TW201819185A - Adhesive sheet laminate, shaped adhesive sheet laminate, and method for producing same - Google Patents

Abstract

Provided is an adhesive sheet laminate provided with an adhesive material layer and a cover portion I peelably laminated on one surface of the adhesive material layer, as a novel adhesive sheet laminate with which it is possible to form an uneven shape matching an uneven portion of an adherend surface at high accuracy on the adhesive material layer surface, wherein the adhesive sheet laminate is characterized in that the storage modulus E'(MA) of the cover portion I at 100 DEG C is 1.0*10<SP>6</SP> to 2.0*10<SP>9</SP> Pa, and the storage modulus E'(MB) of the cover portion I at 30 DEG C is 5.0*10<SP>7</SP> to 1.0*10<SP>10</SP> Pa.

Description

Adhesive sheet laminated body, shaped adhesive sheet laminated body and manufacturing method thereof

The present invention relates to a method for forming images such as a personal computer, a mobile terminal (PDA (personal digital assistant)), a game machine, a television (TV), a car navigation system, a touch panel, a handwriting tablet, and the like. The shaped adhesive sheet laminated body which can be suitably used in a display device, and the adhesive sheet laminated body which is suitable for forming the shaped adhesive sheet laminated body.

An image display device of a touch panel method is generally constituted by combining a surface protection panel, a touch panel, and an image display panel (also collectively referred to as "constituent members for an image display device"). In recent years, a surface protection panel of an image display device of a touch panel method such as a smart phone or a tablet terminal uses a reinforced glass while using a plastic material such as an acrylic resin plate or a polycarbonate plate. The peripheral portions other than the face are printed in black. Moreover, in the touch panel, a plastic film sensor is used together with the glass sensor, or a component called a one-piece touch (TOL) that integrates the touch panel function and the surface protection panel is used. , Or use a component called a surface-embedded or embedded-type that integrates touch panel functions into an image display panel. In this type of image display device, in order to further improve the visibility of the image, a gap between the constituent members for each image display device is usually filled with a transparent resin such as a liquid adhesive, a thermoplastic adhesive sheet, or an adhesive sheet. The structure. In addition, in the field of image display devices centered on mobile phones or mobile terminals, in addition to thinning and high-precision, the diversification of design continues to develop. Previously, black was usually printed in a frame shape on the periphery of the surface protection panel. As the design diversifies, the frame-shaped concealed portion starts to be formed in a color other than black. When the concealed portion is formed in a color other than black, the concealability is low, and therefore the height of the concealed portion, that is, the printed portion is higher than that of black. Therefore, it is required to fill each corner of an adhesive sheet for bonding a constituent member provided with such a printing section in accordance with a large printing step. Therefore, since the past, various methods have been proposed for filling the printing step. For example, in Patent Document 1, a double-sided image display device for double-sided use as a new image display device that can be closely adhered to an adhered surface without a gap even if the adhered surface of the adhered adhesive sheet has a step difference formed by printing or the like. An adhesive sheet is disclosed, and a double-sided adhesive sheet for an image display device is disclosed, which is used to select any two components of an image display device selected from a surface protection panel, a touch panel, and an image display panel. The double-sided adhesive sheet adhered by the adherend, and at least one of the adherends has a stepped portion on the adhered surface of the double-sided adherent sheet to be adhered, and the double-sided adhesive sheet is made to adhere to the above-mentioned adhered surface. The shape of the joint surface is shaped along the surface shape of the adhered surface. Further, in Patent Document 2, a method for manufacturing a double-sided adhesive sheet for bonding any two adherends selected from a surface protection panel, a touch panel, and an image display panel is disclosed, and an image is disclosed. The manufacturing method of a double-sided adhesive sheet for a display device is characterized in that: the double-sided adhesive sheet before lamination uses an adhesive composition having a gel fraction of less than 40%, and is shaped as the same as the above-mentioned adherend. The uneven shape of the bonding surface is the same surface shape. Prior Art Literature Patent Literature Patent Literature 1: WO2014 / 073316 A1 Patent Literature 2: WO2015 / 174392 A1

[Problems to be Solved by the Invention] In recent years, in the field of image display devices centered on mobile phones or mobile terminals, thinner walls and higher precision have been demanded. The adhesive sheet is also required to be able to accurately fill uneven portions on the surface of the adherend such as a printing step, and there is no case where the adhesive material is exposed to the outside. As a countermeasure against this requirement, as disclosed in the aforementioned prior patent documents, it has been studied to form the surface shape of the adhesive sheet in advance with the surface shape of the adherend. In addition, in order to form the surface shape of the adhesive sheet in advance with the surface shape of the adherend as described above, the following method is assumed: an adhesive sheet laminate formed by laminating a release sheet on both sides of the adhesive sheet The body is press-molded to form an uneven shape conforming to the uneven portion on the surface of the adherend. However, an attempt was made to use an adhesive sheet laminated body formed by laminating ordinary release sheets on both sides of the adhesive sheet and actually implementing the above method. As a result, it was clear that it was difficult to form and adhere the surface of the adhesive sheet with high accuracy. Concave-convex shape on the body surface. Therefore, the present invention relates to an adhesive sheet laminate having an adhesive material layer and a covering portion formed by laminating on one side of the adhesive material layer in a peelable manner, and proposes a highly accurate formation on the surface of the adhesive material layer. A new adhesive sheet laminate having a concave-convex shape corresponding to the uneven portion on the surface of the adherend, and a shaped adhesive sheet laminate using the adhesive sheet laminate. [Technical means to solve the problem] The present invention proposes an adhesive sheet laminate, which is an adhesive sheet laminate including an adhesive material layer and a coating portion I formed by laminating on one side of the adhesive material layer in a peelable manner. The body is characterized in that the storage elastic modulus E '(MA) of the coating portion I at 100 ° C is 1.0 × 10 ⁶ to 2.0 × 10 ⁹ Pa, and the storage elastic modulus of the coating portion I at 30 ° C E '(MB) is 5.0 × 10 ⁷ to 1.0 × 10 ¹⁰ Pa. In addition, as the shaped adhesive sheet laminate using the above-mentioned adhesive sheet laminate, the present invention proposes a shaped adhesive sheet laminate, wherein the adhesive layer is provided with recesses, protrusions, or Concavo-convex portions (referred to as "concave-convex portions on the surface of the adhesive material layer"), and the coating portion I is in close contact with one of the front and back surfaces of the adhesive material layer, and has concave, convex, or uneven portions on the front and back surfaces Part (referred to as "concave-convex part of the surface of the coating part"), and the surface on the other side of the front side and the back side opposite to one of the front side and the back side is provided with an irregularity corresponding to the surface uneven side of the adhesive layer. Convex, concave, or convex-concave (referred to as "convex-convex convex-concave"). [Effects of the Invention] The adhesive sheet laminate according to the present invention can be formed on the surface of the adhesive material layer by heating the adhesive sheet laminate and then pressing the mold against the coating portion I to form the adhesive sheet laminate. The unevenness is accurately formed to match the unevenness on the surface of the adherend. In addition, since the coating portion I can maintain the shape retention property in the normal state, the operation is relatively easy. Moreover, since the coating portion I is not too hard, it can prevent the adhesive material layer from forming irregularities that are not intended. The shaped adhesive sheet laminate according to the present invention has uneven portions on the adhesive sheet surface on one of the front and back sides of the adhesive sheet layer, and the coating portion I is in close contact with one of the front and back sides of the adhesive sheet layer. The front surface and the back surface are provided with a covered portion surface uneven portion, and the front and back surfaces on the other side of the front and back surfaces are provided with the covered portion rear surface concave and convex portions. As described above, the shaped adhesive sheet laminate according to the present invention is provided with the coating portion I and is in close contact with one side surface of the front surface and the back surface of the adhesive material layer without gaps, and the coating portion I is peelable. It is formed by laminating on one side surface of the front surface and the back surface of the adhesive material layer, so that it can prevent dust and the like from adhering to the surface of the adhesive material layer and reducing the adhesion, and it can also prevent the formation of the adhesive material layer on the front surface. The shape of the concave-convex part of the surface of the adhesive material layer formed on one side surface of the back surface absorbs moisture in the air and disintegrates, or the adhesion of dust and the like on the surface decreases.

