US2054923A - Vacuum treatment of metals - Google Patents
Vacuum treatment of metals Download PDFInfo
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- US2054923A US2054923A US693239A US69323933A US2054923A US 2054923 A US2054923 A US 2054923A US 693239 A US693239 A US 693239A US 69323933 A US69323933 A US 69323933A US 2054923 A US2054923 A US 2054923A
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- Prior art keywords
- metal
- vacuum
- chamber
- furnace
- metals
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- Expired - Lifetime
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- 229910052751 metal Inorganic materials 0.000 title description 48
- 239000002184 metal Substances 0.000 title description 48
- 150000002739 metals Chemical class 0.000 title description 12
- 238000009489 vacuum treatment Methods 0.000 title description 4
- 239000007789 gas Substances 0.000 description 15
- 238000005266 casting Methods 0.000 description 6
- 230000009471 action Effects 0.000 description 4
- 230000008018 melting Effects 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- -1 ferrous metals Chemical class 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910001338 liquidmetal Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 238000010408 sweeping Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/04—Refining by applying a vacuum
Definitions
- This invention relates to the preparation of metals for casting and more particularly to the vacuum treatment of molten metals.
- the characteristics of the casting are improved.
- the casting may be made particularly free from gases. and voids.
- the present invention accordingly provides an improved method and means for effecting this treatment which is simple, effective and economical and is an improvement on the invention described in the copending application of Jesse O. Betterton, Serial Number 675,149.
- the invention is particularly adapted to the treatment of non-ferrous metals, such as copper and aluminum, but it may also be applied to the treatment of other metals, as will be apparent to a person skilled in the art.
- the metal is melted, preferably in a non-absorbable atmosphere, and onits way to a casting box is passed through a vacuum chamber in which it is agitated to bring all parts of the bath to the surface where it is directly subjected to the action of the vacuum.
- the metal is agitated by a mechanical stirrer or agitator or by passing a gas, such as air, through the metal.
- Fig. 2 ⁇ is a partial vertical section through a modified form of a vacuum chamber
- Fig. v3 is a sectiton taken on the line 3--3 of Fig. 2.
- the furnace is also provided with a bottom I4 having a lining i5 of suitable refractory material upon which a bath I6 of molten metal is supported.
- 'I'he furnace may be provided with a plurality of fire flue tubes I1 which may be supported by the side wail I I in any suitable manner and may join a suitable header I8.
- Each flue I1 may be provided with a suitable burner (not shown) by which heat is supplied to the furnace.
- An auxiliary burner 20 may be mountedin the end wall I3 to assist in raising the temperature of the furnace, for example, in starting the melting operation.
- may also be provided forsupplyingachemically inert, non-absorbable gas to the furnace, which may be controlled by suitable means, such as a. valve '22.
- the vacuum treating device is shown as comprising a cylinder 30 which may be made of any suitable refractory material having suiilcient heat e conductivity to permit a uniform heat distribution to be maintained, for example, graphite, silicon carbide, or other molded material.
- the cylinder 30 is mounted within the end walls of the furnace in' a position to receive heat therefrom, whereby the metalis prevented from freezing as it passes ⁇ through the cylinder in the manner to be described.
- the cylinder 3l)v is provided, preferably 4at its upper end, with a vacuum chamber 3
- the vacuum chamber communicates with the4 bath I6 by a channel 36 and is provided with a discharge'channel 4I controlled by a valve 42 and adaptedA to discharge metal to a suitable casting apparatus (not shown).
- a ⁇ nozzle is mounted in the lower part ofthe vacuum chamber 3l in a position to supply gases under pressure thereto. Said nozzle may be connected by apassage 6I to a pipe 62 through which the gases are passed.
- the metal to be melted is supplied to the furnace III in any convenient manner and is suitably heated by said furnace while a chemically inert, non-absorbable atmosphere is maintained therein.
- the pressure is then reduced within the vacuum chamber 3I by applying suction to pipe 32 and a vacuum is produced in the chamber sumcient to raise the molten metal from the 55 bath I 8 through the channel 30 into the chamber 3
- the metal is then discharged through the channel 4l into the casting apparatus (not shown) 'Ihe vacuum chamber 3
- the gas bubbles, breaking through the liquid metal serve to increase the amount of surface of metal exposed to the vacuum and to agitate the metal so as to facilitate the escape of dissolved gases.
