[go: up one dir, main page]

WO1991011542A2 - Procede et composition de traitement de surface pour tole galvanisee - Google Patents

Procede et composition de traitement de surface pour tole galvanisee Download PDF

Info

Publication number
WO1991011542A2
WO1991011542A2 PCT/US1991/000531 US9100531W WO9111542A2 WO 1991011542 A2 WO1991011542 A2 WO 1991011542A2 US 9100531 W US9100531 W US 9100531W WO 9111542 A2 WO9111542 A2 WO 9111542A2
Authority
WO
WIPO (PCT)
Prior art keywords
ions
treatment
cobalt
nickel
process according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1991/000531
Other languages
English (en)
Other versions
WO1991011542A3 (fr
Inventor
Hitoshi Ishii
Kazuhiko Mori
Toshi Miyawaki
Shizuo Shima
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel Corp
Original Assignee
Henkel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Corp filed Critical Henkel Corp
Priority to US07/916,096 priority Critical patent/US5318640A/en
Publication of WO1991011542A2 publication Critical patent/WO1991011542A2/fr
Publication of WO1991011542A3 publication Critical patent/WO1991011542A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/78—Pretreatment of the material to be coated
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/60—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using alkaline aqueous solutions with pH greater than 8

Definitions

  • a component indispensable to the substitution precipitation of nickel and/or cobalt from the treatment liquid in the neutral region is a complexing agent which exhibits good stability with metal ion in the neutral region and which supports the rapid deposition of quantities sufficient to improve the paint adhesion and post-coating corrosion resistance.
  • salt spray testing was carried out in order to evaluate the corrosion resistance, and the primary physical properties (cross-cut adhesion test, Erichsen test) and secondary physical properties (cross-cut adhesion test, Erichsen test) were measured as described in more detail below in order to evaluate film adhesion. The results obtained are reported in Table 2.
  • the galvanized steel sheet serving as the treatment substrate was hot-dip galvanized steel sheet (GI) with a sheet thickness of 0.35 mm, a sheet width of 200 mm, a length of 300 mm, and coating of 90 g/m 2 of zinc.
  • the respective treatments were implemented according to the conditions described in Table 3, were followed by a water rinse and drying, and afforded the metal add-ons also reported in Table 3.
  • Spraying was employed as the treatment method in all cases, and the spray pressure was 0.5 kilo grams (force) per square centimeter ("kgf/cm 2 ").
  • the top coat paint was subjected to a bending test and salt spray testing, and the back coated sheet was subjected to salt spray testing.
  • the severity of the bending test varies according to the number of sheets inserted during bending, and is reported as 0T, 2T, etc., in correspondence to the number of inserted sheets. Also, the test temperature exercises an effect, and a lower temperature corresponds to greater severity.
  • the test results were obtained in the same manner and reported according to the same scales as in part II, except that the salt spray was continued for 1,000 hours for the top coated samples and for 360 hours for the back coated samples. These results are reported in Table 6.
  • Examples K1 to K10 concern the treatment of galvanized steel sheet with treatment liquid according to the present invention, followed by a water rinse and then a bakable chromate type blackening treatment. Comparison Examples K1 to K5 provide comparison in this regard.
  • the galvanized steel sheet serving as the treatment substrate was electrogalvanized steel sheet (EG) with a sheet thickness of 0.45 mm, sheet width of 200 mm, length of 300 mm, and plating of 20 g/m 2.
  • EG electrogalvanized steel sheet
  • Treatments according to the invention or for comparison were implemented according to the conditions described in Table 11, followed by a water rinse and drying, to afford the metal add-ons also reported in Table 11. Immersion was employed as the treatment method for all examples in this group.
  • a bakable chromate type blackening treatment bath having a pH of 2.2 and containing 80 g/L of Cr6+, 40 g/L of Cr 3+ , and 40 g/L of nonvolatiles from an acrylic resin emulsion was then applied to each sheet by grooved roll coating to give a dry film thickness of 3 micrometers, followed by drying in a hot air drying oven at MPT of 200 degrees Centigrade to afford baked and blackened galvanized steel sheet.