An example of an embodiment of the present invention will be described below. However, the present invention is not limited to the following embodiments. [This adhesive sheet laminate] An adhesive sheet laminate (referred to as "this adhesive sheet laminate"), which is an example of an embodiment of the present invention, is provided with an adhesive material layer in a peelable manner as shown in FIG. 1. Covering part I formed by laminating on one side of the front and back sides of the adhesive material layer, and adhesive sheet of covering part II formed by laminating on the other side of the front and back sides of the adhesive material layer Laminated body. Here, the coating portion II is arbitrary, and a configuration in which the coating portion II is not laminated may be adopted. <Adhesive material layer> As long as the adhesive material layer of the adhesive sheet laminated body is peeled off from the coating portion I and the coating portion II, it can function as a double-sided adhesive sheet, and has a function of softening or melting if heated. Hot melt only. The adhesive material layer preferably has a loss tangent tan δ (SA) of 100 or more at 100 ° C. The loss tangent tanδ (SB) at 30 ° C is preferably not more than 1.0. Here, the loss tangent tanδ means the ratio (G '' / G ') of the loss elastic modulus G''to the storage elastic modulus G'. Since the temperature at which the adhesive sheet laminate is heated and molded is usually 70 to 120 ° C, if the loss tangent tan δ (SA) at 100 ° C is 1.0 or more, it becomes easy to form an uneven shape on the surface of the adhesive layer. . In addition, if the loss tangent tanδ (SB) of the adhesive material layer at 30 ° C is less than 1.0, the shape can be maintained in the normal state, so that it can be maintained on the surface of the adhesive material layer with high accuracy to conform to the unevenness on the surface of the adherend. The state of the uneven shape. Generally, polymer materials have both viscous and elastic properties. The loss tangent tanδ is 1.0 or more. The larger the value, the stronger the viscous properties. On the other hand, the loss tangent tanδ does not reach 1.0, and the smaller the value, the stronger the elastic properties. Therefore, by controlling the loss tangent tanδ of the adhesive material layer at different temperatures, both formability and shape retention can be achieved. From this point of view, the loss tangent tan δ (SA) of the adhesive material layer at 100 ° C is preferably 1.0 or more, preferably 1.5 or 30 or less, and 3.0 or 20 or less. On the other hand, the loss tangent tan δ (SB) of the adhesive material layer at 30 ° C. is preferably less than 1.0, preferably 0.01 or more or 0.9 or less, and more preferably 0.1 or 0.8 or less. Here, the loss tangent tanδ (SA) of the adhesive material layer at 100 ° C and the loss tangent tanδ (SB) at 30 ° C can be adjusted by adjusting the components or gel fraction and weight average of the composition constituting the adhesive material layer. The molecular weight is adjusted to the above range. Furthermore, the storage elastic modulus G '(SA) of the adhesive material layer at 100 ° C is preferably less than 1.0 × 10. ⁴ Pa. The storage elastic modulus G '(SB) of the adhesive material layer at 30 ° C is preferably 1.0 × 10. ⁴ Pa or more. If the storage elastic modulus G '(SA) of the adhesive material layer at 100 ° C does not reach 1.0 × 10 ⁴ Pa is sufficient to obtain sufficient formability. On the other hand, if the storage elastic modulus G '(SB) of the adhesive layer at 30 ° C is 1.0 × 10 ⁴ Pa or more is preferable from the viewpoint of shape stability after forming. From this viewpoint, the storage elastic modulus G '(SA) of the adhesive material layer at 100 ° C is preferably less than 1.0 × 10. ⁴ Pa, more preferably 5.0 × 10 ¹ Above Pa or 5.0 × 10 ³ Pa or less, more preferably 1.0 × 10 ² Above Pa or 1.0 × 10 ³ Pa or less. According to this, the storage elastic modulus G '(SA) of the adhesive material layer at 100 ° C is more preferably 5.0 × 10 ¹ Above Pa and less than 1.0 × 10 ⁴ Pa, or 5.0 × 10 ¹ Above Pa and 5.0 × 10 ³ Pa or less, more preferably 1.0 × 10 ² Above Pa and less than 1.0 × 10 ⁴ Pa, or 1.0 × 10 ² Above Pa and 5.0 × 10 ³ Pa or less, preferably 1.0 × 10 ² Above Pa and 1.0 × 10 ³ Pa or less. From this viewpoint, the storage elastic modulus G '(SB) of the adhesive material layer at 30 ° C is preferably 1.0 × 10. ⁴ Pa or more, more preferably 2.0 × 10 ⁴ Above Pa or 1.0 × 10 ⁷ Pa or less, of which 5.0 × 10 is more preferred ⁴ Above Pa or 1.0 × 10 ⁶ Pa or less. According to this, the storage elastic modulus G '(SB) of the adhesive material layer at 30 ° C is more preferably 1.0 × 10 ⁴ Above Pa and 1.0 × 10 ⁷ Pa or less, or 1.0 × 10 ⁴ Above Pa and 1.0 × 10 ⁶ Pa or less, more preferably 2.0 × 10 ⁴ Above Pa and 1.0 × 10 ⁷ Pa or less, or 2.0 × 10 ⁴ Above Pa and 1.0 × 10 ⁶ Pa or less, preferably 5.0 × 10 ⁴ Above Pa and 1.0 × 10 ⁶ Pa or less. Here, the storage elastic modulus G '(SA) of the adhesive material layer at 100 ° C and the storage elastic modulus G' (SB) of the adhesive material layer at 30 ° C can be adjusted by adjusting the composition of the composition constituting the adhesive material layer. The component, the gel fraction, the weight average molecular weight, and the like are adjusted to the above ranges. The temperature at which the loss tangent tan δ of the adhesive material layer becomes 1.0 is preferably 50 to 150 ° C, more preferably 60 ° C or more or 130 ° C or less, and still more preferably 70 ° C or more or 110 ° C or less. If the temperature at which the loss tangent tan δ of the adhesive material layer becomes 1.0 is 50 to 150 ° C, the present adhesive sheet laminate can be heated to 50 to 150 ° C in advance to perform mold forming. The glass transition temperature (Tg) of the base resin of the adhesive material layer is preferably -50 to 40 ° C, more preferably -30 ° C or more or 25 ° C or less, and still more preferably -10 ° C or more or 20 ° C or less. Here, the measurement of the glass transition temperature refers to the midpoint between the inflection points of the baseline movement when the temperature is raised at a rate of 3 ° C./minute using a differential scanning calorimeter (DSC). If the glass transition temperature (Tg) of the base resin of the adhesive material layer is in the above range, adhesion can be imparted to the adhesive material layer, and further, the temperature at which the loss tangent tanδ of the adhesive material layer becomes 1.0 can be adjusted to 50 to 150 ° C. As the material of the adhesive material layer, as long as the material can be prepared with a specific viscoelastic behavior, a conventionally known adhesive sheet can be used. Examples include: 1) using a (meth) acrylic acid ester-based polymer (which has a meaning including a copolymer, hereinafter referred to as "acrylic acid-based (co) polymer") as a base resin, and formulating a crosslinking monomer therein And, if necessary, a crosslinking initiator or a reaction catalyst, and the adhesive sheet formed by the crosslinking reaction; or 2) using a butadiene or isoprene copolymer as a base resin, Among them, cross-linking monomers are prepared, cross-linking initiators or reaction catalysts are prepared as needed, and the adhesive sheet formed by the cross-linking reaction is performed; or 3) a silicone polymer is used as a base resin, and Among them, cross-linking monomers are prepared, cross-linking initiators or reaction catalysts are prepared as needed, and the adhesive sheet formed by cross-linking reaction is performed; or 4) polyurethane-based polymers are used as a basis Polyurethane-based adhesive sheet of resin and the like. Except for the aforementioned viscoelastic properties or thermal properties, the physical properties of the adhesive material layer itself are not an essential problem in the present invention. However, from the viewpoints of adhesiveness, transparency, and weather resistance, the acrylic resin (co) polymer of 1) described above is preferably used as the base resin. In the case where properties such as electrical characteristics and low refractive index are required, the butadiene or isoprene-based copolymer described in 2) above is preferably used as the base resin. When properties such as heat resistance and rubber elasticity in a wide temperature range are required, it is preferable to use the polysiloxane copolymer of 3) as a base resin. When performance such as re-peelability is required, it is preferred to use the polyurethane polymer of 4) as the base resin. As an example of the adhesive material layer, a resin composition containing a (meth) acrylic copolymer (a) as a base resin, a crosslinking agent (b), and a photopolymerization initiator (c) can be exemplified. Sticky sheet. In this case, the above-mentioned viscoelastic properties must be satisfied in an uncrosslinked state, that is, a state before a three-dimensionally crosslinked network structure is formed. From this viewpoint, the gel fraction of the adhesive material layer is preferably 40% or less. If the gel fraction of the adhesive material layer is 40% or less, the bonding between the molecular chains constituting the adhesive material layer can be suppressed to an appropriate range. Therefore, it can have a moderate degree when it is formed into a shaped adhesive sheet laminate. fluidity. From this viewpoint, the gel fraction of the adhesive material layer is preferably 40% or less, particularly preferably 20% or less, and particularly preferably 10% or less. In addition, the lower limit of the gel fraction of the adhesive material layer is not limited, and may be 0%. The gel fraction of the adhesive material layer is not limited to those containing a (meth) acrylic copolymer (a) as a base resin, a crosslinking agent (b), and a photopolymerization initiator (c). The same applies to the case of the resin composition, and the case of using another resin composition as the adhesive material layer. ((Meth) acrylic copolymer (a)) The (meth) acrylic copolymer (a) can be further adjusted according to the type, composition ratio, and the like of the acrylic monomer or methacrylic monomer to be polymerized. The polymerization conditions and the like appropriately adjust the characteristics such as the glass transition temperature (Tg). Examples of the acrylic monomer or methacrylic monomer for polymerizing an acrylate polymer include 2-ethylhexyl acrylate, n-octyl acrylate, n-butyl acrylate, ethyl acrylate, and methyl. Methyl acrylate, etc. It is also possible to use vinyl acetate, hydroxyethyl acrylate, acrylic acid, glycidyl acrylate, acrylamide, acrylonitrile, methacrylonitrile, and fluoroacrylate which are copolymerized with hydrophilic groups or organic functional groups. , Polysiloxane, etc. Among the acrylate polymers, an alkyl (meth) acrylate-based copolymer is particularly preferred. As the (meth) acrylate used to form the (meth) acrylic acid alkyl ester-based copolymer, that is, an alkyl acrylate or an alkyl methacrylate component, the alkyl group is preferably n-octyl group and isooctyl group. 1 or 2 or 2 ethylhexyl, n-butyl, isobutyl, methyl, ethyl, isopropyl, or an alkyl methacrylate or an alkyl methacrylate A mixture of two or more. As other components, an acrylate or methacrylate having an organic functional group such as a carboxyl group, a hydroxyl group, or a glycidyl group may be copolymerized. Specifically, a monomer component composed of the (meth) acrylic acid alkyl ester component and the (meth) acrylic acid ester component having an organic functional group can be appropriately and selectively combined as a starting material to be heat-polymerized to obtain (Meth) acrylate copolymer polymer. Among them, preferred is an alkyl acrylate such as isooctyl acrylate, n-octyl acrylate, n-butyl acrylate, 2-ethylhexyl acrylate, or a mixture of two or more selected from these, or Examples are those obtained by copolymerizing at least one or more of isooctyl acrylate, n-octyl acrylate, n-butyl acrylate, 2-ethylhexyl acrylate, and the like with acrylic acid. As the polymerization treatment using these monomers, known polymerization methods such as solution polymerization, emulsion polymerization, block polymerization, and suspension polymerization can be adopted. In this case, polymerization is performed using a thermal polymerization initiator or a photopolymerization initiator according to the polymerization method. An initiator, whereby an acrylate copolymer can be obtained. (Acrylic copolymer (A1)) As an example of a preferable base polymer for the adhesive material layer, a (meth) acrylic copolymer (A1) including a graft copolymer having a macromonomer as a branched component can be cited. . If the adhesive material layer is constituted by using the acrylic copolymer (A1) as a base resin, the adhesive material layer can maintain a sheet shape at room temperature and exhibit self-adhesion, and if heated in an uncrosslinked state, it will It can be light-hardened by melting or flowing, and can be made to exhibit excellent cohesion after light-hardening. Therefore, if an acrylic copolymer (A1) is used as the base polymer of the adhesive material layer, even if it is in an uncrosslinked state, it exhibits adhesiveness at room temperature (20 ° C) and has a temperature of 50 to 100 when heated. ℃, more preferably a temperature above 60 ° C or below 90 ° C will soften or fluidize. The glass transition temperature of the copolymer constituting the main chain component of the acrylic copolymer (A1) is preferably -70 to 0 ° C. At this time, the glass transition temperature of the copolymer component constituting the main chain component refers to the glass transition temperature of the polymer obtained by copolymerizing only the monomer components constituting the main chain component of the acrylic copolymer (A1). Specifically, it means the value calculated from the calculation formula of Fox based on the glass transition temperature and composition ratio of the polymer obtained from the homopolymer of each component of the copolymer. In addition, the calculation formula of Fox is a calculation value calculated | required by the following formula, and can be calculated | required using the value described in a polymer manual [Polymer HandBook, J. Brandrup, Interscience, 1989]. 1 / (273 ＋ Tg) = Σ (Wi / (273 ＋ Tgi)) [where Wi represents the weight fraction of monomer i and Tgi represents the Tg (° C) of the homopolymer of monomer i] The glass transition temperature of the copolymer component of the main chain component of (A1) will affect the softness of the adhesive material layer at room temperature, or the wettability, that is, the adhesion of the adhesive material layer to the adherend, so for the purpose of adhesion The material layer obtains moderate adhesiveness (adhesiveness) at room temperature. The glass transition temperature is preferably -70 ° C to 0 ° C, particularly preferably -65 ° C or more or -5 ° C or less, and particularly preferably- Above 60 ° C or below -10 ° C. However, even if the glass transition temperature of the copolymer component is the same temperature, the viscoelasticity can be adjusted by adjusting the molecular weight. For example, by reducing the molecular weight of the copolymer component, it can be further softened. Examples of the (meth) acrylate monomer contained in the main chain component of the acrylic copolymer (A1) include methyl (meth) acrylate, ethyl (meth) acrylate, and (meth) acrylic acid. Propyl ester, isopropyl (meth) acrylate, n-butyl (meth) acrylate, isobutyl (meth) acrylate, second butyl (meth) acrylate, third butyl (meth) acrylate, Amyl (meth) acrylate, isoamyl (meth) acrylate, neopentyl (meth) acrylate, hexyl (meth) acrylate, cyclohexyl (meth) acrylate, heptyl (meth) acrylate , 2-ethylhexyl acrylate, n-octyl acrylate, isooctyl acrylate, nonyl (meth) acrylate, isononyl (meth) acrylate, third butyl cyclohexyl (meth) acrylate, ( Decyl (meth) acrylate, isodecyl (meth) acrylate, undecyl (meth) acrylate, lauryl (meth) acrylate, cetyl (meth) acrylate, hard (meth) acrylate Esters, isostearyl (meth) acrylate, behenyl (meth) acrylate, isopropyl (meth) acrylate, 2-phenoxyethyl (meth) acrylate, 3,5,5 acrylic acid -Trimethylcyclohexyl Ester, p-cumylphenol EO modified (meth) acrylate, dicyclopentyl (meth) acrylate, dicyclopentenyl (meth) acrylate, dicyclopentenyloxy (meth) acrylate, Benzyl (meth) acrylate and the like. These can also be used: hydroxyethyl (meth) acrylate, hydroxypropyl (meth) acrylate, hydroxybutyl (meth) acrylate, glyceryl (meth) acrylate, etc., which have a hydrophilic group or an organic functional group, etc. (Meth) acrylic acid esters containing hydroxyl groups; or (meth) acrylic acid, 2- (meth) acryloxyethylhexahydrophthalic acid, 2- (meth) acryloxypropylhexahydro Phthalic acid, 2- (meth) acryloxyethyl phthalate, 2- (meth) acryloxypropyl phthalate, 2- (meth) acryloxyethyl Maleic acid, 2- (meth) acryloxypropylmaleic acid, 2- (meth) acryloxyethyl succinic acid, 2- (meth) acryloxy Carboxyl-containing monomers such as propyl succinic acid, butenoic acid, fumaric acid, maleic acid, itaconic acid, maleic acid monomethyl ester, and maleic acid monomethyl ester; maleic acid Anhydride group-containing monomers such as oxalic anhydride, itaconic anhydride; glycidyl (meth) acrylate, glycidyl α-ethylacrylate, 3,4-epoxybutyl (meth) acrylate, etc. Monomer; dimethylaminoethyl (meth) acrylate, (meth) propylene (Meth) acrylic monomers containing amine groups such as diethylaminoethyl ester; (meth) acrylamidonium, N-third butyl (meth) acrylamidonium, N-hydroxymethyl (methyl Acrylamide, N-methoxymethyl (meth) acrylamide, N-butoxymethyl (meth) acrylamide, diacetone acrylamide, cis-butylene diamine, cis Monobutylene-imide-containing monomers such as butene diamidine; heterocyclic basic monomers such as vinylpyrrolidone, vinylpyridine, and vinylcarbazole. In addition, styrene, third butylstyrene, α-methylstyrene, vinyltoluene, acrylonitrile, and methyl which can be copolymerized with the above-mentioned acrylic monomer or methacrylic monomer can also be suitably used. Various vinyl monomers, such as acrylonitrile, vinyl acetate, vinyl propionate, alkyl vinyl ether, hydroxyalkyl vinyl ether, and alkyl vinyl monomer. The main chain component of the acrylic copolymer (A1) preferably contains a hydrophobic (meth) acrylate monomer and a hydrophilic (meth) acrylate monomer as constituent units. When the main chain component of the acrylic copolymer (A1) is composed of only a hydrophobic monomer, moist heat and whitening tend to be observed. Therefore, it is preferable to also introduce a hydrophilic monomer into the main chain component to prevent moist and heat whitening. Specifically, as a main chain component of the said acrylic copolymer (A1), the hydrophobic (meth) acrylate monomer, the hydrophilic (meth) acrylate monomer, and the terminal of a macromonomer are mentioned A copolymer component obtained by random copolymerization of polymerizable functional groups. Here, examples of the hydrophobic (meth) acrylate monomer include n-butyl (meth) acrylate, isobutyl (meth) acrylate, second butyl (meth) acrylate, Tert-butyl (meth) acrylate, amyl (meth) acrylate, isoamyl (meth) acrylate, neo-amyl (meth) acrylate, hexyl (meth) acrylate, (meth) acrylic ring Hexyl ester, heptyl (meth) acrylate, 2-ethylhexyl acrylate, n-octyl acrylate, isooctyl acrylate, nonyl (meth) acrylate, isononyl (meth) acrylate, (meth) Third butyl cyclohexyl acrylate, decyl (meth) acrylate, isodecyl (meth) acrylate, undecyl (meth) acrylate, lauryl (meth) acrylate, (meth) acrylic acid Cetyl ester, stearyl (meth) acrylate, isostearyl (meth) acrylate, behenyl (meth) acrylate, isopropyl (meth) acrylate, cyclohexyl (meth) acrylate, Dicyclopentenyloxy (meth) acrylate, methyl methacrylate. Examples of the hydrophobic vinyl monomer include vinyl acetate, styrene, third butylstyrene, α-methylstyrene, vinyl toluene, and an alkyl vinyl monomer. Examples of the hydrophilic (meth) acrylate monomer include methyl acrylate, (meth) acrylic acid, and tetrahydrofurfuryl (meth) acrylate; or hydroxyethyl (meth) acrylate, and (meth) acrylate. (Meth) acrylic acid-containing hydroxypropyl (meth) acrylate, hydroxybutyl (meth) acrylate, glyceryl (meth) acrylate, etc .; (meth) acrylic acid, 2- (meth) acrylic acid Ethyl hexahydrophthalic acid, 2- (meth) acryloxypropylhexahydrophthalic acid, 2- (meth) acryloxyethyl phthalic acid, 2- (formyl) ) Acryloxypropyl phthalic acid, 2- (meth) acryloxyethyl maleic acid, 2- (meth) acryloxypropyl maleic acid, 2 -(Meth) acryloxyethylsuccinic acid, 2- (meth) acryloxypropylsuccinic acid, butenoic acid, fumaric acid, maleic acid, itaconic acid , Monocarboxylic acid-containing monomers such as maleic acid monomethyl ester and monoconic acid; Monocarboxylic acid-containing monomers such as maleic anhydride, itaconic anhydride; glycidyl (meth) acrylate, α-ethyl Glycidyl acrylate, 3,4-epoxy (meth) acrylate Epoxy group-containing monomers such as butyl ester; alkoxy polyalkylene glycol (meth) acrylates such as methoxy polyethylene glycol (meth) acrylate; N, N-dimethylacrylamide , Hydroxyethyl acrylamide, and so on. The acrylic copolymer (A1) preferably incorporates a macromonomer as a branching component of the graft copolymer, and contains a repeating unit derived from the macromonomer. The so-called macromonomer system has a polymerizable functional group at the terminal and a polymer monomer with a high molecular weight skeleton component. The glass transition temperature (Tg) of the macromonomer is preferably higher than the glass transition temperature of the copolymer component constituting the acrylic copolymer (A1). Specifically, since the glass transition temperature (Tg) of the macromonomer will affect the heating melting temperature (hot melting temperature) of the adhesive material layer 2, the glass transition temperature (Tg) of the macromonomer is preferably 30 ° C to 120 Among these, it is more preferably 40 ° C or more or 110 ° C or less, and more preferably 50 ° C or more or 100 ° C or less. If it is such a glass transition temperature (Tg), it can maintain excellent processability or storage stability by adjusting molecular weight, and it can be adjusted by hot-melting around 80 degreeC. The so-called glass transition temperature of the macromonomer refers to the glass transition temperature of the macromonomer itself, which can be measured by a differential scanning calorimeter (DSC). In addition, in order to maintain the branched components close to each other at room temperature, the adhesive composition is physically cross-linked, and the physical cross-linking can be released by heating to a moderate temperature to obtain flow. It is also preferable to adjust the molecular weight or content of the macromonomer. From this viewpoint, the macromonomer is preferably contained in the acrylic copolymer (A1) in a proportion of 5% to 30% by mass, and among them, 6% by mass or more or 25% by mass or less is preferred, and among these, It is 8 mass% or more and 20 mass% or less. The number average molecular weight of the macromonomer is preferably 500 or more and less than 8,000, of which 800 or more or 7500 is preferred, and 1000 or more or 7,000 is preferred. As the macromonomer, an ordinary manufacturer (for example, a macromonomer produced by Toa Kosei, etc.) can be appropriately used. The high molecular weight skeleton component of the macromonomer preferably contains an acrylic polymer or an ethylene polymer. Examples of the high molecular weight skeleton component of the macromonomer include methyl (meth) acrylate, ethyl (meth) acrylate, propyl (meth) acrylate, isopropyl (meth) acrylate, and (methyl) Base) n-butyl acrylate, isobutyl (meth) acrylate, second butyl (meth) acrylate, third butyl (meth) acrylate, amyl (meth) acrylate, isopropyl (meth) acrylate Amyl ester, neopentyl (meth) acrylate, hexyl (meth) acrylate, cyclohexyl (meth) acrylate, heptyl (meth) acrylate, 2-ethylhexyl acrylate, n-octyl acrylate, Isooctyl acrylate, nonyl (meth) acrylate, isononyl (meth) acrylate, tert-butylcyclohexyl (meth) acrylate, decyl (meth) acrylate, isodecyl (meth) acrylate Ester, undecyl (meth) acrylate, lauryl (meth) acrylate, cetyl (meth) acrylate, stearyl (meth) acrylate, isostearyl (meth) acrylate, ( Behenyl (meth) acrylate, isopropyl (meth) acrylate, 2-phenoxyethyl (meth) acrylate, 3,5,5-trimethylcyclohexyl acrylate, p-cumylphenol EO modified (A (Meth) acrylate, dicyclopentyl (meth) acrylate, dicyclopentenyl (meth) acrylate, dicyclopentenyloxy (meth) acrylate, benzyl (meth) acrylate, (meth) acrylic acid Hydroxyalkyl ester, (meth) acrylic acid, glycidyl (meth) acrylate, (meth) acrylamide, N, N-dimethyl (meth) acrylamide, (meth) acrylonitrile, (Meth) acrylate monomers such as alkoxyalkyl (meth) acrylates, alkoxy polyalkylene glycol (meth) acrylates; or styrene, third butylstyrene, α- Various vinyl monomers such as methylstyrene, vinyl toluene, alkyl vinyl monomer, vinyl acetate, alkyl vinyl ether, and hydroxyalkyl vinyl ether, and these can be used alone or in combination of two or more kinds. Examples of the terminal polymerizable functional group of the macromonomer include a methacryl group, acryl group, and vinyl group. (Crosslinking agent (b)) The crosslinking agent (b) can be used as a crosslinking monomer for crosslinking an acrylate polymer. For example, it has a material selected from the group consisting of (meth) acrylfluorenyl, epoxy, isocyanate, carboxyl, hydroxyl, carbodiimide, oxazoline, aziridinyl, vinyl, amino, and imine. As the crosslinking agent of at least one type of crosslinkable functional group among the amino group and the sulfonylamino group, one type may be used or two or more types may be used in combination. The crosslinkable functional group may be protected by a protective group capable of being deprotected. Among them, a polyfunctional (meth) acrylate having two or more (meth) acrylfluorenyl groups can be preferably used; having two or more isocyanate groups, epoxy groups, melamine groups, glycol groups, and siloxanes Multifunctional organic functional resins with organic functional groups such as amine and amine groups; organometallic compounds with metal complexes such as zinc, aluminum, sodium, zirconium, and calcium. Examples of the polyfunctional (meth) acrylate include 1,4-butanediol di (meth) acrylate, neopentyl glycol di (meth) acrylate, and glycerol di (meth) acrylate , Glycerol glycidyl ether di (meth) acrylate, 1,6-hexanediol di (meth) acrylate, 1,9-nonanediol di (meth) acrylate, tricyclodecane dimethanol (Meth) acrylate, bisphenol A polyethoxydi (meth) acrylate, bisphenol A polyalkoxydi (meth) acrylate, bisphenol F polyalkoxydi (meth) acrylic acid Ester, polyalkylene glycol di (meth) acrylate, trimethylolpropane trioxyethyl (meth) acrylate, ε-caprolactone modified tri (2-hydroxyethyl) isocyanate Uric acid tri (meth) acrylate, pentaerythritol tri (meth) acrylate, pentaerythritol tri (meth) acrylate, pentaerythritol tri (meth) acrylate ethoxylate, pentaerythritol tetra (meth) acrylate , Pentaerythritol tetrakis (meth) acrylate propionate, pentaerythritol tetra (meth) acrylate ethoxylate, dipentaerythritol hexa (meth) acrylate, polyethylene glycol di (meth) acrylate, (Propylene ethoxyethyl) isocyanurate, pentaerythritol tetra (meth) acrylate, dipentaerythritol hexa (meth) acrylate, dipentaerythritol penta (meth) acrylate, tripentaerythritol hexa (methyl) Acrylate, tripentaerythritol penta (meth) acrylate, hydroxy-pivalate neopentyl glycol di (meth) acrylate, ε-caprolactone adducts of hydroxypivalate neopentyl glycol (two) Base) acrylate, trimethylolpropane tri (meth) acrylate, alkoxylated trimethylolpropane tri (meth) acrylate, bis (trimethylolpropane) tetra (meth) acrylate, etc. Examples