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WO1987006272A1 - Materiau pour realiser un alliage d'un metal et de vanadium - Google Patents

Materiau pour realiser un alliage d'un metal et de vanadium Download PDF

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Publication number
WO1987006272A1
WO1987006272A1 PCT/SU1986/000030 SU8600030W WO8706272A1 WO 1987006272 A1 WO1987006272 A1 WO 1987006272A1 SU 8600030 W SU8600030 W SU 8600030W WO 8706272 A1 WO8706272 A1 WO 8706272A1
Authority
WO
WIPO (PCT)
Prior art keywords
vanadium
oxide
metal
iron
alloying
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/SU1986/000030
Other languages
English (en)
Russian (ru)
Inventor
Leonid Andreevich Smirnov
Jury Stepanovich Schekalev
Anatoly Anatolievich Filippenkov
Vyacheslav Nikolaevich Zelenov
Irek Nasyrovich Gubaidullin
Ganbar Nutfullovich Nutfullin
Ivan Timofeevich Ryabov
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHUSOVSKOI METALLURGICHESKY ZAVOD
URALSKY NAUCHNO-ISSLEDOVATELSKY INSTITUT CHERNYKH
Original Assignee
CHUSOVSKOI METALLURGICHESKY ZAVOD
URALSKY NAUCHNO-ISSLEDOVATELSKY INSTITUT CHERNYKH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHUSOVSKOI METALLURGICHESKY ZAVOD, URALSKY NAUCHNO-ISSLEDOVATELSKY INSTITUT CHERNYKH filed Critical CHUSOVSKOI METALLURGICHESKY ZAVOD
Priority to JP61503680A priority Critical patent/JPS63502995A/ja
Priority to EP19860904463 priority patent/EP0268679A4/fr
Priority to PCT/SU1986/000030 priority patent/WO1987006272A1/fr
Publication of WO1987006272A1 publication Critical patent/WO1987006272A1/fr
Priority to CN87107749A priority patent/CN1033076A/zh
Priority to FI875570A priority patent/FI875570A7/fi
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C33/00—Making ferrous alloys
    • C22C33/006—Making ferrous alloys compositions used for making ferrous alloys

