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TN2017000545A1 - PROCESS FOR SEPARATING IRON FROM AN ORGANIC PHASE CONTAINING URANIUM AND PROCESS FOR EXTRACTING URANIUM FROM AN AQUEOUS SOLUTION OF MINERAL ACID CONTAINING URANIUM AND IRON. - Google Patents

PROCESS FOR SEPARATING IRON FROM AN ORGANIC PHASE CONTAINING URANIUM AND PROCESS FOR EXTRACTING URANIUM FROM AN AQUEOUS SOLUTION OF MINERAL ACID CONTAINING URANIUM AND IRON.

Info

Publication number
TN2017000545A1
TN2017000545A1 TNP/2017/000545A TN2017000545A TN2017000545A1 TN 2017000545 A1 TN2017000545 A1 TN 2017000545A1 TN 2017000545 A TN2017000545 A TN 2017000545A TN 2017000545 A1 TN2017000545 A1 TN 2017000545A1
Authority
TN
Tunisia
Prior art keywords
uranium
fer
liquide
iron
solution aqueuse
Prior art date
Application number
TNP/2017/000545A
Other languages
French (fr)
Inventor
Frédéric Auger
Bruno Courtaud
Hamid Mokhtari
Original Assignee
Areva Mines
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Areva Mines filed Critical Areva Mines
Publication of TN2017000545A1 publication Critical patent/TN2017000545A1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B60/00Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
    • C22B60/02Obtaining thorium, uranium, or other actinides
    • C22B60/0204Obtaining thorium, uranium, or other actinides obtaining uranium
    • C22B60/0217Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
    • C22B60/0252Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries
    • C22B60/0278Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries by chemical methods
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B60/00Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
    • C22B60/02Obtaining thorium, uranium, or other actinides
    • C22B60/0204Obtaining thorium, uranium, or other actinides obtaining uranium
    • C22B60/0217Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
    • C22B60/0252Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries
    • C22B60/026Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries liquid-liquid extraction with or without dissolution in organic solvents
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B60/00Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
    • C22B60/02Obtaining thorium, uranium, or other actinides
    • C22B60/0204Obtaining thorium, uranium, or other actinides obtaining uranium
    • C22B60/0217Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
    • C22B60/0221Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes by leaching
    • C22B60/0226Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes by leaching using acidic solutions or liquors
    • C22B60/0243Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes by leaching using acidic solutions or liquors phosphorated ion as active agent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B60/00Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
    • C22B60/02Obtaining thorium, uranium, or other actinides
    • C22B60/0204Obtaining thorium, uranium, or other actinides obtaining uranium
    • C22B60/0217Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
    • C22B60/0252Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries
    • C22B60/0278Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries by chemical methods
    • C22B60/0282Solutions containing P ions, e.g. treatment of solutions resulting from the leaching of phosphate ores or recovery of uranium from wet-process phosphoric acid

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Geology (AREA)
  • Materials Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Extraction Or Liquid Replacement (AREA)

Abstract

L'invention concerne un procédé de séparation du fer à partir d'une phase organique liquide initiale contenant de l'uranium, et du fer, dans lequel on met en contact la phase organique liquide initiale avec une solution aqueuse dite solution aqueuse de déferrisation, moyennant quoi le fer passe dans la solution aqueuse pour former une phase aqueuse liquide finale, et l'uranium reste dans la phase organ!que liquide initiale pour former une phase organique liquide finale dite phase organique déferrisée; ledit procédé étant caractérisé en ce que la solution aqueuse de déferrisation contient un acide inorganique et de l'uranium, et ne contient pas de fer. L'invention concerne, en outre, un procédé d'extraction de l'uranium à partir d'une solution aqueuse d'un acide inorganique contenant de l'uranium et du fer.
TNP/2017/000545A 2015-06-30 2016-06-29 PROCESS FOR SEPARATING IRON FROM AN ORGANIC PHASE CONTAINING URANIUM AND PROCESS FOR EXTRACTING URANIUM FROM AN AQUEOUS SOLUTION OF MINERAL ACID CONTAINING URANIUM AND IRON. TN2017000545A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1556181A FR3038326A1 (en) 2015-06-30 2015-06-30 METHOD OF SEPARATING IRON FROM AN URANIUM-CONTAINING ORGANIC PHASE AND METHOD OF EXTRACTING URANIUM FROM AN AQUEOUS SOLUTION OF MINERAL ACID CONTAINING URANIUM AND IRON
PCT/EP2016/065169 WO2017001494A1 (en) 2015-06-30 2016-06-29 Method for separating iron from an organic phase containing uranium and method for extracting uranium from an aqueous solution of mineral acid containing uranium and iron

