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US3839234A - Multi-purpose cleaning concentrate - Google Patents

Multi-purpose cleaning concentrate Download PDF

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US3839234A
US3839234A US00326769A US32676973A US3839234A US 3839234 A US3839234 A US 3839234A US 00326769 A US00326769 A US 00326769A US 32676973 A US32676973 A US 32676973A US 3839234 A US3839234 A US 3839234A
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glycol
parts
ether
diethylene glycol
ammonium hydroxide
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C Roscoe
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/04—Water-soluble compounds
    • C11D7/06—Hydroxides

Definitions

  • an amine such as triethanolamine, monoethanolamine, diethanolamine, monoisopropanolamine, diisopropanolamine, triisopropanolamine, monomethylamine, dimethylarnine, ethylenediamine, propylenediamine, cyclohexylamine, diethylethanolamine, ethyl diethanolamine, or morpholine; and a synthetic detergent.
  • Prior Art There are a number of prior art cleaning compositions which are commercially available. Examples of prior art cleaning compositions are described in U.S. Pat. No. 2,551,634, and US. Pat. No. 2,948,685. Some of the cleaning compositions are very good for removing certain types of contaminants while not being effectivein removing other types of contaminants. Also, some cleaning compositions are highly reactive and unsuitable for handling by hand since they can cause considerable skin irritation. In addition, some of the cleaning compositions leave residues or films of soaps which must be removed by rinsing.
  • An object of the present invention is a new and improved cleaning composition which contains no primary irritants and can be readily used by hand without causing hazardous skin irritation.
  • Another object of the invention is a new and improved cleaning composition which may be used to remove a wide variety of contaminants without leaving any films or residues which necessitate rinsing.
  • a further object of the invention is a new and improved cleaning composition which may be diluted with water in a desired manner to accommodate different cleaning situations.
  • a multi-purpose cleaning composition contains: a glycol ether such as ethylene glycol monobutyl ether,
  • glycol monobutyl ether diethylene glycol monobutyl ether, ethylene glycol monoethyl ether, ethylene glycol monomethyl ether, diethylene glycol monomethyl ether or diethylene glycol monoethyl ether; and glycol selected from the group consisting of propylene glycol, diethylene glycol, hexylene glycol, triethylene glycol and dipropylene glycol; a monohydroxy alcohol selected from the group consisting of isopropanol, n-propanol and isabutanol, ammonium hydroxide; and amine selected from the group consisting of triethanolamine, monoethanolamine, diethanolamine, monoisopropanolamine, diisopropanolamine, triisopropanolamine, monomethylamine, dimethylamine, ethylenediamine, propylenediamine, cyclohexylamine, diethylethanolamine, ethyl diethanolamine and morpholine; and a synthetic detergent.
  • the multi-purpose cleaning concentrate of the invention is a liquid composition of cleaning agents which may be used to remove a number of contaminants from a variety of surfaces.
  • cleaning agents for example, gums, resins, oils, greases, fats, dirt, etc.
  • the cleaning composition can be removed by the cleaning composition (selectively diluted with water) from windows, stoves, walls, floors, etc. All of the agents of the composition cooperate to remove the contaminants from the surfaces.
  • the composition is blended in a concentrated form with less than about 23 parts or percent by volume water. Additional water is added by the user to make a cleaning composition of desired strength.
  • each part refers to a selected volume. Accordingly, each part has the same volume.
  • the composition contains, generally, from 5 to 60 parts of a glycol ether. Preferrably 10 to parts of the glycol ether are mixed in the compositions.
  • the glycol ethers which may be used are ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, ethylene glycol monoethyl ether, ethylene glycol monomethyl ether, diethylene glycol monomethyl ether and diethylene glycol monoethyl ether. Mixtures of two or more of the glycol ethers may also be employed. Ethylene glycol monobutyl ether and diethylene glycol monobutyl ether appear to generally produce better cleaning solutions than the other glycols.
  • the glycol ethers are aggressive solvents for many oils, gums, resins, greases and waxes. Since the glycol ethers are water-soluble they also serve as coupling agents and emulsifiers.
  • glycol such as propylene glycol, diethylene glycol, hexylene glycol (2- methyl-2, 4 pentanediol), triethylene glycol, dipropylene glycol or mixtures of two or more thereof are included in the composition.
  • a glycol such as propylene glycol, diethylene glycol, hexylene glycol (2- methyl-2, 4 pentanediol), triethylene glycol, dipropylene glycol or mixtures of two or more thereof.
  • glycols are bygroscopic high boiling solvents which are completely miscible with water.
  • the glycols aid in the dissolution of various resins, gums and oils. Once the contaminants are removed from a surface, the glycols tend to prevent redeposition of the removed contaminants.
  • the glycols add lubricity to the composition and permit soil or solid particles to be easily wiped away before the surface dries. Further, the glycols aid in the penetration and wetting of the composition into the contaminants.
  • a monohydroxy alcohol such as isopropanol npropanol, isobutanol or a mixture of two or more thereof forms about 1 to 30 parts of the composition. Preferrably from 5 to 20 parts of the monohydroxy alcohol is included.
  • the monohydroxy alcohols add additional solvent power to the composition as well as enhancing the action and cooperation of the other agents.
  • the composition also contains about 1 to 15 parts and preferrably from 2 to 10 parts of an amine selected from triethanolamine, monoethanolamine, diethanolamine, monoisopropanolamine, diisopropanolamine, triisopropanolamine, monomethylamine, dimethylamine, ethylenediamine, propylenediamine, cyclohexylamine, diethylethanolamine, ethyl diethanolamine, morpholine, and mixtures of two or more thereof.
  • Triethanolamine, monoethanolamine and diethanolamine are preferred over the other amines with triethanolamine being the most preferred and diethanolamine the least preferred.
  • the amines are miscible with water and the other agents of the composition.
  • the amines tend to lower the surface tension of water and aqueous solutions. They also serve as solvents for many organic gums, oils and resins.
  • Aqueous ammonium hydroxide is included in the composition. Based upon a 28 percent solution, about 2 to 30 parts of aqueous ammonium hydroxide may be used. Preferrably from 5 to parts of aqueous ammonium hydroxide are mixed in the solution.
  • Aqueous ammonium hydroxide is a good cleaning agent which neutralizes acids and changes fatty oils into water'miscible soaps.
  • the synthetic detergent is one of the commercially available materials which have a cleaning action like soap but are not derived directly from fats and oils. They are surface active agents and have structurally unsymmetrical molecules with a hydrophilic-group and hydrophobic oil-soluble group.
  • Three acceptable synthetic detergents are IGEPAL CO 630 sold by GAF, Inc., TER- GITOL NPX sold by Union Carbide, Inc. AND TRI- TON X 100sold by Robin and 'I-Iaas, Inc.