of the hardening type polyfunctional monomer include polyester (meth) acrylate, epoxy (meth) acrylate, (meth) acrylate urethane, and polyether (methyl ) Multifunctional acrylate oligomers such as acrylate. Among the above, from the viewpoint of improving the adhesion to the adherend or suppressing the effect of moist heat and whitening, it is preferable that the above-mentioned polyfunctional (meth) acrylate monomer contains a hydroxyl group, a carboxyl group, and an amido group. Polyfunctional monomer or oligomer with isopolar functional groups. Among these, it is preferable to use a polyfunctional (meth) acrylate having a hydroxyl group or an amido group. From the viewpoint of preventing moist heat whitening, as the main chain component of the (meth) acrylate copolymer, for example, a graft copolymer, a hydrophobic acrylate monomer and a hydrophilic acrylate monomer are preferred, Furthermore, it is preferable to use a polyfunctional (meth) acrylate which has a hydroxyl group as a crosslinking agent. In addition, in order to adjust effects such as adhesion, moisture and heat resistance, and heat resistance, a monofunctional or polyfunctional (meth) acrylate that reacts with a crosslinking agent may be further added. From the viewpoint of balancing the flexibility and cohesion of the adhesive composition, the content of the crosslinking agent is preferably contained in a proportion of 0.1 to 20 parts by mass relative to 100 parts by mass of the (meth) acrylic copolymer. Among them, particularly preferred is a ratio of 0.5 parts by mass or more or 15 parts by mass or less, and particularly preferred is a ratio of 1 part by mass or more or 13 parts by mass or less. (Photopolymerization initiator (c)) When the acrylate polymer is crosslinked, a crosslinking initiator (peroxidation initiator, photopolymerization initiator) or a reaction catalyst (tertiary amine system) is appropriately added if appropriate. Compounds, quaternary ammonium compounds, tin laurate compounds, etc.) are more effective. In the case of cross-linking by ultraviolet irradiation, it is preferred to blend a photopolymerization initiator (c). Photopolymerization initiators (c) are roughly classified into two types according to the mechanism of free radical generation, and are roughly divided into: photocatalytic initiators which can break the single bond of the photopolymerizable initiator itself to generate free radicals ; And a photo-excited photopolymerization initiator that forms an excitation complex with the hydrogen donor in the system and enables hydrogen transfer by the hydrogen donor. Among these, the cleavage type photopolymerization initiator decomposes into other compounds when free radicals are generated by light irradiation, and once excited, it loses its function as a reaction initiator. Therefore, if the intramolecular cleavage type is used as a photopolymerization initiator having an absorption wavelength in the visible light region, compared with the case of using a hydrogen abstraction type, after the adhesive sheet is crosslinked by light irradiation, the light reacts. Photopolymerizable initiators are preferred because they remain as unreacted residues in the present adhesive composition, leading to unpredictable changes over time in the adhesive sheet or to promote cross-linking. In addition, as for the coloring peculiar to the photopolymerizable initiator, it is also possible to appropriately select a color that decolorizes by disappearing absorption in the visible region by becoming a reaction decomposition product. On the other hand, when the photopolymerization initiator of the hydrogen abstraction type is irradiated with active energy rays such as ultraviolet rays to generate a radical reaction, it does not generate a decomposition product such as a cleavage type photopolymerization initiator, so it is difficult after the reaction is completed. It becomes a volatile component, which can reduce the damage to the adherend. Examples of the cleavage type photopolymerization initiator include 2,2-dimethoxy-1,2-diphenylethane-1-one, 1-hydroxycyclohexylphenyl ketone, and 2-hydroxy- 2-methyl-1-phenyl-propane-1-one, 1- (4- (2-hydroxyethoxy) phenyl) -2-hydroxy-2-methyl-1-propane-1-one, 2-hydroxy-1- [4- {4- (2-hydroxy-2-methyl-propanyl) benzyl} phenyl] -2-methyl-propane-1-one, oligo (2-hydroxy 2-methyl-1- (4- (1-methylvinyl) phenyl) acetone), methyl phenylglyoxylate, 2-benzyl-2-dimethylamino-1- (4- Phenylphenyl) butane-1-one, 2-methyl-1- [4- (methylthio) phenyl] -2-olinylpropane-1-one, 2- (dimethylamino)- 2-[(4-methylphenyl) methyl] -1- [4- (4-olinyl) phenyl] -1-butanone, bis (2,4,6-trimethylbenzyl) ) -Phenylphosphine oxide, 2,4,6-trimethylbenzylidene diphenylphosphine oxide, (2,4,6-trimethylbenzylidene) ethoxyphenylphosphine oxide, bis (2,6-dimethoxybenzylidene) 2,4,4-trimethylpentylphosphine oxide, or derivatives thereof. Among these, bis (2,4,6-trimethylbenzyl) -phenyl is preferred in terms of discoloration due to cleavage-type photopolymerizable initiator as a decomposition product after the reaction. Phosphine oxide, 2,4,6-trimethylbenzylidene diphenylphosphine oxide, (2,4,6-trimethylbenzylidene) ethoxyphenylphosphine oxide, bis (2,6 -Dimethoxybenzylidene) fluorenylphosphine oxide-based photoinitiators such as 2,4,4-trimethylpentylphosphine oxide. Further, in terms of compatibility with an acrylic copolymer including a graft copolymer having a macromonomer as a branched component, it is preferable to use 2,4,6-trimethylbenzyldiphenyl Phosphine oxide, (2,4,6-trimethylbenzyl) ethoxyphenyl phosphine oxide, bis (2,6-dimethoxybenzyl) 2,4,4-trimethyl Amylphosphine oxide and the like serve as a photopolymerization initiator. The content of the photopolymerization initiator is not particularly limited. For example, based on 100 parts by mass of the (meth) acrylic copolymer, 0.1 to 10 parts by mass, particularly preferably 0.2 parts by mass or more or 5 parts by mass or less, particularly preferably 0.5 parts by mass or more, or 3 parts by mass. It is contained in the following ratio. However, in terms of balance with other elements, this range can also be exceeded. The photopolymerization initiator may be used singly or in combination of two or more kinds. In addition to the above ingredients, pigments such as pigments or dyes with near-infrared absorbing properties, adhesion-imparting agents, antioxidants, anti-aging agents, hygroscopic agents, ultraviolet absorbers, silane coupling agents, natural materials, or synthetics can be appropriately blended as needed. Additives such as resins, glass fibers or glass beads. (Layer Structure and Thickness of the Adhesive Material Layer) In addition to the single layer, the adhesive material layer may be a plurality of layers such as two layers and three layers. In addition, the adhesive material layer may have a base material layer (a layer having no adhesiveness) as a core layer, and a layer including an adhesive material layer is laminated on both sides of the base material layer. In the case of such a structure, it is preferable that the base material layer which is a core layer has a material or a characteristic which becomes possible to heat-mold an adhesive sheet laminated body. The adhesive material layer other than the base material layer preferably has a loss tangent tanδ (SA), a loss tangent tanδ (SB), a storage elastic modulus G '(SA), and a storage elastic modulus G' (SB). The above characteristics. The thickness of the adhesive material layer is not particularly limited. Among these, a range of 20 μm to 500 μm is preferred. If it is within this range, for example, if it is a thin adhesive material layer having a thickness of 20 μm, for example, an adhesive sheet having excellent followability in printing steps can be provided. In addition, if it is a thick adhesive material layer having a thickness of 500 μm, it is possible to suppress the overflow of the adhesive material during bonding by forming an amount equivalent to a printing step in advance. Therefore, the thickness of the adhesive material layer is preferably 20 μm to 500 μm, in which the thickness is more preferably 30 μm or more or 300 μm or less, and further preferably 50 μm or more or 200 μm or less. <Coated part I> As shown in FIG. 1, this adhesive sheet laminated body is provided with the following coated part I, which is laminated on one of the front side and the back side of the adhesive material layer in a peelable manner, for example, the front side Shaped uneven side. The storage elastic modulus E '(MA) of the coating portion I at 100 ° C is preferably 1.0 × 10 ⁶ ～ 2.0 × 10 ⁹ Pa. Since the temperature for the heat-molding of the adhesive sheet laminate is generally 70 to 120 ° C, the storage elastic modulus E '(MA) at 100 ° C is 1.0 × 10 ⁶ ～ 2.0 × 10 ⁹ Pa, in the temperature range in which the above-mentioned adhesive composition is plasticized to flow, the coating portion I can also fully follow the uneven shape and deform. Not only this, but also an adhesive material layer that can be squeezed by the coating portion I during molding. The surface is formed with a desired uneven shape with high accuracy, for example, to avoid corner rounding. Previously, as a release film laminated on an adhesive sheet, a material having a higher storage elastic modulus, in other words, a "harder" material was used. The reason is that the characteristics required for the release film are mainly protection of the adhesive material layer and release properties. However, according to research by the present inventors, it has been found that in the case of a new application in which a release film is laminated on an adhesive sheet for thermoforming, when a new issue of thermoformability is required, The physical properties of the film as described above cannot meet the requirements. Therefore, a detailed investigation was performed on the phenomenon occurring during thermoforming or the characteristics of the adhesive layer. As a result, it was found that a characteristic different from the release film that has been conventionally used to solve the new problem of thermoformability In terms of advantages. It has been found that the above-mentioned problems can be solved especially by controlling the storage elastic modulus at a specific range to a specific range. From this viewpoint, the storage elastic modulus E '(MA) of the coating portion I at 100 ° C is preferably 1.0 × 10. ⁶ ～ 2.0 × 10 ⁹ Pa, more preferably 5.0 × 10 ⁶ Above Pa or 1.0 × 10 ⁹ Pa or less, more preferably 1.0 × 10 ⁷ Above Pa or 5.0 × 10 ⁸ Pa or less. Accordingly, the storage elastic modulus E '(MA) of the coating portion I at 100 ° C is more preferably 1.0 × 10 ⁶ ～ 1.0 × 10 ⁹ Pa, or 1.0 × 10 ⁶ ～ 5.0 × 10 ⁸ Pa, of which, more preferably 5.0 × 10 ⁶ ～ 2.0 × 10 ⁹ Pa, or 5.0 × 10 ⁶ ～ 1.0 × 10 ⁹ Pa, the best is 1.0 × 10 ⁷ ～ 1.0 × 10 ⁹ Pa or less, or 1.0 × 10 ⁷ ～ 5.0 × 10 ⁸ Pa. The storage elastic modulus E '(MB) of the coating portion I at 30 ° C is preferably 5.0 × 10. ⁷ ～ 1.0 × 10 ¹⁰ Pa. If the storage elastic modulus E '(MB) of the coated part I at 30 ° C is 5.0 × 10 ⁷ ～ 1.0 × 10 ¹⁰ Pa can maintain shape retention under normal conditions, so it is easier to handle, such as easy peeling. Not only that, because it is not too hard, it can prevent the adhesive material layer from forming irregularities that are not intended. From this point of view, the storage elastic modulus E '(MB) of the coating portion I at 30 ° C is preferably 5.0 × 10. ⁷ ～ 1.0 × 10 ¹⁰ Pa, more preferably 1.0 × 10 ⁸ Above Pa or 8.0 × 10 ⁹ Pa or less, more preferably 1.0 × 10 ⁹ Above Pa or 5.0 × 10 ⁹ Pa or less. According to this, the storage elastic modulus E '(MB) of the coating portion I at 30 ° C is more preferably 5.0 × 10 ⁷ ～ 8.0 × 10 ⁹ Pa, or 5.0 × 10 ⁷ ～ 5.0 × 10 ⁹ Pa, of which, more preferably 1.0 × 10 ⁸ Pa ～ 1.0 × 10 ¹⁰ Pa, or 1.0 × 10 ⁸ Pa ～ 8.0 × 10 ⁹ Pa, the best is 1.0 × 10 ⁹ ～ 8.0 × 10 ⁹ Pa, or 1.0 × 10 ⁹ ～ 5.0 × 10 ⁹ Pa. In order to adjust the storage elastic modulus of the coating portion I at 30 ° C and 100 ° C as described above, the coating portion I can be adjusted by, for example, adjusting the type of base resin, copolymer resin component, weight average molecular weight, glass transition temperature, crystallinity, and the like The material conditions are adjusted by adjusting the production conditions such as the presence or absence of extension, forming conditions, and adjustment of extension conditions in the case of extension. It is not limited to these methods. Furthermore, it is preferable that the storage elastic modulus E '(MA) of the coating portion I at 100 ° C and the storage elastic modulus E' (MB) of the coating portion I at 30 ° C satisfy the following relational expression (1). (1) ・ ・ E '(MB) / E' (MA) ≧ 2.0 If the storage elastic modulus E '(MA) of the coating part I at 100 ° C and the storage elastic modulus E of the coating part I at 30 ° C '(MB) satisfies the above-mentioned relational expression (1), and since sufficient moldability can be obtained, it is more preferable. From this viewpoint, E '(MB) / E' (MA) ≧ 2.0 is preferred, and 30′E ′ (MB) / E '(MA) or E' (MB) / E 'is further preferred. (MA) ≧ 3.0, with 10 ≧ E '(MB) / E' (MA) or E '(MB) / E' (MA) ≧ 5.0 being particularly preferred. In order to adjust the relationship between E '(MB) and E' (MA) as described above, for example, the material of the coating portion I can be adjusted by adjusting the type of base resin, copolymer resin component, weight average molecular weight, glass transition temperature, and crystallinity. Conditions, and adjust the production conditions such as the presence or absence of drawing, forming conditions, and adjustment of the drawing conditions when drawing. It is not limited to these methods. Furthermore, it is preferable that the storage elastic modulus G '(SA) of the adhesive material layer at 100 ° C and the storage elastic modulus E' (MA) of the coating portion I at 100 ° C satisfy the following relationship (2) ). (2) ・ ・ 1.0 × 10 ³ ≦ E '(MA) / G' (SA) ≦ 1.0 × 10 ⁷ If the storage elastic modulus G '(SA) of the adhesive material layer at 100 ° C and the storage elastic modulus E' (MA) of the coating portion I at 100 ° C satisfy the above-mentioned relational expression (2), it is possible to obtain sufficient The formability is better. From this viewpoint, E '(MA) / G' (SA) is preferably 1.0 × 10. ³ ～ 1.0 × 10 ⁷ Of which the best is 5.0 × 10 ³ Above or 5.0 × 10 ⁶ Below, especially preferred is 1.0 × 10 ⁴ Above or 1.0 × 10 ⁶ the following. Based on this, E '(MA) / G' (SA) is more preferably 1.0 × 10 ³ ～ 5.0 × 10 ⁶ , Or 1.0 × 10 ³ ～ 1.0 × 10 ⁶ , And further preferably 5.0 × 10 ³ ～ 5.0 × 10 ⁶ , Or 5.0 × 10 ³ ～ 1.0 × 10 ⁶ , The best is 1.0 × 10 ⁴ ～ 5.0 × 10 ⁶ , Or 1.0 × 10 ⁴ ～ 1.0 × 10 ⁶ . In order to adjust E '(MA) and G' (SA) to the above-mentioned relationship, the characteristics of the adhesive material layer or the coating portion I may be adjusted. The characteristics of the adhesive material layer can be achieved, for example, by adjusting the components of the composition constituting the adhesive material layer, the gel fraction, the weight average molecular weight, and the like. In addition, as the characteristics of the coating portion I, for example, the conditions of the material of the coating portion I, such as the type of the base resin, the copolymer resin component, the weight average molecular weight, the glass transition temperature, and crystallinity, can be adjusted, and the presence or absence of elongation and molding conditions can be adjusted. In the case of extension, adjust the manufacturing conditions such as extension conditions. It is not limited to these methods. The peeling force F (C) of the coated portion I when the coated portion I is peeled from the adhesive material layer in a 30 ° C environment is preferably 0.2 N / cm or less. When the peeling force F (C) is 0.2 N / cm or less, the coating portion I can be easily peeled from the adhesive material layer. From this point of view, the peeling force F (C) is preferably 0.2 N / cm or less, more preferably 0.01 N / cm or more or 0.15 N / cm or less, and even more preferably 0.02 N / cm or more. 0.1 N / cm or less. Further, for the coating part I, the adhesive sheet laminate was heated at 100 ° C for 5 minutes, and then cooled to 30 ° C. The peeling force F (D) when the coating part I was peeled from the adhesive layer at 30 ° C It is preferably 0.2 N / cm or less. If the adhesive sheet laminate is heated at 100 ° C for 5 minutes and then cooled to 30 ° C, and the peel force F (D) measured under the environment of 30 ° C is the same as the above-mentioned peel force F (C), even if the The adhesive sheet laminate is formed by heating, and the peeling force F (D) does not change. Therefore, the coating portion I can be easily peeled from the adhesive layer. From this viewpoint, the peeling force F (D) is preferably 0.2 N / cm or less, more preferably 0.01 N / cm or more or 0.15 N / cm or less, and even more preferably 0.02 N / cm or more. 0.1 N / cm or less. Furthermore, it is preferable that the absolute value of the difference between the peeling force F (C) and the peeling force F (D) of the coating portion I is 0.1 N / cm or less. If the laminated sheet is heated at 100 ° C for 5 minutes and then cooled to 30 ° C, the absolute difference between the peeling force F (D) measured at 30 ° C and the peeling force F (C) under normal conditions is absolute. When the value is 0.1 N / cm or less, the peeling force F (D) does not change even if the adhesive sheet laminate is thermoformed, so that the coating portion I can be easily peeled from the adhesive material layer. From this viewpoint, the absolute value of the difference between the peeling force F (C) and the peeling force F (D) is preferably 0.1 N / cm or less, more preferably 0.08 N / cm or less, and even more preferably 0.05. N / cm or less. The peeling force F (C) and the peeling force F (D) of the coating portion I can be adjusted by the type of the release layer formed on one side of the coating portion I, and the like. It is not limited to this method. Examples of the configuration of the coating portion I include a configuration example including a coating base layer and a release layer. By forming a single-area release layer on the covering base material layer, the covering portion I can be configured to be easily peeled from the adhesive material layer. In this case, the coated base material layer preferably includes, as a main component, one resin or two or more resins selected from the group consisting of polyester, copolymerized polyester, polyolefin, and copolymerized polyolefin. A stretched or unstretched layer, that is, a single or multi-layer containing a stretched or unstretched film with the resin as the main component. Among these, the coating base material layer constituting the coating portion I is preferably provided with an extension containing, for example, a copolymerized polyester, a polyolefin, or a copolymerized polyolefin as a main component from the viewpoints of mechanical strength and chemical resistance. Or single or multiple layers of unstretched film. Specific examples of the above-mentioned copolymerized polyester include, for example, any of phthalic acid as a dicarboxylic acid and cyclohexanedimethanol as a diol, 1,4-butanediol, and diethylene glycol. Copolymerized polyethylene terephthalate. Specific examples of the polyolefin include an α-olefin homopolymer, and examples include a propylene homopolymer and a homopolymer of 4-methylpentene-1. Specific examples of the polyolefin copolymer include copolymers of ethylene, propylene, other α-olefins, and vinyl monomers. The release layer is preferably a layer containing a modified polyolefin in addition to a release agent such as polysiloxane. Here, as a modified olefin which comprises the said release layer, the resin which has polyolefin modified by unsaturated carboxylic acid or its anhydride, or a silane coupling agent as a main component is mentioned. Examples of the unsaturated carboxylic acid or its anhydride include acrylic acid, methacrylic acid, maleic acid, maleic anhydride, citraconic acid, citraconic anhydride, itaconic acid, itaconic anhydride, or the like A monoepoxy compound of a derivative and an ester compound of the above-mentioned acid, a reaction product of a polymer and an acid having a group capable of reacting with these acids in the molecule, and the like. Moreover, these metal salts can also be used. Among these, maleic anhydride can be more preferably used. Moreover, these copolymers can be used individually or in mixture of 2 or more types. In order to produce a modified polyolefin-based resin, for example, the modified monomer may be copolymerized in advance at the stage of polymerizing the polymer, or the temporarily polymerized polymer may be graft-copolymerized with the modified monomer. . In addition, as the modified polyolefin-based resin, these modified monomers may be used alone or in combination, and the content ratio thereof is preferably 0.1% by mass or more, preferably 0.3% by mass or more, and further preferably 0.5. The mass range is at least 5 mass%, preferably at most 4.5 mass%, and more preferably at most 4.0 mass%. Among them, those graft-modified can be suitably used. Suitable examples of the modified polyolefin-based resin include maleic anhydride-modified polypropylene resin, maleic anhydride-modified polyethylene resin, maleic anhydride ethylene-vinyl acetate copolymer, and the like. . From the viewpoint of moldability, the thickness of the coating portion I is preferably from 10 μm to 500 μm, particularly preferably 20 μm or more or 300 μm or less, and particularly preferably 30 μm or more or 150 μm or less. <Coated part II> As described above, the present adhesive sheet laminate can be used to laminate the coated part I in a peelable manner on one of the front and back sides of the adhesive layer, and on the opposite side to the coated part I, that is, The other side of the front surface and the back surface of the adhesive material layer is formed by laminating the covering part II in a peelable manner. Therefore, the workability can be improved by laminating the coating portion II on the other side of the front surface and the back surface of the adhesive material layer in a peelable manner. However, it is also possible to adopt a configuration in which the coating portion II is not laminated. As long as the coating portion II is formed by laminating on the other side of the front surface and the back surface of the adhesive material layer in a peelable manner, the material and structure thereof are not particularly limited. The coating portion II may be, for example, the same laminated structure and material as the coating portion I described above. In this case, the coating portion II may have the same thickness as the coating portion I or a different thickness. If the covering portion II has the same laminated structure and material as the covering portion I, it is possible to prevent warping from occurring when the present adhesive sheet laminate is heated. The coating part II can also adopt the same structure as the coating part I, but the storage elastic modulus E '(MA) at 100 ° C, the storage elastic modulus E' (MB) at 30 ° C, and the ratio (E '(MB) / E' (MA)), peeling force F (C), peeling force F (D), and the like are different from those of the coating portion I. Furthermore, the coating part II may be a laminated structure and a material different from those of the coating part I described above. As the coating portion II, for example, a commonly used release film (also referred to as a "release film") may be used. Specifically, the storage elastic modulus E '(MC) at 100 ° C is 2.0 × 10. ⁹ ～ 1.0 × 10 ¹¹ As the material of Pa, for example, a biaxially stretched polyethylene terephthalate (PET) film can be used. [Coated Part I] As a configuration example of the coated part I described above, a coating film having a coating layer provided on one side of a copolymerized polyester film, and a storage elastic modulus E ′ at 100 ° C. of 1.5 × 10 ⁹ A coating film (hereinafter referred to as "the present coating film") characterized by Pa will be described. If this coating film is used, for example, after heating the above-mentioned adhesive sheet laminate, a mold is pressed against the coating film provided with a release coating layer, and the adhesive sheet can be formed on the adhesive sheet. The surface is formed with an uneven shape conforming to the uneven portion on the surface of the adherend with high accuracy. In addition, since the coating film can maintain shape retention in a normal state, it is easy to handle. Moreover, since the coating film is not too hard, it can prevent the adhesive sheet from forming irregularities that are not intended. <Copolymerized Polyester Film> The copolymerized polyester film constituting the coating film may have a single-layer structure or a laminated structure. For example, in addition to the two-layer and three-layer structures, as long as the purpose of the present invention is not exceeded, The number of layers may be four or more, and it is not particularly limited. For example, when a three-layer structure (surface layer / intermediate layer / surface layer) is used, any one layer of the surface layer or the intermediate layer, or a layer of two or more layers may be used as the copolymer polyester component, and the remaining The layer is constituted by a polyester component containing no copolymerization component. The copolymerized polyester film refers to a film obtained by cooling a molten polyester sheet extruded by an extrusion method and stretching it if necessary. The dicarboxylic acid component of the copolymerized polyester is preferably terephthalic acid. In addition, it may also contain oxalic acid, malonic acid, succinic acid, adipic acid, azelaic acid, sebacic acid, and phthalic acid. One or more known dicarboxylic acids such as dicarboxylic acid, isophthalic acid, naphthalenedicarboxylic acid, diphenyl ether dicarboxylic acid, and cyclohexanedicarboxylic acid are used as the copolymerization component. In addition, as the diol component, ethylene glycol is preferred, and in addition thereto, it may contain propylene glycol, trimethylene glycol, tetramethylene glycol, hexamethylene glycol, and 1,4-cyclohexane. One or more kinds of well-known glycols such as dimethanol, diethylene glycol, triethylene glycol, polyalkylene glycol, neopentyl glycol, etc., are used as the copolymerization component. Among them, phthalic acid, isophthalic acid as a dicarboxylic acid component, 1,4-cyclohexanedimethanol, 1,4-butanediol, and diethylene glycol as diol components are more preferable. Copolymerized polyethylene terephthalate which is arbitrarily copolymerized. The content of the copolymerization component is preferably 1 mol% or more and 50 mol% or less, more preferably 3 mol% or more or 40 mol% or less, and further preferably 4 mol% or more or 30 mol% or less. When the content of the copolymerization component is 1 mol% or more, when it is laminated with the adhesive sheet, a concave shape, a convex shape, or an uneven shape can be formed on the surface of the adhesive sheet. On the other hand, when it is 50 mol% or less, it not only has sufficient dimensional stability, but also can sufficiently suppress the occurrence of wrinkles during processing. The melting point of the copolymerized polyester film is preferably designed to be in a range of preferably 260 ° C or lower, more preferably 200 to 255 ° C. With the above melting point being 260 ° C. or lower, in the heat treatment step after stretching, sufficient strength can be obtained even if the heat treatment is performed at a temperature lower than the melting