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TW201736967A - Photosensitive composition - Google Patents

Photosensitive composition Download PDF

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Publication number
TW201736967A
TW201736967A TW106110340A TW106110340A TW201736967A TW 201736967 A TW201736967 A TW 201736967A TW 106110340 A TW106110340 A TW 106110340A TW 106110340 A TW106110340 A TW 106110340A TW 201736967 A TW201736967 A TW 201736967A
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Taiwan
Prior art keywords
group
carbon atoms
represented
substituent
above formula
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TW106110340A
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Chinese (zh)
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TWI729100B (en
Inventor
Yukiko Kanehara
Tomoyasu Kawahara
Izumi Matsui
Mitsuhiro Okada
Naomi Sato
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Adeka Corp
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    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/08—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated side groups
    • C08F290/12—Polymers provided for in subclasses C08C or C08F
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Materials For Photolithography (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

The purpose of the present invention is to provide a photosensitive composition that gives a cured product having a high heat resistance and a high solvent resistance. Provided is a photosensitive composition that contains a latent additive (A), a polymer (B) having an ethylenically unsaturated bond and a hydrophilic group in each molecule, with a double bond equivalent of 200 to 1,000, an acrylic monomer (C), and a photo-radical polymerization initiator (D). The content of the latent additive (A) in the photosensitive composition is preferably 0.001 to 20% by mass. This photosensitive composition is curable by actinic ray radiation.

Description

感光性組合物Photosensitive composition

本發明係關於一種感光性組合物，其含有於常溫下為鈍性且藉由加熱至既定之溫度而活化並表現功能之潛伏性添加劑、於一分子內具有乙烯性不飽和鍵及親水性基且具有一定之雙鍵當量之聚合物、丙烯酸系單體及光自由基聚合起始劑。進而，本發明係關於一種使用該組合物之可藉由能量線進行聚合之著色感光性組合物及使用該著色感光性組合物之彩色濾光片。The present invention relates to a photosensitive composition comprising a latent additive which is blunt at normal temperature and which is activated and functions by heating to a predetermined temperature, has an ethylenically unsaturated bond and a hydrophilic group in one molecule. A polymer having a certain double bond equivalent, an acrylic monomer, and a photoradical polymerization initiator. Further, the present invention relates to a colored photosensitive composition which can be polymerized by an energy ray using the composition, and a color filter using the colored photosensitive composition.

為了提高樹脂組合物之耐候性或耐熱性，已知添加紫外線吸收劑或抗氧化劑而使其穩定之方法(專利文獻1)。 又，已知於感光性組合物中，藉由將樹脂之雙鍵當量保持於一定範圍內而描繪微細圖案或者提高硬化物之對比度。然而，尚未知藉由將樹脂之雙鍵當量保持於一定範圍內而提高耐溶劑性(專利文獻2～5)。 酚系抗氧化劑具有捕獲對聚合物之劣化產生較大影響之自由基之作用，因此若將抗氧化劑添加至聚合系內，則通常存在作為所謂之聚合抑制劑發揮作用而引起硬化阻礙之問題，故而業界一直在開發潛伏性添加劑(專利文獻6)。 先前技術文獻 專利文獻 專利文獻1：日本專利特開2002-097224號公報 專利文獻2：日本專利特開2009-134078號公報 專利文獻3：日本專利特開2013-037272號公報 專利文獻4：美國專利申請公開第2015/254210號說明書 專利文獻5：日本專利第5460179號公報 專利文獻6：美國專利申請公開第2015/291772號說明書In order to improve the weather resistance and heat resistance of the resin composition, a method of adding an ultraviolet absorber or an antioxidant to stabilize it is known (Patent Document 1). Further, it is known that in a photosensitive composition, a fine pattern is drawn or the contrast of a cured product is improved by keeping the double bond equivalent of the resin within a certain range. However, it has not been known that solvent resistance is improved by keeping the double bond equivalent of the resin within a certain range (Patent Documents 2 to 5). The phenolic antioxidant has a function of trapping a radical which greatly affects the deterioration of the polymer. Therefore, when an antioxidant is added to the polymerization system, there is usually a problem that it acts as a so-called polymerization inhibitor and causes hardening inhibition. Therefore, the industry has been developing latent additives (Patent Document 6). PRIOR ART DOCUMENT Patent Document Patent Document 1: Japanese Patent Laid-Open Publication No. JP-A-2002-097224. Application Publication No. 2015/254210, Patent Document 5: Japanese Patent No. 5,460,179, Patent Document 6: US Patent Application Publication No. 2015/291772

因此，本發明之目的在於提供一種感光性組合物，其含有於常溫下為鈍性且藉由加熱至既定之溫度而活化並表現功能之潛伏性添加劑、於一分子內具有乙烯性不飽和鍵及親水性基且具有一定之雙鍵當量之聚合物、丙烯酸系單體及光自由基聚合起始劑。 本發明者等反覆進行努力研究，結果發現，含有於常溫下為鈍性且藉由加熱至既定之溫度而活化並表現功能之潛伏性添加劑、於一分子內具有乙烯性不飽和鍵及親水性基且具有一定之雙鍵當量之聚合物、丙烯酸系單體及光自由基聚合起始劑的感光性組合物之硬化物係耐熱性及耐溶劑性較高，適於液晶顯示面板等圖像顯示裝置用彩色濾光片，從而完成了本發明。 本發明係基於上述見解而成者，且提供一種感光性組合物，其含有於常溫下為鈍性且藉由加熱至既定之溫度而活化並表現功能之潛伏性添加劑(A)(以下亦稱為潛伏性添加劑(A))、於一分子內具有乙烯性不飽和鍵及親水性基且雙鍵當量為200～1000之聚合物(B)(以下亦稱為聚合物(B))、丙烯酸系單體(C)及光自由基聚合起始劑(D)。Accordingly, an object of the present invention is to provide a photosensitive composition comprising a latent additive which is blunt at normal temperature and which is activated by a heating to a predetermined temperature and which exhibits a function, and has an ethylenically unsaturated bond in one molecule. A polymer having a hydrophilic double group and having a certain double bond equivalent, an acrylic monomer, and a photoradical polymerization initiator. As a result of intensive studies, the present inventors have found that a latent additive which is blunt at normal temperature and which is activated by a heating to a predetermined temperature and exhibits a function, has an ethylenically unsaturated bond and hydrophilicity in one molecule. A cured composition of a photosensitive composition having a certain double bond equivalent polymer, an acrylic monomer, and a photoradical polymerization initiator is high in heat resistance and solvent resistance, and is suitable for an image such as a liquid crystal display panel. The display device uses a color filter, thereby completing the present invention. The present invention is based on the above findings, and provides a photosensitive composition containing a latent additive (A) which is blunt at normal temperature and which is activated by a heating to a predetermined temperature and exhibits a function (hereinafter also referred to as a latent additive (A)), a polymer (B) having an ethylenically unsaturated bond and a hydrophilic group in one molecule and having a double bond equivalent of 200 to 1000 (hereinafter also referred to as a polymer (B)), and acrylic acid A monomer (C) and a photoradical polymerization initiator (D).

