FR2990206B1 - NOVEL BIFUNCTIONAL COMPOUNDS USEFUL AS LIGANDS OF URANIUM (VI), METHODS OF SYNTHESIS AND USES THEREOF - Google Patents

NOVEL BIFUNCTIONAL COMPOUNDS USEFUL AS LIGANDS OF URANIUM (VI), METHODS OF SYNTHESIS AND USES THEREOF

Info

Publication number: FR2990206B1
Authority: FR; France
Prior art keywords: uranium; ligands; synthesis; methods; compounds useful
Prior art date: 2012-05-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Active

Application number

FR1254176A

Other languages

French (fr)

Other versions

FR2990206A1 (en

Inventor

Fabien Burdet

Antoine Leydier

Gilles Bernier

Nicolas Aychet

Elisabeth Zekri

Manuel Miguirditchian

Gabriel Plancque

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Orano Mining SA

Original Assignee

Commissariat a lEnergie Atomique CEA

Commissariat a lEnergie Atomique et aux Energies Alternatives CEA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2012-05-07

Filing date

2012-05-07

Publication date

2014-06-06

2012-05-07 Application filed by Commissariat a lEnergie Atomique CEA, Commissariat a lEnergie Atomique et aux Energies Alternatives CEA filed Critical Commissariat a lEnergie Atomique CEA

2012-05-07 Priority to FR1254176A priority Critical patent/FR2990206B1/en

2012-12-19 Priority to FR1262362A priority patent/FR2990207B1/en

2013-05-06 Priority to AU2013258153A priority patent/AU2013258153B2/en

2013-05-06 Priority to PE2014001977A priority patent/PE20150282A1/en

2013-05-06 Priority to BR112014027732-0A priority patent/BR112014027732B1/en

2013-05-06 Priority to PCT/EP2013/059352 priority patent/WO2013167516A1/en

2013-05-06 Priority to US14/399,935 priority patent/US9441285B2/en

2013-05-06 Priority to CA2872084A priority patent/CA2872084C/en

2013-05-06 Priority to CN201380035914.5A priority patent/CN104470936B/en

2013-11-08 Publication of FR2990206A1 publication Critical patent/FR2990206A1/en

2014-06-06 Application granted granted Critical

2014-06-06 Publication of FR2990206B1 publication Critical patent/FR2990206B1/en

2014-10-31 Priority to TN2014000463A priority patent/TN2014000463A1/en

2014-10-31 Priority to ZA2014/07955A priority patent/ZA201407955B/en

2014-11-05 Priority to IL235520A priority patent/IL235520B/en

Status Active legal-status Critical Current

2032-05-07 Anticipated expiration legal-status Critical

Classifications

- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
- C22B60/02—Obtaining thorium, uranium, or other actinides
- C22B60/0204—Obtaining thorium, uranium, or other actinides obtaining uranium
- C22B60/0217—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
- C22B60/0252—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries
- C22B60/026—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries liquid-liquid extraction with or without dissolution in organic solvents
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/572—Five-membered rings
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
- C22B60/02—Obtaining thorium, uranium, or other actinides
- C22B60/0204—Obtaining thorium, uranium, or other actinides obtaining uranium
- C22B60/0217—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
- C22B60/0221—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes by leaching
- C22B60/0226—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes by leaching using acidic solutions or liquors
- C22B60/0243—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes by leaching using acidic solutions or liquors phosphorated ion as active agent
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/007—Recovery of isotopes from radioactive waste, e.g. fission products
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
- G21F9/06—Processing
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
- G21F9/06—Processing
- G21F9/12—Processing by absorption; by adsorption; by ion-exchange
- G21F9/125—Processing by absorption; by adsorption; by ion-exchange by solvent extraction

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
General Life Sciences & Earth Sciences (AREA)
General Engineering & Computer Science (AREA)
Physics & Mathematics (AREA)
High Energy & Nuclear Physics (AREA)
Health & Medical Sciences (AREA)
Biochemistry (AREA)
General Health & Medical Sciences (AREA)
Molecular Biology (AREA)
Manufacturing & Machinery (AREA)
Materials Engineering (AREA)
Mechanical Engineering (AREA)
Metallurgy (AREA)
Geology (AREA)
Environmental & Geological Engineering (AREA)

FR1254176A 2012-05-07 2012-05-07 NOVEL BIFUNCTIONAL COMPOUNDS USEFUL AS LIGANDS OF URANIUM (VI), METHODS OF SYNTHESIS AND USES THEREOF Active FR2990206B1 (en)

