US1638057A - Process for recovering vanadium from petroleum hydrocarbons - Google Patents
Process for recovering vanadium from petroleum hydrocarbons Download PDFInfo
- Publication number
- US1638057A US1638057A US55171A US5517125A US1638057A US 1638057 A US1638057 A US 1638057A US 55171 A US55171 A US 55171A US 5517125 A US5517125 A US 5517125A US 1638057 A US1638057 A US 1638057A
- Authority
- US
- United States
- Prior art keywords
- vanadium
- petroleum hydrocarbons
- compounds
- oils
- petroleum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052720 vanadium Inorganic materials 0.000 title description 18
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 title description 18
- 229930195733 hydrocarbon Natural products 0.000 title description 12
- 150000002430 hydrocarbons Chemical class 0.000 title description 12
- 238000000034 method Methods 0.000 title description 12
- 239000003208 petroleum Substances 0.000 title description 7
- 229940045605 vanadium Drugs 0.000 description 17
- 239000003921 oil Substances 0.000 description 13
- 239000000463 material Substances 0.000 description 12
- 150000003682 vanadium compounds Chemical class 0.000 description 10
- 239000002250 absorbent Substances 0.000 description 9
- 230000002745 absorbent Effects 0.000 description 9
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- 238000002485 combustion reaction Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000000567 combustion gas Substances 0.000 description 3
- 239000003209 petroleum derivative Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000006681 Combes synthesis reaction Methods 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003818 cinder Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000002006 petroleum coke Substances 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 239000010880 spent shale Substances 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G31/00—Compounds of vanadium
Definitions
- petroleum hydrocarbons and. refers more particularly to a process in which compounds 6 of vanadium are extracted from petroleum products.
- present process has to do primarily with a method of extracting vanadium by consumption of the volatile and oxidizable petroleum products by the action of heat, the
- Vanadium being recovered as an oxide or other vanadium compound by deposition.
- vanadium compounds are usually more prevalent in the poorer grades of oil, i. e., those oils having a high sulphur content such as the Mexican oils,'particularly Panuco crude, Persian crude and certain of the high sulphur bearing Ohio oils. These oils do not make particularl good cracking stock and are, to
- An absorbent material is used with the best effect by being interposed in the form of a tower in the path of the combustion gases so that the gases are directed through the tower and through the absorbent material in their travel to phere.
- any vanadium content may be recovered from the exhaust gases by interposing an absorbent body of activated carbon coke or other relatively inert absorbent materials in the exhaust line.
- the vanadium is normally deposited as a vanadium oxide which is easily dissolved from the absorbent material with a proper solvent.
- absorptive materials which have been found effective in the recovery of this' material are kaolins, such as bauxite,
- '- and colloidal clays including bentonite and metallic vanadium. which may be extracted in a relatively pure state by imply exhausting the hydrocarbon materials from the oil by 'cmnbustion and extracting the metallic vanadium by deposition of the metallic compounds in an absorbent body and subsequently dissolving the metallic compound from the absorbent material.
- a process for recovering vanadium from petroleum hydrocarbons consisting in exhausting hydrocarbon products by combustion and collecting the deposited vanadium compounds in an absorptive material.
- a process for. recovering vanadium from petroleum hydrocarbons consisting in exhausting hydrocarbon products by combustion and collecting the deposited vanadium compounds in an absorptive material and extracting the vanadium compounds 5 therefrom.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Manufacture And Refinement Of Metals (AREA)
Description
Patented Aug. 9, 1927.
UNITED STATES PATENT OFFICE."
ALFRED OBERLE, OF KANSAS CITY, MISSOURI, ASSIGNOR OF ONE-HALE T THOMAS E. SCOFIELD, OF KANSAS CITY, MISSOURI.
PROCESS FOR RECOVERING VAN ADIUM FROM PETROLEUM H YDROCARBONS.
' No Drawing.
petroleum hydrocarbons, and. refers more particularly to a process in which compounds 6 of vanadium are extracted from petroleum products.
v This application is a continuation in part of a previous application Serial No. 722,309 filed June 25, 1924.
In myprevious application I described a process for recovering vanadium from pctroleum residue such as petroleum coke and heavy residual oils or carbonaceous materials such as cokey substances resulting from the cracking of petroleum hydrocarbons. The
present process has to do primarily with a method of extracting vanadium by consumption of the volatile and oxidizable petroleum products by the action of heat, the
Vanadium being recovered as an oxide or other vanadium compound by deposition.