point of the copolymerized polyester film. In terms of improving the workability of the film, it is preferable to include particles in the copolymerized polyester film. Examples of particles include inorganic particles such as calcium carbonate, magnesium carbonate, calcium sulfate, barium sulfate, lithium phosphate, magnesium phosphate, calcium phosphate, lithium fluoride, alumina, silica, and kaolin; acrylic resins, guanamine resins, and the like Organic particles; precipitated particles obtained by granulating the catalyst residuals, but it is not limited to these. The particle diameter of these particles or the content in the copolymerized polyester film can be appropriately determined according to the purpose. The contained particles may be a single component or two or more components may be used simultaneously. Various stabilizers, lubricants, antistatic agents, and the like may be appropriately added. The average particle diameter of the particles contained in the copolymerized polyester film is preferably 0.1 to 5.0 μm. When the average particle diameter of the particles is less than 0.1 μm, the sliding properties of the film may be insufficient and the workability may be reduced. On the other hand, when the average particle diameter of the particles exceeds 5.0 μm, the smoothness of the film surface may be impaired. The content of the particles contained in the copolymerized polyester film is preferably 0.01 to 0.3% by weight. When the content of the particles is less than 0.01% by weight, the sliding properties of the film may be insufficient and the workability may be reduced. On the other hand, when the content of the particles exceeds 0.3% by weight, the smoothness of the film surface may be impaired. The method for adding particles to the copolymerized polyester film is not particularly limited, and a known method can be adopted. For example, it can be added at any stage of manufacturing polyester, preferably at the stage of esterification, or it can also be added in the form of a slurry dispersed in ethylene glycol, etc. at the stage before the polycondensation reaction after the transesterification reaction is completed Instead, a polycondensation reaction is performed. In addition, by using a kneading extruder with a vent hole, a method of blending a slurry of particles dispersed in ethylene glycol or water with a polyester material, or using a kneading extruder to dry the particles A method of blending with a polyester raw material, a method of precipitating particles in a polyester manufacturing step system, and the like are performed. The limiting viscosity of the copolymerized polyester is usually 0.40 to 1.10 dl / g, preferably 0.45 to 0.90 dl / g, and further preferably 0.50 to 0.80 dl / g. If the limiting viscosity does not reach 0.40 dl / g, there is a tendency for the mechanical strength of the film to become weaker. When the limiting viscosity exceeds 1.10 dl / g, there is a case where the melt viscosity becomes high and excessive load is applied to the extruder. situation. Next, although the manufacturing example of a copolymerized polyester film is demonstrated concretely, it is not limited at all by the following manufacturing examples. The method is preferably as follows: first, using the previously described copolymerized polyester raw material, the molten sheet extruded from the die is cooled and solidified by a cooling roller to obtain an unstretched sheet. In this case, in order to improve the flatness of the sheet, it is necessary to improve the adhesion between the sheet and the rotary cooling drum. The electrostatic application and / or liquid coating adhesion method can be preferably used. Further, it is preferable to extend the obtained unstretched sheet at least in a uniaxial direction, and more preferably a biaxial extension in a biaxial direction. For example, in the case of biaxial stretching, in the case of sequential biaxial stretching, the unstretched sheet is stretched in one direction in a mechanical direction by a roller or a stretching machine. The stretching temperature is usually 70 to 120 ° C, preferably 75 to 110 ° C, and the stretching ratio is usually 2.5 to 7.0 times, preferably 3.0 to 6.0 times. Secondly, it extends in a direction perpendicular to the extending direction (mechanical direction) of the first stage. The stretching temperature is usually 70 to 170 ° C, and the stretching ratio is usually 3.0 to 7.0 times, preferably 3.5 to 6.0 times. Then, heat treatment is continued at a temperature of 150 to 270 ° C under stretching or relaxation within 30% to obtain a biaxial alignment film. In the above-mentioned biaxial extension, a method of performing two or more stages of extension in one direction may also be adopted. In this case, it is preferable to carry out in such a manner that the stretching magnifications in the two directions finally become the above ranges, respectively. In addition, as for the production of the copolymerized polyester film, simultaneous biaxial stretching may be adopted. At the same time, biaxial stretching is a method in which the unstretched sheet is simultaneously stretched and aligned in a mechanical direction and a width direction under a temperature controlled state at generally 70 to 120 ° C, preferably 75 to 110 ° C. The stretching magnification is preferably 4 to 50 times, more preferably 7 to 35 times, and even more preferably 10 to 25 times in terms of area magnification. Then, heat treatment is continued at a temperature of 150 to 250 ° C. under stretching or relaxation within 30% to obtain a biaxially stretched film. As for the simultaneous biaxial extension device adopting the above-mentioned extension method, a spiral method, a scaler method, a linear drive method, and the like known from the previous can be used. (Coating layer) In this coating film, it is important to provide a coating layer on at least one side of the copolymerized polyester film. The coating layer is not particularly limited, and specific examples include a release layer, an antistatic layer, an oligomer sealing layer, an easy-adhesion layer, and an undercoat layer. Among them, a release layer is more preferable in terms of manufacturing an adhesive sheet laminate which is laminated with an adhesive sheet. Moreover, you may combine two or more types of functional layers as mentioned above. As a specific example of the coating layer constituting the coating film, a release layer will be described below. Specifically, the type of the resin used in the release layer includes hardened silicone resins, fluorine-based resins, and polyolefin-based resins, among which hardened silicone resins are preferred. It can be a hardened silicone resin, or a type containing a hardened silicone resin as the main component. Within the scope of not harming the spirit of the present invention, it can also be used with urethane resin, ring Modified polysiloxane based on graft polymerization of organic resins such as oxygen resins and alkyd resins. As the type of the curing type silicone resin, any curing reaction type such as addition molding, condensation type, ultraviolet curing type, electron beam curing type, and solventless type can be used. Specific examples include KS-774, KS-775, KS-778, KS-779H, KS-847H, KS-856, X-62-2422, and X-62 manufactured by Shin-Etsu Chemical Industry Co., Ltd. -2461, X-62-1387, X-62-5039, X-62-5040, KNS-3051, X-62-1496, KNS320A, KNS316, X-62-1574A / B, X-62-7052, X -62-7028A / B, X-62-7619, X-62-7213; YSR-3022, TPR-6700, TPR-6720, TPR-6672, TPR6500, TPR6501, UV9300, UV9425, XS56- manufactured by Momentive Performance Materials A2775, XS56-A2982, UV9430, TPR6600, TPR6604, TPR6605; SRX357, SRX211, SD7220, SD7292, LTC750A, LTC760A, LTC303E, SP7259, BY24-468C, SP7248S, BY24-452, DKQ3- manufactured by Dow Corning Toray Co., Ltd. 202, DKQ3-203, DKQ3-204, DKQ3-205, DKQ3-210, etc. Furthermore, in order to adjust the peelability of a release layer, etc., a peel control agent may be used together. The hardening conditions when forming a release layer on a copolymerized polyester film are not particularly limited. In the case of providing a release layer by offline coating, it is generally appropriate to perform heat treatment at 120 to 200 ° C for 3 to 40 seconds, preferably at 100 to 180 ° C for 3 to 40 seconds. In addition, if necessary, a combination of heat treatment and active energy ray irradiation such as ultraviolet irradiation may be used. In addition, as an energy source for hardening by active energy ray irradiation, a device and an energy source known from the past can be used. The coating amount of the release layer (after drying) is generally 0.005 to 1 g / m in terms of coating properties. ² The range is preferably 0.005 to 0.5 g / m ² Range, more preferably 0.01 to 0.2 g / m ² Range. The coating amount (after drying) is less than 0.005 g / m ² In some cases, there is a case in which stability is lacking in terms of coatability and it is difficult to obtain a uniform coating film. On the other hand, at more than 1 g / m ² On the other hand, in the case of thick coating, the adhesion and hardenability of the coating film of the release layer itself may be reduced. As a method for providing a release layer on the copolymerized polyester film, a conventionally known method such as reverse gravure coating, direct gravure coating, roll coating, die coating, bar coating, and curtain coating can be used. Of coating method. Regarding the application method, there are recorded examples in "application method" (by Yoshizumi Harajaki, published by 1979). In addition, in order to provide a coating layer on the copolymerized polyester film, surface treatments such as corona treatment, plasma treatment, and ultraviolet irradiation treatment may be performed in advance. (Coated film) The thickness of the coated film is usually 9 μm to 250 μm, preferably 12 μm to 125 μm, and further preferably 25 μm to 75 μm. When the thickness is less than 9 μm, the film tension may become insufficient, and abnormalities such as wrinkles are likely to occur when cutting. On the other hand, if it exceeds 250 μm, for example, the followability to a molded article having a curved shape may be insufficient. The storage elastic modulus E 'of the coating film at 100 ° C is 1.5 × 10 ⁹ Pa or less, preferably 1.0 × 10 ⁹ Pa or less. With the above storage elastic modulus E 'is 1.5 × 10 ⁹ Pa or less, when laminated with the adhesive sheet, a concave shape, a convex shape, or an uneven shape can be formed on the surface of the adhesive sheet. In order to make the storage elastic modulus E ′ at 100 ° C. satisfy the above range, it can be satisfied by adjusting the kind and content of the copolymerization component contained in the copolymerized polyester film. On the other hand, the lower limit is not particularly limited, but is preferably 1.0 × 10. ⁷ Above Pa, more preferably 1.0 × 10 ⁸ Pa or more. The shrinkage of the coating film after heating at 120 ° C for 5 minutes is 3.0% or less, and preferably 2.5% or less. Since the shrinkage ratio is 3.0% or less, it has sufficient dimensional stability. Therefore, when it is laminated with the adhesive sheet, it can form a concave shape, a convex shape, or an uneven shape on the surface of the adhesive sheet. Furthermore, since the occurrence of wrinkles during processing can be suppressed, the wrinkles are not transferred to the adhesive sheet, and an adhesive sheet having a sufficient appearance can be produced. Among them, the shrinkage in the machine direction (MD) after heating at 120 ° C. for 5 minutes is preferably 3.0% or less, and more preferably 2.5% or less. On the other hand, the lower limit is not particularly limited, but is preferably 0.1% or more, and more preferably 0.5% or more. The shrinkage rate in a direction (TD) perpendicular to the mechanical direction after heating at 120 ° C for 5 minutes is preferably 1.0% or less, and more preferably 0.8% or less. On the other hand, the lower limit is preferably -1.0% or more, and more preferably -0.5% or more. From the viewpoint of preventing contamination caused by the adhesion of oligomers (cyclic terpolymers) to the mold during the molding process, the coating film is preferably applied after the heat treatment (180 ° C, 10 minutes). The extraction amount of the layer surface is 1.0 × 10 ^-3 mg / cm ² Below, more preferably 5.0 × 10 ^-4 mg / cm ² the following. When the extraction amount of the oligomer exceeds the above range, there may be a case where the contamination caused by the adhesion of the oligomer to the mold becomes severe during the molding process. As an example, in the process of continuous heating and forming for many times, the mold contamination is promoted due to the deposition of precipitated oligomers, so it is important to control the amount of oligomers deposited during heating. For these reasons, the smaller the amount of extraction of the oligomer, the better. [Manufacturing method of the present adhesive sheet laminated body] As an example of a method of producing the present adhesive sheet laminated body, for example, the following method may be mentioned: the adhesive composition is sandwiched between two coating portions I or II, and a bonding machine is used. Form an adhesive material layer. Moreover, as another method, the method of apply | coating an adhesive composition to the coating part I or II, and forming an adhesive material layer is mentioned. However, it is not limited to this manufacturing method. Examples of the method for applying the adhesive composition include conventionally known coating methods such as reverse roll coating, gravure coating, bar coating, and doctor blade coating. [The present shaped adhesive sheet laminate] The present shaped sheet laminate can be used to make a shaped adhesive sheet laminate 1 having an uneven shape formed on the surface of the adhesive layer as follows (referred to as "this shaped adhesive sheet" Laminated body 1 "). As shown in FIG. 3, the shaped adhesive sheet laminated body 1 can be made with the following components: it has an adhesive material layer 2, and can be laminated on one of the front and back surfaces of the adhesive material layer 2 in a peelable manner. The covering portion I formed on the side and the covering portion II formed on the other side of the front surface and the back surface of the adhesive material layer 2 in a peelable manner. The adhesive material layer 2 is provided on one side surface 2A of the front surface and the back surface. The concave portion, convex portion, or uneven portion (referred to as the "adhesive sheet surface uneven portion 2B"), and the other side surface 2C of the front surface and the back surface is a flat surface, and the covering portion I is in close contact with the front and back surfaces of the adhesive sheet One side surface 2A is provided with a concave portion, a convex portion, or an uneven portion (referred to as a "covered portion surface uneven portion 3B") on one of the front and back side surfaces 3A, and the sheet back surface 3C is provided with the above-mentioned adhesive sheet surface uneven portion 2B matches, in other words, convex, concave or convex portions forming concave and convex portions (referred to as "protective sheet back convex portion 3D"), and the covering portion II is along the front surface and the other side surface 2C of the adhesive sheet 2 Contains flat faces. In addition, the other side surface 2C of the front surface and the back surface can be made into a flat surface as shown in FIG. 3, and the other side surface 2C of the front surface and the back surface can also be formed with a concave portion, a convex portion, or an uneven portion. As shown in FIG. 2, the shaped adhesive sheet laminate 1 having such a structure can be integrated into one body by using the above-mentioned shaped adhesive sheet laminate to perform pressure forming, vacuum forming, pressure forming, or roll forming. It is manufactured by forming an uneven shape on the present adhesive sheet laminate. By manufacturing in the above manner, the uneven portions 2B on the adhesive sheet surface of the adhesive material layer 2, the uneven portions 3B on the protective sheet surface of the covering portion I, and the convex 3D portions on the back of the protective sheet 3 can be formed at the same positions to form unevenness. The adhesive material layer 2 can be used, for example, as a double-sided adhesive sheet for adhering two image display device constituent members (also referred to as “adhered bodies”) constituting the image display device. That is, the concave-convex portion 2B of the adhesive sheet surface in the adhesive layer 2 may correspond to the concave, convex, or concave-convex portion (referred to as "concave-convex portion on the surface of the adherend") in the bonding surface of the adherend. It is preferable to form into the same outline shape. Thereby, the uneven surface part 2B of the adhesive sheet surface in this shaped adhesive sheet laminated body 1 can be fitted with the uneven surface part of the surface of an adherend in an image display device component which is an adherend. Here, examples of the image display device include a liquid crystal display (LCD) and an organic EL (electroluminescence) display device (OLED (organic light emitting diode)). )), Electronic paper, microelectromechanical system (MEMS) displays and plasma display (PDP) smart phones, tablet terminals, mobile phones, televisions, game consoles, personal computers, car navigation systems, ATM (automatic teller machine, fish teller, etc. But it is not limited to these. In addition, the so-called image display device constituent member as an adherend is a member constituting such image display devices, and examples thereof include a surface protection panel, a touch panel, and an image display panel. 1 can be used for bonding any two adherends selected from a surface protection panel, a touch panel, and an image display panel. For example, it can be used for bonding a surface protection panel and a touch panel, or a touch panel and an image display panel. However, the adherend is not limited to these. <Manufacturing method> Here, the manufacturing method of this shaping | molding adhesive sheet laminated body 1 is demonstrated in detail. As described above, as shown in FIG. 2, the present adhesive sheet laminate 1 can be produced by heating and forming the present adhesive sheet laminate 1 in an integrated manner into an uneven shape. In this case, examples of the forming processing method include pressure forming, vacuum forming, pressure forming, forming using a roll, and forming using a laminate. Among these, from the viewpoint of moldability and processability, press molding is particularly preferred. A more detailed specific example will be described. The adhesive sheet laminated body is preheated by a heater, and the adhesive sheet laminated body is transported to a pressure forming machine at a stage of heating to a specific temperature, and a concave-convex shape equivalent to the printing step shape of the adherend is modeled in advance. The mold is press-processed and cooled at the same time, so that the mold shape can be transferred to one side of the present adhesive sheet laminate, and the original shaped adhesive sheet laminate 1 having unevenness formed on one side is manufactured. At this time, the preheating of the adhesive sheet laminate is preferably heated to a temperature at which the adhesive layer is softened, and specifically, it is preferably heated to 70 to 120 ° C. The material of the mold used for the concave-convex forming is not particularly limited. Examples thereof include resin-based materials such as silicone resin and fluororesin, and metal-based materials such as stainless steel and aluminum. Among them, metal molds capable of controlling the temperature at the time of forming are particularly preferable because high-precision formability is required for the concave-convex forming of the adherend. In addition, the cooling after the press working may be performed after the mold is opened, or the mold may be cooled in advance and cooled while being pressurized. Furthermore, in the present invention, conditions for forming such as pressing pressure and pressing time are not particularly specified, and may be appropriately adjusted according to the size or shape to be formed, the materials used, and the like. In addition, after the forming process, a Thomson blade, a rotary cutter, or the like can be used for cutting. [Manufacturing method of this shaped adhesive sheet laminated body] Next, a coating portion I having an adhesive material layer and being laminated on one surface of the adhesive material layer in a peelable manner is provided, and one surface of the adhesive material is provided. A particularly preferred embodiment of a method for manufacturing a laminated adhesive sheet laminate having a configuration in which concave portions, convex portions, or uneven portions (called "concave and convex portions on the surface of an adhesive material layer") are formed will be described. The inventions related to the present manufacturing method 1 and the present manufacturing method 2 described below propose a high-precision concave-convex portion on the surface of the adhesive material layer that can be formed on the surface of the adhesive material layer with high accuracy, preferably A novel method for continuously forming a laminated body of shaped adhesive sheet. As an example of an embodiment of the present invention, a novel method for manufacturing a laminated body of shaped adhesive sheet (referred to as "this manufacturing method 1") is provided. A coating part I formed by laminating on one surface of the adhesive material layer and forming concave, convex, or uneven portions on the one surface of the adhesive material (referred to as "concave and convex portions on the surface of the adhesive material layer"). The manufacturing method is characterized in that it includes an adhesive material layer and a coating portion I formed by laminating on one side of the adhesive material layer in a peelable manner, and heating the adhesive sheet laminate to The adhesive sheet laminated body is formed and cooled to produce a shaped adhesive sheet laminated body, and the adhesive sheet laminated body is heated, and the storage elastic modulus E '(MS) in the coating portion I is 1.0 × 10 ⁶ ～ 2.0 × 10 ⁹ Forming was started in the state of Pa, and the storage elastic modulus E '(MF) of the covering part I was 5.0 × 10 ⁷ ～ 1.0 × 10 ¹⁰ In the state of Pa, forming is completed. In this manufacturing method 1, a novel manufacturing method of the above-mentioned shaped adhesive sheet laminate is further proposed. When the heated adhesive sheet laminate is formed, the cooled mold is used for forming. According to this manufacturing method 1, for example, after the above-mentioned adhesive sheet laminate is heated, the coating portion I starts to be formed in a specific state, and the coating portion I is finished to be formed in a specific state, so that the surface of the adhesive material layer can be highly accurate A concavo-convex shape corresponding to the concavo-convex portions on the surface of the adherend is formed. Furthermore, when the heated adhesive sheet laminate is molded, if the cooled mold is used for molding, the molding can be cooled and completed at the same time, so that the above-mentioned manufacturing method can be continuously performed. <This manufacturing method 1> This manufacturing method 1 is an example of the manufacturing method of the shape | molded adhesive sheet laminated body (it is called "this manufacturing method") which consists of heating the adhesive sheet laminated body described below (heating process) ). A manufacturing method of forming the heated adhesive sheet laminate and cooling (forming and cooling steps). This manufacturing method 1 may include other steps as long as it includes the heating step and the forming and cooling steps described above. For example, if necessary, it may include steps such as a heat treatment step, a conveying step, a cutting step, and a cutting step. It is not limited to these steps. (Adhesive sheet laminated body) The adhesive sheet laminated body as the starting member in this manufacturing method 1 may include an adhesive material layer and a coating portion I formed by laminating on one side of the adhesive material layer in a peelable manner, Other components may be provided. For example, as shown in FIG. 1, there can be exemplified a coating part I including an adhesive material layer, a peelable layer laminated on one of the front and back sides of the adhesive material layer, and a peelable laminated layer on the adhesive. Adhesive sheet laminate of coating part II formed on the front side and the back side of the material layer. However, whether or not the covering part II is provided is arbitrary, and a configuration in which the covering part II is not laminated may be adopted. The details of the laminated sheet are as described above. (Heating step) In this manufacturing method 1, it is preferable to heat the above-mentioned adhesive sheet laminate and set the storage elastic modulus E '(M) of the coating portion I to 1.0 × 10. ⁶ ～ 2.0 × 10 ⁹ State of Pa. If the storage elastic modulus E '(M) of the coating portion I is in the above range, the coating portion I can be deformed to a degree suitable for molding, and the required unevenness can be accurately formed on the surface of the adhesive layer . From this viewpoint, it is preferable that the storage elastic modulus E '(M) of the coating portion I be heated and adhered to the sheet laminate to be 1.0 × 10. ⁶ ～ 2.0 × 10 ⁹ The state of Pa is more preferably 5.0 × 10. ⁶ Above Pa or 1.0 × 10 ⁹ The state below Pa is more preferably 1.0 × 10. ⁷ Above Pa or 5.0 × 10 ⁸ State below Pa. According to this, it is more preferable that the storage elastic modulus E '(M) of the covering portion I is 1.0 × 10 for heating and adhering the sheet laminate. ⁶ ～ 1.0 × 10 ⁹ Pa, or 1.0 × 10 ⁶ ～ 5.0 × 10 ⁸ Among them, it is more preferably set to 5.0 × 10. ⁶ ～ 2.0 × 10 ⁹ Pa, or 5.0 × 10 ⁶ ～ 1.0 × 10 ⁹ The state of Pa is preferably set to 1.0 × 10 ⁷ ～ 1.0 × 10 ⁹ Pa, or 1.0 × 10 ⁷ ～～ 5.0 × 10 ⁸ Of the state. Here, in order to heat-adhere the sheet laminate, the storage elastic modulus E '(M) of the coating portion I is adjusted to be within the above range, and it can be adjusted according to the components or gel fraction of the composition constituting the coating portion I. Ratio, weight average molecular weight, etc., are adjusted by adjusting heating temperature. It is not limited to this method. Furthermore, it is more preferable to heat the above-mentioned adhesive sheet laminate, and set the storage elastic modulus E '(M) of the coating portion I to 1.0 × 10 ⁶ ～ 2.0 × 10 ⁹ Pa, and the storage elastic modulus G '(S) of the adhesive layer is less than 1.0 × 10 ⁴ State of Pa. If the storage elastic modulus E '(M) of the coating portion I is adjusted to the above range, the effects as described above can be obtained. In addition, if the storage elastic modulus G' (S) of the adhesive material layer is less than 1.0 × 10 ⁴ Pa, sufficient moldability can be imparted to the adhesive material layer. From this point of view, it is preferable that the storage elastic modulus E '(M) of the covering portion I be within the above-mentioned range and that the storage elastic modulus G' (S) of the adhesive material layer is not reached by heating the adhesive sheet laminate. 