TW201816128A - 自粒狀含貴金屬耐火材料中分離貴金屬之方法 - Google Patents

自粒狀含貴金屬耐火材料中分離貴金屬之方法 Download PDF

Info

Publication number: TW201816128A
Authority: TW; Taiwan
Prior art keywords: refractory material; precious metal; noble metal; weight; reaction zone
Prior art date: 2016-10-07

Application number

TW106130260A

Other languages

English (en)

Chinese (zh)

Inventor

荷傑溫克勒

克莉絲汀克勞斯哈爾

彼得史翠弗

簡羅德

克理斯多夫羅利奇

Original Assignee

德商賀利氏德國有限責任兩合公司

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2016-10-07

Filing date

2017-09-05

Publication date

2018-05-01

2017-09-05 Application filed by 德商賀利氏德國有限責任兩合公司 filed Critical 德商賀利氏德國有限責任兩合公司

2018-05-01 Publication of TW201816128A publication Critical patent/TW201816128A/zh

Links

239000010970 precious metal Substances 0.000 title claims abstract description 97
239000011819 refractory material Substances 0.000 title claims abstract description 82
238000000034 method Methods 0.000 title claims abstract description 34
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims abstract description 63
238000006243 chemical reaction Methods 0.000 claims abstract description 60
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 33
239000000460 chlorine Substances 0.000 claims abstract description 33
229910052801 chlorine Inorganic materials 0.000 claims abstract description 33
229910000510 noble metal Inorganic materials 0.000 claims description 61
239000007789 gas Substances 0.000 claims description 45
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 28
239000000203 mixture Substances 0.000 claims description 23
239000002699 waste material Substances 0.000 claims description 18
239000000463 material Substances 0.000 claims description 16
239000011261 inert gas Substances 0.000 claims description 14
229910052697 platinum Inorganic materials 0.000 claims description 14
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 12
239000002893 slag Substances 0.000 claims description 11
238000005065 mining Methods 0.000 claims description 10
239000002638 heterogeneous catalyst Substances 0.000 claims description 9
238000002156 mixing Methods 0.000 claims description 8
229910001510 metal chloride Inorganic materials 0.000 claims description 6
229910052763 palladium Inorganic materials 0.000 claims description 6
239000012141 concentrate Substances 0.000 claims description 5
239000010802 sludge Substances 0.000 claims description 5
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
229910052741 iridium Inorganic materials 0.000 claims description 3
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 3
229910052762 osmium Inorganic materials 0.000 claims description 3
SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims description 3
229910052709 silver Inorganic materials 0.000 claims description 3
239000004332 silver Substances 0.000 claims description 3
239000007787 solid Substances 0.000 claims description 3
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 2
230000015572 biosynthetic process Effects 0.000 claims description 2
230000008021 deposition Effects 0.000 claims description 2
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
229910052737 gold Inorganic materials 0.000 claims description 2
239000010931 gold Substances 0.000 claims description 2
229910052707 ruthenium Inorganic materials 0.000 claims description 2
239000003054 catalyst Substances 0.000 description 25
239000002245 particle Substances 0.000 description 17
238000000227 grinding Methods 0.000 description 10
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
238000000576 coating method Methods 0.000 description 5
239000008187 granular material Substances 0.000 description 5
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
229910052782 aluminium Inorganic materials 0.000 description 4
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
239000011248 coating agent Substances 0.000 description 4
229910017604 nitric acid Inorganic materials 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
230000002093 peripheral effect Effects 0.000 description 4
238000000926 separation method Methods 0.000 description 4
239000000126 substance Substances 0.000 description 4
101150003085 Pdcl gene Proteins 0.000 description 3
238000004380 ashing Methods 0.000 description 3
238000002485 combustion reaction Methods 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
229910052703 rhodium Inorganic materials 0.000 description 3
239000010948 rhodium Substances 0.000 description 3
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 3
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
230000003197 catalytic effect Effects 0.000 description 2
238000004182 chemical digestion Methods 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
230000005611 electricity Effects 0.000 description 2
238000000605 extraction Methods 0.000 description 2
239000012535 impurity Substances 0.000 description 2
238000001095 inductively coupled plasma mass spectrometry Methods 0.000 description 2
238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
238000012545 processing Methods 0.000 description 2
238000000746 purification Methods 0.000 description 2
238000000197 pyrolysis Methods 0.000 description 2
238000007670 refining Methods 0.000 description 2
238000012958 reprocessing Methods 0.000 description 2
ZUGAOYSWHHGDJY-UHFFFAOYSA-K 5-hydroxy-2,8,9-trioxa-1-aluminabicyclo[3.3.2]decane-3,7,10-trione Chemical compound [Al+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O ZUGAOYSWHHGDJY-UHFFFAOYSA-K 0.000 description 1
229910000505 Al2TiO5 Inorganic materials 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
229910052684 Cerium Inorganic materials 0.000 description 1
150000000703 Cerium Chemical class 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
229910021536 Zeolite Inorganic materials 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
239000003570 air Substances 0.000 description 1
238000004887 air purification Methods 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
239000000956 alloy Substances 0.000 description 1
238000000137 annealing Methods 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
238000001354 calcination Methods 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002091 carbon monoxide Inorganic materials 0.000 description 1
239000012159 carrier gas Substances 0.000 description 1
239000012876 carrier material Substances 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
239000006255 coating slurry Substances 0.000 description 1
238000011437 continuous method Methods 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
229910052878 cordierite Inorganic materials 0.000 description 1
JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 1
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
238000005188 flotation Methods 0.000 description 1
238000005243 fluidization Methods 0.000 description 1
239000008246 gaseous mixture Substances 0.000 description 1
239000010439 graphite Substances 0.000 description 1
229910002804 graphite Inorganic materials 0.000 description 1
229910000856 hastalloy Inorganic materials 0.000 description 1
239000001307 helium Substances 0.000 description 1
229910052734 helium Inorganic materials 0.000 description 1
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
238000005984 hydrogenation reaction Methods 0.000 description 1
238000009854 hydrometallurgy Methods 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
230000002452 interceptive effect Effects 0.000 description 1
HFGPZNIAWCZYJU-UHFFFAOYSA-N lead zirconate titanate Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Zr+4].[Pb+2] HFGPZNIAWCZYJU-UHFFFAOYSA-N 0.000 description 1
229910052451 lead zirconate titanate Inorganic materials 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
238000010309 melting process Methods 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
239000007769 metal material Substances 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
NFFIWVVINABMKP-UHFFFAOYSA-N methylidynetantalum Chemical compound [Ta]#C NFFIWVVINABMKP-UHFFFAOYSA-N 0.000 description 1
229910052863 mullite Inorganic materials 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
229910052756 noble gas Inorganic materials 0.000 description 1
150000002835 noble gases Chemical class 0.000 description 1
239000008188 pellet Substances 0.000 description 1
239000011148 porous material Substances 0.000 description 1
AABBHSMFGKYLKE-SNAWJCMRSA-N propan-2-yl (e)-but-2-enoate Chemical compound C\C=C\C(=O)OC(C)C AABBHSMFGKYLKE-SNAWJCMRSA-N 0.000 description 1
239000000376 reactant Substances 0.000 description 1
238000002407 reforming Methods 0.000 description 1
229910003468 tantalcarbide Inorganic materials 0.000 description 1
MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 description 1
LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
238000011144 upstream manufacturing Methods 0.000 description 1
239000010457 zeolite Substances 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/04—Obtaining noble metals by wet processes
- C22B11/042—Recovery of noble metals from waste materials
- C22B11/048—Recovery of noble metals from waste materials from spent catalysts
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/06—Chloridising
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Manufacturing & Machinery (AREA)
Materials Engineering (AREA)
Mechanical Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Catalysts (AREA)
Manufacture And Refinement Of Metals (AREA)