In my prior application, I described the process of leaching the vanadium compounds from the petroleum residue with a vanadium solvent, but where vanadium is desired to be recovered from certain hydrocarbon oils.
whibh are to be burned as fuel as certain of the heavy Mexican, Ohio or l ersian oils, the hydrocarbon products are practically completely consumed in the combustion of the oil and to recover the vanadium compounds, it is necessary to devise some method of obstructing or retarding the metal compounds by means of a deposit screen or by the use of an absorptive agent such as coke, cinders, activated carbonaceous material, ground or broken up slag, spent shale, diatomaceous earth or other absorptive substances which would serve to extract the vanadium compounds may bedissfil'ved from the absorbent material.
In experimenting with hydrocarbons, it
4 has been my experience that the vanadium compounds are usually more prevalent in the poorer grades of oil, i. e., those oils having a high sulphur content such as the Mexican oils,'particularly Panuco crude, Persian crude and certain of the high sulphur bearing Ohio oils. These oils do not make particularl good cracking stock and are, to
a consi rable extent, used as burning oils vanadium compounds from the combustion gases. Subsequent to this separatign the..-
Application filed September 8, 1925. Serial No. 55,171.
so that the recovery of vanadium compounds is best effected by a the consumption of pounds which mag process in which during the oil vanadium combe carried ofi' mechanically in the form 0 fine particles in the combustion gases, are arrested and deposited in an absorbent body or upon specially preparedwlre screens or any other type of 0bstruction devices which effectively prevent the passage of the metallic Vanadium and a cause the same to be deposited in the'ab'sorbent material to be later recovered by extraction with a solvent.
An absorbent material is used with the best effect by being interposed in the form of a tower in the path of the combustion gases so that the gases are directed through the tower and through the absorbent material in their travel to phere.
Where oils containing vanadium are used in internal combustion engines, such as heavy types of Diesel engines, any vanadium content may be recovered from the exhaust gases by interposing an absorbent body of activated carbon coke or other relatively inert absorbent materials in the exhaust line. The vanadium is normally deposited as a vanadium oxide which is easily dissolved from the absorbent material with a proper solvent.
-Among other absorptive materials which have been found effective in the recovery of this' material are kaolins, such as bauxite,
'- and colloidal clays, including bentonite and metallic vanadium. which may be extracted in a relatively pure state by imply exhausting the hydrocarbon materials from the oil by 'cmnbustion and extracting the metallic vanadium by deposition of the metallic compounds in an absorbent body and subsequently dissolving the metallic compound from the absorbent material.
I claim as my invention:
1. A process for recovering vanadium from petroleum hydrocarbons, consisting in exhausting hydrocarbon products by combustion and collecting the deposited vanadium compounds in an absorptive material.
2. A process for. recovering vanadium from petroleum hydrocarbons, consisting in exhausting hydrocarbon products by combustion and collecting the deposited vanadium compounds in an absorptive material and extracting the vanadium compounds 5 therefrom.
3. A process for recovering vanadium from petroleum hydrocarbons, conslstlng in from the absorptive material with a solvent.
' ALFRED OBER-LE.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US55171A US1638057A (en) | 1925-09-08 | 1925-09-08 | Process for recovering vanadium from petroleum hydrocarbons |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US55171A US1638057A (en) | 1925-09-08 | 1925-09-08 | Process for recovering vanadium from petroleum hydrocarbons |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1638057A true US1638057A (en) | 1927-08-09 |
Family
ID=21996097
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US55171A Expired - Lifetime US1638057A (en) | 1925-09-08 | 1925-09-08 | Process for recovering vanadium from petroleum hydrocarbons |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1638057A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3522001A (en) * | 1968-01-22 | 1970-07-28 | Universal Oil Prod Co | Recovery of metals from carbonaceous material |
| US3529944A (en) * | 1967-01-23 | 1970-09-22 | Ashland Oil Inc | Process for clarifying and stabilizing hydrocarbon liquids |
| US4110398A (en) * | 1977-04-08 | 1978-08-29 | Uop Inc. | Metal separation from dragstream material of refining process |
| US6284214B1 (en) * | 1998-06-09 | 2001-09-04 | Marathon Ashland Petroleum Llc | Low or no slag molten metal processing of coke containing vanadium and sulfur |
-
1925
- 1925-09-08 US US55171A patent/US1638057A/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3529944A (en) * | 1967-01-23 | 1970-09-22 | Ashland Oil Inc | Process for clarifying and stabilizing hydrocarbon liquids |
| US3522001A (en) * | 1968-01-22 | 1970-07-28 | Universal Oil Prod Co | Recovery of metals from carbonaceous material |
| US4110398A (en) * | 1977-04-08 | 1978-08-29 | Uop Inc. | Metal separation from dragstream material of refining process |
| US6284214B1 (en) * | 1998-06-09 | 2001-09-04 | Marathon Ashland Petroleum Llc | Low or no slag molten metal processing of coke containing vanadium and sulfur |
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