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US950798A - Process for sintering ore. - Google Patents

Process for sintering ore. Download PDF

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Publication number
US950798A
US950798A US52792009A US1909527920A US950798A US 950798 A US950798 A US 950798A US 52792009 A US52792009 A US 52792009A US 1909527920 A US1909527920 A US 1909527920A US 950798 A US950798 A US 950798A
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Prior art keywords
ore
furnace
smelting
treatment
sintering
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US52792009A
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George G Vivian
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JESSE KNIGHT
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JESSE KNIGHT
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/14Agglomerating; Briquetting; Binding; Granulating
    • C22B1/16Sintering; Agglomerating

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  • Ile 1t known that I, GEORGE G. VIVIAN, a cltizen of the United States. residing at Tintic, in the county of Juab and State of Utah,
  • My invention relates to improvements in ore smelting processes, and the objects of my invention are to provide an ore treatment for finely crushed ore, flue dust and concentrates which will conserve the fuel elements of the material and put it into the best possible condition for the subsequent smelting operations, which treatment will result in a saving of fuel; will require a less amount of barren material to be added to the charge; will result in increased capacity of the furnace, and enable material to be treated in a blast furnace -that could not otherwise be profitably treated therein.
  • Figure 1 is an outside elevation, medial portions cut away.
  • Fig. 2 is a vertical,
  • Fig. 3 is a horizontal section, on line ,m 00 Fig. 1, medial portions cut away.
  • Fig. ⁇ 4 is a transverse vertical section, on line 3 eFig. I.
  • My process comprises the sintering of the material and the burning out of deleterious matter, which treatment results in a more complete and thorough separation of the metallic values from ores by the subsequent smelting treatment in another furnace, than any roasting and smelting processes known by me to be in use, especially is this so when ores are crushed into small pieces and carry considerable fine material: and in the smelting of concentrates and fine dust.
  • this fine dust is mixed with milk of lime, making a plastic mass, which is then pressed into briquets and dried; which briquets yet retain all the deleterious matter.
  • These briquets are again sent through the smelter mixed with other ore for treatment; but it is found that a greater percentage of dust rises from the briquets than from an equal amount of ore, which dust is again to be caiwht, briquetted and smelted. I accomplisi this sintering treatment in some cases by taking advantage of the sulfur elements of ores.
  • the sintering treatment for this class of ore is for the purpose of same percentage of" driving off this second and useless atom of sulfur, controlling the heat applied to the ore, and arresting the process of roast1ng at such point; and'thereby'conserving the sulfur in the ore, and then withdrawingthe ore from the furnace, so that when it is charged into the blast furnace the monosulfid of iron (FeS) can be kept intact until it reaches the smelting-zone, where it meets the blast, and advantage is taken of the oxidation of the remaining sulfur and the iron to carry the smelting process to the end.
  • FeS iron
  • the ore can be fed hot into the blast furnace, but itmust be cooled sufiiciently just before or afterit leaves the sintering furnace to stop further chemical change, in orderto reserve the balance of the sulfur for the-final operation of smelting in the smelting'zone of the blast furnace.
  • roastinglgof ores for the purpose of getting rid 'of the sulfur and ox dlzmg the metals is not new, but the arre s .of the treatment at the point of time who tl 1c ore reaches a sticky or pasty condition, and the eliminating from the ore an exact portion of sulfur while retaining the remaining atom of sulfur, is new.
  • the sintering of the flue dust instead of briquetting it has the advantage of a saving of time, the putting the dust into better form physically, the burning off of objectional matterand preventing a reaccumulation of dust from the smelting of briquets made from flue dust.
  • LettersfPatent N 0. 862683 under the title of Automatic,ore-smelting process for reverberatory-furnaces, and as well in all furnaces, that a sintering treatment should be given to the finely crushed ores, such as are now shipped from minesto smelters, concentrates, and fluedi st, in order to secure, enlarged capacity for the smelter, reduction in cost of smelting, loss in flue dust, a saving of fuel, and economical treatment in blast furnaces of concentrates and fine dust.
