SU562568A1 - Detergent for cleaning metal surfaces - Google Patents
Detergent for cleaning metal surfacesInfo
- Publication number
- SU562568A1 SU562568A1 SU2184978A SU2184978A SU562568A1 SU 562568 A1 SU562568 A1 SU 562568A1 SU 2184978 A SU2184978 A SU 2184978A SU 2184978 A SU2184978 A SU 2184978A SU 562568 A1 SU562568 A1 SU 562568A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- detergent
- proposed
- metal surfaces
- cleaning metal
- nitrogen
- Prior art date
Links
- 238000004140 cleaning Methods 0.000 title claims description 7
- 239000003599 detergent Substances 0.000 title description 10
- 239000002184 metal Substances 0.000 title description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 239000000203 mixture Substances 0.000 description 10
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 9
- 238000005406 washing Methods 0.000 description 6
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 5
- 239000000314 lubricant Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 229920001400 block copolymer Polymers 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002798 polar solvent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 244000007853 Sarothamnus scoparius Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- ZGRFDIQZUMQONF-KVVVOXFISA-N dichloromethane (Z)-octadec-9-enoic acid Chemical compound ClCCl.CCCCCCCC\C=C/CCCCCCCC(O)=O ZGRFDIQZUMQONF-KVVVOXFISA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- OYFWLCJAPSAGCG-UHFFFAOYSA-N n'-methylhexane-1,6-diamine Chemical compound CNCCCCCCN OYFWLCJAPSAGCG-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Description
(54) МОЮЩЕЕ СРЕДСТВО ДЛЯ ОЧИСТКИ МЕТАЛЛИЧЕСКОЙ ПОВЕРХНОСТИ(54) DETERGENT FOR CLEANING METAL SURFACE
где 4ft 60, 4т 27-28, соль азотсодержащего сополимера окиси этилена и окиси пропилена с карбоновыми н(ОНбОз),()шОНбОз N-CH2н (ОНбОз)п(ОН402)к10НбСзwhere 4ft 60, 4t 27-28, a salt of a nitrogen-containing copolymer of ethylene oxide and propylene oxide with carbonic n (OH) O 3, () hOH 3 N-CH 2 n (OH 3) 3 (OH402) k10H3 3
где 4п 60, 4т 27-28, R - алкил или алкилен ,where 4p 60, 4t 27-28, R - alkyl or alkylene,
и дополнительно оно содержит диметилсульфоксид и 4-метил-2,6-дитрет-бутилфенол при следующем соотношении компонентов, вес. %:and additionally it contains dimethyl sulfoxide and 4-methyl-2,6-ditert-butylphenol in the following ratio of components, wt. %:
Азотсодержащий сополимер окиси этилена и окиси пропилена приведенной общей формулы0,01-10Nitrogen-containing copolymer of ethylene oxide and propylene oxide of the general formula 0.01-10
Соль азотсодержащего сополимера 0(Киси этилена и окиси пропилена приведенной общей формулы0,01 -10 4-Метил-2,6-дитрет-бутилфенол0 ,006-1Salt of nitrogen-containing copolymer 0 (Kisi ethylene and propylene oxide given General formula 0,01 -10 4-Methyl-2,6-ditert-butylphenol0, 006-1
Диметилсульфоксид0,02-20Dimethylsulfoxide 0.02-20
Галогензамещенный углеводородный растворитель До 100 Диметилсульфоксид введен в состав как пол рный растворитель, а 4-метил-2,6-дитретбутилфенол (ионол) - в качестве аотикорровионной добавки.Halogen-substituted hydrocarbon solvent Up to 100 Dimethyl sulfoxide is introduced into the composition as a polar solvent, and 4-methyl-2,6-di-t-butylphenol (ionol) as an additive.
Пример. Приготовление средства. В ем,кость с мещалкой и рубащкой зал;;вают галогенпроизводный органический растворитель , затем при посто нном перемешивании в емкость ввод т Диметилсульфоксид, ионол и перемешивают смесь до полного растворени и однородности.Example. Cooking means. A halogen-containing organic solvent is placed in the bone with a broom and a scraper ;; Dimethyl sulfoxide and ionol are introduced into the tank with constant stirring and the mixture is stirred until complete dissolution and uniformity.
