US2880085A - Ferritic alloy steels for use at elevated temperatures - Google Patents
Ferritic alloy steels for use at elevated temperatures Download PDFInfo
- Publication number
- US2880085A US2880085A US645004A US64500457A US2880085A US 2880085 A US2880085 A US 2880085A US 645004 A US645004 A US 645004A US 64500457 A US64500457 A US 64500457A US 2880085 A US2880085 A US 2880085A
- Authority
- US
- United States
- Prior art keywords
- tungsten
- ferritic alloy
- elevated temperatures
- alloy steels
- niobium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910045601 alloy Inorganic materials 0.000 title description 12
- 239000000956 alloy Substances 0.000 title description 12
- 229910000831 Steel Inorganic materials 0.000 title description 3
- 239000010959 steel Substances 0.000 title description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 14
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 13
- 229910052721 tungsten Inorganic materials 0.000 claims description 13
- 239000010937 tungsten Substances 0.000 claims description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 229910052804 chromium Inorganic materials 0.000 claims description 9
- 239000011651 chromium Substances 0.000 claims description 9
- 229910052758 niobium Inorganic materials 0.000 claims description 9
- 239000010955 niobium Substances 0.000 claims description 9
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 9
- 229910052720 vanadium Inorganic materials 0.000 claims description 9
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 9
- 229910052715 tantalum Inorganic materials 0.000 claims description 8
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 8
- 229910052742 iron Inorganic materials 0.000 claims description 7
- 239000012535 impurity Substances 0.000 claims description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 10
- 229910000851 Alloy steel Inorganic materials 0.000 description 8
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 6
- 229910052796 boron Inorganic materials 0.000 description 6
- 239000010941 cobalt Substances 0.000 description 6
- 229910017052 cobalt Inorganic materials 0.000 description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 229910052759 nickel Inorganic materials 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 4
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 4
- 239000000470 constituent Substances 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
Definitions
- This invention relates to improvements relating to ferritic alloy steels for use at elevated temperatures.
- An object of the invention is to provide a forgeable ferritic alloy steel possessing improved creep resistance at temperatures up to 700 C. 1
- British specification No. 658,115 (hereinafter referred to as the earlier specification) describes a forgeable ferritic alloy steel having a composition characterised by the absence of nickel above a proportion of 1.5% and by the presence as essential constituents of 0.05-0.5% carbon, 4-20% chromium, 0.5-3% molybdenum and/or tungsten, 0.22.5% niobium, 0.05-0.25% nitrogen, 0.003- 0.5% boron and 0.1-2% vanadium.
- the alloy may also contain silicon up to 3% manganese up to 4% and cobalt up to
- the preferred proportions of the various constituents, as described in the earlier specification are:
- Percent Alloy steels of the above composition possess stressto-rupture properties of the following order:
- the alloys of this invention comprise as essential constituents 0.03 to 0.30% carbon, 4% to 20% chromium, over 3 and up to 16% tungsten, 0.1 to 2.0% vanadium, and 0.05 to 2.5% niobium interchangeable wholly or in part by tantalum.
- the alloys may also contain up to 2.0% silicon, up to 4% manganese, up to 1.5% nickel, up to 0.25% nitrogen, up to 0.5% boron and up to 20% cobalt.
- the alloys A, B, C contain respectively 4%, 6% and 8% of tungsten, and it will be noted that, with the particular alloys concerned, the rupture strength is approximately a function of the tungsten content.
- the creepresistance of an alloy steel depends to some extent on the heat treatment to which it has been subjected.
- suitable heat treatment as used above is intended to convey that the temperature, the rate of heating and cooling, and the duration of the treatment are such that optimum properties are developed for the particular composition.
- An example of heat treatment suitable in some cases is to harden in air or oil from about 1160 C. followed by a tampering treatment at 675 C.
- a forgeable ferritic alloy steel comprising 0.03 to 0.30% carbon, 4 to 20% chromium, over 3 and up to 16% tungsten, 0.1 to 2.0% vanadium, and 0.05 to 2.5% of at least one element from the group consisting of niobium and tantalum, and the balance iron with incidental impurities in ordinary amounts.
- a forgeable ferritic alloy steel comprising, 0.03 to 0.30% carbon, 4 to 20% chromium, over 3 and up to 16% tungsten, 0.1 to 2.0% vanadium, up to 2% of silicon, up to 4% of manganese, up to 1.5% of nickel, up to 0.25 nitrogen, up to 0.5% of boron, up to 20% of cobalt, 0.05 to 2.5% of at least one element from the group consisting of niobium and tantalum, and the balance iron with incidental impurities in ordinary amounts.
