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WO1988000482A1 - Product for fire control and fireproofing impregnation - Google Patents

Product for fire control and fireproofing impregnation Download PDF

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Publication number
WO1988000482A1
WO1988000482A1 PCT/EP1986/000425 EP8600425W WO8800482A1 WO 1988000482 A1 WO1988000482 A1 WO 1988000482A1 EP 8600425 W EP8600425 W EP 8600425W WO 8800482 A1 WO8800482 A1 WO 8800482A1
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WO
WIPO (PCT)
Prior art keywords
volume
aqueous solution
percent
ethanediol
concentration
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP1986/000425
Other languages
German (de)
French (fr)
Inventor
Edmund Pennartz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toj Produktions- und Handelsgesellschaft fur Techn
Original Assignee
Toj Produktions- und Handelsgesellschaft fur Techn
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toj Produktions- und Handelsgesellschaft fur Techn filed Critical Toj Produktions- und Handelsgesellschaft fur Techn
Priority to EP19860904174 priority Critical patent/EP0277116B1/en
Priority to DE8686904174T priority patent/DE3681455D1/en
Priority to PCT/EP1986/000425 priority patent/WO1988000482A1/en
Publication of WO1988000482A1 publication Critical patent/WO1988000482A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0028—Liquid extinguishing substances
    • A62D1/0035—Aqueous solutions

Definitions

  • the invention relates to an agent, in particular for fire fighting and impregnation, consisting of an aqueous solution which has one or more nonionic surfactants in a concentration of 0.02 to 0.2 percent by volume, and a method for the production thereof.
  • Fire fighting solutions of this type are known (DE-0S 31 00 158).
  • be used as a boundary-active agents are primarily those that are obtainable by condensation of ethylene oxide or propylene oxide with various substances and in particular with phenoll o ⁇ rule compounds having a side chain.
  • Combinations of one or more nonionic surface-active agents are selected in order to achieve water solubility within a 20-100 ° C. cloud point range in order to produce the smallest possible amount of foam.
  • the object of the invention is to create a finely sprayable mixture of substances with a high impregnation capacity which at the same time is readily biodegradable and non-toxic. This object is achieved in that alkylarylsulfonate is used as the surfactant.
  • alkylarylsulfonates (R-Ar-S0 3 -Me) were mainly known as raw materials for synthetic detergents. They have good evolving, degreasing and wetting properties as well as a high chemical resistance. Because of their generally unbranched compounds, they are readily biodegradable. Their toxicity to fish is based solely on the fact that they significantly lower the surface tension of the water.
  • the agent or substance mixture according to the invention can be used advantageously in particular for fire extinguishing or prevention, since the distribution of the individual drops of extinguishing agent at the spray nozzle of the extinguishing device becomes much finer due to the substantial reduction in the surface tension due to alkylarylsulfonate. At the same time, the surface of the extinguishing agent to be sprayed
  • a slightly acidic environment with a pH of 6.5 is built up.
  • 30% acetic acid (CH-C00H) in a concentration of 0.2 percent by volume is mixed with two percent by volume of distilled water to form a solution.
  • This buffer solution also reduces the risk of foam formation, which is unavoidable when tensides are added.
  • the proportion of alkylarylsulfonate in the extinguishing agent is limited to about 0.09 percent by volume. In practice, such
  • an aqueous solution with alkali metal citrate and / or sulfates up to the saturation concentration is used as the extinguishing agent.
  • This solution is colorless, clear, neutral smelling and viscous.
  • alkali metal citrate With alkali metal citrate, a prophylactic impregnation of the fire environment and / or a general impregnation of various, easily flammable materials can be achieved, which thereby become largely fire-resistant.
  • the impregnation effect is then further optimized by adding or combining with alkylarylsulfonate.
  • the use of the agent according to the invention in firefighting leads to a reduction in the extinguishing agent requirement, a widening of the spray mist and a densification of the spray curtain when it emerges from the spray nozzle of the extinguishing device, which enables it in particular to fight class A and B fires .
  • the agent according to the invention can in particular contain fires with a strong formation of embers.
  • alkali metal citrate in aqueous solution 91.4 percent by volume of alkali metal citrate in aqueous solution are used for the agent according to the invention. This is admixed with 1,2-thanediol to 2.1 percent by volume with distilled water to 4.2 percent by volume. As a buffer solution to create a slightly acidic environment with a pH of 6.5, 0.2% by volume of CrU-COOH (30%) is also added together with 2.0% by volume of distilled water. Finally, 0.09 percent by volume of alkylaryl sulfonate is added as a wetting agent.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Fire-Extinguishing Compositions (AREA)