  • IGEPAL- CO630 is a nonyl phenoxy poly (ethyleneoxy) ethanol obtained by condensation reaction of ethylene oxide on nonyl phenol and having about eight ethyleneoxy groups.
  • T-ERGITOL NPX' is a nonyl phenol ethylene glycol ether formed by condensation reaction of 1 mole nonyl phenolwith 10.5 moles ethylene oxide.
  • TRITON X'l00 is'an alkyl polyether alcohol formed by the reaction of octylphenol with ethylene'oxide, and having about nine to ten oxyethylene groups.
  • the synthetic detergent is selected for its ability not to leave significant films and residues of detergent on surfaces when incorporated in the composition of the invention.
  • the synthetic detergent is selected to be compatable with the'other agents of the composition.
  • EXAMPLE II Ingredients Parts diethylene glycol monobutyl ether 30 diethylene glycol 30 n-propanol I0 27% aqueous ammonium hydroxide l0 monoethanolamine 4 IGEPAL CO-630 3 Water l3 EXAMPLE, ll l v Ingredients Parts ethylene glycol monomethyl ether 30 hexylene glycol 30 isobutanol v I0 27% aqueous ammonium hydroxide g 10 diethanolamine v 4 TRITON X I00 3 Water 13 EXAMPLEIV Ingredients 7 Parts ethylene glycol monoethyl ether l0 diethylene glycol monomethyl ether l0 diethylene glycol monoethyl ethe .lO triethylene.
  • glycol l5 dipropylene glycol 15 isopropanol I0 27% aqueous ammonium hydroxide l0 monoisopropanolamine v, 2 diisopropanolamine 2 TERGITOL NPX 3 Water 13
  • the invention are simply'illustrative of the principles of the invention. Many other embodiments may be devised without departing from the scope and spirit of the invention.
  • a cleaning composition which is absent significant residue leaving agents and which is capable of being diluted with water consisting essentially of a blend of the following parts having the same volume:
  • glycol ether selected from the group consisting of ethylene glycol monobutyl ether, diethylene glycol vmonobutyl ether, ethylene glycol monoethyl ether,v ethylene glycol monomethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether and mixtures of two or more thereof;
  • a glycol selected from the group consisting of propylene glycol, diethylene glycol, hexylene glycol, triethylene glycol, dipropylene glyco and mixtures of two or more thereof;
  • a monohydroxy alcohol selected from the group consisting of isopropanol, n-propanol, isobutanol and mixtures of two or more thereof;
  • an aqueous ammonium hydroxide solution equivalent to 2 to 30 parts of a 28 percent aqueous ammonium hydroxide solution; to l5 parts of an amine selected from the group consisting of triethanolamine, monoethanolamine, diethanolamine, monoisopropanolamine diisopropanolamine, triisopropanolamine, monomethylamine, dimethylamine, ethylenediamine, propylenediamine, cyclohexylamine, diethylethanolamine, ethyl diethanolamine, morpholine, and mixtures of two or more thereof; and to 15 parts of a liquid synthetic detergent which does not form any substantial film or residue when a film of water solution thereof is dried.
  • an amine selected from the group consisting of triethanolamine, monoethanolamine, diethanolamine, monoisopropanolamine diisopropanolamine, triisopropanolamine, monomethylamine, dimethylamine, ethylenediamine, propylenediamine, cyclohe
  • a cleaning composition as defined in claim 1 consisting essentially of:

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
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  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

A water miscible cleaning composition contains: A GLYCOL ETHER SUCH AS ETHYLENE GLYCOL MONOBUTLY ETHER, DIETHYLENE GLYCOL MONOBUTYL ETHER, ETHYLENE GLYCOL MONOMETHYL ETHER, ETHYLENE GLYCOL MONOETHYL ETHER, DIETHYLENE GLYCOL MONOMETHYL ETHER OR DIETHYLENE GLYCOL MONOETHYL ETHER; A GLYCOL SUCH AS PROPYLENE GLYCOL, DIETHYLENE GLYCOL, HEXYLENE GLYCOL (2-METHYL-2, 4 PENTANEDIOL), TRIETHYLENE GLYCOL OR DIPROPYLENE GLYCOL; A MONOHYDROXY ALCOHOL SUCH AS ISOPROPANOL, N-PROPANOL OR ISOBUTANOL; AMMONIUM HYDROXIDE; AND AN AMINE, SUCH AS TRIETHANOLAMINE, MONOETHANOLAMINE, DIETHANOLAMINE, MONOISOPROPANOLAMINE, DIISOPROPANOLAMINE, TRIISOPROPANOLAMINE, MONOMETHYLAMINE, DIMETHYLAMINE, ETHYLENEDIAMINE, PROPYLENEDIAMINE, CYCLOHEXYLAMINE, DIETHYLETHANOLAMINE, ETHYL DIETHANOLAMINE, OR MORPHOLINE; AND A SYNTHETIC DETERGENT.

Description

United States Patent [191 Roscoe [4 1 Oct. 1,1974
[ MULTI-PURPOSE CLEANING CONCENTRATE Colon J. Roscoe, 426 Plymouth Ave., Winston-Salem, NC. 27104 22 Filed: Jan. 26, 1973 21 Appl. No.: 326,769
[76] Inventor:
[52] US. Cl 252/544, 252/153, 252/156, 252/170, 252/172, 252/173 [51] Int. Cl ..C1ld 3/30 [58] Field of Search 252/156, 544, 170, 172, 252/173, 153
[56] References Cited UNITED STATES PATENTS 2,929,789 3/1960 Pickett et al 252/170 3,696,042 10/1972 Wright 252/170 Primary Examiner-Ralph S. Kendall Assistant Examiner-Bruce l-l. Hess Attorney, Agent, or Firm-Donald W. Marks [57] ABSTRACT A water miscible cleaning composition contains:
ammonium hydroxide; and
an amine, such as triethanolamine, monoethanolamine, diethanolamine, monoisopropanolamine, diisopropanolamine, triisopropanolamine, monomethylamine, dimethylarnine, ethylenediamine, propylenediamine, cyclohexylamine, diethylethanolamine, ethyl diethanolamine, or morpholine; and a synthetic detergent.
4 Claims, No Drawings MULTI-PURPOSE CLEANING CONCENTRATE BACKGROUND OF THE INVENTION 1. Field of the Invention Contaminates on various surfaces such as glass, metal, enamel, glazed ceramic, floor tile, chrome, plastic, paint, etc. are removed with the aid of cleaning compositions. This invention relates to concentrated liquid cleaning compositions which are mixed with water in various proportions and used to remove contaminants from a variety of surfaces.
