SU1693014A1 - Glue composition for glueing polymeric compositions - Google Patents
Glue composition for glueing polymeric compositions Download PDFInfo
- Publication number
- SU1693014A1 SU1693014A1 SU894749884A SU4749884A SU1693014A1 SU 1693014 A1 SU1693014 A1 SU 1693014A1 SU 894749884 A SU894749884 A SU 894749884A SU 4749884 A SU4749884 A SU 4749884A SU 1693014 A1 SU1693014 A1 SU 1693014A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- phenylenediamine
- diethylene glycol
- isopropyl alcohol
- glueing
- benzoic acid
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 13
- 238000004026 adhesive bonding Methods 0.000 title abstract 2
- 239000003292 glue Substances 0.000 title description 2
- 239000000853 adhesive Substances 0.000 claims abstract description 7
- 230000001070 adhesive effect Effects 0.000 claims abstract description 7
- 239000003822 epoxy resin Substances 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims abstract description 4
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims abstract 6
- WPYMKLBDIGXBTP-UHFFFAOYSA-N Benzoic acid Natural products OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000005711 Benzoic acid Substances 0.000 claims abstract 2
- 235000010233 benzoic acid Nutrition 0.000 claims abstract 2
- -1 M-Phenylenediamine Benzoic acid Diethylene glycol Chemical compound 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 2
- 150000001559 benzoic acids Chemical class 0.000 claims 1
- 239000004848 polyfunctional curative Substances 0.000 claims 1
- 150000003870 salicylic acids Chemical class 0.000 claims 1
- 239000004033 plastic Substances 0.000 abstract description 4
- 229920003023 plastic Polymers 0.000 abstract description 4
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 abstract description 2
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 abstract 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 230000035899 viability Effects 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
Изобретение относитс к клеевым композици м на основе эпоксидных смол дл склеивани элементов пластиковых лыж из различных полимерных материалов и позвол ет повысить прочность склеивани , снизить в зкость, температуру vi врем отверждени . Дл этого композици , включающа ,мае.%: эпоксидна дианова смола 68,8-70,8; фе- нилендиамин 10,3-10,5, дополнительно содержит ускоритель - бензойную кислоту 1,6-2,6; диэтиленгликоль 13,0- 13,3 и изопропиловый спирт - остальное. 2 табл.The invention relates to adhesive compositions based on epoxy resins for gluing plastic ski elements made of various polymeric materials and allows to increase the bonding strength, reduce viscosity, temperature, cure time. For this, a composition comprising, in May.%: Epoxy resin Dianova 68.8-70.8; phenylenediamine 10.3-10.5, additionally contains an accelerator - benzoic acid 1.6-2.6; diethylene glycol 13.0- 13.3 and isopropyl alcohol - the rest. 2 tab.
Description
Изобретение относитс к области клеевых композиций на основе эпоксидных смол и может быть использовано дл склеивани элементов пластиковых лыж из разных полимерных материалов - полистирола, полиэтилена , ламината (стеклонить, пропитанна эпоксидным св зующим), ак- рилонитрилбутадиенстирольного пластика (АБС-пластика).The invention relates to the field of adhesive compositions based on epoxy resins and can be used to glue plastic ski elements from different polymeric materials — polystyrene, polyethylene, laminate (glass-fiber, impregnated with epoxy binder), acrylonitrile-butadiene-styrene plastic (ABS).
Целью изобретени вл етс повышение прочности склеивани , снижение в зкости , температуры и времени отверждени .The aim of the invention is to increase the bonding strength, decrease viscosity, temperature and cure time.
Составы и свойства клеевых композиций по изобретению и известной представлены в табл. 1.The compositions and properties of the adhesive compositions according to the invention and known are presented in table. one.
Смеси получают простым смешением компонентов, кистью нанос т на поверхность образцов из различных полимерных материалов и отверждают в термошкафу при Т 70°С в течение 1ч.The mixtures are obtained by simple mixing of the components, applied with a brush to the surface of samples of various polymeric materials and cured in a heating cabinet at T 70 ° C for 1 hour.
