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US2067166A - Tantalum carbide alloy - Google Patents

Tantalum carbide alloy Download PDF

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US2067166A
US2067166A US659834A US65983433A US2067166A US 2067166 A US2067166 A US 2067166A US 659834 A US659834 A US 659834A US 65983433 A US65983433 A US 65983433A US 2067166 A US2067166 A US 2067166A
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tantalum
alloy
weight
carbide
carbon
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US659834A
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Clarence W Balke
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RAMET Corp
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RAMET CORP
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
    • C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
    • C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds

Definitions

  • This invention relates in general to alloys, and has more particular reference to a novel and an improved alloy suitable for, but not limited to, the formation of tools and other implements.
  • a hard alloy which includes as its predominant constituent, tantalum and carbon, substantially all of the carbon being in the form of a carbide of tantalum, and where desired, some of the tantalum remaining uncarburized after the formation of the carbide; the provision in such an alloy of an auxiliary metal or metals making up a minor percentage by weight-of the entire alloy, and having a melting temperature less than that of the tantalum carbide; and the provision of a hard alloy including the tantalum, carbon, and the auxiliary material and having sufilcient hardness, toughness, and strength to be suitable as a working portion for lathe tools and tools for other metal cutting or working machines, which working portion will retain such hardness, strength, and. toughness even at the relatively high temperatures frequently developed in use.
  • One of the best alloys comprises tantalum and carbon in the proportion of from 93.8% to 95% by weight of tantalum, to from 6.2% to by weight of carbon, substantially all of the carbon being combined with the proper amount of the tantalum to form tantalum carbide according to the formula TaC,
  • a specific alloy within the purview of this invention comprises tantalum and carbon in the proportion of 94.25% by weight of tantalum to 5.75% by weight of carbon, substantially all of the carbon being combined with sufficient tantalum to form tantalum carbide according to the formula TaC, the alloy including in addition to the tantalum and carbon by weight of nickel.
  • the invention is not limited to the precise percentages or proportions and the exact ingredients mentioned above, but contemplates that the tantalum and carbon together may range from barely a predominating amount by weight up to 97% by weight of the entire alloy, and that the proportion of tantalum to carbon may be so calculated that while substantially all of the carbon is used to form tantalum carbide, some of the tantalum remains uncarburized to promote toughness in the final alloy.
  • this uncarburized tantalum may be provided for by having an excess of tantalum for that required to form the carbide, or it may be added as free metal after the carbide has been formed.
  • nickel is specifically mentioned as the auxiliary metal in the examples given above, the invention contemplates the use of any other metal or metals which have a melting temperature less than that of tantalum carbide, and which will wet the carbide or will alloy, at least to some extent, with the carbide at relatively low temperatures as compared with the melting temperature of tantalum carbide.
  • metals for the auxiliary material I may mention in addition to nickel,- iron,
  • tantalum carbide powder to which, where desired, tantalum is added or to start with a mixture of tantalum powder and carbon powder in the desired proportions to produce tantalum carbide according to the formula TaC with or without some free tantalum.
  • the tantalum is first mixed with the carbon powder, the tantalum and carbon are combined by heat and degasified in order to remove or to exclude such embrittling impurities as oxygen from the tantalum carbide. In other words, the tantalum.
  • the auxiliary metal or metals from the class including nickel, chromium, and manganese will bring about or will cause a shrinkage of the bodies into a sound solid alloy substantially free from porosity and voids.
  • the temperature of the combining heat treatment will vary according to the amount of and the particular auxiliary metal or metals from the group including nickel, chromium and manganese employed in the alloy. Ordinarily, however, this temperature is less than the melting temperature of the added auxiliary metal, but not less than 1350" C.
  • This vacuum heat treatment serves not only to combine the ingreto remove such embrlttling impurities as oxygen, which may have been absorbed, occluded, or otherwise picked up by the fine powders during the preceding stages preliminary to the formation of the final alloy.
  • an alloy of one or more metals of the class including nickel, chromium and manganese, and a refractory metal carbide which has a homogeneous and substantially nonporous structure and which will be substantially free from cratering.