2. Prior Art There are a number of prior art cleaning compositions which are commercially available. Examples of prior art cleaning compositions are described in U.S. Pat. No. 2,551,634, and US. Pat. No. 2,948,685. Some of the cleaning compositions are very good for removing certain types of contaminants while not being effectivein removing other types of contaminants. Also, some cleaning compositions are highly reactive and unsuitable for handling by hand since they can cause considerable skin irritation. In addition, some of the cleaning compositions leave residues or films of soaps which must be removed by rinsing.
SUMMARY OF THE INVENTION An object of the present invention is a new and improved cleaning composition which contains no primary irritants and can be readily used by hand without causing hazardous skin irritation.
Another object of the invention is a new and improved cleaning composition which may be used to remove a wide variety of contaminants without leaving any films or residues which necessitate rinsing.
A further object of the invention is a new and improved cleaning composition which may be diluted with water in a desired manner to accommodate different cleaning situations.
In accordance with these and other objects of the invention a multi-purpose cleaning composition contains: a glycol ether such as ethylene glycol monobutyl ether,
diethylene glycol monobutyl ether, ethylene glycol monoethyl ether, ethylene glycol monomethyl ether, diethylene glycol monomethyl ether or diethylene glycol monoethyl ether; and glycol selected from the group consisting of propylene glycol, diethylene glycol, hexylene glycol, triethylene glycol and dipropylene glycol; a monohydroxy alcohol selected from the group consisting of isopropanol, n-propanol and isabutanol, ammonium hydroxide; and amine selected from the group consisting of triethanolamine, monoethanolamine, diethanolamine, monoisopropanolamine, diisopropanolamine, triisopropanolamine, monomethylamine, dimethylamine, ethylenediamine, propylenediamine, cyclohexylamine, diethylethanolamine, ethyl diethanolamine and morpholine; and a synthetic detergent.
DETAILED DESCRIPTION The multi-purpose cleaning concentrate of the invention is a liquid composition of cleaning agents which may be used to remove a number of contaminants from a variety of surfaces. For example, gums, resins, oils, greases, fats, dirt, etc., can be removed by the cleaning composition (selectively diluted with water) from windows, stoves, walls, floors, etc. All of the agents of the composition cooperate to remove the contaminants from the surfaces. Preferrably the composition is blended in a concentrated form with less than about 23 parts or percent by volume water. Additional water is added by the user to make a cleaning composition of desired strength.
As used herein, the term part refers to a selected volume. Accordingly, each part has the same volume.
The composition contains, generally, from 5 to 60 parts of a glycol ether. Preferrably 10 to parts of the glycol ether are mixed in the compositions. The glycol ethers which may be used are ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, ethylene glycol monoethyl ether, ethylene glycol monomethyl ether, diethylene glycol monomethyl ether and diethylene glycol monoethyl ether. Mixtures of two or more of the glycol ethers may also be employed. Ethylene glycol monobutyl ether and diethylene glycol monobutyl ether appear to generally produce better cleaning solutions than the other glycols. The glycol ethers are aggressive solvents for many oils, gums, resins, greases and waxes. Since the glycol ethers are water-soluble they also serve as coupling agents and emulsifiers.
Generally about 5 to 60 parts of a glycol, such as propylene glycol, diethylene glycol, hexylene glycol (2- methyl-2, 4 pentanediol), triethylene glycol, dipropylene glycol or mixtures of two or more thereof are included in the composition. Preferrably from 10 to 40 parts of the composition is glycol. The glycols are bygroscopic high boiling solvents which are completely miscible with water. The glycols aid in the dissolution of various resins, gums and oils. Once the contaminants are removed from a surface, the glycols tend to prevent redeposition of the removed contaminants. Also, the glycols add lubricity to the composition and permit soil or solid particles to be easily wiped away before the surface dries. Further, the glycols aid in the penetration and wetting of the composition into the contaminants. Of glycols, propylene glycol, hexylene glycol and diethylene glycol are preferred over the other glycols.
A monohydroxy alcohol such as isopropanol npropanol, isobutanol or a mixture of two or more thereof forms about 1 to 30 parts of the composition. Preferrably from 5 to 20 parts of the monohydroxy alcohol is included. The monohydroxy alcohols add additional solvent power to the composition as well as enhancing the action and cooperation of the other agents.
The composition also contains about 1 to 15 parts and preferrably from 2 to 10 parts of an amine selected from triethanolamine, monoethanolamine, diethanolamine, monoisopropanolamine, diisopropanolamine, triisopropanolamine, monomethylamine, dimethylamine, ethylenediamine, propylenediamine, cyclohexylamine, diethylethanolamine, ethyl diethanolamine, morpholine, and mixtures of two or more thereof. Triethanolamine, monoethanolamine and diethanolamine are preferred over the other amines with triethanolamine being the most preferred and diethanolamine the least preferred. The amines are miscible with water and the other agents of the composition. They are good penetrating and softening agents while capable of saponifying and emulsifying oils, greases and waxes. The amines tend to lower the surface tension of water and aqueous solutions. They also serve as solvents for many organic gums, oils and resins.
Aqueous ammonium hydroxide is included in the composition. Based upon a 28 percent solution, about 2 to 30 parts of aqueous ammonium hydroxide may be used. Preferrably from 5 to parts of aqueous ammonium hydroxide are mixed in the solution. Aqueous ammonium hydroxide is a good cleaning agent which neutralizes acids and changes fatty oils into water'miscible soaps.
To further enhance the cleaning properties of the composition 1 to 15 parts, and preferrably from 2 to 6 parts, of a liquid synthetic detergent are included. The synthetic detergent is one of the commercially available materials which have a cleaning action like soap but are not derived directly from fats and oils. They are surface active agents and have structurally unsymmetrical molecules with a hydrophilic-group and hydrophobic oil-soluble group. Three acceptable synthetic detergents are IGEPAL CO 630 sold by GAF, Inc., TER- GITOL NPX sold by Union Carbide, Inc. AND TRI- TON X 100sold by Robin and 'I-Iaas, Inc. IGEPAL- CO630 is a nonyl phenoxy poly (ethyleneoxy) ethanol obtained by condensation reaction of ethylene oxide on nonyl phenol and having about eight ethyleneoxy groups. T-ERGITOL NPX' is a nonyl phenol ethylene glycol ether formed by condensation reaction of 1 mole nonyl phenolwith 10.5 moles ethylene oxide. TRITON X'l00 is'an alkyl polyether alcohol formed by the reaction of octylphenol with ethylene'oxide, and having about nine to ten oxyethylene groups. The synthetic detergent is selected for its ability not to leave significant films and residues of detergent on surfaces when incorporated in the composition of the invention.
