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UA118885C2 - Спосіб одержання метилмеркаптану - Google Patents

Спосіб одержання метилмеркаптану

Info

Publication number
UA118885C2
UA118885C2 UAA201700971A UAA201700971A UA118885C2 UA 118885 C2 UA118885 C2 UA 118885C2 UA A201700971 A UAA201700971 A UA A201700971A UA A201700971 A UAA201700971 A UA A201700971A UA 118885 C2 UA118885 C2 UA 118885C2
Authority
UA
Ukraine
Prior art keywords
hydrogen
methyl mercaptan
reacting
hydrogen sulphide
carbon disulphide
Prior art date
Application number
UAA201700971A
Other languages
English (en)
Inventor
Жорж Фремі
Патрис БАР
Жан-Мішель Раймон
Original Assignee
Аркема Франс
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Аркема Франс filed Critical Аркема Франс
Publication of UA118885C2 publication Critical patent/UA118885C2/uk

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
    • C07C319/06—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols from sulfides, hydropolysulfides or polysulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/16—Hydrogen sulfides
    • C01B17/165—Preparation from sulfides, oxysulfides or polysulfides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/70—Compounds containing carbon and sulfur, e.g. thiophosgene
    • C01B32/72—Carbon disulfide
    • C01B32/75—Preparation by reacting sulfur or sulfur compounds with hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/22—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of hydropolysulfides or polysulfides
    • C07C319/24—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of hydropolysulfides or polysulfides by reactions involving the formation of sulfur-to-sulfur bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C321/00—Thiols, sulfides, hydropolysulfides or polysulfides
    • C07C321/02—Thiols having mercapto groups bound to acyclic carbon atoms
    • C07C321/04—Thiols having mercapto groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C321/00—Thiols, sulfides, hydropolysulfides or polysulfides
    • C07C321/12—Sulfides, hydropolysulfides, or polysulfides having thio groups bound to acyclic carbon atoms
    • C07C321/14—Sulfides, hydropolysulfides, or polysulfides having thio groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/00029—Batch processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/00033—Continuous processes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Винахід стосується способу одержання метилмеркаптану в безперервному режимі, що включає наступні стадії: а) реакцію щонайменше вуглеводневої сировини в присутності сірководню (H2S) і необов'язково сірки (S) для одержання дисульфіду вуглецю (CS2) і водню (Н2); b) реакцію гідрування між одержаними на стадії а) дисульфідом вуглецю (CS2) і воднем (Н2) для одержання метилмеркаптану (CH3SH), сірководню (H2S) і необов'язково водню (Н2); с) рециркуляцію сірководню (H2S), що утворюється на стадії b), на стадію a); d) стадію виділення метилмеркаптану.
UAA201700971A 2014-07-04 2015-06-29 Спосіб одержання метилмеркаптану UA118885C2 (uk)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1456439A FR3023287B1 (fr) 2014-07-04 2014-07-04 Procede de preparation de methylmercaptan
PCT/FR2015/051759 WO2016001553A1 (fr) 2014-07-04 2015-06-29 Procédé de préparation de méthylmercaptan

Publications (1)

Publication Number Publication Date
UA118885C2 true UA118885C2 (uk) 2019-03-25

Family

ID=53191728

Family Applications (1)

Application Number Title Priority Date Filing Date
UAA201700971A UA118885C2 (uk) 2014-07-04 2015-06-29 Спосіб одержання метилмеркаптану

Country Status (20)

Country Link
US (2) US10689334B2 (uk)
EP (1) EP3164381B1 (uk)
JP (2) JP2017519791A (uk)
KR (2) KR102265251B1 (uk)
CN (1) CN106715390B (uk)
AU (1) AU2015282543B2 (uk)
BR (1) BR112016030079B1 (uk)
CA (1) CA2952753C (uk)
EA (1) EA036928B1 (uk)
ES (1) ES2767502T3 (uk)
FR (1) FR3023287B1 (uk)
HU (1) HUE047756T2 (uk)
MX (1) MX388147B (uk)
NZ (1) NZ727769A (uk)
PH (1) PH12016502467B1 (uk)
PL (1) PL3164381T3 (uk)
SG (1) SG11201610785UA (uk)
UA (1) UA118885C2 (uk)
WO (1) WO2016001553A1 (uk)
ZA (1) ZA201608777B (uk)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022023365A1 (en) 2020-07-28 2022-02-03 Totalenergies Se Process to conduct an endothermic thio-reforming reaction of hydrocarbons in an installation comprising electrified fluidized bed reactor
WO2022076420A1 (en) 2020-10-07 2022-04-14 Chevron Phillips Chemical Company Lp Methods of making mercaptan compounds using nickel-molybdenum catalysts
FR3122877B1 (fr) * 2021-05-11 2024-05-10 Arkema France Procédé de co-production de méthylmercaptan et de diméthyldisulfure à partir d’oxydes de carbone
FR3122876B1 (fr) * 2021-05-11 2024-03-08 Arkema France Procédé de co-production d’alkylmercaptan et de dialkyldisulfure à partir d’alcool
EP4101815A1 (en) 2021-06-10 2022-12-14 Evonik Operations GmbH Hydrogen sulfide reforming of hydrocarbons
CN113428861B (zh) * 2021-07-19 2024-01-02 华东理工大学 一种甲烷与硫化氢重整制氢工艺
EP4169895A1 (en) 2021-10-21 2023-04-26 TotalEnergies OneTech Process and catalyst for conversion of carbon disulphide into c2-c3 olefins

