US20090324441A1 - Austenitic stainless cast steel part, method for production and use thereof - Google Patents
Austenitic stainless cast steel part, method for production and use thereof Download PDFInfo
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- US20090324441A1 US20090324441A1 US12/374,482 US37448207A US2009324441A1 US 20090324441 A1 US20090324441 A1 US 20090324441A1 US 37448207 A US37448207 A US 37448207A US 2009324441 A1 US2009324441 A1 US 2009324441A1
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- 229910001208 Crucible steel Inorganic materials 0.000 title claims abstract description 146
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 83
- 239000011651 chromium Substances 0.000 claims abstract description 56
- 239000000463 material Substances 0.000 claims abstract description 40
- 230000000694 effects Effects 0.000 claims abstract description 35
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 27
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 27
- 239000007789 gas Substances 0.000 claims abstract description 24
- 238000005266 casting Methods 0.000 claims abstract description 21
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 19
- 238000010276 construction Methods 0.000 claims abstract description 19
- 239000004411 aluminium Substances 0.000 claims abstract description 18
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 18
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000010703 silicon Substances 0.000 claims abstract description 17
- 239000010949 copper Substances 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 239000000126 substance Substances 0.000 claims abstract description 11
- 239000010936 titanium Substances 0.000 claims abstract description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000005275 alloying Methods 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims abstract description 8
- 238000005057 refrigeration Methods 0.000 claims abstract description 8
- 229910052742 iron Inorganic materials 0.000 claims abstract description 5
- 229910000831 Steel Inorganic materials 0.000 claims description 34
- 239000010959 steel Substances 0.000 claims description 34
- 229910045601 alloy Inorganic materials 0.000 claims description 29
- 239000000956 alloy Substances 0.000 claims description 29
- 238000000034 method Methods 0.000 claims description 29
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 24
- 239000011572 manganese Substances 0.000 claims description 21
- 229910052748 manganese Inorganic materials 0.000 claims description 18
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 16
- 229910052750 molybdenum Inorganic materials 0.000 claims description 13
- 229910052757 nitrogen Inorganic materials 0.000 claims description 13
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 12
- 239000011733 molybdenum Substances 0.000 claims description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 10
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- 239000010941 cobalt Substances 0.000 claims description 10
- 229910017052 cobalt Inorganic materials 0.000 claims description 10
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 10
- 229910052802 copper Inorganic materials 0.000 claims description 10
- 239000010955 niobium Substances 0.000 claims description 10
- 229910052721 tungsten Inorganic materials 0.000 claims description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 9
- 239000010937 tungsten Substances 0.000 claims description 9
- 229910052720 vanadium Inorganic materials 0.000 claims description 8
- 239000006260 foam Substances 0.000 claims description 7
- 229910052758 niobium Inorganic materials 0.000 claims description 7
- 229910052715 tantalum Inorganic materials 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 6
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 6
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 6
- 238000005520 cutting process Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 abstract description 3
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 2
- 229910052717 sulfur Inorganic materials 0.000 abstract description 2
- 229910001566 austenite Inorganic materials 0.000 description 16
- 229910000859 α-Fe Inorganic materials 0.000 description 8
- 230000007797 corrosion Effects 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 6
- 229910000734 martensite Inorganic materials 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000005204 segregation Methods 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- 230000001960 triggered effect Effects 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- 101100218329 Caenorhabditis elegans atz-1 gene Proteins 0.000 description 1
- 241000221535 Pucciniales Species 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- -1 for example Inorganic materials 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000011513 prestressed concrete Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 230000003019 stabilising effect Effects 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/005—Modifying the physical properties by deformation combined with, or followed by, heat treatment of ferrous alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
Definitions
- the innovation relates to an austenitic stainless cast steel part, and a method for the production and use thereof.
- Austenitic stainless cast steel alloys are not alloyed with aluminium, and usually contain silicon levels of about 1%. Aluminium and high levels of silicon impair the purity of the cast steel part if contact between the molten steel and oxygen is not suppressed during the metallurgical production process. For this reason, the aluminium and silicon content in austenitic stainless cast steel alloys is minimised or restricted.
- Typical commercial austenitic stainless cast steel parts usually have ⁇ -ferrite levels of 5 to 10%.
- the ⁇ -ferrite level fractions lead to an increase in yield strength at 0.2% offset and in tensile strength and a decrease in elongation at break compared with the purely austenitic microstructure state.
- a balanced nickel and chromium equivalent is adjusted via the chemical composition of the cast steel.
- the low 6-ferrite content changes the solidification structure. Undesirable liquation products, which accumulate at the grain boundaries, are reduced, a fact which positively affects the susceptibility to hot cracking.
- the chromium content of austenitic stainless cast steel is around 19%. Moreover, it is often alloyed with 2 to 3% molybdenum. The chromium and molybdenum content creates a passivating protective layer that increases the resistance to corrosion, especially by halides. It also supports ferrite formation.
- the nickel content of rustproof austenitic cast steel is about 10% and the carbon content is about 0.03% [1-3, 6].
- patent application [7] discloses a stainless cast steel that has a high corrosion fatigue strength and high pitting corrosion resistance.
- the TRIP effect (transformation induced plasticity) has yet to be studied in austenitic cast steel alloys. Nor have technical applications materialized that exploit the TRIP effect in austenitic cast steel. The reason for this is apparently the fact that austenitic cast steel parts are not cold formed and the manufactured parts are used in the cast state. Thus, it is not technically possible to use the TRIP effect in cast alloy parts, as opposed to wrought alloy parts, to improve cold formability. As yet, there are no references in the literature to the occurrence of a TRIP effect in austenitic cast steel alloy parts. This is due primarily to the fact that the TRIP effect in the form of a plastic yield contribution has not yet been quantified.
- High-manganese austenitic steels usually have a chromium content of less than 12%, which is why they are non-rusting. In these steels, iron oxide layers are formed on the surface and the material rusts. If aluminium and silicon oxides are occluded in these rust layers, the corrosion resistance grows.