Затем в смесь ввод т азотсодержащий сополимер и карбоновую КИСЛОТ) При нейтрализации азотсодержащего блок-сополимера карбоновой кислотой получаетс соль ка боновой кислоты и азотсодержащего блок-сополимера . После полного растворени указан ной соли в смесь ввод т остальное количество азотсодержащего блок-сополимера окиси этилена и окиси пропилена. Смесь перемешивают до полного растворени и однородности, после чего средство готово к употреблению. Использовать предлагаемое средство можно известными способами: мойка окупанием, мойка в парах и др. Применение средства увеличивает интенсивность мойки.The nitrogen-containing copolymer and the carboxylic acid are then introduced into the mixture. By neutralizing the nitrogen-containing block copolymer with carboxylic acid, the salt of the carbonic acid and the nitrogen-containing block copolymer is obtained. After complete dissolution of this salt, the remaining nitrogen-containing block copolymer of ethylene oxide and propylene oxide is introduced into the mixture. The mixture is stirred until complete dissolution and uniformity, after which the product is ready for use. To use the proposed tool can be known methods: washing payback, washing in pairs, etc. The use of the tool increases the intensity of washing.
Моющее средство предлагаемого состава обладает высоким моющим действием, огнебезопасно , обладает высокими антикоррозионными свойствами. Пол рный растворитель - диметллсульфоксид практически не обладает моющим действием. Однако его добавка значительно усиливает моющее действие галогенпроизводных углеводородов, а та1кже усиливает моющее действие растворовThe detergent of the proposed composition has a high detergency, fire-safe, has high anti-corrosion properties. Polar solvent - dimethyl sulfoxide has practically no detergent action. However, its addition significantly enhances the detergent action of halogenated hydrocarbons, and also enhances the detergency effect of solutions.
кислотами насыщенными или ненасыщенными , содержащими одну двойную св зь, общей формулыsaturated or unsaturated acids containing one double bond, of general formula
предлагаемых ПАВ и галогенпроизводных углеводородов. Смесь содержащихс в предлагаемом средстве ПАВ также улучшает моющее действие средства. Кроме того, смесь компонентов предлагаемого моющего средства (в предлагаемом соотнощении) обладает синергическим моющим действием.proposed surfactants and halogen derivatives of hydrocarbons. The mixture contained in the proposed surfactant agent also improves the detergent action of the agent. In addition, the mixture of the components of the proposed detergent (in the proposed ratio) has a synergistic detergent action.
Благодар названным свойствам предлагаемое средство особенно эффективно удал ет консервационные технологические смазки и загр знени , а также протирочные, щлифовочные и доводочные пасты. Применение указанных ПАВ в сочетании с ионолом обеспечивает высокую антикоррозионную способность средства, предохран ет металлические издели от коррозии в процессе очистки и при хранении после очистки, а также улучщает поверхность изделий дл нанесени покрытий .Due to these properties, the proposed agent is particularly effective in removing conservation lubricants and impurities, as well as wiping, grinding and finishing pastes. The use of these surfactants in combination with ionol provides a high anticorrosion ability of the agent, protects metal products from corrosion during the cleaning process and during storage after cleaning, and also improves the surface of the coating products.
Дл сравнени эксплуатационных свойств испытанию подвергают предлагаемое моющее средство и известное средство следующего состава , вес. %:To compare the performance properties, the proposed detergent and a known agent of the following composition are subjected to testing, wt. %:
Соль метилгексаметилендиамина и олеиновой кислоты 1,83 Хлористый метилен39,3Methyl hexamethylenediamine and oleic acid salt 1.83 Methylene chloride 39.3
1,1,2-Трихлор-1,2,2-трифторэтан До 1001,1,2-Trichloro-1,2,2-trifluoroethane Up to 100
Мойке подвергают образцы из ст. 45, загр зненные графитовой смазкой марки УССА (ГОСТ 3333-55) и смазкой марки ЦИАТИМ201 (ГОСТ 6267-59).Samples from Art. 45, contaminated with graphite lubricant of the USSA brand (GOST 3333-55) and lubricant of the CIATIM201 brand (GOST 6267-59).