1.0 × 10 ⁴ The state of Pa, preferably 5.0 × 10 ¹ Above Pa or 5.0 × 10 ³ A state of Pa or less, preferably 1.0 × 10 ² Above Pa or 1.0 × 10 ³ State below Pa. According to this, it is more preferable to set the storage elastic modulus E '(M) of the covering part I to be the range described above for heating the adhesive sheet laminate, and the storage elastic modulus G' (S) of the adhesive layer to be 5.0 × 10. ¹ Above Pa and less than 1.0 × 10 ⁴ Pa, or 5.0 × 10 ¹ Above Pa and 5.0 × 10 ³ The state below Pa is more preferably 1.0 × 10. ² Above Pa and less than 1.0 × 10 ⁴ Pa, or 1.0 × 10 ² Above Pa and 5.0 × 10 ³ The state below Pa is preferably 1.0 × 10 ² Above Pa and 1.0 × 10 ³ State below Pa. Here, the storage elastic modulus G '(S) of the adhesive material layer can be adjusted by adjusting the heating temperature according to the components, gel fraction, weight average molecular weight, etc. of the composition constituting the adhesive material layer. It is not limited to this method. Furthermore, it is particularly preferable that the value of the loss tangent tan δ of the adhesive material layer is 1.0 or more in order to heat the adhesive sheet laminate. The loss tangent tan δ will be described below. If the value of the loss tangent tanδ of the adhesive material layer is 1.0 or more, it is preferable that it has a degree of flexibility that can be formed. From this point of view, it is particularly preferable to heat the adhesive sheet laminate so that the value of the loss tangent tan δ of the adhesive layer becomes 1.0 or more, and among these, it is more preferable to make it 1.5 or 20 or less. In order to make it 3.0 or more or 10 or less. But the upper limit is not limited to this. In this manufacturing method 1, it is preferable to heat-adhere a sheet | seat laminated body so that the surface temperature of the coating part I may become 70-180 degreeC. If the surface temperature of the coating portion I is 70 ° C or more, the adhesive material layer is sufficiently softened and the coating portion I can be sufficiently deformed. If it is 180 ° C or less, the occurrence of wrinkles caused by heat shrinkage or heat can be suppressed. The disadvantages such as the decomposition of the adhesive material layer are caused, so it is better. From this viewpoint, it is preferable to heat the above-mentioned adhesive sheet laminate so that the surface temperature of the coating portion I becomes 70 to 180 ° C, more preferably 75 ° C or more or 150 ° C or less, and even more preferably It is 80 ° C or higher or 120 ° C or lower. Examples of the method for heating the adhesive sheet laminated body include a method in which the adhesive sheet laminated body is heated between the upper and lower heating plates provided with heating members such as electric heating heaters from above and below, or directly sandwiched between the heating plates. Holding method, a method using a heating roller, a method of immersing it in hot water, and the like. It is not limited to these methods. (Forming and cooling step) In this step, the heated adhesive sheet laminate is formed as described above, and the adhesive sheet laminate is cooled while being formed. That is, the adhesive sheet laminated body in which the laminated adhesive material layer and the coating part I are integrated into one body is directly formed. Thereby, the covering part I is formed by a mold, and at the same time, the adhesive material layer is also formed through the covering part I. In this step, the heated adhesive sheet laminate may be cooled after being formed, and may also be cooled while being formed. For example, by using a cooled mold to pressurize, forming and cooling can be performed simultaneously and ended at the same time. Thereby, this manufacturing method 1 can be continuously performed as described below. As the forming method, the forming method is not particularly limited as long as the uneven shape can be formed on the adhesive sheet laminate in an integrated manner. Examples include pressure forming, vacuum forming, pressure forming, forming using a roll, compression forming, and forming using a laminate. Among these, from the viewpoint of moldability and processability, press molding is particularly preferred. The material of the mold is not particularly limited. Examples thereof include resin-based materials such as silicone resin and fluororesin, and metal-based materials such as stainless steel and aluminum. Among them, metal molds capable of controlling the temperature at the time of forming are particularly preferable because high-precision formability is required for the concave-convex forming of the adherend. As the cooling method of the mold, a cooling method that is generally performed can be adopted. For example, water cooling or a cooling method using compressed air is mentioned. For a mold, for example, as shown in FIG. 2, a specific concave-convex shape is set on the inner wall surface of at least one of the molds that are opened and closed in advance. The concave and convex shapes corresponding to the concave, convex, or concave and convex portions can be transferred to the adhesive sheet by pressure-molding, vacuum forming, pressure forming, or roll forming of the adhesive sheet laminate using the mold Laminated and shaped. In this step, preferably as described above, the storage elastic modulus E '(MS) of the coating portion I in the adhesive sheet laminate is 1.0 × 10 ⁶ ～ 2.0 × 10 ⁹ In the state of Pa, forming is started. Here, the "starting of molding" means, for example, when forming using a mold, it means that the mold is closed, that is, the sheet laminated body is pressed and adhered by the mold. If the storage elastic modulus E '(MS) of the covering part I is 1.0 × 10 ⁶ ～ 2.0 × 10 ⁹ The range of Pa allows the coating portion I to be deformed to a degree suitable for molding, and it is possible to accurately shape the surface of the adhesive material layer with a desired uneven shape. From this viewpoint, it is preferable that the storage elastic modulus E '(MS) of the coating portion I is 1.0 × 10. ⁶ ～ 2.0 × 10 ⁹ In the state of Pa, the formation of the laminated sheet is started, and it is more preferably 5.0 × 10. ⁶ Above Pa or 1.0 × 10 ⁹ Forming starts at a state of Pa or less, more preferably 1.0 × 10 ⁷ Above Pa or 5.0 × 10 ⁸ Forming is started in a state of Pa or less. According to this, it is more preferable that the storage elastic modulus E '(MS) of the covering portion I is 1.0 × 10 ⁶ ～ 1.0 × 10 ⁹ Pa, or 1.0 × 10 ⁶ ～ 5.0 × 10 ⁸ In the state of Pa, the formation of the laminated sheet is started. Among them, it is more preferably 5.0 × 10. ⁶ ～ 1.0 × 10 ⁹ Pa, or 5.0 × 10 ⁶ ～ 5.0 × 10 ⁸ Forming in the Pa state, preferably 1.0 × 10 ⁷ ～ 1.0 × 10 ⁹ Pa, or 1.0 × 10 ⁷ ～ 5.0 × 10 ⁸ In the state of Pa, forming is started. Furthermore, it is more preferable that the storage elastic modulus E '(MS) of the coating portion I is 1.0 × 10 ⁶ ～ 2.0 × 10 ⁹ Pa, and the storage elastic modulus G '(SS) of the adhesive layer is less than 1.0 × 10 ⁴ In the state of Pa, the forming of the laminated sheet is started. If the storage elastic modulus E '(MS) of the covering part I is in the above range, the above-mentioned effects can be obtained. In addition, if the storage elastic modulus G' ( SS) less than 1.0 × 10 ⁴ When the molding is started in the state of Pa, the molding can be performed in a state where the adhesive layer has more sufficient moldability. From this viewpoint, it is further preferable that the storage elastic modulus E '(MS) of the covering portion I is in the above range and the storage elastic modulus G' (SS) of the adhesive material layer does not reach 1.0 × 10 ⁴ Forming is started in the Pa state, and it is further preferred that the G '(SS) is 5.0 × 10. ¹ Above Pa or 5.0 × 10 ³ Forming starts at a state of Pa or less, and more preferably 1.0 × 10 ² Above Pa or 1.0 × 10 ³ Forming is started in a state of Pa or less. According to this, it is more preferable that the storage elastic modulus E '(MS) of the covering portion I is in the above range and the storage elastic modulus G' (SS) of the adhesive layer is 5.0 × 10. ¹ Above Pa and less than 1.0 × 10 ⁴ Pa, or 5.0 × 10 ¹ Above Pa and 5.0 × 10 ³ Forming is started in a state of Pa or less, and it is more preferably 1.0 × 10. ² Above Pa and less than 1.0 × 10 ⁴ Pa, or 1.0 × 10 ² Above Pa and 5.0 × 10 ³ Forming starts at Pa or less, preferably 1.0 × 10 ² Above Pa and 1.0 × 10 ³ Forming is started in a state of Pa or less. In addition, it is preferable to start molding in a state where the surface temperature of the coating portion I is 70 to 180 ° C. If the surface temperature of the coating part I is 70 ° C or more, the adhesive material layer is sufficiently softened and the coating part I can be sufficiently deformed. If it is 180 ° C or less, the occurrence of wrinkles caused by heat shrinkage or the Defects such as decomposition of the adhesive layer caused by heat are preferred. Therefore, it is preferable to start the molding in a state where the surface temperature of the coating portion I is 70 to 180 ° C. Among them, it is more preferable to make it 75 ° C or more or 150 ° C or less, and it is more preferable to make it 80 ° C or more or 120 ° C. Below ℃. On the other hand, in this step, it is preferable that the storage elastic modulus E '(MF) of the coating portion I is 5.0 × 10. ⁷ ～ 1.0 × 10 ¹⁰ In the state of Pa, forming is completed. Here, the term "end forming" means ending the application of forming pressure to the adhesive sheet laminate, and if the forming is a mold, it means opening the mold. If the storage elastic modulus E '(MF) of the coating part I is 5.0 × 10 ⁷ Above Pa and 1.0 × 10 ¹⁰ A range of Pa or less is preferable because it has excellent shape stability after forming. From this viewpoint, it is preferable that the storage elastic modulus E '(MF) of the coating portion I is 5.0 × 10. ⁷ ～ 1.0 × 10 ¹⁰ Forming is completed in the state of Pa, more preferably 1.0 × 10 ⁸ Above Pa or 8.0 × 10 ⁹ Forming is completed in a state of Pa or less, more preferably 1.0 × 10 ⁹ Above Pa or 5.0 × 10 ⁹ Forming is completed in a state of Pa or less. Accordingly, in this step, it is more preferable that the storage elastic modulus E '(MF) of the coating portion I is 5.0 × 10. ⁷ ～ 8.0 × 10 ⁹ Pa, or 5.0 × 10 ⁷ ～ 5.0 × 10 ⁹ The forming is completed in the state of Pa. Among them, it is preferably 1.0 × 10. ⁸ ～ 8.0 × 10 ⁹ Pa, or 1.0 × 10 ⁸ ～ 5.0 × 10 ⁹ Forming is completed in the state of Pa, preferably 1.0 × 10 ⁹ ～ 8.0 × 10 ⁹ Pa, or 1.0 × 10 ⁹ ～ 5.0 × 10 ⁹ In the state of Pa, forming is completed. Furthermore, it is more preferable that the storage elastic modulus E '(MF) of the coating portion I is in the above range and the storage elastic modulus G' (SF) of the adhesive material layer is 1.0 × 10. ⁴ Forming is completed in a state of Pa or more. If the storage elastic modulus E '(MF) of the coating part I is within the above range, the above-mentioned effects can be obtained. In addition, if the storage elastic modulus G' of the adhesive layer is (SS) is 1.0 × 10 ⁴ When the forming is completed in a state of Pa or more, the formed adhesive material layer can maintain the shape. From this viewpoint, it is preferable that the storage elastic modulus E '(MF) of the coating portion I is in the above range, and the storage elastic modulus G' (SF) of the adhesive material layer is 1.0 × 10. ⁴ The molding is completed in a state of Pa or more, and it is further preferred that the storage elastic modulus G '(SF) of the adhesive material layer is 5.0 × 10. ⁴ Above Pa or 5.0 × 10 ⁷ Forming is completed in a state of Pa or less, and it is more preferably 1.0 × 10. ⁴ Above Pa or 1.0 × 10 ⁷ Forming is completed in a state of Pa or less. In addition, it is preferable to finish the forming in a state where the surface temperature of the coating portion I is less than 50 ° C. For example, in the case of press molding, it is preferable to open the mold while the surface temperature is less than 50 ° C. If the surface temperature of the covering part I does not reach 50 ° C, and the storage elastic modulus E '(MS) of the covering part I is 5.0 × 10 ⁷ ～ 1.0 × 10 ¹⁰ The range of Pa is preferable because it can suppress deformation when the molded body is taken out after the completion of molding, or warpage due to thermal contraction of the coating portion I. From this point of view, it is preferable to finish the molding in a state where the surface temperature of the coating portion I is less than 50 ° C. Among them, it is preferable to finish the molding in a state where it is 0 ° C or more or 45 ° C or less. The molding is completed in a state of 10 ° C or higher or 40 ° C or lower. Furthermore, it is preferable that the storage elastic modulus E '(MS) of the coating portion I at the start of the molding and the storage elastic modulus E' (MF) of the coating portion I at the end of the molding satisfy the following relational expression (1) . (1) ·· E '(MF) / E' (MS) ≧ 1.3 Here, if the storage elastic modulus E '(MS) of the coating portion I and the storage elastic modulus of the coating portion I at the end of the molding are described above If E '(MF) satisfies the above-mentioned relational expression (1), it is soft to the extent that it can be formed at the beginning of forming, and it has the hardness that can maintain the formed shape after the end of forming, so it is preferable. From this point of view, E '(MF) / E' (MS) ≧ 1.3 is preferred, and 100′E ′ (MF) / E '(MS) or E' (MF) / E 'is further preferred. (MS) ≧ 3.0, with 50 ≧ E '(MF) / E' (MS) or E '(MF) / E' (MS) ≧ 5.0 being particularly preferred. However, the upper limit of E '(MF) / E' (MS) is not limited to this. In addition, it is preferable that the storage elastic modulus E '(MF) of the coating portion I at the end of the molding and the storage elastic modulus G' (SF) of the adhesive material layer at the end of the molding satisfy the following relational expression (2) . (2) ・ ・ E '(MF) / G' (SF) ≦ 1.0 × 10 ⁷ Here, if the storage elastic modulus E '(MF) of the coating portion I at the end of the molding and the storage elastic modulus G' (SF) of the adhesive material layer at the end of the molding satisfy the above-mentioned relational expression (2), The formed adhesive material layer can maintain the shape. From this viewpoint, it is preferable that E '(MF) / G' (SF) ≦ 1.0 × 10 ⁷ Among them, it is further preferably 1.0 ≦ E '(MF) / G' (SF) or E '(MF) / G' (SF) ≦ 5.0 × 10 ⁶ , Which is further preferably 1.0 × 10 ¹ ≦ E '(MF) / G' (SF) or E '(MF) / G' (SF) ≦ 1.0 × 10 ⁶ . Although it is repeated, in this manufacturing method 1, the mold may be press-molded and cooled after the mold is opened, or the mold may be cooled in advance and cooled while being press-molded. In this way, if the mold is cooled in advance, and cooling is performed at the same time as the press molding, the molding and cooling can be completed at the same time. Thereby, the shaped adhesive sheet laminate can be transported to the next step immediately after the forming and cooling are completed, so the shaped adhesive sheet laminate can be continuously manufactured. When cooling is performed at the same time as the mold is formed, the surface temperature of the mold is preferably 0 to 50 ° C. If the surface temperature of the mold is below 50 ° C, the shape of the laminated sheet can be fixed in a short time, and the obtained molded body has good accuracy, and can suppress the warpage caused by thermal shrinkage during the cooling process after molding. It is preferable from this viewpoint. Therefore, the surface temperature of the mold is preferably 0 to 50 ° C, more preferably 10 ° C or more or 40 ° C or less, and particularly preferably 15 ° C or more or 30 ° C or less. In addition, the conditions for press forming such as press pressure and press time are not particularly limited, and may be appropriately adjusted according to the size or shape of the press, the materials used, and the like. (Others) The shaped adhesive sheet laminate obtained in the above-mentioned forming and cooling steps can be directly taken up, heat treated, or cut to a specific size and shape. When cutting, for example, a method of cutting using a Thomson blade or a rotary cutter can be cited. In this manufacturing method 1, it is preferable to continuously manufacture a shaped adhesive sheet laminated body. For example, the adhesive sheet laminate can be transported to a heating unit, such as a heater, in which the transportation is stopped for a specific time, or the heated adhesive sheet laminate can be transported to the molding after being heated while being transported. In a unit, such as a forming mold, in the forming unit, for example, pressurization through a cooled mold, cooling while forming, and then conveying it to the next unit as needed to continuously manufacture a shaped adhesive sheet Laminated body. <This Manufacturing Method 2> As an example of an embodiment of the present invention, a manufacturing method of a shaped adhesive sheet laminate (referred to as "this manufacturing method 2") is proposed. The shaped adhesive sheet laminate system includes an adhesive material. Layer and the covering part I formed by laminating on one surface of the adhesive material layer in a peelable manner, and forming concave, convex, or uneven portions on one surface of the adhesive material (referred to as "surface unevenness of the adhesive material layer") The manufacturing method is characterized in that it uses an adhesive sheet laminate having an adhesive material layer and a coating part I formed by laminating on one side of the adhesive material layer in a peelable manner to heat and use The mold forms the heated adhesive sheet laminate to produce a shaped adhesive sheet laminate, and heats the adhesive sheet laminate, starting when the surface temperature of the coating portion I is 70 to 180 ° C. After forming, after forming the surface temperature of the coating part I below 60 ° C., the shaped adhesive sheet laminate is taken out from the mold. According to this manufacturing method 2, by heating the adhesive sheet laminate, molding is started when the surface temperature of the coating portion I is 70 to 180 ° C, and the surface temperature of the coating portion I is removed from the mold after the surface temperature reaches 60 ° C. The shaped adhesive sheet laminate is taken out, and for example, a concave-convex shape conforming to the concave-convex portion on the surface of the adherend can be accurately formed on the surface of the adhesive material layer. This manufacturing method 2 is a manufacturing method including the steps of heating an adhesive sheet laminate described below (heating step), forming the heated adhesive sheet laminate, and cooling (forming, cooling steps). This manufacturing method 2 may include other steps as long as it includes the heating step and the forming and cooling steps described above. For example, if necessary, it may include steps such as a heat treatment step, a conveying step, a cutting step, and a cutting step. It is not limited to these steps. (Adhesive sheet laminated body) The adhesive sheet laminated body as the starting member in the manufacturing method 2 may include an adhesive material layer and a covering portion I formed by laminating on one side of the adhesive material layer in a peelable manner, Other components may be provided. For example, as shown in FIG. 1, there can be exemplified a coating part I including an adhesive material layer, a peelable layer laminated on one of the front and back sides of the adhesive material layer, and a peelable laminated layer on the adhesive. Adhesive sheet laminate of coating part II formed on the front side and the back side of the material layer. However, whether or not the covering part II is provided is arbitrary, and a configuration in which the covering part II is not laminated may be adopted. The details of the laminated sheet are as described above. (Heating step) In this step, the above-mentioned adhesive sheet laminate is heated so that the surface temperature of the coating portion I becomes 70 to 180 ° C. If the surface temperature of the coating portion I is 70 ° C or more, the adhesive material layer is sufficiently softened and the coating portion I can be sufficiently deformed. If it is 180 ° C or less, the occurrence of wrinkles caused by heat shrinkage or heat can be suppressed. The disadvantages such as the decomposition of the adhesive material layer are caused, so it is better. From this viewpoint, it is preferable to heat the above-mentioned adhesive sheet laminate so that the surface temperature of the coating portion I becomes 70 to 180 ° C, more preferably 75 ° C or more or 150 ° C or less, and even more preferably It is 80 ° C or higher or 120 ° C or lower. According to this, it is more preferable to heat the above-mentioned adhesive sheet laminate so that the surface temperature of the coating portion I becomes 70 to 150 ° C or 70 to 120 ° C. Among these, it is more preferable to make it 75 to 150 ° C or 75 to 150 ° C. 120 ° C, preferably 80 to 150 ° C or 80 to 120 ° C. Examples of the method for heating the adhesive sheet laminated body include a method in which the adhesive sheet laminated body is heated between the upper and lower heating plates provided with heating members such as electric heating heaters from above and below, or directly sandwiched between the heating plates. Holding method, a method using a heating roller, a method of immersing it in hot water, and the like. It is not limited to these methods. (Forming and cooling step) In this step, it is preferred to start forming the sheet laminate by adhering the surface temperature of the coating portion I to 70 to 180 ° C. as described above. That is, it is preferable to directly shape the laminated adhesive sheet laminate in a state in which the laminated adhesive layer and the coating portion I are integrated into one body. Thereby, at the same time as the covering portion I is formed, the adhesive material layer can be formed through the covering portion I. In this step, the heated adhesive sheet laminate may be cooled after being formed, and may also be cooled while being formed. For example, by using a cooled mold to pressurize, forming and cooling can be performed simultaneously and ended at the same time. Thereby, the present manufacturing method 2 can be continuously performed as described below. As the forming method, the forming method is not particularly limited as long as the uneven shape can be formed on the adhesive sheet laminate in an integrated manner. Examples include pressure forming, vacuum forming, pressure forming, forming using a roll (roll forming), compression forming, and forming using a laminate. Among these, from the viewpoint of moldability and processability, press molding is particularly preferred. When forming using a mold, the material of the mold is not particularly limited. Examples thereof include resin-based materials such as silicone resin and fluororesin, and metal-based materials such as stainless steel and aluminum. Among them, metal molds capable of controlling the temperature at the time of forming are particularly preferable because high-precision formability is required for the concave-convex forming of the adherend. As the cooling method of the mold, a cooling method that is generally performed can be adopted. For example, water cooling or a cooling method using compressed air is mentioned. For a mold, for example, as shown in FIG. 2, a specific concave-convex shape is set on the inner wall surface of at least one of the molds that are opened and closed in advance. The concave and convex shapes corresponding to the concave, convex, or concave and convex portions can be transferred to the adhesive sheet by pressure-molding, vacuum forming, pressure forming, or roll forming of the adhesive sheet laminate using the mold Laminated and shaped. As described above, it is preferable to start the molding in a state where the surface temperature of the coating portion I is 70 to 180 ° C. If the surface temperature of the coating part I is 70 ° C or more, the adhesive material layer is sufficiently softened and the coating part I can be sufficiently deformed. If it is 180 ° C or less, the occurrence of wrinkles caused by heat shrinkage or the Defects such as decomposition of the adhesive layer caused by heat are preferred. Therefore, it is preferable to start the molding in a state where the surface temperature of the coating portion I is 70 to 180 ° C. Among them, it is more preferable to make it 75 ° C or more or 150 ° C or less, and it is more preferable to make it 80 ° C or more or 120 ° C. Below ℃. On the other hand, in this step, it is preferable to finish the molding in a state where the surface temperature of the coating portion I is less than 60 ° C. For example, in the case of press molding, it is preferable to open the mold while the surface temperature is less than 60 ° C. Here, the term "end forming" means ending the application of forming pressure to the adhesive sheet laminate, and if the forming is a mold, it means opening the mold. If the surface temperature of the coating portion I is less than 60 ° C, it is preferable to prevent deformation of the molded body when the molded body is taken out after the completion of the molding, or warpage caused by the thermal contraction of the coating portion I, so it is preferable. From this viewpoint, it is preferable to finish the molding when the surface temperature of the coating portion I is less than 60 ° C. Among them, it is preferable to finish the molding at a temperature of 0 ° C or higher or 50 ° C or lower. The molding is completed in a state of 10 ° C or higher or 40 ° C or lower. Although it is repeated, in the second manufacturing method, the mold may be press-molded and cooled after the mold is opened, or the mold may be cooled in advance and cooled while being press-molded. In this way, if the mold is cooled in advance, and cooling is performed at the same time as the press molding, the molding and cooling can be completed at the same time. Thereby, the shaped adhesive sheet laminate can be transported to the next step immediately after the forming and cooling are completed, so the shaped adhesive sheet laminate can be continuously manufactured. In the case where cooling is performed while the mold is being formed, the surface temperature of the mold is preferably less than 60 ° C. If the surface temperature of the mold does not reach 60 ° C, the shape of the laminated sheet can be fixed in a short time, and the obtained molded body has good accuracy, and can suppress the warpage accompanying the thermal shrinkage during the cooling process after molding. It is preferable from this viewpoint. Therefore, the surface temperature of the mold is preferably less than 60 ° C, more preferably 0 ° C or more or 50 ° C or less, and even more preferably 10 ° C or more or 40 ° C or less. The difference between the surface temperature of the coating portion I at the start of molding and the end of molding is preferably 10 to 100 ° C, and more preferably 20 ° C or higher or 90 ° C or lower. With the difference in surface temperature of the coating portion I being 10 to 100 ° C., for example, when the uneven shape is transferred to the adhesive sheet laminate and shaped, the shaped adhesive sheet can be formed immediately after forming and cooling. The laminated body is conveyed to the next step, so that the shaped adhesive sheet laminated body can be continuously manufactured. In addition, the conditions for press forming such as press pressure and press time are not particularly limited, and may be appropriately adjusted according to the size or shape of the press, the materials used, and the like. (Others) The shaped adhesive sheet laminate obtained in the above-mentioned forming and cooling steps can be directly taken up, heat treated, or cut to a specific size and shape. When cutting, for example, a method of cutting using a Thomson blade or a rotary cutter can be cited. In this manufacturing method 2, it is preferable to continuously manufacture a shaped adhesive sheet laminated body. For example, the adhesive sheet laminate can be transported to a heating unit, such as a heater, in which the transportation is stopped for a specific time, or the heated adhesive sheet laminate can be transported to the molding after being heated while being transported. In a unit, such as a forming mold, in the forming unit, for example, pressurization through a cooled mold, cooling while forming, and then conveying it to the next unit as needed to continuously manufacture a shaped adhesive sheet Laminated body. <Use> Here, an example of the use of this shaped adhesive sheet laminated body 1 is demonstrated. In recent years, with the popularization of mobile phones, smartphones, and tablet terminals, there are many cases where the image display unit is damaged due to a user's mistakenly dropping it. Especially when the image display device is a touch panel method, not only the display becomes difficult to observe due to damage, but also the touch panel operation itself cannot be performed due to physical obstacles or water infiltration, or it may cause a malfunction. . Therefore, there may be a case where maintenance is performed by replacing only the image display unit, that is, repair. In the maintenance of the image display device, an adhesive sheet is also used when installing a new image display section. Generally, repairs are performed manually by the repair operator, and the repair operator must be skilled. That is, if an unskilled person installs the image display unit through an adhesive sheet, air may enter the interior or the adhesive material may be squeezed out. On the other hand, if the shaped adhesive sheet laminate 1 is used, a step shape with high accuracy can be provided in advance. Therefore, for example, the adhesive material layer can be provided in advance corresponding to the model of the image display device. The step shape can greatly simplify the maintenance work, and can be implemented without the skill of the repair operator. As described above, the adhesive sheet laminate of the present invention can be usefully used for maintenance of an image display device. <Explanation of sentence> In this specification, when it is expressed as "X ~ Y" (X and Y are arbitrary numbers), if there is no special explanation, it means "above X and below Y", and also Contains the meaning of "preferably greater than X" or "preferably less than Y". In addition, when the expression is "above X" (X is an arbitrary number) or "below Y" (Y is an arbitrary number), it also includes "preferably greater than X" or "preferably less than Y" Meaning. In the present invention, the boundary between the sheet and the film is not determined. In the present invention, it is not necessary to distinguish between the two in terms of text. Therefore, in the present invention, the case of "film" also includes "sheet". In the case of "sheet", "film" is also included. EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not limited to the examples. [Group 1 of Examples and Comparative Examples] <Coated Section 1-I> Among Examples 1-1 to 1-3 and Comparative Example 1-1 (hereinafter also collectively referred to as "Group 1 of Examples and Comparative Examples") As the coating portion 1-I of the adhesive sheet laminate, the following coating portions 1-A to 1-D are used. The values of the respective storage elastic modulus are shown in Table 1.