US216949A - Improvement in blasting-powder - Google Patents
Improvement in blasting-powder Download PDFInfo
- Publication number
- US216949A US216949A US216949DA US216949A US 216949 A US216949 A US 216949A US 216949D A US216949D A US 216949DA US 216949 A US216949 A US 216949A
- Authority
- US
- United States
- Prior art keywords
- improvement
- powder
- gunpowder
- blasting
- nitro
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000843 powder Substances 0.000 title description 3
- 239000003721 gunpowder Substances 0.000 description 8
- RJKGJBPXVHTNJL-UHFFFAOYSA-N 1-nitronaphthalene Chemical compound C1=CC=C2C([N+](=O)[O-])=CC=CC2=C1 RJKGJBPXVHTNJL-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- XNKFCDGEFCOQOM-UHFFFAOYSA-N 1,2-dinitronaphthalene Chemical compound C1=CC=CC2=C([N+]([O-])=O)C([N+](=O)[O-])=CC=C21 XNKFCDGEFCOQOM-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- SNIOPGDIGTZGOP-UHFFFAOYSA-N Nitroglycerin Chemical compound [O-][N+](=O)OCC(O[N+]([O-])=O)CO[N+]([O-])=O SNIOPGDIGTZGOP-UHFFFAOYSA-N 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000009514 concussion Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229960003711 glyceryl trinitrate Drugs 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- DGMJZELBSFOPHH-KVTDHHQDSA-N mannite hexanitrate Chemical compound [O-][N+](=O)OC[C@@H](O[N+]([O-])=O)[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)CO[N+]([O-])=O DGMJZELBSFOPHH-KVTDHHQDSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- MHWLNQBTOIYJJP-UHFFFAOYSA-N mercury difulminate Chemical compound [O-][N+]#C[Hg]C#[N+][O-] MHWLNQBTOIYJJP-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B31/00—Compositions containing an inorganic nitrogen-oxygen salt
- C06B31/02—Compositions containing an inorganic nitrogen-oxygen salt the salt being an alkali metal or an alkaline earth metal nitrate
- C06B31/12—Compositions containing an inorganic nitrogen-oxygen salt the salt being an alkali metal or an alkaline earth metal nitrate with a nitrated organic compound
- C06B31/14—Compositions containing an inorganic nitrogen-oxygen salt the salt being an alkali metal or an alkaline earth metal nitrate with a nitrated organic compound the compound being an aromatic
Definitions
- This invention relates to a new and improved gunpowder, the advantages of which are, that it can be made much more rapidly than ordinary gunpowder, and without the intervention of expensive machinery and dangerous manipulation, and is stronger than ordinary gunpowder.
- the object of my invention is to accomplish these results without resorting to those expensive and dangerous processes.
- I employ seventy-five parts of saltpeter, twelve and onehalf parts of sulphur, and twelve and one-half parts of charcoal, which are to be separately reduced to an impalpably fine powder and then intimately mixed.
- Nitro-naphthaline belongs to a class of explosive substances, (nitrated hydrocarbons,) such as nitrate of ethyl and nitro-mannite, some of which are fluid and others solid, and which have not generally come into much practical use. Several of these bodies would, answer my purpose. By preference I use nitro-naph-' thaline, it being the cheapest body.
- the compound resulting from this process has the following properties: It does not explode from friction or concussion. It does not require a fulminate of mercury, gun-cotton, or nitro-glycerine to explode it; and though these agents may be used, it may also be exploded by the use of the common fuse. It burns more slowly than common gunpowder, but with much greater violence. Ignited in the open air it burns, but does not explode.
- composition of matter consistingof niter, sulphur, and charcoal,in the usual proportions of gunpowder, mixed with nitro-naphth'aline, substantially as described.
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
IINITED STATES PATENT OFFICE.
CHARLES FELHOEN, OF NEW YORK, N. Y.
IMPROVEMENT IN BLASTING-POWDER.
Specification forming part of Letters Patent No. 216,949, dated July 1, 1879 application filed June 13, 1878.
To all whom it may concern:
Be it known that I, CHARLES FELHOEN, of New York city, county and State of New York, have invented a new and useful Improvement in the Manufacture of Gunpowder; and I do hereby declare that the followin g is a full, clear, and exact description thereof.
This invention relates to a new and improved gunpowder, the advantages of which are, that it can be made much more rapidly than ordinary gunpowder, and without the intervention of expensive machinery and dangerous manipulation, and is stronger than ordinary gunpowder.
It is well known that the only purpose of graining and glazing ordinary gunpowder is to prevent the separation of its component parts, to prevent the absorption of moisture, and to insure a more rapid combustion.
The object of my invention is to accomplish these results without resorting to those expensive and dangerous processes.
For the purpose of my invention I employ seventy-five parts of saltpeter, twelve and onehalf parts of sulphur, and twelve and one-half parts of charcoal, which are to be separately reduced to an impalpably fine powder and then intimately mixed.
To ninety parts of the above mixture I add and thoroughly mix ten parts of nitro-naph thaline prepared as hereinafter described. No special precaution or mode of mixing is needed in eflecting the several mixtures.
Nitro-naphthaline belongs to a class of explosive substances, (nitrated hydrocarbons,) such as nitrate of ethyl and nitro-mannite, some of which are fluid and others solid, and which have not generally come into much practical use. Several of these bodies would, answer my purpose. By preference I use nitro-naph-' thaline, it being the cheapest body.
Thenitro-naphthalineIprepareby digesting, with or without heat, one part of naphthaline in four parts of nitric acid of specific gravity 1.40forfivedays. Thenaphthalineisconverted into a brown unctuous crystalline mass, which must be well washed with water to free it from all trace of acid, and then dried and pulverized.
By this means I obtain a mononitro-naphthaline containing a small proportion of dinitronaphthaline.
I do not confine myself to the exact proportions either of the gunpowder or the nitronaphthaline as herein set forth, but substantially as above stated.
The compound resulting from this process has the following properties: It does not explode from friction or concussion. It does not require a fulminate of mercury, gun-cotton, or nitro-glycerine to explode it; and though these agents may be used, it may also be exploded by the use of the common fuse. It burns more slowly than common gunpowder, but with much greater violence. Ignited in the open air it burns, but does not explode.
I find from numerous experiments that not less than ten per cent. of the nitro-naphthaline should be used. The quantity may be increased ad libitum to perform the oflices required.
What I claim as my invention, and desire to secure by Letters Patent, is-
The herein-described composition of matter, consistingof niter, sulphur, and charcoal,in the usual proportions of gunpowder, mixed with nitro-naphth'aline, substantially as described.
OHS. FELHOEN.
Witnesses:
PERCY B. BRoMFrELD, RUssELL B. DAVIS.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US216949A true US216949A (en) | 1879-07-01 |
Family
ID=2286351
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US216949D Expired - Lifetime US216949A (en) | Improvement in blasting-powder |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US216949A (en) |
-
0
- US US216949D patent/US216949A/en not_active Expired - Lifetime
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