US1873941A - Process for producing water gas from pulverized coal and steam - Google Patents
Process for producing water gas from pulverized coal and steam Download PDFInfo
- Publication number
- US1873941A US1873941A US303066A US30306628A US1873941A US 1873941 A US1873941 A US 1873941A US 303066 A US303066 A US 303066A US 30306628 A US30306628 A US 30306628A US 1873941 A US1873941 A US 1873941A
- Authority
- US
- United States
- Prior art keywords
- gas
- steam
- water gas
- pulverized coal
- producing water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title description 21
- 239000003245 coal Substances 0.000 title description 14
- 238000000034 method Methods 0.000 title description 10
- 239000007789 gas Substances 0.000 description 39
- 238000010438 heat treatment Methods 0.000 description 12
- 239000000463 material Substances 0.000 description 11
- 238000002485 combustion reaction Methods 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000000571 coke Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000005192 partition Methods 0.000 description 3
- 238000004326 stimulated echo acquisition mode for imaging Methods 0.000 description 3
- 238000010276 construction Methods 0.000 description 2
- LLBZPESJRQGYMB-UHFFFAOYSA-N 4-one Natural products O1C(C(=O)CC)CC(C)C11C2(C)CCC(C3(C)C(C(C)(CO)C(OC4C(C(O)C(O)C(COC5C(C(O)C(O)CO5)OC5C(C(OC6C(C(O)C(O)C(CO)O6)O)C(O)C(CO)O5)OC5C(C(O)C(O)C(C)O5)O)O4)O)CC3)CC3)=C3C2(C)CC1 LLBZPESJRQGYMB-UHFFFAOYSA-N 0.000 description 1
- SLZWEMYSYKOWCG-UHFFFAOYSA-N Etacelasil Chemical group COCCO[Si](CCCl)(OCCOC)OCCOC SLZWEMYSYKOWCG-UHFFFAOYSA-N 0.000 description 1
- 241000283986 Lepus Species 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000011874 heated mixture Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000004449 solid propellant Substances 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/48—Apparatus; Plants
- C10J3/485—Entrained flow gasifiers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/093—Coal
- C10J2300/0933—Coal fines for producing water gas
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S48/00—Gas: heating and illuminating
- Y10S48/04—Powdered fuel injection
Definitions
- This invention relates to a process of and apparatus for producing water gas from pulverized coal and steam.
- coal and steam are made to react at a temperature of approximately It is known to generate water gas in continuous operation from solid fuels, by conducting the necessary heat to the gas-form- 'o ing materials with the assi-stance of alternately heated regenerators. If, however, pulverized coal or pulverized coke is employed, special measures require to be adopted in order to ensure the use of a cheap, simple and l5 reliable apparatus.
- the heating of the regenerators is eected by means of a part of the current of gas generated.
- the reaction heat is supplied to the gas-forming materials either before or during their combination in the heater itself, or is introduced by means of a special agent, for example highly heated water gas. It is in all ⁇ cases of great advantage to employ 3u water gas for conveying the pulverulent coal,
- the gas necessary for heating the regenerators is branched off from the main current of gas to be discharged from the apparatus without the use of valves or cocks subjected to the heat.
- the desired distribution of the flow is maintained by a difference in pressure which is caused to act at the point at 4e which the heating gas is branched ofi' from the main current.
- This difference in pressure is capable of regulation by suitable dimensioning of the resistance of the passages or openings traversed by the two currents, and by regulation of the valves or blowers which are situated at points where the same are not subjected to the heat.
- the heat is also supplied after the commencement of the reaction to the gases already formed and to the materials capable of forming gas.
- the supply of heat to the gas-forming materials is preferably effected in gradual manner, as these materials must be brought into the reactive state at a sufficient and even temperature, and by the gradual supply of heat it is accomplished that a substantial cooling does not occur during the course of the reaction, but rather more an increase in the reaction temperature.
- the gas-forming materials are united prior to being heated, or the point of contact of the previously highly heated gas-forming materials is expanded as much as possible by suitable construction or distribution of the openings required.
- Fig. 1, 1 and 2 are heating chambers, which communicate with each other by means of openings?) and 4 and also the passa e 5, which latter simultaneously acts as ust separator.
- the steam on the one hand and-the mixture of water gas and pulverized coal on the other hand are introduced into the lower part of the .chamber 1 at 6 and 7 respectively.
- the apertures 6 and 7 may be changed about.
- a heat exchange checker work is provided partially shown in section for purposes of illustration. The conversion of the material occurs inand behind the heating chamber 1.
- pulverizedcoal passes through the opening 3 into -100 the dust se arator 5, in which the major ortion of t e articles of ash carried along by the as is eposited in the rece tacle 8,
- t e water gas is divided into two Currents.
- the water gas to be removed from the apparatus 1s discharged at 9, whereby the gas employed for conveying the pulverized coal may be returned in circulation to the conveying fan.
- the remaining part of the gas passes through the opening 4 into the chamber 2 for combustion and heating purposes.
- the combustion air is introduced at 10, while at 11 is provided an ash receptacle.
- the cooled com-- bustion gases escape through the opening 12.