- Patent DE 199 00 199 describes such a high-strength lightweight construction steel that contains manganese. The concentrations of the alloying elements aluminium, silicon, nickel, manganese and nitrogen are similar to the concentrations of the inventive cast steel. Unlike the inventive steel, this steel has a chromium content of less than 10% and is therefore not a stainless steel. Moreover, this steel is not used in the cast state, but rather is worked to produce vehicle bodies and semifinished prestressed concrete goods.
- Warm- or cold-rolled semifinished goods serve as starting material for cold-formed parts.
- the TRIP effect in austenitic alloys is regulated via the chemical composition of the austenite and the forming conditions [5].
- Ni equiv. % Ni+30% C+18% N+0.5% Mn+0.3% Co+0.2% Cu ⁇ 0.2% Al (2)
- inventive austenitic cast steel alloy parts are to be found in the increase in tensile strength and elongation at break. That means that the TRIP effect renders the cast steel part stronger and tougher simultaneously. It can therefore accommodate greater forces and deform more extensively, without breaking. As a result, the application range of the inventive TRIP cast steel alloy parts is expanded. Above all, the resultant lightweight construction leads to savings on costs for energy and material.
- the inventive cast steel yields tensile strength greater than 550 MPa and elongation at break of more than 30%. Consequently, the cast steel can be used to make cast parts with a kind of crash reserve. This means that the steel is cast and integrated into an application, without exposure to a tensile load. If, however, a crash or a heavy load occurs, the part, thanks to the potential to exhibit the TRIP effect, can accommodate/absorb high tensile strength and elongation at break.
- the TRIP effect can be influenced via the chemical composition of the austenite. Moreover, it requires that the austenite- and ferrite-stabilising elements be coordinated.
- the microstructure of austenitic cast steel and the microstructure of formed austenitic wrought alloys of the same chemical composition differ, however.
- the microstructure of austenitic cast steel parts contains solidification-induced liquation, the vast bulk of which is retained during technical cooling.
- dendritic solidification influences the defect structure of the austenite.
- austenite and ferrite are simultaneously present in a stainless cast steel, internal stresses are formed during cooling.
- separation of the alloying elements occurs. When this happens, the austenite-stabilising elements accumulate chiefly in the austenite. At the same time, the austenite becomes depleted in ferrite-stabilising elements. The influence of these factors on the TRIP effect in cast steel alloy parts is not yet known.
- the microstructure of the inventive cast material must consist of metastable austenite. Consequently, austenite has a corresponding tendency to form deformation-induced martensite at room temperature and at low temperatures.
- a corresponding chromium and nickel equivalent is adjusted in the austenitic cast steel.
- the chemical composition of the steels must be coordinated with regard to the ferrite-stabilising and austenite-stabilising elements, as specified in the patent claim.
- the chromium and nickel equivalent to be adjusted for producing an austenitic cast steel part which has a TRIP effect differs from the chromium and nickel equivalent for austenitic wrought alloys which have a TRIP effect.
- Nickel and/or manganese are added to cast austenitic steel in order that austenite may be formed at high temperatures.
- Manganese serves in this regard as an inexpensive substitute for nickel. This is usually accompanied by a deterioration in corrosion resistance. Adding nitrogen can compensate this negative effect in certain circumstances. The nitrogen improves the strength and corrosion properties [8] and simultaneously effects austenite stabilisation.
- the chromium content of the inventive cast steel ranges from 12 to 20%, but is never less than 10%. Steel with a chromium content higher than 12% acts as guarantor for passivation of the material.
- chromium is added to stabilise ferrite. It simultaneously influences the austenite stability as well because it hampers martensite formation as the chromium content rises.
- the contents of the elements for stabilising austenite and ferrite have to be coordinated with each other.
- the elements aluminium and silicon are used first to adjust the necessary chromium or nickel equivalent.
- the influence which the aluminium and silicon dissolved in the austenite exert on the corresponding equivalents is thereby described with the aid of effective factors.
- the TRIP effect can be adjusted selectively via the solution or segregation state of nitrides, such as AlN.
- both grain refinement and consolidation of the austenite are achieved.
- the profile of a cast steel part as regards its strength and toughness properties are additionally improved by highly disperse AlN segregations in the fine-grained austenite.
- the ready availability of the elements silicon and aluminium means that more costly steel alloying elements in steel, such as nickel and chromium, can be replaced.
- the inventive austenitic stainless cast steel part has a manganese content of 0 to 25%, a chromium content of 12 to 20%, but never less than 10%, a nickel content of 0 to 12%, a niobium content of 0 to 1.2%, a tantalum content of 0 to 1.2%, a carbon content of 0.01 to 0.15%, a nitrogen content of 0.005 to 0.5%, a copper content of 0 to 4%, a cobalt content of 0 to 1%, a molybdenum content of 0 to 4%, a tungsten content of 0 to 3%, a titanium content of 0 to 1% and a vanadium content of 0 to 0.15%.
- the mechanical properties improve.
- the tensile strength increases to more than 550 MPa and the elongation at break to more than 30%.
- cast steel material is particularly tough despite the increased strength values.
- the inventive cast steel part has a high energy absorption capacity at room temperature and low temperatures.
- the energy absorption capacity for these alloy parts is approximately between 0.30 and 0.40 J/mm 3 at room temperature. This means that in the event of a sudden stress, such as a crash, the cast steel part consolidates and simultaneously deforms, without breaking. Therefore, the cast steel part is particularly suitable for crash-stressed parts used in automotive construction.
- the manganese content is 0 to 25%
- the chromium content is 12 to 20%
- the nickel content is 0 to 12%
- the niobium content is 0 to 1.2%
- the tantalum content is 0 to 0.2%
- the carbon content is 0.01 to 0.15%
- the nitrogen content is 0.005 to 0.5%
- the copper content is 0 to 4%
- the cobalt content is 0 to 1%
- the molybdenum content is 0 to 4%
- the tungsten content is 0 to 3%
- the titanium content is 0 to 1%
- the vanadium content is 0 to 0.15%.
- the inventive austenitic stainless cast steel part has a chromium content of 16.5%, a nickel content of 6.5%, a silicon content of 1.1%, a manganese content of 7% and an aluminium content of 0.05%.
- the carbon content is 0.04% and the nitrogen content is 0.1%.
- the cast steel part can undergo heat treatment in a further step.