以下，基於較佳之實施形態對本發明進行詳細說明。 本發明之感光性組合物含有潛伏性添加劑(A)、於一分子內具有乙烯性不飽和鍵及親水性基且雙鍵當量200～1000之聚合物(B)、丙烯酸系單體(C)及光自由基聚合起始劑(D)。以下，依序對各成分進行說明。 ＜潛伏性添加劑(A)＞ 用於本發明之感光性組合物之潛伏性添加劑(A)係於常溫下或預烤步驟中為鈍性，藉由以100～250℃進行加熱或者於酸/鹼觸媒存在下以80～200℃進行加熱，保護基脫離而變為活性。所謂潛伏性添加劑(A)為活性，係指對自由基具有反應性，所謂為鈍性係指不與自由基反應或者反應性極低。於本發明之感光性組合物中，關於潛伏性添加劑(A)，具有下述通式(I)所表示之骨架者容易合成且耐熱性較高，因此較佳。 [化1](式中，環A1 表示五員環或六員環之烴環或雜環或縮合環， R61 分別獨立地表示鹵素原子、氰基、羥基、硝基、羧基、亦存在具有取代基之情形之碳原子數1～40之烷基、亦存在具有取代基之情形之碳原子數6～20之芳基、亦存在具有取代基之情形之碳原子數7～20之芳烷基或亦存在具有取代基之情形之碳原子數2～20之含雜環基， R62 分別獨立地表示碳原子數1～20之烷基、碳原子數2～20之烯基、碳原子數6～20之芳基、碳原子數7～20之芳烷基、碳原子數2～20之含雜環基或三烷基矽烷基， R61 及R62 所表示之烷基或芳烷基中之亞甲基存在經將選自碳-碳雙鍵、-O-、-S-、-CO-、-O-CO-、-CO-O-、-O-CO-O-、-O-CO-O-、-S-CO-、-CO-S-、-S-CO-O-、-O-CO-S-、-CO-NH-、-NH-CO-、-NH-CO-O-、-NR'-、-S-S-或-SO2 -中之基以氧原子不相鄰之條件組合而成之基取代之情形，R'表示氫原子或碳原子數1～8之烷基， 複數個R61 亦存在彼此鍵結而形成苯環或萘環之情形， d表示0～4之整數， k表示1～5之整數，d與k之合計少於環A1 可取之取代基之個數， ﹡意指於﹡部分與鄰接之基鍵結) 於具有上述通式(I)所表示之骨架者中，下述通式(I-A)所表示者係耐熱性特別高，因此較佳。 [化2](式中，環A1 、R61 、R62 、d及k與上述通式(I)相同， m表示1～10之整數， X1 表示m價有機基) 於本說明書中，所謂碳原子數2～20之含雜環基意指含有至少一個雜環且基總體之碳數為2～20之基。同樣地，下述所謂碳原子數2～10之含雜環基意指含有至少一個雜環且基總體之碳數為2～10之基。又，下述所謂碳原子數2～35之含雜環基意指含有至少一個雜環且基總體之碳數為2～35之基。於該等含有雜環之基中之該雜環具有取代基之情形時，存在基總體之碳原子數超過各基之上限值之情形。於含有雜環之基中之該雜環具有取代基之情形時，作為該取代基，例如可列舉作為存在將下述X1 所表示之基取代之情形的取代基而例示者。 作為上述通式(I)中之A1 所表示之五員環之烴環，可列舉環戊二烯等，作為五員環之雜環，可列舉：呋喃、噻吩、吡咯、吡咯啶、吡唑啶、吡唑、咪唑、咪唑啶、㗁唑、異㗁唑、異㗁唑啶、噻唑、異噻唑、異四氫噻唑等，作為六員環之烴環，可列舉苯等，作為六員環之雜環，可列舉：哌啶、哌&#134116;、&#134156;啉、硫代&#134156;啉、吡啶、吡&#134116;、嘧啶、嗒&#134116;、三&#134116;等，該等環存在與其他環縮合或經取代之情形，作為縮合環，例如可列舉：喹啉、異喹啉、吲哚、&#134075;咯啶、苯并㗁唑、苯并三唑、薁、萘、蒽、茀、苝、芘等。 作為上述通式(I)中之R61 所表示之鹵素原子，可列舉：氟、氯、溴、碘(再者，於以下之說明書中之記載中，鹵素原子均與上述相同)。 作為上述通式(I)中之R61 所表示之碳原子數1～40之烷基，可列舉：甲基、乙基、丙基、異丙基、丁基、第二丁基、第三丁基、異丁基、戊基、異戊基、第三戊基、環戊基、己基、2-己基、3-己基、環己基、4-甲基環己基、庚基、2-庚基、3-庚基、異庚基、第三庚基、1-辛基、異辛基、第三辛基、金剛烷基等。 作為將上述通式(I)中之R61 所表示之碳原子數1～40之烷基、碳原子數6～20之芳基、碳原子數7～20之芳烷基或碳原子數2～20之含雜環基取代之取代基，可列舉：乙烯基、烯丙基、丙烯酸基、甲基丙烯酸基等乙烯性不飽和基；氟、氯、溴、碘等鹵素原子；乙醯基、2-氯乙醯基、丙醯基、辛醯基、丙烯醯基、甲基丙烯醯基、苯基羰基(苯甲醯基)、鄰苯二甲醯基、4-三氟甲基苯甲醯基、三甲基乙醯基、鄰羥苯甲醯基、草醯基、硬脂醯基、甲氧基羰基、乙氧基羰基、第三丁氧基羰基、正十八烷氧基羰基、胺甲醯基等醯基；乙醯氧基、苯甲醯氧基等醯氧基；胺基、乙基胺基、二甲基胺基、二乙基胺基、丁基胺基、環戊基胺基、2-乙基己基胺基、十二烷基胺基、苯胺基、氯苯基胺基、甲苯胺基、甲氧苯胺基、N-甲基-苯胺基、二苯基胺基、萘基胺基、2-吡啶基胺基、甲氧基羰基胺基、苯氧基羰基胺基、乙醯基胺基、苯甲醯基胺基、甲醯基胺基、三甲基乙醯基胺基、月桂醯基胺基、胺甲醯基胺基、N,N-二甲基胺基羰基胺基、N,N-二乙基胺基羰基胺基、&#134156;啉基羰基胺基、甲氧基羰基胺基、乙氧基羰基胺基、第三丁氧基羰基胺基、正十八烷氧基羰基胺基、N-甲基-甲氧基羰基胺基、苯氧基羰基胺基、胺磺醯基胺基、N,N-二甲基胺基磺醯基胺基、甲基磺醯基胺基、丁基磺醯基胺基、苯基磺醯基胺基等取代胺基；磺醯胺基、磺醯基、羧基、氰基、磺基、羥基、硝基、巰基、醯亞胺基、胺甲醯基、磺醯胺基、膦酸基、磷酸基或羧基、磺基、膦酸基、磷酸基之鹽等。 作為上述通式(I)中之R61 及R62 所表示之碳原子數6～20之芳基，可列舉：苯基、萘基、蒽基、菲基、茀基、茚基、2-甲基苯基、3-甲基苯基、4-甲基苯基、4-乙烯基苯基、3-異丙基苯基、4-異丙基苯基、4-丁基苯基、4-異丁基苯基、4-第三丁基苯基、4-己基苯基、4-環己基苯基、4-辛基苯基、4-(2-乙基己基)苯基、4-硬脂基苯基、2,3-二甲基苯基、2,4-二甲基苯基、2,5-二甲基苯基、2,6-二甲基苯基、3,4-二甲基苯基、3,5-二甲基苯基、2,4-二-第三丁基苯基、2,5-二-第三丁基苯基、2,6-二-第三丁基苯基、2,4-二-第三戊基苯基、2,5-二-第三戊基苯基、2,5-二-第三辛基苯基、2,4-二異丙苯基苯基、4-環己基苯基、(1,1'-聯苯)-4-基、2,4,5-三甲基苯基、二茂鐵基等。 作為上述通式(I)中之R61 及R62 所表示之碳原子數7～20之芳烷基，可列舉：苄基、1-甲基-1-苯基乙基、1-萘基甲基、9-蒽基甲基、9-茀基、3-苯基丙基、甲基-2-苯基丙烷-2-基、二苯基甲基、三苯基甲基、苯乙基、苯乙烯基、苯烯丙基等。 作為上述通式(I)中之R61 及R62 所表示之碳原子數2～20之含雜環基，可列舉：將吡啶環、嘧啶環、嗒&#134116;環、哌啶環、吡喃環、吡唑啉環、三&#134116;環、吡咯啉環、喹啉環、異喹啉環、咪唑啉環、苯并咪唑啉環、三唑啉環、呋喃環、苯并呋喃環、噻二唑啉環、噻唑啉環、苯并噻唑啉環、噻吩環、㗁唑啉環、苯并㗁唑啉環、異噻唑啉環、異㗁唑啉環、吲哚環、吡咯啶環、哌啶酮環、二㗁烷環等雜環與亞甲基鏈組合而成之基。 作為上述通式(I)中之R62 所表示之碳原子數1～20之烷基，可列舉R61 所表示之上述烷基中滿足既定之碳原子數者。 作為上述通式(I)中之R62 所表示之碳原子數2～20之烯基，可列舉：乙烯基、1-甲基乙烯-1-基、丙烯-1-基、丙烯-2-基、丙烯-3-基、丁烯-1-基、丁烯-2-基、2-甲基丙烯-3-基、1,1-二甲基乙烯-2-基、1,1-二甲基丙烯-3-基、3-丁烯基、1-甲基-3-丁烯基、異丁烯基、3-戊烯基、4-己烯基、環己烯基、雙環己烯基、庚烯基、辛烯基、癸烯基、十五烯基、二十烯基、二十三烯基等。 作為上述通式(I)中之R62 所表示之三烷基矽烷基，可列舉三甲基矽烷、三乙基矽烷、乙基二甲基矽烷等經碳原子數1～6之烷基(3個烷基可相同亦可不同)取代之矽烷基。 作為上述通式(I)中之R'所表示之碳原子數1～8之烷基，可列舉R61 所表示之上述烷基中滿足既定之碳原子數者。 通式(I)中，R61 為氫原子、碳原子數1～8之烷基、碳原子數6～12之芳基之情況下容易合成，因此較佳。 通式(I)中，R62 為於碳原子數1～8之烷基之氧原子側之末端鍵結有-CO-O-者可作為潛伏性添加劑而有效率地發揮功能，因此較佳。 於上述通式(I-A)中，X1 表示m價有機基，具體而言，表示直接鍵結、氫原子、氮原子、氧原子、硫原子、磷原子、下述(I-a)或(I-b)所表示之基、＞C＝O、＞NR63 、-OR63 、-SR63 、-NR63 R64 、或亦存在具有取代基之情形的具有與m相同之價數之碳原子數1～120之脂肪族烴基、亦存在具有取代基之情形的具有與m相同之價數之碳原子數6～35之含芳香環烴基、亦存在具有取代基之情形的具有與m相同之價數之碳原子數2～35之含雜環基，R63 及R64 表示氫原子、亦存在具有取代基之情形之碳原子數1～35之脂肪族烴基、亦存在具有取代基之情形之碳原子數6～35之含芳香環烴基或亦存在具有取代基之情形之碳原子數2～35之含雜環基，該脂肪族烴基、含芳香環烴基及含雜環基之亞甲基亦存在經選自碳-碳雙鍵、-O-、-S-、-CO-、-O-CO-、-CO-O-、-O-CO-O-、-O-CO-O-、-S-CO-、-CO-S-、-S-CO-O-、-O-CO-S-、-CO-NH-、-NH-CO-、-NH-CO-O-、-NH-CO-O-、-NR'-、-S-S-、-SO2- 或氮原子中之基取代之情形，R'表示氫原子或碳原子數1～8之烷基。 其中，於X1 為氮原子、磷原子或下述(I-a)或(I-b)所表示之基之情形時，m為3，於X1 為氧原子或硫原子、＞C＝O、-NH-CO-、-CO-NH-或＞NR63 之情形時，m為2，於X1 為-OR63 、-SR63 或-NR63 R64 之情形時，m為1，亦存在X1 與A1 一起而形成環之情形。 [化3](﹡意指於﹡部分與鄰接之基鍵結。) 上述通式(I-A)所表示之潛伏性添加劑具有於X1 所表示之m價之特定原子或基上鍵結有m個特定基之結構。該m個基彼此相同或不同。m之值為1～10，就合成之容易度之方面而言，較佳為2～6。 作為上述通式(I-A)中之X1 所表示之具有與m相同之價數之碳原子數1～120之脂肪族烴基，作為m為1價者，例如可列舉：甲基、乙基、丙基、異丙基、環丙基、丁基、第二丁基、第三丁基、異丁基、戊基、異戊基、第三戊基、環戊基、己基、2-己基、3-己基、環己基、雙環己基、1-甲基環己基、庚基、2-庚基、3-庚基、異庚基、第三庚基、正辛基、異辛基、第三辛基、2-乙基己基、壬基、異壬基、癸基等烷基；甲氧基、乙氧基、丙氧基、異丙氧基、丁氧基、第二丁氧基、第三丁氧基、異丁氧基、戊氧基、異戊氧基、第三戊氧基、己氧基、環己氧基、庚氧基、異庚氧基、第三庚氧基、正辛氧基、異辛氧基、第三辛氧基、2-乙基己氧基、壬氧基、癸氧基等烷氧基；甲硫基、乙硫基、丙硫基、異丙硫基、丁硫基、第二丁硫基、第三丁硫基、異丁硫基、戊硫基、異戊硫基、第三戊硫基、己硫基、環己硫基、庚硫基、異庚硫基、第三庚硫基、正辛硫基、異辛硫基、第三辛硫基、2-乙基己硫基等烷硫基；乙烯基、1-甲基乙烯基、2-甲基乙烯基、2-丙烯基、1-甲基-3-丙烯基、3-丁烯基、1-甲基-3-丁烯基、異丁烯基、3-戊烯基、4-己烯基、環己烯基、雙環己烯基、庚烯基、辛烯基、癸烯基、十五烯基、二十烯基、二十三烯基等烯基及該等基經後述取代基取代而成之基等。 作為上述通式(I-A)中之X1 所表示之具有與m相同之價數之碳原子數1～120之脂肪族烴基，作為m為2價者，可列舉：亞甲基、伸乙基、伸丙基、伸丁基、丁二基等伸烷基；上述伸烷基之亞甲基鏈經-O-、-S-、-CO-O-、-O-CO-取代而成者；乙二醇、丙二醇、丁二醇、戊二醇、己二醇等二醇之殘基；乙二硫醇、丙二硫醇、丁二硫醇、戊二硫醇、己二硫醇等二硫醇之殘基及該等基經後述取代基取代而成之基等。 作為上述通式(I-A)中之X1 所表示之具有與m相同之價數之碳原子數1～120之脂肪族烴基，作為m為3價者，例如可列舉呋喃并吡啶、1,1,3-次丁基等次烷基及該等基經後述取代基取代而成之基。 作為上述通式(I-A)中之X1 所表示之具有與m相同之價數的亦存在具有取代基之情形之碳原子數6～35之含芳香環烴基，作為m為1價者，可列舉：苄基、苯乙基、二苯基甲基、三苯基甲基、苯乙烯基、苯烯丙基等芳烷基；苯基、萘基等芳基；苯氧基、萘氧基等芳氧基；苯硫基、萘硫基等芳硫基及該等基經後述取代基取代而成之基等。 作為上述通式(I-A)中之X1 所表示之亦存在具有取代基之情形的具有與m相同之價數之碳原子數6～35之含芳香環烴基，作為m為2價者，可列舉：伸苯基、伸萘基等伸芳基；鄰苯二酚、雙酚等二官能酚之殘基；2,4,8,10-四氧雜螺[5,5]十一烷等及該等基經後述取代基取代而成之基。 作為上述通式(I-A)中之X1 所表示之亦存在具有取代基之情形的具有與m相同之價數之碳原子數6～35之含芳香環烴基，作為m為3價者，可列舉苯基-1,3,5-三亞甲基及該等基經後述取代基取代而成之基。 作為上述通式(I-A)中之X1 所表示之亦存在具有取代基之情形的具有與m相同之價數之碳原子數2～35之含雜環基，作為m為1價者，可列舉：吡啶基、嘧啶基、嗒&#134116;基、哌啶基、吡喃基、吡唑基、三&#134116;基、吡咯基、喹啉基、異喹啉基、咪唑基、苯并咪唑基、三唑基、呋喃基(furyl)、呋喃基(furanyl)、苯并呋喃基、噻吩基(thienyl)、噻吩基(thiophenyl)、苯并噻吩基、噻二唑基、噻唑基、苯并噻唑基、㗁唑基、苯并㗁唑基、異噻唑基、異㗁唑基、吲哚基、2-吡咯啶酮-1-基、2-哌啶酮-1-基、2,4-二氧基咪唑啶-3-基、2,4-二氧基㗁唑啶-3-基、苯并三唑基等及該等基經後述取代基取代而成之基等。 作為上述通式(I-A)中之X1 所表示之亦存在具有取代基之情形的具有與m相同之價數之碳原子數2～35之含雜環基，作為m為2價者，可列舉：具有吡啶環、嘧啶環、哌啶環、哌&#134116;環、三&#134116;環、呋喃環、噻吩環、吲哚環等之基及該等基經後述取代基取代而成之基。 作為上述通式(I-A)中之X1 所表示之亦存在具有取代基之情形的具有與m相同之價數之碳原子數2～35之含雜環基，作為m為3價者，可列舉：具有異三聚氰酸環之基、具有三&#134116;環之基及該等基經後述取代基取代而成之基。 作為R63 及R64 所表示之亦存在具有取代基之情形之碳原子數1～35之脂肪族烴基，可列舉上述X1 所表示之碳原子數1～120之脂肪族烴基、或該脂肪族烴基與後述取代基之組合中滿足既定之碳原子數者。 作為R63 及R64 所表示之亦存在具有取代基之情形之碳原子數6～35之含芳香環烴基或亦存在具有取代基之情形之碳原子數2～35之含雜環基，可列舉上述X1 所表示之碳原子數6～35之含芳香環烴基或碳原子數2～35之含雜環基、或將該等基與後述取代基組合而成之基。 作為存在將X1 所表示之碳原子數1～120之脂肪族烴基、碳原子數6～35之含芳香環烴基及碳原子數2～35之含雜環基取代之情形的取代基，以及存在將R63 及R6 所表示之碳原子數1～35之脂肪族烴基、碳原子數6～35之含芳香環烴基及碳原子數2～35之含雜環基取代之情形的取代基，可列舉：乙烯基、烯丙基、丙烯酸基、甲基丙烯酸基等乙烯性不飽和基；氟、氯、溴、碘等鹵素原子；乙醯基、2-氯乙醯基、丙醯基、辛醯基、丙烯醯基、甲基丙烯醯基、苯基羰基(苯甲醯基)、鄰苯二甲醯基、4-三氟甲基苯甲醯基、三甲基乙醯基、鄰羥苯甲醯基、草醯基、硬脂醯基、甲氧基羰基、乙氧基羰基、第三丁氧基羰基、正十八烷氧基羰基、胺甲醯基等醯基；乙醯氧基、苯甲醯氧基等醯氧基；胺基、乙基胺基、二甲基胺基、二乙基胺基、丁基胺基、環戊基胺基、2-乙基己基胺基、十二烷基胺基、苯胺基、氯苯基胺基、甲苯胺基、甲氧苯胺基、N-甲基-苯胺基、二苯基胺基、萘基胺基、2-吡啶基胺基、甲氧基羰基胺基、苯氧基羰基胺基、乙醯基胺基、苯甲醯基胺基、甲醯基胺基、三甲基乙醯基胺基、月桂醯基胺基、胺甲醯基胺基、N,N-二甲基胺基羰基胺基、N,N-二乙基胺基羰基胺基、&#134156;啉基羰基胺基、甲氧基羰基胺基、乙氧基羰基胺基、第三丁氧基羰基胺基、正十八烷氧基羰基胺基、N-甲基-甲氧基羰基胺基、苯氧基羰基胺基、胺磺醯基胺基、N,N-二甲基胺基磺醯基胺基、甲基磺醯基胺基、丁基磺醯基胺基、苯基磺醯基胺基等取代胺基；磺醯胺基、磺醯基、羧基、氰基、磺基、羥基、硝基、巰基、醯亞胺基、胺甲醯基、磺醯胺基、膦酸基、磷酸基或羧基、磺基、膦酸基、磷酸基之鹽等，該等基亦存在進一步經取代之情形。又，羧基及磺基亦存在形成鹽之情形。 作為上述通式(I-A)中之R'所表示之碳原子數1～8之烷基，可列舉上述R61 所表示之上述烷基中滿足既定之碳原子數者。 上述通式(I-A)中，m為2時，X1 亦可如下述通式(1)般表示。 [化4](上述通式(1)中，Y10 表示單鍵、-CR65 R66 -、-NR67 -、2價之碳原子數1～35之脂肪族烴基、碳原子數6～35之芳香族烴基或碳原子數2～35之含雜環基、或下述(1-1)～(1-3)所表示之任一取代基， 該脂肪族烴基之鄰接之碳原子亦存在經於-O-、-S-、-CO-、-COO-、-OCO-或-NH-、或氧原子不相鄰的條件下將該等組合而成之鍵結基所中斷之情形， 該脂肪族烴基末端之碳原子亦存在經-O-、-S-、-CO-、-COO-、-OCO-或-NH-取代之情形， 該脂肪族烴基亦存在經羥基、鹵素原子、氰基、硝基、羧基或烷氧基取代之情形， Z1 及Z2 分別獨立地表示直接鍵結、-O-、-S-、＞CO、-CO-O-、-O-CO-、-SO2- 、-SS-、-SO-、＞NR67 或＞PR67 ， R65 、R66 及R67 分別獨立地表示氫原子、羥基、亦存在具有取代基之情形之碳原子數1～35之脂肪族烴基、亦存在具有取代基之情形之碳原子數6～35之芳香族烴基或亦存在具有取代基之情形之碳原子數2～35之含雜環基， ﹡意指於﹡部分與鄰接之基鍵結) [化5](上述式中，R71 表示氫原子、亦存在具有取代基之情形之苯基、或碳原子數3～10之環烷基， R72 表示碳原子數1～10之烷基、碳原子數1～10之烷氧基、碳原子數2～10之烯基或鹵素原子， 上述烷基、烷氧基及烯基存在具有取代基之情形， f為0～5之整數，﹡意指於﹡部分與鄰接之基鍵結) [化6](﹡意指於﹡部分與鄰接之基鍵結) [化7](上述式中，R73 及R74 分別獨立地表示亦存在具有取代基之情形之碳原子數1～10之烷基、亦存在具有取代基之情形之碳原子數6～20之芳基、亦存在具有取代基之情形之碳原子數6～20之芳氧基、亦存在具有取代基之情形之碳原子數6～20之芳硫基、亦存在具有取代基之情形之碳原子數6～20之芳烯基、亦存在具有取代基之情形之碳原子數7～20之芳烷基、亦存在具有取代基之情形之碳原子數2～20之含雜環基或鹵素原子， 該烷基及芳烷基中之亞甲基存在經不飽和鍵、-O-或-S取代之情形， R73 亦存在由鄰接之R73 彼此形成環之情形， p表示0～4之數， q表示0～8之數，g表示0～4之數， h表示0～4之數， g與h之數之合計為2～4， ﹡意指於﹡部分與鄰接之基鍵結) 上述通式(I-A)中，m為3時，X1 亦可如下述通式(2)般表示。 [化8](上述通式(2)中，Y11 表示單鍵、3價之碳原子數3～35之脂肪族烴基、3價之碳原子數3～35之脂環族烴基、3價之碳原子數6～35之芳香族烴基或3價之碳原子數2～35之含雜環基， Z1 、Z2 及Z3 分別獨立地表示直接鍵結、-O-、-S-、＞CO、-CO-O-、-O-CO-、-SO2- 、-SS-、-SO-、＞NR68 或＞PR68 ， R68 表示氫原子、亦存在具有取代基之情形之碳原子數1～35之脂肪族烴基、亦存在具有取代基之情形之碳原子數6～35之芳香族烴基或亦存在具有取代基之情形之碳原子數2～35之含雜環基， 該脂肪族烴基之鄰接之碳原子亦存在經碳-碳雙鍵、-O-、-CO-、-O-CO-、-CO-O-或-SO2- 中斷之情形， 該脂肪族烴基末端之碳原子亦存在經碳-碳雙鍵、-O-、-CO-、-O-CO-、-CO-O-或-SO2- 取代之情形) 上述通式(I-A)中，m為4時，X1 亦可如下述通式(3)般表示。 [化9](上述通式(3)中，Y12 表示單鍵、碳原子、或者4價之碳原子數1～35之脂肪族烴基、4價之碳原子數6～35之芳香族烴基或4價之碳原子數2～35之含雜環基， 該脂肪族烴基之鄰接之碳原子存在經-COO-、-O-、-OCO-、-NHCO-、-NH-或-CONH-中斷之情形， 該脂肪族烴基末端之碳原子存在經-COO-、-O-、-OCO-、-NHCO-、-NH-或-CONH-取代之情形， Z1 ～Z4 分別獨立地為與上述通式(2)中之Z1 ～Z3 所表示之基相同範圍之基) 上述通式(I-A)中，m為5時，X1 亦可如下述通式(4)般表示。 [化10](上述通式(4)中，Y13 表示單鍵、5價之碳原子數2～35之脂肪族烴基、5價之碳原子數6～20之芳香族烴基或5價之碳原子數2～20之含雜環基， 該脂肪族烴基之鄰接之碳原子存在經-COO-、-O-、-OCO-、-NHCO-、-NH-或-CONH-中斷之情形， 該脂肪族烴基末端之碳原子存在經-COO-、-O-、-OCO-、-NHCO-、-NH-或-CONH-取代之情形， Z1 ～Z5 分別獨立地為與上述通式(2)中之Z1 ～Z3 所表示之基相同範圍之基) 上述通式(I-A)中，m為6時，X1 亦可如下述通式(5)般表示。 [化11](上述通式(5)中，Y14 表示單鍵、6價之碳原子數2～35之脂肪族烴基、6價之碳原子數6～35之芳香族烴基或6價之碳原子數2～35之含雜環基， 該脂肪族烴基之鄰接之碳原子存在經-COO-、-O-、-OCO-、-NHCO-、-NH-或-CONH-中斷之情形， 該脂肪族烴基末端之碳原子存在經-COO-、-O-、-OCO-、-NHCO-、-NH-或-CONH-取代之情形， Z1 ～Z6 分別獨立地為與上述通式(2)中之Z1 ～Z3 所表示之基相同範圍之基) 作為上述通式(1)中之R65 、R66 及R67 所表示之亦存在具有取代基之情形之碳原子數1～35之脂肪族烴基，可列舉：作為上述通式(I-A)中之X1 所表示之m價有機基所例示之1價之碳原子數1～120之脂肪族烴基、及該等基經作為表示上述通式(I-A)中之X1 所表示之m價有機基之基的取代基所例示者取代而成之基中滿足既定之碳原子數者等，作為該等基或上述通式(I-A)中之X1 所表示之m價有機基所例示之2價之脂肪族烴基經Z1 及Z2 取代而成之2價之基可列舉作為Y10 所表示之2價之碳原子數1～35之脂肪族烴基。 作為R65 、R66 及R67 所表示之亦存在具有取代基之情形之碳原子數6～35之含芳香環烴基，可列舉：作為上述通式(I-A)中之X1 所表示之m價有機基所例示之1價之碳原子數6～35之含芳香環烴基、及該等基經作為表示上述通式(I-A)中之X1 所表示之m價有機基之基的取代基所例示者取代而成之基等，作為該等基或上述通式(I-A)中之X1 所表示之m價有機基所例示之2價之碳原子數6～35之含芳香環烴基經Z1 及Z2 取代而成之2價之基可列舉作為Y10 所表示之2價之碳原子數6～35之含芳香環烴基。 作為R65 、R66 及R67 所表示之亦存在具有取代基之情形之碳原子數2～35之含雜環基，可列舉：作為上述通式(I-A)中之X1 所表示之m價有機基所例示之1價之碳原子數2～35之含雜環基、及該等基經作為表示上述通式(I-A)中之X1 所表示之m價有機基之基的取代基所例示者取代而成之基等，作為該等基或上述通式(I-A)中之X1 所表示之m價有機基所例示之2價之碳原子數2～35之含芳香環烴基經Z1 及Z2 取代而成之2價之基可列舉作為Y10 所表示之2價之碳原子數2～35之含雜環基。 上述(1-1)所表示之取代基中，作為R71 所表示之碳原子數3～10之環烷基，可列舉：環丙基、環丁基、環戊基、環庚基、環辛基等。 上述(1-1)所表示之取代基中，作為R72 所表示之碳原子數1～10之烷基，可列舉作為R61 所表示之碳原子數1～40之烷基所例示之基中滿足既定之碳原子數之基等。 上述(1-1)所表示之取代基中，作為R72 所表示之碳原子數1～10之烷氧基，可列舉：甲氧基、乙氧基、丙氧基、異丙氧基、丁氧基、第二丁氧基、第三丁氧基、異丁氧基、戊氧基、異戊氧基、第三戊氧基、己氧基、環己氧基、庚氧基、異庚氧基、第三庚氧基、正辛氧基、異辛氧基、第三辛氧基、2-乙基己氧基、壬氧基、癸氧基等。 上述(1-1)所表示之取代基中，上述苯基、烷基、烷氧基及烯基之取代基與作為表示上述通式(I-A)中之X1 所表示之m價有機基之基的取代基所例示者相同。 上述(1-3)所表示之基中，作為R73 及R74 所表示之亦存在具有取代基之情形之碳原子數1～10之烷基，可列舉作為R61 所表示之碳原子數1～40之烷基所例示之基中滿足既定之碳原子數之基等。 上述(1-3)所表示之基中，作為R73 及R74 所表示之亦存在具有取代基之情形之碳原子數6～20之芳基，可列舉作為R61 及R62 所表示之碳原子數6～20之芳基所例示之基等。 上述(1-3)所表示之基中，作為R73 及R74 所表示之亦存在具有取代基之情形之碳原子數6～20之芳氧基，可列舉：苯氧基、萘氧基、2-甲基苯氧基、3-甲基苯氧基、4-甲基苯氧基、4-乙烯基苯氧基、3-異丙基苯氧基、4-異丙基苯氧基、4-丁基苯氧基、4-第三丁基苯氧基、4-己基苯氧基、4-環己基苯氧基、4-辛基苯氧基、4-(2-乙基己基)苯氧基、2,3-二甲基苯氧基、2,4-二甲基苯氧基、2,5-二甲基苯氧基、2.6-二甲基苯氧基、3.4-二甲基苯氧基、3.5-二甲基苯氧基、2,4-二-第三丁基苯氧基、2,5-二-第三丁基苯氧基、2,6-二-第三丁基苯氧基、2.4-二-第三戊基苯氧基、2,5-第三戊基苯氧基、4-環己基苯氧基、2,4,5-三甲基苯氧基、二茂鐵基氧基等基。 上述(1-3)所表示之基中，作為R73 及R74 所表示之亦存在具有取代基之情形之碳原子數6～20之芳硫基，可列舉將上述亦存在具有取代基之情形之碳原子數6～20之芳氧基之氧原子取代為硫原子而成之基等。 上述(1-3)所表示之基中，作為R73 及R74 所表示之亦存在具有取代基之情形之碳原子數6～20之芳烯基，可列舉上述亦存在具有取代基之情形之碳原子數6～20之芳氧基之氧原子經乙烯基、烯丙基、1-丙烯基、異丙烯基、2-丁烯基、1,3-丁二烯基、2-戊烯基、2-辛烯基等烯基取代而成之基等。 上述(1-3)所表示之基中，作為R73 及R74 所表示之碳原子數7～20之芳烷基，可列舉作為R61 及R62 所表示之碳原子數7～20之芳烷基所例示之基等。 上述(1-3)所表示之基中，作為R73 及R74 所表示之亦存在具有取代基之情形之碳原子數2～20之含雜環基，可列舉作為R61 及R62 所表示之碳原子數2～20之含雜環基所例示之基等。 作為上述通式(2)中之Y11 所表示之3價之碳原子數1～35之脂肪族烴基，可列舉：作為上述通式(I-A)中之X1 所表示之m價有機基所例示之1價～3價之脂肪族烴基、及該等基經作為表示上述通式(I-A)中之X1 所表示之m價有機基之基的取代基所例示者取代而成之基中，滿足既定之碳原子數者等經Z1 、Z2 及Z3 取代而成之3價之基等。 作為上述通式(2)中之Y11 所表示之3價之碳原子數3～35之脂環族烴基，可列舉：環戊基、環己基、環庚基、環辛基、環癸基、1-金剛烷基、2-金剛烷基、正金剛烷基、2-甲基金剛烷基、降&#158665;基、異降&#158665;基、全氫萘基、全氫蒽基、雙環[1.1.0]丁基、雙環[1.1.1]戊基、雙環[2.1.0]戊基、雙環[3.1.0]己基、雙環[2.1.1]己基、雙環[2.2.0]己基、雙環[4.1.0]庚基、雙環[3.2.0]庚基、雙環[3.1.1]庚基、雙環[2.2.1]庚基、雙環[5.1.0]辛基、雙環[4.2.0]辛基、雙環[4.1.1]辛基、雙環[3.3.0]辛基、雙環[3.2.1]辛基、雙環[2.2.2]辛基、螺(4,4)壬基、螺(4,5)癸基、十氫萘、三環癸基、四環十二烷基、雪松醇、環十二烷基等基經Z1 、Z2 及Z3 取代而成之3價之基等。 作為上述通式(2)中之Y11 所表示之3價之碳原子數6～35之含芳香環烴基，可列舉：作為上述通式(I-A)中之X1 所表示之m價有機基所例示之1價～3價之含芳香環烴基、及該等基經作為表示上述通式(I-A)中之X1 所表示之m價有機基之基的取代基所例示者取代而成之基等經Z1 、Z2 及Z3 取代而成之3價之基等。 作為上述通式(2)中之Y11 所表示之3價之碳原子數2～35之含雜環基，可列舉：作為上述通式(I-A)中之X1 所表示之m價有機基所例示之1價～3價之含雜環基、及該等基經作為表示上述通式(I-A)中之X1 所表示之m價有機基之基的取代基所例示者取代而成之基等經Z1 、Z2 及Z3 取代而成之3價之基等。 又，作為上述通式(2)中之R68 所表示之亦存在具有取代基之情形之碳原子數1～35之脂肪族烴基、亦存在具有取代基之情形之碳原子數6～35之芳香族烴基及亦存在具有取代基之情形之碳原子數2～35之含雜環基，分別可列舉上述通式(1)中之R65 及R66 之說明中所例示之脂肪族烴基、含芳香環烴基、含雜環基。 作為上述通式(3)中之Y12 所表示之4價之碳原子數1～35之脂肪族烴基，可列舉：作為上述通式(I-A)中之X1 所表示之m價有機基所例示之1價～3價之脂肪族烴基、及該等基經作為表示上述通式(I-A)中之X1 所表示之m價有機基之基的取代基所例示者取代而成之基中，滿足既定之碳原子數者等經Z1 、Z2 、Z3 及Z4 取代而成之4價之基等。 作為上述通式(3)中之Y12 所表示之碳原子數6～35之含芳香環烴基，可列舉：作為上述通式(I-A)中之X1 所表示之m價有機基所例示之1價～3價之含芳香環烴基、及該等基經作為表示上述通式(I-A)中之X1 所表示之m價有機基之基的取代基所例示者取代而成之基等經Z1 、Z2 、Z3 及Z4 取代而成之4價之基等。 作為上述通式(3)中之Y12 所表示之4價之碳原子數2～35之含雜環基，可列舉：作為上述通式(I-A)中之X1 所表示之m價有機基所例示之1價～3價之含雜環基、及該等基經作為表示上述通式(I-A)中之X1 所表示之m價有機基之基的取代基所例示者取代而成之基等經Z1 、Z2 、Z3 及Z4 取代而成之4價之基等。 作為上述通式(4)中之Y13 所表示之5價之碳原子數2～35之脂肪族烴基，可列舉：作為上述通式(I-A)中之X1 所表示之m價有機基所例示之1價～3價之脂肪族烴基、及該等基經作為表示上述通式(I-A)中之X1 所表示之m價有機基之基的取代基所例示者取代而成之基中，滿足既定之碳原子數者等經Z1 、Z2 、Z3 、Z4 及Z5 取代而成之5價之基等。 作為上述通式(4)中之Y14 所表示之5價之碳原子數6～35之含芳香環烴基，可列舉：作為上述通式(I-A)中之X1 所表示之m價有機基所例示之1價～3價之含芳香環烴基、及該等基經作為表示上述通式(I-A)中之X1 所表示之n價有機基之基的取代基所例示者取代而成之基等經Z1 、Z2 、Z3 、Z4 及Z5 取代而成之5價之基等。 作為上述通式(4)中之Y14 所表示之5價之碳原子數2～35之含雜環基，可列舉：作為上述通式(I-A)中之X1 所表示之m價中之X所表示之n價有機基所例示之1價～3價之含雜環基、及該等基經作為表示上述通式(I-A)中之X1 所表示之m價有機基之基的取代基所例示者取代而成之基等經Z1 、Z2 、Z3 、Z4 及Z5 取代而成之5價之基等。 作為上述通式(5)中之Y14 所表示之6價之碳原子數2～35之脂肪族烴基，可列舉：作為上述通式(I-A)中之X1 所表示之m價有機基所例示之1價～3價之脂肪族烴基、及該等基經作為表示上述通式(I-A)中之X1 所表示之m價有機基之基的取代基所例示者取代之基中，滿足既定之碳原子數者等經Z1 、Z2 、Z3 、Z4 、Z5 及Z6 取代而成之6價之基等。 作為上述通式(5)中之Y14 所表示之6價之碳原子數6～35之含芳香環烴基，可列舉：作為上述通式(I-A)中之X1 所表示之m價有機基所例示之1價～3價之含芳香環烴基、及該等基經作為表示上述通式(I-A)中之X1 所表示之m價有機基之基的取代基所例示者取代而成之基等經Z1 、Z2 、Z3 、Z4 、Z5 及Z6 取代而成之6價之基等。 作為上述通式(5)中之Y14 所表示之6價之碳原子數2～35之含雜環基，可列舉：作為上述通式(I-A)中之X1 所表示之m價有機基所例示之1價～3價之含雜環基經作為取代基所例示者取代而成之基等經Z1 、Z2 、Z3 、Z4 、Z5 及Z6 取代而成之6價之基等。 上述通式(I-A)中，d與k之合計小於環A1 可取之取代基之個數。例如，環A1 為六員環之芳香環時，環A1 可取之取代基為6，d＋k≦5。又，環A1 為五員環之雜環時，環A1 可取之取代基為4，d＋k≦3。 作為上述通式(I-A)所表示之化合物，具體而言例如可列舉下述結構者。 [化12]上述通式(I-A)所表示之化合物中，下述通式(II)～(IV)所表示者係容易合成且耐熱性較高，故而較佳。 [化13](式中，環A2 為六員環之脂環、芳香環或雜環，R81 、R82 、R83 、R84 及R85 表示氫原子、鹵素原子、氰基、羥基、硝基、羧基、亦存在具有取代基之情形之碳原子數1～40之烷基、碳原子數6～20之芳基、碳原子數7～20之芳烷基、碳原子數2～20之含雜環基或-O-R62 ，R81 、R82 、R83 、R84 及R85 中之至少1個並非氫原子，R62 與上述通式(I)相同) [化14](式中，X2 為上述通式(1)所表示之基，R86 、R87 、R88 及R89 表示氫原子、鹵素原子、氰基、羥基、硝基、羧基、亦存在具有取代基之情形之碳原子數1～40之烷基、碳原子數6～20之芳基、碳原子數7～20之芳烷基或碳原子數2～20之含雜環基，R86 、R87 、R88 及R89 中之至少1個並非氫原子，R62 與上述通式(I)相同，環A2 與上述通式(II)相同) [化15](式中，r＝2～6，X3 於r＝2時為上述通式(1)所表示之基，於r＝3時為上述通式(2)所表示之基，於r＝4時為上述通式(3)所表示之基，於r＝5時為上述通式(4)所表示之基，於r＝6時為上述通式(5)所表示之基，R91 、R92 、R93 及R94 表示氫原子、鹵素原子、氰基、羥基、硝基、羧基、亦存在具有取代基之情形之碳原子數1～40之烷基、碳原子數6～20之芳基、碳原子數7～20之芳烷基或碳原子數2～20之含雜環基，R91 、R92 、R93 及R94 中之至少1個並非氫原子，R62 與上述通式(I)相同，環A2 與上述通式(II)相同。) 作為上述通式(II)中之環A2 所表示之六員環之脂環、芳香環或雜環，可列舉上述通式(I)中之A1 之說明中所例示者。 作為上述通式(II)中之R81 、R82 、R83 、R84 及R85 所表示之鹵素原子、亦存在具有取代基之情形之碳原子數1～40之烷基、碳原子數6～20之芳基、碳原子數7～20之芳烷基、碳原子數2～20之含雜環基，可列舉上述通式(I)中之R61 或R62 之說明中所例示者。 作為上述通式(III)中之R86 、R87 、R88 及R89 所表示之鹵素原子、亦存在具有取代基之情形之碳原子數1～40之烷基、碳原子數6～20之芳基、碳原子數7～20之芳烷基、碳原子數2～20之含雜環基，可列舉上述通式(I)中之R61 或R62 之說明中所例示者。 作為上述通式(IV)中之R91 、R92 、R93 及R94 所表示之鹵素原子、亦存在具有取代基之情形之碳原子數1～40之烷基、碳原子數6～20之芳基、碳原子數7～20之芳烷基、碳原子數2～20之含雜環基，可列舉上述通式(I)中之R61 或R62 之說明中所例示者。 於上述通式(II)所表示之化合物中， 較佳為環A2 為苯、萘者， 作為R81 、R82 、R83 、R84 及R85 中之除氫原子以外之基，較佳為碳原子數1～20之烷基、碳原子數6～10之芳基、碳原子數7～12之芳烷基、碳原子數2～10之含雜環基，尤佳為R81 ～R85 之任一個為碳原子數1～4之烷基或碳原子數2～10之含雜環基， R62 較佳為介隔-CO-O-而具有下述取代基。 ・碳原子數1～8之烷基(尤其是甲基、乙基、丙基、異丙基、丁基、第二丁基、第三丁基、異丁基、戊基、1-甲基丁基、2-甲基丁基、3-甲基丁基、1-乙基丙基、1,1-二甲基丙基、1,2-二甲基丙基、2,2-二甲基丙基) ・碳原子數7～10之芳烷基(尤其是苄基) ・碳原子數2～6之烯基(尤其是丙烯-1-基) 於上述通式(III)所表示之化合物中， 較佳為環A2 為苯、萘者， 作為R86 、R87 、R88 及R89 中之除氫原子以外之基，較佳為碳原子數1～20之烷基、碳原子數6～10之芳基、碳原子數7～12之芳烷基、碳原子數2～10之含雜環基，尤佳為碳原子數1～8之烷基、碳原子數2～10之含雜環基， R62 較佳為介隔-CO-O-而具有下述取代基。 ・碳原子數1～8之烷基(尤其是甲基、乙基、丙基、異丙基、丁基、第二丁基、第三丁基、異丁基、戊基、1-甲基丁基、2-甲基丁基、3-甲基丁基、1-乙基丙基、1,1-二甲基丙基、1,2-二甲基丙基、2,2-二甲基丙基) ・碳原子數7～10之芳烷基(尤其是苄基) ・碳原子數2～6之烯基(尤其是丙烯-1-基) 於表示X11 之上述通式(1)中，Y10 較佳為硫原子、碳原子數6～25之含芳香環烴基、碳原子數2～21之含雜環基， Z1 及Z2 較佳為直接鍵結、-CO-O-、-O-CO-、或亦存在具有取代基之情形之碳原子數1～20之脂肪族烴基、6～10之芳香族烴基，尤佳為亦存在具有取代基之情形之碳原子數1～8之脂肪族烴基。 上述通式(IV)所表示之化合物中， 作為R91 、R92 、R93 及R94 中之除氫原子以外之基，較佳為碳原子數6～10之芳基、碳原子數7～12之芳烷基、碳原子數2～10之含雜環基，尤佳為R91 ～R94 之任一個為碳原子數1～4之烷基或碳原子數2～10之含雜環基。 R62 較佳為介隔-CO-O-而具有下述取代基。 ・碳原子數1～8之烷基(尤其是甲基、乙基、丙基、異丙基、丁基、第二丁基、第三丁基、異丁基、戊基、1-甲基丁基、2-甲基丁基、3-甲基丁基、1-乙基丙基、1,1-二甲基丙基、1,2-二甲基丙基、2,2-二甲基丙基)・碳原子數7～10之芳烷基(尤其是苄基)・碳原子數2～6之烯基(尤其是丙烯-1-基) 於上述通式(IV)所表示之化合物中r＝2且X3 成為上述通式(1)之情形時，Y10 較佳為硫原子、2價之碳原子數1～20之烷基、2價之碳原子數6～25之含芳香環烴基、2價之碳原子數2～21之含雜環基、2,4,8,10-四氧雜螺[5,5]十一烷，尤佳為2價之碳原子數1～15之烷基、2價之碳原子數6～15之含芳香環烴基、2,4,8,10-四氧雜螺[5,5]十一烷， Z1 及Z2 較佳為直接鍵結、-CO-O-、-O-CO-或亦存在具有取代基之情形之2價之碳原子數1～20之脂肪族烴基、2價之碳原子數6～10之芳香族烴基，尤佳為亦存在具有取代基之情形之2價之碳原子數1～8之脂肪族烴基。 於上述通式(IV)所表示之化合物中r＝3且X3 成為上述通式(2)之情形時，Y11 較佳為3價之碳原子數1～20之烷基、3價之碳原子數6～10之芳基、3價之碳原子數7～12之芳烷基、3價之碳原子數2～10之含雜環基，尤佳為3價之碳原子數1～8之烷基、3價之碳原子數6～9之芳基、3價之碳原子數1～6之含雜環基， Z1 、Z2 及Z3 較佳為直接鍵結、-CO-O-、-O-CO-或亦存在具有取代基之情形之2價之碳原子數1～20之脂肪族烴基、2價之碳原子數6～10之芳香族烴基，尤佳為亦存在具有取代基之情形之2價之碳原子數1～8之脂肪族烴基。 於上述通式(IV)所表示之化合物中r＝4且X3 成為上述通式(3)之情形時，Y12 較佳為4價之碳原子數1～20之烷基、4價之碳原子數6～10之芳基、4價之碳原子數7～12之芳烷基、4價之碳原子數2～10之含雜環基，尤佳為4價之碳原子數1～8之烷基、4價之碳原子數6～9之芳基、4價之碳原子數1～6之含雜環基， Z1 ～Z4 較佳為直接鍵結、-CO-O-、-O-CO-或亦存在具有取代基之情形之2價之碳原子數1～20之脂肪族烴基、2價之碳原子數6～10之芳香族烴基，尤佳為亦存在具有取代基之情形之2價之碳原子數1～8之脂肪族烴基。 於上述通式(IV)所表示之化合物中r＝5且X3 成為上述通式(4)之情形時，Y13 較佳為5價之碳原子數1～20之烷基、5價之碳原子數6～10之芳基、5價之碳原子數7～12之芳烷基、5價之碳原子數2～10之含雜環基，尤佳為5價之碳原子數1～8之烷基、5價之碳原子數6～9之芳基、5價之碳原子數1～6之含雜環基， Z1 ～Z5 較佳為直接鍵結、-CO-O-、-O-CO-或亦存在具有取代基之情形之2價之碳原子數1～20之脂肪族烴基、2價之碳原子數6～10之芳香族烴基，尤佳為亦存在具有取代基之情形之2價之碳原子數1～8之脂肪族烴基。 於上述通式(IV)所表示之化合物中r＝6且X3 成為上述通式(5)之情形時，Y14 較佳為6價之碳原子數1～20之烷基、6價之碳原子數6～10之芳基、6價之碳原子數7～12之芳烷基、6價之碳原子數2～10之含雜環基，尤佳為6價之碳原子數1～8之烷基、6價之碳原子數6～9之芳基、6價之碳原子數1～6之含雜環基， Z1 ～Z6 較佳為直接鍵結、-CO-O-、-O-CO-或亦存在具有取代基之情形之2價之碳原子數1～20之脂肪族烴基、2價之碳原子數6～10之芳香族烴基，尤佳為亦存在具有取代基之情形之2價之碳原子數1～8之脂肪族烴基。 作為上述碳原子數2～10之含雜環基，可列舉上述碳原子數2～35之含雜環基及所例示之化合物中碳原子數為1～10之含雜環基。 於本發明之感光性組合物中，上述潛伏性添加劑(A)之含量較佳為0.001～20質量%，更佳為0.005～5質量%。 ＜聚合物(B)＞ 用於本發明之感光性組合物之聚合物(B)只要為於一分子內具有乙烯性不飽和鍵及親水性基且雙鍵當量為200～1000之聚合物，則並無特別限定，可使用先前所使用者。 作為聚合物(B)所具有之親水性基，可列舉：羥基、硫醇基、羧基、磺基、胺基、醯胺基或其鹽等，羥基及羧基因聚合物(B)對鹼之溶解性變高故而較佳。 聚合物(B)中之親水性基之較佳官能基當量(包含1當量親水性基之聚合物之質量)為50～10000。 聚合物(B)之較佳之質量平均分子量為3000～50000。 作為上述聚合物(B)，可列舉：(甲基)丙烯酸、α-氯丙烯酸、伊康酸、馬來酸、檸康酸、富馬酸、雙環庚烯二甲酸、丁烯酸、異丁烯酸、乙烯基乙酸、烯丙基乙酸、桂皮酸、山梨酸、中康酸、琥珀酸單[2-(甲基)丙烯醯氧基乙基]酯、鄰苯二甲酸單[2-(甲基)丙烯醯氧基乙基]酯，ω-羧基聚己內酯單(甲基)丙烯酸酯等在兩末端具有羧基及羥基之聚合物之單(甲基)丙烯酸酯，(甲基)丙烯酸羥基乙酯-馬來酸酯、(甲基)丙烯酸羥基丙酯-馬來酸酯、二環戊二烯-馬來酸酯或具有1個羧基及2個以上之(甲基)丙烯醯基之多官能(甲基)丙烯酸酯等不飽和多元酸；苯酚及/或甲酚酚醛清漆環氧樹脂，具有聯苯骨架、萘骨架之酚醛清漆環氧樹脂，雙酚A酚醛清漆型環氧化合物，環戊二烯酚醛清漆型環氧化合物等酚醛清漆型環氧化合物；具有多官能環氧基之聚苯基甲烷型環氧樹脂、使不飽和一元酸作用於下述通式(V)所表示之環氧化合物等環氧樹脂之環氧基而成之樹脂、使不飽和一元酸作用於下述通式(V)所表示之環氧化合物等環氧樹脂之環氧基且進而使多元酸酐作用所獲得之樹脂；作為季戊四醇三丙烯酸酯、二季戊四醇五丙烯酸酯等含羥基之多官能丙烯酸酯與琥珀酸酐、鄰苯二甲酸酐、四氫鄰苯二甲酸酐等二元酸酐之反應物的具有酸值之多官能丙烯酸酯等。 [化16](式中，X41 表示直接鍵結、亦存在具有取代基之情形之碳原子數1～4之伸烷基、亦存在具有取代基之情形之碳原子數3～20之脂環式烴基、-O-、-S-、-SO2- 、-SS-、-SO-、-CO-、-OCO-或上述(1-1)～(1-3)所表示之取代基， R41 、R42 、R43 及R44 分別獨立地表示氫原子、亦存在具有取代基之情形之碳原子數1～5之烷基、亦存在具有取代基之情形之碳原子數1～8之烷氧基、亦存在具有取代基之情形之碳原子數2～5之烯基或鹵素原子， n為0～10之整數) 上述聚合物(B)之中，具有選自下述通式(VI-1)所表示之單元、下述通式(VI-2)所表示之單元、下述通式(VI-3)所表示之單元及下述通式(VI-4)所表示之單元中之任一個以上的聚合物因顯影性或耐熱性較高，故而較佳。 [化17](式中，Y1 表示氫原子或甲基，X4 為2價之鍵結基，R1 表示碳原子數1～20之烷基、碳原子數6～30之芳基或碳原子數7～30之芳烷基，該烷基、芳基及芳烷基之氫原子存在經鹵素原子、羥基、硝基或環氧基取代之情形，該烷基及芳烷基中之亞甲基亦存在經-O-、-S-、-CO-、-COO-、-OCO-或-NH-、或該等之組合之鍵結基取代之情形，R2 、R3 及R4 分別獨立地為氫原子或甲基) 作為上述通式(VI-2)中之X4 所表示之2價之鍵結基，並無特別限定，可較佳地列舉上述通式(1)所表示之結構。 上述通式(VI-1)～(VI-4)所表示之單元之構成比為(VI-1)：(VI-2)：(VI-3)：(VI-4)＝0～0.65：0.1～1：0.001～2：0～1，可採用無規共聚、嵌段共聚、接枝共聚等任一排列。 於具有選自上述通式(VI-1)、(VI-2)、(VI-3)及(VI-4)所表示之單元中之任一個以上的聚合物(B)中，較佳為以下者。 R1 較佳為碳原子數1～8之烷基及碳原子數7～30之芳烷基，更佳為碳原子數1～4之烷基。 關於X4 ，於2價之鍵結基為下述通式(1)所表示之結構之情形時，Y10 較佳為碳原子數1～15之伸烷基，更佳為具有伸環烷基之碳原子數7～15之伸烷基或具有含有羧基之取代基者。該等伸烷基中之氫原子亦存在經鹵素原子、羥基或硝基原子取代之情形，又，伸烷基中之鏈狀伸烷基部分之亞甲基亦存在經-O-、-S-、-CO-、-COO-、-OCO-或-NH-基取代之情形。 Z1 及Z2 較佳為直接鍵結。 上述聚合物(B)之酸值較佳為10～200 mg/KOH，進而較佳為30～150 mg/KOH。若酸值未達10 mg/KOH，則存在無法充分獲得鹼顯影性之情形，若大於200 mg/KOH，則有難以製造聚合物(B)之虞。 此次，所謂酸值係指依據JIS K 0050及JIS K 0211所得者。 上述聚合物(B)之雙鍵當量必須為200～1000，較佳為300～500。若上述聚合物(B)中之雙鍵當量小於200，則難以進行製造，若大於1000，則無法充分獲得耐久性。 雙鍵當量係聚合物(B)中之每一個雙鍵之重量平均分子量，可藉由下述式算出。雙鍵當量＝(聚合物(B)之總質量)/{(聚合物(B)之莫耳數)×(聚合物(B)中之乙烯性不飽和基之個數)} 於本發明之感光性組合物中，上述聚合物(B)之含量於本發明之感光性組合物中較佳為1～20質量%，尤佳為5～15質量%。若上述聚合物(B)之含量小於1質量%，則存在無法充分獲得解像度及耐久性之情形，若大於20質量%，則存在無法充分獲得鹼顯影性及硬化性之情形。 ＜丙烯酸系單體(C)＞ 作為用於本發明之感光性組合物之丙烯酸系單體(C)，並無特別限制，可使用公知者，例如可列舉：丙烯酸-2-羥基乙酯、丙烯酸-2-羥基丙酯、丙烯酸異丁酯、丙烯酸正辛酯、丙烯酸異辛酯、丙烯酸異壬酯、丙烯酸硬脂酯、丙烯酸甲氧基乙酯、丙烯酸二甲基胺基乙酯、丙烯酸鋅、1,6-己二醇二丙烯酸酯、三羥甲基丙烷三丙烯酸酯、甲基丙烯酸-2-羥基乙酯、甲基丙烯酸-2-羥基丙酯、甲基丙烯酸丁酯、甲基丙烯酸第三丁酯、甲基丙烯酸環己酯、三羥甲基丙烷三甲基丙烯酸酯、二季戊四醇五丙烯酸酯、二季戊四醇六丙烯酸酯、季戊四醇四丙烯酸酯、季戊四醇三丙烯酸酯、雙酚A二縮水甘油醚(甲基)丙烯酸酯、雙酚F二縮水甘油醚(甲基)丙烯酸酯、雙酚Z二縮水甘油醚(甲基)丙烯酸酯、三丙二醇二(甲基)丙烯酸酯等。 上述之中，具有複數個不飽和鍵之單體可提高耐熱性，因此較佳。 於本發明之感光性組合物中，上述丙烯酸系單體(C)之含量於本發明之感光性組合物中較佳為1～20質量%，尤佳為5～15質量%。若上述丙烯酸系單體(C)之含量小於1質量%，則存在無法充分獲得硬化性及鹼顯影性之情形，若大於20質量%，則存在無法充分獲得解像度及耐久性之情形。 ＜光自由基聚合起始劑(D)＞ 用於本發明之感光性組合物之光自由基聚合起始劑(D)只要為可藉由受到光照射而使自由基開始聚合之化合物即可，例如可例示苯乙酮系化合物、苯偶醯系化合物、二苯甲酮系化合物、9-氧硫&#134079;□系化合物等酮系化合物、肟系化合物等作為較佳者。 作為苯乙酮系化合物，例如可列舉：二乙氧基苯乙酮、2-羥基-2-甲基-1-苯基丙烷-1-酮、4'-異丙基-2-羥基-2-甲基苯丙酮、2-羥基甲基-2-甲基苯丙酮、2,2-二甲氧基-1,2-二苯基乙烷-1-酮、對二甲基胺基苯乙酮、對第三丁基二氯苯乙酮、對第三丁基三氯苯乙酮、對疊氮苯亞甲基苯乙酮、1-羥基環己基苯基酮、2-甲基-1-[4-(甲硫基)苯基]-2-&#134156;啉基丙酮-1、2-苄基-2-二甲基胺基-1-(4-&#134156;啉基苯基)-丁酮-1、安息香、安息香甲醚、安息香乙醚、安息香異丙醚、安息香正丁醚、安息香異丁醚、1-[4-(2-羥基乙氧基)-苯基]-2-羥基-2-甲基-1-丙烷-1-酮等。 作為苯偶醯系化合物，可列舉苯偶醯、茴香偶醯等。 作為二苯甲酮系化合物，例如可列舉：二苯甲酮、鄰苯甲醯基苯甲酸甲酯、米其勒酮、4,4'-雙二乙基胺基二苯甲酮、4,4'-二氯二苯甲酮、4-苯甲醯基-4'-甲基二苯硫醚等。 作為9-氧硫&#134079;□系化合物，可列舉：9-氧硫&#134079;□、2-甲基-9-氧硫&#134079;□、2-乙基-9-氧硫&#134079;□、2-氯-9-氧硫&#134079;□、2-異丙基-9-氧硫&#134079;□、2,4-二乙基-9-氧硫&#134079;□等。 作為肟系化合物，就感度及耐熱性之方面而言，尤佳為下述通式(VII)或(VIII)所表示之化合物。 [化18](式中，R51 及R52 分別獨立地表示氫原子、氰基、亦存在具有取代基之情形之碳原子數1～20之烷基、亦存在具有取代基之情形之碳原子數6～30之芳基、亦存在具有取代基之情形之碳原子數7～30之芳烷基或亦存在具有取代基之情形之碳原子數2～20之含雜環基， R53 及R54 分別獨立地表示鹵素原子、硝基、氰基、羥基、羧基、R55 、OR56 、SR57 、NR58 R59 、COR60 、SOR61 、SO2 R62 或CONR63 R64 ，R53 及R54 存在相互鍵結而形成環之情形， R55 、R56 、R57 、R58 、R59 、R60 、R61 、R62 、R63 及R64 分別獨立地表示亦存在具有取代基之情形之碳原子數1～20之烷基、亦存在具有取代基之情形之碳原子數6～30之芳基、亦存在具有取代基之情形之碳原子數7～30之芳烷基或亦存在具有取代基之情形之碳原子數2～20之含雜環基， X5 表示氧原子、硫原子、硒原子、CR75 R76 、CO、NR77 或PR78 ， X6 表示單鍵或CO， 表示R51 、R52 、R55 、R56 、R57 、R58 、R59 、R60 、R65 、R66 、R67 及R68 中之碳原子數1～20之烷基、碳原子數6～30之芳基或碳原子數7～30之芳烷基，該烷基或芳烷基中之亞甲基存在經鹵素原子、硝基、氰基、羥基、羧基或含雜環基取代之情形，且存在經-O-取代之情形， R53 及R54 存在分別獨立地與鄰接之任一苯環一起形成環之情形， a表示0～4之整數， b表示0～5之整數) [化19](式中，R101 及R102 分別獨立地表示R111 、OR111 、COR111 、SR111 、CONR112 R113 或CN， R111 、R112 及R113 分別獨立地表示氫原子、碳原子數1～20之烷基、碳原子數6～30之芳基、碳原子數7～30之芳烷基或碳原子數2～20之含雜環基， R111 、R112 及R113 所表示之基之氫原子亦存在進一步經R121 、OR121 、COR121 、SR121 、NR122 R123 、CONR122 R123 、-NR122 -OR123 、-NCOR122 -OCOR123 、NR122 COR121 、OCOR121 、COOR121 、SCOR121 、OCSR121 、COSR121 、CSOR121 、羥基、硝基、CN、鹵素原子、或COOR121 取代之情形， R121 、R122 及R123 分別獨立地表示氫原子、碳原子數1～20之烷基、碳原子數6～30之芳基、碳原子數7～30之芳烷基或碳原子數2～20之含雜環基， R121 、R122 及R123 所表示之基之氫原子亦存在進一步經羥基、硝基、CN、鹵素原子、羥基或羧基取代之情形， R111 、R112 、R113 、R121 、R122 及R123 所表示之基之伸烷基部分亦存在經-O-、-S-、-COO-、-OCO-、-NR124- 、-NR124 COO-、-OCONR124- 、-SCO-、-COS-、-OCS-或-CSO-於氧原子不相鄰之條件下取代1～5次之情形， R124 表示氫原子、碳原子數1～20之烷基、碳原子數6～30之芳基、碳原子數7～30之芳烷基或碳原子數2～20之含雜環基， R111 、R112 、R113 、R121 、R122 、R123 及R124 所表示之基之烷基部存在為分支側鏈之情形，亦存在為環狀烷基之情形， R103 表示氫原子、碳原子數1～20之烷基、碳原子數6～30之芳基、碳原子數7～30之芳烷基或碳原子數2～20之含雜環基，R103 所表示之基之烷基部分存在為分支側鏈之情形，亦存在為環狀烷基之情形，又，R103 與R107 、R103 與R108 、R104 與R105 、R105 與R106 及R106 與R107 亦存在分別一起而形成環之情形， R103 所表示之基之氫原子亦存在進一步經R121 、OR121 、COR121 、SR121 、NR122 R123 、CONR122 R123 、-NR122 -OR123 、-NCOR122 -OCOR123 、NR122 COR121 、OCOR121 、COOR121 、SCOR121 、OCSR121 、COSR121 、CSOR121 、羥基、硝基、CN、鹵素原子、或COOR121 取代之情形， R104 、R105 、R106 及R107 分別獨立地表示R111 、OR111 、SR111 、COR114 、CONR151 R116 、NR112 COR111 、OCOR111 、COOR114 、SCOR111 、OCSR111 、COSR114 、CSOR111 、羥基、CN或鹵素原子，R104 與R105 、R105 與R106 及R106 與R107 亦存在分別一起而形成環之情形， R114 、R115 及R116 表示氫原子或碳原子數1～20之烷基，R108 表示R111 、OR111 、SR111 、COR111 、CONR112 R113 、NR112 COR111 、OCOR111 、COOR111 、SCOR111 、OCSR111 、COSR111 、CSOR111 、羥基、CN或鹵素原子， w表示0或1) 作為其他光自由基聚合起始劑(D)，可列舉2,4,6-三甲基苯甲醯基二苯基氧化膦、雙(環戊二烯基)-雙[2,6-二氟-3-(吡咯-1-基)]鈦等。 該等光自由基聚合起始劑(D)可根據所需之性能將1種或2種以上調配而使用。 如上所述之光自由基聚合起始劑(D)於本發明之感光性組合物中較佳為0.01～10質量%，尤佳為0.1～1質量%。若上述光自由基聚合起始劑之含量小於0.01質量%，則存在由曝光所致之硬化變得不充分之情形，若大於10質量%，則存在光自由基聚合起始劑於感光性組合物中析出之情形。 亦可於上述感光性組合物中進而添加著色劑而製成著色感光性組合物。該著色感光性組合物之硬化物適宜用作彩色濾光片。 於上述著色感光性組合物中，著色劑之添加量較佳為0.01～50質量%，更佳為0.1～30質量%。若上述著色劑之添加量小於0.01質量%，則色調不充分，若大於50質量%，則存在著色劑於感光性組合物中析出之情形。 作為上述著色劑，可列舉染料或顏料。 作為染料，只要為於380～1200 nm存在吸收之化合物，則並無特別限定，例如可列舉：偶氮化合物、蒽醌化合物、靛藍類化合物、三芳基甲烷化合物、&#134079;□化合物、茜素化合物、吖啶化合物、茋化合物、噻唑化合物、萘酚化合物、喹啉化合物、硝基化合物、吲達胺化合物、㗁&#134116;化合物、酞菁化合物、花青化合物、二亞銨化合物、氰基乙烯基化合物、二氰基苯乙烯化合物、玫瑰紅化合物、苝化合物、多烯萘內醯胺化合物、香豆素化合物、方酸鎓化合物、克酮鎓化合物、螺吡喃化合物、螺㗁&#134116;化合物、部花青化合物、氧喏化合物、苯乙烯基化合物、吡喃鎓化合物、繞丹寧化合物、㗁唑啉酮化合物、鄰苯二甲醯亞胺化合物、㖕啉化合物、萘醌化合物、氮雜蒽醌化合物、卟啉化合物、氮雜卟啉化合物、吡咯亞甲基化合物、喹吖啶酮化合物、吡咯并吡咯二酮化合物、靛藍化合物、吖啶化合物、&#134116;化合物、甲亞胺化合物、苯胺化合物、喹吖啶酮化合物、喹酞酮化合物、醌亞胺化合物、銥錯合物、銪錯合物等染料等，該等亦可將複數種混合而使用。 作為顏料，可使用無機顏料或有機顏料，例如可使用：亞硝基化合物、硝基化合物、偶氮化合物、重氮化合物、&#134079;□化合物、喹啉化合物、蒽醌化合物、香豆素化合物、酞菁化合物、異吲哚啉酮化合物、異吲哚啉化合物、喹吖啶酮化合物、蒽締蒽酮化合物、紫環酮化合物、苝化合物、吡咯并吡咯二酮化合物、硫靛藍化合物、二㗁&#134116;化合物、三苯基甲烷化合物、喹酞酮化合物、萘四羧酸；偶氮染料、花青染料之金屬錯合物；色澱顏料；藉由爐法、導槽法、熱分析法所獲得之碳黑，或乙炔黑、科琴黑或燈黑等碳黑；利用環氧樹脂對上述碳黑進行調整、被覆而成者，預先於溶劑中利用樹脂對上述碳黑進行分散處理而吸附有20～200 mg/g之樹脂者、對上述碳黑進行酸性或鹼性表面處理而成者、平均粒徑為8 nm以上且DBP吸油量為90 ml/100 g以下者、由950℃下之揮發成分中之CO及CO2 算出之總氧量於碳黑之表面積每100 m2 中為9 mg以上者；石墨、石墨化碳黑、活性碳、碳纖維、奈米碳管、螺旋碳纖維、奈米碳角、碳氣凝膠、富勒烯；苯胺黑、顏料黑7、鈦黑；疏水性樹脂、氧化鉻綠、米洛麗藍、鈷綠、鈷藍、錳系、亞鐵氰化物、磷酸鹽群青、鐵藍、群青、天藍、鉻綠、翡翠綠、硫酸鉛、黃丹、鋅黃、鐵丹(紅色氧化鐵(III))、鎘紅、合成鐵黑、棕土等無機含量或有機顏料。該等顏料可單獨使用，或者將複數種混合而使用。 作為上述無機顏料或有機顏料，亦可使用市售之顏料，例如可列舉：顏料紅1、2、3、9、10、14、17、22、23、31、38、41、48、49、88、90、97、112、119、122、123、144、149、166、168、169、170、171、177、179、180、184、185、192、200、202、209、215、216、217、220、223、224、226、227、228、240、254；顏料橙13、31、34、36、38、43、46、48、49、51、52、55、59、60、61、62、64、65、71；顏料黃1、3、12、13、14、16、17、20、24、55、60、73、81、83、86、93、95、97、98、100、109、110、113、114、117、120、125、126、127、129、137、138、139、147、148、150、151、152、153、154、166、168、175、180、185；顏料綠7、10、36；顏料藍15、15:1、15:2、15:3、15:4、15:5、15:6、22、24、56、60、61、62、64；顏料紫1、19、23、27、29、30、32、37、40、50等。 亦可藉由在本發明之感光性組合物中進而添加交聯劑並與上述聚合物之親水性基進行反應而提高耐水性及耐熱性。作為該交聯劑，可列舉：聚㗁唑啉化合物、碳二醯亞胺化合物、環氧化合物、多胺類、多元醇類、雙氰胺衍生物、肼化合物、多醯肼化合物(二醯肼、三醯肼)、醛類、羥甲基化合物、活化乙烯系化合物、異氰酸酯系化合物、酚系化合物之碳酸伸烷酯化合物、多價金屬鹽、矽烷偶合劑、有機鈦等，其中，聚㗁唑啉化合物及碳二醯亞胺化合物係於100～120℃之熱乾燥溫度下進行反應，因此較佳。 作為上述交聯劑，亦可使用市售品，例如可列舉：Epocros WS-300、WS-500、WS-700(日本觸媒公司製造)；Carbodilite V-02、V-02-L2、SV-02、V-04、V-10、SW-12G、E-02、E-03A、E-05(日清紡公司製造)等。 可進而於上述感光性組合物及著色感光性組合物中添加溶劑。作為該溶劑，通常可列舉視需要可將上述各成分溶解或分散之溶劑，例如甲基乙基酮、甲基戊基酮、二乙基酮、丙酮、甲基異丙基酮、甲基異丁基酮、環己酮、2-庚酮等酮類；乙醚、二㗁烷、四氫呋喃、1,2-二甲氧基乙烷、1,2-二乙氧基乙烷、二丙二醇二甲醚等醚系溶劑；乙酸甲酯、乙酸乙酯、乙酸正丙酯、乙酸異丙酯、乙酸正丁酯、乙酸環己酯、乳酸乙酯、琥珀酸二甲酯、TEXANOL等酯系溶劑；乙二醇單甲醚、乙二醇單乙醚等溶纖劑系溶劑；甲醇、乙醇、異丙醇或正丙醇、異丁醇或正丁醇、戊醇、二丙酮醇等醇系溶劑；乙二醇單甲基乙酸酯、乙二醇單乙基乙酸酯、丙二醇-1-單甲醚-2-乙酸酯(PGMEA)、二丙二醇單甲醚乙酸酯、乙酸-3-甲氧基丁酯、丙酸乙氧基乙酯、1-第三丁氧基-2-丙醇、乙酸-3-甲氧基丁酯、環己二醇乙酸酯等醚酯系溶劑；苯、甲苯、二甲苯等BTX系溶劑；己烷、庚烷、辛烷、環己烷等脂肪族烴系溶劑；松節油、D-檸檬烯、蒎烯等萜烯系烴油；礦油精、Swazol＃310(Cosmo Matsuyama Oil股份有限公司)、Solvesso＃100(Exxon Chemical股份有限公司)等烷烴系溶劑；四氯化碳、氯仿、三氯乙烯、二氯甲烷、1,2-二氯乙烷等鹵化脂肪族烴系溶劑；氯苯等鹵化芳香族烴系溶劑；卡必醇系溶劑、苯胺、三乙基胺、吡啶、乙酸、乙腈、二硫化碳、N,N-二甲基甲醯胺、N,N-二甲基乙醯胺、N-甲基吡咯啶酮、N-乙基吡咯啶酮、二甲基亞碸、水等，該等溶劑可使用1種或以2種以上之混合溶劑之形式使用。該等之中，酮類、醚酯系溶劑等、尤其是丙二醇-1-單甲醚-2-乙酸酯、環己酮等因於感光性組合物中阻劑與光自由基聚合起始劑之相溶性良好，故而較佳。 可使上述著色感光性組合物中進而含有無機化合物。作為該無機化合物，例如可列舉：氧化鎳、氧化鐵、氧化銥、氧化鈦、氧化鋅、氧化鎂、氧化鈣、氧化鉀、氧化矽、氧化鋁等金屬氧化物；層狀黏土礦物、米洛麗藍、碳酸鈣、碳酸鎂、鈷系、錳系、玻璃粉末、雲母、滑石、高嶺土、亞鐵氰化物、各種金屬硫酸鹽、硫化物、硒化物、矽酸鋁、矽酸鈣、氫氧化鋁、鉑、金、銀、銅等。 於上述著色感光性組合物中使用顏料及/或無機化合物之情形時，可添加分散劑。作為該分散劑，只要為可使有色材料、無機化合物分散、穩定化者，則可任意使用，可使用市售之分散劑、例如BYK-Chemie公司製造之BYK系列等，適宜使用以下分散劑：包含具有鹼性官能基之聚酯、聚醚、聚胺基甲酸酯之高分子分散劑；具有氮原子作為鹼性官能基，具有氮原子之官能基為胺及/或其四級鹽，且胺值為1～100 mgKOH/g者。 又，可視需要於上述著色感光性組合物中添加如下添加物：對苯甲醚、對苯二酚、鄰苯二酚、第三丁基鄰苯二酚、啡噻&#134116;等熱聚合抑制劑；塑化劑；接著促進劑；填充劑；消泡劑；調平劑；表面調整劑；酚系抗氧化劑、亞磷酸酯系抗氧化劑、硫醚系抗氧化劑等抗氧化劑；紫外線吸收劑；分散助劑；抗凝聚劑；觸媒；效果促進劑；增黏劑等慣用之添加物。 又，亦可藉由與含有具有上述酸值之乙烯性不飽和鍵之聚合物一併使用其他有機聚合物，而改善本發明之著色感光性組合物之硬化物之特性。作為上述有機聚合物，例如可列舉：聚苯乙烯、聚甲基丙烯酸甲酯、甲基丙烯酸甲酯-丙烯酸乙酯共聚物、聚(甲基)丙烯酸、苯乙烯-(甲基)丙烯酸共聚物、(甲基)丙烯酸-甲基丙烯酸甲酯共聚物、乙烯-氯乙烯共聚物、乙烯-乙烯系共聚物、聚氯乙烯樹脂、ABS樹脂、尼龍6、尼龍66、尼龍12、胺基甲酸酯樹脂、聚碳酸酯聚乙烯醇縮丁醛、纖維素酯、聚丙烯醯胺、飽和聚酯、酚樹脂、苯氧樹脂、聚醯胺醯亞胺樹脂、聚醯胺酸樹脂、環氧樹脂等，該等之中，較佳為聚苯乙烯、(甲基)丙烯酸-甲基丙烯酸甲酯共聚物、環氧樹脂。 可進而於上述著色感光性組合物中併用鏈轉移劑、增感劑、界面活性劑、矽烷偶合劑、三聚氰胺等。 作為上述鏈轉移劑、增感劑，一般使用含硫原子之化合物。例如可列舉：硫代乙醇酸、硫代蘋果酸、硫代水楊酸、2-巰基丙酸、3-巰基丙酸、3-巰基丁酸、N-(2-巰基丙醯基)甘胺酸、2-巰基煙鹼酸、3-[N-(2-巰基乙基)胺甲醯基]丙酸、3-[N-(2-巰基乙基)胺基]丙酸、N-(3-巰基丙醯基)丙胺酸、2-巰基乙磺酸、3-巰基丙磺酸、4-巰基丁磺酸、十二烷基(4-甲硫基)苯醚、2-巰基乙醇、3-巰基-1,2-丙二醇、1-巰基-2-丙醇、3-巰基-2-丁醇、巰基苯酚、2-巰基乙基胺、2-巰基咪唑、2-巰基苯并咪唑、2-巰基-3-羥基吡啶、2-巰基苯并噻唑、巰基乙酸、三羥甲基丙烷三(3-巰基丙酸酯)、季戊四醇四(3-巰基丙酸酯)等巰基化合物，將該巰基化合物氧化所獲得之二硫醚化合物，碘乙酸、碘丙酸、2-碘乙醇、2-碘乙磺酸、3-碘丙磺酸等碘化烷基化合物，三羥甲基丙烷三(3-巰基異丁酸酯)、丁二醇雙(3-巰基異丁酸酯)、己二硫醇、癸烷二硫醇、1,4-二甲基巰基苯、丁二醇雙硫代丙酸酯、丁二醇雙硫代乙醇酸酯、乙二醇雙硫代乙醇酸酯、三羥甲基丙烷三硫代乙醇酸酯、丁二醇雙硫代丙酸酯、三羥甲基丙烷三硫代丙酸酯、三羥甲基丙烷三硫代乙醇酸酯、季戊四醇四硫代丙酸酯、季戊四醇四硫代乙醇酸酯、三硫代丙酸三羥基乙基酯、下述化合物No.C1、三巰基丙酸三(2-羥基乙基)異氰尿酸酯等脂肪族多官能硫醇化合物，昭和電工公司製造之Karenz MT BD1、PE1、NR1等。 [化20]作為上述界面活性劑，可使用：全氟烷基磷酸酯、全氟烷基羧酸鹽等氟界面活性劑，高級脂肪酸鹼金屬鹽、烷磺酸鹽、烷基硫酸鹽等陰離子系界面活性劑，高級胺氫鹵酸鹽、四級銨鹽等陽離子系界面活性劑，聚乙二醇烷基醚、聚乙二醇脂肪酸酯、山梨醇酐脂肪酸酯、脂肪酸單甘油酯等非離子界面活性劑，兩性界面活性劑，聚矽氧系界面活性劑等界面活性劑，該等亦可組合而使用。 作為上述矽烷偶合劑，例如可使用信越化學公司製造之矽烷偶合劑，其中適宜使用KBE-9007、KBM-502、KBE-403等具有異氰酸基、甲基丙烯醯基、環氧基之矽烷偶合劑。 作為上述三聚氰胺化合物，可列舉(聚)羥甲基三聚氰胺、(聚)羥甲基甘脲、(聚)羥甲基苯胍胺、(聚)羥甲基脲等氮化合物中之活性羥甲基(CH2 OH基)之全部或一部分(至少2個)經烷基醚化而成之化合物。此處，作為構成烷基醚之烷基，可列舉甲基、乙基或丁基，有彼此相同或不同之情形。又，未經烷基醚化之羥甲基有於一分子內自縮合之情形，且有於二分子間縮合結果形成低聚物成分之情形。具體而言，可使用六甲氧基甲基三聚氰胺、六丁氧基甲基三聚氰胺、四甲氧基甲基甘脲、四丁氧基甲基甘脲等。該等之中，較佳為六甲氧基甲基三聚氰胺、六丁氧基甲基三聚氰胺等經烷基醚化之三聚氰胺。 上述感光性組合物及著色感光性組合物可利用旋轉塗佈機、輥式塗佈機、棒式塗佈機、模嘴塗佈機、簾幕式塗佈機、各種印刷、浸漬等公知之手段而應用於鈉鈣玻璃、石英玻璃、半導體基板、金屬、紙、塑膠等支持基體上。又，亦可暫時實施於膜等支持基體上之後，轉印至其他支持基體上，其應用方法並無限制。 又，作為使上述感光性組合物及著色感光性組合物硬化時所使用之活性能量線之光源，可使用發出波長300～450 nm之光者，例如可使用超高壓水銀、水銀蒸汽弧、碳弧、氙弧等。 進而，藉由對曝光光源使用雷射光而於不使用遮罩之情況下根據電腦等之數位資訊直接形成圖像的雷射直接刻寫法不僅實現了生產性之提昇，亦實現瞭解像性或位置精度等之提昇，故而較有用，作為該雷射光，適宜使用340～430 nm之波長之光，亦可使用氬離子雷射、氦氖雷射、YAG雷射、及半導體雷射等發出可見光至紅外區域之光者。於使用該等雷射之情形時，添加吸收可見光至紅外之相關區域之增感色素。 本發明之感光性組合物及著色感光性組合物亦可經由雙重圖案化製程進行圖案化，上述雙重圖案化製程使用兩種感光性組合物或著色感光性組合物分兩次進行圖案化。 本發明之感光性組合物及著色感光性組合物可藉由照射上述活性能量線而暫時硬化，並進而藉由加熱而硬化。又，亦可藉由照射上述活性能量線而硬化並顯影之後，藉由加熱而形成圖案。 上述感光性組合物及著色感光性組合物(或其硬化物)可用於光硬化性塗料或清漆、光硬化性接著劑、印刷基板、或彩色電視、PC(Personal Computer，個人電腦)監視器、攜帶型資訊終端、數位相機等彩色顯示之液晶顯示面板中之彩色濾光片、CCD(Charge Coupled Device，電荷耦合元件)影像感測器之彩色濾光片、光間隔件、黑色管柱間隔件、電漿顯示面板用之電極材料、觸控面板、觸控感測器、粉末塗層、印刷油墨、印刷版、接著劑、牙科用組合物、光造形用樹脂、凝膠塗層、電子工學用之光阻、電鍍阻劑、蝕刻阻劑、液狀及乾燥膜兩者、焊接阻劑、用以製造各種顯示用途用之彩色濾光片或用以於電漿顯示面板、電性發光顯示裝置、及LCD(Liquid Crystal Display，液晶顯示裝置)之製造步驟中形成結構的阻劑、用以封入電性及電子零件之組合物、阻焊劑、磁性記錄材料、微小機械零件、波導、光開關、鍍敷用遮罩、蝕刻遮罩、彩色試驗系統、玻璃纖維纜線塗層、網版印刷用模板、用以藉由立體光刻製造三維物體之材料、全像術記錄用材料、圖像記錄材料、微細電子電路、脫色材料、用於圖像記錄材料之脫色材料、使用微膠囊之圖像記錄材料用之脫色材料、印刷配線板用光阻材料、UV及可見光雷射直接圖像系統用之光阻材料、用於印刷電路基板之逐次積層中之介電體層形成的光阻材料、3D安裝用光阻材料或保護膜等各種用途，其用途並無特別限制。 本發明之感光性組合物可用於透明導電膜、反射膜、偏光板、保護膜等，可作為透明積層體而使用，該透明積層體係藉由如下方式積層：於透明基板上依序塗佈上述各層，介隔具有既定之圖案形狀之遮罩照射活性光，利用顯影液對曝光後之覆膜進行顯影，並對顯影後之覆膜進行加熱。例如可列舉於透明基材上使包含氧化銦與氧化鈰之複合氧化物之透明薄膜層與金屬薄膜層交替而成者等。可於上述各層中分別使用含有本發明之化合物作為潛伏性添加劑之感光性組合物，亦可於任一個以上之層中使用該感光性組合物。又，進而，該透明積層體適宜用於顯示裝置。 上述著色感光性組合物係以形成彩色濾光片之像素之目的而使用，尤其作為用以形成液晶顯示面板等圖像顯示裝置用之顯示裝置用彩色濾光片之感光性組合物而較有用。 上述顯示裝置用彩色濾光片係藉由下述步驟而較佳地形成：(1)於基板上形成上述著色感光性組合物之塗膜；(2)介隔具有既定圖案形狀之遮罩向該塗膜照射活性光；(3)利用顯影液對曝光後之覆膜進行顯影；(4)對顯影後之該覆膜進行加熱。又，本發明之著色感光性組合物作為不具有顯影步驟之噴墨方式之著色感光性組合物亦有用。 作為上述遮罩，亦可使用半色調遮罩或灰度遮罩等多階遮罩。 實施例 以下，列舉實施例等更詳細地說明本發明，但本發明並不限定於該等實施例等。 [製造例1]聚合物B-3之製備 向反應容器中添加甲基丙烯酸縮水甘油酯142 g、苯乙烯8.3 g、甲基丙烯酸苄酯3.5 g、偶氮二異丁腈1.0 g及PGMEA38.5 g，於90℃下攪拌9小時。其後，將反應液冷卻至室溫，添加PGMEA 150 g、丙烯酸72 g及四正丁基溴化銨0.24 g，於120℃下攪拌4小時。進而，添加四氫鄰苯二甲酸酐99.6 g，於100℃下攪拌4小時，於60℃下攪拌6小時後，添加PGMEA 136.5 g而以PGMEA溶液之形式獲得目標物之聚合物B-3(Mw＝22000、Mn＝6000、酸值(固形物成分)101 mgKOH/g)。 [製造例2]聚合物B-4之製備 向反應容器中添加1,1-雙(4-(2,3-環氧丙氧基)苯基)茚滿184 g、丙烯酸58 g、2,6-二-第三丁基對甲酚0.26 g、四正丁基溴化銨0.11 g及PGMEA 105 g，於120℃下攪拌16小時。其後，將反應液冷卻至室溫，添加PGMEA 160 g、聯苯四甲酸二酐59 g及四正丁基溴化銨0.24 g，於120℃下攪拌4小時。進而，添加四氫鄰苯二甲酸酐20 g，於120℃下攪拌4小時，於100℃下攪拌3小時，於80℃下攪拌4小時，於60℃下攪拌6小時，於40℃下攪拌11小時後，添加PGMEA 128 g而以PGMEA溶液之形式獲得聚合物B-4(Mw＝5000、Mn＝2100、酸值(固形物成分)92.7 mgKOH/g)。 [實施例1～11及比較例1～2]感光性組合物No.1～No.11及比較感光性組合物No.1～No.2之製備 依據[表1]及[表2]之配方，製備感光性組合物No.1～No.11及比較感光性組合物No.1～No.2。再者，[表1]及[表2]中之數值為質量份。 [表1] [表2] [表1]及[表2]中之A-1～A-4表示下述潛伏性添加劑。 [化21][化22][化23][化24][表1]及[表2]中之符號B-1～B-4、B'-1、C-1～C-2、D-1～D-3、E-1及F-1分別表示下述化合物。B-1：SPC-1000(昭和電工公司製造之丙烯酸系樹脂；重量平均分子量31980，雙鍵當量900)；B-2：SPC-3000(昭和電工公司製造之丙烯酸系樹脂；重量平均分子量7610，雙鍵當量340)；B-3：製造例1中所獲得者(重量平均分子量22000，雙鍵當量330)；B-4：製造例2中所獲得者(重量平均分子量5600，雙鍵當量434)；B'-1：SPC-2000(昭和電工公司製造之丙烯酸系樹脂；重量平均分子量17500，雙鍵當量0)；C-1：ARONIX M450(東亞合成公司製造之丙烯酸系單體)；C-2：Kayarad DPHA(多官能丙烯酸酯；日本化藥公司製造)；D-1：NCI-930(ADEKA公司製造)；D-2：IRGACURE-OXE01(BASF公司製造)；D-3：TR-PBG-304(Tronly公司製造)；E-1：丙二醇-1-單甲醚-2-乙酸酯；F-1：藍色顏料分散液(使用15質量份之C.I.顏料藍15：6作為著色劑、12.5質量份(固形物成分濃度40質量%)之BYK161(BYK-Chemie(BYK)公司製造)作為分散劑、72.5質量份之丙二醇單甲醚乙酸酯作為溶劑，並利用珠磨機進行處理，藉此進行製備。) [評價例1-1～1-11及比較評價例1-1～1-2]利用焙燒進行之耐熱性評價 將實施例1～11中所製備之感光性組合物No.1～No.11以及比較例1～2者所製備之比較感光性組合物No.1～No.2分別以410 rpm×7 sec之條件塗敷於玻璃基板，並利用加熱板使其乾燥(90℃、90 sec)。利用超高壓水銀燈對所獲得之塗膜進行曝光(40 mJ/cm2 )。將曝光後之塗膜以230℃×90分之條件進行焙燒，並測定焙燒後之塗膜於400 nm下之透過率。將結果示於[表3]。   [表3] [評價例2-1～2-11及比較評價例2-1～2-2]耐溶劑性評價 將實施例1～10中所獲得之感光性組合物No.1～No.11及比較例1～2中所獲得之比較感光性組合物No.1～No.2分別以410 rpm×7秒之條件塗敷於玻璃基板，並利用加熱板使其乾燥(90℃、90秒)。利用超高壓水銀燈對所獲得之塗膜進行曝光(40 mJ/cm2 )之後，分別於環己酮、PGMEA、N-甲基吡咯啶酮、N-乙基吡咯啶酮中浸漬30分鐘。其後，利用離子交換水將其洗淨乾燥，並研究對各溶劑之浸漬試驗前後之膜厚。膨潤率(%)＝(試驗後之膜厚－試驗前之膜厚)/試驗前之膜厚×100，將膨潤率0～未達2%之情形時設為A，將2%～未達8%之情形設為B，將8%以上之情形設為C，將試驗後之膜厚較試驗前減少之情形設為D。將結果示於[表4]。   [表4] 根據以上結果，本發明之感光性組合物可維持焙燒後之透明性較高之狀態，即耐熱性較高，且耐溶劑性優異。 [產業上之可利用性] 根據本發明，可提供一種形成耐熱性及耐溶劑性較高之硬化物之感光性組合物。Hereinafter, the present invention will be described in detail based on preferred embodiments. The photosensitive composition of the present invention contains a latent additive (A), a polymer (B) having an ethylenically unsaturated bond and a hydrophilic group in one molecule and having a double bond equivalent of 200 to 1,000, and an acrylic monomer (C). And a photoradical polymerization initiator (D). Hereinafter, each component will be described in order. <latent additive (A)> The latent additive (A) used in the photosensitive composition of the present invention is blunt at normal temperature or in the pre-baking step, by heating at 100 to 250 ° C or at acid / The base is heated at 80 to 200 ° C in the presence of a base catalyst, and the protective group is detached to become active. The latent additive (A) is active and refers to reactivity with a radical, and the term "passive" means that it does not react with a radical or has extremely low reactivity. In the photosensitive composition of the present invention, it is preferred that the latent additive (A) has a skeleton represented by the following formula (I) because it is easily synthesized and has high heat resistance. [Chemical 1] (in the formula, ring A 1 a hydrocarbon ring or a heterocyclic ring or a condensed ring representing a five-membered or six-membered ring, R 61 Each of the halogen atom, the cyano group, the hydroxyl group, the nitro group, the carboxyl group, and the alkyl group having 1 to 40 carbon atoms in the case of having a substituent, and the carbon number of 6 to 20 in the case where a substituent is also present, respectively. An aryl group, an aralkyl group having 7 to 20 carbon atoms in the case of having a substituent, or a heterocyclic group having 2 to 20 carbon atoms in the case of having a substituent, R 62 Each independently represents an alkyl group having 1 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an aralkyl group having 7 to 20 carbon atoms, and 2 to 20 carbon atoms. 20 containing a heterocyclic group or a trialkyldecyl group, R 61 And R 62 The methylene group in the alkyl or aralkyl group indicated will be selected from the group consisting of carbon-carbon double bonds, -O-, -S-, -CO-, -O-CO-, -CO-O-, - O-CO-O-, -O-CO-O-, -S-CO-, -CO-S-, -S-CO-O-, -O-CO-S-, -CO-NH-, - NH-CO-, -NH-CO-O-, -NR'-, -SS- or -SO 2 - In the case where the group is substituted with a group in which oxygen atoms are not adjacent, R' represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, and plural R 61 There are also cases where a benzene ring or a naphthalene ring is bonded to each other, d represents an integer of 0 to 4, k represents an integer of 1 to 5, and the total of d and k is less than ring A. 1 The number of the substituents, * means that the * moiety is bonded to the adjacent group. Among the skeletons represented by the above formula (I), those represented by the following formula (IA) are particularly heat resistant. High, so better. [Chemical 2] (in the formula, ring A 1 , R 61 , R 62 , d and k are the same as the above formula (I), and m represents an integer of 1 to 10, X 1 In the present specification, the heterocyclic group having 2 to 20 carbon atoms means a group having at least one hetero ring and having a carbon number of 2 to 20 as a whole. Similarly, the following heterocyclic group having 2 to 10 carbon atoms means a group having at least one hetero ring and having a carbon number of 2 to 10 as a whole. Further, the following heterocyclic group having 2 to 35 carbon atoms means a group having at least one hetero ring and having a carbon number of 2 to 35 as a whole. In the case where the heterocyclic ring in the heterocyclic-containing group has a substituent, the number of carbon atoms in the entire group exceeds the upper limit of each group. In the case where the heterocyclic ring in the heterocyclic group has a substituent, as the substituent, for example, the following X may be mentioned as being present. 1 The substituents in the case where the base is substituted are exemplified. As the A in the above formula (I) 1 Examples of the hydrocarbon ring of the five-membered ring include cyclopentadiene and the like. Examples of the heterocyclic ring of the five-membered ring include furan, thiophene, pyrrole, pyrrolidine, pyrazole, pyrazole, imidazole, and imidazolium. Examples of the hydrocarbon ring of the six-membered ring include benzoxazole, isoxazole, isoxazole, thiazole, isothiazolidine, thiazole, isothiazole, and isotetrahydrothiazole. Examples of the hydrocarbon ring of the six-membered ring include a piperidine. Peptide &#134116;, &#134156; porphyrin, thio &#134156; porphyrin, pyridine, pyridinium, #134116;, pyrimidine, 嗒&#134116;, three &#134116; etc., the ring exists with other rings In the case of condensation or substitution, examples of the condensed ring include quinoline, isoquinoline, anthracene, &#134075; pyridinium, benzoxazole, benzotriazole, anthracene, naphthalene, anthracene, anthracene,苝, 芘, etc. As the R in the above formula (I) 61 The halogen atom to be represented includes fluorine, chlorine, bromine, and iodine (further, in the description of the following description, the halogen atom is the same as described above). As the R in the above formula (I) 61 The alkyl group having 1 to 40 carbon atoms represented by the formula includes methyl group, ethyl group, propyl group, isopropyl group, butyl group, second butyl group, tert-butyl group, isobutyl group, pentyl group and isobutyl group. Pentyl, third amyl, cyclopentyl, hexyl, 2-hexyl, 3-hexyl, cyclohexyl, 4-methylcyclohexyl, heptyl, 2-heptyl, 3-heptyl, isoheptyl, Triheptyl, 1-octyl, isooctyl, trioctyl, adamantyl and the like. As the R in the above formula (I) 61 The alkyl group having 1 to 40 carbon atoms, the aryl group having 6 to 20 carbon atoms, the aralkyl group having 7 to 20 carbon atoms or the heterocyclic group having 2 to 20 carbon atoms; Examples thereof include an ethylenically unsaturated group such as a vinyl group, an allyl group, an acryl group or a methacryl group; a halogen atom such as fluorine, chlorine, bromine or iodine; an ethyl group, a 2-chloroethyl group or a propyl group; Octyl, propylene sulfhydryl, methacryl fluorenyl, phenylcarbonyl (benzhydryl), phthalic acid, 4-trifluoromethyl benzhydryl, trimethylethenyl, o-hydroxybenzene Mercapto group, sulfhydryl group, stearyl group, methoxycarbonyl group, ethoxycarbonyl group, tert-butoxycarbonyl group, n-octadecyloxycarbonyl group, amine mercapto group, etc.; An anthracene group such as an benzylideneoxy group; an amine group, an ethylamino group, a dimethylamino group, a diethylamino group, a butylamino group, a cyclopentylamino group, a 2-ethylhexylamino group, Dodecylamino, anilino, chlorophenylamino, toluidine, methoxyanilino, N-methyl-anilino, diphenylamino, naphthylamino, 2-pyridylamino , methoxycarbonylamino, phenoxycarbonyl Amino, ethinylamino, benzhydrylamino, decylamino, trimethylethenylamine, laurylamine, aminecarboxamido, N,N-dimethyl Aminocarbonylcarbonylamino, N,N-diethylaminocarbonylamino, &#134156; morphylcarbonylamino, methoxycarbonylamino, ethoxycarbonylamino, tert-butoxycarbonyl Amino, n-octadecyloxycarbonylamino, N-methyl-methoxycarbonylamino, phenoxycarbonylamino, aminesulfonylamino, N,N-dimethylaminosulfonyl Substituted amine group such as arylamino, methylsulfonylamino, butylsulfonylamino, phenylsulfonylamino; sulfonylamino, sulfonyl, carboxy, cyano, sulfo, hydroxy A nitro group, a mercapto group, a quinone imine group, an amine carbenyl group, a sulfonylamino group, a phosphonic acid group, a phosphoric acid group or a carboxyl group, a sulfo group, a phosphonic acid group, a phosphate group salt or the like. As the R in the above formula (I) 61 And R 62 Examples of the aryl group having 6 to 20 carbon atoms represented include a phenyl group, a naphthyl group, an anthracenyl group, a phenanthryl group, an anthryl group, a fluorenyl group, a 2-methylphenyl group, a 3-methylphenyl group, and a 4- Methylphenyl, 4-vinylphenyl, 3-isopropylphenyl, 4-isopropylphenyl, 4-butylphenyl, 4-isobutylphenyl, 4-tert-butylbenzene , 4-hexylphenyl, 4-cyclohexylphenyl, 4-octylphenyl, 4-(2-ethylhexyl)phenyl, 4-stearylphenyl, 2,3-dimethylbenzene Base, 2,4-dimethylphenyl, 2,5-dimethylphenyl, 2,6-dimethylphenyl, 3,4-dimethylphenyl, 3,5-dimethylbenzene Base, 2,4-di-t-butylphenyl, 2,5-di-t-butylphenyl, 2,6-di-t-butylphenyl, 2,4-di-third Phenylphenyl, 2,5-di-third amylphenyl, 2,5-di-th-octylphenyl, 2,4-diisopropylphenylphenyl, 4-cyclohexylphenyl, 1,1'-biphenyl)-4-yl, 2,4,5-trimethylphenyl, ferrocene, and the like. As the R in the above formula (I) 61 And R 62 Examples of the aralkyl group having 7 to 20 carbon atoms represented include a benzyl group, a 1-methyl-1-phenylethyl group, a 1-naphthylmethyl group, a 9-fluorenylmethyl group, and a 9-fluorenyl group. , 3-phenylpropyl, methyl-2-phenylpropan-2-yl, diphenylmethyl, triphenylmethyl, phenethyl, styryl, phenylallyl, and the like. As the R in the above formula (I) 61 And R 62 The heterocyclic group having 2 to 20 carbon atoms represented by the formula includes a pyridine ring, a pyrimidine ring, a fluorene ring, a piperidine ring, a pyran ring, a pyrazoline ring, and a tri- &lt; Ring, pyrroline ring, quinoline ring, isoquinoline ring, imidazoline ring, benzimidazoline ring, triazoline ring, furan ring, benzofuran ring, thiadiazole ring, thiazoline ring, benzo Heterocyclic ring such as thiazoline ring, thiophene ring, oxazoline ring, benzoxazoline ring, isothiazoline ring, isoxazoline ring, anthracene ring, pyrrolidine ring, piperidone ring, dioxane ring It is combined with a methylene chain. As the R in the above formula (I) 62 The alkyl group having 1 to 20 carbon atoms is represented by R. 61 The above-mentioned alkyl group represented by the above-mentioned alkyl group satisfies the predetermined number of carbon atoms. As the R in the above formula (I) 62 Examples of the alkenyl group having 2 to 20 carbon atoms represented by a vinyl group include a vinyl group, a 1-methylvinyl-1-yl group, a propen-1-yl group, a propen-2-yl group, a propen-3-yl group, and a butene group. 