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US2279763A - Alloy - Google Patents

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Publication number
US2279763A
US2279763A US401652A US40165241A US2279763A US 2279763 A US2279763 A US 2279763A US 401652 A US401652 A US 401652A US 40165241 A US40165241 A US 40165241A US 2279763 A US2279763 A US 2279763A
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US
United States
Prior art keywords
percent
palladium
alloys
platinum
ruthenium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US401652A
Inventor
Sivil Cecil Spencer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Baker and Co Inc
Original Assignee
Baker and Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Baker and Co Inc filed Critical Baker and Co Inc
Priority to US401652A priority Critical patent/US2279763A/en
Application granted granted Critical
Publication of US2279763A publication Critical patent/US2279763A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C5/00Alloys based on noble metals
    • C22C5/04Alloys based on a platinum group metal

Definitions

  • This invention relates to alloys and is con cerned in particular with platinum metal alloys.
  • the alloys according to my invention consist of platinum, palladium and ruthenium.
  • the platinum content may be as low as'10% and as high as 80%
  • the palladium content may be as low as 12% and as high as 90%
  • the ruthenium content may vary from l%-15%.
  • alloys of from 60% to 80% platinum from about 15% to 30% palladium and from 1% to 10% ruthenium, such as alloys of 74% platinum palladium and 6% ruthenium, or of 70% platinum 24% palladium and 6% ruthenium, or even of- 80% platinum 14% palladium and 6% ruthenium, orthe alloys may comprise more particularly for instance alloys of from 25% to 60% platinum, from to 74% palladium and from 1% to 10% ruthenium such as alloys of 30% platinum 67% palladium and 3%, ruthenium, or of 40% platinum 57% palladium and 3% ruthenium.
  • ruthenium such as alloys of 74% platinum palladium and 6% ruthenium, or of 70% platinum 24% palladium and 6% ruthenium, or even of- 80% platinum 14% palladium and 6% ruthenium, orthe alloys may comprise more particularly for instance alloys of from 25% to 60% platinum, from to 74% palladium and from 1% to 10% rut
  • the alloys With increasing palladium content the alloys have decreasing specific gravity, increasing tensile strength, increasing electrical resistance and decreasing melting point notwithstanding their high tensile strengtfi'afid bodiments the palladium content of such alloy s/great liardness.
  • the alloys according to my in- 7 should not fall below about lm afififie rutlihi- 20 vention are also highly resistant to corrosion.
  • Alloys containing at least about palladium show particularly favorable properties.
  • the alloys according to my invention are capableof being used advantageously in widely different fields. They may be used in the construction of corrosion resistant apparatus and they may be used in the field of jewelry and the decorative arts. They may be used in the electrical industry for instance as electricalresistance wires, a
  • the electrical resistivity ohms/mil it. varies from- 153 for the alloy of 10% platinum 87% palladium and 3%ruthenium to 220 for the alloy of 60% platinum 37 palladium and 3% ruthenium and from 250 to 235 for the alloy of 70% platinum 24% palladium and 6% ruthenium and the alloy of 80% platinum 14% palladium and 6% ruthenium, respectively.
  • the alloys according to my invention may be such as to have a relatively high palladium content and .such as to have a relatively low palladium content.
  • the alloys may comprise my co-pending application Serial No. 288,572 filed August 5,1939.
  • Such alloys- may be used in the form of wire, sheet or other manufactured article and may be given intricate shapes and forms due to their great hardness combined with great ductility.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Adornments (AREA)

