US763665A - Explosive compound. - Google Patents
Explosive compound. Download PDFInfo
- Publication number
- US763665A US763665A US17046903A US1903170469A US763665A US 763665 A US763665 A US 763665A US 17046903 A US17046903 A US 17046903A US 1903170469 A US1903170469 A US 1903170469A US 763665 A US763665 A US 763665A
- Authority
- US
- United States
- Prior art keywords
- aluminium
- iron
- ammonium
- explosive compound
- alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002360 explosive Substances 0.000 title description 8
- 150000001875 compounds Chemical class 0.000 title description 6
- 239000004411 aluminium Substances 0.000 description 19
- 229910052782 aluminium Inorganic materials 0.000 description 19
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 19
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 18
- 229910045601 alloy Inorganic materials 0.000 description 10
- 239000000956 alloy Substances 0.000 description 10
- 229910052742 iron Inorganic materials 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
- 239000010703 silicon Substances 0.000 description 6
- 229910052710 silicon Inorganic materials 0.000 description 6
- 229910002651 NO3 Inorganic materials 0.000 description 5
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 5
- 229910000838 Al alloy Inorganic materials 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000005422 blasting Methods 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Chemical compound CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- OXNIZHLAWKMVMX-UHFFFAOYSA-N picric acid Chemical compound OC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O OXNIZHLAWKMVMX-UHFFFAOYSA-N 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B33/00—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide
- C06B33/04—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide the material being an inorganic nitrogen-oxygen salt
Definitions
- any alloy of aluminium containing enough iron or similar heavy metal to render it brittle may be used.
- an alloy containing forty per cent. of iron and sixty per cent. of aluminium may be readily pulverized by impact and afterward ground still finer by rolls or other pulverizing machinery. I prefer,
- nitrate of ammonium and the aluminium alloy are finely powdered separately and mixed together.
- the proportions are preferably such that one-third of the oxygen present in the nitrate of ammonium will form alumina with the aluminium present, and if silicon is present a corresponding amount should be allowed for itthat is, there should be suflicirmtnilrale of ammonium, so that one-third of its oxygen will oxidize both the aluminium and silicon to alumina and silica.
- the silicon acts like the aluminium and contributes to the explosivepower of the compound.
- the aluminium alloy such as.
- chlorate of potash or picric acid may be substituted for the nitrate of ammonium.
- the mixture is to be fired with a fulminating agent. It has substantially the advantages of aluminium explosive compound; but these advantages are obtained at a considerably less cost than as when pure aluminium is used. It may be used alone or in admixture with other suitable explosive compounds.
- I claim 7 The herein-described explosive compound, consisting of a finely-divided brittle alloy containing aluminium and a heavier metal, and nitrate of ammonium; substantially as described.
- the herein-described explosive compound consisting of a finely-divided brittle alloy containing aluminium and a heavier metal, and an oxidizing agent; substantially as described.
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Contacts (AREA)
Description
Patented June 28, 1904.
CHARLES M. HALL, OF NIAGARA FALLS, NEW YORK.-
EXPLQSWE onus SPJEGXFIGATION forming part of Letters Patent No. 763,665, dated June 28, 1904. Application filed August 22, 1903. Serial No. 170,469. (No specimens.)
To all whom it may concern.
Be it known that 1, CHARLES M. HALL, of
Niagara Falls, Niagara county, New York,
lowing is a full, clear, and exact description.
