US1542440A - Iron alloy - Google Patents
Iron alloy Download PDFInfo
- Publication number
- US1542440A US1542440A US515571A US51557121A US1542440A US 1542440 A US1542440 A US 1542440A US 515571 A US515571 A US 515571A US 51557121 A US51557121 A US 51557121A US 1542440 A US1542440 A US 1542440A
- Authority
- US
- United States
- Prior art keywords
- sulfur
- iron
- iron alloy
- alloy
- manganese
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910000640 Fe alloy Inorganic materials 0.000 title description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 15
- 229910052717 sulfur Inorganic materials 0.000 description 15
- 239000011593 sulfur Substances 0.000 description 14
- 238000005266 casting Methods 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 7
- 239000011572 manganese Substances 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 229910052748 manganese Inorganic materials 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- 229910001296 Malleable iron Inorganic materials 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 229910001037 White iron Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052752 metalloid Inorganic materials 0.000 description 2
- 150000002738 metalloids Chemical class 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- 229910000805 Pig iron Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 241000282887 Suidae Species 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C37/00—Cast-iron alloys
Definitions
- The'present invention relates to alloys of iron and will be fully understood from the following description thereof.
- the iron alloy of the present invention contains iron, with carbon in excess of 1.5%, sulfur more than 0.30%, the total metalloids being sufiiciently low to produce a white iron on casting.
- the proportion of manganese is materially less than the proportion ,of sulphur, being, for example, less than 0.10%.
- An alloy has been prepared according to the present invention containing, with iron, 0.50% silicon, 0.50% sulfur, 0.15% phosphorus, 0.05% manganese and 2.00 to 2.25% total carbon.
- This metal may be cast in accordance with the usual malleable casting practice, producing white castings which are tough and have a high tensile strength in the order 55,000 lbs. per square inch. Such castings are dense andhomogeneous, the castings having a clear ring. In this state the metal is very hard and must be ground.
- the cast metal may be annealed, for example, at temperatures of 1500 to 1800 F. and for a shorter time than is customary in malleable practice.
- the annealed metal loses its hardness sufiiciently so that it can be machined and its tensile strength rises to about 85,000 lbs. per square inch. In this state the metal may be surface hardened by heating and quenching.
- the metal may be employed for the manu facture of cast gears, and in general may be substituted for steel castings.
- the alloy anordinary pig iron, for example, one running about 3.50% C, 1% S1, 0.05% S, 0.02% P and 0.50% Mn may be melted as in malleable practice, and sulfur added thereto suflicient to bring the sulfur in the finished melt to above 0.30%, say to 0.50%.
- the sulfur is preferably added as ferrous sulfide. The sulfur causes the elimination of a considerable part of the manganese, apparently combining therewith to form sulfides which pass into the slag. Some of the carbon and some of the silicon areoxidized, so that the resulting alloy may contain 0.50% Si, 0.50% s, 0.15% P, 0.05%. Mn and 2 to 2.25% C.
- a homogeneous, dense, tough, malleable iron casting containing 0.50% sulfur, 0.50% silicon, 0.15% phosphorus, 0.05% manganese and 2.00 to 2.25% carbon, and
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
Description
Patented June 16, 1925.
UNITED STATES PATENT OFFICE.
- GEORGE A. DRYSDALE, OF INDIANAPOLIS, INDIANA, ASSIGNOR TO GEORGE A.
OHRITTON, OF CHICAGO, ILLINOIS.
IRON ALLOY.
No Drawing.-
To all whom it may concern:
Be it known that I, GEORGE A. DRYSDALE, a citizen of the United States, residing at Indianapolis, in the county of Marion and State of Indiana, have invented a new and useful Improvement in Iron Alloys, of which the following is a specification.
The'present invention relates to alloys of iron and will be fully understood from the following description thereof.
