US2589175A - Aluminum base alloy for metal evaporation - Google Patents

Description

1952 A. R. WElNRlCZH ALUMINUM BASE ALLOY FOR M ETAL EVAPORATION Filed Dec. 28, 1948 Patented Mar. 11,1952

ALUMINUMWBASE ALLo ron. METAL EVAPORATION Arthur R. Weinrich, Brackenridge, Pa., assignor to Libbey-Owens-Ford Glass Company, Toledo, Ohio, a corporation of Ohio Application December 28, 1948', Serial No. 67,609

1 Claim. 1

This invention relates broadly to improvements in metal evaporation and more particularly to the thermal evaporation of aluminum alloys in the forming of mirrors and other coatings.

In metal evaporation, the metal to be evaporated is usually hung on a filament of tungsten, molybdenum, tantalum, or columbium as small loops or pieces of wire. Electric current is then passed through the filament to heat it and the wire pieces are melted whereupon the fused metal clings to the filament and evaporates as the heating is continued.

In the application of mirror and other coatings by evaporation within a vacuum as known in the thermal evaporation art, considerable spoilage is encountered by small chunks or particles of metal which tend to spatter or fly off the electric filament and cause rough spots upon the mirror or other article being coated, rendering it unfit for commercial use. This highly objectionable condition is frequently encountered when using pure or commercially pure aluminum and is customarily referred to in the art as spitting. The primary object of this invention is to improve the thermal evaporation of aluminum and its alloys so as to minimize, if not entirely eliminate, objectionable spattering or spitting of the metal during evaporation.

Another object of' the invention is to overcome spitting of the metal during evaporation by the provision of a special alloy of aluminum containing a relatively small amount of tungsten or a combination of tungsten and molybdenum and the balance substantially aluminum.

The use of such a special alloy of aluminum with tungsten or with'tungsten and molybdenum has been found to eliminate the spoilage from spitting or explosive boiling such as is found to a considerable degree when evaporating pure or commercially pure aluminum.

Other objects and advantages of the invention will be apparent from the following description and claim.

In the drawings:

Fig. 1 is a perspective view, partially broken away, of one type of thermal evaporation apparatus;

Fig. 2 is a perspective view of a portion of an electric filament showing the application of the metal alloy to several of the coils thereof; and

Figs. 3, 4, 5 and 6 are detail diagrammatic views illustrating the several phases of wetting or coating of the filament by the alloy of this invention.

Suitable apparatus which may be employed in carrying out the invention is illustratedin Fig. 1 and comprises a supporting base 10 upon which is mounted a housing shown as a whole at H. The housing Il may be in the form of a bell-jar or the like having a dome-like or semi-spherical top portion or enclosed end and a bottom open end having a surrounding flange or projection l2 which is adapted to restupon the upper surface of the supporting base l0.

Within the chamber provided by the housing I l is a suitable work support l3 for supporting a work piece such as a plate or piece of glass, plastic, plaster, paper, porcelain, metal, or the like M, in upright position. I

Also located within the chamber and mounted upon the supporting base 10 is a pair of upright supporting posts [5 between which is carried in substantially horizontal position an electric filament I6. The filament, as shown, is in the form of a coiled wire made of tungsten, molybdenum, columbium, or tantalum, whose opposite ends are attached to brackets I! mounted upon the supporting posts 15 and adjustable thereon so as to vary the position or location of the filament IS with relation to the supporting base I0.

The chamber provided by the housing I I may, if desired, be completely evacuated of air through outlet pipe or conduit l8 and have a high vacuum created therein by mean of suitable air evacuat ing and vacuum creating means such as a pump (not shown).

In accordance with the invention, which is carried out within the chamberedhousing ll, short pieces or loops IQ of the special aluminum alloy herein provided and consisting of a relatively small amount of tungsten, or a combination of tungsten and molybdenum with the balance substantially all aluminum, are bent and hung on the convolutions Ilia of the filament I6 in the manner shown.

