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US1750796A - Alloy, and cutting tool made therefrom - Google Patents

Alloy, and cutting tool made therefrom Download PDF

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Publication number
US1750796A
US1750796A US53429A US5342925A US1750796A US 1750796 A US1750796 A US 1750796A US 53429 A US53429 A US 53429A US 5342925 A US5342925 A US 5342925A US 1750796 A US1750796 A US 1750796A
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US
United States
Prior art keywords
alloy
tungsten
boron
chromium
cobalt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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US53429A
Inventor
Burnham E Field
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HAYNES STELLITE Co
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HAYNES STELLITE CO
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Publication date
Application filed by HAYNES STELLITE CO filed Critical HAYNES STELLITE CO
Priority to US53429A priority Critical patent/US1750796A/en
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Publication of US1750796A publication Critical patent/US1750796A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/07Alloys based on nickel or cobalt based on cobalt

Definitions

  • the invention comprises non-rusting alloys of great hardness, suitable for use in making lathe and other machine tools for cutting metals, and for manyother purposes.
  • the alloys of the invention may be regarded as comprising a base of cobalt and tungsten to which has been added boron and in some cases chromium also.
  • the binary alloys consisting substantially entirely of cobalt and tungsten, with the tungsten not above 30%, are forgeable and are suitable material for wood-working tools, and in general for such tools as are usually made of mild tempered steels.
  • the Brinell hardness of this alloy was 600 and the scleroscope 63.
  • the boron content When no chromium, or a very small quantity is added, the boron content may be as high as 1.25%. With a proper boron content 1 the chromium content may be as high as 12%. However, the maximum boron and chromium contents mentioned above should not be present in a single alloy,'as the use of both the hardening agents in such quantities causes the alloy to be too brittle. The maximum quantity of boron which can profitably be added when the chromium content is around 12% seems to be a little less than 1%.
  • the-tungsten shall not exceed 50% in order that the melting point of the alloy may not be too high.
  • alloys with tungsten in excess of 50% have good cutting qualities and I do not intend to restrict myself to tungsten contents of less than 50%.
  • chromium is present in considerable quantities the tungsten should be somewhat lower than' would otherwise be desirable, in order that the alloy may not be too brittle, but the tungsten content should always be above 35% when maximum hardness is desired.
  • the carbon should not exceed 1.5% and preferably should be below 1.0%. Excessive quantities of carbon in the alloy cause it to be weak and brittle. v
  • the alloy can be made without special difliculty by melting together commercial grades of cobalt, tungsten and chromium or their alloys with each other.
  • Theraw materials must of course be suitably low in carbon,
  • the commercial materials which are available always contain small amounts of impurities such as carbon, manganese, iron and slhcon, and, in the case ofcobalt, nickel.
  • the quantitles of these impurltles introduced by reasonably pure raw materials or from i detrimental effect on the final alloy. If de-' other adventitious sources have no serious sired, a small addition of manganese may be used for deoxidizing the alloy.
  • the boron may be added to the charge for melting as a compound or alloy such as boron carbid,
  • a tool suitable for high-speed cutting of steel composed of an alloy containing 40% to 50% tungsten, 8% to 12% chromium, and I 0.5% to 1.0% boron, with the remainder chiefly cobalt.
  • An alloy suitable as material for tools for the high-speed cutting of steel said alloy containing at least of cobalt; at least of tungsten, not more than 12% of chromium, and boron 0.2% to 1.25%.
  • An alloy suitable as material for tools for the high-speed cutting of steel said alloy containing at least 30% of cobalt; at least 35% of tungsten; not more than 12% of chromium; and 0.5% to 1.0% of boron; and being substantially free from nickel.
  • a strongly chilling mold such as a T graphite mold, may be used. If, however,
  • the alloy is of a composition adapted to develop a hardness approaching the maximum
  • Alloys comprised in my invention exhibit a high degree of red-hardness, by which is meant that their hardness is. almost unirnpaired at temperatures up to redness. Tlns property is indispensible in tools for highspeed cutting, and the superiority ofthealloysof the invention over alloys of compin the, former.
  • Thebest lathe tools which I have thus far been able to make from the'new alloys described herein are of the following composiarable composition but 1 free from boron is chiefly due to the greater red-hardnessof tion:
  • An alloy consisting chiefly of tungsten, cobalt, and chromium, and containing 35%to 50% tungsten, upward of 30% cobalt, a substantial proportion of chromium less than 12%, and between 0.2% and 1.25% of boron.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Cutting Tools, Boring Holders, And Turrets (AREA)