Моющую способность средств оценивают по времени полной очистки. Перед нанесением загр знений стальные нластины (размер 40хЗОХ 1,5 лмг) обезжиривают трихлорэтиленом . Затем на нижнюю половину одной стороны пластинок нанос т роВНым слоем одинаковое количество загр знений. Загр зненные образцы одновременно погружат в сосуды с предлагаемым и известным средствами . Погрул ени производ т с частотой 30- 40 раз/лшн при температуре моющего средства 18-20° С.The washing ability of funds is evaluated by the time of complete cleaning. Before application of contamination, steel bases (size 40xZOCH 1.5 lmg) are degreased with trichlorethylene. Then, on the lower half of one side of the plates, an equal amount of contaminants is deposited with a rotated layer. Contaminated samples are simultaneously immersed in vessels with the proposed and known means. The plunging is done with a frequency of 30-40 times per day at a temperature of 18-20 ° C detergent.
Результаты проведенных испытаний показывают , что врем полной очистки при отмывке предлагаемым составом графитовой смазки составл ет 162 с, смазки ЦИАТИМ201 - 311 с по сравнению с 270 и 619 с соответственно при отмывке известиым составом.The results of the tests show that the total cleaning time for washing with the proposed composition of graphite grease is 162 seconds, for CIATIM201 lubricants - 311 seconds as compared to 270 and 619 seconds, respectively, for washing with lime.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU2184978A SU562568A1 (en) | 1975-10-27 | 1975-10-27 | Detergent for cleaning metal surfaces |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU2184978A SU562568A1 (en) | 1975-10-27 | 1975-10-27 | Detergent for cleaning metal surfaces |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU562568A1 true SU562568A1 (en) | 1977-06-25 |
Family
ID=20635832
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU2184978A SU562568A1 (en) | 1975-10-27 | 1975-10-27 | Detergent for cleaning metal surfaces |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU562568A1 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4548744A (en) * | 1983-07-22 | 1985-10-22 | Connor Daniel S | Ethoxylated amine oxides having clay soil removal/anti-redeposition properties useful in detergent compositions |
| US4597898A (en) * | 1982-12-23 | 1986-07-01 | The Proctor & Gamble Company | Detergent compositions containing ethoxylated amines having clay soil removal/anti-redeposition properties |
| US4659802A (en) | 1982-12-23 | 1987-04-21 | The Procter & Gamble Company | Cationic compounds having clay soil removal/anti-redeposition properties useful in detergent compositions |
| US4661288A (en) | 1982-12-23 | 1987-04-28 | The Procter & Gamble Company | Zwitterionic compounds having clay soil removal/anti/redeposition properties useful in detergent compositions |
| US4664848A (en) | 1982-12-23 | 1987-05-12 | The Procter & Gamble Company | Detergent compositions containing cationic compounds having clay soil removal/anti-redeposition properties |
| US4676921A (en) * | 1982-12-23 | 1987-06-30 | The Procter & Gamble Company | Detergent compositions containing ethoxylated amine polymers having clay soil removal/anti-redeposition properties |
-
1975
- 1975-10-27 SU SU2184978A patent/SU562568A1/en active
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4597898A (en) * | 1982-12-23 | 1986-07-01 | The Proctor & Gamble Company | Detergent compositions containing ethoxylated amines having clay soil removal/anti-redeposition properties |
| US4659802A (en) | 1982-12-23 | 1987-04-21 | The Procter & Gamble Company | Cationic compounds having clay soil removal/anti-redeposition properties useful in detergent compositions |
| US4661288A (en) | 1982-12-23 | 1987-04-28 | The Procter & Gamble Company | Zwitterionic compounds having clay soil removal/anti/redeposition properties useful in detergent compositions |
| US4664848A (en) | 1982-12-23 | 1987-05-12 | The Procter & Gamble Company | Detergent compositions containing cationic compounds having clay soil removal/anti-redeposition properties |
| US4676921A (en) * | 1982-12-23 | 1987-06-30 | The Procter & Gamble Company | Detergent compositions containing ethoxylated amine polymers having clay soil removal/anti-redeposition properties |
| US4548744A (en) * | 1983-07-22 | 1985-10-22 | Connor Daniel S | Ethoxylated amine oxides having clay soil removal/anti-redeposition properties useful in detergent compositions |
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