SU1712441A1 - Method of producing crude antimony - Google Patents
Method of producing crude antimony Download PDFInfo
- Publication number
- SU1712441A1 SU1712441A1 SU904815757A SU4815757A SU1712441A1 SU 1712441 A1 SU1712441 A1 SU 1712441A1 SU 904815757 A SU904815757 A SU 904815757A SU 4815757 A SU4815757 A SU 4815757A SU 1712441 A1 SU1712441 A1 SU 1712441A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- antimony
- rough
- target product
- cost
- production
- Prior art date
Links
- 229910052787 antimony Inorganic materials 0.000 title claims abstract description 8
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 title claims abstract description 8
- 238000000034 method Methods 0.000 title claims abstract description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract 4
- 150000001875 compounds Chemical class 0.000 claims abstract 3
- 239000002244 precipitate Substances 0.000 claims abstract 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Inorganic materials [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 229910000410 antimony oxide Inorganic materials 0.000 claims description 3
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims 2
- 238000001035 drying Methods 0.000 claims 2
- 239000003513 alkali Substances 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- 239000003518 caustics Substances 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract 2
- 239000000047 product Substances 0.000 abstract 2
- 229910045601 alloy Inorganic materials 0.000 abstract 1
- 239000000956 alloy Substances 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 abstract 1
- 238000009856 non-ferrous metallurgy Methods 0.000 abstract 1
- 238000007670 refining Methods 0.000 abstract 1
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 235000011118 potassium hydroxide Nutrition 0.000 description 2
- 238000005259 measurement Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Изобретение относитс к технологии получени черновой элементарной сурьмы.дальнейшим рафинированием которой выдел ют металлическую сурьму чистотой 99,3-99,9%. Цель изобретени - упрощение процесса, увеличение выхода и уменьшение себестоимости целевого про- дукта.Реакционную массу,состо щую из суспензии оксида сурьмы в водном растворе гидрооксида кали ,обрабатывают стружкой алюмини при 80®С, после чего осуществл ют фильтрацию,затем осадок промывают ацетоном и эфиром, после чего провод т сушку осадка.Изобретение относитс к цветной металлургии и может быть использовано при. получении черновой сурьмы, рафинированна форма (с 99,3 - 99,9 %-ным содержанием основного вещества) которой широко примен етс в технике в виде сплавов и соединений типа А"'В^.Цель изобретени -упрощение процесса, увеличение выхода и уменьшение себестоимости целеёого продукта.Способ осуществл етс следующим образом. ,Реакцию получени черновой Сурьмм по предлагаемому способу можно выразить уравнением:,5Ь20з+2АИ-6КОН+ЗН2042Кз[А1(01-|^ 1^Дл реакции используют оксид сурь1Й1Ы This invention relates to a technology for the production of rough elemental antimony. Further refining of which produces metallic antimony with a purity of 99.3-99.9%. The purpose of the invention is to simplify the process, increase the yield and reduce the cost of the target product. ether, after which the precipitate is dried. The invention relates to non-ferrous metallurgy and can be used for. the production of rough antimony, the refined form (with 99.3 - 99.9% content of the basic substance) which is widely used in the technique in the form of alloys and compounds of type A "" B ^. The cost of the target product. The method is carried out as follows. The reaction to produce a rough Suermm according to the proposed method can be expressed by the equation:
Description
ветствует содержанию основного вещества в продукте.It corresponds to the content of the main substance in the product.
Пример 2. В услови х по примеру 1 из 14,57 г (0,05 моль) оксида сурьмы (111), 26,93 г (0,48 моль) едкого кали и 3,78 г (0,14 моль) алюмини получают 11,63 г(0,09 моль) черновой сурьмы, что составл ет 95,5% от теор. Содержание основного вещества в целевом продукте 98,66% (средн величина трех измерений).Example 2. Under the conditions of example 1 of 14.57 g (0.05 mol) of antimony oxide (111), 26.93 g (0.48 mol) of potassium hydroxide and 3.78 g (0.14 mol) of aluminum 11.63 g (0.09 mol) of crude antimony are obtained, which is 95.5% of the theory. The content of the basic substance in the target product is 98.66% (average of three measurements).
