US2128146A - Sintered hard metal alloys - Google Patents
Sintered hard metal alloys Download PDFInfo
- Publication number
- US2128146A US2128146A US89469A US8946936A US2128146A US 2128146 A US2128146 A US 2128146A US 89469 A US89469 A US 89469A US 8946936 A US8946936 A US 8946936A US 2128146 A US2128146 A US 2128146A
- Authority
- US
- United States
- Prior art keywords
- carbide
- hard metal
- sintered hard
- metal alloys
- alloys
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910001092 metal group alloy Inorganic materials 0.000 title description 9
- 229910045601 alloy Inorganic materials 0.000 description 14
- 239000000956 alloy Substances 0.000 description 14
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 description 14
- INZDTEICWPZYJM-UHFFFAOYSA-N 1-(chloromethyl)-4-[4-(chloromethyl)phenyl]benzene Chemical compound C1=CC(CCl)=CC=C1C1=CC=C(CCl)C=C1 INZDTEICWPZYJM-UHFFFAOYSA-N 0.000 description 13
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 5
- 229910017052 cobalt Inorganic materials 0.000 description 5
- 239000010941 cobalt Substances 0.000 description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- 229910000851 Alloy steel Inorganic materials 0.000 description 4
- 239000008241 heterogeneous mixture Substances 0.000 description 3
- 150000001247 metal acetylides Chemical class 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- NFFIWVVINABMKP-UHFFFAOYSA-N methylidynetantalum Chemical compound [Ta]#C NFFIWVVINABMKP-UHFFFAOYSA-N 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 229910003468 tantalcarbide Inorganic materials 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 238000005275 alloying Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- -1 separate or mixed Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
- C22C29/08—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds based on tungsten carbide
Definitions
- the invention relates to sintered hard metal alloys intended for the chip-removing machining of steel and steel alloys, and has for its object sintered hard metal alloys which when used for the purpose set forth show an increased efficiency in comparison with the sintered hard metal alloys hitherto known.
- the sintered hard metal alloys used for the chip-removing treatment of steel and steel alloys contain tungsten carbide, auxiliary metals of lower melting point, such as cobalt or nickel, and titanium carbide or tantalum carbide.
- auxiliary metals of lower melting point such as cobalt or nickel
- titanium carbide or tantalum carbide The good effect, as to the increase of emciency, of the addition of the two last-named carbides is based upon the notable resistance to the formation of craters.
- Such craterous cavities frequently occur with sintered hard metal alloys, which besides auxiliary metal contain no alloying element but tungsten carbide, immediately behind the cutting edge and cause a comparatively rapid destruction of the cutting edge.
- auxiliary metal such as cobalt, nickel, iron, manganese, separate or mixed, or alloys of these metals for example with tungsten, molybdenum or chromium
- the content of auxiliary metal may vary within the limits from 0.5 to 20%, while the content of titanium carbide may amount to from 3 to 30% and that of vanadium carbide to from 0.3 to
- the best results are August '7, 1935 (01. 75-136) obtained with from 3 to 10% auxiliary metal, from 5 to 20% titanium carbide and from 0.5 to 5% vanadium carbide.
- the carbides occur at least partly as a heterogeneous mixture.
- Alloys of the compositions hereinbefore given 5 are excellently suited for the various kinds of machining steel and steel alloys and their use is of particular advantage in executing smoothening work. So, for example, a sintered hard metal alloy composed of about 5.5% cobalt, 16% tita- 1o nium carbide, 1% vanadium carbide, balance tungsten carbide, showed in smoothening steel pieces of a strength of about 90 kg/mm a life up to re-grinding of up to twice as long as a corresponding alloy containing no vanadium carbide.
- auxiliary metal when used in the following claims is to be understood as comprising cobalt, nickel, iron manganese, separate or mixed, or alloys of these metals with, for example, tungsten, molybdenum or chromium. 20
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Powder Metallurgy (AREA)
Description
Patented Aug. 23, 1938 PATENT OFFICE 2,128,146 SINTERED HARD IVIETAL ALLOYS Josef Hinniiber,
assignor to General Electric Company,
nectady, N. Y.
Essen-Ruttenscheid, Germany,
Sche- No Drawing. Application July 7, 1936, Serial No. 89,469. In Germany 3 Claims.