Description

Patented Apr. 14, 1942 Baker & Company, Inc., Newark, N. J., a corporation of New Jersey Serial No. 401,652
No Drawing. Application July 9, 1941,
6 Claims.
This invention relates to alloys and is con cerned in particular with platinum metal alloys.
It is one object of my invention to provide alloys-of great corrosion resistance, high melting point and great hardness and strength. It is another object of my invention to provide such alloys of great electrical resistance; It is a further object of my invention to provide such alloys of low specific gravity and low cost.
This application is a continuation in part of 1 my application No. 288,572, filed August 5, 1939.
The alloys according to my invention consist of platinum, palladium and ruthenium. In such alloys according to my invention the platinum content may be as low as'10% and as high as 80%, the palladium content may be as low as 12% and as high as 90% and the ruthenium content may vary from l%-15%. In more specific emmore particularly for instance'alloys of from 60% to 80% platinum, from about 15% to 30% palladium and from 1% to 10% ruthenium, such as alloys of 74% platinum palladium and 6% ruthenium, or of 70% platinum 24% palladium and 6% ruthenium, or even of- 80% platinum 14% palladium and 6% ruthenium, orthe alloys may comprise more particularly for instance alloys of from 25% to 60% platinum, from to 74% palladium and from 1% to 10% ruthenium such as alloys of 30% platinum 67% palladium and 3%, ruthenium, or of 40% platinum 57% palladium and 3% ruthenium. With increasing palladium content the alloys have decreasing specific gravity, increasing tensile strength, increasing electrical resistance and decreasing melting point notwithstanding their high tensile strengtfi'afid bodiments the palladium content of such alloy s/great liardness. The alloys according to my in- 7 should not fall below about lm afififie rutlihi- 20 vention are also highly resistant to corrosion.
um content'should not exceed about 10%. In its best embodiment the alloysconsist entirely of platinum palladium ruthenium'in the proportions specified herein, although of course minor quantities of other metals may be present so long 1.
as they do not substantially aflect the beneficial properties and characteristics of my alloys.
The following table will illustrate the nature and properties of the alloys according to my invention: l
Alloys containing at least about palladium show particularly favorable properties.
The alloys according to my invention are capableof being used advantageously in widely different fields. They may be used in the construction of corrosion resistant apparatus and they may be used in the field of jewelry and the decorative arts. They may be used in the electrical industry for instance as electricalresistance wires, a
' 30 use more particularly described and claimed in Composition Tensile strength E10 gation,
percent Density Menu? on 2 pom Pt Pd Ru Hard Annealed Lbalsq. in. Lba/sg. in. GrJcc. C.
10 87 3 82,500 42, 400 29.0 12.6 1,575 20 77 3 83,700 44, 200 34. 0 13. 2 1, 595 40 57 3 79, 000 50, 100 33. 0 s14. 5 1, 640 60 37 3 86,200 54,400 33. 3 16.4 1, 680 24 6 103, 400 I 70, 700 27. 5 l7. 3 1, 700 74 20 6 107, 200 72, 400 31. 5 17.8 1, 710 14 6 137, 000 83, 700 30. 5 18. 8 1, 730
In the alloys specified in the above table the electrical resistivity ohms/mil it. varies from- 153 for the alloy of 10% platinum 87% palladium and 3%ruthenium to 220 for the alloy of 60% platinum 37 palladium and 3% ruthenium and from 250 to 235 for the alloy of 70% platinum 24% palladium and 6% ruthenium and the alloy of 80% platinum 14% palladium and 6% ruthenium, respectively.
The alloys according to my invention may be such as to have a relatively high palladium content and .such as to have a relatively low palladium content. Thus the alloys may comprise my co-pending application Serial No. 288,572 filed August 5,1939. Such alloys-may be used in the form of wire, sheet or other manufactured article and may be given intricate shapes and forms due to their great hardness combined with great ductility.
What I claim is: 1
1. An alloy of ten (10) percent to eighty (80) percent platinum, twelve (12) percent to ninety (90) percent palladium, and one (1) percent to fifteen (15) percent ruthenium. 1
2. An alloy of sixty (60) percent to eighty (80)- percent platinum, fifteen (15) percent to thirty All such alloys "are" surprisingly ductile (30) percent palladium, end, one (1) percent to ten percent ruthenium.
3. An alloy of seventy ('70) percent to seventyfour (74) percent platinum,'twenty percent to twenty-four (24) percent palladium, and about six (6) percent ruthenium.
4. An alloy of twenty-five (25) percent to sixty (60) percent platinum, thirty percent to seventy-four (74) percent palladium, and one 5. An alloy of thirty (30) ercent to rem (40) percent platinum, fifty-seven (57) percent to percent to seventydour (74) percent palladium,
and one (1) percent to ten (10) percent ruthenium.
US401652A 1941-07-09 1941-07-09 Alloy Expired - Lifetime US2279763A (en)