・ Coated part 1-A: A single-area layer of a biaxially stretched isophthalic acid copolymerized PET film (thickness: 75 μm) is a film composed of a release layer (thickness: 2 μm) of a polysiloxane compound.・ Coated part 1-B: The single-area layer of unstretched polyolefin film (thickness: 50 μm) containing 4-methylpentene-1 includes a release layer (thickness: 38 μm) of modified polyolefin and成 的 膜。 into the film.・ Coated part 1-C: A film containing a polyolefin film (thickness: 70 μm) containing unstretched polypropylene.・ Coated part 1-D: A single-layer layer of a biaxially-stretched homo-PET film (thickness: 75 μm) is a film composed of a release layer (thickness: 2 μm) of a polysiloxane compound. <Example 1-1> (Production of a double-sided adhesive sheet) A polymethylmethacrylate macromonomer (Tg: 105) having a number average molecular weight of 2400 as a (meth) acrylic copolymer (1-a) ℃) 15 parts by mass (18 mol%), 81 parts by mass (75 mol%) of butyl acrylate (Tg: -55 ° C) and 4 parts by mass (7 mol%) of acrylic acid (Tg: 106 ° C) Acrylic copolymer (1-a-1) (weight average molecular weight 230,000) 1 kg of glycerol dimethacrylate (manufactured by Nippon Oil Co., Ltd., product name: GMR) as a crosslinking agent (1-b) (1-b-1) 90 g and a mixture of 2,4,6-trimethylbenzophenone and 4-methylbenzophenone as a photopolymerization initiator (1-c) (Lanberti) Manufactured, product name: Esacure TZT) (1-c-1) 15 g of the resin composition 1-1 used for uniformly mixing to prepare an adhesive layer. The glass transition temperature of the obtained resin composition was -5 ° C. The obtained resin composition 1-1 was sandwiched between a release-treated PET film (manufactured by Mitsubishi Resin Co., Ltd., product name: Diafoil MRV-V06, thickness: 100 μm) and two pieces of the coating portion 1-A, and used The laminator was shaped into a sheet shape so that the thickness of the resin composition 1-1 was 100 μm, and an adhesive sheet laminate 1-1 was produced. The release layer side of the coating portion 1-A is disposed so as to be in contact with the resin composition 1-1. The obtained adhesive sheet laminate 1-1 was formed by using a vacuum pressure forming machine (manufactured by Daiichi Sangyo Co., Ltd., FKS-0632-20) and thermoforming by the following process to produce a shaped adhesive sheet laminate.体 1-1. That is, by preheating an IR heater at 400 ° C, the surface of the adhesive sheet laminate 1-1 is heated to 100 ° C, and then a forming mold cooled to 25 ° C is used under the condition of a clamping pressure of 8 MPa. It was press-molded for 5 seconds, and the shaped adhesive sheet laminated body 1-1 which formed the unevenness | corrugation on the surface was produced. <Example 1-2> Except that the coating portion 1-B was used instead of the coating portion 1-A, in the same manner as in Example 1-1, an adhesive sheet laminate 1-2 and a shaped adhesive sheet were produced. Laminated body 1-2. <Example 1-3> Except that the coating portion 1-C was used in place of the coating portion 1-A, in the same manner as in Example 1-1, an adhesive sheet laminate 1-3 and a shaped adhesive sheet were produced. Laminates 1-3. <Comparative Example 1-1> Except that the coating portion 1-D was used instead of the coating portion 1-A, in the same manner as in Example 1-1, an adhesive sheet laminate 1-4 and a shaped adhesive sheet were produced. Laminates 1-4. <Measurement and Evaluation Methods> The measurement methods and evaluation methods of various physical property values of the samples obtained in Examples 1-1 to 1-3 and Comparative Example 1-1 will be described. (Elastic Modulus of Covering Part) The covering parts 1-A to 1-D used in the group of Example 1 and Comparative Example 1 were cut into a length of 50 mm and a width of 4 mm, respectively, using a dynamic viscoelastic device (IT Meter and Control Co., Ltd.'s DVA-200) was measured with a chuck pitch of 25 mm and a deformation of 1%. The measurement was performed under conditions of a measurement temperature range of -50 ° C to 150 ° C, a frequency of 1 Hz, and a temperature increase rate of 3 ° C / min. The value of the storage elastic modulus at 100 ° C of the obtained data is set to E '(MA), and the value of the storage elastic modulus at 30 ° C is set to E' (MB). (Elastic Modulus of Adhesive Material Layer) The adhesive material layers obtained in Group 1 of Examples and Comparative Examples were overlapped and laminated to a thickness of 1 mm, and were measured using a rheometer (MARSII manufactured by Thermo Fisher Scientific). The measurement was performed under conditions of a measurement temperature range of -50 ° C to 150 ° C, a frequency of 1 Hz, and a temperature increase rate of 3 ° C / min. Set the value of the storage elastic modulus at 100 ° C of the obtained data to G '(SA) and the value of the loss elastic modulus to G''(SA). The storage elastic modulus at 30 ° C The value of the number is set to G '(SB), the value of the loss elastic modulus is set to G''(SB), and the value of G''/G' at each temperature is set to the loss tangent of each adhesive layer. tan δ (SA, SB). (Gel Fraction) The gel fraction of the adhesive material layer is about 0.05 g of the adhesive material layer obtained in Example 1 and Comparative Example 1, respectively. The SUS screen (#) of the mass (X) is measured in advance. 200) The package is in the shape of a bag, and the mouth of the bag is closed and folded. After measuring the quality (Y) of the package, it is immersed in 100 ml of ethyl acetate, and stored in a dark place at 23 ° C for 24 hours, then the package is removed It was heated at 70 ° C for 4.5 hours to evaporate the attached ethyl acetate, the mass (Z) of the dried package was measured, and the obtained mass was substituted into the following formula to obtain it. Gel fraction [%] = [(Z-X) / (Y-X)] × 100 (Formability) In order to confirm the formability, the molds described in the examples and comparative examples were used to form the group 1 below. test. That is, as shown in FIG. 5, the mold above and below is a convex mold having a length of 270 mm, a width of 170 mm, and a thickness of 40 mm. The other mold above and below is an aluminum having a length of 270 mm, a width of 170 mm, and a thickness of 40 mm. flat. For the forming surface of the above convex mold, as shown in FIG. 5, a convex portion of 187 mm in length, 125 mm in width, and 1 mm in height was provided at the center, and further, the depth of the forming surface of the convex portion was 25 μm, 50 μm. , 75 μm, 100 μm, four shaped concave portions (89 mm in length, 58 mm in width) in plan view. The covering portions 1-A to 1-D of the shaped adhesive sheet laminate formed with irregularities obtained by the method described in Group 1 of Examples and Comparative Examples were peeled off, and a scanning white interference microscope was used to separate The non-contact method measures the height of the concave portion corresponding to the printing step and the convex portion corresponding to the display surface. Measure the height h of the convex part (the boundary part between the concave part) and the mold depth of 100 μm. Measure the transfer rate of 50% or more derived from the following calculation formula as ○, and evaluate the transfer rate of less than 50%. Is ×. Transfer rate (%) = h (formed body height) / 100 (die depth) x 100 (peeling force) The adhesive sheet laminates produced in the group 1 of the examples and comparative examples were cut to a length of 150 mm and a width 50 mm, the 180 ° peel test was performed on the interface between the coated portion 1-A to 1-D and the adhesive material layer at a test speed of 300 mm / min. Set the peeling force at 30 ° C as F (C), heat it at 100 ° C for 5 minutes, and let it cool naturally to 30 ° C. Set the peeling force to F (D), and use the obtained values as coatings, respectively. Peeling force of parts 1-A to 1-D. Table 1 shows the evaluation results of the adhesive sheet laminates 1-1 to 1-4 and the shaped adhesive sheet laminates 1-1 to 1-4 obtained in the examples and comparative examples. [Table 1] Based on the results of Table 1 and Figure 4 and the test results so far, it was confirmed that, as shown in Examples 1-1 to 1-3, the storage elastic modulus E '(MB) at 30 ° C was 5.0 × 10 ⁷ ～ 1.0 × 10 ¹⁰ Pa and storage elastic modulus E '(MA) at 100 ° C is 1.0 × 10 ⁶ ～ 2.0 × 10 ⁹ The coating portion of Pa is laminated on the adhesive material layer to form the concave-convex shape on the adhesive material layer with high accuracy. On the other hand, as shown in Comparative Example 1-1, when a biaxially stretched homopolymer PET film that is generally widely used is used as a release film, the storage elastic modulus of the coated portion exceeds 2.0 × even in a high temperature range. 10 ⁹ Pa, so that sufficient unevenness cannot be formed in the adhesive material layer even if thermoforming is performed. From this we know that the storage elastic modulus E '(MB) at 5.0 ° C is 5.0 × 10 ⁷ ～ 1.0 × 10 ¹⁰ Pa and storage elastic modulus E '(MA) at 100 ° C is 1.0 × 10 ⁶ ～ 2.0 × 10 ⁹ The coating portion of Pa is laminated and formed on the adhesive material layer, and a shaped adhesive sheet formed with unevenness can be obtained well. It is also known that by using it, it is better to satisfy the condition that the loss tangent tanδ (A) of the adhesive material layer at 100 ° C is 1.0 or more and that the loss tangent tanδ (B) of the adhesive material layer at 30 ° C does not reach 1.0 The conditions of the adhesive sheet laminate can achieve more accurate shaping. Therefore, it was confirmed that by using the above-mentioned adhesive sheet laminate, the unevenness equivalent to the printing step of the image display device that becomes the adherend can be accurately formed, and there can be no gap between the adherend and the adherend. Moreover, even if the adhesive material in the adherend with a narrow edge design such as the printing part can be used without any overflow, it can form and adhere to the shaped adhesive sheet laminate for image display devices. In terms of peeling force, the heating and cooling conditions when measuring the peeling force F (D), that is, the conditions for heating to 100 ° C for 5 minutes and then naturally cooling to 30 ° C are the conditions when the shaped adhesive sheet laminate is produced. Typical heating and cooling conditions. Since the absolute values of the difference between the peeling force F (C) and the peeling force F (D) in the above examples are both 0.1 N / cm or less, the covering portions 1-A to 1- in the shaped adhesive sheet laminate are confirmed. The peeling force of D is the same as the peeling force of the coated portions 1-A to 1-D in the adhesive sheet laminate. [Group 2 of Examples and Comparative Examples] <Coated Section 2-I> Examples 2-1 to 2-4 and Comparative Example 2-1 (hereinafter also collectively referred to as "group 2 of Examples and Comparative Examples") The coating part I of the adhesive sheet laminate is a release layer (thickness: 2 μm) containing a polysiloxane compound as a single-area layer for a biaxially-stretched isophthalic acid copolymerized PET film (thickness: 75 μm). And made into a film. The values of the respective storage elastic modulus are shown in Table 2. <Example 2-1> (Production of a double-sided adhesive sheet) A polymethylmethacrylate macromonomer (Tg: 105) having a number average molecular weight of 2400 as a (meth) acrylic copolymer (2-a) ℃) 15 parts by mass (18 mol%), 81 parts by mass (75 mol%) of butyl acrylate (Tg: -55 ° C) and 4 parts by mass (7 mol%) of acrylic acid (Tg: 106 ° C) Acrylic copolymer (2-a-1) (weight average molecular weight: 230,000) 1 kg of glycerol dimethacrylate as a cross-linking agent (2-b) (manufactured by Nippon Oil Company, product name: GMR) (2-b-1) 90 g, and a mixture of 2,4,6-trimethylbenzophenone and 4-methylbenzophenone as a photopolymerization initiator (2-c) (Lanberti) Manufacture, product name: Esacure TZT) (2-c-1) 15 g are mixed uniformly, and the resin composition 2-1 used to make the adhesive layer is produced. The glass transition temperature of the obtained resin composition was -5 ° C. The obtained resin composition 2-1 was sandwiched between a release-treated PET film (manufactured by Mitsubishi Resin Co., Ltd., product name: Diafoil MRV-V06, thickness: 100 μm) and two pieces of the coating portion 2-I, and used The laminator was formed into a sheet shape so that the thickness of the resin composition 2-1 became 100 μm, and an adhesive sheet laminate 2-1 was produced. In addition, the release layer side of the coating part 2-I was arrange | positioned so that it might contact the resin composition 2-1. The obtained adhesive sheet laminate 2-1 was formed by using a vacuum pressure forming machine (manufactured by Daiichi Sangyo Co., Ltd., FKS-0632-20) and a forming mold to perform thermoforming by the following process, Adhesive sheet laminate 2-1. As for the forming mold, as shown in FIG. 5, the upper and lower molds are convex molds with a length of 270 mm, a width of 170 mm, and a thickness of 40 mm, and the other molds are aluminum flat plates with a length of 270 mm, a width of 170 mm, and a thickness of 40 mm. . For the forming surface of the above convex mold, as shown in FIG. 5, a convex portion of 187 mm in length, 125 mm in width, and 1 mm in height was provided at the center, and further, the depth of the forming surface of the convex portion was 25 μm, 50 μm. , 75 μm, 100 μm, four shaped concave portions (89 mm in length, 58 mm in width) in plan view. An IR heater having a preheating temperature of 400 ° C. was used to heat the surface of the covering portion 2-I of the adhesive sheet laminate 2-1 to 100 ° C., and the molding was performed. That is, the storage elastic modulus E '(MS) at the coating portion 2-I is 2.1 × 10. ⁸ Pa and the storage elastic modulus G '(SS) of the adhesive layer is 2.9 × 10 ² In the state of Pa, using a mold for cooling the surface temperature of the mold to 30 ° C, press molding under the condition of clamping pressure of 8 MPa for 5 seconds, and the storage elastic modulus E '(MF in the coating portion 2-I ) Is 2.8 × 10 ⁹ Pa and the storage elastic modulus G '(SF) of the adhesive layer is 6.1 × 10 ⁴ The mold was opened in the state of Pa, and a shaped adhesive sheet laminate 2-1 formed by forming irregularities on the surface was produced. In addition, the ratio E '(MS) of the storage elastic modulus E' (MS) of the coating portion 2-I at the start of the molding to the storage elastic modulus E '(MF) of the coating portion 2-I at the end of the molding is described. MF) / E '(MS) is 13.3. The ratio E '(MF) of the storage elastic modulus E' (MF) of the covering portion 2-I at the end of the molding to the storage elastic modulus G '(SF) of the adhesive material layer at the end of the molding. G '(SF) is 4.6 × 10 ⁴ . The loss tangent tan δ (SS) of the adhesive material layer at the start of molding was 4.8, and the loss tangent tan δ (SF) of the adhesive material layer at the end of molding was 0.6. <Example 2-2> For the adhesive sheet laminated body 2-1 used in Example 2-1, an IR heater having a preheating of 400 ° C. was used to heat the coated portion 2 of the adhesive sheet laminated body 2-2. The surface of -I reaches 110 ° C and is formed. That is, the storage elastic modulus E '(MS) at the coating portion 2-I is 1.3 × 10. ⁸ Pa and the storage elastic modulus G '(SS) of the adhesive layer is 9.6 × 10 ¹ In the state of Pa, using a mold for cooling the surface temperature of the mold to 30 ° C, press molding under the condition of clamping pressure of 8 MPa for 5 seconds, and the storage elastic modulus E '(MF in the coating portion 2-I ) Is 2.8 × 10 ⁹ Pa and the storage elastic modulus G '(SF) of the adhesive layer is 6.1 × 10 ⁴ The mold was opened in the state of Pa, and a shaped adhesive sheet laminate 2-2 formed by forming irregularities on the surface was produced. <Example 2-3> For the adhesive sheet laminate 2-1 used in Example 2-1, an IR heater having a preheating of 400 ° C. was used to heat the coated portion 2 of the adhesive sheet laminate 2-3. The surface of -I reaches 90 ° C and is formed. That is, the storage elastic modulus E '(MS) at the coated portion 2-I is 3.5 × 10. ⁸ Pa and the storage elastic modulus G '(SS) of the adhesive layer is 8.9 × 10 ² In the state of Pa, using a mold for cooling the surface temperature of the mold to 30 ° C, press molding under the condition of clamping pressure of 8 MPa for 5 seconds, and the storage elastic modulus E '(MF in the coating portion 2-I ) Is 2.8 × 10 ⁹ Pa and the storage elastic modulus G '(SF) of the adhesive layer is 6.1 × 10 ⁴ In the Pa state, the mold was opened, and a shaped adhesive sheet laminate 2-3 formed by forming irregularities on the surface was produced. In addition, the ratio E '(MS) of the storage elastic modulus E' (MS) of the coating portion 2-I at the start of the molding to the storage elastic modulus E '(MF) of the coating portion 2-I at the end of the molding is described. MF) / E '(MS) was 8.0. The ratio E '(MF) of the storage elastic modulus E' (MF) of the covering portion 2-I at the end of the molding to the storage elastic modulus G '(SF) of the adhesive material layer at the end of the molding. G '(SF) is 4.6 × 10 ⁴ . The loss tangent tan δ (SS) of the adhesive material layer at the start of forming was 2.7, and the loss tangent tan δ (SF) of the adhesive material layer at the end of forming was 0.6. <Example 2-4> For the adhesive sheet laminate 2-1 used in Example 2-1, an IR heater having a preheating of 400 ° C. was used to heat the covering portion 2 of the adhesive sheet laminate 2-4. The surface of -I reaches 70 ° C and is formed. That is, the storage elastic modulus E '(MS) at the coating portion 2-I is 1.9 × 10. ⁹ Pa and the storage modulus G '(SS) of the adhesive layer is 6.4 × 10 ³ In the state of Pa, a forming mold was used to cool the surface temperature of the mold to 25 ° C., and press molding was performed for 5 seconds under the condition of clamping pressure of 8 MPa, and the storage elastic modulus E ′ (MF ) Is 2.8 × 10 ⁹ Pa and the storage elastic modulus G '(SF) of the adhesive layer is 6.1 × 10 ⁴ The mold was opened in the state of Pa, and a shaped adhesive sheet laminate 2-4 formed by forming irregularities on the surface was produced. In addition, the ratio E '(MS) of the storage elastic modulus E' (MS) of the coating portion 2-I at the start of the molding to the storage elastic modulus E '(MF) of the coating portion 2-I at the end of the molding is described. MF) / E '(MS) is 1.4. The ratio E '(MF) of the storage elastic modulus E' (MF) of the covering portion 2-I at the end of the molding to the storage elastic modulus G '(SF) of the adhesive material layer at the end of the molding. G '(SF) is 4.6 × 10 ⁴ . The loss tangent tan δ (SS) of the adhesive material layer at the start of molding was 1.4, and the loss tangent tan δ (SF) of the adhesive material layer at the end of molding was 0.6. <Comparative Example 2-1> The adhesive sheet laminated body 2-1 used in Example 2-1 was heated to the covering portion 2 of the adhesive sheet laminated body 2-5 using an IR heater preheated at 400 ° C. The surface of -I reaches 60 ° C and is formed. That is, the storage elastic modulus E '(MS) at the coating portion 2-I is 2.4 × 10. ⁹ Pa and the storage elastic modulus G '(SS) of the adhesive material layer is 1.3 × 10 ⁴ In the state of Pa, a forming mold was used to cool the surface temperature of the mold to 25 ° C., and press molding was performed for 5 seconds under the condition of clamping pressure of 8 MPa, and the storage elastic modulus E ′ (MF ) Is 2.8 × 10 ⁹ Pa and the storage elastic modulus G '(SF) of the adhesive layer is 6.1 × 10 ⁴ In the Pa state, the mold was opened, and a shaped adhesive sheet laminate 2-5 formed by forming irregularities on the surface was produced. In addition, the ratio E '(MS) of the storage elastic modulus E' (MS) of the coating portion 2-I at the start of the molding to the storage elastic modulus E '(MF) of the coating portion 2-I at the end of the molding is described. MF) / E '(MS) is 1.2. The ratio E '(MF) of the storage elastic modulus E' (MF) of the covering portion 2-I at the end of the molding to the storage elastic modulus G '(SF) of the adhesive material layer at the end of the molding. G '(SF) is 4.6 × 10 ⁴ . The loss tangent tan δ (SS) of the adhesive material layer at the start of molding was 1.1, and the loss tangent tan δ (SF) of the adhesive material layer at the end of molding was 0.6. In addition, the ratio E '(MS) of the storage elastic modulus E' (MS) of the coating portion 2-I at the start of the molding to the storage elastic modulus E '(MF) of the coating portion 2-I at the end of the molding is described. MF) / E '(MS) was 8.0. The ratio E '(MF) of the storage elastic modulus E' (MF) of the covering portion 2-I at the end of the molding to the storage elastic modulus G '(SF) of the adhesive material layer at the end of the molding. G '(SF) is 9.7 × 10 ³ . The loss tangent tan δ (SS) of the adhesive material layer at the start of molding was 0.6, and the loss tangent tan δ (SF) of the adhesive material layer at the end of molding was 0.6. <Measurement and Evaluation Methods> The measurement methods and evaluation methods of various physical property values of the samples obtained in Examples 2-1 to 2-4 and Comparative Example 2-1 will be described. (Elastic Modulus of Covering Part) The storage elastic modulus E '(MS) and E' (MF) of the covering part 2-I are cut into a length of 50 mm and a width of 4 mm, using a dynamic viscoelastic device (IT Meter and Control Co., Ltd.'s DVA-200) was measured with a chuck pitch of 25 mm and a deformation of 1%. The measurement was performed under conditions of a measurement temperature range of -50 ° C to 150 ° C, a frequency of 1 Hz, and a temperature increase rate of 3 ° C / min. In the examples and comparative examples, the value of the storage elastic modulus at the temperature at the start of molding was set to E '(MS), and the value of the storage elastic modulus at the temperature at the end of each molding was set to E' (MF). Furthermore, in Example 2-1, since the temperature at the start of molding was 100 ° C, the storage elastic modulus E '(MS) of Example 2-1 is the storage elastic modulus E' (MA at 100 ° C). ). In addition, since the temperature at the end of forming in Group 2 of the Examples and Comparative Examples is 30 ° C, the E '(MF) and the storage elastic modulus at 30 ° C of the Group 2 of any of the Examples and Comparative Examples are all E '(MB) is the same. (Elastic Modulus of Adhesive Material Layer) The adhesive material layers obtained in Group 2 of Examples and Comparative Examples were superimposed and laminated to a thickness of 1 mm, and measured using a rheometer (MARSII manufactured by Thermo Fisher Scientific). The measurement was performed under conditions of a measurement temperature range of -50 ° C to 150 ° C, a frequency of 1 Hz, and a temperature increase rate of 3 ° C / min. In the obtained data, the value of the storage elastic modulus at 100 ° C is set to G '(SA), the value of the loss elastic modulus is set to G''(SA), and the storage elastic modulus at 30 ° C is set. The value of the number is set to G '(SB), the value of the loss elastic modulus is set to G''(SB), and the value of G''/G' at each temperature is set to the loss tangent of each adhesive layer. tan δ (SA, SB). On the other hand, regarding the storage elastic modulus G '(SA) and G' (SB) of the adhesive material layer, the adhesive material layers obtained in the group 2 of the examples and comparative examples were superimposed and laminated to a thickness of 1 mm, and used A rheometer (MARSII manufactured by Thermo Fisher Scientific) was used for measurement. The measurement was performed under conditions of a measurement temperature range of -50 ° C to 150 ° C, a frequency of 1 Hz, and a temperature increase rate of 3 ° C / min. In the obtained data, the value of the storage elastic modulus at the temperature at the start of each forming of the group 2 of the