Priority Applications (12)

Application Number	Priority Date	Filing Date	Title
FR1254176A FR2990206B1 (en)	2012-05-07	2012-05-07	NOVEL BIFUNCTIONAL COMPOUNDS USEFUL AS LIGANDS OF URANIUM (VI), METHODS OF SYNTHESIS AND USES THEREOF
FR1262362A FR2990207B1 (en)	2012-05-07	2012-12-19	NOVEL BIFUNCTIONAL COMPOUNDS USEFUL AS LIGANDS OF URANIUM (VI), METHODS OF SYNTHESIS AND USES THEREOF
CA2872084A CA2872084C (en)	2012-05-07	2013-05-06	Bifunctional compounds carbamoyl/phosphonic acid or phosphonate used as ligands for uranium(vi), their synthesis processes and their uses uses
BR112014027732-0A BR112014027732B1 (en)	2012-05-07	2013-05-06	COMPOUND, USE OF A COMPOUND AND URANIUM RECOVERY PROCESS
PCT/EP2013/059352 WO2013167516A1 (en)	2012-05-07	2013-05-06	New bifunctional compounds useful as ligands of uranium (vi), methods of synthesising same and uses thereof
US14/399,935 US9441285B2 (en)	2012-05-07	2013-05-06	Bifunctional compounds useful as ligands of uranium (VI), methods of synthesising same and uses thereof
AU2013258153A AU2013258153B2 (en)	2012-05-07	2013-05-06	New bifunctional compounds useful as ligands of uranium (VI), methods of synthesising same and uses thereof
CN201380035914.5A CN104470936B (en)	2012-05-07	2013-05-06	Novel bifunctional compounds useful as uranium(VI) ligands, methods for their synthesis and their uses
PE2014001977A PE20150282A1 (en)	2012-05-07	2013-05-06	NEW USEFUL BIFUNCTIONAL COMPOUNDS AS A LIGAND OF URANIUM (VI), METHODS OF SYNTHESIS OF THE SAME AND USES OF THE SAME
TN2014000463A TN2014000463A1 (en)	2012-05-07	2014-10-31	NOVEL BIFUNCTIONAL COMPOUNDS USEFUL AS URANIUM (VI) LIGANDS, METHODS OF SYNTHESIS AND USES THEREOF
ZA2014/07955A ZA201407955B (en)	2012-05-07	2014-10-31	New bifunctional compounds useful as ligands of uranium (vi), methods of synthesising same and uses thereof
IL235520A IL235520B (en)	2012-05-07	2014-11-05	Bifunctional compounds useful as ligands of uranium(vi) and uses thereof

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
FR1254176A FR2990206B1 (en)	2012-05-07	2012-05-07	NOVEL BIFUNCTIONAL COMPOUNDS USEFUL AS LIGANDS OF URANIUM (VI), METHODS OF SYNTHESIS AND USES THEREOF

Publications (2)

Publication Number	Publication Date
FR2990206A1 FR2990206A1 (en)	2013-11-08
FR2990206B1 true FR2990206B1 (en)	2014-06-06

Family

ID=47049228

Family Applications (2)

Application Number	Title	Priority Date	Filing Date
FR1254176A Active FR2990206B1 (en)	2012-05-07	2012-05-07	NOVEL BIFUNCTIONAL COMPOUNDS USEFUL AS LIGANDS OF URANIUM (VI), METHODS OF SYNTHESIS AND USES THEREOF
FR1262362A Active FR2990207B1 (en)	2012-05-07	2012-12-19	NOVEL BIFUNCTIONAL COMPOUNDS USEFUL AS LIGANDS OF URANIUM (VI), METHODS OF SYNTHESIS AND USES THEREOF

Family Applications After (1)

Application Number	Title	Priority Date	Filing Date
FR1262362A Active FR2990207B1 (en)	2012-05-07	2012-12-19	NOVEL BIFUNCTIONAL COMPOUNDS USEFUL AS LIGANDS OF URANIUM (VI), METHODS OF SYNTHESIS AND USES THEREOF

Country Status (11)

