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US20040245095A1 - Eletrochemical half-element - Google Patents

Eletrochemical half-element Download PDF

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Publication number
US20040245095A1
US20040245095A1 US10/493,485 US49348504A US2004245095A1 US 20040245095 A1 US20040245095 A1 US 20040245095A1 US 49348504 A US49348504 A US 49348504A US 2004245095 A1 US2004245095 A1 US 2004245095A1
Authority
US
United States
Prior art keywords
gas
electrochemical half
pocket
longitudinal sides
diffusion electrode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/493,485
Other languages
English (en)
Inventor
Hans-Dieter Pinter
Andreas Bulan
Walter Klesper
Fritz Gestermann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Covestro Deutschland AG
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Assigned to BAYER MATERIALSCIENCE AG reassignment BAYER MATERIALSCIENCE AG ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: BULAN, ANDREAS, GESTERMANN, FRITZ, KLESPER, WALTER, PINTER, HANS-DIETER
Publication of US20040245095A1 publication Critical patent/US20040245095A1/en
Abandoned legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
    • C25B11/031—Porous electrodes
    • C25B11/032—Gas diffusion electrodes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Definitions

  • the invention relates to an electrochemical half-element having a gas diffusion electrode, in particular for the electrolysis of aqueous solutions of alkali metal chloride.
  • gas diffusion electrodes in alkali metal chloride electrolysis advantageously involves pressure compensation between the height-dependent pressure of the sodium hydroxide solution in front of the gas diffusion electrode and the constant pressure of the oxygen behind the gas diffusion electrode, in the form of gas pockets, as shown in EP-A-0 717 130.
  • gas it has proven advantageous for the gas to be routed in such a way that active venting of the gas pockets is ensured, as described in U.S. Pat. No. 6,165,332.
  • connection stubs on the rear side of the gas pocket is highly laborious and difficult.
  • the operation involves attaching the oxygen supply to the rear side, remote from the gas diffusion electrode, of the gas pocket.
  • the presence of projecting connection stubs on the gas pockets which in practice are over two meters long and approx. 30 cm wide, is a nuisance and has in some cases led to mechanical damage.
  • a further drawback is the need, for design reasons, to keep in stock two types of gas pockets, namely gas pockets whose gas inlet opening is arranged on the right-hand side of the gas pocket and whose gas outlet opening is arranged on the left-hand side of the gas pocket, and gas pockets in which, conversely, the gas inlet opening is arranged on the left-hand side and the gas outlet opening is arranged on the right-hand side. Screwing on the gas pockets in the manner described above has also proven laborious and in need of improvement.
  • the present invention relates to an electrochemical half-cell with gas diffusion electrode as cathode or anode with pressure-compensated gas supply via gas pockets, in such a manner that the removable gas pockets, during all removal and installation operations, are designed such that they can be operated from the side of the gas diffusion electrode, and the mechanical and electrical connection of the gas pockets to the frame-like supporting structure or the like of the half-shell, supporting the gas pockets, is preferably likewise effected by means of readily releasable connections.
  • half-shell is to be understood as meaning the space which receives the electrode space for receiving the electrolyte, the gas space, formed from the gas pockets, for receiving gas and the connecting passage which connects two gas pockets to one another in each case, and which allows electrical contact to be made with the gas diffusion electrodes.
  • a frame-like supporting structure or the like is provided in the half-shell for the purpose of attaching the gas pockets.
  • the electrochemical half-cell has a gas-feed connection which is arranged between a gas pocket and a gas-connecting passage which connects two gas pockets to one another, and can be detached from the side of the gas diffusion electrode.
  • a fixed part or a distributor plate with screw head and sealing system it is preferable for a fixed part or a distributor plate with screw head and sealing system to be arranged as an element of the gas-feed connection at the gas-connecting passage, in particular at a front wall of the gas-connecting passage.
  • the fixed part can be releasably connected to a mating piece which is connected to the gas pocket, in particular to the back wall of the gas pocket.