'It is believed that this class of detergents volitilizes.
Also, the synthetic detergent is selected to be compatable with the'other agents of the composition.
One important aspect of the invention is. the discovery that the abovecombination of cleaning agents of the invention produces a cleaning composition with particularly improved cleaning powers. While all of the agents may have been used individually or in combination with one or two of the other agents in cleaning compositions, the'advantages of the invention are not EXAMPLE I Ingredients Parts Ethylene glycol monobutyl ether 30 Propylene glycol 30 Isopropanol 1O 27% aqueous ammonium hydroxide l0 Triethanolamine 4 TERGITOL NPX 1;
Water For light duty cleaning of enamel surfaces, windows,
' plastic surfaces, table tops, etc., A cup of the concen- 6 trated composition of EXAMPLE I is mixed with 1 gallon ofwatter'. The diluted cleaner is sprayed on the surfaces and wiped off with a cotton cloth to remove the contaminants. After drying no films or residues are visible on the surfaces. 1
For cleaning baked or burnt oils, greases, gums and foods on metal articles, 1 pint of the concentrated composition of EXAMPLE I is mixed with 1 gallon of water. The articles may be soaked and scrubbed in the diluted cleaner to remove the contaminants. After wiping and drying no films or residues are visible on the articles.
EXAMPLE II Ingredients Parts diethylene glycol monobutyl ether 30 diethylene glycol 30 n-propanol I0 27% aqueous ammonium hydroxide l0 monoethanolamine 4 IGEPAL CO-630 3 Water l3 EXAMPLE, ll l v Ingredients Parts ethylene glycol monomethyl ether 30 hexylene glycol 30 isobutanol v I0 27% aqueous ammonium hydroxide g 10 diethanolamine v 4 TRITON X I00 3 Water 13 EXAMPLEIV Ingredients 7 Parts ethylene glycol monoethyl ether l0 diethylene glycol monomethyl ether l0 diethylene glycol monoethyl ethe .lO triethylene. glycol l5 dipropylene glycol 15 isopropanol I0 27% aqueous ammonium hydroxide l0 monoisopropanolamine v, 2 diisopropanolamine 2 TERGITOL NPX 3 Water 13 the invention are simply'illustrative of the principles of the invention. Many other embodiments may be devised without departing from the scope and spirit of the invention.
What is claimed is:
l. A cleaning composition which is absent significant residue leaving agents and which is capable of being diluted with water consisting essentially of a blend of the following parts having the same volume:
5 to parts of a glycol ether selected from the group consisting of ethylene glycol monobutyl ether, diethylene glycol vmonobutyl ether, ethylene glycol monoethyl ether,v ethylene glycol monomethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether and mixtures of two or more thereof;
5 to 60 parts of a glycol selected from the group consisting of propylene glycol, diethylene glycol, hexylene glycol, triethylene glycol, dipropylene glyco and mixtures of two or more thereof;
2 to 30 parts of a monohydroxy alcohol selected from the group consisting of isopropanol, n-propanol, isobutanol and mixtures of two or more thereof;
an aqueous ammonium hydroxide solution equivalent to 2 to 30 parts of a 28 percent aqueous ammonium hydroxide solution; to l5 parts of an amine selected from the group consisting of triethanolamine, monoethanolamine, diethanolamine, monoisopropanolamine diisopropanolamine, triisopropanolamine, monomethylamine, dimethylamine, ethylenediamine, propylenediamine, cyclohexylamine, diethylethanolamine, ethyl diethanolamine, morpholine, and mixtures of two or more thereof; and to 15 parts of a liquid synthetic detergent which does not form any substantial film or residue when a film of water solution thereof is dried.
2. A cleaning composition as defined in claim 1 consisting essentially of:
IO to 40 parts of the glycol ether;
to 40 parts of the glycol;
5 to 20 parts of the monohydroxy alcohol;
5 to parts of the aqueous ammonium hydroxide;
2 to 10 parts of the amine; and 2 to 6 parts of the synthetic detergent. 3. A cleaning composition as defined in claim 1 wherein:
I the monohydroxy alcohol is isopropanol; and
the amine is triethanolamine, diethanolamine or monoethanolamine. 4. A cleaning composition as defined in claim 3, consisting essentially of:
10 to 40 parts of the glycol ether;
10 to 40 parts of the glycol;
5 to 20 parts of the monohydroxy alcohol;
2 to 10 parts of the aqueous ammonium hydroxide;
2 to 10 parts of the amine; and
2 to 6 parts of the synthetic detergent.

Claims (4)

1. A CLEANING COMPOSITION WHICH IS ABSENT SIGNIFICANT RESIDUE LEAVING AGENTS AND WHICH IS CAPABLE OF BEING DILUTED WITH WATER CONSISTING ESSENTIALLY OF A BLEND OF THE FOLLOWING PARTS HAVING THE SAME VOLUME: 5 TO 60 PARTS OF A GLYCOL ETHER SELECTED FROM THE GROUP CONSISTING OF ETHYLENE GLYCOL MONOBUTYL ETHER, DIETHYLENE GLYCOL MONOBUTYL EHTER, ETHYLENE GLYCOL MONOETHYL EHTER, ETHYLENE GLYCOL MONOMETHYL ETHER, DIETHYLENE GLYCOL MONOMETHYL ETHER, DIETHYLENE GLYCOL MONOETHYL EHTER AND MIXTURES OF TWO OR MORE THEREOF; 5 TO 60 PARTS OF A GLYCOL SELECTED FROM THE GROUP CONSISTING OF PROPYLENE GLYCOL, DIETHYLENE GLYCOL, HEXYLENE GLYCOL, TRIETHYLENE GLYCOL, DIETHYLENE GLYCOL AND MIXTURES OF TWO OR MORE THEREOF; 2 TO 30 PARTS OF A MONOHYDROXY ALCOHOL SELECTED FROM THE GROUP CONSISTING OF ISOJPROPANOL, N-PROPANOL, ISOBUTANOL AND MIXTURES OF TWO OR MORE THEREOF; AN AQUEOUS AMMONIUM HYDROXIDE SOLUTION EQUIVALENT TO 2 TO 30 PARTS OF A 28 PERCENT AQUEOUS AMMONIUM HYDROXIDE SOLUTION; 1 TO 15 PARTS OF AN AMINE SELECTED FROM THE GROUP CONSISTING OF TRIETHANOLAMINE, MONOETHANOLAMINE, DIETHANOLAMINE, MONOISOPROPANOLAMINE, DIISOJPROPANOLAMINE, TRIISOPROPANOLAMINE, MONOMETHYLAMINE, DIMETHYLAMINE, ETHYLENEDIAMINE, PROPYLENEDIAMINE, CYCLOHEXYLAMINE, DIETHYLETHANOLAMINE, ETHYL DIETHANOLAMINE, MORPHOLINE, AND MIXTURES OF TWO OR MORE THEREOF; AND 1 TO 15 PARTS OF A LIQUID SYNTHETIC DETERGENT WHICH DOES NOT FROM ANY SUBSTANTIAL FILM OR RESIDUE WHEN A FILM OF WATER SOLUTION THEREOF IS DRIED.