Definitions

  • a wide area of technology The current invention is not available in the area of black metal and is more suitable for alloying with vanadium.
  • vanadium For the manufacture of light-alloying vanadium alloys and first of all, pure vanadium is required to protect and equal to the available vanadium oxide, while for the use of iron, vanadium is used. This is the reason for the search for new alloying vanadium-containing materials. Due to this, it was recommended to use vanadium slag, which is obtained by oxidizing 20 vanadium cast iron, as a result of the reduction of vanadium material.
  • the slag used here contains a large percentage: iron oxide - 41.6 oxides of oxide - 16.4 oxides of vanadium - 15.8 oxides of manganese - 9.1 30 oxides of titanium - 7.4 oxides of oxide - 2.8 oxides 1.5 metal phase - 8-12 ⁇ mixtures ( ⁇ , ⁇ 2 ⁇ ) - Other. 35 The indicated rule is written in the book of ⁇ .P. Dekishev and other "Canada in black metal”. Publishing House “Metallurgy”, Moscow, 1983, p. 36, the same consequence
  • the design is made in the form of two-layer granules with a diameter of 5 metro 5-20 mm.
  • a large amount of carbon was conserved, and the internal layer was completed on a separate basis, which was completed on September 21, 1998.
  • the waste of these products is less than 10 years, and there is a low rate of growth in the metal, which prolongs the process of lightening and lowers the output of the
  • the main task of the invention was to find a material for alloying vanadium, 20 which would increase the energy supply and increase
  • P ⁇ s ⁇ avlennaya problem was ⁇ eshena ⁇ em, ch ⁇ for legzh ⁇ vaniya me ⁇ alla ⁇ edl ⁇ zhen ma ⁇ e ⁇ ial as g ⁇ anul 25 s ⁇ de ⁇ zhaschy me ⁇ alliches ⁇ uyu s ⁇ s ⁇ avlyayuschugo, ⁇ y, s ⁇ g- lasn ⁇ iz ⁇ b ⁇ e ⁇ eniyu, ⁇ a ⁇ a ⁇ e ⁇ izue ⁇ sya ⁇ em, ch ⁇ me ⁇ alliches- ⁇ aya s ⁇ s ⁇ avlyayuschaya ⁇ y ⁇ a ⁇ b ⁇ l ⁇ ch ⁇ y of ⁇ sh ⁇ v ⁇ y s ⁇ s ⁇ evlyayuschey s ⁇ s ⁇ ava in wt.%: 10 ⁇ sid ⁇ emniya -24
  • This explosive disintegration of the material significantly increases the reactivity of the medicament to the alloying material and the liquid, as well as to the
  • the positive effect of “encapsulation” of the metallic component of the refractory and mercantile part is acceptable.
  • the size (average diameter) is less than 0.5 mm, the described effect is weaker due to the insufficient thickness of the slump.
  • Oxides which are part of the slavic component of the granule, play a double role.
  • oxides such as iron and brown, create a silica component that accelerates the reduction of iron and vanadium oxides.
  • d ⁇ ug ⁇ y - ⁇ bladaya znachi ⁇ eln ⁇ y s ⁇ bschey ⁇ ⁇ islam vanadium and ⁇ i ⁇ ana and ⁇ s ⁇ benn ⁇ ⁇ islam ⁇ ma ⁇ b- ⁇ azuyuschi ⁇ vmes ⁇ e with ⁇ sidami iron ⁇ m ⁇ le ⁇ sny shshshelid, sili ⁇ a ⁇ naya s ⁇ s ⁇ avlyayuschaya u ⁇ chnyae ⁇ sya and ⁇ same v ⁇ emya vsleds ⁇ vie presence ⁇ isl ⁇ v ma ⁇ gantsa ⁇ sh ⁇ smachivae ⁇ me ⁇ alliches ⁇ uyu s ⁇ s ⁇ aa
  • the proposed alloying material will possess
  • the constituents of the constituents of the oxide material, forming mineral compounds, are mutually compatible
  • the metal concentrate is intrinsically safe and this is not the case.
  • the material may be-
  • the indicated linguistic material is obtained by the following method.
  • the final grade of slag produced by the vanadium-containing cast iron in acidic inverters is crushed to a fraction of 0.5-30 mm, after that
  • vanadium doping 25 10-30% in comparison with those alloyed with known alloying materials, there are also 50-100 costs of vanadium doping.
  • the usability of vanadium from the legal material is 85–88.
  • Oxidative conversion to metal is introduced with 100% vanadium material, which, in the process of melting without downloading slag, guarantees a transition to metal, 85%, - 9 - loaded into the furnace. And increased reliability and durability of the metal by 20-30. The costs of the production of legally produced metal are reduced by 50% compared with the alloying of the metal by well-known companies. 5 3. An arc furnace melted a plasma containing 35–45 vanadium and 1-25% brown.
  • the assimilation of vanadium by the metal from the proposed alloying material was 95.4%.
  • the smelter smelted carbon steel, containing stainless steel and vanadium.
  • the metallic component of the lightweight material was in wt.%: Carbon - 2.4, vanadium - - 0.03, ⁇ ⁇ m - 0.03, manganese - 0.04, iron - other, - Yu - and the slag component, taken in quantities of 95% of the weight of the granule, consisted, wt.%: Oxide oxide - 10; oksid vayadiya - 25; manganese oxide - 14; titanium oxide - 10; oxid ⁇ lake - 4; calcium oxide - 3; Oxide - 5 leza - the rest.
  • the alloy smelted coal containing steel and vanadium, from. cost of carbon, which is 70% of the total coal output, 20% of waste, which is 2.5% of carbon, 0.03%, 0.03%, 0.03%, 0.03%, 0.03%, 0.03%, 0.03%, 0.03%
  • the product contains 2.7% of carbon, 0.04% of carbon, 0, 020% of sulfur and 0.05% of vanadium. On average, there are also 5 limes and a 2.5% chamois.
  • the fittings are lightweight material, with a size of 30 mm.
  • the metal component was in wt.%: Iron and steel - 2.9;
  • the metal component of the alloying material was in wt.% ,. carbon - 3.1, vanadium - 0.03, ⁇ - traces, manganese - traces, iron - the rest, and the slurry is mainly the bulk, taken in a quantity of 90 weight weight, it was ⁇ . acidity ⁇ emnia - 18; vanadium oxide - 18; manganese oxide - 6; titanium oxide - 6; oxycid ⁇ ma - 3; acid oxide - 30; Iron Oxide - Ost. After the slag was depleted at an unprecedented strength and 10 min, the metal was released.
  • the assimilation of vanadium was 86.2;
  • the relative wear and tear of rolls doped with vanadium due to the specified material increased by 20% compared to rolls doped with vanadium, and the cost was 80%.
  • Example 5 The assimilation of vanadium was 86.2; The relative wear and tear of rolls doped with vanadium due to the specified material increased by 20%
  • the arc furnace melted an alloy containing 35–45% vanadium and 5–25 silicon.
  • the indicated alloying material was introduced in a quantity of 20% (in the case of vanadium). The system was entered on the front of the furnace before downloading the rest of the circuit.
  • a non-metallic component was lightweight, wt.%: Carbon was -3.5, vanadium was 0.05, it was a little more than iron, and 50% of the weight of the granules, consisted, wt.% .: ' : oxide acid - 14; vanadium oxide - 20; manganese oxide - 6; titanium oxide - 4; oxid ⁇ ma - 3; magnesium oxide - 20; acid oxide - 22; Iron Oxide - Other.
  • the invention may be used in industrial applications for leggings.
  • - 13 - nadim chugz / na steel for alloys and for the production of vanadium is a part of the industry.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Nonmetallic Welding Materials (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

