US20160032429A1

US20160032429A1 - Low Silver, Low Nickel Brazing Material

Info

Publication number: US20160032429A1
Application number: US14/880,881
Authority: US
Inventors: Alan Belohlav; Marcin Kuta
Original assignee: Lucas Milhaupt Inc
Current assignee: Lucas Milhaupt Inc
Priority date: 2009-10-26
Filing date: 2015-10-12
Publication date: 2016-02-04
Also published as: EP2493652A4; US9157134B2; US20120207643A1; EP2493652A1; WO2011053506A1

Abstract

A homogenous brazing material essentially consisting of relatively low amounts of silver and nickel together with copper, zinc, and other constituents is provided. The brazing material has a working temperature exceeding 630° F. and is preferably between about 1250° F. and 1500° F. The brazing material preferably has about 30 percent by weight of silver, about 36 percent by weight of copper, about 32 percent by weight of zinc, and about 2 percent by weight of nickel. The addition of nickel in the above-specified amount improves resistance against interface corrosion in aqueous solutions, aids in the strength of the alloy, and provides improved wettability on ferrous and non-ferrous substrates. The brazing material may also include a flux, such as a core or a coating.

Description

CROSS-REFERENCES TO RELATED APPLICATIONS

This application claims a benefit of priority and is a continuation of U.S. application Ser. No. 13/503,551 filed on Apr. 23, 2012, which churns priority under 35 USC §119 to PCT No. PCT/US2010/053561 filed Oct. 21, 2010, the entire contents of both which are hereby expressly incorporated by reference into the present application. This application also claims priority to provisional application No 61/254,864 filed on Oct. 26, 2009. This application also expressly incorporates by reference the entire contents of U.S. patent application Ser. Nos. 12/602,035 and 11/753,045.

BACKGROUND OF THE INVENTION

1. Field of the Invention
This invention relates generally to brazing material and, more particularly, to a low silver, low nickel brazing materials.
2. Related Art
As is known to those skilled in the art, brazing is a joining process whereby a filler metal is heated to a melting temperature which is lower than the melting temperature of the base metal and distributed between two or more close-fitting, parts. The molten filler metal interacts with the base metal and then cools to form a strong, sealed joint. A wide variety of filler metals and alloys may be used. In some cases, flux, in addition to the filler metal, is used.
Brazing with silver-based filler metals has commonly been used as an alternative to bronze brazing because silver brazing does not suffer from the disadvantages that prior forms of bronze brazing have, such as for example, the left-behind residue and oxide layer formation on the base metal which is heavy, aesthetically displeasing, and difficult to remove. Brazing with silver-based filler metal, however, is disadvantageous in that the silver alloys are costly.
Thus, there is a desire for a brazing material that provides the benefits of silver-based fillers but that generally avoids the costs typically associated with such silver based fillers,

BRIEF SUMMARY OF THE INVENTION

Consistent with the foregoing and in accordance with the invention as embodied and broadly described herein, a brazing material consisting essentially of silver, copper, zinc, and nickel is provided, In one embodiment the brazing, material includes silver, copper, zinc, and nickel in a homogenous cast form, flux cored form, powder, paste, and/or flux coated form.
One object of the invention is to provide a brazing material with a lower silver content e.g., approximately 20-60%, and nickel content, e.g., approximately 1-5% in a homogenous form to provide improved braze joint strength and corrosion resistance.
Another object of the invention is to provide a brazing material capable of taking on different forms, such as a strip, wire, ring, washer, powder, paste and other types of performs. Such performs may be coated or cored with an anti-oxide agent, e.g., a flux.
Yet another object is to provide a brazing material that is economical and easy to fabricate and use.
Another object of the present invention is to provide a brazing material that may be configured for use in different applications, For example, the present invention may be used with torch, induction, furnace, or other heating methods that are performed in open air and require the use of a flux and/or controlled atmosphere without the use of flux.
These aspects are merely illustrative of the innumerable aspects associated with the present invention and should not be deemed as limiting in any manner. These and other aspects, features, and advantages of the present invention will become apparent from the following detailed description when taken in conjunction with the drawings.