2. A cleaning composition as defined in claim 1 consisting essentially of: 10 to 40 parts of the glycol ether; 10 to 40 parts of the glycol; 5 to 20 parts of the monohydroxy alcohol; 5 to 15 parts of the aqueous ammonium hydroxide; 2 to 10 parts of the amine; and 2 to 6 parts of the synthetic detergent.
3. A cleaning composition as defined in claim 1 wherein: the glycol ether is ethylene glycol monobutyl ether or diethylene glycol monobutyl ether; the glycol is propylene glycol, diethylene glycol or hexylene glycol; the monohydroxy alcohol is isopropanol; and the amine is triethanolamine, diethanolamine or monoethanolamine.
4. A cleaning composition as defined in claim 3, consisting essentially of: 10 to 40 parts of the glycol ether; 10 to 40 parts of the glycol; 5 to 20 parts of the monohydroxy alcohol; 2 to 10 parts of the aqueous ammonium hydroxide; 2 to 10 parts of the amine; and 2 to 6 parts of the synthetic detergent.
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Cited By (77)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3960742A (en) * 1973-06-29 1976-06-01 Chemical Cleaning Composition Trust Water-dispersable solvent emulsion type cleaner concentrate
US3980587A (en) * 1974-08-16 1976-09-14 G. T. Schjeldahl Company Stripper composition
FR2311090A1 (en) * 1975-05-12 1976-12-10 Boehringer Sohn Ingelheim Cleaning tar off fumigation chambers - with dilute aq. soln. contg. amphotenside, caustic alkali and glycol ether or alkyl acetate
US3998733A (en) * 1973-11-21 1976-12-21 The British Petroleum Company Limited Detergent composition for dispersing oil spills
US4077896A (en) * 1975-01-15 1978-03-07 Minnesota Mining And Manufacturing Company Wax-stripping cleaning composition
US4228028A (en) * 1978-11-13 1980-10-14 Burroughs Corporation Ball point pen, ink, and its eradicator system
DE2918049A1 (en) * 1979-05-04 1980-11-13 Staedtler Fa J S CLEANING AGENTS, IN PARTICULAR FOR COLOR SOILS CAUSED BY WRITING AGENTS
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US4315828A (en) * 1978-03-10 1982-02-16 Max L. Wymore Water based window glass and chrome cleaner composition
US4316322A (en) * 1979-10-25 1982-02-23 Burroughs Corporation Method of fabricating electrical contacts in a printed circuit board
EP0137615A1 (en) * 1983-08-11 1985-04-17 The Procter & Gamble Company Fabric cleaning compositions for clay-based stains
US4537802A (en) * 1984-08-31 1985-08-27 Flanagan John J Floor finishing, cleaning and burnishing compositions containing ucon polymers, and method of use
US4592787A (en) * 1984-11-05 1986-06-03 The Dow Chemical Company Composition useful for stripping photoresist polymers and method
US4606842A (en) * 1982-03-05 1986-08-19 Drackett Company Cleaning composition for glass and similar hard surfaces
US4617251A (en) * 1985-04-11 1986-10-14 Olin Hunt Specialty Products, Inc. Stripping composition and method of using the same
US4737195A (en) * 1983-11-18 1988-04-12 Amchem Products Activator-accelerator mixtures for alkaline paint stripper compositions
FR2624518A1 (en) * 1987-12-09 1989-06-16 Grandry Gerard ADJUVANT LIQUID FOR SPRAYING, WASHING, DEGREASING, STAIN REMOVAL OR PAINT THINNING
EP0275987A3 (en) * 1987-01-20 1989-07-26 The Dow Chemical Company Composition and method for cleaning gas turbine compressors
WO1989008697A1 (en) * 1988-03-08 1989-09-21 Bp Chemicals Limited Liquid detergent compositions
WO1989012673A1 (en) * 1988-06-21 1989-12-28 Vax Appliances Limited Fabric cleaning and sanitizing compositions
WO1990005771A1 (en) * 1988-11-15 1990-05-31 Sheridan Christopher H Substantially dry cleaning wipe
GB2229446A (en) * 1988-06-21 1990-09-26 Vax Appliances Ltd Fabric cleaning and sanitizing compositions
US4978469A (en) * 1987-05-15 1990-12-18 Ecolab Inc. Cleaning composition suitable for the cleaning of sub-freezing surfaces
EP0393772A3 (en) * 1989-04-21 1991-09-11 The Procter & Gamble Company Hard-surface cleaning compositions
US5080825A (en) * 1989-10-30 1992-01-14 International Business Machines Corporation Tape drive cleaning composition
US5091102A (en) * 1988-11-15 1992-02-25 Nordico, Inc. Method of making a dry antimicrobial fabric
US5094770A (en) * 1988-11-15 1992-03-10 Nordico, Inc. Method of preparing a substantially dry cleaning wipe
US5126068A (en) * 1989-05-05 1992-06-30 Burke John J Hard surface cleaning composition containing polyacrylate copolymers as performance boosters
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US5252245A (en) * 1992-02-07 1993-10-12 The Clorox Company Reduced residue hard surface cleaner
US5279760A (en) * 1991-12-20 1994-01-18 Tohoku Electric Power Co., Inc. Cleaning agent compositions used for gas turbine air compressors
WO1994005766A1 (en) * 1992-09-03 1994-03-17 Circuit Chemical Products Gmbh Agent for cleaning printed circuits and electronic components, method of producing the agent and its use
US5334256A (en) * 1993-06-02 1994-08-02 Howe Charles R Paint stripping composition
EP0662529A1 (en) * 1994-01-11 1995-07-12 Mitsubishi Chemical Corporation Degreasing cleaner and method for cleaning oil-deposited material
US5468423A (en) * 1992-02-07 1995-11-21 The Clorox Company Reduced residue hard surface cleaner
US5523024A (en) * 1992-02-07 1996-06-04 The Clorox Company Reduced residue hard surface cleaner
US5529723A (en) * 1994-12-15 1996-06-25 Colgate-Palmolive Co. Microemulsion light duty liquid cleaning compositions
US5531927A (en) * 1992-03-20 1996-07-02 Bio-Safe Specialty Products, Inc. Stain removing compositions and methods of using the same
US5540865A (en) * 1990-01-29 1996-07-30 The Procter & Gamble Company Hard surface liquid detergent compositions containing hydrocarbylamidoalkylenebetaine
US5585342A (en) * 1995-03-24 1996-12-17 The Clorox Company Reduced residue hard surface cleaner