  • furnace is not capable of sintering ores
  • This furnace enables me to give the treatment desired by my process which is in the nature of a. roast, but
  • A is the foundation
  • B and 7 O are the side walls which are suitably supported by I beams D.
  • 1 is the front end wall, 2 the rear end wall, 3 is the roof and 4, the bottom.
  • a fuel feeding door 5 At the front end 1, is provided a fuel feeding door 5, and in the same end is fitted the fire box 6, which consists of grate bars 7 suitably supported on I beams 8, beneath which is the ash pit 9.
  • a horizontally placed hearth 10 is built extending from the said fire box 6, to rear or other end of the furnace. In the rear end of the furnace is built the fine 1], leading to the stack.
  • On the front end of the hearth 10 is the bridge wall 19., within which is formed a horizontal cold air conduit 13,with openings 14, therefrom into the heat chamber 15 of the furnace. This cold air conduit 13, extends through each side wall.
  • each ore chute is fitted with an ore hopper 19.
  • a process for treating ore which consists of subjecting the ore to the action of heat, while the ore is at rest, suliicient to cause it to become sticky, then removing the ore from the heat and manipulating it to form irregular lumps, as and for the purpose described.
  • a process fort-reating ore which consists of spreading the ore in a thin layer on the hearth witlnn a furnace, subjecting it while so spread to the action of heat sufiicient to tause it to become sticky, then removing the ore from the heat and manipulating it to form nodules.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Description

G. G. VIVIAN.
PROCESS FOR SINTERING ORE.
L APPLICATION FILED NOV. 13. 1909.
950,798 y Patented Mar.1,1910.
2 SHEETS-SHLET 1.
W a f M Jaa7lrn 7y??? aw G. G. VIVIAN.
PROCESS FOR SINTERING ORE. APBLIGATION FILED NOV.-l3. 1909.
Patented Mar.1,1910.
2 SHEETS-SHEET 2.
Fro.
GEORGE G. VIVIAN, OF TINTIC, UTAH, ASSIGNOR OF ONE-HALF TO JESSE. KNIGHT, OF PROVO, UTAH.
Specification of letters Patent.
Patented Mar. 1,1910.
Application filed November 13, 1909. Serial No. 527,920.
To all wh0m it may concern:
Ile 1t known that I, GEORGE G. VIVIAN, a cltizen of the United States. residing at Tintic, in the county of Juab and State of Utah,
5 My invention relates to improvements in ore smelting processes, and the objects of my invention are to provide an ore treatment for finely crushed ore, flue dust and concentrates which will conserve the fuel elements of the material and put it into the best possible condition for the subsequent smelting operations, which treatment will result in a saving of fuel; will require a less amount of barren material to be added to the charge; will result in increased capacity of the furnace, and enable material to be treated in a blast furnace -that could not otherwise be profitably treated therein. I attain these objects. by means of my process, which may be carried into practice in a sintering furnace which I have invented especially for use in my present process, and which is illustrated in the accompanying drawings, in which,
Figure 1, is an outside elevation, medial portions cut away. Fig. 2, is a vertical,
longitudinal section, medial portions cut away. Fig. 3, is a horizontal section, on line ,m 00 Fig. 1, medial portions cut away. Fig. {4, is a transverse vertical section, on line 3 eFig. I.
It is not my intention to limit myself to the particular furnace shown, as any device which will carry out the process may be used.
My process comprises the sintering of the material and the burning out of deleterious matter, which treatment results in a more complete and thorough separation of the metallic values from ores by the subsequent smelting treatment in another furnace, than any roasting and smelting processes known by me to be in use, especially is this so when ores are crushed into small pieces and carry considerable fine material: and in the smelting of concentrates and fine dust.
