US1750796A - Alloy, and cutting tool made therefrom - Google Patents
Alloy, and cutting tool made therefrom Download PDFInfo
- Publication number
- US1750796A US1750796A US53429A US5342925A US1750796A US 1750796 A US1750796 A US 1750796A US 53429 A US53429 A US 53429A US 5342925 A US5342925 A US 5342925A US 1750796 A US1750796 A US 1750796A
- Authority
- US
- United States
- Prior art keywords
- alloy
- tungsten
- boron
- chromium
- cobalt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910045601 alloy Inorganic materials 0.000 title description 34
- 239000000956 alloy Substances 0.000 title description 34
- 229910052721 tungsten Inorganic materials 0.000 description 22
- 239000010937 tungsten Substances 0.000 description 22
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 21
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 20
- 229910052796 boron Inorganic materials 0.000 description 20
- 239000011651 chromium Substances 0.000 description 17
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 16
- 229910052804 chromium Inorganic materials 0.000 description 16
- 229910017052 cobalt Inorganic materials 0.000 description 14
- 239000010941 cobalt Substances 0.000 description 14
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000010959 steel Substances 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910000521 B alloy Inorganic materials 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910001347 Stellite Inorganic materials 0.000 description 1
- 229910001080 W alloy Inorganic materials 0.000 description 1
- CPJYFACXEHYLFS-UHFFFAOYSA-N [B].[W].[Co] Chemical compound [B].[W].[Co] CPJYFACXEHYLFS-UHFFFAOYSA-N 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- -1 boron carbid Chemical class 0.000 description 1
- PALQHNLJJQMCIQ-UHFFFAOYSA-N boron;manganese Chemical compound [Mn]#B PALQHNLJJQMCIQ-UHFFFAOYSA-N 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- NUEWEVRJMWXXFB-UHFFFAOYSA-N chromium(iii) boride Chemical compound [Cr]=[B] NUEWEVRJMWXXFB-UHFFFAOYSA-N 0.000 description 1
- AHICWQREWHDHHF-UHFFFAOYSA-N chromium;cobalt;iron;manganese;methane;molybdenum;nickel;silicon;tungsten Chemical compound C.[Si].[Cr].[Mn].[Fe].[Co].[Ni].[Mo].[W] AHICWQREWHDHHF-UHFFFAOYSA-N 0.000 description 1
- JPNWDVUTVSTKMV-UHFFFAOYSA-N cobalt tungsten Chemical compound [Co].[W] JPNWDVUTVSTKMV-UHFFFAOYSA-N 0.000 description 1
- 239000012612 commercial material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/07—Alloys based on nickel or cobalt based on cobalt
Definitions
- the invention comprises non-rusting alloys of great hardness, suitable for use in making lathe and other machine tools for cutting metals, and for manyother purposes.
- the alloys of the invention may be regarded as comprising a base of cobalt and tungsten to which has been added boron and in some cases chromium also.
- the binary alloys consisting substantially entirely of cobalt and tungsten, with the tungsten not above 30%, are forgeable and are suitable material for wood-working tools, and in general for such tools as are usually made of mild tempered steels.
- the Brinell hardness of this alloy was 600 and the scleroscope 63.
- the boron content When no chromium, or a very small quantity is added, the boron content may be as high as 1.25%. With a proper boron content 1 the chromium content may be as high as 12%. However, the maximum boron and chromium contents mentioned above should not be present in a single alloy,'as the use of both the hardening agents in such quantities causes the alloy to be too brittle. The maximum quantity of boron which can profitably be added when the chromium content is around 12% seems to be a little less than 1%.
- the-tungsten shall not exceed 50% in order that the melting point of the alloy may not be too high.
- alloys with tungsten in excess of 50% have good cutting qualities and I do not intend to restrict myself to tungsten contents of less than 50%.
- chromium is present in considerable quantities the tungsten should be somewhat lower than' would otherwise be desirable, in order that the alloy may not be too brittle, but the tungsten content should always be above 35% when maximum hardness is desired.
- the carbon should not exceed 1.5% and preferably should be below 1.0%. Excessive quantities of carbon in the alloy cause it to be weak and brittle. v
- the alloy can be made without special difliculty by melting together commercial grades of cobalt, tungsten and chromium or their alloys with each other.
- Theraw materials must of course be suitably low in carbon,
- the commercial materials which are available always contain small amounts of impurities such as carbon, manganese, iron and slhcon, and, in the case ofcobalt, nickel.