example and the comparative example is set to G '(SS), and the value of the loss elastic modulus is set to G'' (SS), the value of the storage elastic modulus at the temperature at the end of each forming is G '(SF), the value of the loss elastic modulus is G''(SF), and further, the The value of G ″ / G ′ is set as the loss tangent tan δ (SS, SF) of each adhesive material layer. (Gel Fraction) Regarding the gel fraction of the adhesive material layer, about 0.05 g of the adhesive material layer obtained in Example 2 and Comparative Example 2 was collected, and the mass (X) of the SUS screen ( # 200) The package is in the shape of a bag, and the mouth of the bag is closed and folded. After measuring the mass (Y) of the package, it is immersed in 100 ml of ethyl acetate, stored in a dark place at 23 ° C for 24 hours, and then taken out. The package was heated at 70 ° C for 4.5 hours to evaporate the attached ethyl acetate. The mass (Z) of the dried package was measured, and the obtained mass was substituted into the following formula to obtain it. Gel fraction [%] = [(Z-X) / (Y-X)] × 100 (moldability) The shaped adhesive sheet formed with unevenness obtained in the group 2 of Examples and Comparative Examples was laminated. The covering portion I of the body was peeled off, and the height of the concave portion corresponding to the printing step and the convex portion corresponding to the display surface were measured in a non-contact manner using a scanning white interference microscope, respectively. Measure the height h of the convex part (the boundary part between the concave part) and the mold depth of 100 μm. Measure the transfer rate of 50% or more derived from the following calculation formula as ○, and evaluate the transfer rate of less than 50%. Is ×. Transfer rate (%) = h (molded body height) / 100 (die depth) × 100 (peeling force) The adhesive sheet laminates produced in the group 2 of the examples and comparative examples were cut to a length of 150 mm and a width 50 mm, the 180 ° peel test was performed on the interface between the coated portion 2-I and the adhesive material layer at a test speed of 300 mm / min. Set the peeling force at 30 ° C as F (C), heat it at 100 ° C for 5 minutes, and let it cool naturally to 30 ° C. Set the peeling force to F (D), and use the obtained values as coatings, respectively. Peeling force of part 2-I. Table 2 shows the evaluation results of the shaped adhesive sheet laminates 2-1 to 2-5 obtained in Examples 2-1 to 2-4 and Comparative Example 2-1. [Table 2] Based on the results of Table 2 and FIG. 4 and the test results thus far, it was confirmed that the storage elastic modulus E of the coating portion 2-I at the start of molding was shown in Examples 2-1 to 2-4. '(MS) is 1.0 × 10 ⁶ ～ 2.0 × 10 ⁹ Pa, and the storage elastic modulus E '(MF) of the coating portion 2-I at the end of molding becomes 5.0 × 10 ⁷ ～ 1.0 × 10 ¹⁰ The method of Pa is adjusted and formed, and the uneven shape can be accurately formed on the adhesive material layer. On the other hand, as shown in Comparative Example 2-1, the storage elastic modulus E '(MS) of the covering portion 2-I at the start of molding is greater than 2.0 × 10 ⁹ In the case of Pa, even if thermoforming is performed, sufficient unevenness cannot be formed in the adhesive material layer. From this, it is known that the storage elastic modulus E '(MS) of the covering portion 2-I at the start of molding is 1.0 × 10 ⁶ ～ 2.0 × 10 ⁹ Pa and the storage elastic modulus E '(MF) of the coating portion 2-I at the end of molding becomes 5.0 × 10 ⁷ ～ 1.0 × 10 ¹⁰ The method of Pa is adjusted and formed, and a shaped adhesive sheet formed with irregularities can be obtained well. It is also known that by further satisfying the condition that the loss tangent tanδ (SS) of the adhesive material layer at the start of forming is 1.0 or more and satisfying the loss tangent tanδ (SF) of the adhesive material layer at the end of forming is less than 1.0 The conditions and methods are adjusted and shaped to achieve higher precision shaping. Therefore, it was confirmed that by using the above-mentioned adhesive sheet laminate, the unevenness equivalent to the printing step of the image display device that becomes the adherend can be accurately formed, and there can be no gap between the adherend and the adherend. Moreover, even if the adhesive material in the adherend with a narrow edge design such as the printing part can be used without any overflow, it can form and adhere to the shaped adhesive sheet laminate for image display devices. In terms of peeling force, the heating and cooling conditions when measuring the peeling force F (D), that is, the conditions for heating to 100 ° C for 5 minutes and then naturally cooling to 30 ° C are the conditions when the shaped adhesive sheet laminate is produced. Typical heating and cooling conditions. Since the absolute values of the difference between the peeling force F (C) and the peeling force F (D) in the above examples are both 0.1 N / cm or less, it is confirmed that the peeling force hardly changes before and after heating. Furthermore, it was learned that by laminating the sheet laminate by heating, the storage elastic modulus E '(MS) at the coating portion 2-I was 1.0 × 10 ⁶ ～ 2.0 × 10 ⁹ Forming starts in the Pa state, and the storage elastic modulus E '(MF) of the coating portion 2-I is 5.0 × 10 ⁷ ～ 1.0 × 10 ¹⁰ The forming is completed in the state of Pa, and an uneven shape corresponding to the uneven portion on the surface of the adherend can be formed on the surface of the adhesive layer with high accuracy. [Group 3 of Examples and Comparative Examples] <Coated Section 3-I> Examples 3-1 to 3-3 and Comparative Examples 3-1 to 3-2 (hereinafter also collectively referred to as "group of Examples and Comparative Examples" 3 ″) The coating part 3-I of the adhesive sheet laminate is used as a single-layer layer of a biaxially stretched isophthalic acid copolymerized PET film (thickness: 75 μm) containing a release layer of a polysiloxane compound (Thickness: 2 μm). The values of the respective storage elastic modulus are shown in Table 3. <Example 3-1> (Production of double-sided adhesive sheet) A polymethyl methacrylate macromonomer (Tg: 105) having a number average molecular weight of 2400 as a (meth) acrylic copolymer (3-a) ℃) 15 parts by mass (18 mol%), 81 parts by mass (75 mol%) of butyl acrylate (Tg: -55 ° C) and 4 parts by mass (7 mol%) of acrylic acid (Tg: 106 ° C) Acrylic copolymer (3-a-1) (weight average molecular weight 230,000) 1 kg of glycerol dimethacrylate (manufactured by Nippon Oil Co., Ltd., product name: GMR) as a crosslinking agent (3-b) (3-b-1) 90 g and a mixture of 2,4,6-trimethylbenzophenone and 4-methylbenzophenone as a photopolymerization initiator (3-c) (Lanberti) Production, product name: Esacure TZT) (3-c-1) 15 g of resin composition 3-1 used for uniformly mixing to prepare an adhesive layer. The glass transition temperature of the obtained resin composition was -5 ° C. The obtained resin composition 3-1 was sandwiched between a release-treated PET film (manufactured by Mitsubishi Resin Co., Ltd., product name: Diafoil MRV-V06, thickness: 100 μm) and two pieces of the coating portion 3-I, and used The laminator was formed into a sheet shape so that the thickness of the resin composition 3-1 became 100 μm, and an adhesive sheet laminate 3-1 was produced. In addition, the release layer side of the coating portion 3-I is arranged so as to be in contact with the resin composition 3-1. The obtained adhesive sheet laminated body 3-1 was formed by using a vacuum pressure forming machine (manufactured by Daiichi Industries, FKS-0632-20) and a forming mold by thermoforming in the following process. Adhesive sheet laminate 3-1. As for the forming mold, as shown in FIG. 5, the upper and lower molds are convex molds with a length of 270 mm, a width of 170 mm, and a thickness of 40 mm, and the other molds are aluminum flat plates with a length of 270 mm, a width of 170 mm, and a thickness of 40 mm. . For the forming surface of the above convex mold, as shown in FIG. 5, a convex portion of 187 mm in length, 125 mm in width, and 1 mm in height was provided at the center, and further, the depth of the forming surface of the convex portion was 25 μm, 50 μm. , 75 μm, 100 μm, four shaped concave portions (89 mm in length, 58 mm in width) in plan view. An IR heater having a preheating temperature of 400 ° C was used to heat the surface of the covering portion 3-I of the adhesive sheet laminate 3-1 to 100 ° C, and a molding mold was used to cool the mold surface temperature to 30 ° C. The laminated sheet 3-1 in the heated state is pressed for 5 seconds under the condition of clamping pressure of 8 MPa, and then the mold is opened to produce a shaped adhesive sheet layered body 3-1 formed by forming irregularities on the surface. . 〈Example 3-2〉 Using an IR heater preheated at 400 ° C, the adhesive sheet laminate 3-1 used in Example 3-1 was heated to the coating portion 3 of the adhesive sheet laminate 3-2. The surface of -I reaches 70 ° C. Using a forming mold that cools the surface temperature of the mold to 30 ° C, the heated laminated sheet 3-1 is pressed for 5 seconds under the condition of clamping pressure of 8 MPa. Then, the mold was opened, and a shaped adhesive sheet laminate 3-2 formed by forming irregularities on the surface was produced. 〈Example 3-3〉 Using an IR heater preheated at 400 ° C, the adhesive sheet laminate 3-1 used in Example 3-1 was heated to the coating portion 3 of the adhesive sheet laminate 3-3. The surface of -I reaches 100 ° C. Using a molding mold whose surface temperature is adjusted to 50 ° C, the heated laminated sheet 3-1 is press-formed for 5 seconds under a clamping pressure of 8 MPa. Then, the mold is opened, and a shaped adhesive sheet laminate 3-3 formed by forming irregularities on the surface is produced. <Comparative Example 3-1> Using an IR heater preheated at 400 ° C, the adhesive sheet laminate 3-1 used in Example 3-1 was heated to the coating portion 3 of the adhesive sheet laminate 3-5. The surface of -I reaches 60 ° C. Using a forming mold that cools the surface temperature of the mold to 30 ° C, the heated laminated sheet 3-1 is press-molded under the condition of clamping pressure of 8 MPa for 5 seconds. Then, the mold is opened, and a shaped adhesive sheet laminate 3-4 formed by forming irregularities on the surface is produced. <Comparative Example 3-2> Using an IR heater preheated at 400 ° C, the adhesive sheet laminate 3-1 used in Example 3-1 was heated to the coating portion 3 of the adhesive sheet laminate 3-5. The surface of -I reaches 100 ° C. Using a forming mold whose surface temperature is adjusted to 80 ° C, the laminated sheet 3-1 in the heated state is press-molded for 5 seconds under the condition of clamping pressure of 8 MPa. Then, the mold is opened, and a shaped adhesive sheet laminate 3-5 formed by forming irregularities on the surface is produced. <Measurement and Evaluation Methods> The measurement methods and evaluation methods of various physical property values of the samples obtained in Examples 3-1 to 3-3 and Comparative Examples 3-1 to 3-2 will be described. (Elastic Modulus of Covered Part) The storage elastic modulus of Covered Part 3-I is cut into a length of 50 mm and a width of 4 mm, and a dynamic viscoelastic device (DVA-200 from IT Meter and Control Co., Ltd.) is used to clamp The measurement was performed with a head pitch of 25 mm and a deformation of 1%. The measurement was performed under conditions of a measurement temperature range of -50 ° C to 150 ° C, a frequency of 1 Hz, and a temperature increase rate of 3 ° C / min. In the obtained data, the value of the storage elastic modulus of the coating portion 3-I at 30 ° C is set to E '(MB), and the value of the storage elastic modulus of the coating portion 3-I at 100 ° C is set E '(MA). (Elastic Modulus of Adhesive Material Layer) The adhesive material layers obtained in Group 3 of the Examples and Comparative Examples were overlapped and laminated to a thickness of 1 mm, and measured using a rheometer (MARSII manufactured by Thermo Fisher Scientific). The measurement was performed under conditions of a measurement temperature range of -50 ° C to 150 ° C, a frequency of 1 Hz, and a temperature increase rate of 3 ° C / min. In the obtained data, the value of the storage elastic modulus at 100 ° C is set to G '(SA), the value of the loss elastic modulus is set to G''(SA), and the storage elastic modulus at 30 ° C is set. The value of the number is set to G '(SB), the value of the loss elastic modulus is set to G''(SB), and the value of G''/G' at each temperature is set to the loss tangent of each adhesive layer. tan δ (SA, SB). (Formability) The coated part I of the shaped adhesive sheet laminate having irregularities obtained in the group 3 of the examples and comparative examples was peeled off, and each was measured in a non-contact manner using a scanning white interference microscope. The height of the concave portion of the step and the convex portion corresponding to the display surface. Measure the height h of the convex part (the boundary part between the concave part) and the depth of the mold of 100 μm, and evaluate the transfer rate derived from the following calculation formula to be 50% or more and "50" and less than 50% The evaluation was “×”. Transfer rate (%) = h (molded body height) / 100 (die depth) × 100 (warpage, bending) The adhesive sheet laminate produced under each molding condition of the group 3 of the examples and comparative examples was cut out Form a square with a length of 100 mm, and measure the height of each vertex. The obtained 4 points were averaged and the value was used as the warpage. Those with a warpage height of less than 10 mm were judged as "○", and those with a warpage height of 10 mm or more were judged as "×". (Peeling force) The adhesive sheet laminates produced in Group 3 of Examples and Comparative Examples were cut into a length of 150 mm and a width of 50 mm, and the interface between the coating portion 3-I and the adhesive material layer was tested at a speed of 300 mm / A 180 ° peel test was performed in min. Set the peeling force at 30 ° C as F (C), heat it at 100 ° C for 5 minutes, and let it cool naturally to 30 ° C. Set the peeling force to F (D), and use the obtained values as coatings, respectively. Part 3-I peeling force. Table 3 shows the evaluation results of the shaped adhesive sheet laminates 3-1 to 3-5 obtained in Examples 3-1 to 3-3 and Comparative Examples 3-1 to 3-2. [table 3] Based on the results in Table 3 and the test results thus far, it was confirmed that the surface temperature of the coated portion 3-I was 70 to 180 ° C as shown in Example 3-1 to Example 3-3. The molding is completed after the surface temperature of the coating portion 3-I becomes less than 60 ° C., and the molding is performed by taking out the molded product from the mold, and the uneven shape can be accurately formed on the adhesive material layer. On the other hand, as shown in Comparative Example 3-1, if the temperature of the coating portion 3-I at the start of molding does not reach 70 ° C, sufficient unevenness cannot be formed in the adhesive material layer even if thermoforming is performed. It was also found that, as shown in Comparative Example 3-2, if the surface temperature of the coating portion 3-I is 70 ° C or higher when the molding is finished and the molded product is taken out from the mold, the molded product may be warped due to thermal contraction of the sheet. Warping or bending is not good. From this, it is known that, in order to perform unevenness shaping with higher accuracy, it is preferable to start the molding with the surface temperature of the coated portion 3-I at 70 to 180 ° C, and the surface temperature of the coated portion 3-I becomes unsettled. After reaching 60 ° C, the molding was completed, and the molding was performed by taking out the molded product from the mold. Therefore, it was confirmed that by using the above-mentioned adhesive sheet laminate, the unevenness equivalent to the printing step of the image display device that becomes the adherend can be accurately formed, and there can be no gap between the adherend and the adherend. Moreover, even if the adhesive material in the adherend with a narrow edge design such as the printing part can be used without any overflow, it can form and adhere to the shaped adhesive sheet laminate for image display devices. In terms of peeling force, the heating and cooling conditions when measuring the peeling force F (D), that is, the conditions for heating to 100 ° C for 5 minutes and then naturally cooling to 30 ° C are the conditions when the shaped adhesive sheet laminate is produced. Typical heating and cooling conditions. Since the absolute values of the difference between the peeling force F (C) and the peeling force F (D) in the above examples are both 0.1 N / cm or less, it is confirmed that the peeling force hardly changes before and after heating. [Group 4 of Examples] The production method of the polyester raw materials used in the following Examples 4-1 to 4-5 (hereinafter also collectively referred to as "Group 4 of Examples") is as follows. (Manufacturing method of polyester 4-A) 100 parts of dimethyl terephthalate, 70 parts of ethylene glycol, and 0.07 parts of calcium acetate monohydrate were placed in a reactor, heated and heated, and distilled to remove methanol. The transesterification reaction is performed. After the reaction starts, it takes about 4 and a half hours to raise the temperature to 230 ° C, and the transesterification reaction is substantially ended. Then, 0.04 parts of phosphoric acid and 0.035 parts of antimony trioxide were added, and polymerization was performed according to a conventional method. That is, the reaction temperature was gradually raised to 280 ° C., and the pressure was gradually reduced to 0.05 mmHg. After 4 hours, the reaction was completed, and fragmentation was carried out according to a conventional method to obtain polyester 4-A. The limiting viscosity IV of the obtained polyester chips was 0.70 dl / g. (Manufacturing method of polyester 4-B) In the above-mentioned manufacturing method of polyester 4-A, as dicarboxylic acid units, terephthalic acid is 78 mol%, and isophthalic acid is 22 mol%. Except for this, polyester 4-B was obtained by the same method as polyester A. The limiting viscosity IV of the obtained polyester chips was 0.70 dl / g. (Manufacturing method of polyester 4-C) When manufacturing the above-mentioned polyester 4-A, 6000 ppm of amorphous silicon dioxide having an average particle diameter of 3 μm was added to produce polyester 4-C. (Manufacturing method of polyester 4-D) When manufacturing the above-mentioned polyester 4-A, 6000 ppm of amorphous silicon dioxide having an average particle diameter of 4 μm was added to produce polyester 4-D. [Example 4-1] The raw materials obtained by mixing the polyesters 4-B, 4-A, and 4-D in the proportions of 65% by weight, 30% by weight, and 5% by weight, respectively, were melted by a melt extruder. Extruded to obtain a single layer of amorphous sheet. Then, the sheet is co-extruded onto a cooled casting drum, and allowed to cool and solidify to obtain an unoriented sheet. Then, after being stretched 3.4 times in the mechanical direction (longitudinal) at 80 ° C, it was further subjected to a preheating step in the tenter, and then extended 3.9 times in the direction perpendicular to the mechanical direction (transverse) at 80 ° C. After biaxial stretching, a heat treatment was performed at 185 ° C. for 3 seconds, and then a 6.4% relaxation treatment was performed in the width direction to obtain a polyester film having a thickness of 50 μm. The evaluation results are shown in Table 4 below. [Example 4-2], [Example 4-3] A polyester film was obtained in the same manner as in Example 4-1 except that the conditions shown in Table 4 below were changed. The evaluation results are shown in Table 4 below. [Example 4-4] A raw material obtained by mixing the above polyesters 4-A and 4-C at a ratio of 86% by weight and 14% by weight was used as a raw material for the surface layer, and polyesters 4-B and 4 were used. -A is a raw material prepared by mixing 45% by weight and 55% by weight as a raw material for the intermediate layer. Melt extrusion through different melt extruders, respectively, to obtain two kinds of three-layered (surface layer / intermediate layer / surface layer) amorphous sheet. Then, the sheet is co-extruded onto a cooled casting drum and allowed to cool and solidify to obtain an unoriented sheet. Then, after being stretched 3.4 times in the machine direction (MD) at 82 ° C, it was further subjected to a preheating step in the tenter, and then extended 3.9 times in the direction perpendicular to the machine direction (width direction, TD) at 110 ° C. After biaxial stretching, a heat treatment was performed at 210 ° C. for 3 seconds, and then a relaxation treatment of 2.4% was performed in the width direction to obtain a polyester film having a thickness of 50 μm. The evaluation results are shown in Table 4 below. [Example 4-5] A polyester film was obtained in the same manner as in Example 4-4 except that the conditions shown in Table 4 below were changed. The evaluation results are shown in Table 4 below. <Measurement and evaluation method> The measurement method and evaluation method of various physical property values of the sample obtained in the group 4 of the Example are demonstrated. (1) Storage modulus (E ') Regarding the film obtained in the group 4 of the example, a sample of 30 mm in the length direction and 5 mm in the width direction was collected so that the length direction became the mechanical direction. Next, using a dynamic viscoelastic device ("DVA-220" manufactured by IT Meter and Control), the sample was clamped and fixed with a chuck set at an interval of 20 mm, and the temperature was raised from room temperature at a temperature of 10 ° C / min. The temperature was raised to 200 ° C, and the storage elastic modulus was measured at a frequency of 10 Hz. Based on the obtained data, read the storage elastic modulus at 100 ° C. (2) The heat shrinkage rate is cut from the center of the width direction of the film obtained in Example 4 in the example so that the sample length direction becomes the measurement direction, and the sample is cut into short strips (15 mm wide × 150 mm long). Heat treatment was performed in a tension-free state at 120 ° C for 5 minutes. The length of the sample before and after the heat treatment was measured, and the thermal shrinkage (%) of the film was calculated by the following formula. In the following formula, a is the length of the sample before the heat treatment, and b is the length of the sample after the heat treatment. Heat shrinkage (%) = [(a－b) / a] × 100 (3) Amount of oligomer on the surface of the film after heat treatment For the film obtained in Example Group 4, the temperature is 180 ° C under nitrogen atmosphere. The hot air circulation oven treated the polyester film for 10 minutes. The surface of the polyester film after heat treatment was brought into contact with DMF (dimethylformamide) for 3 minutes to dissolve the oligomer deposited on the surface. This operation can be used, for example, in a voluntary standard for synthetic resin food containers and packaging such as polyolefins, and the method described in the dissolution apparatus used in the single-side dissolution method in the dissolution test. Then, if necessary, adjust the concentration of the obtained DMF by dilution and other methods, and supply it to a liquid chromatograph (Shimadzu LC-2010) to determine the amount of oligomers in the DMF. This value is divided by the area of the membrane that contacts the DMF As the amount of oligomer on the film surface (mg / cm ² ). The amount of oligomers in DMF was determined from the ratio of the peak area of the standard sample peak area to the measured sample peak area (absolute calibration curve method). The preparation of the standard sample is made by accurately weighing the oligomer (cyclic trimer) collected in advance and dissolving it in DMF accurately weighed. The concentration of the standard sample is preferably in the range of 0.001 to 0.01 mg / ml. (4) Suitability for molding process 15 mass parts (18 mol%) of polymethyl methacrylate macromonomer (Tg: 105 ° C) as a (meth) acrylic copolymer with a number average molecular weight of 2400, and butyl acrylate ( Tg: -55 ° C) 81 parts by mass (75 mol%) and 4 parts by mass (7 mol%) of acrylic acid (Tg: 106 ° C) randomly copolymerized acrylic copolymer (weight average molecular weight 230,000) 1 kg 90 g of glycerin dimethacrylate (manufactured by Nippon Oil Company, product name: GMR) (b-1) as a crosslinking agent, and 2,4,6-trimethyldiphenyl as a photopolymerization initiator 15 g of a mixture of ketone and 4-methylbenzophenone (manufactured by Lanberti Company, product name: Esacure TZT) was uniformly mixed to prepare a resin composition used for an adhesive sheet. The resin composition obtained by using two release films obtained from the polyester film shown in Group 4 of the example to hold the resin composition up and down (the combination of the upper and lower parts is set to hold each other with the same release film), using a laminator The resin composition was formed into a sheet shape so that the thickness of the resin composition became 100 μm, and an adhesive sheet laminate was produced. The release layer side of the polyester film was arranged so as to be in contact with the resin composition. The obtained adhesive sheet laminate system was vacuum-formed (made by Daiichi Sangyo Co., Ltd., FKS-0632-20), and thermoformed by the following process to produce a shaped adhesive sheet laminate. That is, an IR heater preheated at 400 ° C was used to heat the surface of the laminated sheet to 100 ° C, and then a forming mold cooled to 25 ° C was used for 5 seconds under the condition of clamping pressure of 8 MPa. Press forming to produce a shaped adhesive sheet laminate formed by forming irregularities on the surface. The polyester film of the shaped adhesive sheet laminate formed with irregularities was peeled off, and the heights of the concave and convex portions of the shaped adhesive sheet were measured in a non-contact manner using a scanning white interference microscope, respectively. Set to h. The height h of the convex part of the formed body with respect to the depth of the mold of 100 μm was measured. The transfer rate derived from the following calculation formula was 70% or more, and ○, and 50% or more and less than 70% was evaluated as △. , Those who did not reach 50% were evaluated as ×. Transfer rate (%) = h (molded article height) / 100 (die depth) × 100 (5) Adhesive layer appearance (wrinkle) The following evaluation methods were used to evaluate the obtained by the method described in (4), respectively. The appearance of the adhesive laminate before pressing. <Evaluation method> ○: Laminated without wrinkles, and maintained good appearance. ×: Wrinkles are generated in the film, and the wrinkles are transferred to the adhesive layer, and the film cannot be used as a product. [Table 4] [Industrial availability] The shaped adhesive sheet laminate of the present invention is used to form, for example, a personal computer, a mobile terminal (PDA), a game machine, a television (TV), a car navigation system, a touch panel, a tablet, and the like. This type of image display device can be suitably used. The adhesive sheet laminate or coating film of the present invention can be suitably used when forming such a shaped adhesive sheet laminate.