- the alloy used in the method has, especially, a manganese content of 0 to 25%, a chromium content of 12 to 20%, a nickel content of 0 to 12%, a niobium content of 0 to 1.2%, a tantalum content of 0 to 0.2%, a carbon content of 0.01 to 0.15%, a nitrogen content of 0.005 to 0.5%, a copper content of 0 to 4%, a cobalt content of 0 to 1%, a molybdenum content of to 4%, a tungsten content of 0 to 3%, a titanium content of 0 to 1%, and a vanadium content of 0 to 0.15%.
- the alloy employed in the method has a manganese content of 5 to 12%, a nickel content of 2 to 8%, a copper content of 0 to 2%, a cobalt content of 0 to 0.5%, a molybdenum content of 0 to 2.5%, and/or a tungsten content of 0 to 0.5%.
- the object is also achieved by a cast steel part (steel casting or steel casting part), produced by a method as previously described, characterised in that the cast steel part has a tensile strength greater than 550 MPa and an elongation at break of more than 30%.
- the cast steel part exhibits a TRIP effect under load.
- An inventive method for using a cast steel part in a technical application comprises the steps: performing the steps of one of the methods described above for the production of the cast steel part; and use of the cast steel part in a technical application, wherein use after casting proceeds without the performance of a chipless forming process.
- chipless or non-cutting forming processes are all forming processes which, due to mechanical action, would trigger the TRIP process in the cast steel part.
- These forming processes, such as rolling, forging, pressing, etc. are not performed, with result that the cast steel part, after being integrated in the application, still has the potential to exhibit the TRIP effect and thus, in the event of a stress situation, has a reserve with regard to tensile strength and elongation at break. It should, however, be possible to perform cutting processes on the cast steel part which do not trigger the TRIP effect, without departing from the framework of the invention.
- the cast steel part is used as casting material for plant and refrigeration technology, for equipment and components for the production of gases and for liquefying and fractionating gases, for use in automotive and aircraft construction, for crash-stressed parts, such as crash boxes in motor vehicles, for components for transporting liquid gases and as a component which is exposed to low temperatures, and/or as casting steel foam.
- An inventive component for automotive or aircraft construction especially, crash box, A, B or C pillar of a motor vehicle, is formed as a cast steel part as described above.
- the austenitic cast steel part has an austenitic microstructure at room temperature with a 5% ⁇ -ferrite content. On account of the TRIP effect triggered in the tensile test, tensile strength greater than 550 MPa and elongation at break greater than 30% are obtained. At temperatures below room temperature, the cast steel material is tough despite increased strength values.
- the inventive cast steel has an energy absorption capacity at room temperature of approximately 0.37 J/mm 3 .
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
- Heat Treatment Of Articles (AREA)
Abstract
A rustproof austenitic cast steel part having tensile strength greater than 550 MPA and elongation at break over 30%, is characterised in that the cast steel having an aluminium content of 0 to 4% and a silicon content of 1 to 4% is within an alloying range that is determined by the coordinates of four points (Crequiv.=14; Niequiv.=8), (Crequiv.=14; Niequiv.=14), (Crequiv.=22; Niequiv.=8) and (Crequiv.=22 Niequiv.=16), wherein the chromium and nickel equivalents are calculated from the chemical composition of a cast steel using the relations (1) and (2):
wherein the figures must be quoted in mass percent and the remainder substantially comprises iron and other elements usually present in cast steel (O, P, S). Said cast steel exhibits a TRIP effect and serves as a material for plant and refrigeration engineering, particularly for facilities and components for obtaining gases and for liquefying and fractioning of gases, and as a material in the construction of special vehicles and airplanes for the transport of liquid gases and for components exposed to low temperatures, in addition to crash stressed castings.
Description
- The innovation relates to an austenitic stainless cast steel part, and a method for the production and use thereof.
- After solution annealing, commercial austenitic stainless cast steel alloys have a tensile strength of 440 to 640 MPa and elongation at break of more than 20% in the cast [1, 2].
- Austenitic stainless cast steel alloys are not alloyed with aluminium, and usually contain silicon levels of about 1%. Aluminium and high levels of silicon impair the purity of the cast steel part if contact between the molten steel and oxygen is not suppressed during the metallurgical production process. For this reason, the aluminium and silicon content in austenitic stainless cast steel alloys is minimised or restricted.
- Typical commercial austenitic stainless cast steel parts usually have δ-ferrite levels of 5 to 10%. The δ-ferrite level fractions lead to an increase in yield strength at 0.2% offset and in tensile strength and a decrease in elongation at break compared with the purely austenitic microstructure state. To form austenitic-ferritic microstructure states, a balanced nickel and chromium equivalent is adjusted via the chemical composition of the cast steel. The low 6-ferrite content changes the solidification structure. Undesirable liquation products, which accumulate at the grain boundaries, are reduced, a fact which positively affects the susceptibility to hot cracking.
- In general, the chromium content of austenitic stainless cast steel is around 19%. Moreover, it is often alloyed with 2 to 3% molybdenum. The chromium and molybdenum content creates a passivating protective layer that increases the resistance to corrosion, especially by halides. It also supports ferrite formation. The nickel content of rustproof austenitic cast steel is about 10% and the carbon content is about 0.03% [1-3, 6]. Through changes to the chemical composition, it is possible to produce cast steel alloys that have special properties. Thus, patent application [7] discloses a stainless cast steel that has a high corrosion fatigue strength and high pitting corrosion resistance.
- Unlike the case for austenitic steels, the TRIP effect (transformation induced plasticity) has yet to be studied in austenitic cast steel alloys. Nor have technical applications materialized that exploit the TRIP effect in austenitic cast steel. The reason for this is apparently the fact that austenitic cast steel parts are not cold formed and the manufactured parts are used in the cast state. Thus, it is not technically possible to use the TRIP effect in cast alloy parts, as opposed to wrought alloy parts, to improve cold formability. As yet, there are no references in the literature to the occurrence of a TRIP effect in austenitic cast steel alloy parts. This is due primarily to the fact that the TRIP effect in the form of a plastic yield contribution has not yet been quantified.
- So far, lightweight austenitic steels that have a TRIP effect at room temperature and can be alloyed inter alia with aluminium and silicon are used in wrought alloys in various branches of industry.