- the quantitles of these impurltles introduced by reasonably pure raw materials or from i detrimental effect on the final alloy. If de-' other adventitious sources have no serious sired, a small addition of manganese may be used for deoxidizing the alloy.
- the boron may be added to the charge for melting as a compound or alloy such as boron carbid,
- a tool suitable for high-speed cutting of steel composed of an alloy containing 40% to 50% tungsten, 8% to 12% chromium, and I 0.5% to 1.0% boron, with the remainder chiefly cobalt.
- An alloy suitable as material for tools for the high-speed cutting of steel said alloy containing at least of cobalt; at least of tungsten, not more than 12% of chromium, and boron 0.2% to 1.25%.
- An alloy suitable as material for tools for the high-speed cutting of steel said alloy containing at least 30% of cobalt; at least 35% of tungsten; not more than 12% of chromium; and 0.5% to 1.0% of boron; and being substantially free from nickel.
- a strongly chilling mold such as a T graphite mold, may be used. If, however,
- the alloy is of a composition adapted to develop a hardness approaching the maximum
- Alloys comprised in my invention exhibit a high degree of red-hardness, by which is meant that their hardness is. almost unirnpaired at temperatures up to redness. Tlns property is indispensible in tools for highspeed cutting, and the superiority ofthealloysof the invention over alloys of compin the, former.
- Thebest lathe tools which I have thus far been able to make from the'new alloys described herein are of the following composiarable composition but 1 free from boron is chiefly due to the greater red-hardnessof tion:
- An alloy consisting chiefly of tungsten, cobalt, and chromium, and containing 35%to 50% tungsten, upward of 30% cobalt, a substantial proportion of chromium less than 12%, and between 0.2% and 1.25% of boron.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
Description
Patented Mai. 18, 1930 UNITED STATES PATENT OFFICE:
BURNHAM E. FIELD, OF DOUGLASTON, NEW YORK, ASSIGNOR T HAYNES STELLITE COMPANY, A CORIORATION OF INDIANA ALLOY, AND CUTTING moor. MADE 'rnnnnrnom No Drawing. Application filed August 29, 1925, Serial No. 53,429. Renewed l'annary ll, 1929. P
The invention comprises non-rusting alloys of great hardness, suitable for use in making lathe and other machine tools for cutting metals, and for manyother purposes.
The alloys of the invention may be regarded as comprising a base of cobalt and tungsten to which has been added boron and in some cases chromium also.
The binary alloys consisting substantially entirely of cobalt and tungsten, with the tungsten not above 30%, are forgeable and are suitable material for wood-working tools, and in general for such tools as are usually made of mild tempered steels.
ing the tungsten content of such alloys their hardness is somewhat increased and they become non-forgeable, but even with the tungsten as high as 50% the metal is too soft to be used for cutting any material harder than the softest steels. With 50% tungsten the melting point of the alloy is so high that it is not advantageous to increase the tungsten content further.
I have found that a small content of boron,
- for example 0.2% to 1.25%, greatly increases the hardness of cobalt-tungsten alloys, and if the constituent elements of the boron-containing alloy are properly proportioned the alloy is a suitable material for tools for the high-speed cutting of steel and cast iron.
The hardening effect of the boron is well illustrated by the following comparison: An
alloy containing 45% tungsten with most of the balance cobalt and no boron had a Brinell hardness of 444 and a scleroscope hardness of 43. Another alloy which d-ifiered from the first principally in that it contained 0.66% boron, had a Brinell hardness of 57 8 and a scleroscope hardness of 56. A third similar 1 The cobalt-tungsten-boron alloys are fur- On increas- Per cent W 40 78 Cr 11.51 Bo 0.61 C- 0.77
with the remainder chiefly cobalt. The Brinell hardness of this alloy was 600 and the scleroscope 63.
When no chromium, or a very small quantity is added, the boron content may be as high as 1.25%. With a proper boron content 1 the chromium content may be as high as 12%. However, the maximum boron and chromium contents mentioned above should not be present in a single alloy,'as the use of both the hardening agents in such quantities causes the alloy to be too brittle. The maximum quantity of boron which can profitably be added when the chromium content is around 12% seems to be a little less than 1%.
