DE3527910A1 - Liquid bleaching agent - Google Patents
Liquid bleaching agentInfo
- Publication number
- DE3527910A1 DE3527910A1 DE19853527910 DE3527910A DE3527910A1 DE 3527910 A1 DE3527910 A1 DE 3527910A1 DE 19853527910 DE19853527910 DE 19853527910 DE 3527910 A DE3527910 A DE 3527910A DE 3527910 A1 DE3527910 A1 DE 3527910A1
- Authority
- DE
- Germany
- Prior art keywords
- weight
- bleaching agent
- alkali
- alkyl
- perfume
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000007844 bleaching agent Substances 0.000 title claims abstract description 15
- 239000007788 liquid Substances 0.000 title claims abstract description 7
- -1 alkali metal hypochlorite Chemical class 0.000 claims abstract description 15
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Inorganic materials Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 7
- 239000004094 surface-active agent Substances 0.000 claims abstract description 7
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims abstract description 6
- 239000002304 perfume Substances 0.000 claims description 12
- 150000001447 alkali salts Chemical class 0.000 claims description 9
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 8
- 229910001854 alkali hydroxide Inorganic materials 0.000 claims description 6
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 17
- 239000003945 anionic surfactant Substances 0.000 abstract description 3
- 238000004061 bleaching Methods 0.000 abstract description 2
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 2
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- WEEGYLXZBRQIMU-UHFFFAOYSA-N Eucalyptol Chemical compound C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- KGEKLUUHTZCSIP-HOSYDEDBSA-N [(1s,4s,6r)-1,7,7-trimethyl-6-bicyclo[2.2.1]heptanyl] acetate Chemical compound C1C[C@]2(C)[C@H](OC(=O)C)C[C@H]1C2(C)C KGEKLUUHTZCSIP-HOSYDEDBSA-N 0.000 description 2
- 229930007050 cineol Natural products 0.000 description 2
- 229960005233 cineole Drugs 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000008240 homogeneous mixture Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 229930007744 linalool Natural products 0.000 description 2
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 235000007586 terpenes Nutrition 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229940115397 bornyl acetate Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- SATVIFGJTRRDQU-UHFFFAOYSA-N potassium hypochlorite Chemical compound [K+].Cl[O-] SATVIFGJTRRDQU-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3956—Liquid compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Die Erfindung betrifft ein flüssiges Bleichmittel auf Basis von wäßrigen Alkalimetallhypochloritlösungen, das mit Hilfe eines anionischen Tensidgemisches aus Tensidsulfaten solubilisiert sowie parfümiert ist und sich durch eine besondere Stabilität auszeichnet. Das Bleichmittel ist für allgemeine Bleich- und Desinfektionszwecke im Haushalt geeignet.The invention relates to a liquid bleaching agent based on aqueous Alkali metal hypochlorite solutions using an anionic surfactant mixture is solubilized and perfumed from surfactant sulfates characterized by a special stability. The bleach is for suitable for general bleaching and disinfection purposes in the household.
Aus der DE-AS 20 42 037 ist ein verdicktes flüssiges Bleichmittel auf Basis einer wäßrigen Alkalimetallhypochloritlösung mit Parfüm und eines Tensidgemisches, bestehend aus einem Alkalisalz einer Fettsäure mit 8 bis 18 C-Atomen und einem alkalihypochloritlöslichen Tensid, insbesondere einem Aminoxid, bekannt. Nachteilig an dieser Mischung ist, daß sich diese anfänglich homogene Mischung unter Umständen bei längerer Lagerung trennt.DE-AS 20 42 037 discloses a thickened liquid bleach Basis of an aqueous alkali metal hypochlorite solution with perfume and one Surfactant mixture consisting of an alkali salt of a fatty acid with 8 to 18 carbon atoms and an alkali hypochlorite-soluble surfactant, in particular an amine oxide. The disadvantage of this mixture is that it is initially homogeneous mixture under certain circumstances with longer storage separates.
Aufgabe der vorliegenden Erfindung ist es, für ein Bleichmittel auf Basis einer wäßrigen Alkalimetallhypochloritlösung eine stabile, lagerfähige und homogene Mischung aufzuzeigen.The object of the present invention is for a bleach based an aqueous alkali metal hypochlorite solution a stable, storable and show homogeneous mixture.
