US1839157A - Titanium steel and the process of manufacturing the same - Google Patents
Titanium steel and the process of manufacturing the same Download PDFInfo
- Publication number
- US1839157A US1839157A US331383A US33138329A US1839157A US 1839157 A US1839157 A US 1839157A US 331383 A US331383 A US 331383A US 33138329 A US33138329 A US 33138329A US 1839157 A US1839157 A US 1839157A
- Authority
- US
- United States
- Prior art keywords
- carbon
- titanium
- steel
- steels
- manufacturing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910001200 Ferrotitanium Inorganic materials 0.000 title description 5
- 238000004519 manufacturing process Methods 0.000 title description 5
- 238000000034 method Methods 0.000 title description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 20
- 229910000831 Steel Inorganic materials 0.000 description 20
- 229910052799 carbon Inorganic materials 0.000 description 20
- 239000010959 steel Substances 0.000 description 20
- 239000010936 titanium Substances 0.000 description 14
- 229910052719 titanium Inorganic materials 0.000 description 14
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 12
- 229910052742 iron Inorganic materials 0.000 description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 4
- 239000011651 chromium Substances 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- 239000006104 solid solution Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229910021332 silicide Inorganic materials 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 229910000604 Ferrochrome Inorganic materials 0.000 description 1
- 229910000616 Ferromanganese Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- -1 titanium carbides Chemical class 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
Definitions
- steels thus manufactured have a uniform structure, and that all the components of the iron are contained in the steel in a state of solid solution.
- the ratio of carbon to titanium in the steel should not exceed approximately. 5:4, and
- v the .contentsof carbon and titanium should not exceed about 1% and 0,8% respectivelv. Under such. conditions the steels are still primarily titanium and not carbon steels. They still retain auniform texture and all the constituents are contained in the solid solution condition. In practice the actual contents of carbon and'titanium will preferably not exceed about 0,2% and 0,44% re-' spectively. v
- the strength of the titanium steel containing a slight amount of carbon can be considerably increased by adding slight amounts of manganese and chr0- mium.
- the strength of the steel referred to in the first-named example is further increased to 100 kilogrammes per square millimeter by adding 0,5% of man- In all the said steels is about 80% of the strength.
- the steel can be manufactured by the processes described in the aforesaid pat ent, which patent relates to the manufacture .ofiron-titanium alloys which are free of carbon, the processes being modified only by adding so much carbon, manganese and chromium to the baths as is necessary for obtaining the desired final composition of the baths. But I may also proceed-from the manufacture of the steel on the hearth on'which an iron bath is refined down to a content of 0,1% of carbon and deom'dized by. means of ferromanganese, ferrochromium or ferromanganesechromium-silicides which are nearly free of carbon, being preferably added during the tapping of the metal and preferably in liquid form. In
- a modification I may proceed from an overrefined bath of iron which is nearly free of carbon, the said bath being deoxidized by means of ferromangariese, ferrochromiumor ferromanganesechromium-silicides, containing so much carbon that the deoxidized' bath contains about 0,1% of carbon.
- ferrotitanium which is freeof carthe limit bf elasticity 4 ferrotitanium free of carbon bon is added preferably in a liquid state.
- Such additions are boron, zirconium, tungsten, molybdenum, vanadium, and uranium.
- Iclaim 1. The herein described steel containing about 0,270 of titanium, and about 0,5% of silicon. 2. The herein described steel containin iron, about 0,1% of carbon, about 0,2% of titanium, about 0,5% of silicon, about 0,5% of manganese, and about 0,5% of chromium. In testimony whereof I hereunto aflix my signature. WALTHER MATHESIUS.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Treatment Of Steel In Its Molten State (AREA)
Description
50 ganese and 0,5% of chromium.
Patented Dec. 29, 1931 UNITED. STATES PATENT OFFICE TITANIUM srEEr. AND THE rRocEss or manur'ncmme THE smE no Drawing. Application filed January 9,1929, Serial No. 381,388, and in Germany October 25, 1927.
