TWI728207B - Washable water-repellent makeup composition - Google Patents
Washable water-repellent makeup composition Download PDFInfo
- Publication number
- TWI728207B TWI728207B TW106140747A TW106140747A TWI728207B TW I728207 B TWI728207 B TW I728207B TW 106140747 A TW106140747 A TW 106140747A TW 106140747 A TW106140747 A TW 106140747A TW I728207 B TWI728207 B TW I728207B
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- Taiwan
- Prior art keywords
- water
- weight percentage
- washable
- repellent
- wax
- Prior art date
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- 239000002562 thickening agent Substances 0.000 claims abstract description 23
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- 239000004519 grease Substances 0.000 claims abstract description 19
- 239000000843 powder Substances 0.000 claims abstract description 18
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 22
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- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 16
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- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical group [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 claims description 8
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- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 claims description 8
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- FGUZFFWTBWJBIL-XWVZOOPGSA-N [(1r)-1-[(2s,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)O[C@H](CO)[C@H]1OC[C@H](O)[C@H]1O FGUZFFWTBWJBIL-XWVZOOPGSA-N 0.000 claims description 2
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Abstract
本發明提供一種水洗式防潑水之彩妝組合物，其包括：至少一HLB值小於等於13的乳化劑，其中該HLB值小於等於13的乳化劑的重量百分比為0.1~13%；至少一固態油脂，其中該固態油脂的重量百分比為1~18%；至少一增稠劑，其中該增稠劑的重量百分比為0~18%；至少一粉劑，其中該粉劑的重量百分比為0.5~15%；以及至少一液態油脂，其中該液態油脂的重量百分比為2~80%。本發明之彩妝組合物具有防潑水性，且只要簡單的以水搓揉不必透過特殊的有機卸妝油就能達到將彩妝卸除的效果。 The present invention provides a water-washable water-repellent makeup composition, which comprises: at least one emulsifier with an HLB value of less than or equal to 13, wherein the weight percentage of the emulsifier with an HLB value of less than or equal to 13 is 0.1-13%; and at least one solid oil , Wherein the weight percentage of the solid grease is 1-18%; at least one thickener, wherein the weight percentage of the thickener is 0-18%; at least one powder, wherein the weight percentage of the powder is 0.5-15%; And at least one liquid grease, wherein the weight percentage of the liquid grease is 2 to 80%. The color makeup composition of the present invention has water repellency, and the effect of removing color makeup can be achieved by simply rubbing with water without passing through a special organic cleansing oil.
Description
本發明涉及一種水洗式防潑水之彩妝組合物，特別是涉及一種HLB值小於等於13的乳化劑的彩妝組合物。 The present invention relates to a water-washable water-repellent color cosmetic composition, in particular to a color cosmetic composition of an emulsifier with an HLB value of less than or equal to 13.
近年來隨著生活品質的提升，女性對於使用化妝品的觀念越來越普及化。對大多數女性來說，使用化妝品能讓她們顯得更加健康、年輕。舉例說明：透過粉底的使用，其能掩蓋遮瑕使用者的斑與色塊，並使皮膚顯現出少女才有的那種平滑、無暇的理想狀態。眼影、眼線、睫毛膏和染眉劑的使用，能讓眼睛看起來更大、更年輕、更純真。腮紅則是能使臉部呈現出年輕人激動時產生紅暈的效果。 In recent years, with the improvement of the quality of life, women's concept of using cosmetics has become more and more popular. For most women, using cosmetics can make them look healthier and younger. For example: through the use of foundation, it can conceal the spots and color patches of the concealer, and make the skin show the ideal state of smoothness and flawlessness that a girl can only have. The use of eye shadow, eyeliner, mascara and eyebrow dye can make the eyes look bigger, younger, and more innocent. Blush is the effect that can make the face appear flushed when young people are excited.
為了避免因為夏天的炎熱所產生的汗水及淚水導致脫妝現象，女性消費者在化妝產品的購買上，可選擇具有防水性的化妝品；然而，市面上所販賣這些具有防水效果的防水性化妝品卻有存在不易卸除的問題，且需要透過其他油性或是有機溶劑等特殊卸妝油作為該防水性化妝品的卸除劑才能達到卸除效果，而這類化妝品卸除劑在使用上可能會對眼睛造成刺激疼痛感，或是殘留一層油脂膜在眼睛周圍的皮膚上，同時這類化妝品卸除劑也將增加微生物汙染的問題。 In order to avoid makeup removal caused by sweat and tears caused by the summer heat, female consumers can choose waterproof cosmetics when purchasing cosmetic products; however, these waterproof cosmetics sold on the market have a waterproof effect. There is a problem that it is not easy to remove, and other oily or organic solvents and other special cleansing oils are required as the remover of the waterproof cosmetics to achieve the removal effect, and this type of cosmetics remover may be harmful to the eyes. Cause irritation and pain, or leave a layer of grease on the skin around the eyes. At the same time, this type of cosmetic remover will also increase the problem of microbial contamination.