Country	Link
US (1)	US9441285B2 (en)
CN (1)	CN104470936B (en)
AU (1)	AU2013258153B2 (en)
BR (1)	BR112014027732B1 (en)
CA (1)	CA2872084C (en)
FR (2)	FR2990206B1 (en)
IL (1)	IL235520B (en)
PE (1)	PE20150282A1 (en)
TN (1)	TN2014000463A1 (en)
WO (1)	WO2013167516A1 (en)
ZA (1)	ZA201407955B (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2990206B1 (en)	2012-05-07	2014-06-06	Commissariat Energie Atomique	NOVEL BIFUNCTIONAL COMPOUNDS USEFUL AS LIGANDS OF URANIUM (VI), METHODS OF SYNTHESIS AND USES THEREOF
FR3002463B1 (en) *	2013-02-25	2016-08-19	Commissariat Energie Atomique	ORGANIC-INORGANIC HYBRID MATERIAL, USEFUL FOR EXTRACTING URANIUM (VI) FROM AQUEOUS MEDIA CONTAINING PHOSPHORIC ACID, PROCESSES FOR PREPARING THEM AND USES THEREOF
FR3002951B1 (en) *	2013-03-11	2015-04-17	Areva Mines	USE OF AMIDE AND PHOSPHONATE FUNCTION COMPOUNDS FOR EXTRACTING URANIUM (VI) FROM AQUEOUS SOLUTIONS OF SULFURIC ACID, IN PARTICULAR FROM THE SULFURIC LIXATION OF URANIFIED MINERALS
FR3013059B1 (en) *	2013-11-08	2016-01-01	Commissariat Energie Atomique	USE OF ORGANIC-INORGANIC HYBRID MATERIAL FOR EXTRACTING URANIUM (VI) FROM AQUEOUS SOLUTION OF SULFURIC ACID, IN PARTICULAR FROM THE SULFURIC LIXATION OF A URANIUM URANIUM
FR3034417B1 (en) *	2015-04-03	2019-03-15	Commissariat A L'energie Atomique Et Aux Energies Alternatives	COMPOUNDS HAVING PHOSPHINE AND AMINE OXIDE FUNCTIONS, USEFUL AS LIGANDS OF URANIUM (VI), AND USES THEREOF, IN PARTICULAR FOR EXTRACTING URANIUM (VI) FROM AQUEOUS SOLUTIONS OF SULFURIC ACID
FR3038326A1 (en)	2015-06-30	2017-01-06	Areva Mines	METHOD OF SEPARATING IRON FROM AN URANIUM-CONTAINING ORGANIC PHASE AND METHOD OF EXTRACTING URANIUM FROM AN AQUEOUS SOLUTION OF MINERAL ACID CONTAINING URANIUM AND IRON
FR3044006B1 (en) *	2015-11-19	2020-03-06	Orano Mining	NOVEL ORGANIC MATERIAL FOR EXTRACTING URANIUM FROM AN AQUEOUS PHOSPHORIC ACID SOLUTION, ASSOCIATED URANIUM EXTRACTION AND RECOVERY METHODS AND PRECURSOR OF SUCH ORGANIC MATERIAL
FR3044018B1 (en)	2015-11-19	2017-12-22	Areva Mines	METHODS OF EXTRACTING AND RECOVERING URANIUM PRESENT IN AQUEOUS SOLUTION COMPRISING PHOSPHORIC ACID
FR3055906B1 (en) *	2016-09-15	2018-09-28	Commissariat A L'energie Atomique Et Aux Energies Alternatives	NOVEL EXTRACTOR USEFUL FOR EXTRACTING RARE EARTHS FROM AQUEOUS PHOSPHORIC ACID SOLUTION, AND APPLICATIONS THEREOF
FR3060006B1 (en)	2016-12-13	2020-02-28	Orano Mining	MESOPOROUS ORGANIC MATERIAL, ESPECIALLY USEFUL FOR EXTRACTING URANIUM (VI) FROM AQUEOUS MEDIA COMPRISING PHOSPHORIC ACID, AND USES THEREOF
CN106749407B (en) *	2017-01-06	2019-06-18	中国工程物理研究院核物理与化学研究所	A kind of aminophosphoric acid functionalized ionic liquid and its preparation method and use
FR3069539B1 (en)	2017-07-31	2019-08-30	Areva Mines	BIFUNCTIONAL COMPOUNDS WITH THIOPHOSPHINE FUNCTION, USEFUL AS EXTRACTANTS OF URANIUM (VI), METHODS OF SYNTHESIS AND USES THEREOF
EP3441396A1 (en) *	2017-08-07	2019-02-13	Université de Montpellier	Method for separating uranium and/or thorium
EP4199934A4 (en) *	2020-08-21	2024-09-04	The Board of Regents of the University of Texas System	Functional ionizable phospholipids
FR3116834A1 (en)	2020-12-02	2022-06-03	Commissariat A L'energie Atomique Et Aux Energies Alternatives	Process for the selective recovery of rare earths and uranium(VI) from an aqueous solution of phosphoric acid
CN114797486B (en) *	2022-04-13	2023-02-03	合肥凯华环保科技有限公司	Hydrophobic membrane capable of being hydrophobic again after being hydrophilic for wastewater deamination
CN116284121A (en) *	2023-03-09	2023-06-23	核工业北京化工冶金研究院	Compound and preparation method and application thereof