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Coating With Molten Metal (AREA)

Abstract

Procédé de dépôt de nickel et/ou de cobalt pouvant être mis en ÷uvre à un pH presque neutre. Ce procédé permet de déposer rapidement du nickel et/ou du cobalt en quantité suffisante pour améliorer l'adhérence de la peinture et la résistance à la corrosion après revêtement, et présente une bonne stabilité de solution. Il consiste à traiter une tôle galvanisée à l'aide d'une solution aqueuse présentant un pH compris entre 5 et 10 inclus, et comprenant (A) un total d'au moins 0,01 g/l d'ions métal sélectionnés dans le groupe composé d'ions Ni?2+ et CO2+¿, et (B) une quantité suffisante permettant de transformer complètement en complexe les ions métal cités dans la partie (A) d'agents de transformation en complexe, sélectionnés dans le groupe formé de gaz ammoniac et de composés organiques comportant au moins un groupe amino dans la région neutre. La réaction de précipitation à substitution de nickel et de cobalt est sensiblement accélérée par la présence, à titre de troisième composant ajouté à l'ion métal et à l'agent de transformation en complexe, d'au moins une espèce ou un composé ionique, choisi parmi un ion nitrite, un ion nitrate, un ion thiocyanate, un ion thiosulfate, thiourée, un ion phosphite, un ion hypophosphite et un ion perchlorate.
PCT/US1991/000531 1990-01-30 1991-01-25 Procede et composition de traitement de surface pour tole galvanisee Ceased WO1991011542A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US07/916,096 US5318640A (en) 1990-01-30 1991-01-25 Surface treatment method and composition for zinc coated steel sheet

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP1958190A JPH03226584A (ja) 1990-01-30 1990-01-30 亜鉛系めっき鋼板用表面処理液及び表面処理方法
JP2/19581 1990-01-30

Publications (2)

Publication Number Publication Date
WO1991011542A2 true WO1991011542A2 (fr) 1991-08-08
WO1991011542A3 WO1991011542A3 (fr) 1991-09-19

Family

ID=12003232

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1991/000531 Ceased WO1991011542A2 (fr) 1990-01-30 1991-01-25 Procede et composition de traitement de surface pour tole galvanisee

Country Status (3)

Country Link
JP (1) JPH03226584A (fr)
AU (1) AU7312991A (fr)
WO (1) WO1991011542A2 (fr)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0488430A3 (en) * 1990-11-30 1992-12-16 The Boeing Company Non-chromated cobalt conversion coating
WO1994002661A1 (fr) * 1992-07-20 1994-02-03 Henkel Corporation Procede de traitement de l'acier visant a reduire au minimum la corrosion filiforme
US5298092A (en) * 1990-05-17 1994-03-29 The Boeing Company Non-chromated oxide coating for aluminum substrates
US5378293A (en) * 1990-05-17 1995-01-03 The Boeing Company Non-chromated oxide coating for aluminum substrates
US5411606A (en) * 1990-05-17 1995-05-02 The Boeing Company Non-chromated oxide coating for aluminum substrates
US5468307A (en) * 1990-05-17 1995-11-21 Schriever; Matthias P. Non-chromated oxide coating for aluminum substrates
US5472524A (en) * 1990-05-17 1995-12-05 The Boeing Company Non-chromated cobalt conversion coating method and coated articles
US5551994A (en) * 1990-05-17 1996-09-03 The Boeing Company Non-chromated oxide coating for aluminum substrates
EP0738790A4 (fr) * 1994-09-27 1998-06-03 Nippon Kokan Kk Tole d'acier galvanisee et son procede d'elaboration
US5873953A (en) * 1996-12-26 1999-02-23 The Boeing Company Non-chromated oxide coating for aluminum substrates
EP0979880A1 (fr) * 1998-08-13 2000-02-16 Nippon Paint Co., Ltd. Substances chimiques et procédé pour le prétraitement de métaux
US6432225B1 (en) 1999-11-02 2002-08-13 The Boeing Company Non-chromated oxide coating for aluminum substrates
US7294211B2 (en) 2002-01-04 2007-11-13 University Of Dayton Non-toxic corrosion-protection conversion coats based on cobalt
WO2011067094A1 (fr) * 2009-12-04 2011-06-09 Henkel Ag & Co. Kgaa Procédé de prétraitement à étapes multiples pour des composants métalliques présentant des surfaces en zinc et en fer