Die Lösung der Aufgabe besteht in einem flüssigen Bleichmittel auf der Basis einer wäßrigen Alkalimetallhypochloritlösung, enthaltend Tensidsulfate und Parfüm, das dadurch gekennzeichnet ist, daß es aus 4 bis 10 Gew.% Alkylihypochlorit, 2 bis 10 Gew.% Alkalihydroxid, 0,01 bis 0,5 Gew.% Alkylethersulfat in Form eines Alkalisalzes, 0,1 bis 1,0 Gew.% Alkylsulfat in Form eines Alkalisalzes, 0,05 bis 0,3 Gew.% Parfüm und dem Rest zu 100 Gew.% aus Wasser besteht.The solution to the problem is a liquid bleach on the Basis of an aqueous alkali metal hypochlorite solution containing surfactant sulfates and perfume, which is characterized in that it consists of 4 to 10% by weight alkylihypochlorite, 2 to 10% by weight alkali hydroxide, 0.01 to 0.5% by weight alkyl ether sulfate in the form of an alkali salt, 0.1 to 1.0% by weight Alkyl sulfate in the form of an alkali salt, 0.05 to 0.3% by weight of perfume and the The rest consists of 100% by weight of water.
Die bevorzugte Zusammensetzung besteht aus 5 bis 7 Gew.% Alkalihypochlorit, 5 bis 7 Gew.% Alkalihydroxid, 0,06 bis 0,15 Gew.% Akylethersulfat in Form des Natriumsalzes, 0,2 bis 0,6 Gew.% Alkylsulfat in Form des Natriumsalzes, 0,05 bis 0,3 Gew.% Parfüm und dem Rest zu 100% Wasser.The preferred composition consists of 5 to 7% by weight of alkali hypochlorite, 5 to 7% by weight of alkali hydroxide, 0.06 to 0.15% by weight of alkyl ether sulfate in the form of the sodium salt, 0.2 to 0.6% by weight of alkyl sulfate in the form of sodium salt, 0.05 to 0.3% by weight of perfume and the rest 100% Water.
Mit der erfindungsgemäßen partiellen Zusammensetzung wird in überraschend einfacher Weise eine lagerstabile Formulierung im Hinblick auf die Homogenität und den Chlorgehalt der Lösung erreicht, die sich für die praktische Anwendung auch durch eine vorteilhafte Viskosität auszeichnet.The partial composition according to the invention is surprising in simple way with regard to a storage stable formulation achieved the homogeneity and the chlorine content of the solution, which is suitable for the practical application is also characterized by an advantageous viscosity.
Als Alkalimetallhypochloritlösung wird für die Herstellung der erfindungsgemäßen Zusammensetzung zweckmäßig von einer im Handel erhältlichen Lösung, die in der Regel etwa 13% Aktivchlor enthält, ausgegangen. Bevorzugt wird Natrium- oder Kaliumhypochlorit-Lösung verwendet. As alkali metal hypochlorite solution for the preparation of the invention Appropriately from a commercially available composition Solution, which usually contains about 13% active chlorine, ran out. Prefers sodium or potassium hypochlorite solution is used.
Bei dem zu verwendenden Alkalihydroxid handelt es sich um Natrium- und Kaliumhydroxid, berechnet auf festes Alkalihydroxid.The alkali hydroxide to be used is sodium and Potassium hydroxide, calculated on solid alkali hydroxide.
Erfindungsgemäß wird als anionisches Tensid ein Gemisch aus den Alkalisalzen, insbesondere Na-Salzen, eines Alkylethersulfats und eines Alkylsulfats verwendet.According to the invention, a mixture of the alkali salts, in particular Na salts, an alkyl ether sulfate and an alkyl sulfate used.
Die zu verwendenden Alkylethersulfate bzw. ihre Alkalisalze sind definiert durch den Rest eines gesättigten, geradkettigen oder verzweigten Alkohols mit 12 bis 14 C-Atomen, der mit 2 bis 5 Ethylenoxideinheiten alkoxyliert und mit Schwefelsäure verestert ist. Selbstverständlich kann es sich dabei um die bei der Herstellung anfallenden üblichen Gemische handeln.The alkyl ether sulfates to be used and their alkali salts are defined through the rest of a saturated, straight chain or branched Alcohol with 12 to 14 carbon atoms, with 2 to 5 ethylene oxide units alkoxylated and esterified with sulfuric acid. Of course you can it is the usual mixtures obtained in the production act.