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US3711591A (en)	1970-07-08	1973-01-16	Atomic Energy Commission	Reductive stripping process for the recovery of uranium from wet-process phosphoric acid
SU376387A1 (en) *	1971-06-21	1973-04-05	Институт органической , физической химии А. Е. Арбузова	METHOD FOR OBTAINING PHOSPHORYLATED DIPHENYLAMINES
FR2396803A1 (en)	1977-07-05	1979-02-02	Cogema	URANIUM EXTRACTION PROCESS FROM WET PHOSPHORIC ACID
FR2460958A1 (en)	1979-07-09	1981-01-30	Elf Aquitaine	NEW DIPHOSPHONIC COMPOUNDS USEFUL IN THE EXTRACTION OF HEAVY METALS
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US4316877A (en) *	1979-11-23	1982-02-23	Allied Corporation	Extraction of uranium values from phosphoric acid
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FR2990206B1 (en)	2012-05-07	2014-06-06	Commissariat Energie Atomique	NOVEL BIFUNCTIONAL COMPOUNDS USEFUL AS LIGANDS OF URANIUM (VI), METHODS OF SYNTHESIS AND USES THEREOF

2012
- 2012-05-07 FR FR1254176A patent/FR2990206B1/en active Active
- 2012-12-19 FR FR1262362A patent/FR2990207B1/en active Active
2013
- 2013-05-06 US US14/399,935 patent/US9441285B2/en active Active
- 2013-05-06 CN CN201380035914.5A patent/CN104470936B/en active Active
- 2013-05-06 CA CA2872084A patent/CA2872084C/en active Active
- 2013-05-06 BR BR112014027732-0A patent/BR112014027732B1/en active IP Right Grant
- 2013-05-06 WO PCT/EP2013/059352 patent/WO2013167516A1/en not_active Ceased
- 2013-05-06 AU AU2013258153A patent/AU2013258153B2/en active Active
- 2013-05-06 PE PE2014001977A patent/PE20150282A1/en active IP Right Grant
2014
- 2014-10-31 TN TN2014000463A patent/TN2014000463A1/en unknown
- 2014-10-31 ZA ZA2014/07955A patent/ZA201407955B/en unknown
- 2014-11-05 IL IL235520A patent/IL235520B/en active IP Right Grant

Also Published As

Publication number	Publication date
WO2013167516A1 (en)	2013-11-14
IL235520A0 (en)	2015-02-01
FR2990206A1 (en)	2013-11-08
FR2990207A1 (en)	2013-11-08
CN104470936A (en)	2015-03-25
BR112014027732A2 (en)	2017-06-27
TN2014000463A1 (en)	2016-03-30
CA2872084A1 (en)	2013-11-14
CA2872084C (en)	2020-09-22
ZA201407955B (en)	2015-10-28
PE20150282A1 (en)	2015-03-08
AU2013258153A1 (en)	2014-11-20
US20150133688A1 (en)	2015-05-14
US9441285B2 (en)	2016-09-13
AU2013258153B2 (en)	2017-05-11
FR2990207B1 (en)	2015-08-21
BR112014027732B1 (en)	2022-01-18
CN104470936B (en)	2019-04-19
IL235520B (en)	2018-01-31

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Legal Events

Date	Code	Title	Description
2014-05-09	TP	Transmission of property	Owner name: AREVA MINES, FR Effective date: 20140408
2016-05-27	PLFP	Fee payment	Year of fee payment: 5
2017-05-30	PLFP	Fee payment	Year of fee payment: 6
2018-05-28	PLFP	Fee payment	Year of fee payment: 7
2019-05-31	PLFP	Fee payment	Year of fee payment: 8
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