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2233020T3 (es) 1998-02-18 2005-06-01 Nippon Steel Corporation Material de revestimiento anticorrosivo y metodo de prevencion de la corrosion.
JP4635638B2 (ja) * 2005-02-18 2011-02-23 Ｊｆｅスチール株式会社 耐食性及び耐黒変性に優れたリン酸塩処理電気亜鉛めっき鋼板
JP6151907B2 (ja) * 2012-10-12 2017-06-21 日本パーカライジング株式会社 水系金属表面処理剤、金属表面処理皮膜及び金属表面処理皮膜付き金属材料

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3444007A (en) * 1967-03-13 1969-05-13 Hooker Chemical Corp Process of forming paint-base coatings on zinc and zinc alloy surfaces
US3929514A (en) * 1974-03-05 1975-12-30 Heatbath Corp Composition and method for forming a protective coating on a zinc metal surface
JPS51135840A (en) * 1975-05-21 1976-11-25 Nippon Packaging Kk Surface treatment process for zinc or zinc alloy
JPS6220880A (ja) * 1985-07-19 1987-01-29 Nippon Parkerizing Co Ltd 亜鉛−アルミニウム合金めつき鋼板の表面処理方法
JPH0739634B2 (ja) * 1988-08-03 1995-05-01 住友金属工業株式会社 耐黒変性、耐食性溶融亜鉛系めっき鋼板の製造方法
JPH0723543B2 (ja) * 1988-08-10 1995-03-15 日本パーカライジング株式会社 亜鉛系めっき用表面処理液及び表面処理方法
JPH0730458B2 (ja) * 1988-08-08 1995-04-05 日本パーカライジング株式会社 亜鉛又は亜鉛系めっき材料の黒色化処理方法
JPH0774461B2 (ja) * 1989-04-07 1995-08-09 日本鋼管株式会社 亜鉛または亜鉛合金の表面処理方法
JPH0331484A (ja) * 1989-06-27 1991-02-12 Nippon Parkerizing Co Ltd 亜鉛または亜鉛系メッキ材料の黒色化処理法

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5298092A (en) * 1990-05-17 1994-03-29 The Boeing Company Non-chromated oxide coating for aluminum substrates
US5378293A (en) * 1990-05-17 1995-01-03 The Boeing Company Non-chromated oxide coating for aluminum substrates
US5411606A (en) * 1990-05-17 1995-05-02 The Boeing Company Non-chromated oxide coating for aluminum substrates
US5415687A (en) * 1990-05-17 1995-05-16 The Boeing Company Non-chromated oxide coating for aluminum substrates
US5468307A (en) * 1990-05-17 1995-11-21 Schriever; Matthias P. Non-chromated oxide coating for aluminum substrates
US5472524A (en) * 1990-05-17 1995-12-05 The Boeing Company Non-chromated cobalt conversion coating method and coated articles
US5551994A (en) * 1990-05-17 1996-09-03 The Boeing Company Non-chromated oxide coating for aluminum substrates
EP0488430A3 (en) * 1990-11-30 1992-12-16 The Boeing Company Non-chromated cobalt conversion coating
WO1994002661A1 (fr) * 1992-07-20 1994-02-03 Henkel Corporation Procede de traitement de l'acier visant a reduire au minimum la corrosion filiforme
US5861218A (en) * 1994-09-27 1999-01-19 Nkk Cororation Zinciferous plated steel sheet and method for manufacturing same
EP0738790A4 (fr) * 1994-09-27 1998-06-03 Nippon Kokan Kk Tole d'acier galvanisee et son procede d'elaboration
US5873953A (en) * 1996-12-26 1999-02-23 The Boeing Company Non-chromated oxide coating for aluminum substrates
EP0979880A1 (fr) * 1998-08-13 2000-02-16 Nippon Paint Co., Ltd. Substances chimiques et procédé pour le prétraitement de métaux
US6309477B1 (en) 1998-08-13 2001-10-30 Nippon Paint Co., Ltd. Non-chromium pretreatment chemicals
US6432225B1 (en) 1999-11-02 2002-08-13 The Boeing Company Non-chromated oxide coating for aluminum substrates
US7294211B2 (en) 2002-01-04 2007-11-13 University Of Dayton Non-toxic corrosion-protection conversion coats based on cobalt
WO2011067094A1 (fr) * 2009-12-04 2011-06-09 Henkel Ag & Co. Kgaa Procédé de prétraitement à étapes multiples pour des composants métalliques présentant des surfaces en zinc et en fer
CN102639750A (zh) * 2009-12-04 2012-08-15 汉高股份有限及两合公司 具有锌和铁表面的金属组件的多步骤预处理方法
US8715403B2 (en) 2009-12-04 2014-05-06 Henkel Ag & Co. Kgaa Multi-stage pre-treatment method for metal components having zinc and iron surfaces
CN102639750B (zh) * 2009-12-04 2015-03-11 汉高股份有限及两合公司 具有锌和铁表面的金属组件的多步骤预处理方法