1-yl, buten-2-yl, 2-methylpropen-3-yl, 1,1-dimethylvinyl-2-yl, 1,1-dimethylpropen-3-yl, 3-butyl Alkenyl, 1-methyl-3-butenyl, isobutenyl, 3-pentenyl, 4-hexenyl, cyclohexenyl, dicyclohexenyl, heptenyl, octenyl, nonenyl , pentadecenyl, behenyl, behenyl, and the like. As the R in the above formula (I) 62 The trialkylsulfanyl group to be represented may be an alkyl group having 1 to 6 carbon atoms (three alkyl groups may be the same or different), such as trimethylnonane, triethyldecane or ethyldimethylsilane. Alkyl. Examples of the alkyl group having 1 to 8 carbon atoms represented by R' in the above formula (I) include R. 61 The above-mentioned alkyl group represented by the above-mentioned alkyl group satisfies the predetermined number of carbon atoms. In the general formula (I), R 61 When it is a hydrogen atom, an alkyl group having 1 to 8 carbon atoms or an aryl group having 6 to 12 carbon atoms, it is preferably synthesized. In the general formula (I), R 62 It is preferred that the end of the oxygen atom side of the alkyl group having 1 to 8 carbon atoms is bonded to -CO-O- as a latent additive and functions efficiently. In the above formula (IA), X 1 The m-valent organic group is specifically represented by a direct bond, a hydrogen atom, a nitrogen atom, an oxygen atom, a sulfur atom, a phosphorus atom, a group represented by the following (Ia) or (Ib), >C=O, > NR 63 , -OR 63 , -SR 63 , -NR 63 R 64 Or an aliphatic hydrocarbon group having 1 to 120 carbon atoms having the same valence number as m in the case of having a substituent, and a carbon number having the same valence number as m in the case of having a substituent; a heterocyclic group having 2 to 35 carbon atoms having the same valence number as m in the case of an aromatic ring-containing hydrocarbon group of 35 and having a substituent, R 63 And R 64 In the case of a hydrogen atom, an aliphatic hydrocarbon group having 1 to 35 carbon atoms in the case of having a substituent, and an aromatic ring-containing hydrocarbon group having 6 to 35 carbon atoms in the case of having a substituent, or a case having a substituent a heterocyclic group having 2 to 35 carbon atoms, wherein the aliphatic hydrocarbon group, the aromatic ring-containing hydrocarbon group and the heterocyclic group-containing methylene group are also selected from a carbon-carbon double bond, -O-, -S-, -CO-, -O-CO-, -CO-O-, -O-CO-O-, -O-CO-O-, -S-CO-, -CO-S-, -S-CO-O -, -O-CO-S-, -CO-NH-, -NH-CO-, -NH-CO-O-, -NH-CO-O-, -NR'-, -SS-, -SO 2- Or a case where a group in a nitrogen atom is substituted, R' represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms. Among them, in X 1 In the case of a nitrogen atom, a phosphorus atom or a group represented by the following (Ia) or (Ib), m is 3, and is X. 1 Is an oxygen or sulfur atom, >C=O, -NH-CO-, -CO-NH- or >NR 63 In the case of case, m is 2, in X 1 For -OR 63 , -SR 63 Or -NR 63 R 64 In the case of case, m is 1, and X is also present. 1 With A 1 Together form a ring. [Chemical 3] (* means that the * moiety is bonded to the adjacent group.) The latent additive represented by the above formula (IA) has X 1 The specific atom or the base of the m-value is bonded to have a structure of m specific groups. The m groups are identical or different from each other. The value of m is from 1 to 10, and from the viewpoint of easiness of synthesis, it is preferably from 2 to 6. As the X in the above formula (IA) 1 The aliphatic hydrocarbon group having 1 to 120 carbon atoms having the same valence number as m, and examples in which m is monovalent, and examples thereof include a methyl group, an ethyl group, a propyl group, an isopropyl group, and a cyclopropyl group. Butyl, t-butyl, tert-butyl, isobutyl, pentyl, isopentyl, tert-amyl, cyclopentyl, hexyl, 2-hexyl, 3-hexyl, cyclohexyl, dicyclohexyl, 1 -methylcyclohexyl, heptyl, 2-heptyl, 3-heptyl, isoheptyl, third heptyl, n-octyl, isooctyl, trioctyl, 2-ethylhexyl, decyl, An alkyl group such as isodecyl or fluorenyl; methoxy, ethoxy, propoxy, isopropoxy, butoxy, second butoxy, tert-butoxy, isobutoxy, pentoxide Base, isopentyloxy, third pentyloxy, hexyloxy, cyclohexyloxy, heptyloxy, isoheptyloxy, third heptyloxy, n-octyloxy, isooctyloxy, third octyl Alkoxy groups such as oxy, 2-ethylhexyloxy, decyloxy, decyloxy; methylthio, ethylthio, propylthio, isopropylthio, butylthio, butylthio; Third butylthio group, isobutylthio group, pentylthio group, isopentylthio group, third pentylthio group, hexyl sulfide Alkylthio group such as cyclohexylthio, heptylthio, isoheptylthio, third heptylthio, n-octylthio, isooctylthio, trioctylthio, 2-ethylhexylthio; ethylene Base, 1-methylvinyl, 2-methylvinyl, 2-propenyl, 1-methyl-3-propenyl, 3-butenyl, 1-methyl-3-butenyl, isobutenyl , 3-pentenyl, 4-hexenyl, cyclohexenyl, dicyclohexenyl, heptenyl, octenyl, nonenyl, pentadecenyl, behenyl, icosyl An alkenyl group and a group obtained by substituting the substituents described later. As the X in the above formula (IA) 1 The aliphatic hydrocarbon group having 1 to 120 carbon atoms which is the same valence number as m, and m is a valence, and examples thereof include a methylene group, an ethyl group, a propyl group, a butyl group, and a dibutyl group. An alkyl group; the methylene chain of the above alkyl group is substituted by -O-, -S-, -CO-O-, -O-CO-; ethylene glycol, propylene glycol, butylene glycol, Residues of diols such as pentanediol and hexanediol; residues of dithiols such as ethanedithiol, propylenedithiol, butyldithiol, pentanethiol, hexanedithiol, and the like A group obtained by substituting a substituent described later. As the X in the above formula (IA) 1 The aliphatic hydrocarbon group having 1 to 120 carbon atoms having the same valence number as m, and examples of m being trivalent, and examples thereof include a pyridylpyridine and a 1, alkylidene group and the like. These groups are substituted by a substituent described later. As the X in the above formula (IA) 1 The aromatic ring-containing hydrocarbon group having 6 to 35 carbon atoms in the case of having a substituent having the same valence as m, and examples in which m is monovalent, benzyl, phenethyl or diphenyl is exemplified. An arylalkyl group such as a methyl group, a triphenylmethyl group, a styryl group or a phenylallyl group; an aryl group such as a phenyl group or a naphthyl group; an aryloxy group such as a phenoxy group or a naphthyloxy group; a phenylthio group; An arylthio group such as a group and a group obtained by substituting the substituents with a substituent described later. As the X in the above formula (IA) 1 The aromatic ring-containing hydrocarbon group having 6 to 35 carbon atoms having the same valence number as m in the case of having a substituent is also present, and examples in which m is a divalent group include exophenylene and naphthyl. An aryl group; a residue of a difunctional phenol such as catechol or bisphenol; 2,4,8,10-tetraoxaspiro[5,5]undecane, etc., and the substituents are substituted by the substituents described later The basis. As the X in the above formula (IA) 1 The aromatic ring-containing hydrocarbon group having 6 to 35 carbon atoms having the same valence number as m in the case of having a substituent is also present, and phenyl-1,3,5-triazine is exemplified as m being trivalent. A methyl group and a group obtained by substituting a substituent described later. As the X in the above formula (IA) 1 The heterocyclic group having 2 to 35 carbon atoms having the same valence number as m in the case of having a substituent is also present, and as the one having m being monovalent, pyridyl group, pyrimidinyl group, oxime &# 134116; phenyl, piperidinyl, pyranyl, pyrazolyl, tris-l134,yl, pyrrolyl, quinolyl, isoquinolinyl, imidazolyl, benzimidazolyl, triazolyl, furyl Furyl), furanyl, benzofuranyl, thienyl, thiophenyl, benzothienyl, thiadiazolyl, thiazolyl, benzothiazolyl, oxazolyl, benzo Carbazolyl, isothiazolyl, isoxazolyl, indolyl, 2-pyrrolidone-1-yl, 2-piperidin-1-yl, 2,4-dioxyimidazol-3-yl And a 2,4-dioxyoxazolidin-3-yl group, a benzotriazolyl group, etc., and the base etc. substituted by the substituents mentioned later. As the X in the above formula (IA) 1 The heterocyclic group having 2 to 35 carbon atoms having the same valence number as m in the case of having a substituent is also present, and examples of the m being a divalent group include a pyridine ring, a pyrimidine ring, and a piperidine. a group of a ring, a piperazine, a ring, a trisole, a furan ring, a thiophene ring, an anthracene ring, and the like, and a group obtained by substituting the substituents described later. As the X in the above formula (IA) 1 Further, there is also a heterocyclic group having 2 to 35 carbon atoms having the same valence number as m in the case of having a substituent, and examples in which m is a trivalent group include a group having an iso-cyanuric acid ring. And having a base of the ring and a group substituted by the substituents described later. As R 63 And R 64 The aliphatic hydrocarbon group having 1 to 35 carbon atoms in the case of having a substituent is also represented, and the above X may be mentioned. 1 The aliphatic hydrocarbon group having 1 to 120 carbon atoms or the combination of the aliphatic hydrocarbon group and a substituent described below satisfy a predetermined number of carbon atoms. As R 63 And R 64 The heterocyclic group having 2 to 35 carbon atoms having a carbon atom number of 6 to 35 or a heterocyclic group having 2 to 35 carbon atoms in the case of having a substituent, and the above-mentioned X may be mentioned. 1 The aromatic ring-containing hydrocarbon group having 6 to 35 carbon atoms or the heterocyclic group having 2 to 35 carbon atoms or a group in which the group is bonded to a substituent described later. As a presence, X 1 a substituent in the case of an aliphatic hydrocarbon group having 1 to 120 carbon atoms, an aromatic cyclic hydrocarbon group having 6 to 35 carbon atoms, and a heterocyclic group having 2 to 35 carbon atoms, and the presence of R 63 And R 6 Examples of the substituent in the case of the aliphatic hydrocarbon group having 1 to 35 carbon atoms, the aromatic ring-containing hydrocarbon group having 6 to 35 carbon atoms, and the heterocyclic group having 2 to 35 carbon atoms are represented by a vinyl group. An ethylenically unsaturated group such as an allyl group, an acryl group or a methacryl group; a halogen atom such as fluorine, chlorine, bromine or iodine; an ethyl group, a 2-chloroethyl group, a propyl group, a decyl group or an acryl group; Methyl propylene fluorenyl, phenylcarbonyl (benzhydryl), phthalic acid, 4-trifluoromethyl benzhydryl, trimethylethyl fluorenyl, o-hydroxybenzhydryl, turf Base group, stearyl group, methoxycarbonyl group, ethoxycarbonyl group, tert-butoxycarbonyl group, n-octadecyloxycarbonyl group, amine mercapto group, etc.; ethoxy group, benzyl methoxy group Equivalent oxime; amine, ethylamino, dimethylamino, diethylamino, butylamino, cyclopentylamino, 2-ethylhexylamino, dodecylamino Anilino, chlorophenylamino, toluidine, methoxyanilino, N-methyl-anilino, diphenylamino, naphthylamino, 2-pyridylamino, methoxycarbonylamine Phenoxycarbonylamine Base, acetamidoamine, benzhydrylamine, methionylamine, trimethylethenylamine, laurylamine, aminecarboxamido, N,N-dimethyl Aminocarbonylamino group, N,N-diethylaminocarbonylamino group, &#134156; morphylcarbonylamino group, methoxycarbonylamino group, ethoxycarbonylamino group, third butoxycarbonylamine , n-octadecyloxycarbonylamino, N-methyl-methoxycarbonylamino, phenoxycarbonylamino, aminesulfonylamino, N,N-dimethylaminosulfonyl a substituted amine group such as an amine group, a methylsulfonylamino group, a butylsulfonylamino group or a phenylsulfonylamino group; a sulfonylamino group, a sulfonyl group, a carboxyl group, a cyano group, a sulfo group, a hydroxyl group, a nitro group, a mercapto group, a quinone imine group, an amine carbenyl group, a sulfonylamino group, a phosphonic acid group, a phosphoric acid group or a carboxyl group, a sulfo group, a phosphonic acid group, a phosphate group salt, etc., and these groups are further substituted The situation. Further, a carboxyl group and a sulfo group are also present in the form of a salt. Examples of the alkyl group having 1 to 8 carbon atoms represented by R' in the above formula (IA) include the above R. 61 The above-mentioned alkyl group represented by the above-mentioned alkyl group satisfies the predetermined number of carbon atoms. In the above formula (IA), when m is 2, X 1 It can also be represented by the following general formula (1). [Chemical 4] (In the above formula (1), Y 10 Represents single button, -CR 65 R 66 -, -NR 67 - a divalent aliphatic hydrocarbon group having 1 to 35 carbon atoms, an aromatic hydrocarbon group having 6 to 35 carbon atoms or a heterocyclic group having 2 to 35 carbon atoms, or the following (1-1) to (1) Any of the substituents represented by -3), the adjacent carbon atom of the aliphatic hydrocarbon group is also present in -O-, -S-, -CO-, -COO-, -OCO- or -NH-, or oxygen In the case where the bonded groups are interrupted under the condition that the atoms are not adjacent, the carbon atoms at the terminal of the aliphatic hydrocarbon group are also present via -O-, -S-, -CO-, -COO-, - In the case of OCO- or -NH- substitution, the aliphatic hydrocarbon group is also substituted by a hydroxyl group, a halogen atom, a cyano group, a nitro group, a carboxyl group or an alkoxy group, Z 1 And Z 2 Directly indicating direct bonding, -O-, -S-, >CO, -CO-O-, -O-CO-, -SO 2- , -SS-, -SO-, >NR 67 Or >PR 67 , R 65 , R 66 And R 67 An aliphatic hydrocarbon group having 1 to 35 carbon atoms in the case of having a substituent, and an aromatic hydrocarbon group having 6 to 35 carbon atoms in the case of having a substituent, or In the case of a substituent, a heterocyclic group having 2 to 35 carbon atoms, * means a bond between a * moiety and an adjacent group) [Chemical 5] (In the above formula, R 71 a hydrogen atom, a phenyl group having a substituent, or a cycloalkyl group having 3 to 10 carbon atoms, R 72 And it is an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms or a halogen atom, and the alkyl group, the alkoxy group and the alkenyl group have a substituent. In the case where f is an integer from 0 to 5, * means that the * part is bonded to the adjacent base) [Chem. 6] (* means the * part and the adjacent base bond) [Chem. 7] (In the above formula, R 73 And R 74 The alkyl group having 1 to 10 carbon atoms in the case of having a substituent, the aryl group having 6 to 20 carbon atoms in the case of having a substituent, and the carbon atom in the case of having a substituent are also independently represented. An aryloxy group having 6 to 20 aryloxy groups having 6 to 20 carbon atoms in the case of having a substituent, and an arylalkenyl group having 6 to 20 carbon atoms in the case of having a substituent, In the case of a substituent, an aralkyl group having 7 to 20 carbon atoms, a heterocyclic group having 2 to 20 carbon atoms or a halogen atom in the case of having a substituent, and a methylene group in the alkyl group and the aralkyl group The base is substituted by an unsaturated bond, -O- or -S, R 73 Adjacent R 73 In the case of forming a loop with each other, p represents the number of 0 to 4, q represents the number of 0 to 8, g represents the number of 0 to 4, h represents the number of 0 to 4, and the total of the number of g and h is 2 to 4, * means that the * part is bonded to the adjacent group.) In the above formula (IA), when m is 3, X 1 It can also be represented by the following general formula (2). [化8] (In the above formula (2), Y 11 A single bond, a trivalent aliphatic hydrocarbon group having 3 to 35 carbon atoms, a trivalent alicyclic hydrocarbon group having 3 to 35 carbon atoms, a trivalent carbon group having 6 to 35 carbon atoms or a trivalent group a heterocyclic group having 2 to 35 carbon atoms, Z 1 ,Z 2 And Z 3 Directly indicating direct bonding, -O-, -S-, >CO, -CO-O-, -O-CO-, -SO 2- , -SS-, -SO-, >NR 68 Or >PR 68 , R 68 In the case of a hydrogen atom, an aliphatic hydrocarbon group having 1 to 35 carbon atoms in the case of having a substituent, and an aromatic hydrocarbon group having 6 to 35 carbon atoms in the case of having a substituent, or a case having a substituent a heterocyclic group having 2 to 35 carbon atoms, and a carbon atom adjacent to the aliphatic hydrocarbon group is also present via a carbon-carbon double bond, -O-, -CO-, -O-CO-, -CO-O- or -SO 2- In the case of interruption, the carbon atom at the end of the aliphatic hydrocarbon group also exists via a carbon-carbon double bond, -O-, -CO-, -O-CO-, -CO-O- or -SO 2- In the case of substitution), in the above formula (IA), when m is 4, X 1 It can also be represented by the following general formula (3). [Chemistry 9] (In the above formula (3), Y 12 A single bond, a carbon atom, or a tetravalent aliphatic hydrocarbon group having 1 to 35 carbon atoms, a tetravalent aromatic hydrocarbon group having 6 to 35 carbon atoms or a tetravalent carbon group having 2 to 35 carbon atoms The carbon atom adjacent to the aliphatic hydrocarbon group is interrupted by -COO-, -O-, -OCO-, -NHCO-, -NH- or -CONH-, and the carbon atom at the terminal of the aliphatic hydrocarbon group is present - COO-, -O-, -OCO-, -NHCO-, -NH- or -CONH- substitution, Z 1 ~Z 4 Separately and independently of Z in the above formula (2) 1 ~Z 3 The base of the same range as expressed.) In the above formula (IA), when m is 5, X 1 It can also be represented by the following general formula (4). [化10] (In the above formula (4), Y 13 And a heterocyclic group having a single bond, a 5-valent aliphatic hydrocarbon group having 2 to 35 carbon atoms, a 5-valent aromatic hydrocarbon group having 6 to 20 carbon atoms, or a 5-valent carbon group having 2 to 20 carbon atoms. The adjacent carbon atom of the hydrocarbon group is interrupted by -COO-, -O-, -OCO-, -NHCO-, -NH- or -CONH-, and the carbon atom at the terminal of the aliphatic hydrocarbon group is present via -COO-, - O-, -OCO-, -NHCO-, -NH- or -CONH- substitution, Z 1 ~Z 5 Separately and independently of Z in the above formula (2) 1 ~Z 3 The base of the same range as expressed.) In the above formula (IA), when m is 6, X 1 It can also be represented by the following general formula (5). [11] (In the above formula (5), Y 14 And a heterocyclic group having a single bond, a 6-valent aliphatic hydrocarbon group having 2 to 35 carbon atoms, a 6-valent aromatic hydrocarbon group having 6 to 35 carbon atoms, or a hexavalent carbon atom having 2 to 35 carbon atoms. The adjacent carbon atom of the hydrocarbon group is interrupted by -COO-, -O-, -OCO-, -NHCO-, -NH- or -CONH-, and the carbon atom at the terminal of the aliphatic hydrocarbon group is present via -COO-, - O-, -OCO-, -NHCO-, -NH- or -CONH- substitution, Z 1 ~Z 6 Separately and independently of Z in the above formula (2) 1 ~Z 3 The base of the same range as the base expressed) as the R in the above formula (1) 65 , R 66 And R 67 The aliphatic hydrocarbon group having 1 to 35 carbon atoms in the case of having a substituent is also exemplified as X in the above formula (IA) 1 The monovalent aliphatic hydrocarbon group having 1 to 120 carbon atoms exemplified as the m-valent organic group, and the groups are represented by X in the above formula (IA) 1 The group substituted by the substituent of the m-valent organic group represented by the group represented by the substituent of the m-valent organic group, etc., as the base or the X in the above formula (IA) 1 The divalent aliphatic hydrocarbon group exemplified by the m-valent organic group represented by Z 1 And Z 2 The base of the two-price substitution is listed as Y 10 The divalent aliphatic hydrocarbon group having 1 to 35 carbon atoms is represented. As R 65 , R 66 And R 67 The aromatic ring-containing hydrocarbon group having 6 to 35 carbon atoms in the case of having a substituent, and the X in the above formula (IA) 1 The monovalent aromatic atom-containing hydrocarbon group having 6 to 35 carbon atoms exemplified as the m-valent organic group, and the group are represented by X in the above formula (IA) 1 The substituent represented by the substituent of the m-valent organic group represented by the group, etc., as the group or the X in the above formula (IA) 1 The divalent carbon group having 6 to 35 carbon atoms represented by the m-valent organic group is represented by an aromatic cyclic hydrocarbon group. 1 And Z 2 The base of the two-price substitution is listed as Y 10 The divalent aromatic group-containing hydrocarbon group having 6 or less carbon atoms is represented. As R 65 , R 66 And R 67 The heterocyclic group having 2 to 35 carbon atoms in the case of having a substituent, and the X in the above formula (IA) 1 The monovalent carbon-containing heterocyclic group having 2 to 35 carbon atoms exemplified as the m-valent organic group, and the groups are represented by X in the above formula (IA) 1 The substituent represented by the substituent of the m-valent organic group represented by the group, etc., as the group or the X in the above formula (IA) 1 The divalent organic group represented by the m-valent organic group is represented by a 2-valent aromatic atom-containing hydrocarbon group having 2 to 35 carbon atoms. 