因此，便有需要提供一種具有防水性，同時不用依靠油性或是有機溶劑等特殊卸妝油就能輕易卸除的水洗式防潑水性之彩妝組合物， 其能解決前述的問題。 Therefore, there is a need to provide a water-repellent, water-repellent makeup composition that can be easily removed without relying on special cleansing oils such as oily or organic solvents. It can solve the aforementioned problems.
本發明的一目的在於提供一種水洗式防潑水之彩妝組合物，其包括：至少一HLB值小於等於13的乳化劑，其中該HLB值小於等於13的乳化劑的重量百分比為0.1~13%；至少一固態油脂，其中該固態油脂的重量百分比為1~18%；至少一增稠劑，其中該增稠劑的重量百分比為0~18%；至少一粉劑，其中該粉劑的重量百分比為0.5~15%；以及至少一液態油脂，其中該液態油脂的重量百分比為2~80%。 An object of the present invention is to provide a water-washable water-repellent makeup composition, which includes: at least one emulsifier with an HLB value of less than or equal to 13, wherein the weight percentage of the emulsifier with an HLB value of less than or equal to 13 is 0.1-13%; At least one solid fat, wherein the weight percentage of the solid fat is 1-18%; at least one thickener, wherein the weight percentage of the thickener is 0-18%; at least one powder, wherein the weight percentage of the powder is 0.5 ~15%; and at least one liquid grease, wherein the weight percentage of the liquid grease is 2 to 80%.
本發明之另一目的在於提供一種水洗式防潑水彩妝組合物之製備方法，其包含以下步驟：步驟一：將HLB值小於等於13的乳化劑、固態油脂、增稠劑及液態油脂依一比例加入至攪拌鍋中，攪拌混合形成一中間產物A，並以75~85℃高溫加熱至融化，其中該比例為HLB值小於等於13的乳化劑0.1~13%wt、固態油脂1~18%wt、增稠劑0~18%wt及液態油脂2~80%wt；步驟二：待該中間產物A完全融化後，加入粉劑、色素及防腐劑，形成另一中間產物B；步驟三：攪拌均勻至色素分散；以及步驟四：將色素均勻分散的該中間產物B進行灌模。 Another object of the present invention is to provide a method for preparing a water-washable water-repellent watercolor makeup composition, which comprises the following steps: Step 1: The emulsifier, solid oil, thickener, and liquid oil with an HLB value of less than or equal to 13 are in a proportion Add to the stirring pot, stir and mix to form an intermediate product A, and heat to melt at a high temperature of 75~85℃, where the ratio is 0.1~13%wt of emulsifier with HLB value less than or equal to 13%wt, solid oil 1~18%wt , Thickener 0-18%wt and liquid grease 2~80%wt; Step 2: After the intermediate product A is completely melted, add powder, pigment and preservative to form another intermediate product B; Step 3: Stir evenly To pigment dispersion; and Step 4: Filling the intermediate product B with uniform pigment dispersion.
本發明之再一目的在於提供一種水洗式防潑水之彩妝組合物，其包括：一HLB值小於等於13的乳化劑，其中該HLB值小於等於13的乳化劑為重量百分比0.1~13%的月桂醇聚醚-4(Laureth-4)；至少一固態油脂，其包含一堪地里拉蠟(Candellila wax)、一地蠟(Ceresin wax)、一蜜蠟(Bees wax)及一凡士林(Vaseline)，其中該堪地里拉蠟的重量百分比為2~18%、該地蠟的重量百分比為1~9%、該蜜蠟的重量百分比為1~11%及該凡士林的重 量百分比為1~5%；至少一增稠劑，其包含一硬脂醇(Stearic alcohol)及硬脂酸鋁(Aluminum Stearate)，其中硬脂醇的重量百分比為2~18%及該硬脂酸鋁的重量百分比為0~6%；至少一粉劑，其包含一聚甲基矽倍半氧烷(Polymethysilsesquioxane)、一季銨鹽18水輝石(Quaternium-18 Hectorite)、一滑石粉(Talc Powder)及一二氧化鈦(Titanium Dioxide)，其中該聚甲基矽倍半氧烷的重量百分比為2~8%、該季銨鹽18水輝石的重量百分比為0.5~1.5%、該滑石粉的重量百分比為2~8%及該二氧化鈦的重量百分比為2~8%；至少一液態油脂，其包含一環戊矽氧烷(Cyclopentasiloxane)及礦物油(Mineral Oil)，其中該環戊矽氧烷的重量百分比為2~18%及該礦物油的重量百分比為20~80%；至少一色素，其中該色素的重量百分比為5~15%；至少一香精，其中該香精的重量百分比為0.5~3.5%；以及重量百分比0.1~1.9%的防腐劑。 Another object of the present invention is to provide a water-washable water-repellent makeup composition, which includes: an emulsifier with an HLB value of less than or equal to 13, wherein the emulsifier with an HLB value of less than or equal to 13 is 0.1 to 13% by weight of laurel Laureth-4 (Laureth-4); at least one solid oil containing one Candellila wax, one Ceresin wax, one Bees wax and one Vaseline, The weight percentage of the Candelilla wax is 2-18%, the weight percentage of the ozokerite wax is 1-9%, the weight percentage of the beeswax is 1-11% and the weight of the petrolatum The amount percentage is 1~5%; at least one thickening agent, which includes a stearic alcohol (Stearic alcohol) and aluminum stearate (Aluminum Stearate), wherein