When pure or commercially pure aluminum such as 98.5% aluminum is applied to a thermal evaporation filament and the filament energized by applying a heavy current thereto, the small pieces of aluminum receive their heat by contact with the filament and by heat conduction from the filament down through the metal pieces. Under such circumstances, the filament is invariably at a much higher temperature than the aluminum at the time the aluminum reaches its melting point of 658 Centigrade. Thus, depending upon the construction of the filament and the amount of electrical current applied thereto, the filament may be at a temperature in the range of 1000 to 2000 degrees Centigrade, in order to transfer sumcient heat to the aluminum and to evaporate it in a reasonabl time.

Pure and commercially pure molten aluminum wets by capillary attraction the metals tungsten, molybdenum, tantalum and columbium which are normally employed as evaporation filaments and such wetting occurs very rapidly. In fact, when the aluminum pieces applied to the filament becomes molten, they wet the filament so rapidly that the relatively cold molten aluminum flows out instantly over the much hotter filament surfaces originally not contacted by the aluminum pieces and as these hotter surfaces are above the temperatures required for forming aluminum vapor in the vacuum employed, the advancing molten aluminum is explosively vaporized. That portion of the advancing molten aluminum flowing by capillary attraction over and in direct contact with the very much hotter filament surfaces is the portion which is immediately vaporized and which acts to blow away the overlying liquid aluminum by the explosive boiling conditions thus generated. This spitting results in aluminum masses being deposited upon the surface being coated as small lumps or chunks and such spitted aluminum leads to an unsatisfactory coating and a spoiled article. This action is similar to the explosive boiling and spitting which occurs when water is flowed over a hot stove.

However, when pieces of the special aluminum alloy of this invention containing tungsten or tungsten and molybdenum are applied to similar thermal evaporation filaments and the filaments similarly heated, the alloy, upon melting, supplies molten metal to the hot filament surfaces not originally contacted thereby at a relatively much slower rate. In other words, the inclusion of the tungsten or tungsten and molybdenum acts to retard the speed at which the aluminum alloy feeds out to the filament. While the alloy seems to-be of the same surface tension and good wetting character for the filament metals as with pure or commercially pure aluminum, the alloy does not melt as a whole to a simple molten liquid as with pure or commercially pure aluminum, but gives a melt in which many small crystals of an unmelted material are present.

More particularly, the alloy melts first to a semi-pasty mass as indicated at 19a in Fig. 3, I

and such pasty character retards the flow of molten metal by capillary attraction onto the hotter surrounding filament surfaces. This retardation also permits a longer time for heat to fiow from the filament by conduction into the pasty mass l9a and its temperature is thus raised to a higher temperature so that the mass temperature and any small amounts of molten metal leaking out of the mass onto the hotter filament surfaces are relatively closer to the actual temperature of such surrounding filament surfaces. By reducing the temperature differential between the molten metal ,mass l9a and the surrounding portions of the filament upon which it later moves out upon, the danger of explosive boiling or spitting is minimized.

In Fig. 4, the pasty melted alloy mass I912 has become hotter than as shown in Fig. 3 and from such a pasty mass the molten phase begins to leak out upon the surrounding filament which it wets. The viscosity conditions in the pasty mass are sufficiently high, however, that the rate of leakage of the molten phase from the latter is controlled and relatively slow so that the amount of molten liquid moving out from the mass onto the surrounding filament surfaces results in only a very thin film of such liquid being present upon the filament surface, and the boiling action in such film as the liquid metal evaporates results only in completely vaporized metal and no unvaporized liquid metal is blown off or spitted.

As the temperature of the metal alloy mass is being continuously raised by heat fiow from the surrounding filament, such heat movement from the filament into the mass is cooling the adjacent portions of the filament somewhat and the filament and mass are progressively rapidly approaching each other in temperature, or the temperature differential between the two is becoming less and less. As the mass becomes hotter, more and ,more of the alloy appears to become fluid and the wetting of the filament proceeds through stages such as indicated at I in Fig. 5, and l9d in Fig. 6. In this manner, the improved alloys herein provided slow down the rate of application of the molten metal to the hot filaments and spitting is avoided.