- Thesource of the vacuum may be suillciently large so that the gases admitted through the nozzle Il do not materially increase the gas pressure within the chamber 3
- the sweeping action of the insoluble gas further improves the rate of elimination of the dissolved gas by more effectively removing the same from the vacuum chamber.
- an agitating device comprising a plurality of radially extending blades 10, mounted upon a .rotating shaft 1I, is supported in a suitable manner, such as by housing 12, above the top of the vacuum chamber.
- Suitable means such as a sheave "Il, adapted to cooperate with a belt 14, may be provided for rotating the blades .10.
- a suction pipe 15 may beformed concentric with the shaft 1I and may operate as a support for said housing 12. It is obvious, however, that the mechanical construction may be varied as desired.
- the blades 1l are rotated and are adapted to continuously agitate the metal within the chamber Il so as to conltinuously change the surface of the metal and to expose various parts of the metal directly to the action of the vacuum within said chamber.
- the impeller is preferably formed of some nonmetallic material having a low heat conductivity, such as graphite, lava, fire brick or the like.
- the shaft 1I may be cooled by suitable means, such as by circulating water or" other cooling medium (not shown). It is obvious that the type of impeller may be varied. 4 A preferred form has been shown for purposes of illustration only.
- An apparatus for vacuum treating molten metals comprising a body forming a vacuum chamber, means for passing molten metals therethrough, and means to agitate the metal therein comprising an impeller immersed in said metal.
- An apparatus for vacuum treating molten metals comprising a body forming a vacuum chamber, means for passing molten metals therethrough, and means to agitate the metal therein comprising an impeller formed of non-heat conducting material immersed in said metal.
- vacuum treating means comprising a body ment ber interposed in said furnace and having a vacuum chamber, said chamber being mounted above the level of the metal in said furnace and connected thereto by means of a channel, the eleva.
- vacuum treating means comprising a body member interposed in said furnace and having a vacuum chamber, said chamber being mounted above the level of the metal in said furnace and connected thereto 'by means of a channel, the elevation of the chamber bearing a relation to the barometric height of the metal such that the metal from said bath is raised into said chamber by the vacuum within said chamber, and means to introduce gasesbelow the surface of the metal to agitate the metal and assist in the removal of occluded gases therefrom.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
- Vertical, Hearth, Or Arc Furnaces (AREA)
- Furnace Details (AREA)
Description
:Sep-t- 22, 1935 J. O. BETTERTON ET Al.
VACUUM TREATMENT oF'METALs Filed oct. 12, 1933 2 Vo. .o
Patented Sept. 22, 1936 PATENT OFFICE VACUUM TREATMENT 0F METALS Jesse 0. Betterton and Albert J. Phillips, Mc-
tuchen, N. J., assigner: to American Smeltlnx and Refining Company. New York, N. Y., a corporation of New Jersey Application' October 12, 1933, Serial No. 693,239
6 Claims.
This invention relates to the preparation of metals for casting and more particularly to the vacuum treatment of molten metals.
In certain instances, it has been found that by subjecting molten metals to a vacuum the characteristics of the casting are improved. For example, the casting may be made particularly free from gases. and voids. The present invention accordingly provides an improved method and means for effecting this treatment which is simple, effective and economical and is an improvement on the invention described in the copending application of Jesse O. Betterton, Serial Number 675,149. The invention is particularly adapted to the treatment of non-ferrous metals, such as copper and aluminum, but it may also be applied to the treatment of other metals, as will be apparent to a person skilled in the art.
In accordance with this invention, the metal is melted, preferably in a non-absorbable atmosphere, and onits way to a casting box is passed through a vacuum chamber in which it is agitated to bring all parts of the bath to the surface where it is directly subjected to the action of the vacuum. In certain embodiments of the invention, the metal is agitated by a mechanical stirrer or agitator or by passing a gas, such as air, through the metal.
The invention also consists of certain novel features hereinafter more fully set forth. .Although the novel features which are believed to be characteristic of this invention will be particularly pointed out in the 'claims appended hereto, the invention itself, as to its objects and advantages, and the manner in which it may be carried out, may be better understood by referring to the following description, taken in connection with the 'accompanying drawing forming a part thereof, in which Fig. l is `a partial' vertical section through a furnace illustrating one embodiment of the present invention;
Fig. 2` is a partial vertical section through a modified form of a vacuum chamber; and
Fig. v3 is a sectiton taken on the line 3--3 of Fig. 2.
