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US1162342A - Composite metal body. - Google Patents

Composite metal body. Download PDF

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Publication number
US1162342A
US1162342A US1546415A US1546415A US1162342A US 1162342 A US1162342 A US 1162342A US 1546415 A US1546415 A US 1546415A US 1546415 A US1546415 A US 1546415A US 1162342 A US1162342 A US 1162342A
Authority
US
United States
Prior art keywords
tungsten
gold
composite metal
metal body
molybdenum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US1546415A
Inventor
William D Coolidge
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Electric Co
Original Assignee
General Electric Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Electric Co filed Critical General Electric Co
Priority to US1546415A priority Critical patent/US1162342A/en
Application granted granted Critical
Publication of US1162342A publication Critical patent/US1162342A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14Metallic material, boron or silicon
    • C23C14/18Metallic material, boron or silicon on other inorganic substrates
    • C23C14/185Metallic material, boron or silicon on other inorganic substrates by cathodic sputtering
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3006Ag as the principal constituent
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/922Static electricity metal bleed-off metallic stock
    • Y10S428/9335Product by special process
    • Y10S428/939Molten or fused coating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771Transition metal-base component
    • Y10T428/12806Refractory [Group IVB, VB, or VIB] metal-base component
    • Y10T428/12826Group VIB metal-base component
    • Y10T428/1284W-base component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771Transition metal-base component
    • Y10T428/12861Group VIII or IB metal-base component
    • Y10T428/12868Group IB metal-base component alternative to platinum group metal-base component [e.g., precious metal, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12986Adjacent functionally defined components

Definitions

  • the present invention comprises a metal body consisting of tungsten or molybdenum and a layer of precious metal intimately united therewith which is useful for various purposes in the arts, as, for example, in
  • Tungsten and molybdenumalthough substantially incorrodible are not wet by gold even when care is exercised to prevent oxidation.
  • My invention comprises a composite body of tungsten or molybdenum joined to a laver of a gold-platinum alloy, as, for example, a rod or wire coated with gold-platinum alloy.
  • This new article of metal may be produced by melting gold containing about 1.5% of platinum in an alumina crucible in a hydrogen atmosphere and dipping-the tungsten or molybdenum, for example, as a rod or wire 1 of ductile. metal, into the molten alloy. A thin layer 2 of the gold-platinum alloy will unite firmly with the tungsten or.
  • the hydrogen not only prevents surface oxidation of the tungsten or molybdenum but also.enables the gold alloy to wet or adhere to the surface of the refractory metal.
  • palladium may also be added to the gold alloy to modify its melting point or its hardness.
  • the gold coated metal article has the mechanical strength of tungsten or molybde-.
  • the gold-coated surface is not only incorrodible but may readily be soldered or otherwise joined to other metals.
  • the good mechanical properties of tungsten or molybdenum, particularly toughness and springiness are not lost at the high temperatures necessary for casting or soldering operations, say about 1000 to 1100 C.
  • this new metal article is not limited to this particular field. It may be used in the chemical industry or wherever a" substantially incorrodible, strong, resilient metal article is desired.
  • molybdenum is to be considered the equivalent of tungsten for the purposes of the present invention.
  • a composite metal article comprising tungsten and a coating comprising an alloy of gold and platinum metallically united to or wetting said tungsten.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Products (AREA)