the weight percentage of stearyl alcohol is 2-18% and the stearic acid The weight percentage of aluminum acid is 0~6%; at least one powder, which includes a polymethysilsesquioxane, a quaternary ammonium salt 18 hectorite, and a talc powder And titanium dioxide (Titanium Dioxide), wherein the weight percentage of the polymethylsilsesquioxane is 2~8%, the weight percentage of the quaternary ammonium salt 18 hectorite is 0.5~1.5%, and the weight percentage of the talc powder is 2-8% and the weight percentage of the titanium dioxide is 2-8%; at least one liquid grease, which includes a cyclopentasiloxane (Cyclopentasiloxane) and mineral oil (Mineral Oil), wherein the weight percentage of the cyclopentasiloxane is 2-18% and the weight percentage of the mineral oil is 20-80%; at least one pigment, wherein the weight percentage of the pigment is 5-15%; at least one flavor, wherein the weight percentage of the flavor is 0.5-3.5%; and 0.1~1.9% by weight preservative.
由上述可知，本發明的水洗式防潑水彩妝組合物為HLB值小於等於13的乳化劑之化妝品，可提供一種簡易低成本、防水效果好，且只要簡單的以水搓揉不必透過特殊的有機卸妝油就能達到卸除化妝品的功效。 It can be seen from the above that the water-washable water-repellent watercolor makeup composition of the present invention is an emulsifier cosmetic with an HLB value of less than or equal to 13. It can provide a simple and low-cost, good waterproof effect, and as long as it is simply rubbed with water, it does not need to pass through special organic cosmetics. Cleansing oil can achieve the effect of removing cosmetics.
S100~S300‧‧‧步驟 S100~S300‧‧‧Step
圖1為本發明水洗式防潑水的彩妝組合物的製備方法流程圖；以及圖2~6為本發明水洗式防潑水的彩妝組合物與一般防潑水彩妝的試驗結果照片。 Figure 1 is a flow chart of the preparation method of the water-washable and water-repellent color cosmetic composition of the present invention; and Figures 2 to 6 are photographs of the test results of the water-washable and water-repellent color makeup composition of the present invention and general water-repellent watercolor makeup.
本發明為呈現解決問題所採用的技術手段較佳實施方式或 實施例而已，並非用來限定本發明專利實施之範圍，即凡與本發明專利申請範圍文義相符，或依本發明專利範圍所作的均等變化與修飾，皆為本發明專利所涵蓋。 The present invention presents a preferred embodiment of the technical means used to solve the problem or The embodiments are only used to limit the scope of implementation of the patent of the present invention, that is, all the equivalent changes and modifications made in accordance with the scope of the patent application of the present invention, or equivalent changes and modifications made in accordance with the scope of the patent of the present invention, are covered by the patent of the present invention.
本發明的一種水洗式防潑水彩妝組合物的特徵在於：必須含有：至少一HLB值小於等於13的乳化劑、至少一固態油脂、至少一增稠劑、至少一粉劑以及至少一液態油脂。以下進一步針對本發明的特徵說明。 The water-washable water-repellent watercolor makeup composition of the present invention is characterized in that it must contain: at least one emulsifier with an HLB value of less than or equal to 13, at least one solid oil, at least one thickener, at least one powder, and at least one liquid oil. The following further describes the characteristics of the present invention.
HLB值小於等於13的乳化劑 Emulsifier with HLB value less than or equal to 13
本發明的水洗式防潑水彩妝組合物中所使用的HLB值小於等於13的乳化劑可通過聚合物顆粒在氣液兩相界面吸附降低水的表面張力，或通過吸附在液體界面間來降低油水界面張力而被引入至組合物中，這些乳化劑通常用於穩定聚合物顆粒的表面活性劑。 The emulsifier with an HLB value of less than or equal to 13 used in the water-washable water-repellent watercolor makeup composition of the present invention can reduce the surface tension of water by adsorbing polymer particles at the gas-liquid interface, or reduce oil and water by adsorbing between the liquid interface. The interfacial tension is incorporated into the composition, and these emulsifiers are usually used to stabilize the surfactant of the polymer particles.