- These are both austenitic stainless and non-passivating steels, such as the high-manganese, austenitic lightweight construction steels. Thanks to the TRIP effect, these steels are notable for their high cold formability [4, 5].
- High-manganese austenitic steels usually have a chromium content of less than 12%, which is why they are non-rusting. In these steels, iron oxide layers are formed on the surface and the material rusts. If aluminium and silicon oxides are occluded in these rust layers, the corrosion resistance grows. Patent DE 199 00 199 describes such a high-strength lightweight construction steel that contains manganese. The concentrations of the alloying elements aluminium, silicon, nickel, manganese and nitrogen are similar to the concentrations of the inventive cast steel. Unlike the inventive steel, this steel has a chromium content of less than 10% and is therefore not a stainless steel. Moreover, this steel is not used in the cast state, but rather is worked to produce vehicle bodies and semifinished prestressed concrete goods.
- Warm- or cold-rolled semifinished goods serve as starting material for cold-formed parts. The TRIP effect in austenitic alloys is regulated via the chemical composition of the austenite and the forming conditions [5].
- The disadvantage of the prior art remains the non-exploitation of the TRIP effect, which is known from austenitic wrought alloys, to improve the properties of cast steel.
-
- [1] DIN EN 10213
- [2] DIN EN 10283
- [3] Konstruieren und Giessen 29 (2004)1, p. 27-55
- [4] Bander, Bleche Rohre 5/2006, p. 30-31
- [5] ATZ 1/2005, volume 107, p. 68-72
- [6] SEW 410
- [7] Patent DE 33 06 104 A1
- [8] High Nitrogen Steels, Springer-Verlag Berlin Heidelberg 1999
- It is an object of the invention cited in the main claims to produce austenitic stainless cast steel parts having a tensile strength greater than 550 MPa and an elongation at break of more than 30% and of using it in technical applications.
- This object is achieved in the invention in such a way that an austenitic stainless cast steel part (steel casting or steel casting part) having an aluminium content greater than 0 and equal or less than 4% and a silicon content of 0 to 4%, especially 1 to 4%, and tensile strength greater than 550 MPa and elongation at break exceeding 30% is produced in an alloying range, which is determined by the coordinates of four points (Crequiv.=14; Niequiv.=8), (Crequiv.=14; Niequiv.=14), (Crequiv.=22; Niequiv.=8) and (Crequiv.=22 Niequiv.=16), wherein the chromium and nickel equivalents are calculated from the chemical composition of the cast steel via the relations (1) and (2)
-
Crequiv.=% Cr+% Mo+1.5% Si+0.5% W+0.9% Nb+4% Al+4% Ti+1.5% V+0.9% Ta (1) -
Niequiv.=% Ni+30% C+18% N+0.5% Mn+0.3% Co+0.2% Cu−0.2% Al (2) - where the figures must be quoted in mass percent and the rest essentially consists of iron and other inevitable elements of cast steel, for example, O, P, S, and that this cast steel exhibits a TRIP effect under load.
- Surprisingly, it was found that, in those inventive austenitic cast steel alloy parts which contain aluminium and are alloyed with silicon, deformation-induced martensite formation is triggered at room temperature and low temperatures in the tensile test. This martensite formation causes the TRIP effect. As a result of the TRIP effect, the tensile strength and the elongation at break are increased and necking is improved.
- The advantages of the inventive austenitic cast steel alloy parts are to be found in the increase in tensile strength and elongation at break. That means that the TRIP effect renders the cast steel part stronger and tougher simultaneously. It can therefore accommodate greater forces and deform more extensively, without breaking. As a result, the application range of the inventive TRIP cast steel alloy parts is expanded. Above all, the resultant lightweight construction leads to savings on costs for energy and material. The inventive cast steel yields tensile strength greater than 550 MPa and elongation at break of more than 30%. Consequently, the cast steel can be used to make cast parts with a kind of crash reserve. This means that the steel is cast and integrated into an application, without exposure to a tensile load. If, however, a crash or a heavy load occurs, the part, thanks to the potential to exhibit the TRIP effect, can accommodate/absorb high tensile strength and elongation at break.
- In the case of austenitic cast steel alloy parts, the TRIP effect can be influenced via the chemical composition of the austenite. Moreover, it requires that the austenite- and ferrite-stabilising elements be coordinated. The microstructure of austenitic cast steel and the microstructure of formed austenitic wrought alloys of the same chemical composition differ, however. For one thing, the microstructure of austenitic cast steel parts contains solidification-induced liquation, the vast bulk of which is retained during technical cooling. For another, dendritic solidification influences the defect structure of the austenite. When austenite and ferrite are simultaneously present in a stainless cast steel, internal stresses are formed during cooling. Moreover, in the high-temperature range, separation of the alloying elements occurs. When this happens, the austenite-stabilising elements accumulate chiefly in the austenite. At the same time, the austenite becomes depleted in ferrite-stabilising elements. The influence of these factors on the TRIP effect in cast steel alloy parts is not yet known.
- In order for deformation-induced martensite and thus a TRIP effect to form, the microstructure of the inventive cast material must consist of metastable austenite. Consequently, austenite has a corresponding tendency to form deformation-induced martensite at room temperature and at low temperatures. For the purpose of producing such austenite, a corresponding chromium and nickel equivalent is adjusted in the austenitic cast steel. In other words, the chemical composition of the steels must be coordinated with regard to the ferrite-stabilising and austenite-stabilising elements, as specified in the patent claim. The chromium and nickel equivalent to be adjusted for producing an austenitic cast steel part which has a TRIP effect differs from the chromium and nickel equivalent for austenitic wrought alloys which have a TRIP effect.