Like reference charactersv denote like parts in the several figures of the drawing. In the following description and in the claims various details wi1l be identified by specific names for convenience but they are intended to be as generic in their application as the art will permit.
Referring to the drawing more in detail and particularly to Fig. 1, the invention is shown as applied to a furnace I0 comprising side walls II,
(Gl. 26S-34) roof I2 and an end wall I3. The furnace is also provided with a bottom I4 having a lining i5 of suitable refractory material upon which a bath I6 of molten metal is supported.
'I'he furnace may be provided with a plurality of fire flue tubes I1 which may be supported by the side wail I I in any suitable manner and may join a suitable header I8. Each flue I1 may be provided with a suitable burner (not shown) by which heat is supplied to the furnace. An auxiliary burner 20 may be mountedin the end wall I3 to assist in raising the temperature of the furnace, for example, in starting the melting operation. A pipe 2| may also be provided forsupplyingachemically inert, non-absorbable gas to the furnace, which may be controlled by suitable means, such as a. valve '22.
It is to be understood that the various parts of the furnace outlined above are of standard construction and that only so much thereof has been described as is essential yto a proper understanding of the present invention.
The vacuum treating device is shown as comprising a cylinder 30 which may be made of any suitable refractory material having suiilcient heat e conductivity to permit a uniform heat distribution to be maintained, for example, graphite, silicon carbide, or other molded material. The cylinder 30 is mounted within the end walls of the furnace in' a position to receive heat therefrom, whereby the metalis prevented from freezing as it passes` through the cylinder in the manner to be described.
The cylinder 3l)v is provided, preferably 4at its upper end, with a vacuum chamber 3| which 35 communicates by'v pipe 32, controlled by valve 33, with a suitable source of vacuum (not shown). The vacuum chamber communicates with the4 bath I6 by a channel 36 and is provided with a discharge'channel 4I controlled by a valve 42 and adaptedA to discharge metal to a suitable casting apparatus (not shown). A` nozzle is mounted in the lower part ofthe vacuum chamber 3l in a position to supply gases under pressure thereto. Said nozzle may be connected by apassage 6I to a pipe 62 through which the gases are passed.
In the operation of the above described apparatus, the metal to be melted is supplied to the furnace III in any convenient manner and is suitably heated by said furnace while a chemically inert, non-absorbable atmosphere is maintained therein. The pressure is then reduced within the vacuum chamber 3I by applying suction to pipe 32 and a vacuum is produced in the chamber sumcient to raise the molten metal from the 55 bath I 8 through the channel 30 into the chamber 3|, partially filling the chamber. The metal is then discharged through the channel 4l into the casting apparatus (not shown) 'Ihe vacuum chamber 3| is maintained partially filled with metal, as for example. half full, and inactive, insoluble gases are admitted through the nozzle Il. The gas bubbles, breaking through the liquid metal, serve to increase the amount of surface of metal exposed to the vacuum and to agitate the metal so as to facilitate the escape of dissolved gases. Thesource of the vacuum may be suillciently large so that the gases admitted through the nozzle Il do not materially increase the gas pressure within the chamber 3|. The sweeping action of the insoluble gas further improves the rate of elimination of the dissolved gas by more effectively removing the same from the vacuum chamber.
Referring to Figs. 2 and 3, the vacuum chamber and associated mechanism are similar to that above described. In this form of the invention. however, an agitating device comprising a plurality of radially extending blades 10, mounted upon a .rotating shaft 1I, is supported in a suitable manner, such as by housing 12, above the top of the vacuum chamber. Suitable means, such as a sheave "Il, adapted to cooperate with a belt 14, may be provided for rotating the blades .10. A suction pipe 15 may beformed concentric with the shaft 1I and may operate as a support for said housing 12. It is obvious, however, that the mechanical construction may be varied as desired.
In this form of the invention, the blades 1l are rotated and are adapted to continuously agitate the metal within the chamber Il so as to conltinuously change the surface of the metal and to expose various parts of the metal directly to the action of the vacuum within said chamber. The impeller is preferably formed of some nonmetallic material having a low heat conductivity, such as graphite, lava, fire brick or the like. The shaft 1I may be cooled by suitable means, such as by circulating water or" other cooling medium (not shown). It is obvious that the type of impeller may be varied. 4 A preferred form has been shown for purposes of illustration only.