  • the mating piece preferably has gas inlet openings leading into the gas pocket, and the gas diffusion electrode has an aperture which is gastight with respect to the gas pocket. This forms a through-opening which extends from the back wall of the gas pocket to the gas diffusion electrode.
  • the fixed part and the mating piece are designed in such a manner that the connecting elements of one or both parts are accessible from the gas diffusion electrode, i.e. from the front. This, by simple release of the connection, allows the gas pocket to be exchanged and/or removed. It may also be necessary for connecting elements in the boundary region of the gas pocket, which are connected to a support structure or the like of the half-element, to be released for this purpose.
  • One advantage of the half-cell according to the invention is that the gas pockets do not have any connection stubs. Instead, the gas pockets are flat, easy-to-handle units.
  • the gas supply is preferably fitted halfway up one end of the gas pocket.
  • Gas outlet openings are provided at the other end of the gas pocket, both at the bottom and at the top. This has the advantage that only one type of gas pocket has to be constructed, since, depending on whether the gas supply into the gas pocket takes place to the right or to the left, the gas outlet openings at the top are closed off and those at the bottom are opened or fitted. Therefore, the gas outlet from the gas pocket is always at the bottom, irrespective of how the gas pocket is fitted.
  • the gas-connecting passages may in this case be installed in the half-shell as a fixed unit which is independent of the gas pocket.
  • the back wall of the gas pocket prefferably be provided with a dimension which projects on all sides and for this projection to be connected to the support structure, in order for the gas pockets to be installed in the half-cell, i.e. for the gas pockets to be connected to the support structure, which in EP-A-0 946 791 is effected releasably by screw connection or clamping strips.
  • the projections of the gas pockets on the longitudinal sides are preferably used for this purpose, while the projections on the narrow sides are bent up to the level of the sealing surface of the half-shell and are pushed under the seals.
  • the gas pockets can in each case be connected to the support structure of the half-shell using special self-centering screws or using tensile rivets.
  • the projections of adjacent gas pockets in this case overlap one another.
  • the seal with respect to the electrolyte behind the gas pockets which is required in order to avoid bypass flows out of the electrolyte gap through which flow is forced into the back space, can be achieved by an elastic seal and a prestressed metal section, both with mating holes, being introduced. This prestress allows continuous linear electrical contact with the holding structure. Furthermore, the resistive losses can be minimized here by the contact regions being coated with applications of precious metal, e.g. of silver or gold.
  • the gas pocket could also be secured in the half-shell by welding or soldering.
  • a releasable connection which offers the option of installing and removing an individual gas pocket directly on site, i.e. in the chlorine factory, is preferably selected, however.
  • a gas pocket which can be handled individually has the advantage, for example, that it is considerably easier to fit a gas diffusion electrode, for example when the gas diffusion electrode is being changed on account of wear or damage or for quality assurance checking for any incorrect penetration of gas through the gas diffusion electrode.
  • Nickel is preferably selected as the material for constructing the gas pockets and the gas-connecting passage.
  • the gas diffusion electrodes are substantially an electrochemically active coating which contains a catalyst metal and/or a nonmetallic compound of a metal which forms the catalyst, e.g. silver(I) oxide, and a binder, e.g. a polymer, such as polytetrafluoroethylene (PTFE), on an electrically conductive support, for example a metal mesh, nonwoven or woven fabric.
  • the support may be a carbon mesh, a carbon nonwoven or a carbon woven fabric or a corresponding mesh etc. made from other electrically conductive materials.
  • FIG. 1 shows a diagrammatic longitudinal section through a gas pocket according to the invention
  • FIG. 2 shows an excerpt from a diagrammatic cross section through the gas pocket on line A-A′ in FIG. 1,
  • FIG. 3 shows an excerpt from a diagrammatic cross section through a further embodiment of the gas pocket
  • FIG. 5 shows a diagrammatic cross section, corresponding to FIG. 4, through a further embodiment of the gas-feed connection.
  • the gas pocket according to the invention described below is used in a cathode half-element during the electrolysis of an aqueous solution of alkali metal chloride.