- a foregable ferritic alloy steel comprising, 003 to 0.20% carbon, 0.3 to 1.5% silicon, 0.5 to 1.5% manganese, 0.1 to 1.0% nickel, 9 to 16% chromium, over 3 and up to 10% tungsten, 0.1 to 0.7% vanadium, 5 to 15% cobalt, up to 0.10% nitrogen, up to 0.10% boron and 0.05 to 1.0% of at least one element from the group consisting of niobium and tantalum, and the balance iron with incidental impurities in ordinary amounts.
- a forgeable ferritic alloy steel comprising, 0.03 to 0.30% carbon, 4 to 20% chromium, over 3 and up to 16% tungsten, 0.1 to 2.0% vanadium, up to 2.0% of silicon, up to 4.0% manganese, up to 1.5% of nick l,
- a forgeable ferritic alloy steel article characterized by a rupture strength, expressed as stress for 100 hours at 650 C. of the order of 20 to 28 tons per square inch and having a composition consisting essentially of nickel up to about 1.5%, of 0.03 to 0.30% carbon, 4 to 20% chromium, 4 to 8% tungsten, 0.1 to 2.0% vanadium and 0.05 to 2.5% of at least one element selected from the group consisting of niobium and tantalum, and the balance iron with incidental impurities in ordinary amounts.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
Description
FERRITIC .ALLOY .STEELSEEOR USE-NI ELEVATED TEMPERATURES Henry'William Kirkby and "Charles sykes, sh arer-(man land, assignors toFirth-VickersStai'lilss SteelsIiimited,
Sheffield,EnglandyaBritish company No Drawing. Application March 11, 1957 Serial No. 645,004
Claims priority, application Great Britain March 29, 1956 Claims. (Cl. 75126) This invention relates to improvements relating to ferritic alloy steels for use at elevated temperatures.
An object of the invention is to provide a forgeable ferritic alloy steel possessing improved creep resistance at temperatures up to 700 C. 1
British specification No. 658,115 (hereinafter referred to as the earlier specification) describes a forgeable ferritic alloy steel having a composition characterised by the absence of nickel above a proportion of 1.5% and by the presence as essential constituents of 0.05-0.5% carbon, 4-20% chromium, 0.5-3% molybdenum and/or tungsten, 0.22.5% niobium, 0.05-0.25% nitrogen, 0.003- 0.5% boron and 0.1-2% vanadium. The alloy may also contain silicon up to 3% manganese up to 4% and cobalt up to The preferred proportions of the various constituents, as described in the earlier specification are:
Percent Alloy steels of the above composition possess stressto-rupture properties of the following order:
At 650 C.: Rupture strength (hrs.) tons/sq. in. 463 17 tons/sq. in. 30
It has now been found that with certain modification in the composition described in the earlier specification substantially higher rupture strength at 650 C. can be obtained. It will be noted that in the earlier composition the maximum range of the tungsten content was 0.5 to 3.0%. According to the principal modification of the present invention an increased amount of tungsten is incorporated, the new range being over 3% and up to 16%.
The alloys of this invention comprise as essential constituents 0.03 to 0.30% carbon, 4% to 20% chromium, over 3 and up to 16% tungsten, 0.1 to 2.0% vanadium, and 0.05 to 2.5% niobium interchangeable wholly or in part by tantalum. The alloys may also contain up to 2.0% silicon, up to 4% manganese, up to 1.5% nickel, up to 0.25% nitrogen, up to 0.5% boron and up to 20% cobalt.
2,880,085 Patented Mar. 31 1959 The preferred proportions of the variousconstituents are as follows:
7 Percent Carbon 4--.... 0103 :to 0.20 '-'Silico'n a 0.3 to 1.5 Manganese -05 to" 1.5 -t0 Chromium 9:0 to 16.0 Tungsten Over 3.0 -up *to 10.0 Vanadium 0.1 to 0.7 Niobium (interchangeable with tantalum) 0.05 to 1.0 Nitrogen Up to 0.10 Boron Up to 0.10 Cobalt 5.0 to 15.0 Iron Remainder Alloy A, Alloy B, Alloy 0, Earlier Specification tons/sq. tons/sq. tons/sq.
in. in. in.
163-1615 tons/sq. in. approx n 20 i 25 I 28 The alloys A, B, C contain respectively 4%, 6% and 8% of tungsten, and it will be noted that, with the particular alloys concerned, the rupture strength is approximately a function of the tungsten content.
As is known, the creepresistance of an alloy steel depends to some extent on the heat treatment to which it has been subjected. The term suitable heat treatment" as used above is intended to convey that the temperature, the rate of heating and cooling, and the duration of the treatment are such that optimum properties are developed for the particular composition. An example of heat treatment suitable in some cases is to harden in air or oil from about 1160 C. followed by a tampering treatment at 675 C.