While certain specific terms have been used for convenience in describing the present invention, it is to be understood that the invention is not to be Hunted thereby. For example, the. term vacuum" has been employed in describing the chamber 3| and the operation of the apparatus. It is to be understood, however, that the degree of vacuum may be varied as required in each particular instance without departing from the spirit of the invention. It is also to be understood that the furnace I and the associated apparatus may be operated at substantially atmospheric pressure and preferably in the presence of a non-oxidizing non-absorbable gas in a manner more fully described in the co-pending application above referred to.
Although certain preferred embodiments of the chamber to agitate the same and change invention have been shown for purposes of illustration, it is to be understood that the invention is not to be limited thereto but is only to be limited in accordance with the following claims when interpreted in view of the prior art.
What is claimed is:
. 1. The process of treating molten metals which comprises passing the molten metal through a vacuum chamber and bubbling a. gas through the body of the metal in said chamber whereby the surface exposed to the action of the vacuum is increased and constantly changed through thorough agitation of the metal.
2. An apparatus for vacuum treating molten metals comprising a body forming a vacuum chamber, means for passing molten metals therethrough, and means to agitate the metal therein comprising an impeller immersed in said metal.
3. An apparatus for vacuum treating molten metals comprising a body forming a vacuum chamber, means for passing molten metals therethrough, and means to agitate the metal therein comprising an impeller formed of non-heat conducting material immersed in said metal.
connected thereto by means of a channel, the
elevation of the chamber bearing a relation to the barometric height of the metal such that the metal from said bath is raised into said chamber by the vacuum Within said chamber, and means associated with said chamber to agitate the metal i' for changing the surface exposed to the vacuum. 5. In combination with a metal melting furnace,
vacuum treating means comprising a body ment ber interposed in said furnace and having a vacuum chamber, said chamber being mounted above the level of the metal in said furnace and connected thereto by means of a channel, the eleva.-
tion of the chamber bearing a relation to' the barometric height of the metal such that the metal from said bath is raised into said chamber by the vacuum within said chamber, and an impeller mounted to engage the metal in said face exposed to the vacuum.
6. In combination with a metal melting furnace, vacuum treating means comprising a body member interposed in said furnace and having a vacuum chamber, said chamber being mounted above the level of the metal in said furnace and connected thereto 'by means of a channel, the elevation of the chamber bearing a relation to the barometric height of the metal such that the metal from said bath is raised into said chamber by the vacuum within said chamber, and means to introduce gasesbelow the surface of the metal to agitate the metal and assist in the removal of occluded gases therefrom.'
JESSE O. BE'I'IERTON. ALBERT J. PHILLIPS.
the sur-
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US693239A US2054923A (en) | 1933-10-12 | 1933-10-12 | Vacuum treatment of metals |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US693239A US2054923A (en) | 1933-10-12 | 1933-10-12 | Vacuum treatment of metals |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2054923A true US2054923A (en) | 1936-09-22 |
Family
ID=24783882
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US693239A Expired - Lifetime US2054923A (en) | 1933-10-12 | 1933-10-12 | Vacuum treatment of metals |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2054923A (en) |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2429584A (en) * | 1944-01-27 | 1947-10-21 | Revere Copper & Brass Inc | Method of and apparatus for removing zinc from copper base alloys |
| US2744629A (en) * | 1952-06-02 | 1956-05-08 | Rca Corp | Method and apparatus for processing chemicals |