Publications (1)

Publication Number Publication Date
TN2017000545A1 true TN2017000545A1 (en) 2019-04-12

Family

ID=55361569

Family Applications (1)

Application Number Title Priority Date Filing Date
TNP/2017/000545A TN2017000545A1 (en) 2015-06-30 2016-06-29 PROCESS FOR SEPARATING IRON FROM AN ORGANIC PHASE CONTAINING URANIUM AND PROCESS FOR EXTRACTING URANIUM FROM AN AQUEOUS SOLUTION OF MINERAL ACID CONTAINING URANIUM AND IRON.

Country Status (10)

Country Link
US (1) US20180187290A1 (en)
CN (1) CN107810283A (en)
AU (1) AU2016286275A1 (en)
BR (1) BR112017028091A2 (en)
CA (1) CA2990559A1 (en)
FR (1) FR3038326A1 (en)
IL (1) IL256574A (en)
MA (1) MA41660B1 (en)
TN (1) TN2017000545A1 (en)
WO (1) WO2017001494A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111254296B (en) * 2020-01-21 2020-12-22 中南大学 A kind of uranium extractant with styryl phosphonic acid diester structure and its application
CN114388159B (en) * 2021-12-23 2025-01-21 中国核电工程有限公司 Phase separation method and device, and extraction separation method and system for spent fuel reprocessing plant
CN117383621A (en) * 2023-10-12 2024-01-12 核工业北京化工冶金研究院 A method for extracting and recovering iron red from hydrochloric acid leachate of high-quality dissolved residues
CN117587277B (en) * 2023-11-13 2025-04-29 湖南中核金原新材料有限责任公司 Method for preparing uranate by fractional precipitation

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4105741A (en) * 1976-03-08 1978-08-08 Freeport Minerals Company Process for recovery of uranium from wet process phosphoric acid
FR2442796A1 (en) 1978-11-28 1980-06-27 Commissariat Energie Atomique Extn. of uranium from wet process phosphoric acid - using neutral phosphine oxide, pref. di-N-hexyl octoxy:methyl phosphine oxide and organo-phosphoric or phosphonic acid (J5 18.6.80)
FR2459205A2 (en) 1979-06-15 1981-01-09 Commissariat Energie Atomique Collecting uranium from its phosphoric acid soln. - using a liq. compsn. comprising organic solvent, organic acidic phosphorus cpd. and a neutral phosphine oxide
FR2461681A1 (en) * 1979-07-20 1981-02-06 Rhone Poulenc Ind Extn. of uranium from wet process phosphoric acid - washes organic uranium phase with aq. sulphuric acid to give uranium with a low iron content
FR2494258A1 (en) 1980-11-14 1982-05-21 Commissariat Energie Atomique PROCESS FOR RECOVERING URANIUM PRESENT IN PHOSPHORIC ACID SOLUTIONS
FR2596383B1 (en) 1986-03-28 1990-10-26 Cogema METHOD FOR SEPARATION OF IRON FROM AN ORGANIC SOLUTION CONTAINING URANIUM
IL79999A0 (en) 1986-09-10 1986-12-31 Yeda Res & Dev Bifunctional organophosphorus extractants and polymers for uranium recovery
US6645453B2 (en) * 2001-09-07 2003-11-11 Secretary, Department Of Atomic Energy, Government Of India Solvent extraction process for recovery of uranium from phosphoric acid (25-55% P205)
FR2990206B1 (en) 2012-05-07 2014-06-06 Commissariat Energie Atomique NOVEL BIFUNCTIONAL COMPOUNDS USEFUL AS LIGANDS OF URANIUM (VI), METHODS OF SYNTHESIS AND USES THEREOF
CN103397184B (en) * 2013-07-31 2014-12-03 南昌航空大学 Method for separating uranium and iron from tertiary amine organic phase by back extraction

Also Published As

Publication number Publication date
MA41660B1 (en) 2018-11-30
CN107810283A (en) 2018-03-16
US20180187290A1 (en) 2018-07-05
BR112017028091A2 (en) 2018-08-28
FR3038326A1 (en) 2017-01-06
AU2016286275A1 (en) 2018-01-25
IL256574A (en) 2018-02-28
CA2990559A1 (en) 2017-01-05
MA41660A1 (en) 2018-04-30
WO2017001494A1 (en) 2017-01-05

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