Un matériau pour réaliser un alliage d'un métal et de vanadium comprend un constituant métallique recouvert d'un enrobage composé d'un constituant de production d'alliage dont la composition en pourcentage en poids est comme suit: 10-24 d'oxyde de silicium, 14-25 d'oxyde de vanadium, 4-14 d'oxyde de manganèse, 3-10 d'oxyde de titane, 1-4 d'oxyde de chrome, 3-50 d'oxyde de calcium et/ou d'oxyde de magnésium, le solde étant sous forme de fer. Dans ledit matériau, la teneur en matériau métallique contenant du carbone, du métal et du fer est de 5-95, le solde étant représenté par le constituant de production d'alliage. Le matériau se présente sous forme de granulés dont la dimension est comprise entre 0,5 et 30,0 mm.
PCT/SU1986/000030 1986-04-18 1986-04-18 Materiau pour realiser un alliage d'un metal et de vanadium Ceased WO1987006272A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP61503680A JPS63502995A (ja) 1986-04-18 1986-04-18 金属をバナジウムと合金化する材料
EP19860904463 EP0268679A4 (fr) 1986-04-18 1986-04-18 Materiau pour realiser un alliage d'un metal et de vanadium.
PCT/SU1986/000030 WO1987006272A1 (fr) 1986-04-18 1986-04-18 Materiau pour realiser un alliage d'un metal et de vanadium
CN87107749A CN1033076A (zh) 1986-04-18 1987-11-10 金属加钒合金化所用的材料
FI875570A FI875570A7 (fi) 1986-04-18 1987-12-17 Material foer legering av en metall medelst vanadin.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/SU1986/000030 WO1987006272A1 (fr) 1986-04-18 1986-04-18 Materiau pour realiser un alliage d'un metal et de vanadium

Publications (1)

Publication Number Publication Date
WO1987006272A1 true WO1987006272A1 (fr) 1987-10-22

Family

ID=21616986

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/SU1986/000030 Ceased WO1987006272A1 (fr) 1986-04-18 1986-04-18 Materiau pour realiser un alliage d'un metal et de vanadium

Country Status (4)

Country Link
EP (1) EP0268679A4 (fr)
JP (1) JPS63502995A (fr)
FI (1) FI875570A7 (fr)
WO (1) WO1987006272A1 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5242483A (en) * 1992-08-05 1993-09-07 Intevep, S.A. Process for the production of vanadium-containing steel alloys
RU2200767C2 (ru) * 2001-04-04 2003-03-20 Уральский государственный технический университет (Уральский политехнический институт) Сплав для микролегирования и модифицирования стали
RU2319776C1 (ru) * 2006-05-31 2008-03-20 Юлия Алексеевна Щепочкина Комплексный сплав для раскисления и легирования стали
RU2319777C1 (ru) * 2006-05-31 2008-03-20 Юлия Алексеевна Щепочкина Комплексный сплав для раскисления и легирования стали
BRPI0822168B1 (pt) 2008-04-22 2016-11-16 Nat Cen Of Complex Proc Of Mineral Raw Mat Of Rep Of Kazakhstan liga para desoxidação e fundição de aço

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1046297A1 (ru) * 1982-06-04 1983-10-07 Научно-производственное объединение "Тулачермет" Комплексный модификатор

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1471448A (fr) * 1966-03-10 1967-03-03 Vanadium Corp Of America Procédé de fabrication de briquettes de carbure de vanadium
DE2509650C2 (de) * 1975-03-05 1982-01-21 Central'nyj naučno-issledovatel'skij institut černoj metallurgii imeni I.P. Bardina, Moskva Verfahren zur schmelzmetallurgischen Herstellung von vanadinhaltigen Legierungen
DE2810458A1 (de) * 1978-03-10 1979-09-20 N Proizv Ob Tulatschermet Verfahren zur herstellung von ferrovanadin-legierungen

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1046297A1 (ru) * 1982-06-04 1983-10-07 Научно-производственное объединение "Тулачермет" Комплексный модификатор

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
N. P. LYAKISHEV, et al. "Vanady v Chernoi Metallurgii", 1983, Metallurgia (Moscow), see page 36 *
See also references of EP0268679A4 *

Also Published As

Publication number Publication date
EP0268679A4 (fr) 1989-09-19
FI875570A0 (fi) 1987-12-17
EP0268679A1 (fr) 1988-06-01
JPS63502995A (ja) 1988-11-02
FI875570A7 (fi) 1987-12-17

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