I prefer that the-tungsten shall not exceed 50% in order that the melting point of the alloy may not be too high. However, alloys with tungsten in excess of 50% have good cutting qualities and I do not intend to restrict myself to tungsten contents of less than 50%. When chromium is present in considerable quantities the tungsten should be somewhat lower than' would otherwise be desirable, in order that the alloy may not be too brittle, but the tungsten content should always be above 35% when maximum hardness is desired. 1
The carbon should not exceed 1.5% and preferably should be below 1.0%. Excessive quantities of carbon in the alloy cause it to be weak and brittle. v
The alloy can be made without special difliculty by melting together commercial grades of cobalt, tungsten and chromium or their alloys with each other. Theraw materials must of course be suitably low in carbon, The commercial materials which are available always contain small amounts of impurities such as carbon, manganese, iron and slhcon, and, in the case ofcobalt, nickel. The quantitles of these impurltles introduced by reasonably pure raw materials or from i detrimental effect on the final alloy. If de-' other adventitious sources have no serious sired, a small addition of manganese may be used for deoxidizing the alloy. The boron may be added to the charge for melting as a compound or alloy such as boron carbid,
, manganese-boron, or chromium-boron.
i To develop the hardness of the alloys they are best cast in highly heat-conductive molds when cutting tools are to be made. If the composition to be cast is such that there is no fear that the resulting casting will be too 4. A tool suitable for high-speed cutting of steel composed of an alloy containing 40% to 50% tungsten, 8% to 12% chromium, and I 0.5% to 1.0% boron, with the remainder chiefly cobalt.
5. An alloy suitable as material for tools for the high-speed cutting of steel, said alloy containing at least of cobalt; at least of tungsten, not more than 12% of chromium, and boron 0.2% to 1.25%.
6. An alloy suitable as material for tools for the high-speed cutting of steel, said alloy containing at least 30% of cobalt; at least 35% of tungsten; not more than 12% of chromium; and 0.5% to 1.0% of boron; and being substantially free from nickel.
In testimony whereof, I aflix my signature.
, v BURNHAM E. FIELD.
brittle, a strongly chilling mold, such as a T graphite mold, may be used. If, however,
the alloy is of a composition adapted to develop a hardness approaching the maximum,
a mold of somewhat less chilling capacity,
such as a carbon mold, is preferably used.
Alloys comprised in my invention exhibit a high degree of red-hardness, by which is meant that their hardness is. almost unirnpaired at temperatures up to redness. Tlns property is indispensible in tools for highspeed cutting, and the superiority ofthealloysof the invention over alloys of compin the, former. I
. Thebest lathe tools which I have thus far been able to make from the'new alloys described herein are of the following composiarable composition but 1 free from boron is chiefly due to the greater red-hardnessof tion:
'rl-mgstmu 40-50% Chromium 8-12% V v ,Boron. '0'.51.0%,
with the remainder chiefly cobalt.
7 I I-claim: v
, 1. An alloy consisting chiefly of tungsten,
.cobalt, and chromium, and containing upward of 35% tungsten, upward of 30% cobalt, a substantial proportion of chromium less than 12%, and between 0.2% and 1.25% of boron. i Y
2. An alloy consisting chiefly of tungsten, cobalt, and chromium, and containing 35%to 50% tungsten, upward of 30% cobalt, a substantial proportion of chromium less than 12%, and between 0.2% and 1.25% of boron.
3. An alloy containing 40% to 50% tungsten, 8% to- 12% chromium, and0.5% to 1.0%
boron, with the remainder chiefly cobalt.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US53429A US1750796A (en) | 1925-08-29 | 1925-08-29 | Alloy, and cutting tool made therefrom |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US53429A US1750796A (en) | 1925-08-29 | 1925-08-29 | Alloy, and cutting tool made therefrom |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1750796A true US1750796A (en) | 1930-03-18 |
Family
ID=21984156
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US53429A Expired - Lifetime US1750796A (en) | 1925-08-29 | 1925-08-29 | Alloy, and cutting tool made therefrom |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1750796A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2798474A (en) * | 1951-09-18 | 1957-07-09 | Deutsche Edelstahlwerke Ag | Hard-metal containing mixtures and processes of applying them to supporting bodies and supporting bodies so treated |
-
1925
- 1925-08-29 US US53429A patent/US1750796A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2798474A (en) * | 1951-09-18 | 1957-07-09 | Deutsche Edelstahlwerke Ag | Hard-metal containing mixtures and processes of applying them to supporting bodies and supporting bodies so treated |
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