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WO1992000333A3 - Catalyseurs en alliage organometallique de monocyclopentadienyle depourvu d'aluminium destines a la polymerisation d'olefines - Google Patents

Catalyseurs en alliage organometallique de monocyclopentadienyle depourvu d'aluminium destines a la polymerisation d'olefines Download PDF

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Publication number
WO1992000333A3
WO1992000333A3 PCT/US1991/004390 US9104390W WO9200333A3 WO 1992000333 A3 WO1992000333 A3 WO 1992000333A3 US 9104390 W US9104390 W US 9104390W WO 9200333 A3 WO9200333 A3 WO 9200333A3
Authority
WO
WIPO (PCT)
Prior art keywords
aluminum
free
olefin polymerization
metallocene catalysts
transition metal
Prior art date
Application number
PCT/US1991/004390
Other languages
English (en)
Other versions
WO1992000333A2 (fr
Inventor
Joann Marie Canich
Gregory George Hlatky
Howard William Turner
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=24162910&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO1992000333(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from US07/542,236 external-priority patent/US7163907B1/en
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Priority to JP3511782A priority Critical patent/JP2954351B2/ja
Priority to DE0551277T priority patent/DE551277T1/de
Priority to BR919106589A priority patent/BR9106589A/pt
Priority to KR1019920703315A priority patent/KR0123370B1/ko
Priority to DE69124255T priority patent/DE69124255T3/de
Priority to CA002085581A priority patent/CA2085581C/fr
Priority to EP91912554A priority patent/EP0551277B2/fr
Publication of WO1992000333A2 publication Critical patent/WO1992000333A2/fr
Publication of WO1992000333A3 publication Critical patent/WO1992000333A3/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/74—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
    • C08F4/76—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Système catalyseur comprenant un constituant d'un métal de transition du groupe IV-B ainsi qu'un constituant activateur apte à polymériser les oléfines pour produire un polymère à masse moléculaire élevée. Ledit constituant de métal de transition renferme un seul ligand cyclopentadiényle et un seul ligand hétéroatome, ces ligands pouvant être reliés l'un à l'autre par un pont. Le constituant activateur comporte un cation et un anion non coordonnant compatible, ledit cation pouvant être un acide de Brönsted apte à donner un proton (désigné ci-après par L'-H où L' est une base de Lewis neutre et H est hydrogène).
PCT/US1991/004390 1990-06-22 1991-06-21 Catalyseurs en alliage organometallique de monocyclopentadienyle depourvu d'aluminium destines a la polymerisation d'olefines WO1992000333A2 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
JP3511782A JP2954351B2 (ja) 1990-06-22 1991-06-21 オレフィン重合用のアルミニウムを含まないモノシクロペンタジエニルメタロセン触媒
DE0551277T DE551277T1 (de) 1990-06-22 1991-06-21 Aluminiumfreie monocyclopentadienyl-metallocenkatalysatoren für olefinpolymerisation.
BR919106589A BR9106589A (pt) 1990-06-22 1991-06-21 Catalisadores de monociclopentadienil metaloceno isentos de aluminio para a polimerizacao de olefinas
KR1019920703315A KR0123370B1 (ko) 1990-06-22 1991-06-21 올레핀 중합을 위한 알루미늄-비함유 모노사이클로 펜타디에닐 메탈로센 촉매
DE69124255T DE69124255T3 (de) 1990-06-22 1991-06-21 Aluminiumfreie monocyclopentadienyl-metallocenkatalysatoren für olefinpolymerisation
CA002085581A CA2085581C (fr) 1990-06-22 1991-06-21 Catalyseurs a base de monocyclopentadienylmetallocene exempt d'aluminium pour la polymerisation des olefines
EP91912554A EP0551277B2 (fr) 1990-06-22 1991-06-21 Catalyseurs en alliage organometallique de monocyclopentadienyle depourvu d'aluminium destines a la polymerisation d'olefines

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US542,236 1990-06-22
US07/542,236 US7163907B1 (en) 1987-01-30 1990-06-22 Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization

Publications (2)

Publication Number Publication Date
WO1992000333A2 WO1992000333A2 (fr) 1992-01-09
WO1992000333A3 true WO1992000333A3 (fr) 1992-03-19

Family

ID=24162910

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1991/004390 WO1992000333A2 (fr) 1990-06-22 1991-06-21 Catalyseurs en alliage organometallique de monocyclopentadienyle depourvu d'aluminium destines a la polymerisation d'olefines

Country Status (11)

Country Link
EP (4) EP0551277B2 (fr)
JP (1) JP2954351B2 (fr)
KR (1) KR0123370B1 (fr)
AT (1) ATE147761T1 (fr)
BR (1) BR9106589A (fr)
CA (1) CA2085581C (fr)
DE (3) DE69124255T3 (fr)
DK (1) DK0551277T4 (fr)
ES (2) ES2092913T5 (fr)
RU (1) RU2118203C1 (fr)
WO (1) WO1992000333A2 (fr)