Abstract

A mixture, specially useful for fire control and fireproofing impregnation, is composed of 91.4 vol. % of an alkali metal citrate as fire control substance, 2.1 vol. % of 1,2 ethanediol as anti-freezing substance, 0.09 vol. % of alkylarylsulfonate as wetting agent, 0.2 vol. % of 30 % acetic acid for forming a slightly acid environment and 6.2 vol. % of distilled water.

Description

Mittel, insbesondere zur Brandbekämpfung und Imprägnierung . Agents, in particular for fire fighting and impregnation.

Die Erfindung betrifft ein Mittel, insbesondere zur Brandbekämpfung und Imprägnierung, bestehend aus einer wässerigen Lösung, die ein oder mehrere nichtionische Tenside in einer Konzentration von 0,02 bis 0,2 Volumen¬ prozent aufweist, sowie ein Verfahren zu dessen Herstel¬ lung.The invention relates to an agent, in particular for fire fighting and impregnation, consisting of an aqueous solution which has one or more nonionic surfactants in a concentration of 0.02 to 0.2 percent by volume, and a method for the production thereof.

Brandbekämpfungslösungen solcher Art sind bekannt (DE- 0S 31 00 158). Dabei werden als grenzfl chenaktive Mittel in erster Linie solche verwendet, die durch Kondensation von Äthylenoxid oder Propylenoxid mit verschiedenen Substanzen und insbesondere mit phenollo¬ schen Verbindungen mit einer Seitenkette erhältlich sind. Kombinationen aus einem oder mehreren nichtioni¬ schen grenzflächenaktiven Mitteln werden zur Erzielung einer Wasserlöslichkeit innerhalb eines 20-100°C-Trü- bungspunktbereiches ausgewählt, um eine möglichst geringe Schaummenge zu erzeugen. Demgegenüber liegt der Erfindung die Aufgabe zugrunde, ein fein sprühbares Stoffgemisch mit hohem Imprägnierver¬ mögen zu schaffen, das gleichzeitig biologisch leicht abbaubar und nicht toxisch ist. Diese Aufgabe wird dadurch gelöst, daß als Tensid Alkylarylsulfonat verwendet wird.Fire fighting solutions of this type are known (DE-0S 31 00 158). In this case, be used as a boundary-active agents are primarily those that are obtainable by condensation of ethylene oxide or propylene oxide with various substances and in particular with phenoll o ¬ rule compounds having a side chain. Combinations of one or more nonionic surface-active agents are selected in order to achieve water solubility within a 20-100 ° C. cloud point range in order to produce the smallest possible amount of foam. In contrast, the object of the invention is to create a finely sprayable mixture of substances with a high impregnation capacity which at the same time is readily biodegradable and non-toxic. This object is achieved in that alkylarylsulfonate is used as the surfactant.

Alkylarylsulfonate (R-Ar-S03-Me) waren bisher hauptsächl ch als Rohstoffe für synthetische Waschmittel bekannt. Sie besitzen gutes Emolgier-, Enfettungs- und Netzvermögen sowie eine hohe chemische Beständigkeit. Aufgrund Ihrer in der Regel unverzweigten Verbindungen sind sie biolo¬ gisch gut abbaubar. Ihre Toxidität gegenüber Fischen beruht allein darauf, daß sie die Oberflächenspannung des Wassers stark erniedrigen.Until now, alkylarylsulfonates (R-Ar-S0 3 -Me) were mainly known as raw materials for synthetic detergents. They have good evolving, degreasing and wetting properties as well as a high chemical resistance. Because of their generally unbranched compounds, they are readily biodegradable. Their toxicity to fish is based solely on the fact that they significantly lower the surface tension of the water.