- FIG. 2 A modification of the above arrangement is shown in Fig. 2,. in which the regenerators are furnished with a partition extending approximately to the middle and also heat exchange checker work partly'shown in section.
- the partition extends so far' that the extent of heating of the separately heated distillation materials is such that upon the said materials meeting together at the end of the partition in the hbttest portion, Awhich is not divided and which constitutes the continuation of the divided portion, ⁇ a good con centration of the gas hase is ensured.
- the chamber 1 has cooled down, the chamber 2 having been heated,'the apparatus is switched over, the chamber 1 thenL being heated, while the chamber 2 is employed for producing gas.
- regenerators which may then be arranged ⁇ circularly about the chamber or passage 5.
- The'apparatus accordingly makes provision for the connection-of two or more heating chambers at their hottest ends by means of a passage which is incapable of being closed olf, and through which the highly heated mixture of gas and steam, in so far as the same actsas Vheating gas, passes from the 4one chamber into 'the other for the purpose of ance of the remaining valves, etc., ordinari-ly employed, which are situated at points in the pi es not touched by the heat.
- a method of continuously producin water gas from pulverized coal or coke an steam consisting in passing steam and a mixture of art of the produced Water gas with pulveru ent coal or coke to a hot regenerator, producing water gas in said regenerator which thereby serves also as a generator, passing a part of the'produced water gas to a regenerator temporarily not producin gas, passlng off the remainder of the pro uced water gas from the space between said regenerators, passing combustion air to said latter regenerator and heatin the latter re-l generator by combustion of t e gas therein until such time as the llatter regenerator issuiiicientl heated, and then reversing the direction o iiow by introducing the material into the second named regenerator to' form water gas and heating the first named regenerator by causing combustion therein of part of the gas produced in the second named regenerator.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Solid-Fuel Combustion (AREA)
Description
All@ 23, 1932. H. HlLLx-:BRAND ,873,941
PROCESS FOR PRODUCING WATER GAS FROM PULVERIZED COAL IAND STEAM ug- 235 1932 H. HILLE'BRAND L873,941
PROCESS FOR PRODUCING WATER GAS FROM PULVERIZED COAL AND STEAM Patented Aug. 23, 1932 UNITED STATES HERMANN HILLEBRAND, F BERLIN,
PROCESS FOR PRODUCING WATER GAS FROM PULV'ERIZED COAL, AND\STEAM Application led August 30, 1928, Serial No. 303,066, and in. Germany August 24, 1927.
This invention relates to a process of and apparatus for producing water gas from pulverized coal and steam. In the production of water gas, coal and steam are made to react at a temperature of approximately It is known to generate water gas in continuous operation from solid fuels, by conducting the necessary heat to the gas-form- 'o ing materials with the assi-stance of alternately heated regenerators. If, however, pulverized coal or pulverized coke is employed, special measures require to be adopted in order to ensure the use of a cheap, simple and l5 reliable apparatus. A
The heating of the regenerators is eected by means of a part of the current of gas generated. In this manner the possibility is provided of employing an apparatus of compact construction, which is extremely economical from a thermal standpoint and very simple to regulate, and in which no valve members are required which will be subjected to heat. The reaction heat is supplied to the gas-forming materials either before or during their combination in the heater itself, or is introduced by means of a special agent, for example highly heated water gas. It is in all `cases of great advantage to employ 3u water gas for conveying the pulverulent coal,
thus returning a part of the water gas generated back into the circulatory system.
The gas necessary for heating the regenerators is branched off from the main current of gas to be discharged from the apparatus without the use of valves or cocks subjected to the heat. The desired distribution of the flow is maintained by a difference in pressure which is caused to act at the point at 4e which the heating gas is branched ofi' from the main current. This difference in pressure is capable of regulation by suitable dimensioning of the resistance of the passages or openings traversed by the two currents, and by regulation of the valves or blowers which are situated at points where the same are not subjected to the heat.
A This process is improved upon according to the invention by introducing steam or waste gas in circulation to the combustion process upon the alternate heating of the regenerators for the purpose of avoiding excesslve temperatures, so that as little loss of heat results as possible.
Furthermore, according to the invention, the heat is also supplied after the commencement of the reaction to the gases already formed and to the materials capable of forming gas. The supply of heat to the gas-forming materials is preferably effected in gradual manner, as these materials must be brought into the reactive state at a sufficient and even temperature, and by the gradual supply of heat it is accomplished that a substantial cooling does not occur during the course of the reaction, but rather more an increase in the reaction temperature.
For this purpose either the gas-forming materials are united prior to being heated, or the point of contact of the previously highly heated gas-forming materials is expanded as much as possible by suitable construction or distribution of the openings required.
Two forms of embodiment of an apparatus suitable for carrying out the process as above are illustrated in diagrammatical form in the accompanying drawings. All parts having no direct connection with the invention have been omitted from the two figures in gf question for the sake of better comprehension.