BRIEF DESCRIPTION OF THE DRAWINGS

Preferred exemplary embodiments of the invention are illustrated in the accompanying drawing in which like reference numerals represent like parts throughout, and in which:

FIG. 1 illustrates a cross-sectional view of a round-shaped flux cored wire, feed having an alloy casing according to one aspect of the invention; and

FIG. 2 illustrates a cross-sectional view of an oval-shaped flux cored wire feed having an alloy casing according to one aspect of the invention.

DETAILED DESCRIPTION OF THE INVENTION

The inventors have discovered an alloy suitable for brazing and having a low silver and low nickel content. In one embodiment, the alloy has the following by weight approximate percentages:

- a. Silver 20.0%-60.0%
- b. Copper 20.0%-60.0%
- c. Zinc 31.0%-40.0%
- d. Nickel 0.5%-5.00%
- e. Trace Elements 0.15% Maximum

The “trace elements” typically include elements that are picked up during casting of the alloy or other downstream operations during alloy fabrication, such as rolling, drawing, and the like. The trace elements could include cadmium, tin, manganese, lead, and aluminum, as well as others.
The melting range of the alloy is preferably between approximately 1250° F. and approximately 1450° F. (677° C.-788° C.). The nickel Content of the alloy improves wettability of the filler metal on ferrous and non-ferrous substrates. The addition of nickel in the alloy also improves resistance against interface corrosion in aqueous solutions and makes the alloy particularly well-suited for brazing steels and stainless steel alloys. The presence of nickel also aids in alloy strength. The brazing material may further include a flux, e.g., as a core or coating. The flux preferably has an active temperature substantially lower than that of the liquidus point of the brazing material.
The brazing material may be delivered in a variety of different forms such as flux cored round wires, oval wires, round rods, oval rods, round rings, oval rings, round specialty preforms, oval specialty preform, or homogonous cast solid wires, rings, strips, washers and other such pre-forms, paste, and powder. Additionally, the brazing material described herein provides improved free-flowing characteristics when compared to known non-cadmium to silver content based alloys. It will also be appreciated that a zinc constituent of between 31 and 40% by weight advantageously provides for a lower melting temperature and improves flow. Further, as cadmium is a known carcinogen, the present invention uses a significantly lower amount of cadmium than other known alloys and therefore is compliant with governmental regulations regarding the use and handling of potentially hazardous materials. In addition to improved flow characteristics, the inventors have also found that the present invention advantageously provides an alloy with corrosion characteristics similar to those of more costly high silver content alloys.
FIG. 1 illustrates one exemplary form in which the alloy of the present invention may be embodied. A circular flux cored wire feed 10 is shown in FIG. 1. Although a wire loop is shown, any shape may be used. The flux wire 10 includes a rolled metal alloy sheet 12 having a composition similar to that described above and that defines a casing for flux material 14. The flux used in the core is preferably a low temperature, water-soluble, proprietary post-braze flux, such as HANDY FLUX braze offered by Lucas-Milhaupt.
FIG. 2 illustrates another exemplary form in which the present invention may be embodied. More particularly, the figure shows flux cored ring 16 having an oval cross section. The ring has rolled metal alloy sheet 18 having a composition similar to that described herein and defines a casing for flux material 20. The flux used in the core is preferably a low temperature, water-soluble, proprietary post-braze flux, such as HANDY FLUX braze offered by Lucas-Milhaupt. In one preferred implementation, ring 16 is 0.053 inches wide and 0.092 inches thick; although, rings with other dimensions are possible.
The inventors have found that the present alloy of the present invention provides a braze capable of providing high strength joints. For example, the braze of the present invention, when used with low carbon steel, was found to provide joints having a tensile strength between 55,000 p.s.i-71,900 p.s.i. The table below provides summarizes Ultimate Tensile Strength and elongation characteristics of one embodiment of the braze of the present invention.