Das erfinduπgsgemäße Mittel bzw. Stoffgemisch läßt sich insbesondere zur Brandlöschung bzw. -Verhütung vorteilhaft einsetzen, da aufgrund der wesentlichen Verminderung der Oberfl chenspannung durch Alkylarylsulfo¬ nat die Verteilung der einzelnen Lδschtropfen an der Sprühdüse des Löschgeräts viel feiner wird. Gleichzeitig wird die Oberfl che des zu versprühenden Löschmittels The agent or substance mixture according to the invention can be used advantageously in particular for fire extinguishing or prevention, since the distribution of the individual drops of extinguishing agent at the spray nozzle of the extinguishing device becomes much finer due to the substantial reduction in the surface tension due to alkylarylsulfonate. At the same time, the surface of the extinguishing agent to be sprayed

um ein Vielfaches vergrößert. Indem man dem Löschmittel Alkylarylsulfonat als Netzmittel beimischt, werden bei der Brandlöschung so schwer löschbare Stoffe wie Stroh, Heu, Wollballen, Fertigtextilien, Pulver usw., die oft kompliziert strukturierte Oberfläche aufweisen, unter Verdrängung der Luft benetzt, sozusagen gründlich "durchtränkt". Dies führt zu einer erheblichen Erleich¬ terung und Beschleunigung des Löschens.magnified many times over. By adding alkylarylsulfonate as a wetting agent to the extinguishing agent, fire-extinguishing substances such as straw, hay, bales of wool, finished textiles, powders, etc., which often have a complicated structured surface, are wetted, so to speak, thoroughly "soaked", so to speak. This leads to a considerable easing and acceleration of the deletion.

Um das Ausfällen von Inertstoffen zu verhindern, wird gemäß einer weiteren vorteilhaften Ausbildung der Erfin¬ dung im Löschmittel eine leicht saure Umgebung mit einem pH-Wert von 6,5 aufgebaut. Hierzu wird 30%ige Essigsäure (CH--C00H) in einer Konzentration von 0,2 Volumenprozent zusammen mit zwei Volumenprozent destillier¬ tem Wasser zu einer Lösung angesetzt. Diese Pufferlösung reduziert überdies die Gefahr einer Schaumbildung, die bei Zugabe von Tensiden unumgänglich ist.In order to prevent the precipitation of inert substances, according to a further advantageous embodiment of the invention in the extinguishing agent, a slightly acidic environment with a pH of 6.5 is built up. For this purpose, 30% acetic acid (CH-C00H) in a concentration of 0.2 percent by volume is mixed with two percent by volume of distilled water to form a solution. This buffer solution also reduces the risk of foam formation, which is unavoidable when tensides are added.

Um die Gefahr der Schaumbildung weiter zu vermindern, wird gemäß einer weiteren Ausbildung der Anteil des Alkylarylsulfonats im Löschmittel auf etwa 0.09 Volumen¬ prozent begrenzt. In der Praxis konnte bei einer solchen In order to further reduce the risk of foam formation, the proportion of alkylarylsulfonate in the extinguishing agent is limited to about 0.09 percent by volume. In practice, such

Konzentration dieses Tensids die Oberfl chenspannung um ca. 60 % reduziert werden, ohne daß eine Ausfällung der Inertstoffe auch nach längerer Standzeit (z.B. 3 Wochen) auftrat.Concentration of this surfactant, the surface tension can be reduced by approx. 60%, without precipitation of the inert substances occurring even after a long standing time (e.g. 3 weeks).