This invention relates to improvements in titanium steel and the process of manufacturing the same. U. S. Patent 1,546,176,
July 14, 1925, describes titanium steels and processes of manufacturing the same, which titanium steels are free of carbon? It is now found that similar titanium steels can be manufactured which contain comparatively small amounts of carbon and silicon, and
that steels thus manufactured have a uniform structure, and that all the components of the iron are contained in the steel in a state of solid solution.
It has further been discovered that the property of a'small amount of titanium of about 02% increasing the strength of the steel is even more conspicuous in steels containing a slight amount of carbon than "in steels which are freeof carbon. For example. the strength of a steel containing about 0,1%- of carbon and from about 0.5% to 0.8% of silicon is increased by an addition of about 02% of titanium from 54 kilogrammes to 82 kilogrammes per square millimeter;
In order to obtain the combination of the titanium and carbon in the form of the titanium carbides in solid solution in the steels. the ratio of carbon to titanium in the steel should not exceed approximately. 5:4, and
v the .contentsof carbon and titanium should not exceed about 1% and 0,8% respectivelv. Under such. conditions the steels are still primarily titanium and not carbon steels. They still retain auniform texture and all the constituents are contained in the solid solution condition. In practice the actual contents of carbon and'titanium will preferably not exceed about 0,2% and 0,44% re-' spectively. v
It is also found that the strength of the titanium steel containing a slight amount of carbon can be considerably increased by adding slight amounts of manganese and chr0- mium. For example, the strength of the steel referred to in the first-named example is further increased to 100 kilogrammes per square millimeter by adding 0,5% of man- In all the said steels is about 80% of the strength.
Notwithstanding its high strength the steel can be readily worked, and it has a high expansion and contraction. Further, the'steel is distinguished by a high degree of resistance to wear. The steel can be manufactured by the processes described in the aforesaid pat ent, which patent relates to the manufacture .ofiron-titanium alloys which are free of carbon, the processes being modified only by adding so much carbon, manganese and chromium to the baths as is necessary for obtaining the desired final composition of the baths. But I may also proceed-from the manufacture of the steel on the hearth on'which an iron bath is refined down to a content of 0,1% of carbon and deom'dized by. means of ferromanganese, ferrochromium or ferromanganesechromium-silicides which are nearly free of carbon, being preferably added during the tapping of the metal and preferably in liquid form. In
a modification I may proceed from an overrefined bath of iron which is nearly free of carbon, the said bath being deoxidized by means of ferromangariese, ferrochromiumor ferromanganesechromium-silicides, containing so much carbon that the deoxidized' bath contains about 0,1% of carbon. To the said bath ferrotitanium which is freeof carthe limit bf elasticity 4 ferrotitanium free of carbon bon is added preferably in a liquid state. In
another modification I proceed from an overerty of increasing the'strength, though their influence is less conspicuousfascompared to that of the metals manganese and chromium.-
-refined iron bath which is nearly free of car- 5 iron, about 0,1% of carbon,
Such additionsare boron, zirconium, tungsten, molybdenum, vanadium, and uranium.
Iclaim: 1. The herein described steel containing about 0,270 of titanium, and about 0,5% of silicon. 2. The herein described steel containin iron, about 0,1% of carbon, about 0,2% of titanium, about 0,5% of silicon, about 0,5% of manganese, and about 0,5% of chromium. In testimony whereof I hereunto aflix my signature. WALTHER MATHESIUS.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1839157X | 1927-10-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1839157A true US1839157A (en) | 1931-12-29 |
Family
ID=7745491
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US331383A Expired - Lifetime US1839157A (en) | 1927-10-25 | 1929-01-09 | Titanium steel and the process of manufacturing the same |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1839157A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2474766A (en) * | 1945-10-11 | 1949-06-28 | Alvin G Waggoner | Alloy steel |
| US2736648A (en) * | 1952-03-06 | 1956-02-28 | United States Steel Corp | Low metalloid enameling steel and method of producing same |
-
1929
- 1929-01-09 US US331383A patent/US1839157A/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2474766A (en) * | 1945-10-11 | 1949-06-28 | Alvin G Waggoner | Alloy steel |
| US2736648A (en) * | 1952-03-06 | 1956-02-28 | United States Steel Corp | Low metalloid enameling steel and method of producing same |
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