Cited By (15)

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RU2142953C1 (ru) * 1995-03-29 1999-12-20 Юнион Карбайд Кемикалз Энд Пластикс Текнолоджи Корпорейшн Комплексы переходных металлов, каталитическая система, содержащая их, способ получения полиолефинов и полиолефиновая композиция
US6867260B2 (en) 1998-07-01 2005-03-15 Exxonmobil Chemical Patents, Inc. Elastic blends comprising crystalline polymer and crystallizable polymers of propylene
US6916892B2 (en) 2001-12-03 2005-07-12 Fina Technology, Inc. Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene
US6982310B2 (en) 1997-08-12 2006-01-03 Exxonmobil Chemical Patents Inc. Alpha-olefin/propylene copolymers and their use
US7205371B2 (en) 1997-08-12 2007-04-17 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
US7232871B2 (en) 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
US7572859B2 (en) 2002-06-26 2009-08-11 Basell Polyolefine Italia S.R.L. Impact-resistant polyolefin compositions
US8946329B2 (en) 2003-08-25 2015-02-03 Dow Global Technologies Llc Coating compositions
US9169406B2 (en) 2003-08-25 2015-10-27 Dow Global Technologies Llc Coating compositions
US9168720B2 (en) 2009-02-27 2015-10-27 Exxonmobil Chemical Patents Inc. Biaxially elastic nonwoven laminates having inelastic zones
US9168718B2 (en) 2009-04-21 2015-10-27 Exxonmobil Chemical Patents Inc. Method for producing temperature resistant nonwovens
US9175240B2 (en) 2009-04-28 2015-11-03 Exxonmobil Chemical Patents Inc. Ethylene-based copolymers, lubricating oil compositions containing the same, and methods for making them
US9422444B2 (en) 2012-12-28 2016-08-23 Dow Global Technologies Llc Coating compositions
US9441060B2 (en) 2009-04-28 2016-09-13 Exxonmobil Chemical Patents Inc. Ethylene copolymers, methods for their production, and use
US9498932B2 (en) 2008-09-30 2016-11-22 Exxonmobil Chemical Patents Inc. Multi-layered meltblown composite and methods for making same

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US5763547A (en) * 1992-10-02 1998-06-09 The Dow Chemical Company Supported catalyst complexes for olefin in polymerization
US5064802A (en) † 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US6294625B1 (en) 1990-03-20 2001-09-25 Exxonmobil Chemical Patents Inc. Catalyst system of enhanced productivity and its use in polymerization process
US5801113A (en) * 1990-06-22 1998-09-01 Exxon Chemical Patents, Inc. Polymerization catalyst systems, their production and use
HK1003596A1 (en) * 1991-10-15 1998-10-30 The Dow Chemical Company Preparation of metal coordination complex
DE69222317T2 (de) * 1991-11-25 1998-02-12 Exxon Chemical Patents, Inc., Baytown, Tex. Polyionische, uebergangsmetall enthaltende katalysatorzusammensetzung
JP3275078B2 (ja) * 1992-01-06 2002-04-15 ザ ダウ ケミカル カンパニー オレフィンの重合法
JPH07504934A (ja) * 1992-03-16 1995-06-01 エクソン・ケミカル・パテンツ・インク 制御されたタクチシティーのポリ‐α‐オレフィン製造用イオン触媒
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WO1992000333A2 (fr) 1992-01-09
DE69124255T3 (de) 2005-10-06
EP0670334A3 (fr) 1995-09-13
DE69124255D1 (de) 1997-02-27
CA2085581A1 (fr) 1991-12-23
DE69122275D1 (de) 1996-10-24
EP0672689A1 (fr) 1995-09-20
DK0551277T4 (da) 2005-04-04
EP0551277B2 (fr) 2005-03-09
EP0672688B2 (fr) 2002-04-17
RU2118203C1 (ru) 1998-08-27
JP2954351B2 (ja) 1999-09-27
CA2085581C (fr) 2002-07-30
DE69124255T2 (de) 1997-06-05
EP0672688B1 (fr) 1996-09-18
BR9106589A (pt) 1993-06-01
ATE147761T1 (de) 1997-02-15
ES2079330T1 (es) 1996-01-16
ES2079330T5 (es) 2005-10-01
DE69122275T3 (de) 2002-10-31
EP0672688A1 (fr) 1995-09-20
ES2079330T3 (es) 1997-03-01
DE69122275T2 (de) 1997-05-15
KR0123370B1 (ko) 1997-11-12
EP0551277B1 (fr) 1997-01-15
DK0551277T3 (da) 1997-07-14
EP0551277A1 (fr) 1993-07-21
ES2092913T3 (es) 1996-12-01
JPH05507756A (ja) 1993-11-04
KR930701493A (ko) 1993-06-11
ES2092913T5 (es) 2002-10-16
DE551277T1 (de) 1996-10-10
EP0670334A2 (fr) 1995-09-06

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