US5597793A (en) * 1993-06-01 1997-01-28 Ecolab Inc. Adherent foam cleaning compositions
US5626656A (en) * 1992-12-28 1997-05-06 Tetra Co., Ltd. Stock solution of release agent for green sand mold forming
US5665689A (en) * 1996-09-04 1997-09-09 Colgate-Palmolive Co. Cleaning compositions comprising mixtures of partially esterified full esterified and non-esterfied ethoxylated polyhydric alcohols and N-alkyl aldonamides
US5731281A (en) * 1993-08-04 1998-03-24 Colgate-Palmolive Company Microemulsion liquid crystal cleaning compositions comprising esterified and non-esterfied ethoxylated glycerol mixture and sulfoxy anionic surfactant
US5741760A (en) * 1993-08-04 1998-04-21 Colgate-Palmolive Company Aqueous cleaning composition which may be in microemulsion form comprising polyalkylene oxide-polydimethyl siloxane
US5755827A (en) * 1991-12-23 1998-05-26 Precision Processes Textiles Method for the treatment of wool
US5759983A (en) * 1993-08-04 1998-06-02 Colgate-Palmolive Co. Aqueous cleaning composition which may be in microemulsion form comprising polyalkylene oxide -polydimethyl siloxane and ethoxylated secondary alcohol
US5780415A (en) * 1997-02-10 1998-07-14 Colgate-Palmolive Company Stable microemulsion cleaning composition
US5817615A (en) * 1992-02-07 1998-10-06 The Clorox Company Reduced residue hard surface cleaner
WO1998047635A1 (en) * 1997-04-24 1998-10-29 Black Robert H Composition for cleaning transparent hard surfaces and method of using same
US5849681A (en) * 1996-02-09 1998-12-15 S. C. Johnson & Son, Inc. Glass cleaner with enhanced anti-streaking properties
US5861367A (en) * 1993-08-04 1999-01-19 Colgate Palmolive Company Cleaning and disinfecting composition in microemulsion/liquid crystal form comprising aldehyde and mixture of partially esterified, fully esterified and non-esterified polyhydric alcohols
US5990065A (en) * 1996-12-20 1999-11-23 The Procter & Gamble Company Dishwashing detergent compositions containing organic diamines for improved grease cleaning, sudsing, low temperature stability and dissolution
US6069122A (en) * 1997-06-16 2000-05-30 The Procter & Gamble Company Dishwashing detergent compositions containing organic diamines for improved grease cleaning, sudsing, low temperature stability and dissolution
DE19900242A1 (en) * 1999-01-07 2000-07-13 Basf Coatings Ag Aqueous detergent and its use
US6187731B1 (en) 1998-12-23 2001-02-13 Henkel Kommandigesellschaft Auf Aktien (Kgaa) Cleaning compositions for hard surfaces containing naphthalene sulfonic acid/formaldehyde condensates
US6288015B1 (en) 1998-12-23 2001-09-11 Henkel Kommanditgesellschaft Auf Aktien Multiphase cleaning composition containing lignin sulfonate
US6350727B1 (en) 2000-01-28 2002-02-26 Amway Corporation Non-streaking no-wipe cleaning compositions with improved cleaning capability
US6362154B1 (en) 1998-12-23 2002-03-26 Henkel Kommanditgesellschaft Auf Aktien Multiphase cleaning composition containing naphthalene sulfonic acid/formaldehyde condensate
US6521584B1 (en) 1998-03-16 2003-02-18 Henkel Kommanditgesellschaft Auf Aktien Liquid multiphase detergents
US20030118731A1 (en) * 2001-12-21 2003-06-26 Applied Materials, Inc. Method of fabricating a coated process chamber component
US6589926B1 (en) 1998-06-02 2003-07-08 Procter & Gamble Company Dishwashing detergent compositions containing organic diamines
US6727212B2 (en) 1997-11-10 2004-04-27 The Procter & Gamble Company Method for softening soil on hard surfaces
US6797701B2 (en) 1998-11-19 2004-09-28 Pfizer Inc. Antiparasitic formulations
US20050134629A1 (en) * 2003-12-19 2005-06-23 Martin Thomas W. Ink jet cleaning wipes
US20050227898A1 (en) * 2004-04-09 2005-10-13 Leskowicz James J Zero to low VOC glass and general purpose cleaner
DE4210364B4 (en) * 1992-03-30 2006-05-18 Henkel Kgaa Cleaning agents for hard surfaces, in particular glass
US20080092806A1 (en) * 2006-10-19 2008-04-24 Applied Materials, Inc. Removing residues from substrate processing components
WO2008134023A1 (en) * 2007-04-25 2008-11-06 Caterpillar Inc. Cleaning compositions
US20100179246A1 (en) * 2009-01-14 2010-07-15 Perry Stephen C Anti-slip detergent
US20100196503A1 (en) * 2009-02-05 2010-08-05 American Sterilizer Company Low odor, hard surface sporicide
US20100196505A1 (en) * 2009-02-05 2010-08-05 American Sterilizer Company Low odor, hard surface sporicides and chemical decontaminants
US20110020560A1 (en) * 2005-12-07 2011-01-27 Mtu Aero Engines Gmbh Method for Manufacturing a Run-In Coating
US20110190187A1 (en) * 2010-01-29 2011-08-04 W. M. Barr & Company Organic residue remover composition
US10100270B1 (en) 2017-01-04 2018-10-16 Gail R. Moser Procedure to acquire cleaning agent
US10433545B2 (en) 2016-07-11 2019-10-08 Ecolab Usa Inc. Non-streaking durable composition for cleaning and disinfecting hard surfaces
US11884897B2 (en) 2016-11-28 2024-01-30 S. C. Johnson & Son, Inc. Hard surface cleaners including fluorosurfactants

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Cited By (95)

* Cited by examiner, † Cited by third party
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US3960742A (en) * 1973-06-29 1976-06-01 Chemical Cleaning Composition Trust Water-dispersable solvent emulsion type cleaner concentrate
US3998733A (en) * 1973-11-21 1976-12-21 The British Petroleum Company Limited Detergent composition for dispersing oil spills
US3980587A (en) * 1974-08-16 1976-09-14 G. T. Schjeldahl Company Stripper composition
US4077896A (en) * 1975-01-15 1978-03-07 Minnesota Mining And Manufacturing Company Wax-stripping cleaning composition
FR2311090A1 (en) * 1975-05-12 1976-12-10 Boehringer Sohn Ingelheim Cleaning tar off fumigation chambers - with dilute aq. soln. contg. amphotenside, caustic alkali and glycol ether or alkyl acetate