The iron alloy of the present invention contains iron, with carbon in excess of 1.5%, sulfur more than 0.30%, the total metalloids being sufiiciently low to produce a white iron on casting. The proportion of manganese is materially less than the proportion ,of sulphur, being, for example, less than 0.10%. An alloy has been prepared according to the present invention containing, with iron, 0.50% silicon, 0.50% sulfur, 0.15% phosphorus, 0.05% manganese and 2.00 to 2.25% total carbon. This metal may be cast in accordance with the usual malleable casting practice, producing white castings which are tough and have a high tensile strength in the order 55,000 lbs. per square inch. Such castings are dense andhomogeneous, the castings having a clear ring. In this state the metal is very hard and must be ground.
The cast metal may be annealed, for example, at temperatures of 1500 to 1800 F. and for a shorter time than is customary in malleable practice. The annealed metal loses its hardness sufiiciently so that it can be machined and its tensile strength rises to about 85,000 lbs. per square inch. In this state the metal may be surface hardened by heating and quenching.
The metal may be employed for the manu facture of cast gears, and in general may be substituted for steel castings.
Application filed November 16, 1921. Serial No. 515,571.
In making the alloy anordinary pig iron, for example, one running about 3.50% C, 1% S1, 0.05% S, 0.02% P and 0.50% Mn may be melted as in malleable practice, and sulfur added thereto suflicient to bring the sulfur in the finished melt to above 0.30%, say to 0.50%. The sulfur is preferably added as ferrous sulfide. The sulfur causes the elimination of a considerable part of the manganese, apparently combining therewith to form sulfides which pass into the slag. Some of the carbon and some of the silicon areoxidized, so that the resulting alloy may contain 0.50% Si, 0.50% s, 0.15% P, 0.05%. Mn and 2 to 2.25% C.
It is readily apparent that some or all of the added sulfur may be otherwise supplied, for example, by the use of high sulfur pigs, 00 in the manufacture of which high sulfur ores or fuels may be employed.
I claim:
1. A homogeneous, dense, tough, malleable iron casting containing about 0.5% sulfur 5 and materially less manganese than sulfur, said alloy containing carbon in excess of 1.5% and total metalloids sufliciently low in amount to produce a white iron casting and having a tensile strength above 50,000 lbs.
per square inch.
2. A homogeneous, dense, tough, malleable iron casting containing 0.50% sulfur, 0.50% silicon, 0.15% phosphorus, 0.05% manganese and 2.00 to 2.25% carbon, and
having a tensile strength above 50,000 lbs.
per square inch.
3. A dense, homogeneous, annealed m1- le'able iron casting containing about 0.50% sulfur and materially less manganese than sulfur, having a tensile strength above 80,- 000 lbs. per square inch.
GEORGE A. DRYSDALE.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US515571A US1542440A (en) | 1921-11-16 | 1921-11-16 | Iron alloy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US515571A US1542440A (en) | 1921-11-16 | 1921-11-16 | Iron alloy |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1542440A true US1542440A (en) | 1925-06-16 |
Family
ID=24051885
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US515571A Expired - Lifetime US1542440A (en) | 1921-11-16 | 1921-11-16 | Iron alloy |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1542440A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2791526A (en) * | 1953-08-27 | 1957-05-07 | Renault | Method of producing castings having high mechanical properties |
| US2887421A (en) * | 1955-01-05 | 1959-05-19 | Renault | Method of producing castings having high mechanical properties |
| US3000770A (en) * | 1953-11-16 | 1961-09-19 | Eisenwerke Gelsenkirchen Ag Fa | Malleable white cast iron alloys |
| US3998664A (en) * | 1973-07-13 | 1976-12-21 | Rote Franklin B | Cast iron |
-
1921
- 1921-11-16 US US515571A patent/US1542440A/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2791526A (en) * | 1953-08-27 | 1957-05-07 | Renault | Method of producing castings having high mechanical properties |
| US3000770A (en) * | 1953-11-16 | 1961-09-19 | Eisenwerke Gelsenkirchen Ag Fa | Malleable white cast iron alloys |
| US2887421A (en) * | 1955-01-05 | 1959-05-19 | Renault | Method of producing castings having high mechanical properties |
| US3998664A (en) * | 1973-07-13 | 1976-12-21 | Rote Franklin B | Cast iron |
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