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Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1092212B (en) * 1957-04-20 1960-11-03 Degussa Use of a noble metal alloy as a material for resistors, especially for potentiometer wires
DE1092213B (en) * 1957-04-20 1960-11-03 Degussa Use of a noble metal alloy as a material for resistors, especially for potentiometer wires
DE1758069B1 (en) * 1967-03-28 1971-11-04 Du Pont METALIZING AGENTS AND CONDENSER MADE FROM THEM
US3873675A (en) * 1971-09-14 1975-03-25 Degussa Catalyst and catalyst arrangement for the production of nitric acid
US4155660A (en) * 1976-03-10 1979-05-22 Pilot Man-Nen-Hitsu Kabushiki Kaisha Dot printing wire
US6048492A (en) * 1998-03-19 2000-04-11 Alexander Primak Jewelry, Inc. Platinum alloy composition
US6242104B1 (en) * 1995-10-27 2001-06-05 Implico B.V. Precious metal composition and artifacts made therefrom
US20050169791A1 (en) * 2004-02-04 2005-08-04 Peter Tews Platinum alloy and method of production thereof
EP1820867A1 (en) * 2006-02-16 2007-08-22 Allgemeine Gold- Und Silberscheideanstalt AG Platin alloy and method for its manufacture
EP1878574A1 (en) * 2006-07-11 2008-01-16 Samsung Electronics Co., Ltd. Inkjet Printhead and Image Forming Apparatus including the Same
DE202008002753U1 (en) 2008-02-27 2008-07-10 Burger, Bernhard, Dr. Platinum alloy and a piece of jewelry made from the platinum alloy, in particular a wedding ring
DE102007006623A1 (en) 2007-02-06 2008-08-07 Burger, Bernhard, Dr. Platinum alloy used in the production of a piece of jewelry contains platinum, palladium and copper
US20080232999A1 (en) * 2005-09-07 2008-09-25 Fogel Kenneth D Platinum-palladium alloy
DE102007022992A1 (en) 2007-02-06 2008-10-09 Burger, Bernhard, Dr. Ductile platinum alloy containing palladium and copper, has good optical and mechanical properties and is useful for producing inexpensive palladium jewelry pieces, e.g. wedding rings
DE202005021636U1 (en) 2005-08-03 2009-02-19 Allgemeine Gold- Und Silberscheideanstalt Aktiengesellschaft platinum alloy
DE202005021635U1 (en) 2005-08-03 2009-02-19 Allgemeine Gold- Und Silberscheideanstalt Aktiengesellschaft platinum alloy
RU2356971C2 (en) * 2004-02-04 2009-05-27 Карат Платинум Ллс. Platinum alloy and method of its manufacturing
US20090218647A1 (en) * 2008-01-23 2009-09-03 Ev Products, Inc. Semiconductor Radiation Detector With Thin Film Platinum Alloyed Electrode
DE102008011355A1 (en) 2008-02-27 2009-09-10 Burger, Bernhard, Dr. Platinum alloy, useful for producing a piece of jewelry, preferably a wedding ring or watch cases, comprises platinum, palladium, silver, copper and cobalt