Адгезионную прочность оценивают по прочности св зи полиэтилена и стеклоткани с АБС-пластиком при отрыве, определ емойAdhesive strength is assessed by the bond strength of polyethylene and fiberglass with ABS plastic with a tear-off determined by
в соответствии с ГОСТом. В зкость композиций определ ют на вискозиметре ВЗ-1 с соплом 5,4 мм при Т 20 ± 2°С.in accordance with GOST. The viscosity of the compositions is determined on a VZ-1 viscometer with a 5.4 mm nozzle at T 20 ± 2 ° C.
Жизнеспособность смесей оценивают по времени, в течение которого клей наноситс на склеиваемую поверхность при комнатной температуре.The viability of the mixtures is evaluated by the time during which the adhesive is applied to the bonding surface at room temperature.
Предел текучести клеевого соединени при сдвиге (Тсул. )определ ют при 20 ±2°С и скорости движени зажима разрывной машины , равной 10 мм/мин.The yield strength of the adhesive joint under shear (Tsul.) Is determined at 20 ± 2 ° C and the movement speed of the tensile clamping machine is 10 mm / min.
Разрывные характеристики ( 0риЈр) определ ют при 20 ± 2°С и скорости движени зажима 20 мм/мин.The rupture characteristics (0 ° C) are determined at 20 ± 2 ° C and the movement speed of the clamp 20 mm / min.
Вибростойкость определ етс по ИС077-98.Vibration resistance is determined by IS077-98.
Пластиковые лыжи, изготовленные с применением предлагаемой композиции, не разрушаютс после приложени нагрузки 5-7 МПа с частотой 3-5 Гц до 50000 циклов .Plastic skis made using the proposed composition are not destroyed after a load of 5-7 MPa is applied with a frequency of 3-5 Hz and up to 50,000 cycles.
В табл. 2 приведены сравнительные данные по скорости отверждени и достигаwIn tab. 2 shows comparative data on the cure rate and is achieved.
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с оwith about
СА ОSA Oh
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU894749884A SU1693014A1 (en) | 1989-08-07 | 1989-08-07 | Glue composition for glueing polymeric compositions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU894749884A SU1693014A1 (en) | 1989-08-07 | 1989-08-07 | Glue composition for glueing polymeric compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU1693014A1 true SU1693014A1 (en) | 1991-11-23 |
Family
ID=21474910
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU894749884A SU1693014A1 (en) | 1989-08-07 | 1989-08-07 | Glue composition for glueing polymeric compositions |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU1693014A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7148294B2 (en) * | 2001-03-30 | 2006-12-12 | Toray Industries, Inc. | Epoxy resin composition, process for producing fiber-reinforced composite materials and fiber-reinforced composite materials |
| RU2756173C1 (en) * | 2020-11-12 | 2021-09-28 | Федеральное государственное бюджетное учреждение науки Институт высокомолекулярных соединений Российской академии наук | Adhesive composition for polymer composite materials |
-
1989
- 1989-08-07 SU SU894749884A patent/SU1693014A1/en active
Non-Patent Citations (1)
| Title |
|---|
| Авторское свидетельство СССР № 806712,кл.С 08 L 63/02, 1978. * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7148294B2 (en) * | 2001-03-30 | 2006-12-12 | Toray Industries, Inc. | Epoxy resin composition, process for producing fiber-reinforced composite materials and fiber-reinforced composite materials |
| US7501087B2 (en) | 2001-03-30 | 2009-03-10 | Toray Industries, Inc. | Injection molding thermosetting resin composition into reinforcing fiber substrate |
| RU2756173C1 (en) * | 2020-11-12 | 2021-09-28 | Федеральное государственное бюджетное учреждение науки Институт высокомолекулярных соединений Российской академии наук | Adhesive composition for polymer composite materials |
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