Referring now to Fig. 1, 1 and 2 are heating chambers, which communicate with each other by means of openings?) and 4 and also the passa e 5, which latter simultaneously acts as ust separator. In the position shown the steam on the one hand and-the mixture of water gas and pulverized coal on the other hand are introduced into the lower part of the .chamber 1 at 6 and 7 respectively. The apertures 6 and 7 may be changed about. Within thechambers 1 and 2 a heat exchange checker work is provided partially shown in section for purposes of illustration. The conversion of the material occurs inand behind the heating chamber 1. Thewater gas generated, including the quantity ernployed as conveying means for the. pulverizedcoal, passes through the opening 3 into -100 the dust se arator 5, in which the major ortion of t e articles of ash carried along by the as is eposited in the rece tacle 8, In the ust separator or passage 5 t e water gas is divided into two Currents. The water gas to be removed from the apparatus 1s discharged at 9, whereby the gas employed for conveying the pulverized coal may be returned in circulation to the conveying fan. The remaining part of the gas passes through the opening 4 into the chamber 2 for combustion and heating purposes. The combustion air is introduced at 10, while at 11 is provided an ash receptacle. The cooled com-- bustion gases escape through the opening 12.
An additional advantage in connection with the present method is attained by the fact that steam may be added to the combustion air introduced through 10. This is to be preferred in view of the fact that combustion of the current of gas branched'ol at 14 with pure air would result'in very high temperatures, which mi ht easily result Ain rapid wear of the materlal of the generator.
A modification of the above arrangement is shown in Fig. 2,. in which the regenerators are furnished with a partition extending approximately to the middle and also heat exchange checker work partly'shown in section. In this manner a separate heating of the gas acting as conveying means for the coal and of the steam is accomplished, whereby the partition extends so far' that the extent of heating of the separately heated distillation materials is such that upon the said materials meeting together at the end of the partition in the hbttest portion, Awhich is not divided and which constitutes the continuation of the divided portion,`a good con centration of the gas hase is ensured.
By the' division o the regenerators itis also necessary to provide two separate discharge passages 12 for the burnt gas, Aas shown in the drawings.
If the chamber 1 has cooled down, the chamber 2 having been heated,'the apparatus is switched over, the chamber 1 thenL being heated, while the chamber 2 is employed for producing gas.
Obviously in place of the two chambers 1 and 2 it is alsol possible to employ a larger number of regenerators, which may then be arranged `circularly about the chamber or passage 5. l
The'apparatus accordingly makes provision for the connection-of two or more heating chambers at their hottest ends by means of a passage which is incapable of being closed olf, and through which the highly heated mixture of gas and steam, in so far as the same actsas Vheating gas, passes from the 4one chamber into 'the other for the purpose of ance of the remaining valves, etc., ordinari-ly employed, which are situated at points in the pi es not touched by the heat.
t will of course be understood that no restriction is made to the exact forms of em-A bodiment shown, and that various other means may be employed without departing from 'the spirit of the invention.
- What I claim as new and desire to secure by Letters Patent is:
1. A method of continuously producin water gas from pulverized coal or coke an steam, consisting in passing steam and a mixture of art of the produced Water gas with pulveru ent coal or coke to a hot regenerator, producing water gas in said regenerator which thereby serves also as a generator, passing a part of the'produced water gas to a regenerator temporarily not producin gas, passlng off the remainder of the pro uced water gas from the space between said regenerators, passing combustion air to said latter regenerator and heatin the latter re-l generator by combustion of t e gas therein until such time as the llatter regenerator issuiiicientl heated, and then reversing the direction o iiow by introducing the material into the second named regenerator to' form water gas and heating the first named regenerator by causing combustion therein of part of the gas produced in the second named regenerator.
2. The method according to claim 1 including separately passing said steam and the said mixture of water ga's and pulverulentl coal or coke to said regenerator and separate-V ly heating said steam and' gas mixture currents in said regenerator, and combining the separately heated currents in said regenerator at the hottest portion thereof producing the Water gas in said regenerator.
' In testimony whereof I have aixed my signature,
HERMANN IIILIJEBRAND.
los
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1873941X | 1927-08-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1873941A true US1873941A (en) | 1932-08-23 |
Family
ID=7747044
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US303066A Expired - Lifetime US1873941A (en) | 1927-08-24 | 1928-08-30 | Process for producing water gas from pulverized coal and steam |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1873941A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2614915A (en) * | 1947-11-24 | 1952-10-21 | Gulf Research Development Co | Manufacture of synthesis gas |
| US2665200A (en) * | 1948-07-01 | 1954-01-05 | Hydrocarbon Research Inc | Process for the gasification of solid carbonaceous materials |
| US2845335A (en) * | 1952-03-20 | 1958-07-29 | Koppers Co Inc | Regenerative processes and apparatus |
-
1928
- 1928-08-30 US US303066A patent/US1873941A/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2614915A (en) * | 1947-11-24 | 1952-10-21 | Gulf Research Development Co | Manufacture of synthesis gas |
| US2665200A (en) * | 1948-07-01 | 1954-01-05 | Hydrocarbon Research Inc | Process for the gasification of solid carbonaceous materials |
| US2845335A (en) * | 1952-03-20 | 1958-07-29 | Koppers Co Inc | Regenerative processes and apparatus |
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