1‧‧‧ this shaped adhesive sheet laminate

2‧‧‧ Adhesive material layer

2A‧‧‧ Adhesive material layer on one side of front and back

2B‧‧‧ Concave and convex part on the surface of the adhesive sheet

2C‧‧‧ Adhesive material layer on the other side

3A‧‧‧ One of the front and back side surfaces of the covered part I

3B‧‧‧ Surface uneven part

3C‧‧‧ Sheet back

3D‧‧‧Protects convex and concave portions on the back of the sheet

FIG. 1 is a cross-sectional view schematically showing an example of an adhesive sheet laminate as an embodiment of the present invention. FIG. 2 is a cross-sectional view for explaining an example of a pressure step when a shaped adhesive sheet laminate is produced using an example of the adhesive sheet laminate as an embodiment of the present invention. FIG. 3 is a view schematically showing an example of a laminated body of shaped adhesive sheet as an embodiment of the present invention, (A) is a cross-sectional view, and (B) is a perspective view. FIG. 4 is a graph showing a viscoelastic curve of a material used for an adhesive sheet laminate produced in Examples and Comparative Examples. FIG. 5 is a perspective view showing one of the molds used in Examples and Comparative Examples.

Claims (30)

An adhesive sheet laminated body is provided with an adhesive material layer and a coating portion I formed by laminating on one side of the adhesive material layer in a peelable manner, characterized in that the above-mentioned coating portion I is at 100 ° C. The storage elastic modulus E '(MA) is 1.0 × 10 ⁶ to 2.0 × 10 ⁹ Pa, and the storage elastic modulus E ′ (MB) of the coated portion I at 30 ° C. is 5.0 × 10 ⁷ to 1.0 × 10 ¹⁰ Pa. For example, the adhesive sheet laminate of claim 1, wherein the storage elastic modulus E '(MA) and the storage elastic modulus E' (MB) satisfy the following relational expressions (1), (1) E '(MB) /E'(MA)≧2.0. For example, the adhesive sheet laminate of claim 1 or 2, wherein the loss tangent tanδ (SA) of the above adhesive material layer at 100 ° C is 1.0 or more, and the loss tangent tanδ (SB) of the above adhesive material layer at 30 ° C is not Up to 1.0. For example, the adhesive sheet laminate according to any one of claims 1 to 3, wherein the storage elastic modulus G '(SA) of the above adhesive material layer at 100 ° C does not reach 1.0 × 10 ⁴ Pa, and the above adhesive material layer is The storage elastic modulus G '(SB) at 30 ° C is 1.0 × 10 ⁴ Pa or more. For example, the adhesive sheet laminate according to any one of claims 1 to 4, wherein the storage elastic modulus E '(MA) of the coating portion I at 100 ° C and the storage elastic modulus of the adhesive layer at 100 ° C G '(SA) satisfies the following relational expression (2), (2) 1.0 × 10 ³ ≦ E ′ (MA) / G ′ (SA) ≦ 1.0 × 10 ⁷ . The adhesive sheet laminate according to any one of claims 1 to 5, wherein the coating portion I includes a coating base material layer and a release layer, and the coating base material layer is selected from the group consisting of polyester, copolymerized polyester, poly One or more resins in the group consisting of olefins and copolymerized polyolefins as the main component of the stretched or unstretched layer. For example, the adhesive sheet laminate according to any one of claims 1 to 6, wherein the adhesive material layer and the coating portion I satisfy the following conditions (I) to (III), (I) the coating is performed at 30 ° C The peeling force F (C) when the part I was peeled from the above-mentioned adhesive material layer was 0.2 N / cm or less; (II) The adhesive sheet laminate was heated at 100 ° C for 5 minutes, and then cooled to 30 ° C, under the environment of 30 ° C. The peeling force F (D) when peeling the coating portion I from the adhesive material layer is 0.2 N / cm or less; (III) The absolute value of the difference between the peeling force F (C) and the peeling force F (D) is 0.1 N / cm or less. The adhesive sheet laminate according to any one of claims 1 to 7, wherein the adhesive layer is composed of a (meth) acrylic copolymer (a), a crosslinking agent (b), and a photopolymerization initiator ( c) a resin composition. A shaped adhesive sheet laminated body, which uses the adhesive sheet laminated body according to any one of claims 1 to 8, and the adhesive layer is provided with recesses, protrusions, or irregularities on one of the front and back side surfaces. (The "concave and convex portion on the surface of the adhesive material layer"), and the covering portion I is in close contact with one of the front and back surfaces of the adhesive material layer, and has concave, convex, or uneven portions on the front and back surfaces (Referred to as "concave-convex part on the surface of the coating part"), and the surface on the other side of the front side and the back side opposite to one of the front and back sides is provided with projections corresponding to the uneven portions on the surface of the adhesive layer Part, concave part, or convex-concave part (referred to as "convex-convex part convex-concave part"). For example, the laminated adhesive sheet laminated body according to claim 9, wherein the adhesive layer is a double-sided adhesive sheet for bonding two adherends, and the uneven portion on the surface of the adhesive layer is connected to any of the adherends. The concave part, convex part, or uneven part in the adhered surface (referred to as "convex part on the surface of the adherend"). For example, the shaped adhesive sheet laminate of claim 10, wherein any one of the above-mentioned adhered systems is selected from the group consisting of a surface protection panel, a touch panel, and an image display panel. A method for manufacturing a shaped adhesive sheet laminated body, characterized in that it is heating the adhesive sheet laminated body according to any one of claims 1 to 8, and applies pressure forming, vacuum forming, pressure forming or rolls The at least one side of the above-mentioned adhesive sheet is formed into a concave-convex shape by press forming. A coating film characterized in that it constitutes the coating part I of the adhesive sheet laminate according to any one of claims 1 to 8 and is provided on at least one side of the copolymerized polyester film with a coating The coating film of the cloth layer has a storage elastic modulus E ′ at 100 ° C. of 1.5 × 10 ⁹ Pa or less, and a shrinkage rate of 3.0% or less after heating at 120 ° C. for 5 minutes. For example, the coating film of claim 13, wherein the storage elastic modulus E 'at 100 ° C is 1.0 × 10 ⁸ Pa or more. For example, the coating film of claim 13 or 14 has a surface oligomer amount of 1.0 × 10 ^-3 mg / cm ² or less after heating at 180 ° C for 10 minutes. The coating film according to any one of claims 13 to 15, wherein the coating layer is a release layer containing a hardened silicone resin. A manufacturing method of a shaped adhesive sheet laminated body, the shaped adhesive sheet laminated system has a coating part I having an adhesive material layer and a peelable layer laminated on one side of the adhesive material layer, and the adhesive The manufacturing method is characterized by forming a concave portion, a convex portion, or an uneven portion on one surface of a material (referred to as "an uneven portion on the surface of an adhesive material layer"). The manufacturing method is characterized in that it is provided with an adhesive material layer and laminated in a peelable manner. Covering part I formed on one side of the adhesive material layer, heating the adhesive sheet laminate, forming the heated adhesive sheet laminate, and cooling to manufacture a shaped adhesive sheet laminate Method, and heating the laminated sheet body, starting to form when the storage elastic modulus E '(MS) of the covering part I is 1.0 × 10 ⁶ to 2.0 × 10 ⁹ Pa, and storing elasticity in the covering part I The molding was completed in a state where the modulus E '(MF) was 5.0 × 10 ⁷ to 1.0 × 10 ¹⁰ Pa. For example, the method for manufacturing a shaped adhesive sheet laminate according to claim 17 is performed on an adhesive sheet laminate having an adhesive material layer and a covering part I formed by laminating on one side of the adhesive material layer in a peelable manner. Heat, and use a cooled mold to form the heated adhesive sheet laminate. For example, the method for manufacturing a laminated body of shaped adhesive sheet according to claim 17 or 18, wherein the storage elastic modulus E '(MS) of the covering portion I at the beginning of the above-mentioned molding and the storage elastic modulus of the covering portion I at the end of the above-mentioned molding The number E '(MF) satisfies the following relational expression (1), (1) · E' (MF) / E '(MS) ≧ 1.3. For example, the method for manufacturing a shaped adhesive sheet laminate according to any one of claims 17 to 19, wherein the adhesive sheet laminate is heated, and the storage elastic modulus E '(MS) in the coating portion I is 1.0 × 10 ⁶ ～ 2.0 × 10 ⁹ Pa, and the storage elastic modulus G ′ (SS) of the adhesive material layer does not reach 1.0 × 10 ⁴ Pa, and the storage elastic modulus E ′ (MF) of the covering part I The molding is completed in a state of 5.0 × 10 ⁷ to 1.0 × 10 ¹⁰ Pa and the storage elastic modulus G ′ (SF) of the adhesive material layer is 1.0 × 10 ⁴ Pa or more. The method for manufacturing a shaped adhesive sheet laminate according to any one of claims 17 to 20, wherein the storage elastic modulus E '(MF) of the covering portion I at the end of the above-mentioned forming and the adhesive material layer at the end of the above-mentioned forming The storage elastic modulus G '(SF) satisfies the following relational expression (2), (2) E' (MF) / G '(SF) ≦ 1.0 × 10 ⁷ . A manufacturing method of a shaped adhesive sheet laminated body, the shaped adhesive sheet laminated system has a coating part I having an adhesive material layer and a peelable layer laminated on one side of the adhesive material layer, and the adhesive The manufacturing method is characterized by forming a concave portion, a convex portion, or an uneven portion on one surface of a material (referred to as "an uneven portion on the surface of an adhesive material layer"). The manufacturing method is characterized in that it is provided with an adhesive material layer and is peelable. The adhesive sheet laminate of the coating portion I laminated on one side of the adhesive layer is heated, and the heated adhesive sheet laminate is formed by a mold to manufacture a shaped adhesive sheet laminate. The adhesive sheet laminate is heated, forming is started when the surface temperature of the coating part I is 70 to 180 ° C, and the shaped adhesive sheet laminate is taken out from the mold after the surface temperature of the coating part I becomes less than 60 ° C. For example, the method for manufacturing a laminated body of shaped adhesive sheet according to claim 22 is formed by any one of the forming methods of pressure forming, vacuum forming, air forming, roll forming and compression forming. If the manufacturing method of the shaped adhesive sheet laminated body of Claim 22 or 23 is performed continuously using the said shaping | molding method. The manufacturing method of the shaped adhesive sheet laminate according to any one of claims 17 to 24, wherein the coating portion I includes a coating base material layer and a release layer, and the coating base material layer is One or more resins in the group consisting of polyester, copolymerized polyester, unstretched polyolefin, stretched polyolefin, and copolymerized polyolefin as the main component. The method for manufacturing a shaped adhesive sheet laminate according to any one of claims 17 to 25, wherein the adhesive layer is composed of a (meth) acrylic copolymer (a), a crosslinking agent (b), and a light Formed from the resin composition of the polymerization initiator (c). According to the method for manufacturing a shaped adhesive sheet laminate according to any one of claims 17 to 26, in the shaped adhesive sheet laminate, the above-mentioned adhesive material layer is provided with recesses and protrusions on one of the front and back side surfaces. (The "concave and convex portion on the surface of the adhesive material layer"), and the covering portion I is in close contact with one of the front and back side surfaces of the adhesive material layer, and has concave and convex portions on the front and back side surfaces Or asperities (referred to as "covered part surface asperities"), and the asperities are formed on the other side of the front and back surfaces opposite to one of the front and back surfaces to form asperities Convex part, concave part, or convex concave part (referred to as "convex part back convex part"). For example, the method for manufacturing a laminated body of laminated adhesive sheet according to claim 27, wherein the above-mentioned adhesive layer is a double-sided adhesive sheet for bonding two adherends, and the uneven portion on the surface of the adhesive layer is in accordance with any of the above. Concave, convex, or uneven portions on the adhered surface of the adherend (referred to as "convex portions on the adherend surface"). For example, the method for manufacturing a shaped adhesive sheet laminate according to claim 28, wherein any one of the above-mentioned adhered systems is selected from the group consisting of a surface protection panel, a touch panel, and an image display panel. The manufacturing method of the shaped adhesive sheet laminated body according to any one of claims 17 to 29, which comprises heating the adhesive sheet laminated body by press forming, vacuum forming, air forming or roll forming. A concave-convex shape is formed on at least one side of the adhesive sheet.