TW106130260A 2016-10-07 2017-09-05 自粒狀含貴金屬耐火材料中分離貴金屬之方法 TW201816128A (zh)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
EP16192810		2016-10-07
??16192810.6		2016-10-07

Publications (1)

Publication Number	Publication Date
TW201816128A true TW201816128A (zh)	2018-05-01

Family

ID=57133022

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
TW106130260A TW201816128A (zh)	2016-10-07	2017-09-05	自粒狀含貴金屬耐火材料中分離貴金屬之方法

Country Status (2)

Country	Link
TW (1)	TW201816128A (fr)
WO (1)	WO2018065126A1 (fr)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2828200A (en) *	1955-07-25	1958-03-25	Universal Oil Prod Co	Method of removing platinum from a composite containing platinum and alumina
US2860045A (en)	1955-07-25	1958-11-11	Universal Oil Prod Co	Method of removing platinum from a composite containing platinum and alumina
PL2985354T3 (pl) *	2014-11-10	2017-04-28	Heraeus Deutschland Gmbh & Co Kg	Sposób usuwania metalu szlachetnego z kształtek katalizatora zawierających metal szlachetny

2017
- 2017-04-13 WO PCT/EP2017/058911 patent/WO2018065126A1/fr not_active Ceased
- 2017-09-05 TW TW106130260A patent/TW201816128A/zh unknown

Also Published As

Publication number	Publication date
WO2018065126A1 (fr)	2018-04-12

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