Description

W. D. COOLIDGE.
COMPOSITE METAL BODY.
APPLICATION FlLEl) MAR. 19. 1915.
1 ,162,342. Patented Nov. 30, 1915.
tungsten Qo1d-p1atin um 61 1 0H Inventor:
William D. Coolidge His Attorneg.
ran STATES PATENT curios.
WILLIAM COOLIDG-E, SCHENECTADY, NEW YORK, ASSIGNOR TO GENERAL ELECTRIC COMPANY, A CORPORATION OF NEW YORK.
COMPOSITE METAL BODY.
Specification of Letters Patent.
Patented Nov. 30, 1915.
Application filed March 19, 1915 Serial No. 15,464.
To all whom it may concern:
Be it known that I, WILLIAM D. Coomoon, I
a citizen of the United States, residing at Schenectady, in the. county of Schenectady, State of New York, have invented certain new and useful Improvements in Composite Metal Bodies, of which the following isa specification.
The present invention comprises a metal body consisting of tungsten or molybdenum and a layer of precious metal intimately united therewith which is useful for various purposes in the arts, as, for example, in
dentistry, as dental pins or the like.
Tungsten and molybdenumalthough substantially incorrodible are not wet by gold even when care is exercised to prevent oxidation.
I have discovered that when a small amount of platinum is alloyed with the gold, the tungsten 'or molybdenum is wet by the molten alloy' in an-atmosphere of hydrogen and a firm union is produced.
My inventioncomprises a composite body of tungsten or molybdenum joined to a laver of a gold-platinum alloy, as, for example, a rod or wire coated with gold-platinum alloy.
The accompanymg drawing shows partly in section'a metal article made inaccordance with my invention.
This new article of metal may be produced by melting gold containing about 1.5% of platinum in an alumina crucible in a hydrogen atmosphere and dipping-the tungsten or molybdenum, for example, as a rod or wire 1 of ductile. metal, into the molten alloy. A thin layer 2 of the gold-platinum alloy will unite firmly with the tungsten or.
molybdenum. The hydrogen not only prevents surface oxidation of the tungsten or molybdenum but also.enables the gold alloy to wet or adhere to the surface of the refractory metal. Other alloying metals, such,
for example, as palladium may also be added to the gold alloy to modify its melting point or its hardness.
The gold coated metal article. has the mechanical strength of tungsten or molybde-.
num, and the gold-coated surface is not only incorrodible but may readily be soldered or otherwise joined to other metals. The good mechanical properties of tungsten or molybdenum, particularly toughness and springiness are not lost at the high temperatures necessary for casting or soldering operations, say about 1000 to 1100 C.
While especially useful in dentistry this new metal article is not limited to this particular field. It may be used in the chemical industry or wherever a" substantially incorrodible, strong, resilient metal article is desired.
As above indicated, molybdenum is to be considered the equivalent of tungsten for the purposes of the present invention.
What I claim as new and desire to secure by Letters Patent of the United States, is
1. A composite metal article comprising tungsten and a coating comprising an alloy of gold and platinum metallically united to or wetting said tungsten.
2. A metal article consisting of ductile Cerrection in Letters Patent Not 1,162,342.
' 1 Signed and sealed this' ll th day ef Jniiary, A. D., 1916 It is hereby certified that in'Letteie P a'tent No. 1,162,342, granted j-Ne v eihber 30, 1915, upen the application of Wiliiam D. Coolidge, of Sehenect edy, Nevi York,
for an improvement i1 1 C0mposite Metal Bodies,.--an errer appeers in the printed A specification reqhiring eorreetio as folipws: Page-'1, 1ine'25, for the Word "lever read lag eh," and that the said Letters latent sholild he read withrthis (:orreetion therein that the same may co forni to the recoi'd of the eeee in the Patent Oflice.
J. TLNEWTQNQ i i-Abting Uohtm'issiener;of 1 dtents., 01.29-1s2 V
US1546415A 1915-03-19 1915-03-19 Composite metal body. Expired - Lifetime US1162342A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US1546415A US1162342A (en) 1915-03-19 1915-03-19 Composite metal body.

Applications Claiming Priority (1)

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US1546415A US1162342A (en) 1915-03-19 1915-03-19 Composite metal body.

Publications (1)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3079676A (en) * 1959-03-25 1963-03-05 Raytheon Co Composite article with tungsten and copper parts
DE1178273B (en) * 1956-04-27 1964-09-17 Siemens Ag Manufacture of gold alloy coatings on wire-shaped metallic bodies in a molten way
US3494748A (en) * 1966-12-16 1970-02-10 Xerox Corp Oxidation resistant coating and article
US4286026A (en) * 1978-06-08 1981-08-25 Massachusetts Institute Of Technology Article for implanting radioactive metal on a substrate

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1178273B (en) * 1956-04-27 1964-09-17 Siemens Ag Manufacture of gold alloy coatings on wire-shaped metallic bodies in a molten way
US3079676A (en) * 1959-03-25 1963-03-05 Raytheon Co Composite article with tungsten and copper parts
US3494748A (en) * 1966-12-16 1970-02-10 Xerox Corp Oxidation resistant coating and article
US4286026A (en) * 1978-06-08 1981-08-25 Massachusetts Institute Of Technology Article for implanting radioactive metal on a substrate

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