Die zu verwendenden Alkylsulfate bzw. ihre Akalisalze sind definiert durch einen gesättigten, geradkettigen oder verzweigten Alkylrest mit 6 bis 12, bevorzugt 6 bis 10 C-Atomen. Der ganz besonders bevorzugte Rest ist der 2-Ethylhexylrest.The alkyl sulfates to be used and their akali salts are defined by a saturated, straight-chain or branched alkyl radical with 6 to 12, preferably 6 to 10 carbon atoms. The most preferred rest is the 2-ethylhexyl radical.
Die Mischung dieser ganz speziellen anionischen Tensidsulfate innerhalb relativ enger Grenzen führt zu einer homogenen Lösung, die stabil und lagerfähig ist. Interessanterweise führt die Verwendung der genannten Tensidsulfate allein zu einer Lösung, die sich im Laufe der Zeit trennt. Dieser synergistische Effekt im Hinblick auf die Stabilität war in keiner Weise vorhersehbar. Alkylsulfonate mit höheren Alkylresten und Alkylarylsulfonate, führen im Hinblick auf die Stabilität des Aktivchlors zu schlechteren Ergebnissen.The mixture of these very special anionic surfactant sulfates within relatively narrow limits leads to a homogeneous solution that is stable and is storable. Interestingly, the use of the above leads Surfactant sulfates alone into a solution that separates over time. This synergistic effect in terms of stability was none Way predictable. Alkyl sulfonates with higher alkyl radicals and alkyl aryl sulfonates, lead with regard to the stability of the active chlorine worse results.
Die zu verwendenden Parfüme bzw. Parfümmischungen sollen natürlich im wesentlichen beständig gegen Hypochlorit sein, um eine Abnahme des Aktivchlorgehalts so gering wie möglich zu halten.The perfumes or perfume mixtures to be used should of course be in be essentially resistant to hypochlorite in order to keep a decrease in the active chlorine content as low as possible.
Insbesondere haben sich zu diesem Zweck bewährt Parfümmischungen, deren Hauptbestandteile z. B. Bornylacetat (30%), Linalool (20%) und Terpineol (20%) sind; eine Parfümmischung, deren Hauptbestandteile z. B. Terpenkohlenwasserstoffe (10%), Cincol (15%), Linalool (30%) und Campher (10%) sind; reines Cineol; eine Parfümmischung, deren Hauptbestandteile z. B. Terpenkohlenwasserstoffe (5%), Cineol (77%) und p-Cresol (15%) sind. In particular, perfume mixtures have proven themselves for this purpose Main components e.g. B. Bornyl acetate (30%), linalool (20%) and terpineol (20%) are; a perfume mixture, the main components of which, for. B. terpene hydrocarbons (10%), Cincol (15%), Linalool (30%) and Camphor (10%); pure cineol; a perfume mixture, the main components of which, for. B. terpene hydrocarbons (5%), cineol (77%) and p-cresol (15%).
Die erfindungsgemäßen Formulierung werden in an sich üblicher Weise ohne Schwierigkeiten durch Mischen der einzelnen Bestandteile, zweckmäßig in Form ihrer konzentrierten Lösungen, in an sich üblicher Weise hergestellt.The formulation according to the invention are in a conventional manner without Difficulties due to mixing the individual components, useful in Form of their concentrated solutions, prepared in a conventional manner.
Zusammensetzung erfindungsgemäßer Bleichmittel. Teile sind Gewichtsteile. Composition of bleaching agents according to the invention. Parts are parts by weight.
Die frisch hergestellte Lösung weist einen Aktivkohlegehalt von 5,3 bzw. 6,7% auf. Der Chlorgehalt nach 3-monatiger Lagerung bei 23°C beträgt nach iodometrischer Titration etwa 20%. Die Viskosität entspricht den Anforderungen der Praxis.The freshly prepared solution has an activated carbon content of 5.3 or 6.7%. The chlorine content after 3 months of storage at 23 ° C is after iodometric titration about 20%. The viscosity corresponds to the Practical requirements.