1 And Z 2 The base of the two-price substitution is listed as Y 10 The divalent heterocyclic group having 2 to 35 carbon atoms is represented. Among the substituents represented by the above (1-1), as R 71 Examples of the cycloalkyl group having 3 to 10 carbon atoms represented by the ring include a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, a cycloheptyl group, and a cyclooctyl group. Among the substituents represented by the above (1-1), as R 72 The alkyl group having 1 to 10 carbon atoms represented by R can be cited as R 61 The group exemplified by the alkyl group having 1 to 40 carbon atoms represented by the base group satisfying a predetermined number of carbon atoms. Among the substituents represented by the above (1-1), as R 72 Examples of the alkoxy group having 1 to 10 carbon atoms represented by the formula include a methoxy group, an ethoxy group, a propoxy group, an isopropoxy group, a butoxy group, a second butoxy group, and a third butoxy group. Isobutoxy, pentyloxy, isopentyloxy, third pentyloxy, hexyloxy, cyclohexyloxy, heptyloxy, isoheptyloxy, third heptyloxy, n-octyloxy, iso Octyloxy, trioctyloxy, 2-ethylhexyloxy, decyloxy, decyloxy and the like. In the substituent represented by the above (1-1), the substituent of the above phenyl group, alkyl group, alkoxy group and alkenyl group is represented by X in the above formula (IA) 1 The substituents of the m-valent organic group represented by the same are exemplified. In the base represented by the above (1-3), as R 73 And R 74 The alkyl group having 1 to 10 carbon atoms in the case of having a substituent is also shown as R. 61 The group exemplified by the alkyl group having 1 to 40 carbon atoms represented by the base group satisfying a predetermined number of carbon atoms. In the base represented by the above (1-3), as R 73 And R 74 The aryl group having 6 to 20 carbon atoms in the case of having a substituent is also present, and it can be cited as R. 61 And R 62 The group represented by the aryl group having 6 to 20 carbon atoms is represented. In the base represented by the above (1-3), as R 73 And R 74 Examples of the aryloxy group having 6 to 20 carbon atoms in the case of having a substituent include a phenoxy group, a naphthyloxy group, a 2-methylphenoxy group, a 3-methylphenoxy group, and 4 -Methylphenoxy, 4-vinylphenoxy, 3-isopropylphenoxy, 4-isopropylphenoxy, 4-butylphenoxy, 4-tert-butylphenoxy , 4-hexylphenoxy, 4-cyclohexylphenoxy, 4-octylphenoxy, 4-(2-ethylhexyl)phenoxy, 2,3-dimethylphenoxy, 2, 4-dimethylphenoxy, 2,5-dimethylphenoxy, 2.6-dimethylphenoxy, 3.4-dimethylphenoxy, 3.5-dimethylphenoxy, 2,4 -di-t-butylphenoxy, 2,5-di-t-butylphenoxy, 2,6-di-t-butylphenoxy, 2.4-di-third-pentylphenoxy a group such as 2,5-tripentylphenoxy, 4-cyclohexylphenoxy, 2,4,5-trimethylphenoxy, or ferrocenyloxy. In the base represented by the above (1-3), as R 73 And R 74 In the case of the arylthio group having 6 to 20 carbon atoms in the case of having a substituent, the oxygen atom of the aryloxy group having 6 to 20 carbon atoms in the case where the substituent is present may be substituted with sulfur. The base of the atom and so on. In the base represented by the above (1-3), as R 73 And R 74 The aralkenyl group having 6 to 20 carbon atoms in the case of having a substituent is also present, and the oxygen atom of the aryloxy group having 6 to 20 carbon atoms in the case where the substituent is present may be mentioned as a vinyl group. A group obtained by substituting an alkenyl group such as allyl, 1-propenyl, isopropenyl, 2-butenyl, 1,3-butadienyl, 2-pentenyl or 2-octenyl. In the base represented by the above (1-3), as R 73 And R 74 The aralkyl group having 7 to 20 carbon atoms is shown as R 61 And R 62 The group represented by the aralkyl group having 7 to 20 carbon atoms is represented. In the base represented by the above (1-3), as R 73 And R 74 Also shown is a heterocyclic group having 2 to 20 carbon atoms in the case of having a substituent, and it can be cited as R. 61 And R 62 The group represented by the heterocyclic group having 2 to 20 carbon atoms is represented. As Y in the above formula (2) 11 The trivalent aliphatic hydrocarbon group having 1 to 35 carbon atoms is exemplified as X in the above formula (IA). 1 The monovalent to trivalent aliphatic hydrocarbon group exemplified by the m-valent organic group represented, and the groups are represented by X in the above formula (IA) 1 In the group in which the substituent of the m-valent organic group is substituted, the group satisfying the predetermined number of carbon atoms, etc. 1 ,Z 2 And Z 3 Replaced by the base of the 3 price. As Y in the above formula (2) 11 Examples of the trivalent alicyclic hydrocarbon group having 3 to 35 carbon atoms include a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclooctyl group, a cyclodecyl group, a 1-adamantyl group, and a 2-adamantane group. Base, n-adamantyl, 2-methyladamantyl, Descending &#158665; yl, iso-lowering, yl, perhydronaphthyl, perhydroindolyl, bicyclo[1.1.0]butyl, bicyclic [1.1.1] pentyl, bicyclo[2.1.0]pentyl, bicyclo[3.1.0]hexyl, bicyclo[2.1.1]hexyl, bicyclo[2.2.0]hexyl, bicyclo[4.1.0]heptyl, Bicyclo [3.2.0] heptyl, bicyclo [3.1.1] heptyl, bicyclo [2.2.1] heptyl, bicyclo [5.1.0] octyl, bicyclo [4.2.0] octyl, bicyclo [4.1.1 ] octyl, bicyclo [3.3.0] octyl, bicyclo [3.2.1] octyl, bicyclo [2.2.2] octyl, spiro (4,4) fluorenyl, spiro (4, 5) fluorenyl, ten Hydrogen naphthalene, tricyclodecyl, tetracyclododecyl, cedarol, cyclododecyl, etc. 1 ,Z 2 And Z 3 Replaced by the base of the 3 price. As Y in the above formula (2) 11 The trivalent aromatic group-containing hydrocarbon group having 6 to 35 carbon atoms is exemplified as X in the above formula (IA). 1 The monovalent to trivalent aromatic ring-containing hydrocarbon group exemplified by the m-valent organic group represented, and the groups are represented by X in the above formula (IA) 1 The substituent represented by the substituent of the m-valent organic group represented by the group 1 ,Z 2 And Z 3 Replaced by the base of the 3 price. As Y in the above formula (2) 11 The trivalent-containing heterocyclic group having 2 to 35 carbon atoms is exemplified as X in the above formula (IA) 1 The monovalent to trivalent heterocyclic group exemplified by the m-valent organic group represented, and the groups are represented by X in the above formula (IA) 1 The substituent represented by the substituent of the m-valent organic group represented by the group 1 ,Z 2 And Z 3 Replaced by the base of the 3 price. Further, as R in the above formula (2) 68 Also, there are also an aliphatic hydrocarbon group having 1 to 35 carbon atoms in the case of a substituent, an aromatic hydrocarbon group having 6 to 35 carbon atoms in the case of having a substituent, and a carbon having a substituent. The heterocyclic group having 2 to 35 atoms, and R in the above formula (1) 65 And R 66 The aliphatic hydrocarbon group, the aromatic ring-containing hydrocarbon group, and the heterocyclic group-containing group exemplified in the description. As Y in the above formula (3) 12 The tetravalent aliphatic hydrocarbon group having 1 to 35 carbon atoms is exemplified as X in the above formula (IA). 1 The monovalent to trivalent aliphatic hydrocarbon group exemplified by the m-valent organic group represented, and the groups are represented by X in the above formula (IA) 1 In the group in which the substituent of the m-valent organic group is substituted, the group satisfying the predetermined number of carbon atoms, etc. 1 ,Z 2 ,Z 3 And Z 4 Replaced by the four-valent base. As Y in the above formula (3) 12 The aromatic ring-containing hydrocarbon group having 6 to 35 carbon atoms represented by the formula, as X in the above formula (IA) 1 The monovalent to trivalent aromatic ring-containing hydrocarbon group exemplified by the m-valent organic group represented, and the groups are represented by X in the above formula (IA) 1 The substituent represented by the substituent of the m-valent organic group represented by the group 1 ,Z 2 ,Z 3 And Z 4 Replaced by the four-valent base. As Y in the above formula (3) 12 The tetravalent carbon group having 2 to 35 carbon atoms represented by the above may be mentioned as X in the above formula (IA) 1 The monovalent to trivalent heterocyclic group exemplified by the m-valent organic group represented, and the groups are represented by X in the above formula (IA) 1 The substituent represented by the substituent of the m-valent organic group represented by the group 1 ,Z 2 ,Z 3 And Z 4 Replaced by the four-valent base. As Y in the above formula (4) 13 The aliphatic hydrocarbon group having 5 or less carbon atoms having 2 to 35 carbon atoms represented by the above formula (IA) 1 The monovalent to trivalent aliphatic hydrocarbon group exemplified by the m-valent organic group represented, and the groups are represented by X in the above formula (IA) 1 In the group in which the substituent of the m-valent organic group is substituted, the group satisfying the predetermined number of carbon atoms, etc. 1 ,Z 2 ,Z 3 ,Z 4 And Z 5 Substitute the five-valent base. As Y in the above formula (4) 14 The 5-membered aromatic ring-containing hydrocarbon group having 6 to 35 carbon atoms is exemplified as X in the above formula (IA). 1 The monovalent to trivalent aromatic ring-containing hydrocarbon group exemplified by the m-valent organic group represented, and the groups are represented by X in the above formula (IA) 1 The substituent represented by the substituent of the n-valent organic group represented by the substituent 1 ,Z 2 ,Z 3 ,Z 4 And Z 5 Substitute the five-valent base. As Y in the above formula (4) 14 The 5-membered heterocyclic group having 5 to 35 carbon atoms is exemplified as X in the above formula (IA). 1 The monovalent to trivalent heterocyclic group exemplified by the n-valent organic group represented by X in the m-value represented, and the bases are represented by X in the above formula (IA) 1 The substituent represented by the substituent of the m-valent organic group represented by the group 1 ,Z 2 ,Z 3 ,Z 4 And Z 5 Substitute the five-valent base. As Y in the above formula (5) 14 The aliphatic hydrocarbon group having 6 or less carbon atoms having 2 to 35 carbon atoms represented by the above formula (IA) 1 The monovalent to trivalent aliphatic hydrocarbon group exemplified by the m-valent organic group represented, and the groups are represented by X in the above formula (IA) 1 In the group substituted by the substituent of the m-valent organic group represented by the group, the Z or the like satisfying the predetermined number of carbon atoms 1 ,Z 2 ,Z 3 ,Z 4 ,Z 5 And Z 6 Replaced by the 6-valent base. As Y in the above formula (5) 14 The aromatic ring-containing hydrocarbon group having 6 or more carbon atoms having 6 to 35 carbon atoms represented by the above formula (IA) 1 The monovalent to trivalent aromatic ring-containing hydrocarbon group exemplified by the m-valent organic group represented, and the groups are represented by X in the above formula (IA) 1 The substituent represented by the substituent of the m-valent organic group represented by the group 1 ,Z 2 ,Z 3 ,Z 4 ,Z 5 And Z 6 Replaced by the 6-valent base. As Y in the above formula (5) 14 The 6-valent heterocyclic group having 6 to 35 carbon atoms is exemplified as X in the above formula (IA) 1 The monovalent to trivalent heterocyclic group represented by the m-valent organic group represented by the m-valent organic group is substituted by a substituent as exemplified as a substituent. 1 ,Z 2 ,Z 3 ,Z 4 ,Z 5 And Z 6 Replaced by the 6-valent base. In the above formula (IA), the sum of d and k is smaller than ring A 1 The number of substituents is preferred. For example, ring A 1 Ring A for a six-membered ring 1 A preferred substituent is 6,d+k≦5. Again, ring A 1 Ring A for a five-membered ring 1 A preferred substituent is 4, d+k≦3. Specific examples of the compound represented by the above formula (IA) include the following structures. [化12] Among the compounds represented by the above formula (IA), those represented by the following formulae (II) to (IV) are preferred because they are easily synthesized and have high heat resistance. [Chemistry 13] (in the formula, ring A 2 An alicyclic, aromatic or heterocyclic ring of six members, R 81 , R 82 , R 83 , R 84 And R 85 The hydrogen atom, the halogen atom, the cyano group, the hydroxyl group, the nitro group, the carboxyl group, the alkyl group having 1 to 40 carbon atoms, the aryl group having 6 to 20 carbon atoms, and the 7-carbon number in the case of having a substituent. 20 aralkyl group, heterocyclic group having 2 to 20 carbon atoms or -OR 62 ,R 81 , R 82 , R 83 , R 84 And R 85 At least one of them is not a hydrogen atom, R 62 Same as the above formula (I)) [Chem. 14] (where, X 2 Is a group represented by the above formula (1), R 86 , R 87 , R 88 And R 89 The hydrogen atom, the halogen atom, the cyano group, the hydroxyl group, the nitro group, the carboxyl group, the alkyl group having 1 to 40 carbon atoms, the aryl group having 6 to 20 carbon atoms, and the 7-carbon number in the case of having a substituent. 20 aralkyl or heterocyclic group having 2 to 20 carbon atoms, R 86 , R 87 , R 88 And R 89 At least one of them is not a hydrogen atom, R 62 Same as the above formula (I), ring A 2 Same as the above formula (II)) [Chem. 15] (where r=2~6, X 3 When r=2, it is a group represented by the above formula (1), and when r=3, it is a group represented by the above formula (2), and when r=4, it is a group represented by the above formula (3). When r=5, it is a group represented by the above formula (4), and when r=6, it is a group represented by the above formula (5), R 91 , R 92 , R 93 And R 94 The hydrogen atom, the halogen atom, the cyano group, the hydroxyl group, the nitro group, the carboxyl group, the alkyl group having 1 to 40 carbon atoms, the aryl group having 6 to 20 carbon atoms, and the 7-carbon number in the case of having a substituent. 20 aralkyl or heterocyclic group having 2 to 20 carbon atoms, R 91 , R 92 , R 93 And R 94 At least one of them is not a hydrogen atom, R 62 Same as the above formula (I), ring A 2 It is the same as the above formula (II). ) as the ring A in the above formula (II) 2 The alicyclic ring, aromatic ring or heterocyclic ring of the six-membered ring represented by the above formula (I) 1 Illustrated in the description. As the R in the above formula (II) 81 , R 82 , R 83 , R 84 And R 85 The halogen atom to be represented, an alkyl group having 1 to 40 carbon atoms, an aryl group having 6 to 20 carbon atoms, an aralkyl group having 7 to 20 carbon atoms, and 2 to 20 carbon atoms in the case of having a substituent. The heterocyclic group containing 20 may, for example, be R in the above formula (I) 61 Or R 62 Illustrated in the description. As the R in the above formula (III) 86 , R 87 , R 88 And R 89 The halogen atom to be represented, an alkyl group having 1 to 40 carbon atoms, an aryl group having 6 to 20 carbon atoms, an aralkyl group having 7 to 20 carbon atoms, and 2 to 20 carbon atoms in the case of having a substituent. The heterocyclic group containing 20 may, for example, be R in the above formula (I) 61 Or R 62 Illustrated in the description. As the R in the above formula (IV) 91 , R 92 , R 93 And R 94 The halogen atom to be represented, an alkyl group having 1 to 40 carbon atoms, an aryl group having 6 to 20 carbon atoms, an aralkyl group having 7 to 20 carbon atoms, and 2 to 20 carbon atoms in the case of having a substituent. The heterocyclic group containing 20 may, for example, be R in the above formula (I) 61 Or R 62 Illustrated in the description. In the compound represented by the above formula (II), ring A is preferred. 2 For benzene, naphthalene, as R 81 , R 82 , R 83 , R 84 And R 85 The group other than the hydrogen atom is preferably an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 10 carbon atoms, an aralkyl group having 7 to 12 carbon atoms, and 2 to 10 carbon atoms. Containing a heterocyclic group, especially preferably R 81 ~R 85 Any one of them is an alkyl group having 1 to 4 carbon atoms or a heterocyclic group having 2 to 10 carbon atoms, R 62 It is preferred to have the following substituents in the form of -CO-O-.・Alkyl group having 1 to 8 carbon atoms (especially methyl, ethyl, propyl, isopropyl, butyl, t-butyl, tert-butyl, isobutyl, pentyl, 1-methyl) Butyl, 2-methylbutyl, 3-methylbutyl, 1-ethylpropyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethyl (propyl group) - an aralkyl group having 7 to 10 carbon atoms (especially a benzyl group) - an alkenyl group having 2 to 6 carbon atoms (particularly a propylene-1-yl group) represented by the above formula (III) Among the compounds, ring A is preferred. 2 For benzene, naphthalene, as R 86 , R 87 , R 88 And R 89 The group other than the hydrogen atom is preferably an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 10 carbon atoms, an aralkyl group having 7 to 12 carbon atoms, and 2 to 10 carbon atoms. a heterocyclic group-containing group, particularly preferably an alkyl group having 1 to 8 carbon atoms or a heterocyclic group having 2 to 10 carbon atoms, R 62 It is preferred to have the following substituents in the form of -CO-O-.・Alkyl group having 1 to 8 carbon atoms (especially methyl, ethyl, propyl, isopropyl, butyl, t-butyl, tert-butyl, isobutyl, pentyl, 1-methyl) Butyl, 2-methylbutyl, 3-methylbutyl, 1-ethylpropyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethyl Propyl group) aralkyl group having 7 to 10 carbon atoms (especially benzyl group) ・Alkenyl group having 2 to 6 carbon atoms (especially propylene-1-yl group) 11 In the above formula (1), Y 10 Preferred is a sulfur atom, an aromatic cyclic hydrocarbon group having 6 to 25 carbon atoms, a heterocyclic group having 2 to 21 carbon atoms, and Z. 1 And Z 2 It is preferably a direct bond, -CO-O-, -O-CO-, or an aliphatic hydrocarbon group having 1 to 20 carbon atoms or 6 to 10 aromatic hydrocarbon groups in the case of having a substituent, and particularly preferably There is also an aliphatic hydrocarbon group having 1 to 8 carbon atoms in the case of a substituent. Among the compounds represented by the above formula (IV), as R 91 , R 92 , R 93 And R 94 The group other than the hydrogen atom is preferably an aryl group having 6 to 10 carbon atoms, an aralkyl group having 7 to 12 carbon atoms, or a heterocyclic group having 2 to 10 carbon atoms, and particularly preferably R. 91 ~R 94 Any one of them is an alkyl group having 1 to 4 carbon atoms or a heterocyclic group having 2 to 10 carbon atoms. R 62 It is preferred to have the following substituents in the form of -CO-O-.・Alkyl group having 1 to 8 carbon atoms (especially methyl, ethyl, propyl, isopropyl, butyl, t-butyl, tert-butyl, isobutyl, pentyl, 1-methyl) Butyl, 2-methylbutyl, 3-methylbutyl, 1-ethylpropyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethyl a propyl group, an aralkyl group having 7 to 10 carbon atoms (particularly a benzyl group), an alkenyl group having 2 to 6 carbon atoms (particularly, a propen-1-yl group) represented by the above formula (IV) Compound = r = 2 and X 3 When it is in the case of the above formula (1), Y 10 Preferably, it is a sulfur atom, a divalent alkyl group having 1 to 20 carbon atoms, a divalent carbon-containing aromatic hydrocarbon group having 6 to 25 carbon atoms, a divalent carbon group having 2 to 21 carbon atoms, and 2 , 4,8,10-tetraoxaspiro[5,5]undecane, particularly preferably a divalent alkyl group having 1 to 15 carbon atoms and a divalent carbon group having 6 to 15 carbon atoms , 2,4,8,10-tetraoxaspiro[5,5]undecane, Z 1 And Z 2 It is preferably a direct bond, -CO-O-, -O-CO- or a divalent aliphatic hydrocarbon group having 1 to 20 carbon atoms and a divalent carbon number of 6 to 10 in the case of having a substituent. The aromatic hydrocarbon group is particularly preferably a divalent aliphatic hydrocarbon group having 1 to 8 carbon atoms in the case of having a substituent. In the compound represented by the above formula (IV), r = 3 and X 3 When it is in the case of the above formula (2), Y 11 Preferably, it is a trivalent carbon atom having 1 to 20 carbon atoms, a trivalent carbon atom having 6 to 10 carbon atoms, a trivalent carbon atom having 7 to 12 carbon atoms, and a trivalent carbon atom number of 2 The heterocyclic group of ～10 is particularly preferably a trivalent carbon atom having 1 to 8 carbon atoms, a trivalent carbon group having 6 to 9 carbon atoms, and a trivalent carbon atom having 1 to 6 carbon atoms. Base, Z 1 ,Z 2 And Z 3 It is preferably a direct bond, -CO-O-, -O-CO- or a divalent aliphatic hydrocarbon group having 1 to 20 carbon atoms and a divalent carbon number of 6 to 10 in the case of having a substituent. The aromatic hydrocarbon group is particularly preferably a divalent aliphatic hydrocarbon group having 1 to 8 carbon atoms in the case of having a substituent. In the compound represented by the above formula (IV), r = 4 and X 3 When it is in the case of the above formula (3), Y 12 Preferably, it is a tetravalent alkyl group having 1 to 20 carbon atoms, a tetravalent aryl group having 6 to 10 carbon atoms, a tetravalent aralkyl group having 7 to 12 carbon atoms, and a tetravalent carbon atom number of 2 a heterocyclic group of ～10, particularly preferably a tetravalent alkyl group having 1 to 8 carbon atoms, a tetravalent aryl group having 6 to 9 carbon atoms, and a tetravalent carbon atom having 1 to 6 carbon atoms Base, Z 1 ~Z 4 It is preferably a direct bond, -CO-O-, -O-CO- or a divalent aliphatic hydrocarbon group having 1 to 20 carbon atoms and a divalent carbon number of 6 to 10 in the case of having a substituent. The aromatic hydrocarbon group is particularly preferably a divalent aliphatic hydrocarbon group having 1 to 8 carbon atoms in the case of having a substituent. In the compound represented by the above formula (IV), r = 5 and X 3 In the case of the above formula (4), Y 13 Preferably, it is a 5-valent alkyl group having 1 to 20 carbon atoms, a 5-valent aryl group having 6 to 10 carbon atoms, a 5-valent aralkyl group having 7 to 12 carbon atoms, and a 5-valent carbon atom number 2. The heterocyclic group of ～10 is particularly preferably a 5-valent alkyl group having 1 to 8 carbon atoms, a 5-valent aryl group having 6 to 9 carbon atoms, and a 5-valent heterocyclic group having 1 to 6 carbon atoms. Base, Z 1 ~Z 5 It is preferably a direct bond, -CO-O-, -O-CO- or a divalent aliphatic hydrocarbon group having 1 to 20 carbon atoms and a divalent carbon number of 6 to 10 in the case of having a substituent. The aromatic hydrocarbon group is particularly preferably a divalent aliphatic hydrocarbon group having 1 to 8 carbon atoms in the case of having a substituent. In the compound represented by the above formula (IV), r = 6 and X 3 When it is in the case of the above formula (5), Y 14 Preferably, it is a 6-valent alkyl group having 1 to 20 carbon atoms, a 6-valent aryl group having 6 to 10 carbon atoms, a 6-valent aralkyl group having 7 to 12 carbon atoms, and a hexavalent carbon atom number of 2 a heterocyclic group of ～10, particularly preferably a 6-valent alkyl group having 1 to 8 carbon atoms, a 6-valent aryl group having 6 to 9 carbon atoms, and a 6-valent heterocyclic group having 1 to 6 carbon atoms Base, Z 1 ~Z 6 It is preferably a direct bond, -CO-O-, -O-CO- or a divalent aliphatic hydrocarbon group having 1 to 20 carbon atoms and a divalent carbon number of 6 to 10 in the case of having a substituent. The aromatic hydrocarbon group is particularly preferably a divalent aliphatic hydrocarbon group having 1 to 8 carbon atoms in the case of having a substituent. The heterocyclic group having 2 to 10 carbon