- Nickel and/or manganese are added to cast austenitic steel in order that austenite may be formed at high temperatures. Manganese serves in this regard as an inexpensive substitute for nickel. This is usually accompanied by a deterioration in corrosion resistance. Adding nitrogen can compensate this negative effect in certain circumstances. The nitrogen improves the strength and corrosion properties [8] and simultaneously effects austenite stabilisation. The chromium content of the inventive cast steel ranges from 12 to 20%, but is never less than 10%. Steel with a chromium content higher than 12% acts as guarantor for passivation of the material. In addition, chromium is added to stabilise ferrite. It simultaneously influences the austenite stability as well because it hampers martensite formation as the chromium content rises. To obtain a TRIP effect at room temperature in the inventive materials, the contents of the elements for stabilising austenite and ferrite have to be coordinated with each other. In the inventive cast steel, the elements aluminium and silicon are used first to adjust the necessary chromium or nickel equivalent. The influence which the aluminium and silicon dissolved in the austenite exert on the corresponding equivalents is thereby described with the aid of effective factors. Moreover, via different levels of aluminium and silicon, the TRIP effect can be adjusted selectively via the solution or segregation state of nitrides, such as AlN. Moreover, as a result of the segregation state, both grain refinement and consolidation of the austenite are achieved. The profile of a cast steel part as regards its strength and toughness properties are additionally improved by highly disperse AlN segregations in the fine-grained austenite. The ready availability of the elements silicon and aluminium means that more costly steel alloying elements in steel, such as nickel and chromium, can be replaced.
- Preferably, the inventive austenitic stainless cast steel part has a manganese content of 0 to 25%, a chromium content of 12 to 20%, but never less than 10%, a nickel content of 0 to 12%, a niobium content of 0 to 1.2%, a tantalum content of 0 to 1.2%, a carbon content of 0.01 to 0.15%, a nitrogen content of 0.005 to 0.5%, a copper content of 0 to 4%, a cobalt content of 0 to 1%, a molybdenum content of 0 to 4%, a tungsten content of 0 to 3%, a titanium content of 0 to 1% and a vanadium content of 0 to 0.15%. Due to the TRIP effect, which is triggered by tensile loading in the inventive cast steel part at room temperature and low temperatures, the mechanical properties improve. Thus, the tensile strength increases to more than 550 MPa and the elongation at break to more than 30%. At room temperature and low temperatures, cast steel material is particularly tough despite the increased strength values. Moreover, the inventive cast steel part has a high energy absorption capacity at room temperature and low temperatures. The energy absorption capacity for these alloy parts is approximately between 0.30 and 0.40 J/mm3 at room temperature. This means that in the event of a sudden stress, such as a crash, the cast steel part consolidates and simultaneously deforms, without breaking. Therefore, the cast steel part is particularly suitable for crash-stressed parts used in automotive construction.
- Preferably, in the inventive cast steel part, the manganese content is 0 to 25%, the chromium content is 12 to 20%, the nickel content is 0 to 12%, the niobium content is 0 to 1.2%, the tantalum content is 0 to 0.2%, the carbon content is 0.01 to 0.15%, the nitrogen content is 0.005 to 0.5%, the copper content is 0 to 4%, the cobalt content is 0 to 1%, the molybdenum content is 0 to 4%, the tungsten content is 0 to 3%, the titanium content is 0 to 1%, and the vanadium content is 0 to 0.15%.
- Preferably, the inventive austenitic stainless cast steel part has a chromium content of 16.5%, a nickel content of 6.5%, a silicon content of 1.1%, a manganese content of 7% and an aluminium content of 0.05%. The carbon content is 0.04% and the nitrogen content is 0.1%.
- The inventive method for producing a cast steel part (steel casting or steel casting part) comprises the following steps: Provision of an alloy comprising an aluminium content of 0 to 4% and a silicon content of 0 to 4%, with the alloy produced in an alloying range determined by the coordinates of four points (Crequiv.=14; Niequiv.=8), (Crequiv.=14; Niequiv.=14), (Crequiv.=22; Niequiv.=8) and (Crequiv.=22 Niequiv.=16), with the chromium and nickel equivalent being calculated via relation (1) and (2)
-
- from the chemical composition of the cast steel, wherein the figures must be quoted in mass percent and the rest essentially consists of iron and other inevitable elements of cast steel; and the casting steel part is cast in a casting mould.
- Preferably, the cast steel part can undergo heat treatment in a further step.
- The alloy used in the method has, especially, a manganese content of 0 to 25%, a chromium content of 12 to 20%, a nickel content of 0 to 12%, a niobium content of 0 to 1.2%, a tantalum content of 0 to 0.2%, a carbon content of 0.01 to 0.15%, a nitrogen content of 0.005 to 0.5%, a copper content of 0 to 4%, a cobalt content of 0 to 1%, a molybdenum content of to 4%, a tungsten content of 0 to 3%, a titanium content of 0 to 1%, and a vanadium content of 0 to 0.15%.
- Especially, the alloy employed in the method has a manganese content of 5 to 12%, a nickel content of 2 to 8%, a copper content of 0 to 2%, a cobalt content of 0 to 0.5%, a molybdenum content of 0 to 2.5%, and/or a tungsten content of 0 to 0.5%.
- The object is also achieved by a cast steel part (steel casting or steel casting part), produced by a method as previously described, characterised in that the cast steel part has a tensile strength greater than 550 MPa and an elongation at break of more than 30%.
- Especially, the cast steel part exhibits a TRIP effect under load.
- An inventive method for using a cast steel part in a technical application comprises the steps: performing the steps of one of the methods described above for the production of the cast steel part; and use of the cast steel part in a technical application, wherein use after casting proceeds without the performance of a chipless forming process. In the context of this invention, chipless or non-cutting forming processes are all forming processes which, due to mechanical action, would trigger the TRIP process in the cast steel part. These forming processes, such as rolling, forging, pressing, etc. are not performed, with result that the cast steel part, after being integrated in the application, still has the potential to exhibit the TRIP effect and thus, in the event of a stress situation, has a reserve with regard to tensile strength and elongation at break. It should, however, be possible to perform cutting processes on the cast steel part which do not trigger the TRIP effect, without departing from the framework of the invention.
- Especially, the cast steel part is used as casting material for plant and refrigeration technology, for equipment and components for the production of gases and for liquefying and fractionating gases, for use in automotive and aircraft construction, for crash-stressed parts, such as crash boxes in motor vehicles, for components for transporting liquid gases and as a component which is exposed to low temperatures, and/or as casting steel foam.
- An inventive component for automotive or aircraft construction, especially, crash box, A, B or C pillar of a motor vehicle, is formed as a cast steel part as described above.