  • This alloy retains the properties of sufficient hardness, mechanical strength and toughness for use in tools, even at the temperatures frequently developed in its use as a lathe, planing, or other cutting or metal working tool.
  • An imporous tool comprising an alloy consisting of deoxidized tantalum carbide predominating by weight therein, and a metal of the iron group united therewith.
  • An imporous tool comprising'zan alloy consisting of deoxidized tantalum carbide predominating by weight therein, and more than one metal of the iron group united therewith.
  • a hard and tough alloy comprising from 3% to 15% by weight of a metal of the iron group, and the remainder tantalum carbide having from 5% to 6.2% by weight of carbon.
  • a cutting tool comprising 10% by weight of nickel, the remainder tantalum and carbon in the proportion of 5.75% by weight of carbon to 94.25% by weight of tantalum.
  • a hard and tough alloy comprising tantalum carbide, including tantalum and carbon in the proportion of from 93.8% to 95% by weight of tantalum to from 6.2% to 5% by weight of carbon, and having in addition thereto a metal of the iron group making up the remainder of said alloy and ranging from 3% the entire alloy.
  • a hard and tough tool having a low heat conductivity comprising tantalum, carbon combined therewith in the proportion of from 93.8% to 95% by weight of the tantalum to fr'om.6.2% to 5% by weight of the carbon, the the carbon together making up not more than 97% by weight of the'tool, but not less than a predominating amount by weight of the tool, and a metal of the iron group combined with the tantalum and carbon and making up from 3% to 15% by weight of the tool.
  • a hard and tough tool having a low heat conductivity comprising tantalum, carbon combined therewith in the proportion of from 93.8% to 95% by weight of tantalum to from 6.2% to 5% by weight of the carbon, the tantalum and the carbon together making up not more than 97% by weight of the tool, but not less than a predominating amount by weight of the tool, and more than one metal of the iron group combined with the tantalum and carbon and making up from 3% to 15% by weight of the tool.
  • a hard alloy comprisingfrom' to 97% by weight of tantalum carbide and from 15% to 3% by weight of an auxiliary metal having a melting temperature below the melting temperature of the tantalum carbide and adapted to combine with tantalum at 'a relatively low temperature as compared with the melting point of the tantalum carbide.
  • a hard alloy comprising from 85% to 97% by weight of. tantalum carbide and from 15% to 3% by weight of nickel.
  • An alloy comprising a refractory metal from the group consisting of tantalum and columbium, carbon combined therewith in the proportion of from 93.8% to by weight of said refractory metal to from 6.2% to 5% by weight of carbon, said carbon being combined with'said refractory metal to form a carbide therewith, and from 3% to 15% by weight of nickel makingup the remainder of the alloy.
  • a hard and tough alloy comprising from 3% to 15% by weight of one or more metals of the iron group and the remainder one or more carbides of a hard refractory metal from the group consisting of tantalum and columbium.
  • a sintered, hard, tough, metal composition consisting substantially of tantalum carbide and a binder material, said binder to 15% by weight of tantalum and 30 material contain- 76 W055 Ktttlitlibt 'ent in said composition in appreciable but minor quantities.
  • composition consisting substantially oi columbium carbide, said binder material having a lower melting point than said carbide and consisting mainly of metal of the iron group.
  • a sintered, hard, tough, metal, composition consisting substantially of tantalum carbide and nickel, the nickel comprising from about 3% to about 20% of said composition.
  • a sintered, hard, tough, metal composition consisting substantially of tantalum carbide and metal of the iron group, said metal of the iron group comprising fromabout 3% to about 20% of said composition.
  • a sintered, hard, tough, metal composition consistingsubstantially of tantalum carbide and cobalt-the cobalt comprising from about 3% to about 20% of said composition.
  • a sintered, metal composition containing about 3% to about 20% of a binder material, the remainder of said composition consisting substantially of tantalum carbide, said binder having a lower melting point than said carbide.