We claim:
1. A forgeable ferritic alloy steel comprising 0.03 to 0.30% carbon, 4 to 20% chromium, over 3 and up to 16% tungsten, 0.1 to 2.0% vanadium, and 0.05 to 2.5% of at least one element from the group consisting of niobium and tantalum, and the balance iron with incidental impurities in ordinary amounts.
2. A forgeable ferritic alloy steel comprising, 0.03 to 0.30% carbon, 4 to 20% chromium, over 3 and up to 16% tungsten, 0.1 to 2.0% vanadium, up to 2% of silicon, up to 4% of manganese, up to 1.5% of nickel, up to 0.25 nitrogen, up to 0.5% of boron, up to 20% of cobalt, 0.05 to 2.5% of at least one element from the group consisting of niobium and tantalum, and the balance iron with incidental impurities in ordinary amounts.
3. A foregable ferritic alloy steel comprising, 003 to 0.20% carbon, 0.3 to 1.5% silicon, 0.5 to 1.5% manganese, 0.1 to 1.0% nickel, 9 to 16% chromium, over 3 and up to 10% tungsten, 0.1 to 0.7% vanadium, 5 to 15% cobalt, up to 0.10% nitrogen, up to 0.10% boron and 0.05 to 1.0% of at least one element from the group consisting of niobium and tantalum, and the balance iron with incidental impurities in ordinary amounts.
4. A forgeable ferritic alloy steel comprising, 0.03 to 0.30% carbon, 4 to 20% chromium, over 3 and up to 16% tungsten, 0.1 to 2.0% vanadium, up to 2.0% of silicon, up to 4.0% manganese, up to 1.5% of nick l,
.. 3 up to 0.25% of nitrogen, up to 0.5% of boron, up to 20% of cobalt, up to 3% of molybdenum, and 0.05 to 2.5% of at least one element from the group consisting of niobium and tantalum, and the balance iron with incidental impurities in ordinary amounts.
5. A forgeable ferritic alloy steel article characterized by a rupture strength, expressed as stress for 100 hours at 650 C. of the order of 20 to 28 tons per square inch and having a composition consisting essentially of nickel up to about 1.5%, of 0.03 to 0.30% carbon, 4 to 20% chromium, 4 to 8% tungsten, 0.1 to 2.0% vanadium and 0.05 to 2.5% of at least one element selected from the group consisting of niobium and tantalum, and the balance iron with incidental impurities in ordinary amounts.
References Cited in the file of this patent UNITED STATES PATENTS 2,253,385 Mahin Aug. 19, 1941 2,432,614 Franks et a1 Dec. 16, 1947 2,462,665 Olcott Feb. 22, 1949 2,542,220 Urban et a1 Feb. 20, 1951 2,590,835 Kirkby et a1. Apr. 1, 1952
Claims (1)
1. A FORGEABLE FERRITIC ALLOY STEEL COMPRISING 0.03 TO 0.30% CARBON, 4 TO 20% CHROMIUM, OVER 3 AND UP TO 16% TUNGSTEN, 0.1 TO 0.0% VANADIUM AND 0.05 TO 2.5% OF AT LEAST ONE ELEMENT FROM THE GROUP CONSISTING OF NIOBIUM AND TANTALUM, AND THE BALANCE IRON WITH INCIDENTAL IMPURITIES IN ORDINARY AMOUNTS.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2880085X | 1956-03-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2880085A true US2880085A (en) | 1959-03-31 |
Family
ID=10917044
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US645004A Expired - Lifetime US2880085A (en) | 1956-03-29 | 1957-03-11 | Ferritic alloy steels for use at elevated temperatures |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2880085A (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2967103A (en) * | 1958-12-11 | 1961-01-03 | James F Baldwin | Alloys for high-temperature service |
| US3154412A (en) * | 1961-10-05 | 1964-10-27 | Crucible Steel Co America | Heat-resistant high-strength stainless steel |
| US3364013A (en) * | 1967-02-06 | 1968-01-16 | Carpenter Steel Co | Stainless steel alloy |
| US3533780A (en) * | 1966-02-10 | 1970-10-13 | Sumitomo Metal Ind | High-strength austenitic stainless steel for a boiler |
| US3607238A (en) * | 1967-06-29 | 1971-09-21 | English Steel Corp Ltd | Heat-resistant to low chromium-nickel alloy steel for large forgings |
| US3663208A (en) * | 1968-06-20 | 1972-05-16 | Firth Brown Ltd | A chromium-nickel alloy steel containing copper |
| US3770425A (en) * | 1971-07-15 | 1973-11-06 | A Belenky | Welding electrode for continuous welding |
