung von Keratinsubstanzen, die ein zwitterionisches Polymer in Kombination mit einem nicht wasserlöslichen, nicht flüchtigen Silicon enthalten
DE3522256A1 (de) Kosmetisches mittel zur verzoegerung des fettigaussehens von haaren
EP0648103B1 (fr) Agent de traitement capillaire
DE4420880A1 (de) Festigendes Haarreinigungsmittel
WO2007104740A1 (fr) Émulsion lavante sans silicone pour les cheveux
DE19735865C1 (de) Verwendung eines Mittels auf wäßriger Basis zur Verbesserung der Farbstabilität und/oder Formbeständigkeit von gefärbten und/oder dauergewellten Haaren
WO1994016678A1 (fr) Melanges tensioactifs
EP0648104B1 (fr) Agents de traitement capillaire
WO1990015589A1 (fr) Produit translucide pour les soins du corps et des cheveux
EP0943314B1 (fr) Utilisation d' une composition traitante pour la chevelure
DE19904359A1 (de) Haarpflegemittel
EP0880916B1 (fr) Procédé pour l'ondulation permanent des cheveux
WO1994001078A1 (fr) Preparations capillaires cosmetiques
DE4129124A1 (de) Milde reinigungsmittel
EP0925775A2 (fr) Agent de traitement du cheveu
EP1366756A1 (fr) Composition de coloration des cheveux humains
DE2542338C3 (de) Mittel zur Festigung der Frisur
EP0605503A1 (fr) Preparations pour le traitement des cheveux.

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): JP US

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
122 Ep: pct application non-entry in european phase