- The austenitic cast steel part has an austenitic microstructure at room temperature with a 5% δ-ferrite content. On account of the TRIP effect triggered in the tensile test, tensile strength greater than 550 MPa and elongation at break greater than 30% are obtained. At temperatures below room temperature, the cast steel material is tough despite increased strength values. The inventive cast steel has an energy absorption capacity at room temperature of approximately 0.37 J/mm3.
Claims (63)
1. An austenitic stainless cast steel part having an aluminium content of greater than 0% and equal or smaller than 4% and a silicon content of 0 to 4%, and tensile strength greater than 550 MPa and elongation at break greater than 30% produced in an alloying range determined by the coordinates of four points (Crequiv.=14; Niequiv.=8), (Crequiv.=14; Niequiv.=14), (Crequiv.=22; Niequiv.=8) and (Crequiv.=22 Niequiv.=16), wherein the chromium and nickel equivalent are calculated via relation (1) and (2)
from the chemical composition of the cast steel part, where the figures must be quoted in mass percent and the rest essentially consists of iron and other inevitable elements of cast steel part and that this cast steel part exhibits a TRIP effect under load.
2. The cast steel part in accordance with claim 1 , characterised by the fact that
the manganese content is 0 to 25%;
the chromium content is 12 to 20%;
the nickel content is 0 to 12%;
the niobium content is 0 to 1.2%;
the tantalum content is 0 to 0.2%;
the carbon content is 0.01 to 0.15%;
the nitrogen content is 0.005 to 0.5%;
the copper content is 0 to 4%;
the cobalt content is 0 to 1%;
the molybdenum content is 0 to 4%;
the tungsten content is 0 to 3%;
the titanium content is 0 to 1%; and
the vanadium content is 0 to 0.15%.
3. The cast steel part in accordance with claim 2 , characterised by the fact that
the manganese content is 5 to 12%;
the nickel content is 2 to 8%;
the copper content is 0 to 2%;
the cobalt content is 0 to 0.5%;
the molybdenum content is 0 to 2.5%; and/or
the vanadium content is 0 to 0.5%.
4. The cast steel part in accordance with claim 3 , characterised by the fact that
the chromium content is 16.5%;
the nickel content is 6.5%;
the silicon content is 1.1%;
the manganese content is 7%;
the aluminium content is 0.05%;
the nitrogen content is 0.1%; and
the carbon content is 0.04%.
5. A method for producing a cast steel part comprising the following steps: Provision of an alloy comprising an aluminium content of 0 to 4% and a silicon content of 0 to 4%, with the alloy produced in an alloying range determined by the coordinates of four points (Crequiv.=14; Niequiv.=8), (Crequiv.=14; Niequiv.=14), (Crequiv.=22; Niequiv.=8) and (Crequiv.=22; Niequiv.=16), with the chromium and nickel equivalent being calculated via relation (1) and (2)
from the chemical composition of the cast steel part, wherein the figures must be quoted in mass percent and the rest essentially consists of iron and other inevitable elements of cast steel; and
the casting steel part is cast in a casting mould.
6. The method in accordance with claim 5 , characterised by the fact that the cast steel part undergoes a heat treatment process in a further step.
7. The method in accordance with claim 5 , characterised by the fact that the alloy has
a manganese content of 0 to 25%;
a chromium content of 12 to 20%;
a nickel content of 0 to 12%;
a niobium content of 0 to 1.2%;
a tantalum content of 0 to 0.2%;
a carbon content is 0.01 to 0.15%;
a nitrogen content of 0.005 to 0.5%;
a copper content of 0 to 4%;
a cobalt content of 0 to 1%;
a molybdenum content of 0 to 4%;
a tungsten content of 0 to 3%;
a titanium content of 0 to 1%; and
a vanadium content of 0 to 0.15%.
8. The method in accordance with claim 7 , characterised by the fact that the alloy has
a manganese content of 5 to 12%;
a nickel content of 2 to 8%;
a copper content of 0 to 2%;
a cobalt content of 0 to 0.5%;
a molybdenum content of 0 to 2.5%; and/or
a tungsten content of 0 to 0.5%.
9. A cast steel part, produced by a method in accordance with claim 5 , characterised by the fact that the cast steel part has a tensile strength greater than 550 MPa and an elongation at break greater than 30%.
10. A cast steel part, produced by a method in accordance with claim 5 , characterised by the fact that the cast steel part exhibits a TRIP effect under load.
11. A method for using a cast steel part in a technical application, comprising the steps:
Performance of the steps of one of the methods in accordance with claim 5 for the manufacture of the cast steel part; and
use of the cast steel part in the technical application, wherein use after casting proceeds without the performance of a chipless cutting process.
12. Use of the cast steel part in accordance with claim 1 as material for plant and refrigeration engineering.
13. Use of the cast steel part in accordance with claim 1 as material for plant and components for producing gases and for liquefying and fractionating gases.
14. Use of the cast steel part in accordance with claim 1 as material for applications in automotive and aircraft construction.
15. Use of the cast steel part in accordance with claim 1 as material for crash-stressed parts, such as crash boxes in motor vehicles.
16. Use of the cast steel part in accordance with claim 1 as material for transporting liquid gases and as a component that is exposed to low temperatures.
17. Use of the cast steel part in accordance with claim 1 as casting steel foam for foamed parts.
18. Component for automotive or aircraft construction, especially, crash box, A, B or C-pillar of a motor vehicle, which is formed as a cast steel part in accordance with claim 1 .
19. The method in accordance with claim 6 , characterised by the fact that the alloy has
a manganese content of 0 to 25%;
a chromium content of 12 to 20%;
a nickel content of 0 to 12%;
a niobium content of 0 to 1.2%;
a tantalum content of 0 to 0.2%;
a carbon content is 0.01 to 0.15%;
a nitrogen content of 0.005 to 0.5%;
a copper content of 0 to 4%;
a cobalt content of 0 to 1%;
a molybdenum content of 0 to 4%;
a tungsten content of 0 to 3%;
a titanium content of 0 to 1%; and
a vanadium content of 0 to 0.15%.