It is a Well-known fact that the expansion or gases on firing explosives is increased by any means which raises the temperature of the gases. For this purpose powdered aluminium has been used in admixture with oxidizing agents in certain explosives, the aluminium becoming oxidized to alumina during the firing by part of thedisposable oxygen present. The use of pure aluminium, however, is subject to disadvantages resulting from the great difiiculty and expense of reducing the aluminium to powder. In order to overcome this disadvantage and at the same time to obtain the metal in less expensive form than pure aluminium, I employ alloys of aluminium, particularly with heavy metals, such as iron, which can be readily ground to powder and pulverized to an extreme degree of fineness by ordinary means of pulverization. Any alloy of aluminium containing enough iron or similar heavy metal to render it brittle may be used. Thus an alloy containing forty per cent. of iron and sixty per cent. of aluminium may be readily pulverized by impact and afterward ground still finer by rolls or other pulverizing machinery. I prefer,
however, to use an alloy which contains more than simply aluminium and iron. The following is an analysis of an alloy which I have used and which gives good results: aluminium, 60.66 per cent; silicon, 6.70 per cent; titanium, .78 per cent.; iron, 29.95 per cent.; carbon, 1.91 percent. This alloy goes to powder spontaneously soon after being formed, and similar. alloys containing aluminium, silicon, and iron act in the same way.
In making up the explosive l have used nitrate of ammonium and the aluminium alloy. These are finely powdered separately and mixed together. The proportions are preferably such that one-third of the oxygen present in the nitrate of ammonium will form alumina with the aluminium present, and if silicon is present a corresponding amount should be allowed for itthat is, there should be suflicirmtnilrale of ammonium, so that one-third of its oxygen will oxidize both the aluminium and silicon to alumina and silica. The silicon acts like the aluminium and contributes to the explosivepower of the compound.
sively with the aluminium alloy, such as.
chlorate of potash or picric acid, either alone or in combination, may be substituted for the nitrate of ammonium.
The mixture is to be fired with a fulminating agent. It has substantially the advantages of aluminium explosive compound; but these advantages are obtained at a considerably less cost than as when pure aluminium is used. It may be used alone or in admixture with other suitable explosive compounds.
I claim 7 1. The herein-described explosive compound, consisting of a finely-divided brittle alloy containing aluminium and a heavier metal, and nitrate of ammonium; substantially as described.
2. The herein-described blasting agent,eonsisting of a finely-powdered brittle alloy containing aluminium and iron, and nitrate of ammonium; substantially as described.
3. The herein-described explosive compound, consisting of a finely-divided brittle alloy containing aluminium and a heavier metal, and an oxidizing agent; substantially as described. I p
4. The herein-described blastingagent,consisting of a finclyqioumlcred brittle alloy containing aluminium and iron, and an oxidizing agent; substantially as described.
5. The herein-described blasting agent,con-
sisting of a finely-powdered brittle alloy containing aluminium, iron and silicon, and nitratc of ammonium; substanti ally as described.
In testimony whereof I have hereunto set my hand.
CHARLES M. llALL. Vitnesses:
WM. L. CLARK, Lieu li. Surru.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US17046903A US763665A (en) | 1903-08-22 | 1903-08-22 | Explosive compound. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US17046903A US763665A (en) | 1903-08-22 | 1903-08-22 | Explosive compound. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US763665A true US763665A (en) | 1904-06-28 |
Family
ID=2832151
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US17046903A Expired - Lifetime US763665A (en) | 1903-08-22 | 1903-08-22 | Explosive compound. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US763665A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2836484A (en) * | 1955-05-04 | 1958-05-27 | Reynolds Metals Co | Aqueous metal powder explosive |
| US3140208A (en) * | 1962-01-18 | 1964-07-07 | Barnet R Adelman | Gasless ignition composition for solid rocket propellants |
| US3183133A (en) * | 1960-10-21 | 1965-05-11 | Aerojet General Co | Solid propellant compositions containing iron catalyst |
-
1903
- 1903-08-22 US US17046903A patent/US763665A/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2836484A (en) * | 1955-05-04 | 1958-05-27 | Reynolds Metals Co | Aqueous metal powder explosive |
| US3183133A (en) * | 1960-10-21 | 1965-05-11 | Aerojet General Co | Solid propellant compositions containing iron catalyst |
| US3140208A (en) * | 1962-01-18 | 1964-07-07 | Barnet R Adelman | Gasless ignition composition for solid rocket propellants |
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