  • a sintered composition consisting substantially of hard, metal carbide particles and a metallic cementing medium therefor, one of the principal ingredients 01' said composition being tantalum carbide.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Cutting Tools, Boring Holders, And Turrets (AREA)

Description

Patented Jan. 12, 1937 UNITED STATES OD KEFEHENL E PATENT OFFICE TANTALUM CARBIDE ALLOY Clarence W. Balke, Highland Park, Ill., assignor to Ramet Corporation of America, North Chi- No Drawing.
Serial No. 659,834
20 Claims.
This invention relates in general to alloys, and has more particular reference to a novel and an improved alloy suitable for, but not limited to, the formation of tools and other implements.
For so much of the subject matter herein dis' closed, which is also disclosed in either of my copending United States Letters Patent applications entitled Tantalum carbide alloy, Serial No. 439,227, filed March 26, 1930, and entitled Method of making hard alloys for cutting tools, Serial No. 439,228, filed March 26, 1930, the latter having since matured into Patent 1,937,185 dated Nov. 28, 1933, I claim the priority of said patent applications.
Among the objects of the invention is the provision of a novel alloy which, when used as a cutting tool, will be substantially non-cratering, that is, substantially free from undue wear or adherence between the chips from the work and the upper face of the tool when the tool is used for rapidly turning or cutting materials asdiiiicul so to work as steel.
Among other objects of the invention are the provision of a hard alloy which includes as its predominant constituent, tantalum and carbon, substantially all of the carbon being in the form of a carbide of tantalum, and where desired, some of the tantalum remaining uncarburized after the formation of the carbide; the provision in such an alloy of an auxiliary metal or metals making up a minor percentage by weight-of the entire alloy, and having a melting temperature less than that of the tantalum carbide; and the provision of a hard alloy including the tantalum, carbon, and the auxiliary material and having sufilcient hardness, toughness, and strength to be suitable as a working portion for lathe tools and tools for other metal cutting or working machines, which working portion will retain such hardness, strength, and. toughness even at the relatively high temperatures frequently developed in use.
Other objects and advantages of the invention will be apparent from the following description.
One of the best alloys, according to the invention, comprises tantalum and carbon in the proportion of from 93.8% to 95% by weight of tantalum, to from 6.2% to by weight of carbon, substantially all of the carbon being combined with the proper amount of the tantalum to form tantalum carbide according to the formula TaC,
and the carbon and tantalum together making A specific alloy within the purview of this invention comprises tantalum and carbon in the proportion of 94.25% by weight of tantalum to 5.75% by weight of carbon, substantially all of the carbon being combined with sufficient tantalum to form tantalum carbide according to the formula TaC, the alloy including in addition to the tantalum and carbon by weight of nickel. The invention is not limited to the precise percentages or proportions and the exact ingredients mentioned above, but contemplates that the tantalum and carbon together may range from barely a predominating amount by weight up to 97% by weight of the entire alloy, and that the proportion of tantalum to carbon may be so calculated that while substantially all of the carbon is used to form tantalum carbide, some of the tantalum remains uncarburized to promote toughness in the final alloy. Of course, this uncarburized tantalum may be provided for by having an excess of tantalum for that required to form the carbide, or it may be added as free metal after the carbide has been formed.
Furthermore, while nickel is specifically mentioned as the auxiliary metal in the examples given above, the invention contemplates the use of any other metal or metals which have a melting temperature less than that of tantalum carbide, and which will wet the carbide or will alloy, at least to some extent, with the carbide at relatively low temperatures as compared with the melting temperature of tantalum carbide. As examples of such metals for the auxiliary material, I may mention in addition to nickel,- iron,
DEHPRLIE? KUUWE cobalt, manganese, chromium, palladium, plat- One method which I have found suitable for combining the above mentioned ingredients is to start with tantalum carbide powder to which, where desired, tantalum is added or to start with a mixture of tantalum powder and carbon powder in the desired proportions to produce tantalum carbide according to the formula TaC with or without some free tantalum. Where the tantalum is first mixed with the carbon powder, the tantalum and carbon are combined by heat and degasified in order to remove or to exclude such embrittling impurities as oxygen from the tantalum carbide. In other words, the tantalum. and carbon in finely divided form are degasified by a heat treatment in vacuo and the carbide powders are intermixed with one or more of the auxiliary metals from the class including nickel, chromium -dients, but also serves and manganese in finely divided form. This mixture of tantalum carbide and the auxiliary metal with or without tantalum is pressed into workable bodies which are heat treated in vacuo to a temperature sufficient to form the alloy.