20. The method in accordance with claim 19 , characterised by the fact that the alloy has
a manganese content of 5 to 12%;
a nickel content of 2 to 8%;
a copper content of 0 to 2%;
a cobalt content of 0 to 0.5%;
a molybdenum content of 0 to 2.5%; and/or
a tungsten content of 0 to 0.5%.
21. A cast steel part, produced by a method in accordance with claim 7 , characterised by the fact that the cast steel part has a tensile strength greater than 550 MPa and an elongation at break greater than 30%.
22. A cast steel part, produced by a method in accordance with claim 19 , characterised by the fact that the cast steel part has a tensile strength greater than 550 MPa and an elongation at break greater than 30%.
23. A cast steel part, produced by a method in accordance with claim 8 , characterised by the fact that the cast steel part has a tensile strength greater than 550 MPa and an elongation at break greater than 30%.
24. A cast steel part, produced by a method in accordance with claim 20 , characterised by the fact that the cast steel part has a tensile strength greater than 550 MPa and an elongation at break greater than 30%.
25. A cast steel part, produced by a method in accordance with claim 7 , characterised by the fact that the cast steel part exhibits a TRIP effect under load.
26. A cast steel part, produced by a method in accordance with claim 19 , characterised by the fact that the cast steel part exhibits a TRIP effect under load.
27. A cast steel part, produced by a method in accordance with claim 8 , characterised by the fact that the cast steel part exhibits a TRIP effect under load.
28. A cast steel part, produced by a method in accordance with claim 20 , characterised by the fact that the cast steel part exhibits a TRIP effect under load.
29. Use of the cast steel part in accordance with claim 2 as material for plant and refrigeration engineering.
30. Use of the cast steel part in accordance with claim 2 as material for plant and components for producing gases and for liquefying and fractionating gases.
31. Use of the cast steel part in accordance with claim 2 as material for applications in automotive and aircraft construction.
32. Use of the cast steel part in accordance with claim 2 as material for crash-stressed parts, such as crash boxes in motor vehicles.
33. Use of the cast steel part in accordance with claim 2 as material for transporting liquid gases and as a component that is exposed to low temperatures.
34. Use of the cast steel part in accordance with claim 2 as casting steel foam for foamed parts.
35. Component for automotive or aircraft construction, especially, crash box, A, B or C-pillar of a motor vehicle, which is formed as a cast steel part in accordance with claim 2 .
36. Use of the cast steel part in accordance with claim 3 as material for plant and refrigeration engineering.
37. Use of the cast steel part in accordance with claim 3 as material for plant and components for producing gases and for liquefying and fractionating gases.
38. Use of the cast steel part in accordance with claim 3 as material for applications in automotive and aircraft construction.
39. Use of the cast steel part in accordance with claim 3 as material for crash-stressed parts, such as crash boxes in motor vehicles.
40. Use of the cast steel part in accordance with claim 3 as material for transporting liquid gases and as a component that is exposed to low temperatures.
41. Use of the cast steel part in accordance with claim 3 as casting steel foam for foamed parts.
42. Component for automotive or aircraft construction, especially, crash box, A, B or C-pillar of a motor vehicle, which is formed as a cast steel part in accordance with claim 3 .
43. Use of the cast steel part in accordance with claim 4 as material for plant and refrigeration engineering.
44. Use of the cast steel part in accordance with claim 4 as material for plant and components for producing gases and for liquefying and fractionating gases.
45. Use of the cast steel part in accordance with claim 4 as material for applications in automotive and aircraft construction.
46. Use of the cast steel part in accordance with claim 4 as material for crash-stressed parts, such as crash boxes in motor vehicles.
47. Use of the cast steel part in accordance with claim 4 as material for transporting liquid gases and as a component that is exposed to low temperatures.
48. Use of the cast steel part in accordance with claim 4 as casting steel foam for foamed parts.
49. Component for automotive or aircraft construction, especially, crash box, A, B or C-pillar of a motor vehicle, which is formed as a cast steel part in accordance with claim 4 .
50. Use of the cast steel part in accordance with claim 9 as material for plant and refrigeration engineering.
51. Use of the cast steel part in accordance with claim 9 as material for plant and components for producing gases and for liquefying and fractionating gases.
52. Use of the cast steel part in accordance with claim 9 as material for applications in automotive and aircraft construction.
53. Use of the cast steel part in accordance with claim 9 as material for crash-stressed parts, such as crash boxes in motor vehicles.
54. Use of the cast steel part in accordance with claim 9 as material for transporting liquid gases and as a component that is exposed to low temperatures.
55. Use of the cast steel part in accordance with claim 9 as casting steel foam for foamed parts.
56. Component for automotive or aircraft construction, especially, crash box, A, B or C-pillar of a motor vehicle, which is formed as a cast steel part in accordance with claim 9 .
57. Use of the cast steel part in accordance with claim 10 as material for plant and refrigeration engineering.
58. Use of the cast steel part in accordance with claim 10 as material for plant and components for producing gases and for liquefying and fractionating gases.
59. Use of the cast steel part in accordance with claim 10 as material for applications in automotive and aircraft construction.
60. Use of the cast steel part in accordance with claim 10 as material for crash-stressed parts, such as crash boxes in motor vehicles.
61. Use of the cast steel part in accordance with claim 10 as material for transporting liquid gases and as a component that is exposed to low temperatures.
62. Use of the cast steel part in accordance with claim 10 as casting steel foam for foamed parts.
63. Component for automotive or aircraft construction, especially, crash box, A, B or C-pillar of a motor vehicle, which is formed as a cast steel part in accordance with claim 10 .