| US2859262A (en) * | 1955-09-05 | 1958-11-04 | Hoerder Huettenunion Ag | Apparatus for degasifying liquid metal |
| US2893715A (en) * | 1955-09-05 | 1959-07-07 | Hoerder Huettenunion Ag | Equipment for degassing metals in particular steel melts |
| US2895820A (en) * | 1956-11-08 | 1959-07-21 | Hoerder Huettenunion Ag | Methods of reducing iron ores and carburizing under vacuum |
| US2993780A (en) * | 1957-11-16 | 1961-07-25 | Siderurgie Fse Inst Rech | Method for treating steel in vacuo |
| US3083422A (en) * | 1959-04-13 | 1963-04-02 | Finkl & Sons Co | Porous stopper rod |
| US3169058A (en) * | 1960-11-18 | 1965-02-09 | Union Carbide Corp | Decarburization, deoxidation, and alloy addition |
| US3236635A (en) * | 1958-12-02 | 1966-02-22 | Finkl & Sons Co | Method for degassing molten metal |
| DE1216904B (en) * | 1957-04-03 | 1966-05-18 | Heraeus Gmbh W C | Process for vacuum degassing of molten metals, in particular steel |
| US3389989A (en) * | 1965-06-03 | 1968-06-25 | Finkl & Sons Co | Treatment of molten metal |
| US3870511A (en) * | 1971-12-27 | 1975-03-11 | Union Carbide Corp | Process for refining molten aluminum |
| US3975187A (en) * | 1975-02-13 | 1976-08-17 | Reynolds Metals Company | Treatment of carbothermically produced aluminum |
| US5470201A (en) * | 1992-06-12 | 1995-11-28 | Metaullics Systems Co., L.P. | Molten metal pump with vaned impeller |
| US5597289A (en) * | 1995-03-07 | 1997-01-28 | Thut; Bruno H. | Dynamically balanced pump impeller |
| US5603749A (en) * | 1995-03-07 | 1997-02-18 | Bethlehem Steel Corporation | Apparatus and method for vacuum treating molten steel |
| US5634770A (en) * | 1992-06-12 | 1997-06-03 | Metaullics Systems Co., L.P. | Molten metal pump with vaned impeller |
| US6019576A (en) * | 1997-09-22 | 2000-02-01 | Thut; Bruno H. | Pumps for pumping molten metal with a stirring action |
-
1933
- 1933-10-12 US US693239A patent/US2054923A/en not_active Expired - Lifetime
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2429584A (en) * | 1944-01-27 | 1947-10-21 | Revere Copper & Brass Inc | Method of and apparatus for removing zinc from copper base alloys |
| US2744629A (en) * | 1952-06-02 | 1956-05-08 | Rca Corp | Method and apparatus for processing chemicals |
| US2859262A (en) * | 1955-09-05 | 1958-11-04 | Hoerder Huettenunion Ag | Apparatus for degasifying liquid metal |
| US2893715A (en) * | 1955-09-05 | 1959-07-07 | Hoerder Huettenunion Ag | Equipment for degassing metals in particular steel melts |
| US2895820A (en) * | 1956-11-08 | 1959-07-21 | Hoerder Huettenunion Ag | Methods of reducing iron ores and carburizing under vacuum |
| DE1216904B (en) * | 1957-04-03 | 1966-05-18 | Heraeus Gmbh W C | Process for vacuum degassing of molten metals, in particular steel |
| US2993780A (en) * | 1957-11-16 | 1961-07-25 | Siderurgie Fse Inst Rech | Method for treating steel in vacuo |
| US3236635A (en) * | 1958-12-02 | 1966-02-22 | Finkl & Sons Co | Method for degassing molten metal |
| US3083422A (en) * | 1959-04-13 | 1963-04-02 | Finkl & Sons Co | Porous stopper rod |
| US3169058A (en) * | 1960-11-18 | 1965-02-09 | Union Carbide Corp | Decarburization, deoxidation, and alloy addition |
| US3389989A (en) * | 1965-06-03 | 1968-06-25 | Finkl & Sons Co | Treatment of molten metal |
| US3870511A (en) * | 1971-12-27 | 1975-03-11 | Union Carbide Corp | Process for refining molten aluminum |
| US3975187A (en) * | 1975-02-13 | 1976-08-17 | Reynolds Metals Company | Treatment of carbothermically produced aluminum |
| US5470201A (en) * | 1992-06-12 | 1995-11-28 | Metaullics Systems Co., L.P. | Molten metal pump with vaned impeller |
| US5586863A (en) * | 1992-06-12 | 1996-12-24 | Metaullics Systems Co., L.P. | Molten metal pump with vaned impeller |
| US5634770A (en) * | 1992-06-12 | 1997-06-03 | Metaullics Systems Co., L.P. | Molten metal pump with vaned impeller |
| US5597289A (en) * | 1995-03-07 | 1997-01-28 | Thut; Bruno H. | Dynamically balanced pump impeller |
| US5603749A (en) * | 1995-03-07 | 1997-02-18 | Bethlehem Steel Corporation | Apparatus and method for vacuum treating molten steel |
| US6019576A (en) * | 1997-09-22 | 2000-02-01 | Thut; Bruno H. | Pumps for pumping molten metal with a stirring action |
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