Also Published As

Publication number Publication date
JPH03226584A (ja) 1991-10-07
AU7312991A (en) 1991-08-21
WO1991011542A3 (fr) 1991-09-19

Similar Documents

Publication Publication Date Title
CA1215934A (fr) Tole d'acier traitee en surface aux fins du peinturage
RU2482220C2 (ru) Металлизирующая предварительная обработка цинковых поверхностей
WO1991011542A2 (fr) Procede et composition de traitement de surface pour tole galvanisee
EP1394288A2 (fr) Solution et procédé pour former des revêtements protecteurs sur des métaux
EP1433877A1 (fr) Procédé de prétraitement avant revêtement
US4537837A (en) Corrosion resistant metal composite with metallic undercoat and chromium topcoat
EP1230422A1 (fr) Procede et composition de traitement pour des metaux
US4500610A (en) Corrosion resistant substrate with metallic undercoat and chromium topcoat
CA2018631C (fr) Postrincage-passivation de couches de phosphate
JP3851482B2 (ja) 耐白錆性および塗膜密着性に優れる亜鉛系めっき鋼板
US5318640A (en) Surface treatment method and composition for zinc coated steel sheet
EP1859930B1 (fr) Matiere metallique a traitement superficiel
WO1993009265A1 (fr) Traitement de formation d'une couche mince resistant a la corrosion sur des surfaces metalliques
US4497876A (en) Corrosion resistant metal composite with zinc and chromium coating
US6649275B1 (en) Zinc phosphate-treated galvanized steel sheet excellent in corrosion resistance and color tone
JPH08218193A (ja) 有機複合被覆鋼板
JPS6155592B2 (fr)
JP3903900B2 (ja) 耐食性、塗料密着性及び加工性に優れた非クロム系リン酸亜鉛処理鋼板
JPH0232360B2 (ja) Chakushokuaenmetsukikohannoseizohoho
JPH0422992B2 (fr)
JPH11138096A (ja) 燃料タンク用有機被覆鋼板
JPH09228067A (ja) 耐環境汚染性、耐食性に優れた表面処理鋼板
CN109715853B (zh) 可作为二胺或多胺与α,β-不饱和羧酸衍生物的反应产物获得的粘合促进剂用于金属表面处理的用途
JP2579487B2 (ja) 表面特性の優れた白色クロメ−ト処理方法
JP2945046B2 (ja) 亜鉛系めつき鋼板のクロメート処理方法

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AU BR CA US

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): AT BE CH DE DK ES FR GB GR IT LU NL SE

AK Designated states

Kind code of ref document: A3

Designated state(s): AU BR CA US

AL Designated countries for regional patents

Kind code of ref document: A3

Designated state(s): AT BE CH DE DK ES FR GB GR IT LU NL SE

NENP Non-entry into the national phase

Ref country code: CA