atoms may, for example, be a heterocyclic group having 2 to 35 carbon atoms and a heterocyclic group having 1 to 10 carbon atoms in the exemplified compound. In the photosensitive composition of the present invention, the content of the latent additive (A) is preferably 0.001 to 20% by mass, more preferably 0.005 to 5% by mass. <Polymer (B)> The polymer (B) used in the photosensitive composition of the present invention is a polymer having an ethylenically unsaturated bond and a hydrophilic group in one molecule and having a double bond equivalent of 200 to 1,000. There is no particular limitation, and the previous user can be used. Examples of the hydrophilic group of the polymer (B) include a hydroxyl group, a thiol group, a carboxyl group, a sulfo group, an amine group, a decylamino group or a salt thereof, and a hydroxyl group and a carboxyl group due to the polymer (B) to a base. It is preferred that the solubility becomes high. The preferred functional group equivalent of the hydrophilic group in the polymer (B) (the mass of the polymer containing 1 equivalent of the hydrophilic group) is 50 to 10,000. The polymer (B) preferably has a mass average molecular weight of from 3,000 to 50,000. Examples of the polymer (B) include (meth)acrylic acid, α-chloroacrylic acid, itaconic acid, maleic acid, citraconic acid, fumaric acid, bicycloheptene dicarboxylic acid, crotonic acid, and methacrylic acid. , vinyl acetate, allyl acetic acid, cinnamic acid, sorbic acid, mesaconic acid, succinic acid mono [2-(methyl) propylene methoxyethyl] ester, phthalic acid mono [2-(methyl) a mono(meth)acrylate of a polymer having a carboxyl group and a hydroxyl group at both terminals, such as a propylene methoxyethyl ester, an ω-carboxypolycaprolactone mono(meth)acrylate, or a (meth)acrylic acid hydroxyl group Ethyl ester-maleate, hydroxypropyl (meth)acrylate-maleate, dicyclopentadiene-maleate or having one carboxyl group and two or more (meth) acrylonitrile groups Unsaturated polybasic acid such as polyfunctional (meth) acrylate; phenol and/or cresol novolac epoxy resin; novolac epoxy resin having biphenyl skeleton, naphthalene skeleton, bisphenol A novolac epoxy compound, A novolac type epoxy compound such as a cyclopentadiene novolak type epoxy compound; a polyphenylmethane type epoxy resin having a polyfunctional epoxy group, which is insufficient A monobasic acid is applied to a resin obtained by reacting an epoxy group of an epoxy resin such as an epoxy compound represented by the following formula (V), and an unsaturated monobasic acid is applied to an epoxy compound represented by the following formula (V). a resin obtained by the action of an epoxy group of an epoxy resin and further a polybasic acid anhydride; a hydroxyl group-containing polyfunctional acrylate such as pentaerythritol triacrylate or dipentaerythritol pentaacrylate, and succinic anhydride, phthalic anhydride, tetrahydrogen A polyfunctional acrylate having an acid value of a reactant of a dibasic acid anhydride such as phthalic anhydride. [Chemistry 16] (where, X 41 The direct-bonding, the alkylene group having 1 to 4 carbon atoms in the case of having a substituent, and the alicyclic hydrocarbon group having 3 to 20 carbon atoms in the case of having a substituent, -O-, -S -, -SO 2- , -SS-, -SO-, -CO-, -OCO- or a substituent represented by the above (1-1) to (1-3), R 41 , R 42 , R 43 And R 44 Each of the hydrogen atoms independently represents an alkyl group having 1 to 5 carbon atoms in the case of having a substituent, and an alkoxy group having 1 to 8 carbon atoms in the case of having a substituent, and a substituent having a substituent. In the case of an alkenyl group having 2 to 5 carbon atoms or a halogen atom, and n is an integer of 0 to 10), the polymer (B) has a unit selected from the group consisting of the following formula (VI-1) and The polymer represented by the general formula (VI-2), the unit represented by the following general formula (VI-3), and the polymer represented by the following general formula (VI-4) are developed. It is preferred because it has a high degree of heat or heat resistance. [化17] (in the formula, Y 1 Represents a hydrogen atom or a methyl group, X 4 For the 2-valent bond group, R 1 And an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms or an aralkyl group having 7 to 30 carbon atoms, wherein a hydrogen atom of the alkyl group, the aryl group and the aralkyl group is present via a halogen atom; In the case of a hydroxyl group, a nitro group or an epoxy group, the methylene group in the alkyl group and the aralkyl group is also present via -O-, -S-, -CO-, -COO-, -OCO- or -NH- Or the combination of the combination of these combinations, R 2 , R 3 And R 4 Each of which is independently a hydrogen atom or a methyl group) as the X in the above formula (VI-2) 4 The divalent bond group represented by the above is not particularly limited, and a structure represented by the above formula (1) is preferably used. The composition ratio of the units represented by the above formulas (VI-1) to (VI-4) is (VI-1): (VI-2): (VI-3): (VI-4) = 0 to 0.65: 0.1 to 1: 0.001 to 2: 0 to 1, and any arrangement such as random copolymerization, block copolymerization, or graft copolymerization may be employed. In the polymer (B) having any one or more selected from the group consisting of the units represented by the above formulas (VI-1), (VI-2), (VI-3) and (VI-4), it is preferably The following. R 1 It is preferably an alkyl group having 1 to 8 carbon atoms and an aralkyl group having 7 to 30 carbon atoms, more preferably an alkyl group having 1 to 4 carbon atoms. About X 4 When the bond group of the divalent bond is a structure represented by the following formula (1), Y 10 It is preferably an alkylene group having 1 to 15 carbon atoms, more preferably an alkylene group having 7 to 15 carbon atoms or a substituent having a carboxyl group having a cycloalkyl group. The hydrogen atom in the alkylene group is also substituted by a halogen atom, a hydroxyl group or a nitro atom, and the methylene group of the chain alkyl group in the alkyl group is also present via -O-, -S -, -CO-, -COO-, -OCO- or -NH- group substitution. Z 1 And Z 2 It is preferably a direct bond. The acid value of the above polymer (B) is preferably from 10 to 200 mg/KOH, more preferably from 30 to 150 mg/KOH. If the acid value is less than 10 mg/KOH, the alkali developability may not be sufficiently obtained. If it is more than 200 mg/KOH, it may be difficult to produce the polymer (B). This time, the acid value refers to those obtained according to JIS K 0050 and JIS K 0211. The double bond equivalent of the above polymer (B) must be from 200 to 1,000, preferably from 300 to 500. When the double bond equivalent in the polymer (B) is less than 200, production is difficult, and if it is more than 1,000, durability cannot be sufficiently obtained. The weight average molecular weight of each double bond in the double bond equivalent polymer (B) can be calculated by the following formula. Double bond equivalent = (total mass of polymer (B)) / {(mole of polymer (B)) x (number of ethylenically unsaturated groups in polymer (B))} in the present invention In the photosensitive composition, the content of the polymer (B) is preferably from 1 to 20% by mass, particularly preferably from 5 to 15% by mass, based on the photosensitive composition of the present invention. When the content of the polymer (B) is less than 1% by mass, the resolution and durability may not be sufficiently obtained. When the content is more than 20% by mass, the alkali developability and the curability may not be sufficiently obtained. <Acrylic monomer (C)> The acrylic monomer (C) used in the photosensitive composition of the present invention is not particularly limited, and a known one can be used, and examples thereof include 2-hydroxyethyl acrylate. 2-hydroxypropyl acrylate, isobutyl acrylate, n-octyl acrylate, isooctyl acrylate, isodecyl acrylate, stearyl acrylate, methoxyethyl acrylate, dimethylaminoethyl acrylate, acrylic acid Zinc, 1,6-hexanediol diacrylate, trimethylolpropane triacrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl methacrylate, butyl methacrylate, methyl Tert-butyl acrylate, cyclohexyl methacrylate, trimethylolpropane trimethacrylate, dipentaerythritol pentaacrylate, dipentaerythritol hexaacrylate, pentaerythritol tetraacrylate, pentaerythritol triacrylate, bisphenol A Glycidyl ether (meth) acrylate, bisphenol F diglycidyl ether (meth) acrylate, bisphenol Z diglycidyl ether (meth) acrylate, tripropylene glycol di (meth) acrylate, and the like. Among the above, a monomer having a plurality of unsaturated bonds is preferred because it can improve heat resistance. In the photosensitive composition of the present invention, the content of the acrylic monomer (C) is preferably from 1 to 20% by mass, particularly preferably from 5 to 15% by mass, based on the photosensitive composition of the present invention. When the content of the acrylic monomer (C) is less than 1% by mass, the curing property and the alkali developability may not be sufficiently obtained. When the content is more than 20% by mass, the resolution and durability may not be sufficiently obtained. <Photoradical polymerization initiator (D)> The photoradical polymerization initiator (D) used in the photosensitive composition of the present invention is a compound which can initiate polymerization by radical irradiation by light irradiation. For example, an acetophenone-based compound, a benzoin-based compound, a benzophenone-based compound, a 9-oxosulfide &#134079; a ketone compound such as a quinone compound, an anthraquinone compound, and the like are preferable. Examples of the acetophenone-based compound include diethoxyacetophenone, 2-hydroxy-2-methyl-1-phenylpropan-1-one, and 4'-isopropyl-2-hydroxy-2. -methylpropiophenone, 2-hydroxymethyl-2-methylpropiophenone, 2,2-dimethoxy-1,2-diphenylethane-1-one, p-dimethylaminophenyl Ketone, p-tert-butyldichloroacetophenone, p-tert-butyltrichloroacetophenone, p-azidobenzylidene acetophenone, 1-hydroxycyclohexyl phenyl ketone, 2-methyl-1 -[4-(methylthio)phenyl]-2-&#134156;phenylpropanone-1,2-benzyl-2-dimethylamino-1-(4-&#134156; phenyl benzene Butanone-1, benzoin, benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, benzoin n-butyl ether, benzoin isobutyl ether, 1-[4-(2-hydroxyethoxy)-phenyl]- 2-hydroxy-2-methyl-1-propan-1-one and the like. Examples of the benzoin-based compound include benzoin, fentanyl and the like. Examples of the benzophenone-based compound include benzophenone, methyl ortho-benzoylbenzoate, mischrone, and 4,4'-bisdiethylaminobenzophenone. 4'-Dichlorobenzophenone, 4-benzylidene-4'-methyldiphenyl sulfide, and the like. As the 9-oxosulfur &#134079; □-based compound, 9-oxosulfur &#134079; □, 2-methyl-9-oxosulfide &#134079; □, 2-ethyl-9-oxosulfuric acid &#134079;□, 2-Chloro-9-oxosulfur &#134079;□, 2-isopropyl-9-oxosulfide&#134079;□, 2,4-diethyl-9-oxosulfide&# 134079; □ and so on. The oxime compound is preferably a compound represented by the following formula (VII) or (VIII) in terms of sensitivity and heat resistance. [化18] (where, R 51 And R 52 Each of the hydrogen atom and the cyano group independently represents an alkyl group having 1 to 20 carbon atoms in the case of having a substituent, and an aryl group having 6 to 30 carbon atoms in the case of having a substituent, and also having a substitution. In the case of a group, an aralkyl group having 7 to 30 carbon atoms or a heterocyclic group having 2 to 20 carbon atoms in the case of having a substituent, R 53 And R 54 Respectively represent a halogen atom, a nitro group, a cyano group, a hydroxyl group, a carboxyl group, and R, respectively. 55 OR 56 , SR 57 NR 58 R 59 , COR 60 , SOR 61 , SO 2 R 62 Or CONR 63 R 64 ,R 53 And R 54 There are cases where bonds are formed to form a ring, R 55 , R 56 , R 57 , R 58 , R 59 , R 60 , R 61 , R 62 , R 63 And R 64 Each of the alkyl groups having 1 to 20 carbon atoms in the case of having a substituent, an aryl group having 6 to 30 carbon atoms in the case of having a substituent, and a carbon atom having a substituent in the case of a substituent are also independently indicated. a 7 to 30 aralkyl group or a heterocyclic group having 2 to 20 carbon atoms in the case of having a substituent, X 5 Indicates oxygen atom, sulfur atom, selenium atom, CR 75 R 76 , CO, NR 77 Or PR 78 , X 6 Represents a single key or CO, indicating R 51 , R 52 , R 55 , R 56 , R 57 , R 58 , R 59 , R 60 , R 65 , R 66 , R 67 And R 68 An alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms or an aralkyl group having 7 to 30 carbon atoms, wherein the methylene group in the alkyl group or the aralkyl group is present via a halogen atom, a case where a nitro group, a cyano group, a hydroxyl group, a carboxyl group or a heterocyclic group is substituted, and there is a case of -O- substitution, R 53 And R 54 There are cases in which a ring is formed independently with any adjacent benzene ring, a represents an integer of 0 to 4, and b represents an integer of 0 to 5) [Chem. 19] (where, R 101 And R 102 Representing R independently 111 OR 111 , COR 111 , SR 111 , CONR 112 R 113 Or CN, R 111 , R 112 And R 113 Each independently represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms, an aralkyl group having 7 to 30 carbon atoms or a heterocyclic group having 2 to 20 carbon atoms. R 111 , R 112 And R 113 The hydrogen atom represented by the group also exists further through R 121 OR 121 , COR 121 , SR 121 NR 122 R 123 , CONR 122 R 123 , -NR 122 -OR 123 -NCOR 122 -OCOR 123 NR 122 COR 121 OCOR 121 COOR 121 , SCOR 121 OCSR 121 , COSR 121 , CSOR 121 , hydroxyl, nitro, CN, halogen atom, or COOR 121 In the case of replacement, R 121 , R 122 And R 123 Each independently represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms, an aralkyl group having 7 to 30 carbon atoms or a heterocyclic group having 2 to 20 carbon atoms. R 121 , R 122 And R 123 The hydrogen atom represented by the group also has a further substitution by a hydroxyl group, a nitro group, a CN, a halogen atom, a hydroxyl group or a carboxyl group, R 111 , R 112 , R 113 , R 121 , R 122 And R 123 The alkyl group of the indicated group also exists via -O-, -S-, -COO-, -OCO-, -NR 124- , -NR 124 COO-, -OCONR 124- , -SCO-, -COS-, -OCS- or -CSO- in the case where the oxygen atoms are not adjacent to each other for 1 to 5 times, R 124 And a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms, an aralkyl group having 7 to 30 carbon atoms or a heterocyclic group having 2 to 20 carbon atoms, R 111 , R 112 , R 113 , R 121 , R 122 , R 123 And R 124 The case where the alkyl group of the group represented is a branched side chain, and a cyclic alkyl group is also present, R 103 And a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms, an aralkyl group having 7 to 30 carbon atoms or a heterocyclic group having 2 to 20 carbon atoms, R 103 Where the alkyl moiety of the group represented is a branched side chain, and a cyclic alkyl group is also present, and 103 With R 107 , R 103 With R 108 , R 104 With R 105 , R 105 With R 106 And R 106 With R 107 There are also cases where the rings are formed together, R 103 The hydrogen atom represented by the group also exists further through R 121 OR 121 , COR 121 , SR 121 NR 122 R 123 , CONR 122 R 123 , -NR 122 -OR 123 -NCOR 122 -OCOR 123 NR 122 COR 121 OCOR 121 COOR 121 , SCOR 121 OCSR 121 , COSR 121 , CSOR 121 , hydroxyl, nitro, CN, halogen atom, or COOR 121 In the case of replacement, R 104 , R 105 , R 106 And R 107 Representing R independently 111 OR 111 , SR 111 , COR 114 , CONR 151 R 116 NR 112 COR 111 OCOR 111 COOR 114 , SCOR 111 OCSR 111 , COSR 114 , CSOR 111 , hydroxyl, CN or halogen atom, R 104 With R 105 , R 105 With R 106 And R 106 With R 107 There are also cases where the rings are formed together, R 114 , R 115 And R 116 Represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, R 108 Represents R 111 OR 111 , SR 111 , COR 111 , CONR 112 R 113 NR 112 COR 111 OCOR 111 COOR 111 , SCOR 111 OCSR 111 , COSR 111 , CSOR 111 , hydroxy, CN or a halogen atom, w represents 0 or 1) As another photoradical polymerization initiator (D), 2,4,6-trimethylbenzimidyldiphenylphosphine oxide, bis ( Cyclopentadienyl)-bis[2,6-difluoro-3-(pyrrol-1-yl)]titanium or the like. These photo-radical polymerization initiators (D) can be used in combination of one or two or more kinds depending on the desired properties. The photoradical polymerization initiator (D) as described above is preferably from 0.01 to 10% by mass, particularly preferably from 0.1 to 1% by mass, based on the photosensitive composition of the present invention. When the content of the photoradical polymerization initiator is less than 0.01% by mass, the curing due to exposure may be insufficient. If it is more than 10% by mass, the photoradical polymerization initiator may be combined in a photosensitive composition. The situation of precipitation. Further, a coloring agent may be added to the photosensitive composition to prepare a colored photosensitive composition. The cured product of the colored photosensitive composition is suitably used as a color filter. In the coloring photosensitive composition, the amount of the colorant added is preferably from 0.01 to 50% by mass, more preferably from 0.1 to 30% by mass. When the amount of the coloring agent added is less than 0.01% by mass, the color tone is insufficient, and when it is more than 50% by mass, the coloring agent is precipitated in the photosensitive composition. As the coloring agent, a dye or a pigment can be mentioned. The dye is not particularly limited as long as it is a compound having an absorption at 380 to 1200 nm, and examples thereof include an azo compound, an anthraquinone compound, an indigo compound, a triarylmethane compound, a &lt;134079; Compound, acridine compound, hydrazine compound, thiazole compound, naphthol compound, quinoline compound, nitro compound, indamine compound, 㗁&#134116; compound, phthalocyanine compound, cyanine compound, diimmonium compound, Cyanovinyl compound, dicyanyl compound, rosin compound, hydrazine compound, polyenolamine compound, coumarin compound, strontium sulphate compound, ketoxime compound, spiropyran compound, snail &#134116; compound, merocyanine compound, oxonium compound, styryl compound, pyrylium compound, rhodanine compound, oxazolinone compound, phthalimide compound, porphyrin compound, naphthalene Anthraquinone compound, azaindole compound, porphyrin compound, azaporphyrin compound, pyrrolemethylene compound, quinacridone compound, pyrrole Pyrrolidinone compound, indigo compound, acridine compound, &#134116; compound, methylimine compound, aniline compound, quinacridone compound, quinophthalone compound, quinone compound, ruthenium complex, ruthenium complex Dyes such as substances, etc., may be used in combination of plural kinds. As the pigment, an inorganic pigment or an organic pigment can be used, and for example, a nitroso compound, a nitro compound, an azo compound, a diazo compound, a &lt;134079;□ compound, a quinoline compound, an anthraquinone compound, and a coumarin can be used. a compound, a phthalocyanine compound, an isoindolinone compound, an isoporphyrin compound, a quinacridone compound, an indolinone compound, a purple ring ketone compound, an anthraquinone compound, a pyrrolopyrroledione compound, a thioindigo compound,二㗁&#134116; compound, triphenylmethane compound, quinophthalone compound, naphthalenetetracarboxylic acid; azo dye, metal complex of cyanine dye; lake pigment; by furnace method, channel method, heat Carbon black obtained by the analysis method, or carbon black such as acetylene black, ketjen black or lamp black; if the carbon black is adjusted and coated with an epoxy resin, the carbon black is dispersed by a resin in advance in a solvent. For those who have been adsorbed with 20 to 200 mg/g of resin and have an acidic or alkaline surface treatment of the above carbon black, the average particle size is 8 nm or more and the DBP oil absorption is 90 ml/100 g or less. 950 ° C CO and CO in the volatile components 2 Calculate the total oxygen content per 100 m of surface area of carbon black 2 Medium 9 mg or more; graphite, graphitized carbon black, activated carbon, carbon fiber, carbon nanotube, spiral carbon fiber, nano carbon angle, carbon aerogel, fullerene; aniline black, pigment black 7, titanium black Hydrophobic resin, chrome oxide green, milorie blue, cobalt green, cobalt blue, manganese, ferrocyanide, phosphate green, iron blue, ultramarine blue, sky blue, chrome green, emerald green, lead sulfate, yellow dan Inorganic content or organic pigments such as zinc yellow, iron oxide (red iron oxide (III)), cadmium red, synthetic iron black, brown earth. These pigments may be used singly or in combination of plural kinds. As the above inorganic pigment or organic pigment, commercially available pigments can also be used, and examples thereof include pigment red 1, 2, 3, 9, 10, 14, 17, 22, 23, 31, 38, 41, 48, 49. 88, 90, 97, 112, 119, 122, 123, 144, 149, 166, 168, 169, 170, 171, 177, 179, 180, 184, 185, 192, 200, 202, 209, 215, 216, 217, 220, 223, 224, 226, 227, 228, 240, 254; Pigment Orange 13, 31, 34, 36, 38, 43, 46, 48, 49, 51, 52, 55, 59, 60, 61, 62, 64, 65, 71; pigment yellow 1, 3, 12, 13, 14, 16, 17, 20, 24, 55, 60, 73, 81, 83, 86, 93, 95, 97, 98, 100, 109, 110, 113, 114, 117, 120, 125, 126, 127, 129, 137, 138, 139, 147, 148, 150, 151, 152, 153, 154, 166, 168, 175, 180, 185; Pigment green 7, 10, 36; pigment blue 15, 15:1, 15:2, 15:3, 15:4, 15:5, 15:6, 22, 24, 56, 60, 61, 62, 64; Pigment Violet 1, 19, 23, 27, 29, 30, 32, 37, 40, 50, and the like. Further, by adding a crosslinking agent to the photosensitive composition of the present invention and reacting with the hydrophilic group of the polymer, water resistance and heat resistance can be improved. Examples of the crosslinking agent include a polyoxazoline compound, a carbodiimide compound, an epoxy compound, a polyamine, a polyhydric alcohol, a dicyandiamide derivative, an anthraquinone compound, and a polyfluorene compound.