WO1983003222A1

WO1983003222A1 - Extruder mixer

Info

Publication number: WO1983003222A1
Application number: PCT/GB1982/000086
Authority: WO
Inventors: And Plastics Research Association Of Great Rubber; George Martin Gale
Original assignee: Rubber and Plastics Research Association of Great Britain
Current assignee: Rubber and Plastics Research Association of Great Britain
Priority date: 1982-03-15
Filing date: 1982-03-15
Publication date: 1983-09-29
Anticipated expiration: 1984-09-15
Also published as: SE8402071L; ATA907982A; SE8402071D0; CH662778A5; DK520083A; BR8208088A; NO162183B; DK520083D0; AT393989B; DK160750C; NO162183C; SE438282B; DK160750B; NO834033L

Abstract

Une mélangeuse extrudeuse comprend un stator cylindrique creux (14) possédant un rotor cylindrique (10) tourillonné à l'intérieur, les surfaces cylindriques en vis à vis du rotor et du stator étant pourvues respectivement de pluralités de rangées parallèles de cavités hémisphériques (18, 20) s'étendant sur la circonférence. Afin d'obtenir des caractéristiques exponentielles de mélange dans lequel un simple mélange par cisaillement est interrompu périodiquement par des étapes de coupe et de retournage, les cavités de rotor et de stator (18, 20) sont disposées de manière que (a) les cavités (20) dans des rangées adjacentes sur le stator sont décalées vers la circonférence, (b) les cavités (18) dans des rangées adjacentes sur le rotor sont décalées vers la circonférence, et (c) les rangées de cavités (18, 20) sur le stator et le rotor sont décalées axialement.An extruder mixer comprises a hollow cylindrical stator (14) having a cylindrical rotor (10) journalled therein, the cylindrical surfaces facing the rotor and the stator being respectively provided with pluralities of parallel rows of hemispherical cavities (18, 20) spanning the circumference. In order to obtain exponential mixing characteristics in which a simple shear mixing is interrupted periodically by cutting and turning steps, the rotor and stator cavities (18, 20) are arranged so that (a) the cavities (20) in adjacent rows on the stator are offset towards the circumference, (b) the cavities (18) in adjacent rows on the rotor are offset towards the circumference, and (c) the rows of cavities (18, 20) on the stator and the rotor are offset axially.

Description

DESCRIPTION "EXTRUDER KIXER"

The present invention relates to extruder mixers for viscous fluids, such as molten plastics and rubbers, and is particularly concerned with extruder mixers of the cavity-trans er type.

An example of a known cavity-transfer type extruder mixer is that disclosed in British Patent Specification No. 930 339 and includes a hollow cylindrical stator member and a cylindrical rotor member which is rotatable within the stator. The facing cylindrical surfaces on the rotor and stator carry respective pluralities of rows of elongate, longitudinally extending grooves. The rows of grooves on each member extend peripherally around the member and are spaced apart axially, the rows on one member being axially offset from the rows on the other member whereby there is axial overlap of the grooves in adjacent rows on the stator and rotor. By virtue of this arrangement of overlapping closed cavities on the rotor and stator, material progressing through this mixer has to travel in a path which alternates between rotor and stator cavities. Where a cavity on one meiafoer happens to be opposite a land on the other member the material is subjected to simple shear so that it is cut in half before being displaced approximately at right angles to its original direction as it passes into the next cavity. Another known machine of this type is -described in British Patent Specification No. 1 475 216.

It has been found that, whereas such mixers operate satisfactorily when constructed on a small, laboratory scale, when scaled up to a large production size machine the efficiency of the mixer falls, a size limitation being reached where either the product is unsuitable or the added length necessary makes engin- eering complexity uneconomic. This is because the output rate per screw revolution of an extruder increases in proportion to the cubed power of the screw diameter whereas the available mixer area increases by only the square of the screw diameter if the length to diameter ratio of the mixer is kept constant.

If one attempts to increase the mixing capacity by making the cavities deeper then, for example in the case of molten plastics, there is a risk of polymer stagnation and degradation occurring in the corners of the^* cavities.

It is an object of the present invention to provide ^"an extruder mixer and mixing process which enables large scale operation whilst reducing the problems of the known mixers outlined above.