  • the gas diffusion electrode is in this case operated as an oxygen consumption cathode.
  • a gas pocket 2 is provided with a detachable gas-feed connection 3 which is arranged on one side of the gas pocket symmetrically or centrally between the longitudinal sides 37 , 38 (FIG. 1).
  • a detachable gas-feed connection 3 which is arranged on one side of the gas pocket symmetrically or centrally between the longitudinal sides 37 , 38 (FIG. 1).
  • the outlet openings 30 and 30 ′ only those which lie at the bottom are open.
  • Gas pockets with a gas-feed connection located on the left are thus of the same design as those with a gas-feed connection located on the right.
  • the gas-feed connection 3 comprises a fixed part 6 (FIGS. 2 and 4), which is connected to the front wall 4 of the gas-connecting passage 1 , and the mating piece 7 , which is part of the removable gas pocket 2 .
  • the gas-connecting passage 1 is used to connect two gas pockets 2 located above one another. The gas which emerges from the lower gas pocket flows through the gas-connecting passage into the gas pocket above.
  • the bottom gas pocket has a gas-feed connection stub, and a further connection is provided for the gas discharge, and the gas can be discharged together with the electrolyte via the gas discharge connection stub.
  • the gas pocket 2 is connected to the gas-connecting passage I via a screw connection between fixed part 6 and mating piece 7 through the through-opening 19 in the mating piece 7 via a securing pin, such as for example a threaded pin 15 and the nut 16 with washer 17 .
  • the through-opening 19 extends from the back wall 5 to the gas diffusion electrode 22 and is therefore accessible from the front, i.e. from the side on which the gas diffusion electrode 22 is arranged.
  • Simply loosening the nut 16 allows the gas-feed connection 3 to be released and the gas pocket 2 can be removed after the connection to a support structure 33 , which in the exemplary embodiment illustrated is configured as a riveted connection 34 (FIG. 2), has been released.
  • Gas is in this case transported via the mating channels or gas passages 8 and 10 in the fixed part 6 and in the mating piece 7 , respectively, with a compensation passage 9 serving to improve the gas transport in the event of poorly aligned, for example offset, gas passages 8 , 10 .
  • Seals 13 and 14 outside and inside the through-openings in corresponding seal seats 11 and 12 are responsible, in the screwed-together state, for providing a seal with respect to the electrolyte and therefore for avoiding uncontrolled loss of gas.
  • a baffle plate, in particular a metal baffle sheet, 20 fitted to the edge 18 of the mating piece 7 associated with the gas pocket 2 diverts the incoming gas into a direction of flow parallel to the gas diffusion electrode 22 and thereby avoids unacceptably high gas velocities at the rear side of the gas diffusion electrode 22 .
  • connection of the gas diffusion electrode 22 to the edge 18 can be effected either by means of a suitable weld (ultrasonic or laser welding) or by soldering.
  • a suitable weld ultrasonic or laser welding
  • soldering soldering
  • the gas pocket 2 itself is provided with a rim 21 , the height of which defines the distance between back wall 5 and gas diffusion electrode 22 .
  • Back wall 5 , rim 21 and gas diffusion electrode 22 are preferably connected by ultrasonic or laser welding, welding advantageously being carried out using an angle plate 24 designed as an edge protector. This constitutes a gas pocket electrode unit.
  • the gas pockets are likewise secured to the securing rail 33 belonging to the cathode half-cell (FIG. 2) releasably by means of a screw connection or riveted connection 34 .
  • a prestressed metal profiled strip 31 which is perforated so as to match the perforations in the gas pocket and securing rail, and a permanently elastic seal 32 beneath it are pressed on via the screw connection/riveted connection, thereby producing linear contact between the securing points of the gas pocket electrode unit.
  • gas pocket electrode units can be exchanged using components which have been tested for leaktightness, the gas pocket electrode units forming flat structures without projecting parts which are therefore easy to handle. If the releasable connection of the gas pocket electrode units is also selected, they can be exchanged in situ in the installation.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Hybrid Cells (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
US10/493,485 2001-10-23 2002-10-14 Eletrochemical half-element Abandoned US20040245095A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10152274.6 2001-10-23
DE10152274A DE10152274A1 (de) 2001-10-23 2001-10-23 Neue, einzeln herausnehmbare Gastaschen
PCT/EP2002/011476 WO2003036741A2 (fr) 2001-10-23 2002-10-14 Demi-element electrochimique