Gemäß einer weiteren Ausbildung der Erfindung wird als Löschmittel eine wässerige Lösung mit Alkalimetall¬ citrat und/oder Sulfaten bis zur Sättigungskonzentra¬ tion verwendet. Diese Lösung ist farblos, klar, neutral riechend und viskos. Mit Alkal metallcitrat läßt sich bereits eine prophylaktische Imprägnierung des Brand¬ umfeldes und/oder eine generelle Imprägnierung verschie¬ denster, leicht entflammbarer Materialien erreichen, die dadurch weitgehend feuerfest werden. Durch Zugabe von bzw. Kombination mit Alkylarylsulfonat wird die Imprägnierwirkung dann noch weiter optimiert.According to a further embodiment of the invention, an aqueous solution with alkali metal citrate and / or sulfates up to the saturation concentration is used as the extinguishing agent. This solution is colorless, clear, neutral smelling and viscous. With alkali metal citrate, a prophylactic impregnation of the fire environment and / or a general impregnation of various, easily flammable materials can be achieved, which thereby become largely fire-resistant. The impregnation effect is then further optimized by adding or combining with alkylarylsulfonate.

Eine weitere grundlegende Anforderung an Mittel zum Feuerlöschen besteht in der Sicherheit vor Gefrieren bei Temperaturen bis mindestens -30°C. Da das im wesent¬ lichen aus Al alimetallcitrat bestehende Löschmittel aufgrund der konzentrierten Lösung aliphatischer Salze einen hohen Sättigungsgrad aufweist, ist es an sich bereits bis -15°C frostfest. Gemäß einer besonders vorteilhaften Ausbildung wird dem erfindungsgemäßen Another basic requirement for fire extinguishing agents is the protection against freezing at temperatures down to at least -30 ° C. Since the extinguishing agent consisting essentially of aluminum metal citrate has a high degree of saturation due to the concentrated solution of aliphatic salts, it is inherently frost-resistant down to -15 ° C. According to a particularly advantageous embodiment of the invention

Stoffge isch 1,2-Äthandiol hinzugegeben. Da eine Lösung von einem Teil Wasser und einem Teil 1 ,2-Äthandiol erst bei -40°C gefriert, und in der praktischen Anwendung die freien Wassermoleküle in der wässrigen Lösung mit Alkalimetallcitrat mit 1 ,2-Äthandiol ebenfalls im Verhält¬ nis 1:1 gemischt sind, ist mit dem erfindungsgemäßen Mittel eine Sicherheit vor Gefrieren jedenfalls bis -30°C gewährleistet. Zusätzliche Vorteile durch die Anwendung von 1 ,2-Äthandiol als Gefrierschutz ergeben sich aus dessen Kostengünstigkeit, relativer Umweltverträg¬ lichkeit und einer Vermeidung einer sofortigen Übersätti¬ gung des erfindungsgemäßen Stoffgemisches.Stoffge isch 1,2-ethanediol added. Since a solution of a part of water and a part of 1,2-ethanediol only freezes at -40 ° C, and in practical use the free water molecules in the aqueous solution with alkali metal citrate with 1,2-ethanediol also in a ratio of 1: 1 are mixed, the agent according to the invention guarantees security against freezing in any case down to -30 ° C. Additional advantages from the use of 1,2-ethanediol as anti-freeze result from its cost-effectiveness, relative environmental compatibility and the avoidance of immediate oversaturation of the mixture of substances according to the invention.

Im Ergebnis führt die Anwendung des erfindungsgemäßen Mittels bei der Brandbekämpfung zu einer Verringerung des Löschmittelbedarfes, einer Verbreiterung des Sprühne¬ bels und einer Verdichtung des Sprühvorhanges beim Austritt aus der Sprühdüse des Löschgeräts, was es vor allem zur Bekämpfung von Bränden der Klassen A und B befähigt. Durch die verstärkte Imprägniertiefe bei porösen Stoffen kann das erfindungsgemäße Mittel insbesondere Brände mit starker Glutnestbildung eindämmen.As a result, the use of the agent according to the invention in firefighting leads to a reduction in the extinguishing agent requirement, a widening of the spray mist and a densification of the spray curtain when it emerges from the spray nozzle of the extinguishing device, which enables it in particular to fight class A and B fires . Due to the increased impregnation depth in the case of porous substances, the agent according to the invention can in particular contain fires with a strong formation of embers.