In accordance with one aspect of the present invention this is achieved by arranging the rotor and stator cavities in parallel rows on the rotor and stator such that (i) the cavities in adjacent rows on the stator are circumferentially offset, (ii) the cavities in adjacent rows on the rotor are circumferentially offset and (iii) the rows of cavities on the stator and rotor are axially offset.

By this means, an overall increase in mixing capacity for the same surface area can be obtained whilst achieving a desired exponential mixing charac¬ teristic in wnich simple shear mixing is repeatedly interrupted by cutting and turning stages.

Preferably, in the case of both the stator and the rotor, the circumferential offset is equal to half the circumferential distance between the centres of adjacent cavities in a row. _ ^ _.

The axial offset of the stator and rotor rows is preferably equal to half the axial spacing between adjacent rotor or stator rows. Particularly when the circumferential offset corresponds to half the centre spacing between adjacent cavities in a row and the axial offset is such that the adjacent edges of the cavity mouths in each pair of 5 adjacent rows on the stator or rotor lie on or adjacent the centre line of the cavities in a row on the rotor or stator, respectively, tne cavities can be packed together so as to occupy about 60% or more of the respective stator and rotor surfaces and so as to 10 increase the number of transfer points between the rotor and stator compared with known mixers and hence achieve better ixing. The resulting staggered formation achieves better mixing by dividing the melt streams, better transfer of material and hence higher output 15 rate for the same pressure drop.

Preferably, the rotor and stator cavities all have circular mouths.

In accordance with a second aspect of the present invention, there is provided an extrusion mixing 20 process in which two or more components are mixed by transfer between rows of cavities within both a hollow cylindrical stator and a cylindrical rotor journalled therewithin, an exponential mixing process being obtained by repeated cutting and turning operations on 25 the mixture at the transfers between cavities on the opposed faces of the stator and rotor and by dividing the mixture flow between pairs of adjacent cavities on the same rotor or sta.tor face by means of a respect¬ ive overlapping cavity on the opposite stator or rotor 30 face.

In accordance with a third aspect of the present invention the rotor and stator cavities are of hemis¬ pherical configuration and are arranged in parallel rows on the rotor and stator such that (i) the cavities 35 in adjacent rows on the stator are circumferentially

offset, (ii) the cavities in adjacent rows on the rotor are circumferentially offset and (iii) the rows of cavities on the stator and rotor are axially offset. The invention is described further hereinafter, by way of example, with reference to the accompanying drawings, in which:-

Fig.l -is a longitudinal section through an assembled mixer in accordance with the present invention; Fig.2 is a transverse section through the rotor alone, taken along the line II-II in Fig.l;

Fig.3 is a transverse section through the stator alone taken along the line III-III in Fig.l;

Fig.4 is a developed view of part of the rotor and stator illustrating the axial offset of the rows of hemispherical depressions in the rotor and stator; and

Fig.5 is an experimental graph illustrating the improved mixing characteristic of a mixer in accordance with the present invention compared with a known mixer. The illustrated mixer includes a rotor 10 which is rotatably mounted within a basically cylindrical bore 12 in a stator 14. The right-hand end of the rotor 10, as viewed in Fig.l, is adapted to be keyed to the output end of a screw conveyor (not shown) and the left-hand end of the stator 14 is adapted to be attache to an extrusion die (not shown) whereby material being processed, e.g. polymer is forced between the rotor and stator in passing from the screw conveyor to the extrusion die. The arrangement described so far is conventional.

As shown in the drawings, the facing surfaces 16 and 12 on the rotor and stator are formed with respective pluralities of hemispherical cavities 18,20. The cavities 18 on the rotor are disposed in a plurality of circumferentially extending rows. As

OMPI indicated in Fig.2, Fig.3 and Fig.4, adjacent rows on the rotor are circumferentially displaced such that the centre of each cavity in a-given row lies midway between the centres of the two nearest cavities in the or each adjacent row. This can best be seen from the developed view of Fig. where, for example, the circles 18a, 18b, 18c represent the cavities in one row on the 'rotor and the circles 18a', 18b' 18c' and 18a", 18b" 18c" represent the cavities in the adjacent rotor rows. It will be noted that the circle identified as 18b is offset in the circumferential direction from the adjacent circles 18a*, 18b', 18a" and 18b" by half the distance between the centres of any two adjacent cavities in a row, e.g. between the centres of the cavities 18a and 18b.