TABLE 1

Diameter	Ultimate Tensile	Yield Stress	Elong.	Young's Modulus	Maximum Load	Yield Load	BreaK Load	Break Disp
(in)	Strength (psi)	(psi)	(%)	(Auto) (psi)	(lbf)	(lbf)	(Auto) (lbf)	(Auto) (in)

1	0.125	99251.227	41206.961	7.154	6263201.00	1217.996	505.686	849.092	0.143
2	0.125	99626.852	51780.965	6.334	6708642.50	1222.605	635.448	865.360	0.127
Mean	0.125	99439.039	46493.961	6.744	6485922.00	1220.301	570.567	857.226	0.135
S.D.	0.000	265.607	7476.950	0.580	314974.719	3.259	91.756	11.503	0.012
Minimum	0.125	99251.227	41206.961	6.334	6263201.00	1217.996	505.686	849.092	0.127
Maximum	0.125	99626.852	51780.965	7.154	6708642.50	1222.605	635.448	865.360	0.143

It will be appreciated that the inventive alloy may be used with a number of different known brazing and to-be-developed brazing techniques. One exemplary brazing technique is described in U.S. Ser. No. 12/523,112, the disclosure of which is incorporated herein. Additionally, the invention provides a braze that is ductile, conductive, provides generally leak tight joints, user-friendly, and forgiving. Joints formed with the braze of the invention are also believed to be visually pleasing.
While preferred examples of the present invention have been illustrated and described, this has been by way of illustration only, and the invention should not be limited except as required by the scope of the appended claims and their equivalents.
Many changes and modifications could be made to the invention without departing from the spirit thereof. The scope of these changes will become apparent from the appended claims.

Claims

We claim:

1. A brazing material consisting essentially of

less than approximately 35 percent by weight of silver;

less than approximately 40 percent by weight of copper;

more than 18 percent by weight of zinc; and

from approximately 1.75 percent by weight to approximately 2.25 percent by weight of nickel.

2. The material of claim 1 having silver in an amount less than 32 percent by weight of silver.

3. The material of claim 2 having silver in an amount less than 31 percent by weight of silver.

4. The material of claim 3 having from approximately 29 percent by weight to approximately 31 percent by weight of silver.

5. The material of claim 1 having from approximately 31 percent by weight to approximately 40 percent by weight of zinc.

6. The material of claim 1 having copper in an amount less than 38 percent by weight.

7. The material of claim 6 having copper in an amount less than approximately 37 percent by weight.

8. The material of claim 7 having from approximately 35 percent by W eight to approximately 37 percent by weight of copper.

9. The material of claim 1 having a working temperature greater than approximately 630° F.

10. The material of claim 9 having a working temperature of between 1250° F. and 1450° F.

11. The material of claim 1 in the form of at least one of a strip, a wire, a ring, a washer, a powder, and a paste.

12. The material of claim 1 configured for at least one of:

use with torch, induction, furnace or other heating methods that are performed in open air and require the use of a flux; and

controlled atmosphere heating without the use of a flux.

13. The material of claim 1 having less than 0.20 percent by weight of indium, gallium, tin, aluminum, and titanium.

14. A brazing material essentially consisting of:

copper;

zinc;

nickel;

silver;

less than six percent by weight of cadmium;

trace constituents amounting to no more than 0.15 percent by weight of the total material composition; and

the brazing material having a working temperature exceeding 630° F.

15. The material of claim 14 having from approximately 29 percent by weight to approximately 31 percent by weight of silver.

16. The material of claim 14 having from approximately 1.75 percent by weight to approximately 225 percent by weight of nickel.

17. The material of claim 14 having from approximately 31 percent by weight to approximately 33 percent by weight of zinc.

18. The material of claim 14 having from approximately 35 percent by weight to approximately 37 percent by weight of copper.

19. The material of claim 14 having a working temperature between approximately 1250° F. to approximately 1450° F.

20. A brazing material having a total composition consisting essentially of:

from approximately 20 percent by weight to approximately 60 percent by weight of silver;

from approximately 20 percent by weight to approximately 60 percent by weight of copper:

from approximately 31 percent to approximately 40 percent by weigh of zinc;

from approximately 0.5 percent by weight to approximately 5.00 percent by weight of nickel; and

trace elements amounting to no more than approximately 0.15 percent by weight of the total composition.