US4315828A (en) * 1978-03-10 1982-02-16 Max L. Wymore Water based window glass and chrome cleaner composition
US4243559A (en) * 1978-06-05 1981-01-06 Kao Soap Co., Ltd. Liquid detergent compositions containing alkanolamines and polyoxyalkylene alkyl ethers
US4228028A (en) * 1978-11-13 1980-10-14 Burroughs Corporation Ball point pen, ink, and its eradicator system
DE2918049A1 (en) * 1979-05-04 1980-11-13 Staedtler Fa J S CLEANING AGENTS, IN PARTICULAR FOR COLOR SOILS CAUSED BY WRITING AGENTS
US4316322A (en) * 1979-10-25 1982-02-23 Burroughs Corporation Method of fabricating electrical contacts in a printed circuit board
US4606842A (en) * 1982-03-05 1986-08-19 Drackett Company Cleaning composition for glass and similar hard surfaces
EP0137615A1 (en) * 1983-08-11 1985-04-17 The Procter & Gamble Company Fabric cleaning compositions for clay-based stains
US4737195A (en) * 1983-11-18 1988-04-12 Amchem Products Activator-accelerator mixtures for alkaline paint stripper compositions
US4537802A (en) * 1984-08-31 1985-08-27 Flanagan John J Floor finishing, cleaning and burnishing compositions containing ucon polymers, and method of use
US4592787A (en) * 1984-11-05 1986-06-03 The Dow Chemical Company Composition useful for stripping photoresist polymers and method
US4617251A (en) * 1985-04-11 1986-10-14 Olin Hunt Specialty Products, Inc. Stripping composition and method of using the same
EP0275987A3 (en) * 1987-01-20 1989-07-26 The Dow Chemical Company Composition and method for cleaning gas turbine compressors
US4978469A (en) * 1987-05-15 1990-12-18 Ecolab Inc. Cleaning composition suitable for the cleaning of sub-freezing surfaces
FR2624518A1 (en) * 1987-12-09 1989-06-16 Grandry Gerard ADJUVANT LIQUID FOR SPRAYING, WASHING, DEGREASING, STAIN REMOVAL OR PAINT THINNING
WO1989008697A1 (en) * 1988-03-08 1989-09-21 Bp Chemicals Limited Liquid detergent compositions
EP0334463A1 (en) * 1988-03-08 1989-09-27 BP Chemicals Limited Liquid detergent compositions
WO1989012673A1 (en) * 1988-06-21 1989-12-28 Vax Appliances Limited Fabric cleaning and sanitizing compositions
GB2229446A (en) * 1988-06-21 1990-09-26 Vax Appliances Ltd Fabric cleaning and sanitizing compositions
US4946617A (en) * 1988-11-15 1990-08-07 Nordico, Inc. Substantially dry cleaning wipe capable of rendering a cleaned surface static free
US5091102A (en) * 1988-11-15 1992-02-25 Nordico, Inc. Method of making a dry antimicrobial fabric
US5094770A (en) * 1988-11-15 1992-03-10 Nordico, Inc. Method of preparing a substantially dry cleaning wipe
WO1990005771A1 (en) * 1988-11-15 1990-05-31 Sheridan Christopher H Substantially dry cleaning wipe
EP0393772A3 (en) * 1989-04-21 1991-09-11 The Procter & Gamble Company Hard-surface cleaning compositions
US5126068A (en) * 1989-05-05 1992-06-30 Burke John J Hard surface cleaning composition containing polyacrylate copolymers as performance boosters
US5080825A (en) * 1989-10-30 1992-01-14 International Business Machines Corporation Tape drive cleaning composition
US5540865A (en) * 1990-01-29 1996-07-30 The Procter & Gamble Company Hard surface liquid detergent compositions containing hydrocarbylamidoalkylenebetaine
EP0523892A1 (en) * 1991-07-18 1993-01-20 The British Petroleum Company P.L.C. Cleaning compositions
TR28591A (en) * 1991-07-18 1996-11-01 British Petroleum Co Cleaning compounds.
US5279760A (en) * 1991-12-20 1994-01-18 Tohoku Electric Power Co., Inc. Cleaning agent compositions used for gas turbine air compressors
US5755827A (en) * 1991-12-23 1998-05-26 Precision Processes Textiles Method for the treatment of wool
US5523024A (en) * 1992-02-07 1996-06-04 The Clorox Company Reduced residue hard surface cleaner
US5437807A (en) * 1992-02-07 1995-08-01 The Clorox Company Reduced residue hard surface cleaner
US5468423A (en) * 1992-02-07 1995-11-21 The Clorox Company Reduced residue hard surface cleaner
US5817615A (en) * 1992-02-07 1998-10-06 The Clorox Company Reduced residue hard surface cleaner
US5252245A (en) * 1992-02-07 1993-10-12 The Clorox Company Reduced residue hard surface cleaner
US5531927A (en) * 1992-03-20 1996-07-02 Bio-Safe Specialty Products, Inc. Stain removing compositions and methods of using the same
DE4210364B4 (en) * 1992-03-30 2006-05-18 Henkel Kgaa Cleaning agents for hard surfaces, in particular glass
WO1994005766A1 (en) * 1992-09-03 1994-03-17 Circuit Chemical Products Gmbh Agent for cleaning printed circuits and electronic components, method of producing the agent and its use
US5626656A (en) * 1992-12-28 1997-05-06 Tetra Co., Ltd. Stock solution of release agent for green sand mold forming
US5597793A (en) * 1993-06-01 1997-01-28 Ecolab Inc. Adherent foam cleaning compositions
US5334256A (en) * 1993-06-02 1994-08-02 Howe Charles R Paint stripping composition
US5861367A (en) * 1993-08-04 1999-01-19 Colgate Palmolive Company Cleaning and disinfecting composition in microemulsion/liquid crystal form comprising aldehyde and mixture of partially esterified, fully esterified and non-esterified polyhydric alcohols
US5731281A (en) * 1993-08-04 1998-03-24 Colgate-Palmolive Company Microemulsion liquid crystal cleaning compositions comprising esterified and non-esterfied ethoxylated glycerol mixture and sulfoxy anionic surfactant
US5741760A (en) * 1993-08-04 1998-04-21 Colgate-Palmolive Company Aqueous cleaning composition which may be in microemulsion form comprising polyalkylene oxide-polydimethyl siloxane
US5759983A (en) * 1993-08-04 1998-06-02 Colgate-Palmolive Co. Aqueous cleaning composition which may be in microemulsion form comprising polyalkylene oxide -polydimethyl siloxane and ethoxylated secondary alcohol
EP0647706A3 (en) * 1993-10-08 1996-04-10 Clorox Co Reduced residue hard surface cleaner.