本發明的彩妝組合物可包括至少一種HLB值小於等於13的乳化劑，其中該HLB值小於等於13的乳化劑相對於組合物之重量百分比為0.1~13%，進一步為5~10%，更進一步為6~8%。本發明所提及的HLB值小於等於13的乳化劑中採用的是非離子表面活性劑，例如：二聚羥基硬脂酸酯(PEG-30 Dipolyhydroxystearate)、甘油硬脂酸(Glyceryl Stearate)、聚乙二醇-100硬脂酸酯(PEG-100 Stearate)、月桂醇聚醚-4(Laureth-4)、十六烷基二甲聚矽氧烷共聚醇(Cetyl Dimethicone Copolyol)、雙-PEG/PPG-14/14聚二甲基矽氧烷(Bis-PEG/PPG-14/14 Dimethicone)、聚乙二醇月桂醇醚(Lauryl Alcohol Polythylene Glycol Ether)、鯨蠟/硬脂醚-22(Ceteareth-22)及十三烷醇聚醚-10(Trideceth-10)。 The color cosmetic composition of the present invention may include at least one emulsifier with an HLB value of less than or equal to 13, wherein the weight percentage of the emulsifier with an HLB value of less than or equal to 13 relative to the composition is 0.1-13%, further 5-10%, and more It is further 6~8%. The emulsifiers with HLB value less than or equal to 13 mentioned in the present invention are non-ionic surfactants, such as: dipolyhydroxystearate (PEG-30 Dipolyhydroxystearate), glyceryl stearate (Glyceryl Stearate), polyethylene Glycol-100 Stearate (PEG-100 Stearate), Laureth-4 (Laureth-4), Cetyl Dimethicone Copolyol (Cetyl Dimethicone Copolyol), Bis-PEG/PPG -14/14 Polydimethylsiloxane (Bis-PEG/PPG-14/14 Dimethicone), polyethylene glycol lauryl ether (Lauryl Alcohol Polythylene Glycol Ether), cetyl/stearyl ether-22 (Ceteareth- 22) and Trideceth-10 (Trideceth-10).
進一步地，也可以是非離子表面活性劑-聚醚型，例如：聚 甘油-4異硬脂酸酯(Polyglycery-4 Isostearate)或聚甘油-3油酸酯(Polyglycery-3 Oleate)。 Further, it can also be a non-ionic surfactant-polyether type, for example: polyether Polyglycery-4 Isostearate or Polyglycery-3 Oleate.
再者，也可以是非離子表面活性劑-酯型，例如：脫水山梨醇異硬脂酯(Sorbitan isostearate)或脫水山梨醇倍半油酸酯(Sorbitan sesquioleate)。 Furthermore, it may also be a non-ionic surfactant-ester type, for example: Sorbitan isostearate or Sorbitan sesquioleate.
固態油脂 Solid grease
本發明的水洗式防潑水彩妝組合物中所使用的固態油脂可提供柔潤皮膚、控制黏度及作為成膜劑的功效，其可針對水洗式防潑水彩妝組合物的結構性質進一步調節該固態油脂的用量。 The solid oil used in the water-washable water-repellent watercolor makeup composition of the present invention can provide soft skin, control viscosity, and function as a film-forming agent. It can further adjust the solid oil and fat according to the structural properties of the water-washable water-repellent watercolor makeup composition. Dosage.
本發明的彩妝組合物可包括至少一種固態油脂，其中該固態油脂相對於組合物之重量百分比為1~18%，進一步為3~15%，更進一步為5~12%。本發明所提及的固態油脂可包含以下至少一種植物性蠟，例如：堪地里拉蠟(Candellila wax)又稱小燭樹蠟、棕櫚蠟(Carnaub wax)及漆果皮蠟(Rhus verniciflua Peel Wax)，其中堪地里拉蠟(Candellila wax)其內含40~50%碳氫化合物，及酯類、酸類、樹脂等成份。 The color cosmetic composition of the present invention may include at least one solid oil, wherein the weight percentage of the solid oil relative to the composition is 1-18%, further 3-15%, and still further 5-12%. The solid oil mentioned in the present invention may contain at least one of the following vegetable waxes, for example: Candelilla wax, also known as candelilla wax, Carnaub wax, and Rhus verniciflua Peel Wax Among them, Candellila wax contains 40-50% hydrocarbons, esters, acids, resins and other ingredients.
