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US1873941A - Process for producing water gas from pulverized coal and steam - Google Patents

Process for producing water gas from pulverized coal and steam Download PDF

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US1873941A
US1873941A US303066A US30306628A US1873941A US 1873941 A US1873941 A US 1873941A US 303066 A US303066 A US 303066A US 30306628 A US30306628 A US 30306628A US 1873941 A US1873941 A US 1873941A
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gas
steam
water gas
pulverized coal
producing water
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US303066A
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Hillebrand Hermann
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • C10J3/485Entrained flow gasifiers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/093Coal
    • C10J2300/0933Coal fines for producing water gas
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S48/00Gas: heating and illuminating
    • Y10S48/04Powdered fuel injection

Definitions

  • This invention relates to a process of and apparatus for producing water gas from pulverized coal and steam.
  • coal and steam are made to react at a temperature of approximately It is known to generate water gas in continuous operation from solid fuels, by conducting the necessary heat to the gas-form- 'o ing materials with the assi-stance of alternately heated regenerators. If, however, pulverized coal or pulverized coke is employed, special measures require to be adopted in order to ensure the use of a cheap, simple and l5 reliable apparatus.
  • the heating of the regenerators is eected by means of a part of the current of gas generated.
  • the reaction heat is supplied to the gas-forming materials either before or during their combination in the heater itself, or is introduced by means of a special agent, for example highly heated water gas. It is in all ⁇ cases of great advantage to employ 3u water gas for conveying the pulverulent coal,
  • the gas necessary for heating the regenerators is branched off from the main current of gas to be discharged from the apparatus without the use of valves or cocks subjected to the heat.
  • the desired distribution of the flow is maintained by a difference in pressure which is caused to act at the point at 4e which the heating gas is branched ofi' from the main current.
  • This difference in pressure is capable of regulation by suitable dimensioning of the resistance of the passages or openings traversed by the two currents, and by regulation of the valves or blowers which are situated at points where the same are not subjected to the heat.
  • the heat is also supplied after the commencement of the reaction to the gases already formed and to the materials capable of forming gas.
  • the supply of heat to the gas-forming materials is preferably effected in gradual manner, as these materials must be brought into the reactive state at a sufficient and even temperature, and by the gradual supply of heat it is accomplished that a substantial cooling does not occur during the course of the reaction, but rather more an increase in the reaction temperature.
  • the gas-forming materials are united prior to being heated, or the point of contact of the previously highly heated gas-forming materials is expanded as much as possible by suitable construction or distribution of the openings required.
  • Fig. 1, 1 and 2 are heating chambers, which communicate with each other by means of openings?) and 4 and also the passa e 5, which latter simultaneously acts as ust separator.
  • the steam on the one hand and-the mixture of water gas and pulverized coal on the other hand are introduced into the lower part of the .chamber 1 at 6 and 7 respectively.
  • the apertures 6 and 7 may be changed about.
  • a heat exchange checker work is provided partially shown in section for purposes of illustration. The conversion of the material occurs inand behind the heating chamber 1.
  • pulverizedcoal passes through the opening 3 into -100 the dust se arator 5, in which the major ortion of t e articles of ash carried along by the as is eposited in the rece tacle 8,
  • t e water gas is divided into two Currents.
  • the water gas to be removed from the apparatus 1s discharged at 9, whereby the gas employed for conveying the pulverized coal may be returned in circulation to the conveying fan.
  • the remaining part of the gas passes through the opening 4 into the chamber 2 for combustion and heating purposes.
  • the combustion air is introduced at 10, while at 11 is provided an ash receptacle.
  • the cooled com-- bustion gases escape through the opening 12.
  • FIG. 2 A modification of the above arrangement is shown in Fig. 2,. in which the regenerators are furnished with a partition extending approximately to the middle and also heat exchange checker work partly'shown in section.
  • the partition extends so far' that the extent of heating of the separately heated distillation materials is such that upon the said materials meeting together at the end of the partition in the hbttest portion, Awhich is not divided and which constitutes the continuation of the divided portion, ⁇ a good con centration of the gas hase is ensured.
  • the chamber 1 has cooled down, the chamber 2 having been heated,'the apparatus is switched over, the chamber 1 thenL being heated, while the chamber 2 is employed for producing gas.
  • regenerators which may then be arranged ⁇ circularly about the chamber or passage 5.
  • The'apparatus accordingly makes provision for the connection-of two or more heating chambers at their hottest ends by means of a passage which is incapable of being closed olf, and through which the highly heated mixture of gas and steam, in so far as the same actsas Vheating gas, passes from the 4one chamber into 'the other for the purpose of ance of the remaining valves, etc., ordinari-ly employed, which are situated at points in the pi es not touched by the heat.
  • a method of continuously producin water gas from pulverized coal or coke an steam consisting in passing steam and a mixture of art of the produced Water gas with pulveru ent coal or coke to a hot regenerator, producing water gas in said regenerator which thereby serves also as a generator, passing a part of the'produced water gas to a regenerator temporarily not producin gas, passlng off the remainder of the pro uced water gas from the space between said regenerators, passing combustion air to said latter regenerator and heatin the latter re-l generator by combustion of t e gas therein until such time as the llatter regenerator issuiiicientl heated, and then reversing the direction o iiow by introducing the material into the second named regenerator to' form water gas and heating the first named regenerator by causing combustion therein of part of the gas produced in the second named regenerator.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Solid-Fuel Combustion (AREA)