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006033973.8 | 2006-07-20 | ||
| DE102006033973A DE102006033973A1 (en) | 2006-07-20 | 2006-07-20 | Stainless austenitic cast steel and its use |
| PCT/EP2007/057473 WO2008009722A1 (en) | 2006-07-20 | 2007-07-19 | Rustproof austenitic cast steel, method for production and use thereof |
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| US20090324441A1 true US20090324441A1 (en) | 2009-12-31 |
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| US12/374,482 Abandoned US20090324441A1 (en) | 2006-07-20 | 2007-07-19 | Austenitic stainless cast steel part, method for production and use thereof |
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| Country | Link |
|---|---|
| US (1) | US20090324441A1 (en) |
| EP (1) | EP2059623A1 (en) |
| JP (1) | JP5340148B2 (en) |
| KR (1) | KR20090035710A (en) |
| CN (1) | CN101490297B (en) |
| CA (1) | CA2657747A1 (en) |
| DE (1) | DE102006033973A1 (en) |
| RU (1) | RU2451763C2 (en) |
| WO (1) | WO2008009722A1 (en) |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3910788A (en) * | 1973-04-21 | 1975-10-07 | Nisshin Steel Co Ltd | Austenitic stainless steel |
| US5376195A (en) * | 1992-04-16 | 1994-12-27 | Nippon Steel Corporation | Austenitic stainless steel sheet having excellent surface quality and method of producing the same |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE420623B (en) * | 1979-12-28 | 1981-10-19 | Fagersta Ab | AUSTENITIC, EXCEPTION CARDABLE STAINLESS CHROME-NICKEL ALUMINUM STEEL |
| JPH04154921A (en) * | 1990-10-16 | 1992-05-27 | Nisshin Steel Co Ltd | Manufacture of high strength stainless steel strip having excellent shape |
| RU2173351C2 (en) * | 1996-12-15 | 2001-09-10 | Санкт-Петербургский государственный университет низкотемпературных и пищевых технологий | Metastable austenitic steel |
| IT1294228B1 (en) * | 1997-08-01 | 1999-03-24 | Acciai Speciali Terni Spa | PROCEDURE FOR THE PRODUCTION OF AUSTENITIC STAINLESS STEEL BELTS, AUSTENITIC STAINLESS STEEL BELTS SO |
| EP1091006B1 (en) * | 1999-10-04 | 2004-12-08 | Hitachi Metals, Ltd. | Process of producing steel strip or sheet comprising strain-induced martensite |
| RU2188874C1 (en) * | 2001-03-01 | 2002-09-10 | Федеральное государственное унитарное предприятие Центральный научно-исследовательский институт конструкционных материалов "Прометей" | High-strength corrosion-resistant welded steel for pipelines |
| JP3696552B2 (en) * | 2001-04-12 | 2005-09-21 | 日新製鋼株式会社 | Soft stainless steel plate with excellent workability and cold forgeability |
| DE102005024029B3 (en) * | 2005-05-23 | 2007-01-04 | Technische Universität Bergakademie Freiberg | Austenitic lightweight steel and its use |
| DE102005030413C5 (en) * | 2005-06-28 | 2009-12-10 | Technische Universität Bergakademie Freiberg | High-strength austenitic-martensitic lightweight steel and its use |
-
2006
- 2006-07-20 DE DE102006033973A patent/DE102006033973A1/en not_active Ceased
-
2007
- 2007-07-19 WO PCT/EP2007/057473 patent/WO2008009722A1/en not_active Ceased
- 2007-07-19 KR KR1020097003429A patent/KR20090035710A/en not_active Withdrawn
- 2007-07-19 JP JP2009519986A patent/JP5340148B2/en not_active Expired - Fee Related
- 2007-07-19 US US12/374,482 patent/US20090324441A1/en not_active Abandoned
- 2007-07-19 CN CN2007800274368A patent/CN101490297B/en not_active Expired - Fee Related
- 2007-07-19 CA CA002657747A patent/CA2657747A1/en not_active Abandoned
- 2007-07-19 EP EP07787731A patent/EP2059623A1/en not_active Ceased
- 2007-07-19 RU RU2009105693/02A patent/RU2451763C2/en not_active IP Right Cessation
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3910788A (en) * | 1973-04-21 | 1975-10-07 | Nisshin Steel Co Ltd | Austenitic stainless steel |
| US5376195A (en) * | 1992-04-16 | 1994-12-27 | Nippon Steel Corporation | Austenitic stainless steel sheet having excellent surface quality and method of producing the same |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20160040262A1 (en) * | 2008-04-11 | 2016-02-11 | Questek Innovations Llc | Surface hardenable stainless steels |
| US10351921B2 (en) | 2008-04-11 | 2019-07-16 | Questek Innovations Llc | Martensitic stainless steel strengthened by copper-nucleated nitride precipitates |
| US10351922B2 (en) * | 2008-04-11 | 2019-07-16 | Questek Innovations Llc | Surface hardenable stainless steels |
| US20110226391A1 (en) * | 2009-07-13 | 2011-09-22 | Korea Institute Of Machinery And Materials | C+n austenitic stainless steel having high strength and excellent corrosion resistance, and fabrication method thereof |
| US9816163B2 (en) | 2012-04-02 | 2017-11-14 | Ak Steel Properties, Inc. | Cost-effective ferritic stainless steel |
| US20160122839A1 (en) * | 2013-05-06 | 2016-05-05 | Salzgitter Flachstahl Gmbh | Method for producing components from lightweight steel |
| US10214790B2 (en) * | 2013-05-06 | 2019-02-26 | Salzgitter Flachstahl Gmbh | Method for producing components from lightweight steel |
| US10337091B2 (en) | 2016-09-09 | 2019-07-02 | Hyundai Motor Company | High heat resistant steel with low nickel |
| CN110205543A (en) * | 2019-05-28 | 2019-09-06 | 共享铸钢有限公司 | A kind of casting method of high intensity austenitic stainless steel steel-casting |
| WO2022101278A1 (en) | 2020-11-13 | 2022-05-19 | Acerinox Europa, S.A.U. | Low ni content austenitic stainless steel with high strength / ductility properties |
| CN116397164A (en) * | 2023-03-27 | 2023-07-07 | 宁波宝新不锈钢有限公司 | Austenitic stainless steel for connecting parts and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101490297A (en) | 2009-07-22 |
| EP2059623A1 (en) | 2009-05-20 |
| WO2008009722A1 (en) | 2008-01-24 |
| CN101490297B (en) | 2012-02-01 |
| DE102006033973A1 (en) | 2008-01-24 |
| KR20090035710A (en) | 2009-04-10 |
| CA2657747A1 (en) | 2008-01-24 |
| RU2009105693A (en) | 2010-08-27 |
| JP2009543952A (en) | 2009-12-10 |
| RU2451763C2 (en) | 2012-05-27 |
| JP5340148B2 (en) | 2013-11-13 |
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