進一步地，也可以是地蠟(Ceresin wax)、蜂蠟(Bees wax)或凡士林(Vasline)。 Further, it may also be Ceresin wax, Bees wax or Vasline.
增稠劑 Thickener
本發明的水洗式防潑水彩妝組合物中所使用的增稠劑可通過與表面活性劑(乳化劑)形成棒狀膠束、與水作用形成三維水化網絡結構、或利用自身的大分子長鏈結構等使體系達到增稠的目的。此外，透過多種增稠劑其能對產品的最終流變形態有更好的效果。 The thickener used in the water-washable water-repellent watercolor makeup composition of the present invention can form rod-shaped micelles with surfactants (emulsifiers), interact with water to form a three-dimensional hydration network structure, or use its own macromolecular growth. The chain structure makes the system achieve the purpose of thickening. In addition, through a variety of thickeners, it can have a better effect on the final rheological shape of the product.
本發明的彩妝組合物可包括至少一種增稠劑，其中該增稠劑相對於組合物之重量百分比為0~18%，進一步為3~15%，更進一步為6~13%。本發明所提及的增稠劑可包含以下至少一種親水性增稠劑，例如：聚丙烯酸鈉(Sodium polyacrylate)、硬脂醇(Stearic alcohol)、聚乙烯(Polyethylene)、聚季銨鹽(Polyquaternium)及聚丙烯醯基二甲基牛磺酸鈉(Sodium polyacryloyldimethyl taurate)。 The color cosmetic composition of the present invention may include at least one thickener, wherein the weight percentage of the thickener relative to the composition is 0-18%, further 3-15%, and still further 6-13%. The thickener mentioned in the present invention may contain at least one of the following hydrophilic thickeners, for example: sodium polyacrylate, stearic alcohol, polyethylene, polyquaternium ) And Sodium polyacryloyldimethyl taurate.
進一步地，也可以是親油性增稠劑，例如：硬脂酸(Stearic acid)。 Further, it may also be a lipophilic thickener, such as stearic acid.
再者，也可以是有機黏土礦物類，例如：司拉氯銨膨潤土(Stearalkonium bentonite)、氫化牛油鉀膨潤土(Hydrogenated Tallowalkonium Bentonite)或苯扎氯銨膨潤土(Benzalkonium Bentonite)。 Furthermore, it can also be organic clay minerals, such as: Stearalkonium bentonite, Hydrogenated Tallowalkonium Bentonite, or Benzalkonium Bentonite.
粉劑 powder
本發明的彩妝組合物可包括至少一種粉劑，其中該粉劑相對於組合物之重量百分比為0.5~15%，進一步為3~15%，更進一步為5~15%。本發明所提及的粉劑係選自由滑石粉(Talc Powder)、矽粉(Silicon powder)、氧化鋅(Zinc Oxide)、聚甲基丙烯酸甲酯(PMMA，Polymethylmethacrylate)、矽酸鈣(Calcium Silicate)、聚甲基矽倍半氧烷(Polymethysilsesquioxane)、硬脂酸鋅(Zinc stearate)、澱粉辛烯基琥珀酯鋁鹽(Aluminum Starch Octenylsuccinate)、二氧化鈦(Titanium Dioxide)、膨潤土(Bentonite)、高嶺石(Kaolinite)、季銨鹽18膨潤土(Quaternium-18 Bentonite)、季銨鹽90膨潤土(Quaternium-90 Bentonite)及季銨鹽18水輝石(Quaternium-18 Hectorite)組成之群組。其中氧化鋅(Zinc Oxide)與二氧化鈦(Titanium Dioxide)可作為防曬 劑抵抗UVA、UVB；另外，矽粉(Silicon powder)與聚甲基矽倍半氧烷(Polymethysilsesquioxane)具有耐水性可作為防水劑。 The color cosmetic composition of the present invention may include at least one powder, wherein the weight percentage of the powder relative to the composition is 0.5-15%, further 3-15%, and still further 5-15%. The powder mentioned in the present invention is selected from Talc Powder, Silicon powder, Zinc Oxide, PMMA, Polymethylmethacrylate, Calcium Silicate , Polymethysilsesquioxane, Zinc stearate, Aluminum Starch Octenylsuccinate, Titanium Dioxide, Bentonite, Kaolinite Kaolinite), Quaternium-18 Bentonite (Quaternium-18 Bentonite), Quaternium-90 Bentonite (Quaternium-90 Bentonite) and Quaternium-18 Hectorite (Quaternium-18 Hectorite). Among them, Zinc Oxide and Titanium Dioxide can be used as sunscreen The agent resists UVA and UVB; in addition, silicon powder and polymethysilsesquioxane have water resistance and can be used as waterproofing agents.