Aluminum forms with tungsten or with molybdenum intermetallic compounds which are of very high melting point, and in alloys of these materials the intermetallic compounds are present as fine crystals generally of a needle like nature. On heating such aluminum alloys containing small amounts of these metals, the excess aluminum over that needed to form such intermetallic compounds begins to become fluid as temperature beyond the melting point of aluminum are reached. The intermetallic compound materials, however, do not melt until much higher temperatures are reached and the presence of these crystalline materials in the molten aluminum phase results in the pasty or highly viscous nature of the molten alloys. As the temperatures are raised beyond the melting point of pure or commercially pure aluminum and the mass approaches the temperature of the filament surfaces, the viscosity of the molten aluminum alloy decreases and finally the intermetallic compounds melt, and as the crystals disappear the pasty mass becomes more liquid and fluid.

As the fiuid aluminum or mixture of melted aluminum and intermetallic compounds or molten alloy flows onto the surrounding filament surfaces, the aluminum is vaporized into the evacuated chamber and deposits upon the article M to give a coating of aluminum. The aluminum present in the intermetallic compounds is also apparently distilled away from such compounds and the tungsten or molybdenum set free remains upon the filament. Thus, while an alloy of aluminum is provided for evaporation purposes the deposits formed are of pure aluminum and show all of the high reflectivity of pure aluminum. By way of contrast, the aluminum alloys, due to the intermetallic compounds, are grey and dull and will not take a polish such as is true of pure aluminum. By the use of the special aluminum alloys herein provided, aluminum mirrors of equal high reflectivity to those secured when evaporating pure aluminum are obtained.

In the thermal evaporation art, it has been suggested that the cause of spitting has been small amounts of air or other gases trapped in the aluminum, during the casting of the original billets, becoming heated and freed explosively at the time of the melting of the aluminum pieces in the vacuum. This, however, does not seem to be the case, but rather is caused by the above described temperature differential effects of the aluminum pieces and electric filament.

In general, it has been found that suitable aluminum alloys accomplishing the objects of this invention in producing coatings of aluminum by thermal evaporation are those containing tungsten in an amount of less than 10% and the balance substantially aluminum. Further, it has been discovered that the amount of tungsten in the aluminum alloy may be in the amount of 0.25% to 6.0 with good results being obtained with an alloy of aluminum containing 1.0% tungsten. Forming of the alloys either into a wire or a pellet is more readily carried out with the smaller amounts of the alloying tungsten or combination of tungsten and molybdenum as the presence of the intermetallic compounds in the aluminum alloys cause these alloys to be much harder than pure aluminum.

When a combination of tungsten and molybdenum are employed in an alloy with aluminum, it has been found desirable that the combined amount of the two alloying metals be less than 10% with the balance of the alloy substantially aluminum. For example, the tungsten in an alloy of this type may be of at least 0.1% and the total of the two metals tungsten and molybdenum varied within a combined amount in the alloy of up to 6.0% with the balance substantially aluminum. These alloys are very useful and a more specific alloy of this type would be one containing 2% tungsten and 4% molybdenum, the balance being substantially aluminum.

Other specific aluminum alloy compositions which may be used in following the invention are by Way of example:

1. Tungsten 0.25%, balance aluminum.

2. Tungsten 5.5%, balance aluminum.

3. Tungsten 0.1%, molybdenum 0.8%, balance aluminum.

4. Tungsten 2%. molybdenum 3.7%, balance aluminum.

In stating that the balance of the alloy, besides the tungsten, or combined tungsten and molybdenum content, is substantially aluminum, it is the intent herein to signify that such balance is pure aluminum or commercially pure aluminum, the alloy being such as would result from the addition of the tungsten or combined tungsten and molybdenum to such forms of aluminum. The other elements such as iron, silicon, copper, etc. present in small trace amounts in commercially pure aluminum and thereby introduced in the alloys are of obviously no importance in the special alloys herein provided or in their action, since commercially pure aluminum and pure aluminum are equally bad in causing spitting.

I claim:

An aluminum alloy for thermal evaporation composed of about 2% tungsten and 4% molybdenum, and the balance aluminum.

ARTHUR R. WEINRICH.

REFERENCES CITED The following references are of record in the file of this patent:

UNITED STATES PATENTS Number Name Date 1,974,970 Nook Sept. 25, 1934 2,067,907 Edwards Jan. 19, 1937 2,410,733 Hewlett Nov. 5, 1946 2,447,979 Hensel et al Aug. 24, 1948 OTHER REFERENCES Metallography of Aluminum Alloys, by Mondolfo, published by Wiley and Sons, 1943, pages 49 and 50.

Images