| US4477280A (en) * | 1981-12-25 | 1984-10-16 | Hitachi, Ltd. | Heat resisting steel |
| EP0159119A1 (en) * | 1984-02-29 | 1985-10-23 | KABUSHIKI KAISHA KOBE SEIKO SHO also known as Kobe Steel Ltd. | Low alloy steels for use in pressure vessels |
| EP0449611A1 (en) * | 1990-03-27 | 1991-10-02 | Hitachi Metals, Ltd. | Heat resistant steel |
| US5158745A (en) * | 1990-02-19 | 1992-10-27 | Nippon Steel Corporation | High-nitrogen ferritic heat-resisting steel |
| US5204056A (en) * | 1990-02-19 | 1993-04-20 | Nippon Steel Corporation | Method of production of high-nitrogen ferritic heat-resisting steel |
| EP0626463A1 (en) * | 1993-05-28 | 1994-11-30 | ABB Management AG | Heat- and creepresisting steel with martensitic structure, obtained by a thermal treatment process |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2253385A (en) * | 1941-01-29 | 1941-08-19 | Westinghouse Electric & Mfg Co | Steel |
| US2432614A (en) * | 1945-06-13 | 1947-12-16 | Haynes Stellite Co | Ferrous alloys for high temperature service |
| US2462665A (en) * | 1946-04-11 | 1949-02-22 | Gen Electric | Alloy |
| US2542220A (en) * | 1948-10-05 | 1951-02-20 | Nat Lead Co | Ferritic alloy |
| US2590835A (en) * | 1948-12-16 | 1952-04-01 | Firth Vickers Stainless Steels Ltd | Alloy steels |
-
1957
- 1957-03-11 US US645004A patent/US2880085A/en not_active Expired - Lifetime
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2253385A (en) * | 1941-01-29 | 1941-08-19 | Westinghouse Electric & Mfg Co | Steel |
| US2432614A (en) * | 1945-06-13 | 1947-12-16 | Haynes Stellite Co | Ferrous alloys for high temperature service |
| US2462665A (en) * | 1946-04-11 | 1949-02-22 | Gen Electric | Alloy |
| US2542220A (en) * | 1948-10-05 | 1951-02-20 | Nat Lead Co | Ferritic alloy |
| US2590835A (en) * | 1948-12-16 | 1952-04-01 | Firth Vickers Stainless Steels Ltd | Alloy steels |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2967103A (en) * | 1958-12-11 | 1961-01-03 | James F Baldwin | Alloys for high-temperature service |
| US3154412A (en) * | 1961-10-05 | 1964-10-27 | Crucible Steel Co America | Heat-resistant high-strength stainless steel |
| US3533780A (en) * | 1966-02-10 | 1970-10-13 | Sumitomo Metal Ind | High-strength austenitic stainless steel for a boiler |
| US3364013A (en) * | 1967-02-06 | 1968-01-16 | Carpenter Steel Co | Stainless steel alloy |
| US3607238A (en) * | 1967-06-29 | 1971-09-21 | English Steel Corp Ltd | Heat-resistant to low chromium-nickel alloy steel for large forgings |
| US3663208A (en) * | 1968-06-20 | 1972-05-16 | Firth Brown Ltd | A chromium-nickel alloy steel containing copper |
| US3770425A (en) * | 1971-07-15 | 1973-11-06 | A Belenky | Welding electrode for continuous welding |
| US4477280A (en) * | 1981-12-25 | 1984-10-16 | Hitachi, Ltd. | Heat resisting steel |
| EP0159119A1 (en) * | 1984-02-29 | 1985-10-23 | KABUSHIKI KAISHA KOBE SEIKO SHO also known as Kobe Steel Ltd. | Low alloy steels for use in pressure vessels |
| US5158745A (en) * | 1990-02-19 | 1992-10-27 | Nippon Steel Corporation | High-nitrogen ferritic heat-resisting steel |
| US5204056A (en) * | 1990-02-19 | 1993-04-20 | Nippon Steel Corporation | Method of production of high-nitrogen ferritic heat-resisting steel |
| EP0449611A1 (en) * | 1990-03-27 | 1991-10-02 | Hitachi Metals, Ltd. | Heat resistant steel |
| US5152850A (en) * | 1990-03-27 | 1992-10-06 | Hitachi Metals, Ltd. | Heat-resistant, ferritic cast steel and exhaust equipment member made thereof |
| EP0626463A1 (en) * | 1993-05-28 | 1994-11-30 | ABB Management AG | Heat- and creepresisting steel with martensitic structure, obtained by a thermal treatment process |
| US5415706A (en) * | 1993-05-28 | 1995-05-16 | Abb Management Ag | Heat- and creep-resistant steel having a martensitic microstructure produced by a heat-treatment process |
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