進一步地，滑石粉(Talc Powder)、矽酸鈣(Calcium Silicate)、澱粉辛烯基琥珀酯鋁鹽(Aluminum Starch Octenylsuccinate)、膨潤土(Bentonite)、高嶺石(Kaolinite)可作為吸附劑具有吸油吸水的特性。 Further, talc (Talc Powder), calcium silicate (Calcium Silicate), starch octenyl succinate aluminum salt (Aluminum Starch Octenylsuccinate), bentonite (Bentonite), kaolinite (Kaolinite) can be used as adsorbents with oil and water absorption. characteristic.
液態油脂 Liquid grease
本發明的彩妝組合物可包括至少一種液態油脂，其中該液態油脂相對於組合物之重量百分比為2~80%，進一步為15~60%，更進一步為30~50%。本發明的水洗式防潑水彩妝組合物中所使用的液態油脂主要是作為該彩妝組合物的潤膚劑及提供保濕的功效，其可包含有揮發性的油脂，例如：環甲基矽氧烷(Cyclonethicone)、環戊矽氧烷(Cyclopentasiloxane)及環戊矽氧烷(Cyclopentasiloxane)。 The color cosmetic composition of the present invention may include at least one liquid oil, wherein the weight percentage of the liquid oil relative to the composition is 2 to 80%, further 15 to 60%, and still further 30 to 50%. The liquid oil used in the water-washable water-repellent watercolor makeup composition of the present invention is mainly used as an emollient and moisturizing effect of the makeup composition, and it may contain volatile oils, such as cyclomethylsiloxane (Cyclonethicone), Cyclopentasiloxane and Cyclopentasiloxane.
進一步地，也可以是非揮發性的油脂，例如：聚二甲基矽氧烷(Dimethicone)。 Further, it may also be a non-volatile grease, such as: Dimethicone.
再者，也可以是不飽和烴礦物油(Mineral Oil)、二異硬脂醇蘋果酸酯(Dissostearyl malate)、十四酸異丙酯(Isopropyl myristate)、辛酸/癸酸三酸甘油酯(Caprylic/Capric Triglyceride)、硬脂酸正丁酯(N-butyl stearate)、角鯊烷(Squalane)、氫化聚異丁烯(Hydrogenated Polyisobutene)、異壬酸異壬酯(Isononyl Isononanoate)、鯨蠟矽氧烷(Cetyl Dimethicone)及棕櫚酸異辛酯(Ethylhexyl palmitate)。 In addition, unsaturated hydrocarbon mineral oil (Mineral Oil), dissostearyl malate (Dissostearyl malate), isopropyl myristate (Isopropyl myristate), caprylic/capric triglyceride (Caprylic /Capric Triglyceride), N-butyl stearate, Squalane, Hydrogenated Polyisobutene, Isononyl Isononanoate, Cetylsiloxane ( Cetyl Dimethicone) and Ethylhexyl palmitate.
著色劑 Colorant
本發明的彩妝組合物可進一步包含有著色劑，其中該著色劑 相對於組合物之重量百分比為1~15%，進一步為3~13%，更進一步為9~12%。而著色劑的種類可選自由人工合成的著色劑及由動、植物組織中提取的天然著色劑所組成的群組。 The color cosmetic composition of the present invention may further include a colorant, wherein the colorant The weight percentage relative to the composition is 1 to 15%, further 3 to 13%, and still further 9 to 12%. The type of coloring agent can be selected from the group consisting of artificially synthesized coloring agents and natural coloring agents extracted from animal and plant tissues.
更進一步地，本發明的彩妝組合物可進一步包含有香精、抗氧化劑及防腐劑。 Furthermore, the makeup composition of the present invention may further include flavors, antioxidants and preservatives.
此外，本發明的彩妝組合物可以是以下任一型態呈現，包含有膏狀、乳液狀、粉條狀或膠狀，且該彩妝組合物的應用產品可以是眼影、粉餅、粉底液、粉條、睫毛膏、染眉劑或腮紅。 In addition, the color makeup composition of the present invention can be presented in any of the following forms, including cream, emulsion, noodles or gel, and the application products of the color makeup composition can be eye shadow, pressed powder, liquid foundation, vermicelli, Mascara, eyebrow dye or blush.