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US2668752A (en) * 1949-11-09 1954-02-09 Fmc Corp Process for the production of carbon disulfide
US2788262A (en) * 1953-05-01 1957-04-09 Pan American Petroleum Corp Process for preparation of carbon disulfide
FR1412376A (fr) * 1963-09-23 1965-10-01 Aquitaine Petrole Nouveau procédé pour la fabrication de mercaptans
GB1126465A (en) * 1964-09-14 1968-09-05 Ivor Gray Nixon Manufacture of hydrogen and carbon disulphide
FR2130985A5 (uk) 1971-03-29 1972-11-10 Aquitaine Petrole
US3880933A (en) * 1973-05-02 1975-04-29 Phillips Petroleum Co Hydrogenation of carbon disulfide to methyl mercaptan in presence of hydrogen sulfide
US4481181A (en) 1982-02-08 1984-11-06 Ga Technologies Inc. Hydrogen production from in situ partial burning of H2 S
DE68900007D1 (de) 1988-04-14 1990-10-04 Elf Aquitaine Verfahren zur herstellung von organischen di- und polysulfiden.
US4822938A (en) * 1988-05-03 1989-04-18 Mobil Oil Corporation Processes for converting methane to higher molecular weight hydrocarbons via sulfur-containing intermediates
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FR2781795B1 (fr) 1998-07-31 2000-09-08 Atochem Elf Sa Compositions a base de dimethyldisulfure a odeur masquee
DE19854427A1 (de) * 1998-11-25 2000-05-31 Basf Ag Verfahren zur Herstellung von organischen Disulfiden
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FR2844208B1 (fr) 2002-09-06 2004-10-15 Atofina Purification du h2s par supports poreux
DE10319739A1 (de) 2003-04-30 2004-11-18 Basf Ag Katalysator zur Herstellung von Methylmercaptan aus Methanol und Schwefelwasserstoff
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DE102007024576A1 (de) 2007-05-25 2009-05-20 Evonik Degussa Gmbh Verfahren zur kontinuierlichen Herstellung von Methylmercaptan aus kohlenstoff- und wasserstoffhaltigen Verbindungen
CN101468310B (zh) 2007-12-28 2016-11-16 赢创德固赛有限责任公司 用于从高H2S合成气合成甲硫醇的负载型Mo-O-K-MexOy催化剂
FR2937566B1 (fr) 2008-10-24 2014-07-18 Arkema France Catalyseur d'hydrogenation, notamment de sulfure de carbone
WO2010102653A1 (en) * 2009-03-13 2010-09-16 Eni S.P.A. Process for the abatement of hydrogen sulphide from compositions containing it with simultaneous production of hydrogen
DE102009027837A1 (de) 2009-07-20 2011-01-27 Evonik Degussa Gmbh Verfahren zur kontinuierlichen Herstellung von Methylmercaptan aus kohlenstoffhaltigen Verbindungen, Schwefel und Wasserstoff
CA2673149A1 (en) * 2009-07-20 2011-01-20 National Research Council Of Canada Audio feedback for motor control training
TWI389420B (zh) 2009-11-13 2013-03-11 Beyond Innovation Tech Co Ltd 充電裝置、電子裝置以及充電方法
JP5981995B2 (ja) 2011-09-02 2016-08-31 アルケマ フランス Ｌ−メチオニンの製造方法
EP2606967A1 (de) 2011-12-19 2013-06-26 Evonik Degussa GmbH Katalysator zur Synthese von Alkylmercaptanen und Verfahren zu seiner Herstellung

Also Published As

Publication number Publication date
ES2767502T3 (es) 2020-06-17
FR3023287A1 (fr) 2016-01-08
BR112016030079A2 (pt) 2017-08-22
FR3023287B1 (fr) 2016-07-22
CA2952753A1 (fr) 2016-01-07
JP6942686B2 (ja) 2021-09-29
US20200331851A1 (en) 2020-10-22
US11104642B2 (en) 2021-08-31
KR102265251B1 (ko) 2021-06-14
PL3164381T3 (pl) 2020-04-30
PH12016502467B1 (en) 2020-02-21
US20170158631A1 (en) 2017-06-08
NZ727769A (en) 2020-08-28
BR112016030079B1 (pt) 2021-07-20
JP2019052155A (ja) 2019-04-04
CN106715390A (zh) 2017-05-24
US10689334B2 (en) 2020-06-23
JP2017519791A (ja) 2017-07-20
MX2016017253A (es) 2017-04-10
EP3164381B1 (fr) 2019-12-11
MX388147B (es) 2025-03-19
ZA201608777B (en) 2018-05-30
HUE047756T2 (hu) 2020-05-28
CN106715390B (zh) 2020-06-30
KR20190004369A (ko) 2019-01-11
KR20170023149A (ko) 2017-03-02
EP3164381A1 (fr) 2017-05-10
CA2952753C (fr) 2019-04-16
WO2016001553A1 (fr) 2016-01-07
PH12016502467A1 (en) 2017-04-10
SG11201610785UA (en) 2017-01-27
EA201692365A1 (ru) 2017-05-31
AU2015282543B2 (en) 2017-10-05
AU2015282543A1 (en) 2017-01-12
EA036928B1 (ru) 2021-01-15

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