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SU1308584A1 - Solution for processing glass surface - Google Patents

Solution for processing glass surface Download PDF

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Publication number
SU1308584A1
SU1308584A1 SU843785267A SU3785267A SU1308584A1 SU 1308584 A1 SU1308584 A1 SU 1308584A1 SU 843785267 A SU843785267 A SU 843785267A SU 3785267 A SU3785267 A SU 3785267A SU 1308584 A1 SU1308584 A1 SU 1308584A1
Authority
SU
USSR - Soviet Union
Prior art keywords
solution
mechanical strength
glass surface
order
metal salts
Prior art date
Application number
SU843785267A
Other languages
Russian (ru)
Inventor
Виктор Валентинович Шевченко
Игорь Васильевич Янышин
Original Assignee
Львовский политехнический институт им.Ленинского комсомола
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Львовский политехнический институт им.Ленинского комсомола filed Critical Львовский политехнический институт им.Ленинского комсомола
Priority to SU843785267A priority Critical patent/SU1308584A1/en
Application granted granted Critical
Publication of SU1308584A1 publication Critical patent/SU1308584A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C23/00Other surface treatment of glass not in the form of fibres or filaments

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Surface Treatment Of Glass (AREA)
  • Glass Compositions (AREA)

Abstract

Изобретение относитс  к производству листового стекла с улучшенг ными физико-химическими свойствами. С целью повышени  механической прочности и химической устойчивости раствор дл  обработки поверхности стекла содержит следующие компоненты, мас.%: РЬ(т) 5-6; NaNO, 2,7-3,7 или 4,,1; 2,3-4,5; Hj,0 - остальное. Механическа  прочность стекол, обработанных данным раствором на симметричный изгиб 165- 242 МПа, химическа  устойчивость после 1 ч кип чени  0,1-0,38%. 2 табл.The invention relates to the production of sheet glass with improved physicochemical properties. In order to increase the mechanical strength and chemical stability, the solution for treating the surface of the glass contains the following components, wt%: Pb (t) 5-6; NaNO, 2.7-3.7 or 4, 1; 2.3-4.5; Hj, 0 - the rest. The mechanical strength of glasses treated with this solution on a symmetrical bend is 165-242 MPa, chemical resistance after 1 hour of boiling is 0.1-0.38%. 2 tab.

Description

1one

Изобретение относитс  к стеклоделию , в частности к производствуThe invention relates to glassmaking, in particular to the production of

листового стекла дл  улучшени  его физико-химических свойств.sheet glass to improve its physicochemical properties.

Целью изобретени   вл етс  повышение механической прочности и химической устойчивости.The aim of the invention is to increase the mechanical strength and chemical resistance.

Предлагаемый раствор дл  обработки поверхности стекла готов т растворением в дистиллированной воде Pb(NO,)2, , и , или LiNOj в определенных соотношени х. Полученный раствор методом пульверизации наноситс  на поверхность листового стекла при 600 с. После этого стекло подвергают дополнительной термообработке в электрической силитовой печи при 700 С в течение 1-5 мин или 1 ч (в случае содержани  в растворе NaNO или LiNO соответственно) и. медленно охлаждают. В последнем слчае между ионами лити  покрыти  и ионами натри  стекла-подложки происходит ионный обмен.The proposed glass surface treatment solution is prepared by dissolving Pb (NO,) 2,, and, or LiNOj in distilled water in certain ratios. The resulting solution is sprayed onto the surface of sheet glass at 600 s. After that, the glass is subjected to an additional heat treatment in an electric silica oven at 700 ° C for 1-5 minutes or 1 hour (if NaNO or LiNO is contained in the solution, respectively) and. cool slowly. In the latter case, ion exchange occurs between the lithium ions of the coating and the sodium ions of the glass substrate.