When these pressed bodies are heated in vacuo to a temperature at which the particular auxiliary metal or metals are molten or plastic, the auxiliary metal or metals from the class including nickel, chromium, and manganese, will bring about or will cause a shrinkage of the bodies into a sound solid alloy substantially free from porosity and voids. The temperature of the combining heat treatmentwill vary according to the amount of and the particular auxiliary metal or metals from the group including nickel, chromium and manganese employed in the alloy. Ordinarily, however, this temperature is less than the melting temperature of the added auxiliary metal, but not less than 1350" C. This vacuum heat treatment serves not only to combine the ingreto remove such embrlttling impurities as oxygen, which may have been absorbed, occluded, or otherwise picked up by the fine powders during the preceding stages preliminary to the formation of the final alloy.
I have found that tools of my novel alloy when used for rapidly turning or cutting materials as diflicult so to work as steel, are substantially free from that objectionable action known as cratering, or the undue wearing away of the tool material just back of the cutting edge of the tool, or adherence between the work chips and the tool material resulting in the removal of some tool material from the face of the tool.
Thus, an alloy of one or more metals of the class including nickel, chromium and manganese, and a refractory metal carbide is formed which has a homogeneous and substantially nonporous structure and which will be substantially free from cratering. This alloy retains the properties of sufficient hardness, mechanical strength and toughness for use in tools, even at the temperatures frequently developed in its use as a lathe, planing, or other cutting or metal working tool.
Illustrative of the advantages of this improved alloy, I have found that tools made thereof are extremely hard, and that in taking heavy cuts on a hard manganese steel, the tools did not heat so rapidly as other tools, and apparently offered a minimum resistance to the relative movement of the material being cut. In addition, the tools did not crater while operating under this exceedingly heavy duty.
While I have described as a preferred embodiment of my invention an alloy comprising tantalum carbide with or without free tantalum, it will be understood that the invention contemplates the use of other hard refractory metals and their carbides. In this connection I have particular reference to the refractory metal columbium and a carbide thereof. I do not, therefore, wish to be limited to the precise refractory metal or carbide thereof set forth, but contemplate that colurnbium carbide and/or columbium metal may replace tantalum carbide and/or tantalum, respectively, in whole or in part in my alloy, and I desire to avail myself of all such changes within the scope of the appended claims.
Having thus described my invention, what I claim as new and desire to secure by Letters Patent of the United States is:
1. An imporous tool comprising an alloy consisting of deoxidized tantalum carbide predominating by weight therein, and a metal of the iron group united therewith.
2. An imporous tool comprising'zan alloy consisting of deoxidized tantalum carbide predominating by weight therein, and more than one metal of the iron group united therewith.
3. A hard and tough alloy comprising from 3% to 15% by weight of a metal of the iron group, and the remainder tantalum carbide having from 5% to 6.2% by weight of carbon.
4. A cutting tool comprising 10% by weight of nickel, the remainder tantalum and carbon in the proportion of 5.75% by weight of carbon to 94.25% by weight of tantalum.
5. -A hard and tough alloy composed of from 3% to 15% by weight of nickel, and tantalum carbide making up the remainder of said alloy.
6. A hard and tough alloy comprising tantalum carbide, including tantalum and carbon in the proportion of from 93.8% to 95% by weight of tantalum to from 6.2% to 5% by weight of carbon, and having in addition thereto a metal of the iron group making up the remainder of said alloy and ranging from 3% the entire alloy.
7. A hard and tough tool having a low heat conductivity, comprising tantalum, carbon combined therewith in the proportion of from 93.8% to 95% by weight of the tantalum to fr'om.6.2% to 5% by weight of the carbon, the the carbon together making up not more than 97% by weight of the'tool, but not less than a predominating amount by weight of the tool, and a metal of the iron group combined with the tantalum and carbon and making up from 3% to 15% by weight of the tool.