Cited By (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1092212B (en) * 1957-04-20 1960-11-03 Degussa Use of a noble metal alloy as a material for resistors, especially for potentiometer wires
DE1092213B (en) * 1957-04-20 1960-11-03 Degussa Use of a noble metal alloy as a material for resistors, especially for potentiometer wires
DE1758069B1 (en) * 1967-03-28 1971-11-04 Du Pont METALIZING AGENTS AND CONDENSER MADE FROM THEM
US3873675A (en) * 1971-09-14 1975-03-25 Degussa Catalyst and catalyst arrangement for the production of nitric acid
US4155660A (en) * 1976-03-10 1979-05-22 Pilot Man-Nen-Hitsu Kabushiki Kaisha Dot printing wire
US6242104B1 (en) * 1995-10-27 2001-06-05 Implico B.V. Precious metal composition and artifacts made therefrom
US6048492A (en) * 1998-03-19 2000-04-11 Alexander Primak Jewelry, Inc. Platinum alloy composition
US7410546B2 (en) 2004-02-04 2008-08-12 Karat Platinum, Llc Platinum alloy and method of production thereof
US20050169791A1 (en) * 2004-02-04 2005-08-04 Peter Tews Platinum alloy and method of production thereof
WO2005075690A1 (en) * 2004-02-04 2005-08-18 Allgemeine Gold- Und Silberscheideanstalt Ag Platinum alloy and method of production thereof
RU2356971C2 (en) * 2004-02-04 2009-05-27 Карат Платинум Ллс. Platinum alloy and method of its manufacturing
DE202004021558U1 (en) 2004-02-04 2009-01-08 Allgemeine Gold- Und Silberscheideanstalt Ag platinum alloy
EP1978118A1 (en) 2004-02-04 2008-10-08 Allgemeine Gold- Und Silberscheideanstalt AG Platinium alloy and method of production thereof
DE202005021635U1 (en) 2005-08-03 2009-02-19 Allgemeine Gold- Und Silberscheideanstalt Aktiengesellschaft platinum alloy
US20100139319A1 (en) * 2005-08-03 2010-06-10 Peter Tews Platinum alloy and method of production thereof
DE202005021636U1 (en) 2005-08-03 2009-02-19 Allgemeine Gold- Und Silberscheideanstalt Aktiengesellschaft platinum alloy
US20080232999A1 (en) * 2005-09-07 2008-09-25 Fogel Kenneth D Platinum-palladium alloy
US7740720B2 (en) * 2005-09-07 2010-06-22 Fogel Kenneth D Platinum-palladium alloy
DE102006007556A1 (en) * 2006-02-16 2007-08-23 Allgemeine Gold- Und Silberscheideanstalt Ag Platinum alloy and process for its production
EP1820867A1 (en) * 2006-02-16 2007-08-22 Allgemeine Gold- Und Silberscheideanstalt AG Platin alloy and method for its manufacture
DE202007018831U1 (en) 2006-02-16 2009-06-04 Allgemeine Gold- Und Silberscheideanstalt Aktiengesellschaft Platinum alloy and jewelery made therefrom
CN101104334B (en) * 2006-07-11 2012-07-25 三星电子株式会社 Inkjet printhead and image forming apparatus including the same
US20080012906A1 (en) * 2006-07-11 2008-01-17 Samsung Electronics Co., Ltd. Inkjet printhead and image forming apparatus including the same
EP1878574A1 (en) * 2006-07-11 2008-01-16 Samsung Electronics Co., Ltd. Inkjet Printhead and Image Forming Apparatus including the Same
US7581820B2 (en) 2006-07-11 2009-09-01 Samsung Electronics Co., Ltd. Inkjet printhead and image forming apparatus including the same
DE102007022992A1 (en) 2007-02-06 2008-10-09 Burger, Bernhard, Dr. Ductile platinum alloy containing palladium and copper, has good optical and mechanical properties and is useful for producing inexpensive palladium jewelry pieces, e.g. wedding rings
DE102007006623A1 (en) 2007-02-06 2008-08-07 Burger, Bernhard, Dr. Platinum alloy used in the production of a piece of jewelry contains platinum, palladium and copper
US20090218647A1 (en) * 2008-01-23 2009-09-03 Ev Products, Inc. Semiconductor Radiation Detector With Thin Film Platinum Alloyed Electrode
US8896075B2 (en) 2008-01-23 2014-11-25 Ev Products, Inc. Semiconductor radiation detector with thin film platinum alloyed electrode
DE102008011355A1 (en) 2008-02-27 2009-09-10 Burger, Bernhard, Dr. Platinum alloy, useful for producing a piece of jewelry, preferably a wedding ring or watch cases, comprises platinum, palladium, silver, copper and cobalt
DE202008002753U1 (en) 2008-02-27 2008-07-10 Burger, Bernhard, Dr. Platinum alloy and a piece of jewelry made from the platinum alloy, in particular a wedding ring

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