本發明還提供了一種水洗式防潑水彩妝組合物的製備方法，具體如下： 請參閱圖1，圖1為本發明水洗式防潑水的彩妝組合物的製備方法流程圖。首先先將HLB值小於等於13的乳化劑、固態油脂、增稠劑及液態油脂依一比例分別加入至攪拌鍋中，攪拌混合形成一中間產物A，並以75~85℃高溫加熱至融化，其中該比例為HLB值小於等於13的乳化劑0.1~13%wt、固態油脂1~18%wt、增稠劑0~18%wt及液態油脂2~80%wt(步驟S100)。待該中間產物A完全融化後，接著加入粉劑、色素及防腐劑，一樣均勻攪拌形成另一中間產物B，且攪拌均勻直到色素完全分散(步驟S200)。最後，將色素均勻分散的該中間產物B進行灌模，並放置常溫陰影處冷卻，待冷卻後即可使用(步驟S300)。 The invention also provides a preparation method of the water-washable splash-proof watercolor makeup composition, which is specifically as follows: Please refer to FIG. 1, which is a flow chart of the preparation method of the water-washable water-repellent color cosmetic composition of the present invention. First, add the emulsifier, solid grease, thickener and liquid grease with HLB value less than or equal to 13 into the mixing pot in a proportion, stir and mix to form an intermediate product A, and heat it to melt at a high temperature of 75-85°C. The ratio is 0.1-13%wt of emulsifier with HLB value less than or equal to 13, 1-18%wt of solid fat, 0-18%wt of thickener, and 2~80%wt of liquid fat (step S100). After the intermediate product A is completely melted, the powder, the pigment and the preservative are then added, and the same is uniformly stirred to form another intermediate product B, and the intermediate product B is uniformly stirred until the pigment is completely dispersed (step S200). Finally, the intermediate product B with evenly dispersed pigments is poured into a mold, and placed in a shaded place at room temperature to cool, and can be used after cooling (step S300).
進一步地，本發明還提供另一種水洗式防潑水之彩妝組合物，其包括：一HLB值小於等於13的乳化劑，其中該HLB值小於等於13的乳化劑為重量百分比0.1~13%的月桂醇聚醚-4(Laureth-4)；至少一固態油 脂，其包含一堪地里拉蠟(Candellila wax)、一地蠟(Ceresin wax)、一蜜蠟(Bees wax)及一凡士林(Vaseline)，其中該堪地里拉蠟的重量百分比為2~18%、該地蠟的重量百分比為1~9%、該蜜蠟的重量百分比為1~11%及該凡士林的重量百分比為1~5%；至少一增稠劑，其包含一硬脂醇(Stearic alcohol)及硬脂酸鋁(Aluminum Stearate)，其中硬脂醇的重量百分比為2~18%及該硬脂酸鋁的重量百分比為0~6%；至少一粉劑，其包含一聚甲基矽倍半氧烷(Polymethysilsesquioxane)、一季銨鹽18水輝石(Quaternium-18 Hectorite)、一滑石粉(Talc Powder)及一二氧化鈦(Titanium Dioxide)，其中該聚甲基矽倍半氧烷的重量百分比為2~8%、該季銨鹽18水輝石的重量百分比為0.5~1.5%、該滑石粉的重量百分比為2~8%及該二氧化鈦的重量百分比為2~8%；至少一液態油脂，其包含一環戊矽氧烷(Cyclopentasiloxane)及礦物油(Mineral Oil)，其中該環戊矽氧烷的重量百分比為2~18%及該礦物油的重量百分比為20~80%；至少一色素，其中該色素的重量百分比為5~15%；至少一香精，其中該香精的重量百分比為0.5~3.5%；以及重量百分比0.1~1.9%的防腐劑。 Further, the present invention also provides another water-washable water-repellent makeup composition, which includes: an emulsifier with an HLB value of less than or equal to 13, wherein the emulsifier with an HLB value of less than or equal to 13 is 0.1-13% by weight of laurel Laureth-4; at least one solid oil Grease, which includes one Candelilla wax, one Ceresin wax, one Bees wax and one Vaseline, wherein the weight percentage of the Candelilla wax is 2-18% , The weight percentage of the ozokerite wax is 1-9%, the weight percentage of the beeswax is 1-11% and the weight percentage of the petrolatum is 1~5%; at least one thickener, which includes a stearyl alcohol (Stearic alcohol) and aluminum stearate (Aluminum Stearate), in which the weight percentage of stearyl alcohol is 2-18% and the weight percentage of the aluminum stearate is 0~6%; at least one powder, which contains a polymethicone Polymethysilsesquioxane, Quaternium-18 Hectorite, Talc Powder and Titanium Dioxide, wherein the weight percentage of the polymethysilsesquioxane is 2~8%, the weight percentage of the quaternary ammonium salt 18 hectorite is 0.5~1.5%, the weight percentage of the talc powder is 2~8%, and the weight percentage of the titanium dioxide is 2~8%; at least one liquid grease, which Contains a cyclopentasiloxane (Cyclopentasiloxane) and mineral oil (Mineral Oil), wherein the weight percentage of the cyclopentasiloxane is 2-18% and the weight percentage of the mineral oil is 20-80%; at least one pigment, of which The weight percentage of the pigment is 5 to 15%; at least one flavor, wherein the weight percentage of the flavor is 0.5 to 3.5%; and the weight percentage of the preservative is 0.1 to 1.9%.