Claims (4)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19853527910 DE3527910A1 (en) | 1985-08-03 | 1985-08-03 | Liquid bleaching agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19853527910 DE3527910A1 (en) | 1985-08-03 | 1985-08-03 | Liquid bleaching agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE3527910A1 true DE3527910A1 (en) | 1987-02-12 |
Family
ID=6277627
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19853527910 Withdrawn DE3527910A1 (en) | 1985-08-03 | 1985-08-03 | Liquid bleaching agent |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE3527910A1 (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3815456A1 (en) * | 1988-05-06 | 1989-11-16 | Cealin Chem Fab | AQUEOUS SOLUTION FOR OXIDATION, DISMOUNTING AND DESODORATION, AND METHOD FOR PRODUCING THIS SOLUTION |
| EP0340371A3 (en) * | 1988-05-05 | 1990-04-04 | Henkel Iberica, S.A. | Bleaching composition containing alkaline hypochlorite and process for its manufacture |
| EP0302705A3 (en) * | 1987-08-07 | 1990-09-05 | The Clorox Company | Mitigation of stress-cracking in stacked loads of fragranced bleach-containing bottles, bottles containing such fragranced bleach, bleach for use in such bottles, and storage systems including such bottles |
| US5080826A (en) * | 1987-08-07 | 1992-01-14 | The Clorox Company | Stable fragranced bleaching composition |
| EP0478086A2 (en) | 1990-09-25 | 1992-04-01 | Colgate-Palmolive Company | Stable microemulsion disinfecting detergent composition |
| AU625848B2 (en) * | 1989-05-03 | 1992-07-16 | Clorox Company, The | Thickened hypochlorite bleach solution and method of use |
| US5227366A (en) * | 1987-08-07 | 1993-07-13 | The Clorox Company | Mitigation of stress-cracking in fragranced bleach-containing bottles |
| US6036789A (en) * | 1998-02-25 | 2000-03-14 | Reckitt & Colman Inc. | Aqueous cleaning compositions containing 2-ethylhexyl sulfate and optionally myristyldimethylamine oxide for removing soap scum |
| US6180583B1 (en) | 1992-11-03 | 2001-01-30 | The Procter & Gamble Company | Cleaning compositions containing short-chain surfactants |
-
1985
- 1985-08-03 DE DE19853527910 patent/DE3527910A1/en not_active Withdrawn
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0302705A3 (en) * | 1987-08-07 | 1990-09-05 | The Clorox Company | Mitigation of stress-cracking in stacked loads of fragranced bleach-containing bottles, bottles containing such fragranced bleach, bleach for use in such bottles, and storage systems including such bottles |
| US5080826A (en) * | 1987-08-07 | 1992-01-14 | The Clorox Company | Stable fragranced bleaching composition |
| EP0518451A1 (en) * | 1987-08-07 | 1992-12-16 | The Clorox Company | Homogeneous fragrance preblend |
| US5227366A (en) * | 1987-08-07 | 1993-07-13 | The Clorox Company | Mitigation of stress-cracking in fragranced bleach-containing bottles |
| EP0340371A3 (en) * | 1988-05-05 | 1990-04-04 | Henkel Iberica, S.A. | Bleaching composition containing alkaline hypochlorite and process for its manufacture |
| DE3815456A1 (en) * | 1988-05-06 | 1989-11-16 | Cealin Chem Fab | AQUEOUS SOLUTION FOR OXIDATION, DISMOUNTING AND DESODORATION, AND METHOD FOR PRODUCING THIS SOLUTION |
| AU625848B2 (en) * | 1989-05-03 | 1992-07-16 | Clorox Company, The | Thickened hypochlorite bleach solution and method of use |
| EP0478086A2 (en) | 1990-09-25 | 1992-04-01 | Colgate-Palmolive Company | Stable microemulsion disinfecting detergent composition |
| US6180583B1 (en) | 1992-11-03 | 2001-01-30 | The Procter & Gamble Company | Cleaning compositions containing short-chain surfactants |
| US6036789A (en) * | 1998-02-25 | 2000-03-14 | Reckitt & Colman Inc. | Aqueous cleaning compositions containing 2-ethylhexyl sulfate and optionally myristyldimethylamine oxide for removing soap scum |
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