肼, triterpene), aldehydes, methylol compounds, activated vinyl compounds, isocyanate compounds, alkylene carbonate compounds of phenolic compounds, polyvalent metal salts, decane coupling agents, organic titanium, etc. The oxazoline compound and the carbodiimide compound are preferably reacted at a heat drying temperature of from 100 to 120 ° C. Commercially available products can also be used as the above-mentioned crosslinking agent, and examples thereof include Epocros WS-300, WS-500, and WS-700 (manufactured by Nippon Shokubai Co., Ltd.); Carbodilite V-02, V-02-L2, and SV- 02, V-04, V-10, SW-12G, E-02, E-03A, E-05 (manufactured by Nisshinbo Co., Ltd.). Further, a solvent may be added to the photosensitive composition and the coloring photosensitive composition. The solvent is usually a solvent which can dissolve or disperse the above components as needed, for example, methyl ethyl ketone, methyl amyl ketone, diethyl ketone, acetone, methyl isopropyl ketone, methyl meth Ketones such as butyl ketone, cyclohexanone, and 2-heptanone; diethyl ether, dioxane, tetrahydrofuran, 1,2-dimethoxyethane, 1,2-diethoxyethane, dipropylene glycol An ether solvent such as ether; an ester solvent such as methyl acetate, ethyl acetate, n-propyl acetate, isopropyl acetate, n-butyl acetate, cyclohexyl acetate, ethyl lactate, dimethyl succinate or TEXANOL; a cellosolve solvent such as ethylene glycol monomethyl ether or ethylene glycol monoethyl ether; an alcohol solvent such as methanol, ethanol, isopropanol or n-propanol, isobutanol or n-butanol, pentanol or diacetone; Ethylene glycol monomethyl acetate, ethylene glycol monoethyl acetate, propylene glycol-1-monomethyl ether-2-acetate (PGMEA), dipropylene glycol monomethyl ether acetate, acetic acid-3- An ether ester solvent such as methoxybutyl ester, ethoxyethyl propionate, 1-third butoxy-2-propanol, acetic acid-3-methoxybutyl ester or cyclohexanediol acetate; Benzene, toluene, xylene, etc. BT X-based solvent; aliphatic hydrocarbon solvent such as hexane, heptane, octane or cyclohexane; terpene hydrocarbon oil such as turpentine, D-limonene or decene; mineral oil, Swazol #310 (Cosmo Matsuyama Oil) Alkane solvent such as Solvesso #100 (Exxon Chemical Co., Ltd.); halogenated aliphatic hydrocarbon solvent such as carbon tetrachloride, chloroform, trichloroethylene, dichloromethane or 1,2-dichloroethane; Halogenated aromatic hydrocarbon solvent such as chlorobenzene; carbitol solvent, aniline, triethylamine, pyridine, acetic acid, acetonitrile, carbon disulfide, N,N-dimethylformamide, N,N-dimethyl B The indoleamine, the N-methylpyrrolidone, the N-ethylpyrrolidone, the dimethyl hydrazine, the water, etc. may be used alone or in the form of a mixed solvent of two or more. Among these, ketones, ether ester solvents, etc., especially propylene glycol-1-monomethyl ether-2-acetate, cyclohexanone, etc., are initiated by photoreceptor polymerization and photoradical polymerization in photosensitive compositions. The compatibility of the agent is good, so it is preferred. The coloring photosensitive composition may further contain an inorganic compound. Examples of the inorganic compound include metal oxides such as nickel oxide, iron oxide, cerium oxide, titanium oxide, zinc oxide, magnesium oxide, calcium oxide, potassium oxide, cerium oxide, and aluminum oxide; layered clay minerals and Milo Lilan, calcium carbonate, magnesium carbonate, cobalt, manganese, glass powder, mica, talc, kaolin, ferrocyanide, various metal sulfates, sulfides, selenides, aluminum citrate, calcium citrate, hydroxide Aluminum, platinum, gold, silver, copper, etc. When a pigment and/or an inorganic compound is used for the coloring photosensitive composition, a dispersing agent may be added. The dispersing agent can be used arbitrarily as long as it can disperse and stabilize the colored material or the inorganic compound, and a commercially available dispersing agent such as BYK series manufactured by BYK-Chemie Co., Ltd. can be used, and the following dispersing agent is suitably used: a polymer dispersant comprising a polyester, a polyether or a polyurethane having a basic functional group; a nitrogen atom as a basic functional group; and a functional group having a nitrogen atom is an amine and/or a quaternary salt thereof, And the amine value is 1 to 100 mgKOH / g. Further, if necessary, the following additives may be added to the coloring photosensitive composition: thermal polymerization such as para-anisole, hydroquinone, catechol, tert-butyl catechol, and thiophene &#134116;Inhibitor;plasticizer; subsequent accelerator; filler; defoamer; leveling agent; surface conditioner; phenolic antioxidant, phosphite antioxidant, thioether antioxidant, etc.; ; dispersing aid; anti-agglomerating agent; catalyst; effect promoter; tackifier and other conventional additives. Further, the properties of the cured product of the colored photosensitive composition of the present invention can be improved by using another organic polymer together with a polymer containing an ethylenically unsaturated bond having the above acid value. Examples of the above organic polymer include polystyrene, polymethyl methacrylate, methyl methacrylate-ethyl acrylate copolymer, poly(meth)acrylic acid, and styrene-(meth)acrylic acid copolymer. , (meth)acrylic acid-methyl methacrylate copolymer, ethylene-vinyl chloride copolymer, ethylene-ethylene copolymer, polyvinyl chloride resin, ABS resin, nylon 6, nylon 66, nylon 12, urethane Ester resin, polycarbonate polyvinyl butyral, cellulose ester, polypropylene decylamine, saturated polyester, phenol resin, phenoxy resin, polyamide amide resin, poly phthalic acid resin, epoxy resin Among these, polystyrene, (meth)acrylic acid-methyl methacrylate copolymer, and epoxy resin are preferable. Further, a chain transfer agent, a sensitizer, a surfactant, a decane coupling agent, melamine or the like may be used in combination with the coloring photosensitive composition. As the chain transfer agent and the sensitizer, a compound containing a sulfur atom is generally used. For example, thioglycolic acid, thiomalic acid, thiosalicylic acid, 2-mercaptopropionic acid, 3-mercaptopropionic acid, 3-mercaptobutyric acid, N-(2-amidinopropyl)glycolamine Acid, 2-mercaptonicotinic acid, 3-[N-(2-mercaptoethyl)amine-methylhydrazine]propionic acid, 3-[N-(2-mercaptoethyl)amino]propionic acid, N-( 3-mercaptopropyl)alanine, 2-mercaptoethanesulfonic acid, 3-mercaptopropanesulfonic acid, 4-mercaptobutanesulfonic acid, dodecyl(4-methylthio)phenyl ether, 2-mercaptoethanol, 3-mercapto-1,2-propanediol, 1-mercapto-2-propanol, 3-mercapto-2-butanol, nonylphenol, 2-mercaptoethylamine, 2-mercaptoimidazole, 2-mercaptobenzimidazole, a mercapto compound such as 2-mercapto-3-hydroxypyridine, 2-mercaptobenzothiazole, thioglycolic acid, trimethylolpropane tris(3-mercaptopropionate), pentaerythritol tetrakis(3-mercaptopropionate), etc. a disulfide compound obtained by oxidation of a mercapto compound, an iodide alkyl compound such as iodoacetic acid, iodopropionic acid, 2-iodoethanol, 2-iodoethanesulfonic acid or 3-iodopropanesulfonic acid, trimethylolpropane tris(III) 3-mercaptoisobutyrate), butanediol bis(3-mercaptoisobutyrate), hexanedithiol, decanedithiol, 1,4-dimethylnonylbenzene, Glycol dithiopropionate, butanediol dithioglycolate, ethylene glycol dithioglycolate, trimethylolpropane trithioglycolate, butanediol dithiopropionate , trimethylolpropane trithiopropionate, trimethylolpropane trithioglycolate, pentaerythritol tetrathiopropionate, pentaerythritol tetrathioglycolate, trishydroxyethyl trithiopropionate An ester, an aliphatic polyfunctional thiol compound such as the following compound No. C1, tris-propionic acid tris(2-hydroxyethyl)isocyanurate, Karenz MT BD1, PE1, NR1, etc. manufactured by Showa Denko. [Chemistry 20] As the above surfactant, a fluorosurfactant such as a perfluoroalkyl phosphate or a perfluoroalkyl carboxylate, an anionic interfacial activity such as an alkali metal salt of a higher fatty acid, an alkanesulfonate or an alkyl sulfate can be used. Agent, cationic surfactant such as higher amine hydrohalide or quaternary ammonium salt, nonionic such as polyethylene glycol alkyl ether, polyethylene glycol fatty acid ester, sorbitan fatty acid ester, fatty acid monoglyceride Surfactants such as surfactants, amphoteric surfactants, and polyoxo-based surfactants may be used in combination. As the decane coupling agent, for example, a decane coupling agent manufactured by Shin-Etsu Chemical Co., Ltd. may be used, and a decane having an isocyanato group, a methacryl fluorenyl group or an epoxy group such as KBE-9007, KBM-502 or KBE-403 is suitably used. Coupling agent. Examples of the melamine compound include an active methylol group in a nitrogen compound such as (poly)methylol melamine, (poly)hydroxymethyl glycoluril, (poly)hydroxymethylphenylguanamine or (poly)hydroxymethylurea. (CH 2 All or a portion (at least 2) of the OH group is a compound obtained by alkyl etherification. Here, examples of the alkyl group constituting the alkyl ether include a methyl group, an ethyl group, and a butyl group, which may be the same or different from each other. Further, the methylol group which is not alkyl etherified has a self-condensation in one molecule, and there is a case where an oligomer component is formed by condensation between two molecules. Specifically, hexamethoxymethyl melamine, hexabutoxymethyl melamine, tetramethoxymethyl glycoluril, tetrabutoxymethyl glycoluril or the like can be used. Among these, melamine which is alkyl etherified, such as hexamethoxymethyl melamine or hexabutoxymethyl melamine, is preferable. The photosensitive composition and the coloring photosensitive composition can be known by a spin coater, a roll coater, a bar coater, a die coater, a curtain coater, various printing, immersion, and the like. The method is applied to a support substrate such as soda lime glass, quartz glass, semiconductor substrate, metal, paper or plastic. Further, it may be temporarily applied to a support substrate such as a film and then transferred to another support substrate, and the application method is not limited. Further, as a light source for the active energy ray used for curing the photosensitive composition and the colored photosensitive composition, those emitting light having a wavelength of 300 to 450 nm can be used, for example, ultrahigh pressure mercury, mercury vapor arc, carbon can be used. Arc, arc, etc. Further, by using laser light for an exposure light source and directly forming an image based on digital information such as a computer without using a mask, direct laser writing directly realizes productivity improvement and also realizes image understanding or position. It is useful to improve the accuracy and the like. As the laser light, it is suitable to use light of a wavelength of 340 to 430 nm, and it is also possible to emit visible light by using an argon ion laser, a krypton laser, a YAG laser, and a semiconductor laser. The light in the infrared area. In the case of using such lasers, a sensitizing dye that absorbs visible light to the relevant region of the infrared is added. The photosensitive composition and the colored photosensitive composition of the present invention may also be patterned by a double patterning process in which the two photosensitive compositions or the colored photosensitive composition are patterned twice. The photosensitive composition and the coloring photosensitive composition of the present invention can be temporarily cured by irradiation with the above-mentioned active energy ray, and further cured by heating. Further, it is also possible to form a pattern by heating after being cured and developed by irradiation with the above-mentioned active energy ray. The photosensitive composition and the colored photosensitive composition (or a cured product thereof) can be used for a photocurable paint, a varnish, a photocurable adhesive, a printed circuit board, a color television, a PC (Personal Computer) monitor, Color filter in color display liquid crystal display panel such as portable information terminal, digital camera, color filter of CCD (Charge Coupled Device) image sensor, optical spacer, black column spacer Electrode material for plasma display panel, touch panel, touch sensor, powder coating, printing ink, printing plate, adhesive, dental composition, photo-forming resin, gel coating, electronics Learning photoresist, plating resist, etching resist, liquid and dry film, solder resist, color filter for various display purposes or for plasma display panel, electroluminescence a display device, a resist for forming a structure in a manufacturing process of an LCD (Liquid Crystal Display), a composition for encapsulating electrical and electronic components, a solder resist, a magnetic recording material, and a micro Small mechanical parts, waveguides, optical switches, plating masks, etching masks, color test systems, fiberglass cable coatings, templates for screen printing, materials used to fabricate three-dimensional objects by stereolithography, Materials for image recording, image recording materials, fine electronic circuits, decolorizing materials, decolorizing materials for image recording materials, decolorizing materials for image recording materials using microcapsules, photoresist materials for printed wiring boards, UV And various uses such as a photoresist material for a visible light laser direct image system, a photoresist material for forming a dielectric layer in a successive layer of a printed circuit board, a photoresist for 3D mounting, or a protective film. Special restrictions. The photosensitive composition of the present invention can be used for a transparent conductive film, a reflective film, a polarizing plate, a protective film, etc., and can be used as a transparent laminate, which is laminated by sequentially coating the above substrate on a transparent substrate. Each layer is irradiated with active light by a mask having a predetermined pattern shape, and the exposed film is developed by a developing solution, and the developed film is heated. For example, a transparent film layer containing a composite oxide of indium oxide and cerium oxide and a metal thin film layer may be alternately formed on a transparent substrate. A photosensitive composition containing the compound of the present invention as a latent additive may be used in each of the above layers, and the photosensitive composition may be used in any one or more layers. Further, the transparent laminate is suitably used for a display device. The coloring photosensitive composition is used for the purpose of forming a pixel of a color filter, and is particularly useful as a photosensitive composition for forming a color filter for a display device for an image display device such as a liquid crystal display panel. . The color filter of the display device described above is preferably formed by (1) forming a coating film of the coloring photosensitive composition on a substrate; (2) masking a mask having a predetermined pattern shape. The coating film irradiates the active light; (3) develops the exposed film by the developing solution; and (4) heats the film after development. Further, the coloring photosensitive composition of the present invention is also useful as a coloring photosensitive composition which does not have an inkjet method of a developing step. As the mask, a multi-step mask such as a halftone mask or a gray scale mask can also be used. EXAMPLES Hereinafter, the present invention will be described in more detail by way of examples, but the present invention is not limited to the examples and the like. [Production Example 1] Preparation of Polymer B-3 To a reaction vessel, 142 g of glycidyl methacrylate, 8.3 g of styrene, 3.5 g of benzyl methacrylate, 1.0 g of azobisisobutyronitrile, and PGMEA 38 were added. 5 g, stirred at 90 ° C for 9 hours. Thereafter, the reaction liquid was cooled to room temperature, and 150 g of PGMEA, 72 g of acrylic acid and 0.24 g of tetra-n-butylammonium bromide were added, and the mixture was stirred at 120 ° C for 4 hours. Further, 99.6 g of tetrahydrophthalic anhydride was added, and the mixture was stirred at 100 ° C for 4 hours, and after stirring at 60 ° C for 6 hours, 136.5 g of PGMEA was added to obtain a polymer B-3 of the target in the form of a PGMEA solution ( Mw = 22,000, Mn = 6000, and acid value (solid content) 101 mgKOH/g). [Production Example 2] Preparation of Polymer B-4 1,1-bis(4-(2,3-epoxypropoxy)phenyl)indan 184 g, acrylic acid 58 g, 2 were added to the reaction vessel. 0.26 g of 6-di-t-butyl-p-cresol, 0.11 g of tetra-n-butylammonium bromide and 105 g of PGMEA were stirred at 120 ° C for 16 hours. Thereafter, the reaction liquid was cooled to room temperature, and 160 g of PGMEA, 59 g of biphenyltetracarboxylic dianhydride, and 0.24 g of tetra-n-butylammonium bromide were added, and the mixture was stirred at 120 ° C for 4 hours. Further, 20 g of tetrahydrophthalic anhydride was added, and the mixture was stirred at 120 ° C for 4 hours, at 100 ° C for 3 hours, at 80 ° C for 4 hours, at 60 ° C for 6 hours, and at 40 ° C for 4 hours. After 11 hours, PGMEA 128 g was added to obtain a polymer B-4 (Mw = 5000, Mn = 2100, acid value (solid content) 92.7 mgKOH/g) in the form of a PGMEA solution. [Examples 1 to 11 and Comparative Examples 1 and 2] Preparation of photosensitive compositions No. 1 to No. 11 and comparative photosensitive compositions No. 1 to No. 2 were based on [Table 1] and [Table 2]. In the formulation, photosensitive compositions No. 1 to No. 11 and comparative photosensitive compositions No. 1 to No. 2 were prepared. Further, the numerical values in [Table 1] and [Table 2] are parts by mass. [Table 1] [Table 2] A-1 to A-4 in [Table 1] and [Table 2] represent the following latent additives. [Chem. 21] [化22] [化23] [Chem. 24] The symbols B-1 to B-4, B'-1, C-1 to C-2, D-1 to D-3, E-1 and F-1 in [Table 1] and [Table 2] respectively indicate The following compounds. B-1: SPC-1000 (acrylic resin manufactured by Showa Denko Co., Ltd.; weight average molecular weight 31980, double bond equivalent: 900); B-2: SPC-3000 (acrylic resin manufactured by Showa Denko Co., Ltd.; weight average molecular weight 7610, Double bond equivalent 340); B-3: obtained in Production Example 1 (weight average molecular weight 22000, double bond equivalent 330); B-4: obtained in Production Example 2 (weight average molecular weight 5600, double bond equivalent 434 B'-1: SPC-2000 (acrylic resin manufactured by Showa Denko Co., Ltd.; weight average molecular weight 17500, double bond equivalent 0); C-1: ARONIX M450 (acrylic monomer manufactured by Toagosei Co., Ltd.); -2: Kayarad DPHA (multifunctional acrylate; manufactured by Nippon Kayaku Co., Ltd.); D-1: NCI-930 (manufactured by ADEKA); D-2: IRGACURE-OXE01 (manufactured by BASF Corporation); D-3: TR- PBG-304 (manufactured by Trond); E-1: propylene glycol-1-monomethyl ether-2-acetate; F-1: blue pigment dispersion (using 15 parts by mass of CI Pigment Blue 15:6 as coloring) Agent, 12.5 parts by mass (solid content concentration 40% by mass) of BYK161 (manufactured by BYK-Chemie (BYK) Co., Ltd.) as a dispersing agent, 72.5 parts by mass of propylene glycol monomethyl The ether acetate was used as a solvent and was processed by a bead mill to prepare the product.) [Evaluation Examples 1-1 to 1-11 and Comparative Evaluation Examples 1-1 to 1-2] Evaluation of heat resistance by baking The photosensitive compositions No. 1 to No. 2 prepared in the photosensitive compositions No. 1 to No. 11 and Comparative Examples 1 and 2 prepared in Examples 1 to 11 were respectively 410 rpm × 7 sec. The conditions were applied to a glass substrate and dried by a hot plate (90 ° C, 90 sec). Exposure of the obtained coating film using an ultra-high pressure mercury lamp (40 mJ/cm 2 ). The exposed coating film was fired at 230 ° C × 90 minutes, and the transmittance of the coated film after firing at 400 nm was measured. The results are shown in [Table 3]. [table 3] [Evaluation Examples 2-1 to 2-11 and Comparative Evaluation Examples 2-1 to 2-2] Evaluation of Solvent Resistance The photosensitive compositions No. 1 to No. 11 and Comparative Examples obtained in Examples 1 to 10 were compared. The comparative photosensitive compositions No. 1 to No. 2 obtained in 1 to 2 were applied to a glass substrate under conditions of 410 rpm × 7 seconds, and dried by a hot plate (90 ° C, 90 seconds). Exposure of the obtained coating film using an ultra-high pressure mercury lamp (40 mJ/cm 2 After that, it was immersed in cyclohexanone, PGMEA, N-methylpyrrolidone, and N-ethylpyrrolidone for 30 minutes, respectively. Thereafter, it was washed and dried with ion-exchanged water, and the film thickness before and after the immersion test for each solvent was examined. The swelling ratio (%) = (film thickness after the test - film thickness before the test) / film thickness before the test × 100, when the swelling ratio is 0 to less than 2%, it is set to A, and 2% to less The case of 8% is set to B, the case where 8% or more is set to C, and the case where the film thickness after the test is decreased before the test is set to D. The results are shown in [Table 4]. [Table 4] According to the above results, the photosensitive composition of the present invention can maintain a state in which the transparency after firing is high, that is, it has high heat resistance and is excellent in solvent resistance. [Industrial Applicability] According to the present invention, it is possible to provide a photosensitive composition which forms a cured product having high heat resistance and solvent resistance.