Bezüglich weiterer Ausbildungen und Vorteile der Erfin¬ dung wird auf die Unteransprüche verwiesen. With regard to further designs and advantages of the invention, reference is made to the subclaims.

Im folgenden wird die Erfindung anhand eines beispiel¬ haften Rezepts näher erläutert.The invention is explained in more detail below on the basis of an exemplary recipe.

Zunächst werden 91,4 Volumenprozent Alkalimetallcitrat in wässriger Lösung für das erfindungsgemäße Mittel eingesetzt. Dem werden 1,2 - thandiol zu 2,1 Volumenpro¬ zent mit destilliertem Wasser zu 4,2 Volumenprozent beigemischt. Als Pufferlösung zur Schaffung einer leicht sauren Umgebung mit einem ph-Wert von 6,5 werden ferner CrU-COOH (30%) zu 0,2 Volumenprozent zusammen mit destil¬ liertem Wasser zu 2,0 Volumenprozent zugegeben. Als Netzmittel wird schließlich noch Alkyarylsulfonat zu 0,09 Volumenprozent beigemischt. First, 91.4 percent by volume of alkali metal citrate in aqueous solution are used for the agent according to the invention. This is admixed with 1,2-thanediol to 2.1 percent by volume with distilled water to 4.2 percent by volume. As a buffer solution to create a slightly acidic environment with a pH of 6.5, 0.2% by volume of CrU-COOH (30%) is also added together with 2.0% by volume of distilled water. Finally, 0.09 percent by volume of alkylaryl sulfonate is added as a wetting agent.