Description

All@ 23, 1932. H. HlLLx-:BRAND ,873,941
PROCESS FOR PRODUCING WATER GAS FROM PULVERIZED COAL IAND STEAM ug- 235 1932 H. HILLE'BRAND L873,941
PROCESS FOR PRODUCING WATER GAS FROM PULVERIZED COAL AND STEAM Patented Aug. 23, 1932 UNITED STATES HERMANN HILLEBRAND, F BERLIN,
PROCESS FOR PRODUCING WATER GAS FROM PULV'ERIZED COAL, AND\STEAM Application led August 30, 1928, Serial No. 303,066, and in. Germany August 24, 1927.
This invention relates to a process of and apparatus for producing water gas from pulverized coal and steam. In the production of water gas, coal and steam are made to react at a temperature of approximately It is known to generate water gas in continuous operation from solid fuels, by conducting the necessary heat to the gas-form- 'o ing materials with the assi-stance of alternately heated regenerators. If, however, pulverized coal or pulverized coke is employed, special measures require to be adopted in order to ensure the use of a cheap, simple and l5 reliable apparatus. A
The heating of the regenerators is eected by means of a part of the current of gas generated. In this manner the possibility is provided of employing an apparatus of compact construction, which is extremely economical from a thermal standpoint and very simple to regulate, and in which no valve members are required which will be subjected to heat. The reaction heat is supplied to the gas-forming materials either before or during their combination in the heater itself, or is introduced by means of a special agent, for example highly heated water gas. It is in all `cases of great advantage to employ 3u water gas for conveying the pulverulent coal,
thus returning a part of the water gas generated back into the circulatory system.
The gas necessary for heating the regenerators is branched off from the main current of gas to be discharged from the apparatus without the use of valves or cocks subjected to the heat. The desired distribution of the flow is maintained by a difference in pressure which is caused to act at the point at 4e which the heating gas is branched ofi' from the main current. This difference in pressure is capable of regulation by suitable dimensioning of the resistance of the passages or openings traversed by the two currents, and by regulation of the valves or blowers which are situated at points where the same are not subjected to the heat.
A This process is improved upon according to the invention by introducing steam or waste gas in circulation to the combustion process upon the alternate heating of the regenerators for the purpose of avoiding excesslve temperatures, so that as little loss of heat results as possible.
Furthermore, according to the invention, the heat is also supplied after the commencement of the reaction to the gases already formed and to the materials capable of forming gas. The supply of heat to the gas-forming materials is preferably effected in gradual manner, as these materials must be brought into the reactive state at a sufficient and even temperature, and by the gradual supply of heat it is accomplished that a substantial cooling does not occur during the course of the reaction, but rather more an increase in the reaction temperature.
For this purpose either the gas-forming materials are united prior to being heated, or the point of contact of the previously highly heated gas-forming materials is expanded as much as possible by suitable construction or distribution of the openings required.
Two forms of embodiment of an apparatus suitable for carrying out the process as above are illustrated in diagrammatical form in the accompanying drawings. All parts having no direct connection with the invention have been omitted from the two figures in gf question for the sake of better comprehension.
Referring now to Fig. 1, 1 and 2 are heating chambers, which communicate with each other by means of openings?) and 4 and also the passa e 5, which latter simultaneously acts as ust separator. In the position shown the steam on the one hand and-the mixture of water gas and pulverized coal on the other hand are introduced into the lower part of the .chamber 1 at 6 and 7 respectively. The apertures 6 and 7 may be changed about. Within thechambers 1 and 2 a heat exchange checker work is provided partially shown in section for purposes of illustration. The conversion of the material occurs inand behind the heating chamber 1. Thewater gas generated, including the quantity ernployed as conveying means for the. pulverizedcoal, passes through the opening 3 into -100 the dust se arator 5, in which the major ortion of t e articles of ash carried along by the as is eposited in the rece tacle 8, In the ust separator or passage 5 t e water gas is divided into two Currents. The water gas to be removed from the apparatus 1s discharged at 9, whereby the gas employed for conveying the pulverized coal may be returned in circulation to the conveying fan. The remaining part of the gas passes through the opening 4 into the chamber 2 for combustion and heating purposes. The combustion air is introduced at 10, while at 11 is provided an ash receptacle. The cooled com-- bustion gases escape through the opening 12.