無no

Claims (3)

一種感光性組合物，其含有潛伏性添加劑(A)、於一分子內具有乙烯性不飽和鍵及親水性基且雙鍵當量為200～1000之聚合物(B)、丙烯酸系單體(C)及光自由基聚合起始劑(D)。A photosensitive composition comprising a latent additive (A), a polymer (B) having an ethylenically unsaturated bond and a hydrophilic group in one molecule and having a double bond equivalent of 200 to 1,000, and an acrylic monomer (C) And a photoradical polymerization initiator (D). 一種硬化方法，其係藉由對如請求項1之感光性組合物照射活性能量線而使其硬化。A hardening method which hardens a photosensitive composition as claimed in claim 1 by irradiating an active energy ray. 一種硬化物，其係如請求項1之感光性組合物之硬化物。A cured product which is a cured product of the photosensitive composition of claim 1.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI814775B (en) * 2018-01-30 2023-09-11 日商納美仕股份有限公司 Resin compositions and hardened products, adhesives, semiconductor devices, and electronic parts

Families Citing this family (3)

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CN109852202B (en) * 2019-01-09 2021-05-14 山西大学 The Application of Thioesters Containing Benzo Heterocyclic Skeletons as Ultraviolet Absorbers
JP6766287B1 (en) * 2019-04-11 2020-10-07 キヤノン株式会社 Photocurable resin composition for three-dimensional modeling and method for manufacturing articles
WO2020230732A1 (en) * 2019-05-15 2020-11-19 株式会社Adeka Composition, cured product, cured product production method, and additive

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3956597B2 (en) 2000-09-26 2007-08-08 三菱化学株式会社 Photocurable composition and cured product thereof
JP2009134078A (en) 2007-11-30 2009-06-18 Sumitomo Chemical Co Ltd Photosensitive resin composition
JP5460179B2 (en) 2009-08-25 2014-04-02 株式会社Ｄｎｐファインケミカル Photosensitive red composition for color filter and color filter using the same
JP2013037272A (en) 2011-08-10 2013-02-21 Mitsubishi Paper Mills Ltd Photosensitive resin composition and photosensitive film
JP2013182174A (en) 2012-03-02 2013-09-12 Toyo Ink Sc Holdings Co Ltd Photosensitive resin composition
US9777138B2 (en) 2012-07-31 2017-10-03 Adeka Corporation Latent additive and composition containing latent additive
JP6309834B2 (en) * 2013-12-11 2018-04-11 株式会社Adeka Coloring composition
JP2015132791A (en) * 2013-12-13 2015-07-23 株式会社Adeka Colored photosensitive composition
JP2015163671A (en) * 2013-12-13 2015-09-10 株式会社Adeka Radical-polymerizable composition
JP6318710B2 (en) 2014-03-06 2018-05-09 富士ゼロックス株式会社 Information processing apparatus, document processing system, information processing system, and information processing program
JP2016038569A (en) * 2014-08-05 2016-03-22 株式会社Adeka Photosensitive composition
JP6401982B2 (en) * 2014-09-10 2018-10-10 株式会社Adeka Latent additive and photosensitive composition
JP6447298B2 (en) * 2015-03-26 2019-01-09 Jsr株式会社 Composition for forming cured film for display element, cured film for display element, method for forming cured film for display element, display element and method for producing display element
JP2017008219A (en) * 2015-06-23 2017-01-12 株式会社Adeka Composition
CN107636024B (en) * 2015-08-17 2020-06-19 株式会社艾迪科 Composition comprising a metal oxide and a metal oxide
CN107614485A (en) * 2015-08-24 2018-01-19 株式会社艾迪科 Oxime ester compound and the polymerization initiator containing the compound
CN107614477B (en) * 2015-09-11 2021-08-24 株式会社艾迪科 Compounds, latent additives and compositions containing the same
JP6799540B2 (en) * 2015-09-25 2020-12-16 株式会社Adeka Oxime ester compound and polymerization initiator containing the compound

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI814775B (en) * 2018-01-30 2023-09-11 日商納美仕股份有限公司 Resin compositions and hardened products, adhesives, semiconductor devices, and electronic parts

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