EP0662529A1 (en) * 1994-01-11 1995-07-12 Mitsubishi Chemical Corporation Degreasing cleaner and method for cleaning oil-deposited material
US5674827A (en) * 1994-01-11 1997-10-07 Mitsubishi Chemical Corporation Degreasing cleaner and method for cleaning oil-deposited material
US5580848A (en) * 1994-12-15 1996-12-03 Colgate Palmolive Co. Microemulsion light duty liquid cleaning comnpositions
US5529723A (en) * 1994-12-15 1996-06-25 Colgate-Palmolive Co. Microemulsion light duty liquid cleaning compositions
US5714448A (en) * 1995-03-24 1998-02-03 The Clorox Company Reduced residue hard surface cleaner
US5851981A (en) * 1995-03-24 1998-12-22 The Clorox Company Reduced residue hard surface cleaner
US5585342A (en) * 1995-03-24 1996-12-17 The Clorox Company Reduced residue hard surface cleaner
US5849681A (en) * 1996-02-09 1998-12-15 S. C. Johnson & Son, Inc. Glass cleaner with enhanced anti-streaking properties
US5665689A (en) * 1996-09-04 1997-09-09 Colgate-Palmolive Co. Cleaning compositions comprising mixtures of partially esterified full esterified and non-esterfied ethoxylated polyhydric alcohols and N-alkyl aldonamides
US5990065A (en) * 1996-12-20 1999-11-23 The Procter & Gamble Company Dishwashing detergent compositions containing organic diamines for improved grease cleaning, sudsing, low temperature stability and dissolution
US5780415A (en) * 1997-02-10 1998-07-14 Colgate-Palmolive Company Stable microemulsion cleaning composition
WO1998047635A1 (en) * 1997-04-24 1998-10-29 Black Robert H Composition for cleaning transparent hard surfaces and method of using same
US6069122A (en) * 1997-06-16 2000-05-30 The Procter & Gamble Company Dishwashing detergent compositions containing organic diamines for improved grease cleaning, sudsing, low temperature stability and dissolution
US6727212B2 (en) 1997-11-10 2004-04-27 The Procter & Gamble Company Method for softening soil on hard surfaces
US6521584B1 (en) 1998-03-16 2003-02-18 Henkel Kommanditgesellschaft Auf Aktien Liquid multiphase detergents
US6589926B1 (en) 1998-06-02 2003-07-08 Procter & Gamble Company Dishwashing detergent compositions containing organic diamines
US6797701B2 (en) 1998-11-19 2004-09-28 Pfizer Inc. Antiparasitic formulations
US6288015B1 (en) 1998-12-23 2001-09-11 Henkel Kommanditgesellschaft Auf Aktien Multiphase cleaning composition containing lignin sulfonate
US6362154B1 (en) 1998-12-23 2002-03-26 Henkel Kommanditgesellschaft Auf Aktien Multiphase cleaning composition containing naphthalene sulfonic acid/formaldehyde condensate
US6187731B1 (en) 1998-12-23 2001-02-13 Henkel Kommandigesellschaft Auf Aktien (Kgaa) Cleaning compositions for hard surfaces containing naphthalene sulfonic acid/formaldehyde condensates
DE19900242A1 (en) * 1999-01-07 2000-07-13 Basf Coatings Ag Aqueous detergent and its use
US6350727B1 (en) 2000-01-28 2002-02-26 Amway Corporation Non-streaking no-wipe cleaning compositions with improved cleaning capability
US6656535B2 (en) * 2001-12-21 2003-12-02 Applied Materials, Inc Method of fabricating a coated process chamber component
US20030118731A1 (en) * 2001-12-21 2003-06-26 Applied Materials, Inc. Method of fabricating a coated process chamber component
US20050134629A1 (en) * 2003-12-19 2005-06-23 Martin Thomas W. Ink jet cleaning wipes
US20050227898A1 (en) * 2004-04-09 2005-10-13 Leskowicz James J Zero to low VOC glass and general purpose cleaner
US20110020560A1 (en) * 2005-12-07 2011-01-27 Mtu Aero Engines Gmbh Method for Manufacturing a Run-In Coating
US20080092806A1 (en) * 2006-10-19 2008-04-24 Applied Materials, Inc. Removing residues from substrate processing components
WO2008134023A1 (en) * 2007-04-25 2008-11-06 Caterpillar Inc. Cleaning compositions
US20100179246A1 (en) * 2009-01-14 2010-07-15 Perry Stephen C Anti-slip detergent
US8138237B2 (en) * 2009-01-14 2012-03-20 Perry Stephen C Anti-slip detergent
US20100196505A1 (en) * 2009-02-05 2010-08-05 American Sterilizer Company Low odor, hard surface sporicides and chemical decontaminants
WO2011008225A3 (en) * 2009-02-05 2011-04-21 American Sterilizer Company Low odor, hard surface sporicides and chemical decontaminants
CN102307467A (en) * 2009-02-05 2012-01-04 美国消毒者公司 Low odor, hard surface sporicides and chemical decontaminants
US20100196503A1 (en) * 2009-02-05 2010-08-05 American Sterilizer Company Low odor, hard surface sporicide
US8969283B2 (en) * 2009-02-05 2015-03-03 American Sterilizer Company Low odor, hard surface sporicides and chemical decontaminants
US8969282B2 (en) 2009-02-05 2015-03-03 American Sterilizer Company Low odor, hard surface sporicide
CN102307467B (en) * 2009-02-05 2015-03-11 美国消毒者公司 Low odor, hard surface sporicides and chemical decontaminants
US20110190187A1 (en) * 2010-01-29 2011-08-04 W. M. Barr & Company Organic residue remover composition
US8394751B2 (en) 2010-01-29 2013-03-12 W. M. Barr & Company Organic residue remover composition
US10433545B2 (en) 2016-07-11 2019-10-08 Ecolab Usa Inc. Non-streaking durable composition for cleaning and disinfecting hard surfaces
US10945431B2 (en) 2016-07-11 2021-03-16 Ecolab Usa Inc. Non-streaking durable composition for cleaning and disinfecting hard surfaces
US11884897B2 (en) 2016-11-28 2024-01-30 S. C. Johnson & Son, Inc. Hard surface cleaners including fluorosurfactants
US10100270B1 (en) 2017-01-04 2018-10-16 Gail R. Moser Procedure to acquire cleaning agent

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