Claims

Patentansprüche Claims 1. Mittel, insbesondere zur Brandbekämpfung bei festen und/oder flüssigen oder flüssig werdenden Stoffen und Imprägnierung, bestehend aus einer wässerigen Lösung, die ein oder mehrere nichtionische Tenside in einer Konzentration von 0,02 bis 0,2 Volumenprozent aufweist, dadurch gekennzeichnet, daß als Tensid Alkylarylsulfonat verwendet wird.1. Agents, in particular for fire fighting solid and / or liquid or liquid substances and impregnation, consisting of an aqueous solution which has one or more nonionic surfactants in a concentration of 0.02 to 0.2 percent by volume, characterized in that alkylarylsulfonate is used as surfactant. 2. Mittel nach Anspruch 1, dadurch gekennzeichnet, daß es 1 ,2-Äthandiol aufweist.2. Composition according to claim 1, characterized in that it has 1, 2-ethanediol. 3. Mittel nach Anspruch 2, dadurch gekennzeichnet, daß dessen noch freie Wassermoleküle mit dem 1,2- Äthandiol im Verhältnis 1:1 gemischt sind.3. Composition according to claim 2, characterized in that its still free water molecules are mixed with the 1,2-ethanediol in a ratio of 1: 1. 4. Mittel nach Anspruch 2 oder 3, dadurch gekennzeichnet, daß es 2,1 Volumenprozent 1 ,2-Äthandiol mit 4,2 Volumenprozent destilliertem Wasser aufweist. 4. Composition according to claim 2 or 3, characterized in that it has 2.1 volume percent 1, 2-ethanediol with 4.2 volume percent distilled water. 5. Mittel nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, daß es Alkylarylsulfonat in einer Konzentration von etwa 0,09 Volumenprozent aufweist.5. Agent according to one of claims 1 to 4, characterized in that it has alkylarylsulfonate in a concentration of about 0.09 percent by volume. 6. Mittel nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, daß es 30%ige Essigsä'ure in einer Konzentration von weniger als 1 Volumenpro¬ zent aufweist.6. A composition comprising according to any one of claims 1 to 5, characterized in that acid 30% Essigsä 'centered at a concentration of less than 1 Volumenpro¬. 7. Mittel nach Anspruch 6, dadurch gekennzeichnet, daß es 0,2 Volumenprozent 30%ige Essigsäure mit 2,0 Volumenprozent destilliertem Wasser aufweist.7. Composition according to claim 6, characterized in that it has 0.2 volume percent 30% acetic acid with 2.0 volume percent distilled water. 8. Mittel nach einem der Ansprüche 1 bis 7, dadurch gekennzeichnet, daß die wässerige Lösung Alkalimetallcitrat höchstens bis zur Sättigungskonzentration aufweist.8. Agent according to one of claims 1 to 7, characterized in that the aqueous solution has alkali metal citrate at most up to the saturation concentration. 9. Mittel nach einem der Ansprüche 1 bis 8, dadurch gekennzeichnet, daß die wässerige Lösung Sulfate höchstens bis zur Sättigungskonzentration aufweist. 9. Composition according to one of claims 1 to 8, characterized in that the aqueous solution contains sulfates at most up to the saturation concentration. 10. Verfahren zur Brandbekämpfung und -Verhütung insbeson¬ dere bei festen und/oder flüssigen oder flüssig werdenden Stoffen mittels einer wässerigen Lösung, der nichtionische Tenside in einer Konzentration von 0,02 bis 0,2 Vo umenprozent beigefügt sind, dadurch gekennzeichnet, daß als Tensid Alkylarylsulfonat verwendet wird.10. Fire-fighting and prevention method, in particular in the case of solid and / or liquid or liquid substances, by means of an aqueous solution which contains nonionic surfactants in a concentration of 0.02 to 0.2% by volume, characterized in that as Alkylaryl sulfonate surfactant is used. 11. Verfahren nach Anspruch 10, dadurch gekennzeichnet, daß der wässerigen Lösung Glykol , vorzugsweise 1,2-Äthandiol , zugefügt wird.11. The method according to claim 10, characterized in that the aqueous solution glycol, preferably 1,2-ethanediol, is added. 12. Verfahren nach Anspruch 11, dadurch gekennzeichnet, daß die wässerige Lösung hauptsächlich aus Alkali¬ metallcitrat und/oder Sulfonaten besteht.12. The method according to claim 11, characterized in that the aqueous solution consists mainly of alkali metal citrate and / or sulfonates. 13. Verfahren zur Herstellung einer wässerigen Lösung, insbesondere für die Brandbekämpfung bei festen und/oder flüssigen oder flüssig werdenden Stoffen und Imprägnierung, mit nichtionischen Tensiden, gekennzeichnet durch folgende Rezeptur:13. A process for the preparation of an aqueous solution, in particular for firefighting with solid and / or liquid or liquid substances and impregnation, with nonionic surfactants, characterized by the following recipe: - 91,4 Volumenprozent Alkalimetallcitrat und/oder- 91.4 volume percent alkali metal citrate and / or SulfonateSulfonates - 6,2 Volumenprozent destilliertes Wasser- 6.2 percent by volume distilled water - 2,1 Volumenprozent 1,2-Äthandiol- 2.1 volume percent 1,2-ethanediol - 0,2 Volumenprozent 30%ige Essigsäure, und- 0.2% by volume of 30% acetic acid, and - 0,09 Volumenprozent Alkylarylsulfonat. - 0.09 volume percent alkylarylsulfonate.
PCT/EP1986/000425 1986-07-18 1986-07-18 Product for fire control and fireproofing impregnation Ceased WO1988000482A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP19860904174 EP0277116B1 (en) 1986-07-18 1986-07-18 Product for fire control and fireproofing impregnation
DE8686904174T DE3681455D1 (en) 1986-07-18 1986-07-18 AGENT, ESPECIALLY FOR FIRE FIGHTING AND IMPREGNATION.
PCT/EP1986/000425 WO1988000482A1 (en) 1986-07-18 1986-07-18 Product for fire control and fireproofing impregnation