В результате термообработки на стеклоподложке образуетс  стеклообразное , покрытие толщиной 5-20 мм следующих составов, мас.%: РЬО 50-60J В,0э 20-35; NajO или 15-20. 06As a result of the heat treatment on the glass substrate, a glassy coating of 5–20 mm is formed with the following compositions, wt%: PHO 50-60J B, 0e 20-35; NajO or 15-20. 06

5five

00

5five

разовавшеес  покрытие  вл етс  бесцветным , прозрачным, блест щим, равномерным по толщине.The developed coating is colorless, transparent, glossy, uniform in thickness.

Конкретные составы предлагаемых растворов приведены в табл. 1.Specific formulations of the proposed solutions are given in table. one.

Физико-химические свойства полученных покрытий представлены.в табл.2,Physico-chemical properties of the coatings are presented in Table 2,

Из табл. 2 следует, что стекла, обработанные предлагаемым раствором, обладают значительно более высокой механической прочностью и химической устойчивостью.From tab. 2 it follows that the glass treated with the proposed solution, have a significantly higher mechanical strength and chemical resistance.

Claims (1)

Формула изобретени Invention Formula Раствор дл  обработки поверхности стекла, включающий соли металлов и воду, отличающийс  тем, что, с целью повьшени  механической прочности и химической устойчивости, он дополнительно содержит , а в качестве солей металлов Pb(NOj)2 и NaNOg или LiNOg при следующем соотношении компонентов, мас.%:A solution for glass surface treatment, including metal salts and water, characterized in that, in order to increase mechanical strength and chemical stability, it additionally contains, and as metal salts, Pb (NOj) 2 and NaNOg or LiNOg in the following ratio of components, wt. .%: Pb(NO,),,5,0-6,0 Pb (NO,) ,, 5.0-6.0 NaNOg2,7-3,7NaNOg2,7-3,7 или LiNO, 4,6-6,1or LiNO, 4.6-6.1 Н ВОэ2,3-4,5H VO2,3-4,5 Н ООстальноеH OTHER Таблица 1Table 1 Составитель Г.Буровцева Редактор С.Пекарь Техред Л.СердюковаКорректор СЛИекмарCompiled by G. Burovtseva Editor S. Pekar Tehred L. Serdyukova Corrector SLIekmar Заказ 1770/19Тираж 428ПодписноеOrder 1770/19 Circulation 428 Subscription ВНИИПИ Государственного комитета СССРVNIIPI USSR State Committee по делам изобретений и открытий . 113035, Москва, Ж-35, Раушска  наб., д. 4/5for inventions and discoveries. 113035, Moscow, Zh-35, Raushsk nab. 4/5 Производственно-полиграфическое предпри тие, г. Ужгород, ул. Проектна , 4Production and printing company, Uzhgorod, st. Project, 4 Т а б л и Ц а 2Table 2
SU843785267A 1984-07-09 1984-07-09 Solution for processing glass surface SU1308584A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU843785267A SU1308584A1 (en) 1984-07-09 1984-07-09 Solution for processing glass surface

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU843785267A SU1308584A1 (en) 1984-07-09 1984-07-09 Solution for processing glass surface

Publications (1)

Publication Number Publication Date
SU1308584A1 true SU1308584A1 (en) 1987-05-07

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Family Applications (1)

Application Number Title Priority Date Filing Date
SU843785267A SU1308584A1 (en) 1984-07-09 1984-07-09 Solution for processing glass surface

Country Status (1)

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SU (1) SU1308584A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0278390A3 (en) * 1987-02-06 1989-02-22 E.I. Du Pont De Nemours And Company Thick film electronic materials
WO2002002473A1 (en) * 2000-06-30 2002-01-10 Globaltele Pty Ltd Method of coating glass articles

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Борисенко А.И; и др. Тонкослойные стеклоэмалевые и стеклокристал- лические покрыти .-Л.: Наука, 1970, с. 18-19. Авторское свидетельство СССР № 140966, кл. С 03 С 17/22, 1960. *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0278390A3 (en) * 1987-02-06 1989-02-22 E.I. Du Pont De Nemours And Company Thick film electronic materials
WO2002002473A1 (en) * 2000-06-30 2002-01-10 Globaltele Pty Ltd Method of coating glass articles

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