As is well known, it is the practice of miners to ship ores' to custom sampling plants and to have their ores sampled be fore selling to the smelter. In the sampler the ore from the mines is crushed to a very fine mesh, and the mass is divided and subdivided, samples are taken, pulverized and assayed to determine the value of the shipment, consequently a large proportion of the ore received by the smelter is finely crushed and sampled ore. In addition to this ore product, a large tonnage of concentrates is shipped to the smelter from custom and private concentrating plants. These concentrates comprise the ore product that has been obtained by crushing crude ore from the mine, and grinding it to from 20 to 80 mesh, and running it over the concen trating machines, which are adapted to separate the mineral particles from the gangue matter. These separate mineral particles are called concentrates, and are shipped to the smelters to be smelted by themselves, or mixed with the crude ore from the mines and samplers and smelters In addition to this, in the treatment of ores through blast and other furnaces a large product called fine dust accumulates in flue chambers, which product is exceedingly fine, and carries relatively the values and gangue matter as the ore under treatment. In some smelting plants this fine dust is mixed with milk of lime, making a plastic mass, which is then pressed into briquets and dried; which briquets yet retain all the deleterious matter. These briquets are again sent through the smelter mixed with other ore for treatment; but it is found that a greater percentage of dust rises from the briquets than from an equal amount of ore, which dust is again to be caiwht, briquetted and smelted. I accomplisi this sintering treatment in some cases by taking advantage of the sulfur elements of ores. It is well known that the second atom of sulfur in the loi-sulfid of iron (FeSQ) held so feebly that it cannot be fully utilized as fuel in the pyritic or blast furnace, as it passes off in the upper part of the furnace and *ausos irregularities and much trouble in various ways in the fusing of the charges in such furnaces, \which sometimes results in clogging up the charge, and making a hot top with its attendant loss in the metallic value, and also in burning off a large. portion of the sulfur, which may be used for fuel The sintering treatment for this class of ore is for the purpose of same percentage of" driving off this second and useless atom of sulfur, controlling the heat applied to the ore, and arresting the process of roast1ng at such point; and'thereby'conserving the sulfur in the ore, and then withdrawingthe ore from the furnace, so that when it is charged into the blast furnace the monosulfid of iron (FeS) can be kept intact until it reaches the smelting-zone, where it meets the blast, and advantage is taken of the oxidation of the remaining sulfur and the iron to carry the smelting process to the end. The ore can be fed hot into the blast furnace, but itmust be cooled sufiiciently just before or afterit leaves the sintering furnace to stop further chemical change, in orderto reserve the balance of the sulfur for the-final operation of smelting in the smelting'zone of the blast furnace.
The roastinglgof ores for the purpose of getting rid 'of the sulfur and ox dlzmg the metals is not new, but the arre s .of the treatment at the point of time who tl 1c ore reaches a sticky or pasty condition, and the eliminating from the ore an exact portion of sulfur while retaining the remaining atom of sulfur, is new. The ore when in the form of concentrates, frequently exceedingly fine, is so unsuited to any form of smelting, especially in the pyritic or blast furnace, that a sintering roast is necessary to agglomerate it into umps which is the most suitable condition for it to be put in, to be fed to the smelting furnaces, as it prevents practically all loss from the floating away of the finer dustportion of the dry ore with the draft through the fines and chimney of the furnace. The sintering of the flue dust instead of briquetting it has the advantage of a saving of time, the putting the dust into better form physically, the burning off of objectional matterand preventing a reaccumulation of dust from the smelting of briquets made from flue dust.