Description

Patented Mai. 18, 1930 UNITED STATES PATENT OFFICE:
BURNHAM E. FIELD, OF DOUGLASTON, NEW YORK, ASSIGNOR T HAYNES STELLITE COMPANY, A CORIORATION OF INDIANA ALLOY, AND CUTTING moor. MADE 'rnnnnrnom No Drawing. Application filed August 29, 1925, Serial No. 53,429. Renewed l'annary ll, 1929. P
The invention comprises non-rusting alloys of great hardness, suitable for use in making lathe and other machine tools for cutting metals, and for manyother purposes.
The alloys of the invention may be regarded as comprising a base of cobalt and tungsten to which has been added boron and in some cases chromium also.
The binary alloys consisting substantially entirely of cobalt and tungsten, with the tungsten not above 30%, are forgeable and are suitable material for wood-working tools, and in general for such tools as are usually made of mild tempered steels.
ing the tungsten content of such alloys their hardness is somewhat increased and they become non-forgeable, but even with the tungsten as high as 50% the metal is too soft to be used for cutting any material harder than the softest steels. With 50% tungsten the melting point of the alloy is so high that it is not advantageous to increase the tungsten content further.
I have found that a small content of boron,
- for example 0.2% to 1.25%, greatly increases the hardness of cobalt-tungsten alloys, and if the constituent elements of the boron-containing alloy are properly proportioned the alloy is a suitable material for tools for the high-speed cutting of steel and cast iron.
The hardening effect of the boron is well illustrated by the following comparison: An
alloy containing 45% tungsten with most of the balance cobalt and no boron had a Brinell hardness of 444 and a scleroscope hardness of 43. Another alloy which d-ifiered from the first principally in that it contained 0.66% boron, had a Brinell hardness of 57 8 and a scleroscope hardness of 56. A third similar 1 The cobalt-tungsten-boron alloys are fur- On increas- Per cent W 40 78 Cr 11.51 Bo 0.61 C- 0.77
with the remainder chiefly cobalt. The Brinell hardness of this alloy was 600 and the scleroscope 63.
When no chromium, or a very small quantity is added, the boron content may be as high as 1.25%. With a proper boron content 1 the chromium content may be as high as 12%. However, the maximum boron and chromium contents mentioned above should not be present in a single alloy,'as the use of both the hardening agents in such quantities causes the alloy to be too brittle. The maximum quantity of boron which can profitably be added when the chromium content is around 12% seems to be a little less than 1%.
I prefer that the-tungsten shall not exceed 50% in order that the melting point of the alloy may not be too high. However, alloys with tungsten in excess of 50% have good cutting qualities and I do not intend to restrict myself to tungsten contents of less than 50%. When chromium is present in considerable quantities the tungsten should be somewhat lower than' would otherwise be desirable, in order that the alloy may not be too brittle, but the tungsten content should always be above 35% when maximum hardness is desired. 1
The carbon should not exceed 1.5% and preferably should be below 1.0%. Excessive quantities of carbon in the alloy cause it to be weak and brittle. v
The alloy can be made without special difliculty by melting together commercial grades of cobalt, tungsten and chromium or their alloys with each other. Theraw materials must of course be suitably low in carbon, The commercial materials which are available always contain small amounts of impurities such as carbon, manganese, iron and slhcon, and, in the case ofcobalt, nickel. The quantitles of these impurltles introduced by reasonably pure raw materials or from i detrimental effect on the final alloy. If de-' other adventitious sources have no serious sired, a small addition of manganese may be used for deoxidizing the alloy. The boron may be added to the charge for melting as a compound or alloy such as boron carbid,
, manganese-boron, or chromium-boron.
i To develop the hardness of the alloys they are best cast in highly heat-conductive molds when cutting tools are to be made. If the composition to be cast is such that there is no fear that the resulting casting will be too 4. A tool suitable for high-speed cutting of steel composed of an alloy containing 40% to 50% tungsten, 8% to 12% chromium, and I 0.5% to 1.0% boron, with the remainder chiefly cobalt.
5. An alloy suitable as material for tools for the high-speed cutting of steel, said alloy containing at least of cobalt; at least of tungsten, not more than 12% of chromium, and boron 0.2% to 1.25%.
6. An alloy suitable as material for tools for the high-speed cutting of steel, said alloy containing at least 30% of cobalt; at least 35% of tungsten; not more than 12% of chromium; and 0.5% to 1.0% of boron; and being substantially free from nickel.
In testimony whereof, I aflix my signature.
, v BURNHAM E. FIELD.
brittle, a strongly chilling mold, such as a T graphite mold, may be used. If, however,
the alloy is of a composition adapted to develop a hardness approaching the maximum,
a mold of somewhat less chilling capacity,
such as a carbon mold, is preferably used.
Alloys comprised in my invention exhibit a high degree of red-hardness, by which is meant that their hardness is. almost unirnpaired at temperatures up to redness. Tlns property is indispensible in tools for highspeed cutting, and the superiority ofthealloysof the invention over alloys of compin the, former. I
. Thebest lathe tools which I have thus far been able to make from the'new alloys described herein are of the following composiarable composition but 1 free from boron is chiefly due to the greater red-hardnessof tion:
'rl-mgstmu 40-50% Chromium 8-12% V v ,Boron. '0'.51.0%,
with the remainder chiefly cobalt.
7 I I-claim: v
, 1. An alloy consisting chiefly of tungsten,
.cobalt, and chromium, and containing upward of 35% tungsten, upward of 30% cobalt, a substantial proportion of chromium less than 12%, and between 0.2% and 1.25% of boron. i Y
2. An alloy consisting chiefly of tungsten, cobalt, and chromium, and containing 35%to 50% tungsten, upward of 30% cobalt, a substantial proportion of chromium less than 12%, and between 0.2% and 1.25% of boron.
3. An alloy containing 40% to 50% tungsten, 8% to- 12% chromium, and0.5% to 1.0%
boron, with the remainder chiefly cobalt.
US53429A 1925-08-29 1925-08-29 Alloy, and cutting tool made therefrom Expired - Lifetime US1750796A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2798474A (en) * 1951-09-18 1957-07-09 Deutsche Edelstahlwerke Ag Hard-metal containing mixtures and processes of applying them to supporting bodies and supporting bodies so treated

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2798474A (en) * 1951-09-18 1957-07-09 Deutsche Edelstahlwerke Ag Hard-metal containing mixtures and processes of applying them to supporting bodies and supporting bodies so treated

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