An additional advantage in connection with the present method is attained by the fact that steam may be added to the combustion air introduced through 10. This is to be preferred in view of the fact that combustion of the current of gas branched'ol at 14 with pure air would result'in very high temperatures, which mi ht easily result Ain rapid wear of the materlal of the generator.
A modification of the above arrangement is shown in Fig. 2,. in which the regenerators are furnished with a partition extending approximately to the middle and also heat exchange checker work partly'shown in section. In this manner a separate heating of the gas acting as conveying means for the coal and of the steam is accomplished, whereby the partition extends so far' that the extent of heating of the separately heated distillation materials is such that upon the said materials meeting together at the end of the partition in the hbttest portion, Awhich is not divided and which constitutes the continuation of the divided portion,`a good con centration of the gas hase is ensured.
By the' division o the regenerators itis also necessary to provide two separate discharge passages 12 for the burnt gas, Aas shown in the drawings.
If the chamber 1 has cooled down, the chamber 2 having been heated,'the apparatus is switched over, the chamber 1 thenL being heated, while the chamber 2 is employed for producing gas.
Obviously in place of the two chambers 1 and 2 it is alsol possible to employ a larger number of regenerators, which may then be arranged `circularly about the chamber or passage 5. l
The'apparatus accordingly makes provision for the connection-of two or more heating chambers at their hottest ends by means of a passage which is incapable of being closed olf, and through which the highly heated mixture of gas and steam, in so far as the same actsas Vheating gas, passes from the 4one chamber into 'the other for the purpose of ance of the remaining valves, etc., ordinari-ly employed, which are situated at points in the pi es not touched by the heat.
t will of course be understood that no restriction is made to the exact forms of em-A bodiment shown, and that various other means may be employed without departing from 'the spirit of the invention.
- What I claim as new and desire to secure by Letters Patent is:
1. A method of continuously producin water gas from pulverized coal or coke an steam, consisting in passing steam and a mixture of art of the produced Water gas with pulveru ent coal or coke to a hot regenerator, producing water gas in said regenerator which thereby serves also as a generator, passing a part of the'produced water gas to a regenerator temporarily not producin gas, passlng off the remainder of the pro uced water gas from the space between said regenerators, passing combustion air to said latter regenerator and heatin the latter re-l generator by combustion of t e gas therein until such time as the llatter regenerator issuiiicientl heated, and then reversing the direction o iiow by introducing the material into the second named regenerator to' form water gas and heating the first named regenerator by causing combustion therein of part of the gas produced in the second named regenerator.
2. The method according to claim 1 including separately passing said steam and the said mixture of water ga's and pulverulentl coal or coke to said regenerator and separate-V ly heating said steam and' gas mixture currents in said regenerator, and combining the separately heated currents in said regenerator at the hottest portion thereof producing the Water gas in said regenerator.
' In testimony whereof I have aixed my signature,
HERMANN IIILIJEBRAND.
los
US303066A 1927-08-24 1928-08-30 Process for producing water gas from pulverized coal and steam Expired - Lifetime US1873941A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2614915A (en) * 1947-11-24 1952-10-21 Gulf Research Development Co Manufacture of synthesis gas
US2665200A (en) * 1948-07-01 1954-01-05 Hydrocarbon Research Inc Process for the gasification of solid carbonaceous materials
US2845335A (en) * 1952-03-20 1958-07-29 Koppers Co Inc Regenerative processes and apparatus

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2614915A (en) * 1947-11-24 1952-10-21 Gulf Research Development Co Manufacture of synthesis gas
US2665200A (en) * 1948-07-01 1954-01-05 Hydrocarbon Research Inc Process for the gasification of solid carbonaceous materials
US2845335A (en) * 1952-03-20 1958-07-29 Koppers Co Inc Regenerative processes and apparatus

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