8. A hard and tough tool having a low heat conductivity, comprising tantalum, carbon combined therewith in the proportion of from 93.8% to 95% by weight of tantalum to from 6.2% to 5% by weight of the carbon, the tantalum and the carbon together making up not more than 97% by weight of the tool, but not less than a predominating amount by weight of the tool, and more than one metal of the iron group combined with the tantalum and carbon and making up from 3% to 15% by weight of the tool.
9. A hard alloy comprisingfrom' to 97% by weight of tantalum carbide and from 15% to 3% by weight of an auxiliary metal having a melting temperature below the melting temperature of the tantalum carbide and adapted to combine with tantalum at 'a relatively low temperature as compared with the melting point of the tantalum carbide.
10. A hard alloy comprising from 85% to 97% by weight of. tantalum carbide and from 15% to 3% by weight of nickel.
11. An alloy comprising a refractory metal from the group consisting of tantalum and columbium, carbon combined therewith in the proportion of from 93.8% to by weight of said refractory metal to from 6.2% to 5% by weight of carbon, said carbon being combined with'said refractory metal to form a carbide therewith, and from 3% to 15% by weight of nickel makingup the remainder of the alloy. I
12. A hard and tough alloy comprising from 3% to 15% by weight of one or more metals of the iron group and the remainder one or more carbides of a hard refractory metal from the group consisting of tantalum and columbium.
13. A sintered, hard, tough, metal composition consisting substantially of tantalum carbide and a binder material, said binder to 15% by weight of tantalum and 30 material contain- 76 W055 Ktttlitlibt 'ent in said composition in appreciable but minor quantities.
15. A sintered composition containing about" 3% to about 25% of a metallic binder material,
the remainder of said composition consisting substantially oi columbium carbide, said binder material having a lower melting point than said carbide and consisting mainly of metal of the iron group.
16. A sintered, hard, tough, metal, composition consisting substantially of tantalum carbide and nickel, the nickel comprising from about 3% to about 20% of said composition.
17. A sintered, hard, tough, metal composition consisting substantially of tantalum carbide and metal of the iron group, said metal of the iron group comprising fromabout 3% to about 20% of said composition.
18. A sintered, hard, tough, metal composition consistingsubstantially of tantalum carbide and cobalt-the cobalt comprising from about 3% to about 20% of said composition.
19. A sintered, metal composition containing about 3% to about 20% of a binder material, the remainder of said composition consisting substantially of tantalum carbide, said binder having a lower melting point than said carbide.
20. A sintered composition consisting substantially of hard, metal carbide particles and a metallic cementing medium therefor, one of the principal ingredients 01' said composition being tantalum carbide.
CIARENC'E W. BALKE.
OEHHUH
US659834A 1933-03-06 1933-03-06 Tantalum carbide alloy Expired - Lifetime US2067166A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3109917A (en) * 1959-04-18 1963-11-05 Boehler & Co Ag Geb Hard facing
US3150938A (en) * 1958-05-28 1964-09-29 Union Carbide Corp Coating composition, method of application, and product thereof
US3628921A (en) * 1969-08-18 1971-12-21 Parker Pen Co Corrosion resistant binder for tungsten carbide materials and titanium carbide materials
US3746456A (en) * 1969-08-18 1973-07-17 Parker Pen Co Ball point pen writing ball composed of a cemented carbide composition

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3150938A (en) * 1958-05-28 1964-09-29 Union Carbide Corp Coating composition, method of application, and product thereof
US3109917A (en) * 1959-04-18 1963-11-05 Boehler & Co Ag Geb Hard facing
US3628921A (en) * 1969-08-18 1971-12-21 Parker Pen Co Corrosion resistant binder for tungsten carbide materials and titanium carbide materials
US3746456A (en) * 1969-08-18 1973-07-17 Parker Pen Co Ball point pen writing ball composed of a cemented carbide composition

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