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PCT/EP1986/000425 WO1988000482A1 (en) 1986-07-18 1986-07-18 Product for fire control and fireproofing impregnation

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Cited By (14)

* Cited by examiner, † Cited by third party
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WO1991000122A1 (en) * 1989-06-23 1991-01-10 Kidde-Graviner Limited Methods, apparatus and substances for extinguishing fires
FR2702963A1 (en) * 1993-03-22 1994-09-30 Landrieau Michel Equipment for monitoring and protecting a building in the event of peripheral fire
GB2301122A (en) * 1995-05-24 1996-11-27 Cyril Glass Flame retardant compositions
WO1999024120A1 (en) * 1997-11-12 1999-05-20 Kidde-Graviner Limited Fire or explosion suppressants and methods
NL1020162C2 (en) * 2002-03-13 2003-09-16 Plyboo Bambooflooring Internat Preparation of bamboo for interior decoration, comprises contacting bamboo pieces with fireproof material in aqueous medium
US8080186B1 (en) 2010-11-16 2011-12-20 Pennartz Edmund R J Fire mitigation and moderating agents
US8273813B2 (en) 2004-11-24 2012-09-25 Basf Aktiengesellschaft Fire extinguishing and/or fire retarding compositions
US10874890B2 (en) 2018-03-05 2020-12-29 Fire Mitigation Technologies, LLC Fire retardant and mitigation compositions and agents
US11826592B2 (en) 2018-01-09 2023-11-28 Mighty Fire Breaker Llc Process of forming strategic chemical-type wildfire breaks on ground surfaces to proactively prevent fire ignition and flame spread, and reduce the production of smoke in the presence of a wild fire
US11865394B2 (en) 2017-12-03 2024-01-09 Mighty Fire Breaker Llc Environmentally-clean biodegradable water-based concentrates for producing fire inhibiting and fire extinguishing liquids for fighting class A and class B fires
US11865390B2 (en) 2017-12-03 2024-01-09 Mighty Fire Breaker Llc Environmentally-clean water-based fire inhibiting biochemical compositions, and methods of and apparatus for applying the same to protect property against wildfire
US11911643B2 (en) 2021-02-04 2024-02-27 Mighty Fire Breaker Llc Environmentally-clean fire inhibiting and extinguishing compositions and products for sorbing flammable liquids while inhibiting ignition and extinguishing fire
US12168152B2 (en) 2021-02-04 2024-12-17 Mighty Fire Breaker Llc Remotely-triggered wildfire defense system for automatically spraying environmentally-clean water-based liquid fire inhibitor to proactively form thin fire-inhibiting alkali metal salt crystalline coatings on sprayed combustible surfaces prior to wildfire
US12364885B2 (en) 2017-12-02 2025-07-22 Mighty Fire Breaker Llc System for proactively forming and maintaining GPS-tracked and mapped environmentally-clean chemical fire protection zones over the property surfaces of a neighborhood of homes so as to inhibit fire ignition and flame spread in the presence of wild fire

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FR1444056A (en) * 1965-05-13 1966-07-01 Soc Etu Chimiques Ind Et Agri Compositions for extinguishing solutions
DE3100158A1 (en) * 1980-03-12 1981-11-19 Fire Out Enterprises Co. Inc., 13843 South New Berlin, N.Y. FIRE-FIGHTING MEASURES AND THEIR USE FOR FIGHTING BRAZES
EP0059178A1 (en) * 1981-02-12 1982-09-01 Franz Ragailler Use of a solution for extinguishing fires and simultaneously flame-proofing the surroundings of the fire

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FR1338454A (en) * 1962-08-03 1963-09-27 Soc Etu Chimiques Ind Et Agri Extinguishing compositions
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US8080186B1 (en) 2010-11-16 2011-12-20 Pennartz Edmund R J Fire mitigation and moderating agents
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Also Published As

Publication number Publication date
DE3681455D1 (en) 1991-10-17
EP0277116B1 (en) 1991-09-11
EP0277116A1 (en) 1988-08-10

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