綜合上述，本發明所提供的水洗式防潑水的彩妝組合物是涉及一種HLB值小於等於13的乳化劑的彩妝組合物，其具有一半以上的油脂量成分，能提供防潑水性及良好的油相(連續相)溶解度以達到容易卸除的效果，其中該油脂量成分主要取決於固態油脂與液態油脂的用量比，此外，本發明是採用中性乳化劑(非離子型的表面活性劑)作為穩定乳化體的成分，比起其他離子型的表面活性劑，本發明提供的乳化體穩定度更為優異。 In summary, the water-washable and water-repellent makeup composition provided by the present invention relates to a makeup composition of an emulsifier with an HLB value of 13 or less. It has more than half of the oil content and can provide water repellency and good oil. Phase (continuous phase) solubility in order to achieve the effect of easy removal, wherein the amount of oil composition mainly depends on the amount of solid oil and liquid oil ratio, in addition, the present invention uses a neutral emulsifier (non-ionic surfactant) As a component for stabilizing the emulsified body, compared with other ionic surfactants, the emulsified body provided by the present invention is more stable than other ionic surfactants.
實施例1-眼影系列的彩妝組合物 Example 1-Make-up composition of eye shadow series
請參閱圖2~6，圖2~6為本發明水洗式防潑水的彩妝組合物 與一般防潑水彩妝的試驗結果照片，在圖2的部分，呈現的是水洗式防潑水彩妝組合物(左邊)與一般防水彩妝(右邊)塗抹於玻璃片上的示意圖；接著，圖3的部分是將水分別注入塗抹水洗式防潑水彩妝組合物(左邊)與一般防水彩妝(右邊)的玻璃片上，可以發現相較於圖2下，圖3右邊的將水注入於一般防水彩妝的色塊有呈現掉色模糊的現象，而圖3左邊的水洗式防潑水彩妝組合物在注入水的情況下，並沒有掉色模糊的現象。 Please refer to Figures 2~6, Figures 2~6 are the water-washable and water-repellent makeup composition of the present invention Compared with the test result photos of general water-repellent watercolor makeup, the part in Figure 2 shows a schematic diagram of the water-washable water-repellent makeup composition (left) and the general water-repellent makeup (right) applied on a glass plate; then, the part of Figure 3 is Pour water into the glass sheets for applying the washable water-repellent watercolor makeup composition (left) and general water-repellent makeup (right). It can be seen that compared to the bottom of Figure 2, the color blocks on the right of Figure 3 that inject water into the general water-repellent makeup have It presents the phenomenon of fading and blurring, and the water-washable water-repellent watercolor makeup composition on the left side of FIG. 3 does not fade and blurring when water is injected.
在圖4與圖5的部分，分別為水洗式防潑水彩妝組合物的使用清水清潔之狀況(圖4)與一般防水彩莊的使用清水清潔之狀況(圖5)，可以發現圖4在使用清水及清潔刷的搓揉即可輕易去除水洗式防潑水彩妝組合物，而圖5在使用清水及清潔刷的搓揉卻無法輕易去除一般防水彩妝。 In Figure 4 and Figure 5, the water-washable water-repellent watercolor makeup composition is cleaned with water (Figure 4) and the general water-repellent makeup composition is cleaned with water (Figure 5). It can be found that Figure 4 is in use Rubbing with water and a cleaning brush can easily remove the washable water-repellent watercolor makeup composition, while in Figure 5, rubbing with water and a cleaning brush cannot easily remove general water-repellent makeup.
接著，在圖6的部分所呈現的是水洗式防潑水彩妝組合物與一般防水彩妝在使用清水清除後殘留彩妝的對照，可以發現水洗式防潑水彩妝組合物能被清水完全的清除，而一般防水彩妝無法被清水完全的清除乾淨。 Next, shown in the part of Figure 6 is the comparison between the water-washable water-repellent watercolor makeup composition and the general water-repellent makeup after cleaning with water. It can be found that the water-washable water-repellent watercolor makeup composition can be completely removed by water, while the general Waterproof makeup cannot be completely removed by water.
上述圖2~6中所提及的本發明水洗式防潑水的彩妝組合物之配方用量，列於表1中，各成分的用量皆以重量百分比作為表示。 The formula dosage of the water-washable water-repellent makeup composition of the present invention mentioned in the above-mentioned Figures 2 to 6 is listed in Table 1, and the dosage of each component is expressed as a percentage by weight.
S100~S300‧‧‧步驟 S100~S300‧‧‧Step
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