Таким образом, применение предлагаемого технического решени позвол ет значительно упростить процесс за счет устранени стадийности, увеличить выход на 6 - 40% по сравнению с прототипом, уменьшить себестоимость целевого продукта за счет применени оксида сурьмы (III) вThus, the application of the proposed technical solution significantly simplifies the process by eliminating staging, increases the yield by 6–40% compared to the prototype, reduces the cost of the target product by using antimony oxide (III) in
качестве исходного вещества и сэкономить на 1/3 расход алюмини за счет применени триоксида сурьмы и проведени процесса в среде едкого кали .as a starting material and save on 1/3 the consumption of aluminum due to the use of antimony trioxide and carrying out the process in caustic potash.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU904815757A SU1712441A1 (en) | 1990-04-17 | 1990-04-17 | Method of producing crude antimony |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU904815757A SU1712441A1 (en) | 1990-04-17 | 1990-04-17 | Method of producing crude antimony |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU1712441A1 true SU1712441A1 (en) | 1992-02-15 |
Family
ID=21509129
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU904815757A SU1712441A1 (en) | 1990-04-17 | 1990-04-17 | Method of producing crude antimony |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU1712441A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101928842A (en) * | 2010-09-27 | 2010-12-29 | 娄底市兴华有色金属有限公司 | Lead removing agent for use in stibium pyrorefining and lead removing method thereof |
| CN105838906A (en) * | 2016-05-19 | 2016-08-10 | 益阳生力材料科技股份有限公司 | Antimony smelting method |
| RU2682365C1 (en) * | 2018-04-10 | 2019-03-19 | Федеральное государственное автономное образовательное учреждение высшего образования "Уральский федеральный университет имени первого Президента России Б.Н. Ельцина" | Antimony-containing raw materials processing method |
-
1990
- 1990-04-17 SU SU904815757A patent/SU1712441A1/en active
Non-Patent Citations (1)
| Title |
|---|
| Агладзе Р.И. и др. Цементаци сурьмы металлическими осадител ми. - Труды/Институт металла и горного дела. - Тбилиси, 1957. T.VIII.C.135-140. * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101928842A (en) * | 2010-09-27 | 2010-12-29 | 娄底市兴华有色金属有限公司 | Lead removing agent for use in stibium pyrorefining and lead removing method thereof |
| CN105838906A (en) * | 2016-05-19 | 2016-08-10 | 益阳生力材料科技股份有限公司 | Antimony smelting method |
| CN105838906B (en) * | 2016-05-19 | 2017-12-26 | 益阳生力材料科技股份有限公司 | A kind of method that antimony is smelted |
| RU2682365C1 (en) * | 2018-04-10 | 2019-03-19 | Федеральное государственное автономное образовательное учреждение высшего образования "Уральский федеральный университет имени первого Президента России Б.Н. Ельцина" | Antimony-containing raw materials processing method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6096892A (en) | Chemical process | |
| ATE5074T1 (en) | PROCESS FOR PRODUCTION OF TRIMETHYLSILYLCYANIDE. | |
| SU1712441A1 (en) | Method of producing crude antimony | |
| US4060551A (en) | Method of producing pantethine | |
| US3975264A (en) | Flotation of copper sulfide ores with improved thionocarbamates | |
| US3002011A (en) | Intermediates and processes for producing alpha-lipoic acid | |
| JPS6241655B2 (en) | ||
| SU790698A1 (en) | Method of preparing alkaline salts of oxyethylidenediphosphonic acid complexes with second group metals | |
| JPS5699494A (en) | Preparation of triarylphosphine | |
| SU395362A1 (en) | METHOD OF OBTAINING 0-CHLOROBENZONITRILE | |
| SU383373A1 (en) | Method for preparing 3,3-dipropanedisulfonic acid disulfide disodium salt | |
| SU639863A1 (en) | Method of obtaining complexing agent of iminodisuccinic acid | |
| US3360534A (en) | Method of producing a guanyl-o-alkylisourea salt | |
| SU571473A1 (en) | Method of preparing lythium acrylate | |
| SU666134A1 (en) | Method of producing bishmuth oxide | |
| SU1182039A1 (en) | Method of producing 3-(benzothiazolyl-2)-thiapropansulfonate of alkali metal | |
| SU697514A1 (en) | Method of preparing 2,4-diethyl-3-propylpentanolide-1,5 | |
| SU461103A1 (en) | The method of obtaining the monosodium salt - (-thioethyl-2-amino) -thiophosphoric acid | |
| RU2707190C1 (en) | Acetylacetone production method | |
| SU1351917A1 (en) | Method of obtaining acenaphthylenon-1(2h) | |
| SU557996A1 (en) | The method of obtaining trisubstituted aluminum phosphate | |
| SU737395A1 (en) | Method of preparing selenourea | |
| SU456525A1 (en) | The method of obtaining water-soluble salts of the ferrocene thiophosphinic acid series | |
| US2432438A (en) | Amides and their manufacture | |
| SU136350A1 (en) | Method for producing peroxide cumyl |