The invention relates to sintered hard metal alloys intended for the chip-removing machining of steel and steel alloys, and has for its object sintered hard metal alloys which when used for the purpose set forth show an increased efficiency in comparison with the sintered hard metal alloys hitherto known.
As known, the sintered hard metal alloys used for the chip-removing treatment of steel and steel alloys contain tungsten carbide, auxiliary metals of lower melting point, such as cobalt or nickel, and titanium carbide or tantalum carbide. The good effect, as to the increase of emciency, of the addition of the two last-named carbides is based upon the notable resistance to the formation of craters. Such craterous cavities frequently occur with sintered hard metal alloys, which besides auxiliary metal contain no alloying element but tungsten carbide, immediately behind the cutting edge and cause a comparatively rapid destruction of the cutting edge. With coarse approximation one may say that with increasing addition of titanium carbide or tantalum carbide also the resistance increases to formation of craters, whilst, however, simultaneously the properties of strength of the alloy deteriorate, so that in general the addition of these carbides has to be kept within determined limits.
It has now appeared that the hard metal alloys under consideration containing titanium carbide or tantalum carbide and hitherto used for the chip-removing mechanical working of steels and steel alloys surprisingly are far surpassed as to their efliclency in this work by sintered hard metal alloys which besides tungsten carbide and auxiliary metal of lower melting point contain both titanium carbide and vanadium carbide, the content of titanium carbide exceeding that of vanadium carbide. The content of auxiliary metal, such as cobalt, nickel, iron, manganese, separate or mixed, or alloys of these metals for example with tungsten, molybdenum or chromium, may vary within the limits from 0.5 to 20%, while the content of titanium carbide may amount to from 3 to 30% and that of vanadium carbide to from 0.3 to The best results are August '7, 1935 (01. 75-136) obtained with from 3 to 10% auxiliary metal, from 5 to 20% titanium carbide and from 0.5 to 5% vanadium carbide. In the alloy the carbides occur at least partly as a heterogeneous mixture.
Alloys of the compositions hereinbefore given 5 are excellently suited for the various kinds of machining steel and steel alloys and their use is of particular advantage in executing smoothening work. So, for example, a sintered hard metal alloy composed of about 5.5% cobalt, 16% tita- 1o nium carbide, 1% vanadium carbide, balance tungsten carbide, showed in smoothening steel pieces of a strength of about 90 kg/mm a life up to re-grinding of up to twice as long as a corresponding alloy containing no vanadium carbide.
The word auxiliary metal when used in the following claims is to be understood as comprising cobalt, nickel, iron manganese, separate or mixed, or alloys of these metals with, for example, tungsten, molybdenum or chromium. 20
What I claim and Patent is:
l. A sintered alloy containing about 5.5% cobalt, about 16% titanium carbide, about 1% vanadium carbide, and the remainder tungsten carbide.
2. A sintered alloy containing about .5% to 20% of auxiliary metal, about 3% to titanium carbide, about .3% to 10% vanadium carbide with the remainder tungsten carbide, the. 30 titanium carbide and vanadium carbide being present in the alloy principally as a, heterogeneous mixture and the titanium carbide content of the alloy being greater than the vanadium carbide content.
3. A sintered alloy containing about .5% to ,20% of auxiliary metal, about 3% to 30% titanium carbide, about .3% to 10% vanadium carbide with the remainder tungsten carbide, the titanium carbide and vanadium carbide being present in the alloy at least partly as a heterogeneous mixture and the titanium carbide content of the alloy being greater than the vanadium carbide content.
desire to secure by Letters JOSEF HmNUBER.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2128146X | 1935-08-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2128146A true US2128146A (en) | 1938-08-23 |
Family
ID=7986279
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US89469A Expired - Lifetime US2128146A (en) | 1935-08-07 | 1936-07-07 | Sintered hard metal alloys |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2128146A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3150938A (en) * | 1958-05-28 | 1964-09-29 | Union Carbide Corp | Coating composition, method of application, and product thereof |
-
1936
- 1936-07-07 US US89469A patent/US2128146A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3150938A (en) * | 1958-05-28 | 1964-09-29 | Union Carbide Corp | Coating composition, method of application, and product thereof |
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