In a similar manner, the cavities 20 on the stator are disposed in a plurality of circumferentially extending rows, adjacent rows on the stator again being circumferentially displaced such that the cavities in a given row are offset by half the distance between the centres of any two adjacent cavities in a row.

In addition to the above-described offset nature of the adjacent rows of cavities on the rotor and stator, the relative axial positions of the rows on the rotor and stator are also offset as best seen in Fig.4, such that the circumferential line joining the centre of any given row of cavities on the stator lies in the same axial position as a circumferential line positioned midway between the two circumferential lines joining the centres of the cavities in the two adjacent rotor rows. Thus, for example, in Fig.4 the centres of the stator cavities 20a, 20b lie on a circumferential line positioned midway between the circumferential line joining the centres of rotor cavities 18a", 18b", 18c" and the circumferential line joining the centres of the rotor cavities 18a, 18b, 18c. his arrangement results in- several practical advantages compared with the originally described known arrangements. The mixing capacity for the same εurface area is considerably increased compared with the initially described arrangements. The configuration of the hemispherical cavities can be arranged so that overlaps occur between three cavities at any given time so that extra mixing or blending is obtained by repeated division of the melt streams. The hemispher¬ ical shape gives excellent streamlining so that, for example, polymer stagnation will not occur and purging is efficient when polymer changes are made. The hemispherical cavities can be cut with a ball end milling cutter which makes machining comparatively simple. Polishing is also easy so that overall manu¬ facturing costs are reduced. Removal of polymer from hemispherical cavities is comparatively easy, which reduces cleaning time of the mixer and therefore "down- time" in production situations.

In an experimental comparison of a mixer as described above and a mixer of the known type described initially, striation thickness measurements of flexible PVC samples removed from the ejected stator of the present mixer following black striation injection before the mixer gave a graph (Fig.5) of log striation thickness ratio versus mixer stage which had a steeper gradient (curve A) than when the same test was repeated with the known mixer (curve B), i.e. mixing was improved in the present mixer.

Although illustrated as being purely hemispherical, the rotor and stator cavities can also be in the form of cylinders, or of radiussed cylinders, i.e. a cylindrical cavity having radiussed closed end, and cylinder and hemispheres, i.e. a cylindrical cavity having a hemispherical closed end. The cylindrical arrangement is not favoured, however, as it can give rise to dead spots where unmixed material can lodge. Other cavity configurations, such as diamond-shaped, are possible but it is preferred for the cavities to have circular mouths.

Whereas the aforegoing description has been concerned particularly with the mixing of- molten plastics and rubbers, the present mixer and process is also useful for mixing operations on other viscous fluids, such as soaps, doughs, clays and margarines.

Furthermore, the above-described mixer has useful applications in injection moulding systems for mixing, at a position upstream of an injection die or dies, components which are to be injection moulded.

Claims

CLAI MS

1. An extruder mixer comprising a hollow cylind¬ rical stator member (14), a cylindrical rotor member (10) journalled for rotation within the stator, the facing cylindrical surfaces (16,12) of the rotor and stator carrying respective pluralities of parallel, circumferentially extending rows of cavities (18,20), characterised in that the cavities are disposed with: (a) the cavities in adjacent rows on the stator circumferentially offset; (b) the cavities in adjacent rows on the rotor circumferentially offset; and

(c) the rows of cavities on the stator and rotor axially offset.

2. An extruder mixer as claimed in claim 1, wherein, in the case of both the stator and the rotor, the circumferential offset between the cavities in adjacent rows is equal to half the circumferential distance between the centres of adjacent cavities in a row.

3. An extruder mixer as claimed in claim 1 or 2, wherein the axial offset of the stator and rotor rows is equal to half the axial spacing between adjacent stator and rotor rows, respectively.

4. An extruder mixer as claimed in claim 1 or 2, wherein the rotor and stator cavities have circular mouths.

5. An extruder mixer as claimed in claim 1 or 2, 'wherein the rotor and stator cavities are of hemis¬ pherical configuration.

6. An extrusion mixing process in which two or more components are mixed by transfer between rows of cavities within both a hollow cylindrical stator and a cylindrical rotor journalled therewith, characterised

OMPI in that an exponential mixing process is obtained by repeated cutting and turning operations on the mixture at the transfers between cavities on the opposed faces of the stator and rotor and by dividing the mixture flow between pairs of adjacent cavities on the same rotor or stator face by means of a respective over¬ lapping cavity on the opposite stator or rotor face.