I have found in practice that in the process patented to me August 6th, 1907, by
LettersfPatent N 0. 862683 under the title of Automatic,ore-smelting process for reverberatory-furnaces, and as well in all furnaces, that a sintering treatment should be given to the finely crushed ores, such as are now shipped from minesto smelters, concentrates, and fluedi st, in order to secure, enlarged capacity for the smelter, reduction in cost of smelting, loss in flue dust, a saving of fuel, and economical treatment in blast furnaces of concentrates and fine dust. My experi ence proving that while my improved reverberatory furnace is all that could be de sired as a separator of the metallic values and the molten ore, yet it, in common with all reverberatory furnaces is an expensive type of furnace in which to fuse the ore,
and as the blast, furnace is not capable of sintering ores, I have invented and illustrate herewith a furnace especially designed and adapted to practically and economically affect a siutering treatment of ores, concentrates and flue dust preparatory to being taken to a blast furnace. This furnace enables me to give the treatment desired by my process which is in the nature of a. roast, but
it differs from the common manner of roasting ores in that the ore is heated only hot enough to become sticky, and to agglomerate into irregular lumpy masses.
I am aware of the fact that other roasting and sintering devices have been used, but the product from which does not meet the requirements of the subsequent smelting treatment in blast furnaces.
In my furnace, A is the foundation, B and 7 O are the side walls which are suitably supported by I beams D.
1 is the front end wall, 2 the rear end wall, 3 is the roof and 4, the bottom. At the front end 1, is provided a fuel feeding door 5, and in the same end is fitted the fire box 6, which consists of grate bars 7 suitably supported on I beams 8, beneath which is the ash pit 9. A horizontally placed hearth 10, is built extending from the said fire box 6, to rear or other end of the furnace. In the rear end of the furnace is built the fine 1], leading to the stack. On the front end of the hearth 10 is the bridge wall 19., within which is formed a horizontal cold air conduit 13,with openings 14, therefrom into the heat chamber 15 of the furnace. This cold air conduit 13, extends through each side wall. In the side wall B, are fitted working doors or openings 16, through which openings the attendants work and manipulate the ore under treatment. Opposite said openings 16in the side wall C, is fitted the ore chutes 17. Said ore chutes are water-jacketed by allowing 5 water to circulate around the chutes by means of pipes 18, one of which is ingress and the other egress. Each ore chute is fitted with an ore hopper 19.
The operation of my sintering furnace and therein carrying out my process is as follows: Fire is started in the fire box and the ore to be treated is fed into the ore hoppers 19, (which are kept filled at all subsequent steps of the treatment,) which material will by gravity assume the position shown in Fig. 4. The attendant will open one of the openings 16 and by means of rabbles gently draw and spread some of the ore over the hearth; and in this manner cover, through said openings, all of said hearth. hen sufficient heat has been absorbed by the ore so spread, to render it sticky, a door is opened and the sticky ore is removed. During such removal the ore receives some manipulation. After the removal it is dumped on the floor. It is then while hot spreae out in a thin sheet or mass to chill which chilling arrests further chemical change and renders it brittle and easily broken into con'venient sized lumps for feeding into a smelting furnace.
Having thus described my process, 1 claim and desire to secure by Letters Patent.
1. A process for treating ore. which consists of subjecting the ore to the action of heat, while the ore is at rest, suliicient to cause it to become sticky, then removing the ore from the heat and manipulating it to form irregular lumps, as and for the purpose described.
L A process for treating ore, which cono't' subjecting the ore to the action of i heat while the ore 1s at rest Within a furnace having a lateral draft over the ore to cause it to become sticky, then removing the ore from the furnace before the heat elements in the ore are consumed, and manipulating it to form nodules, as and for the purpose described.
3. A process fort-reating ore, which consists of spreading the ore in a thin layer on the hearth witlnn a furnace, subjecting it while so spread to the action of heat sufiicient to tause it to become sticky, then removing the ore from the heat and manipulating it to form nodules.
In testimony whereof I have affixed my signature in presence of two witnesses.
GEORGE G. VIVIAN.- lVitn-esses Gr. B. BLAKELY, Jos. F. SIMMONS.
US52792009A 1909-11-13 1909-11-13 Process for sintering ore. Expired - Lifetime US950798A (en)

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