Publications (1)

Publication Number Publication Date
US20040245095A1 true US20040245095A1 (en) 2004-12-09

Family

ID=7703438

Family Applications (1)

Application Number Title Priority Date Filing Date
US10/493,485 Abandoned US20040245095A1 (en) 2001-10-23 2002-10-14 Eletrochemical half-element

Country Status (9)

Country Link
US (1) US20040245095A1 (fr)
EP (1) EP1440488A2 (fr)
JP (1) JP2005506460A (fr)
KR (1) KR20040058216A (fr)
CN (1) CN1575355A (fr)
AU (1) AU2002350537A1 (fr)
DE (1) DE10152274A1 (fr)
HU (1) HUP0401576A3 (fr)
WO (1) WO2003036741A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10978712B2 (en) * 2005-05-21 2021-04-13 Covestro Deutschland Ag Process for the manufacture of gas diffusion electrodes

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10152794A1 (de) * 2001-10-25 2003-05-08 Bayer Ag Drainage im Gasraum bei Elektrolyseprozessen

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4253932A (en) * 1978-05-19 1981-03-03 Hooker Chemicals & Plastics Corp. Unitary frame and membrane for electrolytic cells
US6165322A (en) * 1997-07-29 2000-12-26 Hercules Incorporated Polyamidoamine/epichlorohydrin resins bearing polyol sidechains as dry strength agents

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19646950A1 (de) * 1996-11-13 1998-05-14 Bayer Ag Elektrochemische Gasdiffusionshalbzelle
DE19954247C2 (de) * 1999-11-11 2002-11-14 Wolfgang Strewe Elektrolysezelle mit Gasdiffusionselektrode für großtechnische Anlagen sowie Verwendungen der Elektrolysezelle

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4253932A (en) * 1978-05-19 1981-03-03 Hooker Chemicals & Plastics Corp. Unitary frame and membrane for electrolytic cells
US6165322A (en) * 1997-07-29 2000-12-26 Hercules Incorporated Polyamidoamine/epichlorohydrin resins bearing polyol sidechains as dry strength agents

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10978712B2 (en) * 2005-05-21 2021-04-13 Covestro Deutschland Ag Process for the manufacture of gas diffusion electrodes

Also Published As

Publication number Publication date
HUP0401576A3 (en) 2005-07-28
CN1575355A (zh) 2005-02-02
WO2003036741A2 (fr) 2003-05-01
JP2005506460A (ja) 2005-03-03
HUP0401576A2 (hu) 2004-11-29
WO2003036741A3 (fr) 2003-11-20
DE10152274A1 (de) 2003-04-30
AU2002350537A1 (en) 2003-05-06
EP1440488A2 (fr) 2004-07-28
KR20040058216A (ko) 2004-07-03

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Legal Events

Date Code Title Description
AS Assignment

Owner name: BAYER MATERIALSCIENCE AG, GERMANY

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:PINTER, HANS-DIETER;BULAN, ANDREAS;KLESPER, WALTER;AND OTHERS;REEL/FRAME:015734/0240

Effective date: 20040326

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION